Nitrogen Or Chalcogen Attached Indirectly To The -c(=o)o- Group By Nonionic Bonding Patents (Class 44/410)
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Patent number: 12031098Abstract: The present invention relates to a method of marking a petroleum hydrocarbon by adding to and uniformly mixing with said petroleum hydrocarbon a chemical marker of general formula (I) wherein two of the residues R1-R10 are independently of each other selected from C1-C4-alkoxy, and eight of the residues R1-R10 are independently of each other selected from the group consisting of hydrogen and C1-C4-alkyl, as well as to a composition of a petroleum hydrocarbon comprising a petroleum hydrocarbon and at least one chemical marker of general formula (I). The presence and concentration of the chemical marker of general formula (I) in the composition of the petroleum hydrocarbon can be advantageously determined by laser ionization coupled with mass spectrometry or by laser ionization coupled with ion mobility spectrometry.Type: GrantFiled: November 26, 2020Date of Patent: July 9, 2024Assignee: SICPA HOLDING SAInventors: Martin Zühlke, Daniel Riebe, Toralf Beitz, Thomas Tiller, Juan Lopez Gejo, Ünige Laskay
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Patent number: 10941362Abstract: A clean, high efficient and environmentally friendly gasoline product with main fractions of C6-C11 has a low octane rating and a low spontaneous ignition temperature. It can be compressively ignited within an internal combustion engine with a compression ratio of 16-19. Small amount of ethanol or dimethyl ether can be added into the gasoline product.Type: GrantFiled: June 10, 2011Date of Patent: March 9, 2021Inventor: Xiangjin Zhou
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Patent number: 10100265Abstract: A lubricating oil composition for internal combustion engines containing a base oil mixture with specific properties and a monoglyceride with a specific structure. The lubricating oil composition of the present 5 invention, as well as providing outstanding wear resistance and fuel economy, causes condensed water etc. from water vapor produced as a result of fuel combustion to be dispersed in the oil, so preventing corrosion or rusting of the engine.Type: GrantFiled: July 29, 2013Date of Patent: October 16, 2018Assignee: SHELL OIL COMPANYInventors: Kiyoshi Hanyuda, Kouji Murakami, Izumi Kobayashi, Kouichi Kubo
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Publication number: 20140173973Abstract: A liquid fuel composition containing (a) a diesel base fuel suitable for use in an internal combustion engine; and (b) one or more organic sunscreen compounds. The liquid fuel composition of the present invention provides benefits in terms of power output of a diesel engine, and modifying the ignition delay and/or modifying the burn period and/or increasing the cetane number of the liquid fuel composition.Type: ApplicationFiled: December 19, 2013Publication date: June 26, 2014Applicant: SHELL OIL COMPANYInventor: Mark Lawrence BREWER
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Publication number: 20140173972Abstract: A liquid fuel composition containing (a) a gasoline base fuel suitable for use in an internal combustion engine; and (b) one or more organic sunscreen compounds. The liquid fuel composition of the present invention provides benefits in terms of improved acceleration and/or power output of an internal combustion engine fuelled by said fuel as well as an increase in flame speed.Type: ApplicationFiled: December 19, 2013Publication date: June 26, 2014Applicant: SHELL OIL COMPANYInventors: Mark Lawrence BREWER, Michael William HOWE
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Patent number: 8668749Abstract: A diesel fuel additive composition, a fuel containing the fuel additive, a method for improving diesel engine performance using the additive. The diesel fuel additive includes a reaction product of (a) a hydrocarbyl-substituted acylating agent and (b) a reactant selected from the group consisting of a nitrogen-containing compound, a hydroxyl-containing compound, and water that provides a reaction product selected from the group consisting (1) a mono-amide/mono-acid or metal free mono-acid salt thereof, (2) a diacid or metal free diacid salt thereof, and (3) mono-ester/mono-acid or metal free mono-acid salt thereof. The reaction product includes at least about 10 molar percent acid groups based on total moles of the reaction product.Type: GrantFiled: November 3, 2010Date of Patent: March 11, 2014Assignee: Afton Chemical CorporationInventor: Xinggao Fang
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Patent number: 8535399Abstract: The present invention is related to the use of hydroxyalkanoic acid derivatives as a fuel additive. In particular, the present invention provides the use of lower alkyl esters and/or salts of hydroxyalkanoic acid as biofuels and/or fuel additives. The present invention also provides a fuel composition including at least one fuel and lower alkyl esters and/or salts of hydroxyalkanoic acid.Type: GrantFiled: May 26, 2009Date of Patent: September 17, 2013Assignee: Shandong Lukang Pharmaceutical Co., Ltd.Inventors: Guoqiang Chen, Rongcong Luo
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Patent number: 8100988Abstract: The invention concerns a multifunctional additive enabling fuels to be operable in cold conditions, consisting of copolymers of at least a dicarboxylic compound with at least an olefin, and whereon are grafted nitrogenous functions and/or esters of general formula (1) wherein: R1 and R2, and R4 and R5, R3 and R6 are hydrogen or alkyl radicals, and x is selected among the amine salts and N-alkylpolyalkylenepolyamines and their monohydroxylated and polyhydroxylated derivatives, N-alkylpolyalkylenepolyamine alkylesters and esters, and alkylamines and N-alkylpolyalkylenepolyamines.Type: GrantFiled: February 4, 2008Date of Patent: January 24, 2012Assignee: Elf Antar FranceInventors: Frank G Eydoux, Philippe Pu. F. Flores, Dominique Vichard, Laurent Germanaud
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Publication number: 20120010112Abstract: The present invention relates to novel acid-free quaternized nitrogen compounds, to the preparation thereof and to the use thereof as a fuel and lubricant additive, more particularly as a detergent additive, as a wax antisettling additive (WASA) or as an additive for reducing internal diesel injector deposits (IDID); to additive packages which comprise these compounds; and to fuels and lubricants thus additized. The present invention further relates to the use of these acid-free quaternized nitrogen compounds as a fuel additive for reducing or preventing deposits in the injection systems of direct-injection diesel engines, especially in common-rail injection systems, for reducing the fuel consumption of direct-injection diesel engines, especially of diesel engines with common-rail injection systems, and for minimizing power loss in direct-injection diesel engines, especially in diesel engines with common-rail injection systems.Type: ApplicationFiled: July 6, 2011Publication date: January 12, 2012Applicant: BASF SEInventors: Wolfgang Grabarse, Harald Böhnke, Christian Tock, Cornelia Röger-Göpfert, Ludwig Völkel
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Patent number: 8038740Abstract: The present invention relates to the use of at least one hydrophobin or of a derivative thereof as a defoamer in additive compositions or fuels, to a process for defoaming fuels, to an additive and fuel composition comprising at least one hydrophobin or derivative thereof and at least one further fuel additive, and to a process for preparing at least one fuel composition.Type: GrantFiled: October 9, 2006Date of Patent: October 18, 2011Assignee: BASF SEInventors: Thomas Subkowski, Hans-Georg Lemaire, Marvin Karos, Susan Hammer, Joern Karl, Dietmar Posselt
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Publication number: 20110082062Abstract: Lubricating oil used for the lubrication of engines run on biodiesel fuels are improved in their resistance to oxidation by the addition to said to lubricating oil of particular detergents, and premixed mixtures of particular detergents and anti-oxidants.Type: ApplicationFiled: September 28, 2010Publication date: April 7, 2011Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Jacob J. Habeeb, Ramesh Varadaraj, Steven M. Jetter
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Publication number: 20110067294Abstract: Disclosed are biodiesel fuels with improved oxidative stability. Disclosed are biodiesel fuels which comprise two or more antioxidants which increase the oxidative stability of the biodiesel fuel.Type: ApplicationFiled: February 26, 2009Publication date: March 24, 2011Inventors: K.Y. Simon Ng, Haiying Tang, Steven O. Salley
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Publication number: 20110056123Abstract: A method of making cerium dioxide nanoparticles includes: a) providing an aqueous reaction mixture having a source of cerous ion, a source of hydroxide ion, a nanoparticle stabilizer, and an oxidant at an initial temperature no higher than about 20° C.; b) mechanically shearing the mixture and causing it to pass through a perforated screen, thereby forming a suspension of cerium hydroxide nanoparticles; and c) raising the initial temperature to achieve oxidation of cerous ion to eerie ion and thereby form cerium dioxide nanoparticles having a mean diameter in the range of about 1 nm to about 15 nm. The cerium dioxide nanoparticles may be formed in a continuous process.Type: ApplicationFiled: September 4, 2007Publication date: March 10, 2011Applicant: CERION TECHNOLOGY, INC.Inventors: Albert Gary Difrancesco, Richard K. Hailstone, Andreas Langner, Kenneth J. Reed
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Publication number: 20110034357Abstract: To provide a novel composition useful as lubricant composition or the like. It is disclosed a composition comprising an oily medium and at least one compound represented by following formula (Z). A-L-{D1-(E)q-D2-(B)m—Z1—R}p??(Z) A represents a p-valent chain or cyclic residue; L represents a single bond or a divalent linking group; p represents an integer of 2 or more; D1 represents a carbonyl group (—C(?O)—) or a sulfonyl group (—S(?O)2—); D2 represents a carbonyl group (—C(?O)—), a sulfonyl group (—S(?O)2—), a carboxyl group (—C(?O)O—), a sulfonyloxyl group (—S(?O)2O—), a carbamoyl group (—C(?O)N(Alk) or a sulfamoyl group (—S(?O)2N(Alk)-); E represents a divalent group; R represents a hydrogen atom, a substituted or non-substituted C8 or longer alkyl group, a perfluoroalkyl group or a trialkylsilyl group; B represents an oxyethylene group or the like; and Z1 represents a single bond or a divalent group.Type: ApplicationFiled: March 27, 2009Publication date: February 10, 2011Inventors: Ken Kawata, Saisuke Watanabe
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Publication number: 20100107484Abstract: The present invention provides a fuel additive concentrate comprising a detergent, antioxidant; and a friction modifier selected from the group consisting of an alkoxylated fatty amine, a fatty acid or derivative thereof, and mixture thereof. Additionally, the present invention further provides for a fuel composition comprising a fuel, which is a liquid at room temperature; and additive, wherein the additive is selected from the group consisting of: a detergent; antioxidant; friction modifier selected from the group consisting of an alkoxylated fatty amine, a fatty acid or derivative thereof, and mixture thereof; and mixtures thereof.Type: ApplicationFiled: March 19, 2008Publication date: May 6, 2010Applicant: The Lubrizol CorporationInventor: Jonathan S. Vilardo
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Publication number: 20100024287Abstract: The present invention provides a liquid fuel composition comprising: a) a base fuel suitable for use in an internal combustion engine; and b) one or more poly(hydroxycarboxylic acid) derivative having a terminal acid group having formula (III): [Y—CO[O-A-CO]n-Zp]m-X??(III) wherein Y is hydrogen or optionally substituted hydrocarbyl group, A is a divalent optionally substituted hydrocarbyl group, n is from 1 to 100, m is 1 or 2, Z is an optionally substituted divalent bridging group, p is 0 or 1, and X is terminal acid group or a group carrying a terminal acid group, wherein the terminal acid group is selected from carboxylic acid, carboxymethyl, sulphate, sulphonate, phosphate and phosphonate.Type: ApplicationFiled: July 29, 2009Publication date: February 4, 2010Inventors: Susan Jane SMITH, Mark Clift SOUTHBY, Nigel Peter TAIT
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Patent number: 7435272Abstract: A friction modifier for combustible fuels is provided that is prepared by combining a saturated carboxylic acid and an alkoxylated amine or etheramine. Furthermore, there also is an additive concentrate for use in fuels, especially in gasoline for internal combustion engines, comprising (a) a friction modifier comprising of a branched saturated carboxylic acid salt of an alkoxylated amine, such as isohexyloxypropylamine isostearate; (b) a detergent package, as well as the combustible fuels containing this additive concentrate. The particular selection of friction modifier (a) enables a stable additive concentrate to be formulated providing a significant benefit in friction loss when incorporated in gasoline used to fuel an internal combustion engine, and hence an improvement in fuel economy.Type: GrantFiled: April 22, 2003Date of Patent: October 14, 2008Assignee: Afton Chemical IntangiblesInventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab, William J. Colucci
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Patent number: 7351268Abstract: There is described a fuel composition incorporating levulinic acid or a functional derivative thereof.Type: GrantFiled: May 13, 2002Date of Patent: April 1, 2008Assignee: AAE Technologies International PLCInventors: Alan Rae, William Hodgson
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Patent number: 7323019Abstract: An additive for low-sulfur mineral oil distillates having improved cold flowability and paraffin dispersancy, comprising at least one ester of an alkoxylated polyol and at least one polar nitrogen-containing paraffin dispersant.Type: GrantFiled: November 2, 2002Date of Patent: January 29, 2008Assignee: Clariant Produkte (Deutschland) GmbHInventors: Matthias Krull, Martina Hess
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Patent number: 6402797Abstract: This invention provides a fuel oil composition comprising a major amount of a fuel oil and a minor amount of an additive comprising at least one fuel oil-soluble alkyl or alkoxy aromatic compound wherein at last one group independently selected from alkyl and alkoxy groups of 1 to 30 carbon atoms is attached to an aromatic nucleus and at least one carboxyl group and optionally one or two hydroxyl groups are attached to the aromatic nucleus; a process for the preparation of such a fuel oil composition; and the use of such a fuel oil composition as fuel in a compression-ignition engine for controlling wear rate in the fuel injection system thereof.Type: GrantFiled: July 28, 1999Date of Patent: June 11, 2002Assignee: Shell Oil CompanyInventors: Jian Lin, Struan Douglas Robertson
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Patent number: 6270538Abstract: Oils having improved low temperature properties and additives for use therein.Type: GrantFiled: May 21, 1999Date of Patent: August 7, 2001Assignee: Exxon Chemical Patents INCInventors: Christophe Ledeore, Graham Jackson, Robert Dryden Tack, Iain More
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Patent number: 6210452Abstract: Highly effective fuel additives that control the formation of deposits in internal combustion engines, particularly, in the fuel injection system and combustion chamber of such engines. The fuel additives comprise carboxylic acid alkoxylates, and are particular suited for use with nitrogen-containing fuel detergents. Fuel compositions comprising the fuel additives, and methods of controlling engine deposits are also disclosed.Type: GrantFiled: February 8, 2000Date of Patent: April 3, 2001Assignee: Hhntsman Petrochemical CorporationInventor: Wei-Yang Su
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Patent number: 6053955Abstract: The present invention relates to polyether amino acid ester compounds, preparation method and their use as hydrocarbon fuel additives.Type: GrantFiled: September 25, 1998Date of Patent: April 25, 2000Assignee: SK CorporationInventors: Byung Hyung Lee, Woo Sun Kim, Sang Chul Lim, Ho Young Kwon, Dae Joon Yang
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Patent number: 5998530Abstract: Improving the flowability of mineral oils and mineral oil distillates using alkylphenol-aldehyde resinsThe invention relates to a process for improving the flowability of paraffin-containing mineral oils and mineral oil distillates by adding flow improvers based on ethylene/vinyl ester co- and terpolymers, alkylphenol-aldehyde resins and, if appropriate, other paraffin dispersants, mixtures of these different flow improvers and mineral oils and mineral oil distillates which comprise these flow improvers.Type: GrantFiled: January 5, 1998Date of Patent: December 7, 1999Assignee: Clariant GmbHInventors: Matthias Krull, Michael Feustel, Werner Reimann, Ulrike Tepper
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Patent number: 5997592Abstract: This invention provides a fuel oil composition comprising a major amount of a fuel oil and a minor amount of an additive comprising at least one fuel oil-soluble alkyl or alkoxy aromatic compound wherein at least one group independently selected from alkyl and alkoxy groups of 1 to 30 carbon atoms is attached to an aromatic nucleus and at least one carboxyl group and optionally one or two hydroxyl groups are attached to the aromatic nucleus; a process for the preparation of such a fuel oil composition; and the use of such a fuel oil composition as fuel in a compression-ignition engine for controlling wear rate in the fuel injection system thereof.Type: GrantFiled: July 11, 1997Date of Patent: December 7, 1999Assignee: Shell Oil CompanyInventors: Jian Lin, Struan Douglas Robertson
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Patent number: 5830244Abstract: A fuel additive having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are independently hydrogen or lower alkyl; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl and each R.sub.3 and R.sub.4 is independently selected in each --O--CHR.sub.3 --CHR.sub.4 -- unit; R.sub.5 is hydrogen, alkyl having 1 to 100 carbon atoms, phenyl, aralkyl having 7 to 100 carbon atoms or alkaryl having 7 to 100 carbon atoms, or an acyl group of the formula: ##STR2## where R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, aralkyl having 7 to 36 carbon atoms or alkaryl having 7 to 36 carbon atoms; n is an integer from 5 to 100; and x is an integer from 0 to 10.Type: GrantFiled: December 30, 1996Date of Patent: November 3, 1998Assignee: Chevron Chemical CompanyInventor: Richard E. Cherpeck
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Patent number: 5827805Abstract: Compositions represented by the structures ##STR1## where Ar represents an aromatic group, each R is independently a hydrocarbyl group, at least one R having more than 12 carbon atoms, a is 1 to 4, and R' is hydrogen or alkyl, are useful as lubricant and fuel additives and as intermediates for the preparation of derivatives useful as such additives.Type: GrantFiled: February 29, 1996Date of Patent: October 27, 1998Assignee: The Lubrizol CorporationInventors: Paul E. Adams, Bryan A. Grisso, Mark R. Baker
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Patent number: 5733346Abstract: Oil-soluble polar nitrogen components are used in combination with fuel oil antifoams to control foaming in fuel oils.Type: GrantFiled: January 10, 1997Date of Patent: March 31, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Brian William Davies, Alessandro Lombardi, Rinaldo Caprotti
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Patent number: 5688751Abstract: Two-stroke cycle engines can be effectively lubricated by supplying to the engine a mixture of an oil of lubricating viscosity and a hydrocarbyl-substituted hydroxyaromatic carboxylic acid or an ester, unsubstituted amide, hydrocarbyl-substituted amide, ammonium salt, hydrocarbylamine salt, or monovalent metal salt thereof in an amount suitable to reduce piston deposits in said engine. The mixture supplied to the engine contains less than 0.06 percent by weight of divalent metals.Type: GrantFiled: August 14, 1996Date of Patent: November 18, 1997Assignee: The Lubrizol CorporationInventors: William K. S. Cleveland, Jack L. Karn, Daniel M. Vargo
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Patent number: 5667539Abstract: Compounds of the formula I below are useful as additives in oleaginous compositions: ##STR1## wherein B represents an aromatic system, A represents a hydrocarbyl group, R.sup.1 and R.sup.2 are the same or are different and each independently is an aliphatic hydrocarbyl group containing 10-40 carbon atoms, provided that one of R.sup.1 and R.sup.2 may represent hydrogen; z is at least 1 and wherein the aromatic system carries at least one substituent group which is an activating group for the ring system or a derivative of an activating group.Type: GrantFiled: August 7, 1996Date of Patent: September 16, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Graham Jackson, Rachel Evelyn Mary Kenward, Barbara Catherine Brooke
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Patent number: 5468263Abstract: The present invention relates to an alkylphenyl poly(oxyalkylene) polyamine acid ester fuel detergent effective for controlling deposit generated in an automobile engine, prepared by reacting polyamine and alkylphenyl poly(oxyalkylene) maleate derivative prepared by reaction of alkylphenyl poly(oxyalkylene) alcohol and maleic anhydride, through Michael reaction. A fuel detergent diluted solution comprising 5-70 wt % of said fuel detergent and an inert organic solvent, and a hydrocarbon fuel composition comprising thereof are prepared. The present invention does not use deadly toxic phosgene gas used in preparation of a deposit control additive for conventional polyether amine deposit control additive and prevents generation of amine salt to eliminate the process for removing amine salt.Type: GrantFiled: February 18, 1994Date of Patent: November 21, 1995Assignee: Yukong LimitedInventors: Hyun-jong Chung, Sang-chul Yim, Bon-chul Ku, Ho-young Guen, Duk-han Kim
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Patent number: 5441544Abstract: A fuel additive having the formula: ##STR1## where A.sub.1 is a thioether, a sulfoxide, a sulfone, a sulfonic acid, a sulfonamide, a nitrile, a carboxylic acid or ester, or a carboxamide; R.sub.1 and R.sub.2 are independently hydrogen, hydroxy, lower alkyl, or lower alkoxy; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl and each R.sub.3 and R.sub.4 is independently selected in each --O--CHR.sub.3 --CHR.sub.4 -- unit; R.sub.5 is hydrogen, alkyl having 1 to 100 carbon atoms, phenyl, aralkyl having 7 to 100 carbon atoms or alkaryl having 7 to 100 carbon atoms, or an acyl group of the formula: ##STR2## where R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, aralkyl having 7 to 36 carbon atoms or alkaryl having 7 to 36 carbon atoms; n is an integer from 5 to 100; and x is an integer from 0 to 10.Type: GrantFiled: December 23, 1993Date of Patent: August 15, 1995Assignee: Chevron Chemical CompanyInventor: Richard E. Cherpeck
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Patent number: 5380345Abstract: Polyalkyl nitro and amino aromatic esters having the formula: ##STR1## wherein A.sub.1 is nitro, amino, N-alkylamino wherein the alkyl group contains 1 to 6 carbon atoms, or N,N-dialkylamino wherein each alkyl group independently contains 1 to 6 carbon atoms; R.sub.1 and R.sub.2 are independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 is a polyalkyl group having a weight average molecular weight in the range of about 450 to 5,000; and x is an integer from 0 to 10.The polyalkyl nitro and amino aromatic esters of formula I are useful as fuel additives for the prevention and control of engine deposits.Type: GrantFiled: December 3, 1993Date of Patent: January 10, 1995Assignee: Chevron Research and Technology CompanyInventor: Richard E. Cherpeck
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Patent number: 5281346Abstract: This invention relates to lubricants for two-cycle engines comprising a major amount of at least one oil of lubricating viscosity and a minor amount of at least one compound of the general formulaA.sup.y- M.sup.y+ (I)wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each anion containing group is a group of the formula ##STR1## wherein T is selected from the group consisting of ##STR2## Additive concentrates and lubricant-fuel mixtures for two cycle engines are also disclosed as well as methods for operating two-cycle engines.Type: GrantFiled: April 16, 1992Date of Patent: January 25, 1994Assignee: The Lubrizol CorporationInventors: Paul E. Adams, William K. S. Cleveland
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Patent number: 5114436Abstract: This invention relates to processes and compositions for stabilizing distillate fuel oil which comprises adding to the distillate fuel oil an effective stabilizing amount of a mixture of (a) a phosphite compound having the formula ##STR1## wherein R, R' and R" are the same or different and are alkyl, aryl, alkaryl or aralkyl groups, and (b) an effective carboxylic acid having from 2 to about 20 carbon atoms, wherein the weight ratio of (a):(b) is from about 1:5 to aboug 1000:1.Type: GrantFiled: April 20, 1987Date of Patent: May 19, 1992Assignee: Betz Laboratories, Inc.Inventor: Dwight K. Reid
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Patent number: 5100438Abstract: Coal-water slurries containing a rheological additive are provided. Rheological additives employed for preparation of the coal-water slurries are ester-amide products obtained by reaction of a polycarboxylic acid with a polyether glycol and aliphatic amine. Salts of the ester-amides may also be advantageously employed as dispersants. The ester-amide additives are employed in an amount from about 0.1 to about 4 percent by weight of the slurry. Stable aqueous slurries containing from 60 to 80 percent by weight coal solids are produced.Type: GrantFiled: July 26, 1988Date of Patent: March 31, 1992Assignee: Henkel CorporationInventors: William S. Kain, Donald D. Staker