Heavy Metal Or Aluminum Carboxylate Salt Or Complex Patents (Class 44/363)
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Patent number: 11072753Abstract: The present invention aims a new diesel composition comprising a diesel fuel and from 0.01 to 0.8% by volume of a glycerol acetal or ketal. The new diesel composition shows a higher cetane number and better lubricity performances compared to known diesel compositions.Type: GrantFiled: July 5, 2016Date of Patent: July 27, 2021Assignee: RHODIA POLIAMIDA E ESPECIALIDADES S.A.Inventors: Sébastien Nicolas, Fernanda Grigoletto, Sergio Martins
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Publication number: 20140345192Abstract: A stabilized nano-Fe6-iron-crown ether complex is added to a heavy oil to reduce the viscosity of the heavy oil. The complex may be formed by preparing a solution of an iron salt and an oligomer crown compound in dialkylamine or diethylamine. Sodium tetrahydroboron (NaBH4) and dialkylamine or ethylendiamine are added at a temperature of 0-10° C. The mixture is heated to room temperature and boiled, thereby converting the formed iron (II)-borhydride complex (Fe(BH4)2) to a crown ether—iron-hydride complex [CWFe06].(2H)6. At higher temperature this last complex is converted to the Fe 6-crown nanocomposite complex.Type: ApplicationFiled: August 5, 2014Publication date: November 27, 2014Inventors: Alimamed L. Shabanov, Elmira M. Ramazanova, Uliviyya A. Gasanova
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Patent number: 8870981Abstract: An additive composition for a fuel comprises: (i) a metal compound selected from an iron compound, a manganese compound, a calcium compound, a cerium compound and mixtures thereof; (ii) an organic compound selected from a bicyclic monoterpene, substituted bicyclic monoterpene, adamantane, propylene carbonate and mixtures thereof; and (iii) a stabilizer. The additive composition allows fuels which are prone to separation, for example blended fuels or fuels having a high content of asphaltenes, to be used successfully.Type: GrantFiled: November 14, 2012Date of Patent: October 28, 2014Assignee: Innospec LimitedInventors: Miltiades Papachristos, Ian Malcolm McRobbie, Deepak Kamran
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Patent number: 8641791Abstract: The invention concerns a method for supplying iron, via the fuel, to the particulate trap of a diesel engine exhaust in a form suitable for promoting trap regeneration. The method involves the addition to the fuel of a defined colloid of iron oxide. Combustion of this colloid produces iron-containing compounds, especially iron oxides, which collect in association with carbonaceous particulate matter in the particulate trap, and function to promote the combustion of this matter. The colloid in particular shows a lower level of associated deposit formation on the fuel injectors than the iron additives of the prior art. The method is thus particularly suitable for modern engines showing increased susceptibility to fuel injector deposits. The colloid also shows a balance of properties providing excellent suitability for use as an additive in fuels, and especially in diesel engine on-board dosing devices.Type: GrantFiled: March 7, 2008Date of Patent: February 4, 2014Assignee: Infineum International LimitedInventor: Russell M. Thompson
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Publication number: 20140000156Abstract: Provided in a fuel additive for heavy oil, made using a composition comprising: an oil-soluble metallic compound containing any one metal selected from calcium, barium, manganese, and iron; alcohol; hydrotreated light distillate; paraffin (kerosene); mineral oil; and a nonionic surfactant. The fuel additive for heavy oil, when added in a small amount to a heavy oil, can lower the kinematic viscosity and the flash point of the heavy oil, minimize the occurrence of a residual carbon fraction, dust, a sulfur fraction, or the like, increase the caloric value of the heavy oil, and improve the combustion efficiency during the combustion of the heavy oil.Type: ApplicationFiled: March 2, 2012Publication date: January 2, 2014Inventor: Young Seo Lee
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Publication number: 20130283676Abstract: A fuel additive for hydrocarbon fuel that is fueled in fired burners and open flames for enhancing fuel storage, for enhancing fuel combustion by increasing fuel efficiency, and/or for reducing undesirable emissions, such as pollutants, includes an inorganic metal oxide, a metal carboxylate, an acid, and an organic dispersion fluid.Type: ApplicationFiled: April 19, 2013Publication date: October 31, 2013Applicant: ADITIVOS Y PROYECTOS ENERGÉTICOS E INDUSTRIALES, S.A. DE C.V.Inventors: Pablo Jesús Morales Leal, Jesús Pablo Morales Pinal
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Publication number: 20130185990Abstract: A composition for improving the combustion efficiency of an internal combustion engine. The composition includes a mixture of a hydrocarbon fuel and an organometallic soap selected from among several cerium-containing and ferric compounds. The cerium-containing compound or compounds increase the energy released during combustion of the fuel. The ferric compound or compounds coat an interior wall of a combustion chamber of the internal combustion engine to increase the power output of the engine by reducing the accumulation of residues deposited on the interior wall which interfere with the combustion of fuel.Type: ApplicationFiled: December 5, 2012Publication date: July 25, 2013Inventor: Stephen C. Perry
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Patent number: 8323362Abstract: A composition for improving the combustion efficiency of an internal combustion engine. The composition includes a mixture of a hydrocarbon fuel and an organometallic soap selected from among several cerium-containing and ferric compounds. The cerium-containing compound or compounds increase the energy released during combustion of the fuel. The ferric compound or compounds coat an interior wall of a combustion chamber of the internal combustion engine to increase the power output of the engine by reducing the accumulation of residues deposited on the interior wall which interfere with the combustion of fuel.Type: GrantFiled: March 7, 2011Date of Patent: December 4, 2012Inventor: Stephen C. Perry
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Patent number: 8287607Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methyisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.Type: GrantFiled: February 4, 2009Date of Patent: October 16, 2012Inventors: Robert Wilfred Carroll, Noel Carroll, William F. Carroll, Michael Carroll
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Patent number: 8211190Abstract: This invention relates to fuel oil, especially middle distillate fuel oil, compositions comprising middle distillate fuel oil and incorporated therein an incorporated therein an additive composition comprising (a) at least one fuel-soluble or fuel-dispersible neutral alkaline earth metal compound and/or at least one fuel-soluble or fuel-dispersible neutral alkali metal compound, and (b) at least one fuel-soluble or fuel-dispersible transition metal compound, characterized in that the fuel oil composition contains at most 0.05 mass % of sulfur, the total metal content derived from (a) and (b) in the fuel oil composition is at most 50 ppm by mass, and the mass proportion of (a) to (b), based on metal content, is in the range of from 1:99 to 99:1.Type: GrantFiled: April 20, 2005Date of Patent: July 3, 2012Assignee: Infineum International LimitedInventors: Rinaldo Caprotti, Brid Dilworth, Carlo S. Fava, Philip Collier
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Patent number: 8147568Abstract: A diesel fuel composition containing metallic additives that are stabilized against phase separation. The diesel fuel contains a colloidally dispersed or solubilized metal catalyst compound, which can be used for diesel particulate trap regeneration and, as a stabilizer, 5-1,000 ppm (weight) of an oil-soluble or oil-dispersible organic compound having a lipophilic hydrocarbyl chain having attached directly thereto at least two contiguous polar head functional groups, i.e., the functional groups are separated by no more than three carbon atoms. The diesel fuel composition is particularly suitable for use with diesel engines fitted with a particulate trap for emissions control.Type: GrantFiled: September 1, 2004Date of Patent: April 3, 2012Assignee: Infineum International LimitedInventors: Rinaldo Caprotti, Russell M. Thompson
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Patent number: 8088184Abstract: A simple method is disclosed to produce oil soluble nano particle size additives with significantly higher flash points to improve the safety aspects of these products especially when used in, around, and near high temperature combustion equipment.Type: GrantFiled: September 29, 2008Date of Patent: January 3, 2012Inventors: Mark D. Hughes, Daniel T. Smith, Kenneth W. Koch, Nathaniel Smoter
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Patent number: 7967876Abstract: There is disclosed a composition comprising an alloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n( . . . )n; wherein each capital letter and ( . . . ) is a metal; wherein A is a combustion modifier; B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer; wherein each subscript letter represents compositional stoichiometry; wherein n is greater than or equal to zero; and wherein the alloy comprises at least two different metals; and with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7. There is also disclosed a fuel additive comprising an alloy; a fuel composition comprising the fuel additive composition; methods of making the fuel additive composition; and methods of using the disclosed alloy.Type: GrantFiled: August 17, 2006Date of Patent: June 28, 2011Assignee: Afton Chemical CorporationInventors: Allen A. Aradi, Carl K. Esche, Jr., Katrina McIntosh, Tze-Chi Jao
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Patent number: 7901472Abstract: A composition for improving the combustion efficiency of an internal combustion Engine. The composition includes a mixture of a hydrocarbon fuel and an organometallic soap selected from among several cerium-containing and ferric compounds. The cerium-containing compound or compounds increase the energy released during combustion of the fuel. The ferric compound or compounds coat an interior wall of a combustion chamber of the internal combustion engine to increase the power output of the engine by reducing the accumulation of residues deposited on the interior wall which interfere with the combustion of fuel.Type: GrantFiled: August 29, 2007Date of Patent: March 8, 2011Assignee: ConSeal International IncorporatedInventor: Stephen C. Perry
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Publication number: 20110021396Abstract: A composition and method for improving the performance, and thus, also the fuel economy, of an internal combustion engine by introducing a fuel additive into the engine's fuel supply to enhance fuel lubricity. The composition can feature a mixture of esters, glycol ether, and a solvent. The mixture of esters can include adipate esters, azelate esters, dodecanedioate esters, sebacate esters, or phthalate esters. Esters that may be used to create the composition can include a mixture of two or more adipate esters such as, for example, an adipic acid ester, a glutaric acid ester, and a succinic acid ester. The composition can further feature a smoke suppressant that can be an organometallic soap. The organometallic soap can be an iron salt of a fatty acid such as, for example, ferrocene. The composition can be used as a combustion modifier fuel additive and as a lubricating oil.Type: ApplicationFiled: October 1, 2010Publication date: January 27, 2011Inventor: Stephen C. Perry
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Patent number: 7704376Abstract: The use of water-soluble aromatic polysulfonic acid salts for inhibiting fouling in process equipment used in the thermal treatment of heavy oils.Type: GrantFiled: May 12, 2005Date of Patent: April 27, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramesh Varadaraj, Michael Siskin, Leo D. Brown, Maa S. Maa
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Publication number: 20100043411Abstract: An iron-containing polymer is provided for use as a fuel additive for promoting trap regeneration. The polymer shows a beneficial balance of physical properties, and is prepared from iron salts by a polymerisation process involving base addition, and subsequent coordination of branched-chain polycarboxylate ligands. The polymer can be stored in highly concentrate form, and shows particular suitability for on board dosing systems.Type: ApplicationFiled: March 7, 2008Publication date: February 25, 2010Inventors: Colin Morton, Russell M. Thompson
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Publication number: 20090282730Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methyisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.Type: ApplicationFiled: February 4, 2009Publication date: November 19, 2009Inventors: Robert Wilfred Carroll, Noel Carroll, William F. Carroll, Michael Carroll
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Patent number: 7594989Abstract: A method for upgrading heavy oils by contacting the heavy oil with a water-soluble aromatic polysulfonic acid salt and then thermally treating the contacted heavy oil. The polysulfonic acid salt can be recovered and recycled from contacting the heavy oil. The polysulfonic acid salt is recovered and recycled. The invention also relates to the upgraded product from the enhanced thermal treatment process.Type: GrantFiled: May 12, 2005Date of Patent: September 29, 2009Assignee: ExxonMobile Research and Engineering CompanyInventors: Ramesh Varadaraj, Leo D. Brown
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Patent number: 7585336Abstract: A fuel additive composition comprising a solution or dispersion of an oil soluble metal carboxylate or metal complex derived from a compound of the formula: where R1, R2, R3 and R4 represent hydrogen or a hydrocarbyl having 1-30 carbon atoms (C1-C30), but at least two of R1, R2, R3 or R4 are C1-C30 hydrocarbyl; R5 is a hydrocarbyl having 1 to 120 carbon atoms and m and n may each be zero or an integer such that the total number of carbon atoms in the carboxylate is not more than 125.Type: GrantFiled: March 10, 2003Date of Patent: September 8, 2009Assignee: Infineum International LimitedInventors: Philip E. Collier, Rinaldo Caprotti
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Patent number: 7524340Abstract: A catalyst and method for improving combustion efficiency in boilers, engines, and other equipment by adding to fossil and other fuels a fuel additive that contains an oil-soluble iron compound and an over-based magnesium compound and for which the median particle size of the additive is less than about 0.01 micrometers.Type: GrantFiled: April 28, 2003Date of Patent: April 28, 2009Inventor: Walter R. May
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Patent number: 7503944Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methylisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.Type: GrantFiled: November 8, 2002Date of Patent: March 17, 2009Inventors: Robert W. Carroll, Noel Carroll, William F. Carroll, Michael Carroll
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Patent number: 7332001Abstract: A method of enhancing the operation of diesel fuel combustion systems in a combustion system includes supplying a fuel and additive that includes a manganese compound to a diesel fuel combustion system. The fuel is then combusted in the combustion chamber to produce at least one byproduct including the manganese compound. The manganese compound is supplied in an amount effective to complex with the combustion byproduct. The diesel fuel combustion system operation is enhanced by improving the attributes of lubricating oil loaded with the combustion byproduct soot particles.Type: GrantFiled: October 2, 2003Date of Patent: February 19, 2008Assignee: Afton Chemical CorporationInventors: Gregory H. Guinther, Mark T. Devlin, Joseph W. Roos, David M. Human
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Patent number: 7306634Abstract: A fuel additive iron salt composition effective in improving the operation of diesel engine particulate traps when added to a diesel fuel so as to provide 1-25 ppm iron in the fuel which comprises an oil soluble or oil dispersible neutral or overbased iron salt of an acidic organic compound, 50-99 mole % of the total iron present in the composition being in the ferric form, the balance being the ferrous form.Type: GrantFiled: May 19, 2003Date of Patent: December 11, 2007Assignee: Infineum International LimitedInventors: Rinaldo Caprotti, Robert J. Pilling
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Patent number: 7300477Abstract: A combustion additive is used for protecting and improving the operation of diesel fuel combustion systems. The additive contains one or more iron-containing compounds. The additive can be added to the fuel prior to introduction into a combustion chamber or to the exhaust after the combustion chamber. The additive will then enhance the operation of diesel fuel combustions systems by improving, for example, exhaust aftertreatment performance.Type: GrantFiled: August 14, 2003Date of Patent: November 27, 2007Assignee: Afton Chemical CorporationInventors: Timothy J. Brennan, Scott D. Schwab
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Patent number: 7285140Abstract: A low-emissions diesel fuel comprises a catalyzed blend of fatty acid esters, preferably derived from soybean oil and/or tallow and aviation kerosene. The catalyzed blend is effective in lowering regulated emission pollutants, among which are NOx, particulates, hydrocarbons and carbon monoxide. The catalyst will comprise fuel-soluble platinum and/or cerium or iron. The cerium or iron are typically employed at concentrations of from 2 to 25 ppm and the platinum from 0.05 to 2 ppm, with preferred levels of cerium or iron being from 5 to 10 ppm, e.g., 7.5 ppm, and the platinum being employed at a level of from 0.1 to 0.5 ppm, e.g., 0.15 ppm. A preferred ratio of cerium and/or iron to platinum is from 75:1 to 10:1. The jet fuel component will typically be employed at a volume ratio to the fatty acid esters of from about 2:1 to about 5:1, e.g., about 4:1. The full range of blends extends from 50:1 to 1:50 with some benefit.Type: GrantFiled: February 3, 2003Date of Patent: October 23, 2007Assignee: Clean Diesel Technologies, Inc.Inventor: James M. Valentine
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Patent number: 7229482Abstract: A method of reducing smoke and particulate emissions from steam boilers and process heaters operating on solid fuel by adding a fuel additive which contains an oil-dispersible iron compound and an over-based magnesium compound to the solid fuel.Type: GrantFiled: April 28, 2003Date of Patent: June 12, 2007Assignee: SFA International, Inc.Inventor: Walter R. May
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Patent number: 7063729Abstract: A low-emissions diesel fuel comprises fungible aviation kerosene grade 55, 50–300 ppm detergent, 25–500 ppm lubricity additive and a bimetallic, fuel soluble platinum and cerium fuel borne catalyst (e.g., 0.1–2.0 ppm platinum COD and 5–20 ppm cerium oleate). The fuel can be used as is or in the form of an emulsion. A method of reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined. Retarding engine timing can further reduce NOx and the use of a diesel particulate filter and/or diesel oxidation catalyst can provide further reductions in carbon monoxide, unburned hydrocarbons and particulates.Type: GrantFiled: November 8, 2002Date of Patent: June 20, 2006Assignee: Clean Diesel Technologies, Inc.Inventors: James M. Valentine, Barry N. Sprague, Jeremy D. Peter-Hoblyn
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Patent number: 6881235Abstract: A method of reducing smoke and particulate emissions from an exhaust gas from a spark-ignited reciprocating engine by adding a fuel additive which contains an oil-soluble iron compound and an over-based magnesium compound to liquid petroleum fuel.Type: GrantFiled: April 17, 2003Date of Patent: April 19, 2005Inventor: Walter R. May
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Publication number: 20040211112Abstract: A fuel composition, and a method and an apparatus for combusting it in a two-stroke engine, in which molybdenum introduced from the fuel will interact with alkaline earth metal originating from a detergent or other co-ingredient of the fuel in the combustion products to increase detergency without increasing the level of alkaline earth metal or compounds present in the fuel or combustion products thereof. In this manner, the engine operates more cleanly and efficiently without increasing the risk of harmful alkaline earth materials and compounds thereof blocking and poisoning catalysts, sensors and/or automotive on-board diagnostic devices, and it can lead to improved durability of exhaust after treatment systems.Type: ApplicationFiled: March 29, 2004Publication date: October 28, 2004Inventors: Nicholas P. Clague, Michael A. Haynes, Peter Growcott
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Publication number: 20040118032Abstract: The present invention relates to the reduction or inhibition of corrosion in an atmospheric burner unit by adding to a combustion system an effective amount of manganese, or a manganese precursor source, or derivative. The system may further include a catalyst package that may be composed of one or more individual organometallic compounds of Li, Na, K, Mg, Ca, Sr, Ba, Mo, Fe, Co, Pt, Ce, and combinations, mixtures or precursors thereof. The manganese component of the catalyst package of the present invention reduces or eliminates the poisoning of the combustion system, whereby improved combustion and reduced emissions result. In addition, this invention inhibits both high- and low-temperature corrosion that occurs on the hot surfaces of burner furnace walls and tubes, and on cooler surfaces of the burner unit exhaust stack.Type: ApplicationFiled: December 18, 2002Publication date: June 24, 2004Inventors: Allen A. Aradi, Michael Wayne Adams, Stephen Alan Factor
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Publication number: 20040074140Abstract: A method of enhancing the operation of an emission after treatment system in a combustion system includes supplying a fuel and additive that includes a manganese compound to a combustion system. The fuel is then combusted in the combustion chamber to produce at least one byproduct including the manganese compound. The manganese compound is supplied in an amount effective to complex with the combustion byproduct. The combustion system may include a catalyzed, or alternatively, a continuously regenerating technology, diesel particulate filter.Type: ApplicationFiled: October 16, 2002Publication date: April 22, 2004Inventors: Gregory H. Guinther, Joseph W. Roos, David M. Human, Scott D. Schwab
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Publication number: 20040068921Abstract: A fuel additive iron salt composition effective in improving the operation of diesel engine particulate traps when added to a diesel fuel so as to provide 1-25 ppm iron in the fuel which comprises an oil soluble or oil dispersible neutral or overbased iron salt of an acidic organic compound, 50-99 mole % of the total iron present in the composition being in the ferric form, the balance being the ferrous form.Type: ApplicationFiled: May 19, 2003Publication date: April 15, 2004Inventors: Rinaldo Caprotti, Robert J. Pilling
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Publication number: 20040065002Abstract: The present invention provides a fuel oil additive capable of effectively improving the quality of fuel oils, which comprises an oil-soluble metal salt of organic acid having the general formula MR, where R is an organic acid radical and the corresponding organic acid is a C1-C40 saturated or unsaturated fatty acid, naphthenic acid, aromatic acid or alkylphenol, M is a metal cation and the corresponding metal is an alkali metal, alkali-earth metal, rare-earth metal, transition metal, or the like. The present invention also provides fuel oil products added to the fuel oil additive, including gasoline, diesel oil, kerosene, heavy oil, resid, or the like. The present invention especially provides a gasoline antiknock agent and a gasoline having excellent antiknock property, and this kind of gasoline antiknock agent is characteristic of effectiveness, economy, safety, no environmental pollution, no toxicity to human body, no adverse effect on parts of automobile engine, use convenience, and the like.Type: ApplicationFiled: August 1, 2003Publication date: April 8, 2004Inventor: Shibin Hu
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Publication number: 20040035045Abstract: A fuels additive metallic salt composition effective in improving the operation of diesel engine particulate traps when added to a diesel fuel so as to provide 1-25 ppm metal in the fuel which comprises an oil soluble or oil dispersible overbased metal salt of an acidic organic compound, said salt composition containing 5-85 wt. % of a stoichiometric excess of metal over that required to neutralize the anionic portion of the salt, the metal being selected from the group consisting of Ca, Fe, Mg, Sr, Na, Ti, Zr, Mn, Zn and Ce.Type: ApplicationFiled: May 19, 2003Publication date: February 26, 2004Inventors: Rinaldo Caprotti, Robert J. Pilling
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Publication number: 20040031192Abstract: An additive for fuels such as diesel oil and fuel oil, used respectively for diesel engines and boilers of various types, is described, comprising a metal oxidation catalyst, an organic nitrate and a dispersing agent in suitable ratios, able to improve combustion efficiency in such a way as to reduce the formation of particulate by as much as 90%.Type: ApplicationFiled: May 22, 2003Publication date: February 19, 2004Inventor: Cesare Pedrazzini
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Publication number: 20030221362Abstract: A fuel additive composition comprising a solution or dispersion of an oil soluble metal carboxylate or metal complex derived from a compound of the formula: 1Type: ApplicationFiled: March 10, 2003Publication date: December 4, 2003Inventors: Philip E. Collier, Rinaldo Caprotti
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Patent number: 6652608Abstract: A fuel composition of the present invention exhibits minimized hydrolysis and increased fuel stability, even after extended storage at 65° F. for 6-9 months. The composition, which is preferably not strongly alkaline (3.0 to 10.5), is more preferably weakly alkaline to mildly acidic (4.5 to 8.5) and most preferably slightly acidic (6.3 to 6.8), includes a lower dialkyl carbonate, a combustion improving amount of at least one high heating combustible compound containing at least one element selected from the group consisting of aluminum, boron, bromine, bismuth, beryllium, calcium, cesium, chromium, cobalt, copper, francium, gallium, germanium, iodine, iron, indium, lithium, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, phosphorus, potassium, palladium, rubidium, sodium, tin, zinc, praseodymium, rhenium, silicon, vanadium, or mixture, and a hydrocarbon base fuel.Type: GrantFiled: December 8, 1997Date of Patent: November 25, 2003Inventor: William C. Orr
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Publication number: 20030196371Abstract: A method of reducing smoke and particulate emissions from an exhaust gas from a spark-ignited reciprocating engine by adding a fuel additive which contains an oil-soluble iron compound and an over-based magnesium compound to liquid petroleum fuel.Type: ApplicationFiled: April 17, 2003Publication date: October 23, 2003Inventor: Walter R. May
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Publication number: 20030192232Abstract: A catalyst and method for improving combustion efficiency in boilers, engines, and other equipment by adding to fossil and other fuels a fuel additive that contains an oil-soluble iron compound and an over-based magnesium compound and for which the median particle size of the additive is less than about 0.01 micrometers.Type: ApplicationFiled: April 28, 2003Publication date: October 16, 2003Inventor: Walter R. May
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Publication number: 20030182847Abstract: An additive to a fuel oil for a Diesel engine having a Diesel particulate filter (DPF), which comprises a molybdenum compound and having the function of improving the combustion property of a particulate matter (PM) trapped with DPF; a fuel oil comprising the additive; a lubricating oil composition for a Diesel engine having DPF, which has a sulfated ash content of 1.0% by weight or smaller, a sulfur content of 0.3% by weight or smaller and a molybdenum content of 100 ppm or greater; and DPF for removing PM in combustion gas discharged from a Diesel engine vehicle by trapping and burning PM, DPF comprising a filter supporting a molybdenum compound. The combustion property of PM trapped with the filter of DPF is improved, PM is burned at a low temperature with stability, the efficiency of removal of PM is improved and the life of DPF is increased.Type: ApplicationFiled: February 24, 2003Publication date: October 2, 2003Inventor: Tadashi Katafuchi
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Publication number: 20030163950Abstract: The object of the present invention is to improve the efficiency of combustion of fuel and to reduce toxic components contained in the combustion gas.Type: ApplicationFiled: December 6, 2002Publication date: September 4, 2003Inventor: Shinji Makino
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Publication number: 20030159338Abstract: The invention concerns inhibition of vanadium corrosion of thermal equipment materials burning vanadium-contaminated liquid fuels using nickel compounds. The invention is applicable in particular to liquid fuel combustion in gas turbines.Type: ApplicationFiled: March 21, 2003Publication date: August 28, 2003Inventors: Michel Moliere, Emmanuel Rocca, Pierre Steinmetz
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Publication number: 20030126789Abstract: A low-emissions diesel fuel comprises fungible aviation kerosene grade 55, 50-300 ppm detergent, 25-500 ppm lubricity additive and a bimetallic, fuel soluble platinum and cerium fuel borne catalyst (e.g., 0 1-2 0 ppm platinum COD and 5-20 pmm cerium oleate). The fuel can be used as is or in the form of an emulsion A method of reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined.Type: ApplicationFiled: November 8, 2002Publication date: July 10, 2003Inventors: James M. Valentine, Barry N. Sprague, Jeremy D. Peter-Hoblyn
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Patent number: 6488724Abstract: The additive described essentially comprises a selected alkoxylated fatty amine or fatty amine derivative and a special metal salt compound, preferably a metal soap. This additive for heavy oils effects a good emulsification or dispersion of asphaltenes and other higher-molecular weight compounds and, in addition, inter alia, increased storage stability, improved pumpability due to decreased viscosity of the oil and longer service lives of the filter systems. In addition, it also effects enhanced combustion of the heavy oils. The effective amount of additive in these oils is 2 to 2000 ppm. The oils described are suitable, in particular, as furnace fuel for industrial plants and power stations and as engine fuel for marine engines.Type: GrantFiled: October 27, 1997Date of Patent: December 3, 2002Assignee: Clariant GmbHInventors: Günther Hertel, Michael Feustel, Hakan Byström, Geoffrey Richards
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Patent number: 6488725Abstract: The present invention relates to the use of fuel additives in the regeneration of particulate filter traps, e.g. diesel particulate filter traps. The invention further relates to fuel additives suitable for use in such a process.Type: GrantFiled: June 30, 2000Date of Patent: December 3, 2002Assignee: The Associated Octel Company LimitedInventors: Matthew William Vincent, Paul Joseph Richards, Stephen Leonard Cook
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Patent number: 6096104Abstract: Compositions including at least three metals (M1, M2, M3) are disclosed. The first metal (M1) is at least one metal selected from the iron group or the manganese group, and is preferably selected from iron, manganese, cobalt and nickel. The second metal (M2) is at least one metal selected from the rare earth group and is preferably selected from cerium, lanthanum, neodymium and praseodymiium. The third metal (M3) is selected from the group of alkaline or alkaline-earth metals, and is preferably selected from barium, strontium, calcium and lithium. The weight ratio (R) of metal (M3) to metal (M2) is greater than 0.15, and preferably greater than 1.5.Type: GrantFiled: April 27, 1999Date of Patent: August 1, 2000Assignees: Total Raffinage Distribution S.A., Gamlen Industries S.A.Inventors: Corinne Van den Neste, Jean Peyrot, Guy Brisset, Gerard Briard
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Patent number: 6093223Abstract: Vehicular emissions are reduced/purified via combustion of the hydrocarbon fuel therefor, e.g., diesel fuel, in the presence of a cerium compound, preferably a cerium (IV) compound, to produce soots having depressed ignition temperatures that contain effective purifying amounts of aggregates of ceric oxide crystallites, the largest particle size dimension of which ranging from 50 .ANG. (5 nanometers) to 10,000 .ANG. (1,000 nanometers) and the crystallite sizes of which, measured by Debye-Scherrer technique, ranging from 50 .ANG. (5 nanometers) to 250 .ANG. (25 nanometers).Type: GrantFiled: November 4, 1996Date of Patent: July 25, 2000Assignee: Rhone-Poulenc ChimieInventors: Jacques Lemaire, Denis Petta, Olivier Touret
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Patent number: 6056792Abstract: A process of improving the oxidation of carbonaceous products derived from the combustion of fuel and improving combustion of a fuel is described. The process comprises adding to the fuel before combustion thereof a composition comprising at least an organo-metallic complex of a Group I or Group II metal characterized in that the concentration of the complex in the fuel before combustion is 30 ppm or less.Type: GrantFiled: February 13, 1998Date of Patent: May 2, 2000Assignee: The Associated Octel Company LimitedInventors: Donald Barr, Stephen L. Cook, Paul J. Richards, Maurice W. Rush
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Patent number: 6051040Abstract: A method improves the operation of a diesel engine through the use of a fuel additive, a diesel particulate trap and a NO.sub.x -reducing catalyst. The operation of the NO.sub.x -reducing catalyst is enhanced by the introduction of urea or like compound upstream of the catalyst at temperatures effective for non-catalytic NO.sub.x reduction and the generation of ammonia. The additive comprises fuel-soluble compositions of platinum group metal in effective amounts to lower the emissions of unburned hydrocarbons and carbon monoxide from the trap. The catalytic activity provided to the exhaust system by the fuel additive is selective and preferably reduces the oxidation of SO.sub.2 to SO.sub.3. The platinum group metal compositions are preferably added in amounts effective to provide concentrations of the metal in the fuel of less than 1 part per million (ppm). Lithium and/or sodium compositions can be used in amounts effective to reduce the trap regeneration temperature, e.g.Type: GrantFiled: November 26, 1997Date of Patent: April 18, 2000Assignee: Clean Diesel Technologies, Inc.Inventor: Jeremy D. Peter-Hoblyn