The Heavy Metal Is Cr, Zr, Or A Lanthanide Patents (Class 44/364)
  • Patent number: 10577553
    Abstract: Provided are water-based fuel additive compositions that, when combusted with a fuel containing vanadium in a gas turbine, inhibit vanadium hot corrosion in the gas turbine. The water-based fuel additive compositions include at least one rare earth element compound or alkaline earth element compound that retards vanadium corrosion resulting from combustion of vanadium rich fuel.
    Type: Grant
    Filed: August 9, 2017
    Date of Patent: March 3, 2020
    Assignee: General Electric Company
    Inventors: Murali Krishna Kalaga, Donald Meskers, Jr., Sundar Amancherla
  • Patent number: 8506657
    Abstract: The invention relates to a dispersion of the type comprising particles of a rare earth compound, particularly a compound of cerium, an acid and an organic phase, characterized in further comprising an anti-oxidant agent which can particularly be selected from substituted derivatives of phenol, aromatic amines or tocopherols. Said dispersion may be used as additive for diesel fuel for internal combustion engines, in particular as additive for diesel for diesel engines.
    Type: Grant
    Filed: April 1, 2004
    Date of Patent: August 13, 2013
    Assignee: Rhodia Operations
    Inventor: Gilbert Blanchard
  • Patent number: 8287607
    Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methyisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: October 16, 2012
    Inventors: Robert Wilfred Carroll, Noel Carroll, William F. Carroll, Michael Carroll
  • Patent number: 8056529
    Abstract: This invention presents a compact, light, efficient and high power output rotary internal combustion engine utilizing the waste heat. The engine has a rotor rotatable within a housing, but has no piston. The rotor has a plurality of combustion chambers, with inlets for introduction of fuel and outlets for exhaust of combustion products. The exhaust imparts rotation to the rotor within the housing. Fixed end caps are provided at each end of the housing. The engine is cooled with steam, air and water. The engine is suitable for applications that require efficient, high power to weight ratio, such as aircrafts, ships, and heavy duty transportation. The engine may use low grade fuel with a low cetane number, by using specially treated pulverized coal.
    Type: Grant
    Filed: July 20, 2009
    Date of Patent: November 15, 2011
    Inventor: Ziyad A. Qamhiyeh
  • Patent number: 7780746
    Abstract: The disclosure is directed to a method of enhancing a fuel value for a used or waste lubricating oil, lubricating oils having improved combustion and emission characteristics, and a business method for distributing and using waste oils as components of primary combustion fuels. In one embodiment, there is provided a lubricating oil composition having improved combustion and emission properties when burned as a used lubricating oil composition. The lubricating oil composition includes a major amount of oil of lubricating viscosity and a minor combustion improving amount of a combustion improving additive.
    Type: Grant
    Filed: September 22, 2006
    Date of Patent: August 24, 2010
    Assignee: Afton Chemical Corporation
    Inventors: Ian Macpherson, Allen A. Aradi, David Cleaver
  • Patent number: 7503944
    Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methylisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: March 17, 2009
    Inventors: Robert W. Carroll, Noel Carroll, William F. Carroll, Michael Carroll
  • Patent number: 7285140
    Abstract: A low-emissions diesel fuel comprises a catalyzed blend of fatty acid esters, preferably derived from soybean oil and/or tallow and aviation kerosene. The catalyzed blend is effective in lowering regulated emission pollutants, among which are NOx, particulates, hydrocarbons and carbon monoxide. The catalyst will comprise fuel-soluble platinum and/or cerium or iron. The cerium or iron are typically employed at concentrations of from 2 to 25 ppm and the platinum from 0.05 to 2 ppm, with preferred levels of cerium or iron being from 5 to 10 ppm, e.g., 7.5 ppm, and the platinum being employed at a level of from 0.1 to 0.5 ppm, e.g., 0.15 ppm. A preferred ratio of cerium and/or iron to platinum is from 75:1 to 10:1. The jet fuel component will typically be employed at a volume ratio to the fatty acid esters of from about 2:1 to about 5:1, e.g., about 4:1. The full range of blends extends from 50:1 to 1:50 with some benefit.
    Type: Grant
    Filed: February 3, 2003
    Date of Patent: October 23, 2007
    Assignee: Clean Diesel Technologies, Inc.
    Inventor: James M. Valentine
  • Patent number: 7063729
    Abstract: A low-emissions diesel fuel comprises fungible aviation kerosene grade 55, 50–300 ppm detergent, 25–500 ppm lubricity additive and a bimetallic, fuel soluble platinum and cerium fuel borne catalyst (e.g., 0.1–2.0 ppm platinum COD and 5–20 ppm cerium oleate). The fuel can be used as is or in the form of an emulsion. A method of reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined. Retarding engine timing can further reduce NOx and the use of a diesel particulate filter and/or diesel oxidation catalyst can provide further reductions in carbon monoxide, unburned hydrocarbons and particulates.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: June 20, 2006
    Assignee: Clean Diesel Technologies, Inc.
    Inventors: James M. Valentine, Barry N. Sprague, Jeremy D. Peter-Hoblyn
  • Publication number: 20040065002
    Abstract: The present invention provides a fuel oil additive capable of effectively improving the quality of fuel oils, which comprises an oil-soluble metal salt of organic acid having the general formula MR, where R is an organic acid radical and the corresponding organic acid is a C1-C40 saturated or unsaturated fatty acid, naphthenic acid, aromatic acid or alkylphenol, M is a metal cation and the corresponding metal is an alkali metal, alkali-earth metal, rare-earth metal, transition metal, or the like. The present invention also provides fuel oil products added to the fuel oil additive, including gasoline, diesel oil, kerosene, heavy oil, resid, or the like. The present invention especially provides a gasoline antiknock agent and a gasoline having excellent antiknock property, and this kind of gasoline antiknock agent is characteristic of effectiveness, economy, safety, no environmental pollution, no toxicity to human body, no adverse effect on parts of automobile engine, use convenience, and the like.
    Type: Application
    Filed: August 1, 2003
    Publication date: April 8, 2004
    Inventor: Shibin Hu
  • Publication number: 20030221362
    Abstract: A fuel additive composition comprising a solution or dispersion of an oil soluble metal carboxylate or metal complex derived from a compound of the formula: 1
    Type: Application
    Filed: March 10, 2003
    Publication date: December 4, 2003
    Inventors: Philip E. Collier, Rinaldo Caprotti
  • Patent number: 6652608
    Abstract: A fuel composition of the present invention exhibits minimized hydrolysis and increased fuel stability, even after extended storage at 65° F. for 6-9 months. The composition, which is preferably not strongly alkaline (3.0 to 10.5), is more preferably weakly alkaline to mildly acidic (4.5 to 8.5) and most preferably slightly acidic (6.3 to 6.8), includes a lower dialkyl carbonate, a combustion improving amount of at least one high heating combustible compound containing at least one element selected from the group consisting of aluminum, boron, bromine, bismuth, beryllium, calcium, cesium, chromium, cobalt, copper, francium, gallium, germanium, iodine, iron, indium, lithium, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, phosphorus, potassium, palladium, rubidium, sodium, tin, zinc, praseodymium, rhenium, silicon, vanadium, or mixture, and a hydrocarbon base fuel.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: November 25, 2003
    Inventor: William C. Orr
  • Patent number: 6649156
    Abstract: An organic sol containing: cerium oxide particles; an organic liquid phase; and at least one amphiphilic compound chosen from polyoxyethylenated alkyl ethers of carboxylic acids, polyoxyethylenated alkyl ether phosphates, dialkyl sulphosuccinates and quaternary ammonium compounds. A process for preparing the sol is characterized in that the abovementioned amphiphilic compound and the organic liquid phase are mixed together and the cerium oxide particles are then dispersed in the mixture obtained. According to a second variant, a mixture of cerium oxide and of at least one abovementioned amphiphilic compound is formed and the said mixture is then dispersed in the organic liquid phase.
    Type: Grant
    Filed: November 26, 2001
    Date of Patent: November 18, 2003
    Assignee: Rhodia Chimie
    Inventor: Jean-Yves Chane-Ching
  • Patent number: 6488724
    Abstract: The additive described essentially comprises a selected alkoxylated fatty amine or fatty amine derivative and a special metal salt compound, preferably a metal soap. This additive for heavy oils effects a good emulsification or dispersion of asphaltenes and other higher-molecular weight compounds and, in addition, inter alia, increased storage stability, improved pumpability due to decreased viscosity of the oil and longer service lives of the filter systems. In addition, it also effects enhanced combustion of the heavy oils. The effective amount of additive in these oils is 2 to 2000 ppm. The oils described are suitable, in particular, as furnace fuel for industrial plants and power stations and as engine fuel for marine engines.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: December 3, 2002
    Assignee: Clariant GmbH
    Inventors: Günther Hertel, Michael Feustel, Hakan Byström, Geoffrey Richards
  • Patent number: 6136048
    Abstract: A method for processing soot containing one or more rare earths, wherein said soot is contacted with an oxygen-containing gas, is disclosed. The method comprises (a) preparing an aqueous phase comprising a dispersion of at least one oxygenated metal compound; (b) simultaneously or consecutively contacting a suspension from step (a) with an organic phase including at least one amphiphilic agent and preferably an organic mixture or compound as the solvent; and c recovering the organic phase. Said oxygenated metal compound is produced by means of a method according to which a solution including at least one soluble rare-earth salt, usually an acetate and/or a chloride, is prepared; the solution is contacted with a basic medium and the resulting reaction mixture is maintained at a basic pH; and the precipitate formed by atomization or freeze-drying is recovered. Said method is useful in inorganic synthesis and catalysis.
    Type: Grant
    Filed: November 19, 1998
    Date of Patent: October 24, 2000
    Assignee: Rhodia Chimie
    Inventors: Thierry Birchem, Pierre MacAudiere, Olivier Touret
  • Patent number: 6096104
    Abstract: Compositions including at least three metals (M1, M2, M3) are disclosed. The first metal (M1) is at least one metal selected from the iron group or the manganese group, and is preferably selected from iron, manganese, cobalt and nickel. The second metal (M2) is at least one metal selected from the rare earth group and is preferably selected from cerium, lanthanum, neodymium and praseodymiium. The third metal (M3) is selected from the group of alkaline or alkaline-earth metals, and is preferably selected from barium, strontium, calcium and lithium. The weight ratio (R) of metal (M3) to metal (M2) is greater than 0.15, and preferably greater than 1.5.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: August 1, 2000
    Assignees: Total Raffinage Distribution S.A., Gamlen Industries S.A.
    Inventors: Corinne Van den Neste, Jean Peyrot, Guy Brisset, Gerard Briard
  • Patent number: 6023928
    Abstract: Operation of a diesel engine with low particulate emissions is achieved. A diesel engine is equipped with a platinum-catalyzed particulate trap. The engine is operated with a blend of diesel fuel and a fuel-soluble cerium composition to reduce the balance point of the trap with reduced cerium content. Preferably, the fuel will also contain a fuel-soluble organo-platinum group metal compound, or an effective platinum group metal compound can be added to the exhaust or combustion air.
    Type: Grant
    Filed: April 16, 1998
    Date of Patent: February 15, 2000
    Assignee: Clean Diesel Technologies, Inc.
    Inventors: Jeremy D. Peter-Hoblyn, James M. Valentine
  • Patent number: 5637118
    Abstract: A corrosion inhibited fuel mixture includes a hydrocarbon fuel, at least one vanadium composition, and a yttrium composition. The concentration of the yttrium composition in the mixture provides at least a stoichiometric amount of yttrium for a substantially complete reaction between the yttrium and V.sub.2 O.sub.5 formed from the vanadium composition when the mixture is burned. The yttrium and V.sub.2 O.sub.5 react to form YVO.sub.4. One particular yttrium composition useful as a hydrocarbon fuel soluble, water stable vanadium corrosion inhibitor incorporates a yttrium ester having at least four carbon atoms and a hydrocarbon fuel soluble chelating agent that includes 2,4-pentanediene. The complex has a molar ratio of 2,4-pentanediene to yttrium of up to 5:1.
    Type: Grant
    Filed: June 30, 1994
    Date of Patent: June 10, 1997
    Assignee: United Technologies Corporation
    Inventors: Norman S. Bornstein, Hilton A. Roth, Roscoe A. Pike
  • Patent number: 5501714
    Abstract: The invention provides a method employing a fuel additive to improve the operation of a pass-through oxidation catalyst over long periods of time with continued catalytic activity and without the undesirable conversion of SO.sub.2 to SO.sub.3. A pass-through catalyst support is continuously, selectively catalyzed by the combustion of a fuel containing a platinum group metal composition which burns to release the catalyst metal in active form. The effectiveness of the process is attributed to improved combustion in the engine by the catalyst and the treatment of the catalytic oxidizer with active catalyst metal released during combustion such that, in the exhaust system, the soluble organic fraction of the particulates and the levels of gaseous unburned hydrocarbons and carbon monoxide are significantly reduced. The catalysts conditioned by the present invention cause minimal conversion of SO.sub.2 to SO.sub.3.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: March 26, 1996
    Assignee: Platinum Plus, Inc.
    Inventors: James M. Valentine, Jeremy D. Peter-Hoblyn
  • Patent number: 5449387
    Abstract: Novel cerium (IV) oxidic compounds, well suited as catalysts, e.g., for the clean combustion of hydrocarbon fuels and for the "drying" of paint compositions, each Ce(IV) atom of which being coordinated with two anions of an organic oxyacid advantageously having a pKa greater than 1, preferably greater than 2, or a mixture of such oxyacids, and the oxidic oxygen atom or atoms of which being other than those comprising the organic oxyacids; representative such novel cerium (IV) oxidic compounds, whether yellow crystalline solids or yellow liquids, have the formula:(H.sub.2 O).sub.p [CeO(A).sub.2 .multidot.(AH).sub.n .multidot.].sub.min which the radicals A, which may be the same or different, are each the residue of an organic oxyacid of formula AH, p is an integer ranging from 0 to 5, n ranges from 0 to 2 and m is an integer ranging from 1 to 12.
    Type: Grant
    Filed: January 18, 1994
    Date of Patent: September 12, 1995
    Assignee: Rhone-Poulenc Chemicals Limited
    Inventors: Ian M. Hawkins, Heiko H. K. Mauermann
  • Patent number: 5266083
    Abstract: The invention presented relates to a method for reducing the emission of nitrogen oxides from a diesel engine without significant loss of fuel efficiency and without significant increases in carbon monoxide and hydrocarbon emissions. The method involves preparing a diesel engine such that the injection timing thereof is set at a point sufficient to obtain reductions in the nitrogen oxides emissions from the engine; and firing the diesel engine with a diesel fuel having admixed therein an additive which comprises a fuel soluble organometallic platinum group metal coordination composition.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: November 30, 1993
    Assignee: Platinum Plus, Inc.
    Inventors: Jeremy D. Peter-Hoblyn, James M. Valentine, W. Robert Epperly, Barry N. Sprague
  • Patent number: 4973336
    Abstract: A composition for the improvement of hydrocarbon fuel as exhibiting a boiling range of gasoline. The composition comprises an amine, a polyaminated detergent, a phenylamine diamine inhibited aromatic monomer stabilized by a polymeric substrate, a catalyst, a solvent, a promotor, alternative promoter and co-promoter. When used collectively, the recited composition has been found to significantly increase the octane of such hydrocarbon fuels while enhancing their anti-knock, anti-icing, anti-oxidency, anti-corrosion, detergency, and combustion properties and providing a lubrication quality to spark ignition-type engines used to burn the hydrocarbon fuels.
    Type: Grant
    Filed: August 11, 1989
    Date of Patent: November 27, 1990
    Inventor: Jean-Louis G. Gheysens
  • Patent number: 4968322
    Abstract: Disclosed herein are a fuel composition comprising a fuel oil added with at least two kinds of soaps selected from cerium, neodymium and lanthanum soaps and a fuel additive comprising an organic solution that contains at least two kinds of soaps selected from cerium, neodymium and lanthanum soaps.
    Type: Grant
    Filed: April 7, 1989
    Date of Patent: November 6, 1990
    Assignee: Nippon Mining Company, Limited
    Inventors: Shintaro Miyawaki, Kiyomi Ishii, Mamoru Yamane
  • Patent number: RE36117
    Abstract: A corrosion inhibited fuel mixture includes a hydrocarbon fuel, at least one vanadium composition, and a yttrium composition. The concentration of the yttrium composition in the mixture provides at least a stoichiometric amount of yttrium for a substantially complete reaction between the yttrium and V.sub.2 O.sub.5 formed from the vanadium composition when the mixture is burned. The yttrium and V.sub.2 O.sub.5 react to form YVO.sub.4. One particular yttrium composition useful as a hydrocarbon fuel soluble, water stable vanadium corrosion inhibitor incorporates a yttrium ester having at least four carbon atoms and a hydrocarbon fuel soluble chelating agent that includes 2,4-pentanedi.?.e.!..Iadd.o.Iaddend.ne. The complex has a molar ratio of 2,4-pentanedi.?.e.!..Iadd.o.Iaddend.ne to yttrium of up to 5:1.
    Type: Grant
    Filed: March 4, 1998
    Date of Patent: March 2, 1999
    Assignee: United Technologies Corporation
    Inventors: Norman S. Bornstein, Hilton A. Roth, Roscoe A. Pike