Organic Nitrogen Compound Salt Of Carboxylic Acids Patents (Class 44/408)
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Patent number: 8894726Abstract: A fuel composition for a fuel injected diesel engine, a method for improving performance of fuel injectors and a method for cleaning fuel injectors for a diesel engine. The fuel composition includes a major amount of fuel and a minor effective amount of a reaction product of (i) a hydrocarbyl substituted compound containing at least one tertiary amino group and (ii) a halogen substituted C2-C8 carboxylic acid, ester, amide, or salt thereof, wherein the reaction product as made is substantially devoid of free anion species.Type: GrantFiled: June 13, 2012Date of Patent: November 25, 2014Assignee: Afton Chemical CorporationInventors: Xinggao Fang, Scott D. Schwab
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Patent number: 8863700Abstract: In accordance with the disclosure, exemplary embodiments provide a fuel additive concentrate, a method for cleaning fuel injectors, a method for restoring power to a diesel fuel injected engine, a fuel composition, and a method of operating a fuel injected diesel engine. The additive concentrate includes (a) a hydrocarbyl substituted quaternary ammonium internal salt; and (b) a reaction product of (i) a hydrocarbyl substituted dicarboxylic acid, anhydride, or ester and (ii) an amine compound or salt thereof of the formula wherein R is selected from hydrogen and a hydrocarbyl group containing from about 1 to about 15 carbon atoms, and R1 is selected from hydrogen and a hydrocarbyl group containing from about 1 to about 20 carbon atoms. The reaction product (b) on average has less than 2 amino-triazole groups per molecule. A weight ratio of (a) to (b) in the additive concentrate ranges from about 10:1 to about 1:10.Type: GrantFiled: November 1, 2012Date of Patent: October 21, 2014Assignee: Afton Chemical CorporationInventors: Xinggao Fang, Scott D. Schwab
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Patent number: 8734542Abstract: The invention relates to the use of at least one oil-soluble compound B) which acts as a nucleating agent for paraffin crystallization and which is selected from ethylene copolymers and 2 to 10.5 mole % of at least one ethylenically unsaturated carbonic ester for improving the response of cold flow improvers for mineral oils C), which are different from B), in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.Type: GrantFiled: June 17, 2008Date of Patent: May 27, 2014Assignee: Clariant Finance (BVI) LimitedInventors: Matthias Krull, Robert Janssen
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Patent number: 8690970Abstract: A fuel composition for a fuel injected internal combustion engine, a method for improving performance of fuel injectors and a method for cleaning fuel injectors for a fuel-injected internal combustion engine. The fuel composition includes a major amount of fuel and a minor, effective amount of a quaternary ammonium salt of a hydrocarbyl amine and a hydrocarbyl-substituted alkyl-hydroxybenzoate. The amount of quaternary ammonium salt present in the fuel is sufficient to improve performance of the fuel injected internal combustion engine having combusted the composition compared to the performance of such engine having combusted a fuel composition that does not contain the quaternary ammonium salt. The hydrocarbyl-substituted alkyl-hydroxybenzoate contains one or more hydrocarbyl substituents providing a total of at least 8 up to about 200 carbon atoms, provided the one or more hydrocarbyl substituents do not contain sulfur, oxygen, or nitrogen atoms.Type: GrantFiled: February 24, 2012Date of Patent: April 8, 2014Assignee: Afton Chemical CorporationInventor: Xinggao Fang
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Patent number: 8668749Abstract: A diesel fuel additive composition, a fuel containing the fuel additive, a method for improving diesel engine performance using the additive. The diesel fuel additive includes a reaction product of (a) a hydrocarbyl-substituted acylating agent and (b) a reactant selected from the group consisting of a nitrogen-containing compound, a hydroxyl-containing compound, and water that provides a reaction product selected from the group consisting (1) a mono-amide/mono-acid or metal free mono-acid salt thereof, (2) a diacid or metal free diacid salt thereof, and (3) mono-ester/mono-acid or metal free mono-acid salt thereof. The reaction product includes at least about 10 molar percent acid groups based on total moles of the reaction product.Type: GrantFiled: November 3, 2010Date of Patent: March 11, 2014Assignee: Afton Chemical CorporationInventor: Xinggao Fang
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Patent number: 8647395Abstract: A surfactant package for a water-in-hydrocarbon emulsion includes a fatty acid component; a fatty acid salt component; an alcohol component and a salt of carboxylic acid. Emulsions formed using this surfactant package are stable and have ratios of water to surfactant of at least about 3.Type: GrantFiled: August 27, 2010Date of Patent: February 11, 2014Assignee: Intevep, S.A.Inventors: Xiomara Gutierrez, Hercilio Rivas, Migdalia Carrasquero, Luis Marcano
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Patent number: 8413475Abstract: The disclosure relates to a cold rolling fluid, including: (a) a hydrocarbon base including at least 50 wt % of isoparaffins; (b) one or more frictional modifiers selected from among fatty alcohols, fatty acids, fatty amines, fatty acid esters, or polymer esters resulting from the esterification of alpha-olefin copolymers and dicarboxylic acids using alcohols; and (c) one or more phosphorous anti-wear and/or extreme pressure additives. The disclosure also relates to an emulsion containing the rolling fluid and to the use of the rolling fluid for cold-rolling steel.Type: GrantFiled: July 2, 2010Date of Patent: April 9, 2013Assignee: Total Raffinage MarketingInventors: Nicole Genet, Frédéric Jarnias
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Patent number: 8313541Abstract: The use of a mixture comprising (A) 5 to 95% by weight of at least one oil-soluble polar nitrogen compound which can interact with paraffin crystals in middle distillate fuels under cold conditions, and (B) 5 to 95% by weight of at least one oil-soluble aliphatic compound with an alkyl or alkenyl chain having at least 8 carbon atoms, obtainable from aliphatic mono- or dicarboxylic acids having 4 to 300 carbon atoms or derivatives thereof with mono- or polyamines or with alcohols, for lowering the cloud point in middle distillate fuels which, before the addition of additives, have a CP of ?8.0° C. or lower by at least 1.5° C. compared to the unadditized middle distillate fuel at a dosage of the mixture of 50 to 300 ppm by weight, with no simultaneous deterioration in the response behavior for the lowering of the cold filter plugging point on addition of cold flow improvers.Type: GrantFiled: April 5, 2010Date of Patent: November 20, 2012Assignee: BASF SEInventors: Frank-Olaf Maehling, Jan Strittmatter, Heinrich Lubojanski, Andreas Minke, Uwe Rebholz, Alex J. Attlesey, Stephan B. Lopes, II
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Patent number: 8187345Abstract: Provided is a mixture containing: (a) a polar oil-soluble nitrogen compounds which is capable of sufficiently dispersing paraffin crystals precipitated out under cold conditions in a fuel and is a reaction product formed from reacting a poly(C2- to C20-carboxylic acid), which has at least one tertiary amino group, with a primary or secondary amine; (b) an oil-soluble acid amide reaction product formed from reacting a polyamide, which has from 2 to 1000 carbon atoms, with a C8- to C30-fatty acid or fatty acid-like compound, which has a free carboxyl group; and (c) an oil-soluble reaction product formed from reacting an ?,?-dicarboxylic acid, which has from 4 to 300 carbon atoms, or a derivatives thereof, with a primary alkylamine, wherein the sum of components (a) to (c) constitute 100 wt. % of the mixture. The mixture is suitable as a paraffin dispersant in fuels, especially those having a biodiesel content.Type: GrantFiled: June 12, 2007Date of Patent: May 29, 2012Assignee: BASF SEInventors: Ansgar Eisenbeis, Irene Troetsch-Schaller, Ulrich Annen
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Patent number: 8100988Abstract: The invention concerns a multifunctional additive enabling fuels to be operable in cold conditions, consisting of copolymers of at least a dicarboxylic compound with at least an olefin, and whereon are grafted nitrogenous functions and/or esters of general formula (1) wherein: R1 and R2, and R4 and R5, R3 and R6 are hydrogen or alkyl radicals, and x is selected among the amine salts and N-alkylpolyalkylenepolyamines and their monohydroxylated and polyhydroxylated derivatives, N-alkylpolyalkylenepolyamine alkylesters and esters, and alkylamines and N-alkylpolyalkylenepolyamines.Type: GrantFiled: February 4, 2008Date of Patent: January 24, 2012Assignee: Elf Antar FranceInventors: Frank G Eydoux, Philippe Pu. F. Flores, Dominique Vichard, Laurent Germanaud
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Publication number: 20110302827Abstract: An effective stress corrosion cracking (SCC) inhibiting amount of a corrosion inhibitor is added into a blend of fuel and ethanol that contacts a metal, wherein the corrosion inhibitor is an organic acid selected from citric acid, ascorbic acid, succinic acid, pyruvic acid, maleic acid, oxaloacetic acid, oxalosuccinic acid, ketoglutaric acid, isocitric acid, malic acid, aconitic acid, fumaric acid, isomers of these organic acids, and a combination thereof. For example, the corrosion inhibitors inhibit stress corrosion cracking of pipeline grade metal pipe at ethanol concentrations greater than fifteen percent. In one embodiment, the corrosion inhibitor is added into a blend of fuel and ethanol flowing through a pipeline at a plurality of injection points spaced apart along the length of the pipeline. In one option, the corrosion inhibitor is ammoniated to form the ammonium salt of the organic acid.Type: ApplicationFiled: June 15, 2011Publication date: December 15, 2011Applicant: CHAMPION TECHNOLOGIES, INC.Inventors: Tracey Jackson, Russell Strong
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Patent number: 7645305Abstract: Improved highly stable formulation for aqueous fuel emulsion compositions with a water continuous phase, having reduced NOx emissions. The fuel emulsion formulation includes diesel fuel, purified water, and an additive package that includes one or more surfactants, lubricity additive, cetane improver, anti-corrosion additive, and an alcohol or other suitable antifreeze, the emulsion having an average droplet size of less than 10 microns.Type: GrantFiled: July 1, 1998Date of Patent: January 12, 2010Assignee: Clean Fuels Technology, Inc.Inventors: Gerald N. Coleman, Dennis L. Endicott, Edward A. Jakush
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Patent number: 7604672Abstract: The present invention relates to the field of fuel additives for hydrocarbon fuels that acts to enhance efficiency and/or reduce pollution. The fuel additive is a phosphorus-containing composition that can be dispersed in hydrocarbon fuels or liquid carriers for combustion with the fuel in a combustion zone.Type: GrantFiled: June 23, 2004Date of Patent: October 20, 2009Assignee: EnviroFuels, LLCInventors: Dwight Morrell Smith, Abdul R. Chughtai, James Dadura, James Dadura, Jr., legal representative
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Patent number: 7597725Abstract: An additive composition for a fuel oil composition and that is free of polycyclic carboxylic acids and of acid derivatives thereof comprises an additive that comprises one or more monocarboxylic acids, each having from 10 to 24 carbon atoms, or acid derivatives thereof, optionally in combination with one or both of an anti-oxidant additive and an anti-static additive.Type: GrantFiled: September 30, 2003Date of Patent: October 6, 2009Assignee: Infineum International Ltd.Inventors: Rinaldo Caprotti, Carlo S. Fava, Graham Jackson, Iain More
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Patent number: 7550019Abstract: The invention therefore provides an additive for improving the cold flow performance of middle distillates, comprising I) at least one paraffin dispersant which is a derivative of a fatty amine, II) at least one block copolymer of the structure (AB)nA or (AB)m, where A represents blocks which are composed of olefinically unsaturated, aromatic monomers, and B represents blocks which are composed of structural elements based on polyolefins and are capable of cocrystallizing with the paraffins precipitating out of the middle distillate in the course of cooling, and n is a number in the range from 1 to 10 and m is a number in the range from 2 to 10.Type: GrantFiled: July 21, 2004Date of Patent: June 23, 2009Assignee: Clariant Produkte (Deutschland) GmbHInventors: Matthias Krull, Heinz Hoffmann, Klaus Redlich
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Publication number: 20080289247Abstract: A novel method to prepare high-enthalpy biofuels has been developed based on a new chemical pattern which has never been used before in the synthesis of renewable fuels. These biofuels are based on natural oleaginous feedstock, rendering low viscosity liquids with broad liquid range and enthalpy levels much superior to those found in common biodiesel, meaning ethyl or methyl fatty esters. As in the case of biodiesel, these new biofuels contain zero sulfur, causing none of the major pollution associated with commercial diesel. High enthalpy biofuels are aliphatic nitrile compounds, containing a single nitrogen substituent, are chemically aprotic, even though their high degree of polarity is reflected in its high cetane index and solubility parameter. The present invention includes fuels associated with diesel, as well as other high-enthalpy fractions, which according to their boiling point, correspond to naphtha in the lower scale, and bunker in the upper scale.Type: ApplicationFiled: July 11, 2007Publication date: November 27, 2008Applicant: Rlo Oeste, S.A.Inventor: Nicholas M. Irving
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Patent number: 7435272Abstract: A friction modifier for combustible fuels is provided that is prepared by combining a saturated carboxylic acid and an alkoxylated amine or etheramine. Furthermore, there also is an additive concentrate for use in fuels, especially in gasoline for internal combustion engines, comprising (a) a friction modifier comprising of a branched saturated carboxylic acid salt of an alkoxylated amine, such as isohexyloxypropylamine isostearate; (b) a detergent package, as well as the combustible fuels containing this additive concentrate. The particular selection of friction modifier (a) enables a stable additive concentrate to be formulated providing a significant benefit in friction loss when incorporated in gasoline used to fuel an internal combustion engine, and hence an improvement in fuel economy.Type: GrantFiled: April 22, 2003Date of Patent: October 14, 2008Assignee: Afton Chemical IntangiblesInventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab, William J. Colucci
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Patent number: 7402185Abstract: A method for reducing the formation of combustion chamber deposits in an engine using a friction modifier for combustible fuels is provided. The friction modifier is prepared by combining a saturated carboxylic acid and an alkylated or alkoxylated amine. The particular selection of friction modifier enables a stable additive concentrate to be formulated providing a significant decrease in CCD without increasing the incidence of IVD deposits in combustion engines running on a fuel modified with the additive concentrate.Type: GrantFiled: March 26, 2003Date of Patent: July 22, 2008Assignee: Afton Chemical Intangibles, LLCInventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab, William J. Colucci
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Patent number: 7377949Abstract: An additive for middle distillates with a maximum sulfur content of 0.05 percent by weight, comprising at least one fatty acid ester of alkoxylated polyols with at least 3 OH groups (A) and at least one alkylphenol-aldehyde resin (C).Type: GrantFiled: November 2, 2002Date of Patent: May 27, 2008Assignee: Clariant Produkte (Deutschland) GmbHInventors: Matthias Krull, Martina Hess
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Patent number: 7374589Abstract: The invention concerns a fuel for diesel engines, with a sulphur content of less than 500 ppm containing in a major proportion at least one average distillate from a straight-run distilling cup of crude oil, with temperature ranges between 150 and 400° C. and in a minor proportion a lubricating additive containing monocarboxylic and polycyclic acids.Type: GrantFiled: May 29, 2003Date of Patent: May 20, 2008Assignee: Elf Antar FranceInventors: Christian Bernasconi, Laurent Germanaud, Jean-Michel Laupie, Paul Maldonado
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Patent number: 7326262Abstract: The invention concerns a multifunctional additive enabling fuels to be operable in cold conditions, consisting of copolymers of at least a dicarboxylic compound with at least an olefin, and whereon are grafted nitrogenous functions and/or esters of general formula (I) wherein: R1 and R2, and R4 and R5, R3 and R6 are hydrogen or alkyl radicals, and x is selected among the amine salts and N-alkylpolyalkylenepolyamines and their monohydroxylated and polyhydroxylated derivatives, N-alkylpolyalkylenepolyamine alkylesters and esters, and alkylamines and N-alkylpolyalkylenepolyamines.Type: GrantFiled: December 27, 2000Date of Patent: February 5, 2008Assignee: Elf Antar FranceInventors: Frank Eydoux, Philippe Flores, Dominique Vichard, Laurent Germanaud
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Patent number: 6946008Abstract: The present invention relates to an additive composition for a combustible fuel to produce improved combustion and reduced exhaust pollution of the combusted fuel, which additive composition comprises: a) one or more water-soluble alcohols having between 1 and 5 carbon atoms, in an anhydrous state or as a 0.5-36% aqueous solution, and one or more of the following: b) one or more straight- or branched-chain alcohols having between 6-18 carbon atoms; c) one or more ethoxylated alcohols having between 12 and 18 carbon atoms where the ethylene oxide add-on is less than 5 moles; d) a fatty acid of the structure R—(C?O)—OH having from 10 to 24 carbon atoms with e) a source of nitrogen in an anhydrous state or as an aqueous solution; wherein components a) to e), when combined with mixing with said combustible fuel, form a clear, stable microemulsion having a viscosity similar to the liquid fossil fuel. Combustion is improved and pollutant and particulate levels are reduced.Type: GrantFiled: December 19, 2001Date of Patent: September 20, 2005Assignee: Saga Fuel Systems, Inc.Inventor: Deborah Wenzel
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Patent number: 6884271Abstract: The present invention relates to an additive composition for a combustible fuel to produce improved combustion and reduced exhaust pollution of the combusted fuel, which additive composition comprises: a) one or more water-soluble alcohols having between 1 and 5 carbon atoms, in an anhydrous state or as a 0.5-36% aqueous solution, and one or more of the following: b) one or more straight- or branched- chain alcohols having between 6-18 carbon atoms; c) one or more ethoxylated alcohols having between 12 and 18 carbon atoms where the ethylene oxide add-on is less than 5 moles; d) a fatty acid of the structure R—(C?O)—OH having from 10 to 24 carbon atoms with e) a source of nitrogen in an anhydrous state or as an aqueous solution; wherein components a) to e), when combined with mixing with said combustible fuel, form a clear, stable microemulsion having a viscosity similar to the liquid fossil fuel. Combustion is improved and pollutant and particulate levels are reduced.Type: GrantFiled: February 19, 2002Date of Patent: April 26, 2005Assignee: Saga Fuel Systems, Inc.Inventor: Deborah Wenzel
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Patent number: 6866690Abstract: A friction modifier for combustible fuels is provided that is prepared by combining a saturated carboxylic acid and an alkylated amine. Furthermore, there also is an additive concentrate for use in fuels, especially in gasoline for internal combustion engines, comprising (a) a friction modifier comprising of a branched saturated carboxylic acid salt of an alkylated amine, such as n-butylamine isostearate; (b) a detergent package, as well as the combustible fuels containing this additive concentrate. The particular selection of friction modifier (a) enables a stable additive concentrate to be formulated providing a significant benefit in friction loss when incorporated in gasoline used to fuel an internal combustion engine, and hence an improvement in fuel economy.Type: GrantFiled: April 24, 2002Date of Patent: March 15, 2005Assignee: Ethyl CorporationInventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab
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Patent number: 6858046Abstract: This invention relates to an emulsified water-blended fuel composition comprising: (A) a hydrocarbon boiling in the gasoline or diesel range; (B) water; (C) a minor emulsifying amount of at least one fuel-soluble salt made by reacting (C)(I) at least one acylating agent having about 16 to 500 carbon atoms with (C)(II) ammonia and/or at least one amine; and (D) about 0.001 to about 15% by weight of the water-blended fuel composition of a water soluble, ashless, halogen-, boron-, and phosphorus-free, amine salt, distinct from component (C). In one embodiment, the composition further comprises (E) at least one cosurfactant distinct from component (C); in one embodiment, (F) at least one organic cetane improver; and in one embodiment, (G) at least one antifreeze. The invention also relates to a method for fueling an internal combustion engine comprising fueling said engine with the composition of the present invention.Type: GrantFiled: February 5, 2002Date of Patent: February 22, 2005Assignee: The Lubrizol CorporationInventors: Daniel T. Daly, John J. Mullay, Elizabeth A. Schiferl
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Publication number: 20040255511Abstract: The invention relates to middle distillates having a maximal sulphur content of 0.05 wt. %, which contain fatty acid esters of alkoxylated polyols with at least 3 OH groups (A) and at least one cold-fluidity improving additive (B), whereby said cold-fluidity improving additive contains at least one copolymer of ethylene and one or several ethylenically unsaturated carboxylic acid esters, said copolymer having an ethylene portion of 60 to 90 mole %.Type: ApplicationFiled: May 12, 2004Publication date: December 23, 2004Inventors: Matthias Krull, Martina Hess
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Publication number: 20040250467Abstract: Aviation fuel, such as jet fuel, blends and methods for improving cold flow properties of such fuels at extremely low temperatures are disclosed. Cold flow properties of, for example, JP-8+100 jet fuel, are improved by addition to the fuel of a polymer formed from polymerization of an &agr;-olefin monomer or monomers. Demonstratable cold flow improvement of such fuels at temperatures of about −53° C. and lower is shown.Type: ApplicationFiled: June 12, 2003Publication date: December 16, 2004Applicant: General Electric CompanyInventors: Fang Deng, William S. Carey, Sherif Eldin, Alan E. Goliaszewski
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Patent number: 6793696Abstract: Disclosed is a fuel oil composition comprising a middle distillate having a sulfur content of up to 0.05% by weight and reaction products of A) mono- or dicarboxylic acids of 6 to 50 carbon atoms and B) primary, secondary or tertiary amines of the formula NR1R2R3 where R1 is branched alkyl of 3 to 18 carbon atoms and R2 and R3 are independently hydrogen, R1 or alkyl of 1-12 carbon atoms.Type: GrantFiled: November 9, 2001Date of Patent: September 21, 2004Assignee: Clariant GmbHInventors: Matthias Krull, Markus Kupetz
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Patent number: 6786940Abstract: The mixture contains (a) from 5 to 95% by weight of at least one reaction product of a poly(C2-20-carboxylic acid) having at least one tertiary amino group with secondary amines and (b) from 5 to 95% by weight of at least one reaction product of maleic anhydride and a primary alkylamine.Type: GrantFiled: April 23, 2001Date of Patent: September 7, 2004Assignee: BASF AktiengesellschaftInventors: Bernd Wenderoth, Dieter Hermeling
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Patent number: 6780209Abstract: The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second intermeType: GrantFiled: January 24, 2000Date of Patent: August 24, 2004Assignee: The Lubrizol CorporationInventors: Brian B. Filippini, Richard M. Lange, Bryan A. Grisso, Bryn Hird
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Publication number: 20040093790Abstract: Fuel compositions comprising a major amount of a normally liquid fuel and a minor amount of a hydroxylamine or a salt thereof, more often wherein each hydroxylamino group of the hydroxylamine or salt thereof contains no more than one tertiary alkyl substituent. The hydroxylamine or salt thereof provide improved combustion properties to a wide variety of normally liquid fuels, including hydrocarbon based fuels, oxygenates and synthetic fuels.Type: ApplicationFiled: August 22, 2003Publication date: May 20, 2004Inventors: Mark R. Baker, Douglas M. Barr, Daniel T. Daly
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Publication number: 20040020106Abstract: Jet fuel compositions having good low temperature operability.Type: ApplicationFiled: April 7, 2003Publication date: February 5, 2004Inventors: Robert D. Tack, Graham Jackson, Phillip Armitage
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Publication number: 20040010966Abstract: A method for reducing the formation of combustion chamber deposits in an engine using a friction modifier for combustible fuels is provided. The friction modifier is prepared by combining a saturated carboxylic acid and an alkylated or alkoxylated amine. The particular selection of friction modifier enables a stable additive concentrate to be formulated providing a significant decrease in CCD without increasing the incidence of IVD deposits in combustion engines running on a fuel modified with the additive concentrate.Type: ApplicationFiled: March 26, 2003Publication date: January 22, 2004Inventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab, William J. Colucci
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Publication number: 20040010967Abstract: A friction modifier for combustible fuels is provided that is prepared by combining a saturated carboxylic acid and an alkoxylated amine or etheramine. Furthermore, there also is an additive concentrate for use in fuels, especially in gasoline for internal combustion engines, comprising (a) a friction modifier comprising of a branched saturated carboxylic acid salt of an alkoxylated amine, such as isohexyloxypropylamine isostearate; (b) a detergent package, as well as the combustible fuels containing this additive concentrate. The particular selection of friction modifier (a) enables a stable additive concentrate to be formulated providing a significant benefit in friction loss when incorporated in gasoline used to fuel an internal combustion engine, and hence an improvement in fuel economy.Type: ApplicationFiled: April 22, 2003Publication date: January 22, 2004Inventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab, William J. Colucci
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Patent number: 6648929Abstract: This invention relates to an emulsified water-blended fuel composition comprising: (A) a hydrocarbon boiling in the gasoline or diesel range; (B) water; (C) a minor emulsifying amount of at least one fuel-soluble salt made by reacting (C)(I) at least one acylating agent having about 16 to 500 carbon atoms with (C)(II) ammonia and/or at least one amine; and (D) about 0.001 to about 15% by weight of the water-blended fuel composition of a water soluble, ashless, halogen-, boron-, and phosphorus-free, amine salt, distinct from component (C). In one embodiment, the composition further comprises (E) at least one cosurfactant distinct from component (C); in one embodiment, (F) at least one organic cetane improver; and in one embodiment, (G) at least one antifreeze. The invention also relates to a method for fueling an internal combustion engine comprising fueling said engine with the composition of the present invention.Type: GrantFiled: September 14, 1998Date of Patent: November 18, 2003Assignee: The Lubrizol CorporationInventors: Daniel T. Daly, John J. Mullay, Elizabeth A. Schiferl
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Publication number: 20030200697Abstract: A friction modifier for combustible fuels is provided that is prepared by combining a saturated carboxylic acid and an alkylated amine. Furthermore, there also is an additive concentrate for use in fuels, especially in gasoline for internal combustion engines, comprising (a) a friction modifier comprising of a branched saturated carboxylic acid salt of an alkylated amine, such as n-butylamine isostearate; (b) a detergent package, as well as the combustible fuels containing this additive concentrate. The particular selection of friction modifier (a) enables a stable additive concentrate to be formulated providing a significant benefit in friction loss when incorporated in gasoline used to fuel an internal combustion engine, and hence an improvement in fuel economy.Type: ApplicationFiled: April 24, 2002Publication date: October 30, 2003Inventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab
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Publication number: 20030154650Abstract: This invention relates to a fuel composition comprising (i) a low sulphur fuel having a sulphur content of less than 30 ppm, a bromine number of less than 10 and an ultraviolet absorbance at 319 nm is below 0.15 and (ii) an effective amount of an ashless friction reducing additive which is a fatty acid having 10-30 carbon atoms or a derivative thereof. The fuel of the specified characteristics shown improved response to the friction reducing additive in respect of its lubricity performance.Type: ApplicationFiled: November 15, 2002Publication date: August 21, 2003Inventors: Robert Howie Barbour, Gideon Freeman, Alan Mark Schilowitz
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Publication number: 20020129541Abstract: This invention relates to an emulsified water-blended fuel composition comprising: (A) a hydrocarbon boiling in the gasoline or diesel range; (B) water; (C) a minor emulsifying amount of at least one fuel-soluble salt made by reacting (C)(I) at least one acylating agent having about 16 to 500 carbon atoms with (C)(II) ammonia and/or at least one amine; and (D) about 0.001 to about 15% by weight of the water-blended fuel composition of a water soluble, ashless, halogen-, boron-, and phosphorus-free, amine salt, distinct from component (C). In one embodiment, the composition further comprises (E) at least one cosurfactant distinct from component (C); in one embodiment, (F) at least one organic cetane improver; and in one embodiment, (G) at least one antifreeze. The invention also relates to a method for fueling an internal combustion engine comprising fueling said engine with the composition of the present invention.Type: ApplicationFiled: February 5, 2002Publication date: September 19, 2002Inventors: Daniel T. Daly, John J. Mullay, Elizabeth A. Schiferl
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Publication number: 20020088167Abstract: An emulsified water-blended fuel composition comprising:Type: ApplicationFiled: October 22, 2001Publication date: July 11, 2002Applicant: The Lubrizol CorporationInventors: Brian B. Filippini, William R. Sweet, Thomas F. Steckel, John J. Mullay, James C. Ray
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Patent number: 6348074Abstract: The present invention relates to an additive composition for a combustible fuel to utilize readily available and renewable resources and to produce improved combustion and reduced smoke and particulate production of the combusted fuel, which additive composition comprises: a. ethanol, in an anhydrous state or as a 0.5-36% aqueous solution, optionally with alcohols having between about 3 and 5 carbon atoms, and one or more of the following: b. one or more alcohols selected from the group consisting of clear, liquid saturated or unsaturated, straight- or branched-chain alcohols having from between about 6 and 12 carbon atoms, optionally with alcohols having between about 13-18 carbon atoms, orone or more alcohols selected from the group consisting of ethoxylated straight- or branched-long-chain alcohols having between about 13 and 18 carbon atoms, where the ethylene oxide add-on is less than 5 moles; c.Type: GrantFiled: January 11, 1999Date of Patent: February 19, 2002Assignee: SAGA Fuel Systems, Inc.Inventor: Deborah Wenzel
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Publication number: 20010015030Abstract: The present invention relates to an additive composition for a combustible fuel to utilize readily available and renewable resources and to produce improved combustion and reduced smoke and particulate production of the combusted fuel, which additive composition comprises:Type: ApplicationFiled: January 11, 1999Publication date: August 23, 2001Inventor: DEBORAH WENZEL
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Patent number: 6277158Abstract: An additive concentrate for use in fuels, especially in gasoline for internal combustion engines, comprising (a) 0.2 to 10 wt. % ashless friction modifier which is liquid at room temperature and pressure selected from (i) n-butylamine oleate or derivatives thereof, (ii) a substance comprising tall oil fatty acid or derivatives thereof, and (iii) mixtures of (i) and (ii); (b) 10 to 80 wt. % deposit inhibitor, and (c) carrier fluid. The particular selection of friction modifier (a) enables a stable additive concentrate to be formulated without the need for additional solubilising agent for the friction modifier, while containing sufficient friction modifier to achieve a significant benefit in fri loss, when incorporated in gasoline used to fuel an internal combustion engine, and hence an improvement in fuel economy.Type: GrantFiled: July 18, 2000Date of Patent: August 21, 2001Assignee: Exxon Research and Engineering CompanyInventor: Gail McLean
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Patent number: 6277159Abstract: Specific substituted aromatic amine salt compounds are useful as lubricity additives for middle distillate fuel oils.Type: GrantFiled: July 15, 1999Date of Patent: August 21, 2001Assignee: Exxon Chemical Patents INCInventors: Rinaldo Caprotti, Christophe Le Deore
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Patent number: 6270538Abstract: Oils having improved low temperature properties and additives for use therein.Type: GrantFiled: May 21, 1999Date of Patent: August 7, 2001Assignee: Exxon Chemical Patents INCInventors: Christophe Ledeore, Graham Jackson, Robert Dryden Tack, Iain More
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Patent number: 6051039Abstract: This invention relates to a diesel fuel composition containing an additive composition made by admixing at least two components: A) at least one dicarboxylic acid having about 8 to about 500 carbon atoms or a reactive equivalent thereof; and B) at least one amine having about 6 to about 80 carbon atoms. In one embodiment, the additive composition also contains: C) at least one monocarboxylic acid of about 8 to about 28 carbon atoms or a reactive equivalent thereof. The additive composition is useful as a lubricity additive for diesel fuel, especially low sulfur diesel fuel and provide excellent storage stability, rust-inhibiting and anti-wear performance to diesel fuel.Type: GrantFiled: September 14, 1998Date of Patent: April 18, 2000Assignee: The Lubrizol CorporationInventor: Shigeru Sugimoto
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Patent number: 5998530Abstract: Improving the flowability of mineral oils and mineral oil distillates using alkylphenol-aldehyde resinsThe invention relates to a process for improving the flowability of paraffin-containing mineral oils and mineral oil distillates by adding flow improvers based on ethylene/vinyl ester co- and terpolymers, alkylphenol-aldehyde resins and, if appropriate, other paraffin dispersants, mixtures of these different flow improvers and mineral oils and mineral oil distillates which comprise these flow improvers.Type: GrantFiled: January 5, 1998Date of Patent: December 7, 1999Assignee: Clariant GmbHInventors: Matthias Krull, Michael Feustel, Werner Reimann, Ulrike Tepper
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Patent number: 5968211Abstract: The present invention is a gasoline additive concentrate which remains liquid at low temperatures of about 0.degree. F. which contains a fatty acid, ester or mixtures thereof in combination with an alcohol, an amine or a mixture thereof.Type: GrantFiled: May 26, 1998Date of Patent: October 19, 1999Assignee: Exxon Research and Engineering Co.Inventor: Alan M. Schilowitz
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Patent number: 5827805Abstract: Compositions represented by the structures ##STR1## where Ar represents an aromatic group, each R is independently a hydrocarbyl group, at least one R having more than 12 carbon atoms, a is 1 to 4, and R' is hydrogen or alkyl, are useful as lubricant and fuel additives and as intermediates for the preparation of derivatives useful as such additives.Type: GrantFiled: February 29, 1996Date of Patent: October 27, 1998Assignee: The Lubrizol CorporationInventors: Paul E. Adams, Bryan A. Grisso, Mark R. Baker
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Patent number: 5755834Abstract: The invention is directed to a method of enhancing the low temperature flow properties of fuels comprising adding to the fuel a heated additive concentrate comprising: (A) at least one nitrogen-containing derivative of carboxylic acid, (B) an organic acid, and (C) at least one other flow improver, wherein the concentrate is heated to at least about 35.degree. C.Type: GrantFiled: November 21, 1996Date of Patent: May 26, 1998Assignee: Exxon Chemical Patents Inc.Inventor: John E. Chandler
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Patent number: 5733346Abstract: Oil-soluble polar nitrogen components are used in combination with fuel oil antifoams to control foaming in fuel oils.Type: GrantFiled: January 10, 1997Date of Patent: March 31, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Brian William Davies, Alessandro Lombardi, Rinaldo Caprotti