Nitro Or Nitroso Bonded Directly To Carbon Patents (Class 44/413)
  • Publication number: 20150113859
    Abstract: The use of a polyalkylene glycol of formula HO—(A—O)p—(CH2CH2—O)m—(A—O)q—H wherein A is a C3- to C20-alkylene group or a mixture of such alkylene groups, m is a number of from 2 to 100 and p and q are each numbers of from 1 to 100, as an additive in a fuel for reducing fuel consumption in the operation of an internal combustion engine with this fuel.
    Type: Application
    Filed: October 24, 2013
    Publication date: April 30, 2015
    Applicant: BASF SE
    Inventors: Ludwig VOELKEL, Markus HANSCH, Thomas HAYDEN, Marc WALTER, Nawid KASHANI-SHIRAZI, Thomas WEISS
  • Patent number: 8920524
    Abstract: Disclosed are polyisobutenyl alcohols and substituted polyisobuentyl alcohols of the formula: wherein n is an integer from 5 to 90, R is selected from the group consisting of hydrogen, haloalkyl, alkoxycarbonyl and substituted aryl wherein at least one substituent group of the substituted aryl is selected from cyano, nitro and alkoxycarbonyl.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: December 30, 2014
    Assignee: Chevron Oronite Company LLC
    Inventors: Richard E. Cherpeck, Ruth Smocha
  • Patent number: 8894727
    Abstract: The present invention discloses a fuel composition useful for internal combustion engine having an Octane Number from 95 to 105 comprising: (a) an unleaded and devoid of organometal compounds base gasoline having an Octane Number (RON) from 90.1 to 103: (b) one or more aromatic amines selected in the group consisting of: (b1) 2,4-dialkylaniline, wherein the alkyl groups in position 2 and 4, independently one from the other, are selected in the group consisting of methyl, ethyl, n-propyl, iso-propyl, preferably both the alkyl groups in position 2 and 4 are methyl; (b2) N-Nitrosodiphenylamine. The process for preparing the above composition is also described along with the use of the aromatic amines selected between (b1) and (b2) and related mixtures for increasing the Octane Number.
    Type: Grant
    Filed: November 22, 2010
    Date of Patent: November 25, 2014
    Assignee: Chimec S.p.A.
    Inventors: Alessandra Berra, Marco Buccolini, Gennaro Ferrante
  • Patent number: 8709110
    Abstract: The present invention relates to a composition comprising a) a substance selected from the group of astaxanthinmonoalkanoylesters, astaxanthindialkanoylesters, isozeaxanthin, isozeaxanthinmonoalkanoylesters, isozeaxanthindialkanoylesters and mixtures thereof; and b) a substance selected from the group of alkyl nitrates, nitrooxy esters of alkoxy substituted aliphatic alcohols and organic peroxides; as well as to a change in oxidation reactions of hydrocarbons, especially fuels, admixed to these compositions. The invention also relates to a composition comprising a) a compound selected from the group consisting of astaxanthinmonoalkanoylesters, astaxanthindialkanoylesters, iso-zeaxanthin, iso-zeaxanthinmonoalkanoylesters, iso-zeaxanthindialkanoylesters and mixtures thereof; and c) a fuel.
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: April 29, 2014
    Assignee: DSM IP Assets B.V.
    Inventors: Max Hugentobler, Steffen Ruf, Bettina Wuestenberg
  • Patent number: 8603200
    Abstract: The present disclosure relates to a gasoline combustion improver comprising an organic nitro compound with C—NO2 bond dissociation energy of about 60 to about 80 Kcal/mol of compound, wherein the organic nitro compound is selected from the group consisting of nitro-aromatics, heteroatom aromatic ring compounds, heteroatom nonaromatic ring compounds, and nitrated furfuryls, and wherein the organic nitro compound is not nitrotoluene or dinitrotoluene.
    Type: Grant
    Filed: June 22, 2009
    Date of Patent: December 10, 2013
    Assignee: Afton Chemical Corporation
    Inventors: Allen A. Aradi, Joseph W. Roos
  • Patent number: 8529643
    Abstract: A method for cleaning internal components of a fuel injector for a diesel engine. The method includes operating a fuel injected diesel engine on a fuel composition comprising a major amount of fuel and from about 10 to about 100 ppm by weight based on the total weight of the fuel composition of (A) a compound of the formula: and tautomers and enantiomers thereof, wherein R2 is a hydrocarbyl group having a number average molecular weight ranging from 100 to 5000.
    Type: Grant
    Filed: April 19, 2012
    Date of Patent: September 10, 2013
    Assignee: Afton Chemical Corporation
    Inventors: Julienne M. Galante-Fox, Scott D. Schwab, Xinggao Fang
  • Publication number: 20130184341
    Abstract: A biocidal composition comprising 2,2-dibromomalonamide and an electrophile containing biocide, and its use for the control of microorganisms in aqueous and water-containing systems.
    Type: Application
    Filed: September 30, 2010
    Publication date: July 18, 2013
    Applicant: DOW GLOBAL TECHNOLOGIES INC.
    Inventors: Bei Yin, Freddie L. Singleton
  • Publication number: 20130125452
    Abstract: An amine mixture includes a polyisobuteneamine and an aliphatic amine. The amine mixture is obtained by reductive amination of a mixture with ammonia or an amine HNR2R3. The mixture can be a mixture of the oxo process product formed in the hydroformylation of polybutene or polyisobutene and an alkanol R4—OH. The mixture can also be a mixture of the epoxide formed in the epoxidation of polybutene or polyisobutene and an alkanol R4—OH. Or, instead, the mixture can be a mixture of the nitro compound formed in the reaction of polybutene or polyisobutene with nitrogen oxides and an alkanol R4—OH. The amine mixture is suitable for cleaning and keeping clean intake valves and injection nozzles in gasoline engines.
    Type: Application
    Filed: November 19, 2012
    Publication date: May 23, 2013
    Inventors: Harald SCHWAHN, Marc Walter
  • Publication number: 20130019522
    Abstract: The invention provides fuel mixtures containing fuel oil, glycerol, glycerol impurities and non-ionic surfactants. The mixtures remain homogeneous longer and are more chemically stable than previous mixtures. Upon combustion, the mixtures generate reduced SOx, NOx and particulate matter emissions compared to residual fuels and offer improved engine performance over previous mixtures.
    Type: Application
    Filed: January 24, 2012
    Publication date: January 24, 2013
    Applicant: SeaChange Group, LLC
    Inventors: Scott Eaton, George Harakas
  • Patent number: 8317887
    Abstract: Mixture to be employed specifically as an agent for adding an odour to a gaseous combustible fuel such as natural gas, consisting of: at least one alkyl acrylate (I) of which the alkyl radicals contain from one to 12 carbon atoms; at least on compound of formula (II) in a quantity sufficient to inhibit the polymerization of the alkyl acrylate or acrylates(I) in the presence and/or absence of oxygen.
    Type: Grant
    Filed: June 25, 2007
    Date of Patent: November 27, 2012
    Assignee: Arkema France
    Inventor: Patrick Charles
  • Publication number: 20120279112
    Abstract: The present invention discloses a fuel composition useful for internal combustion engine having an Octane Number from 95 to 105 comprising: (a) an unleaded and devoid of organometal compounds base gasoline having an Octane Number (RON) from 90.1 to 103: (b) one or more aromatic amines selected in the group consisting of: (b1) 2,4-dialkylaniline, wherein the alkyl groups in position 2 and 4, independently one from the other, are selected in the group consisting of methyl, ethyl, n-propyl, iso-propyl, preferably both the alkyl groups in position 2 and 4 are methyl; (b2) N-Nitrosodiphenylamine. The process for preparing the above composition is also described along with the use of the aromatic amines selected between (b1) and (b2) and related mixtures for increasing the Octane Number.
    Type: Application
    Filed: November 22, 2010
    Publication date: November 8, 2012
    Applicant: CHIMEC S.P.A.
    Inventors: Alessandra Berra, Marco Buccolini, Gennaro Ferrante
  • Patent number: 8192511
    Abstract: A method of burning fuel in a combustion chamber whereby reducing overall carbon emissions, comprising: feeding an oxidizing component and a combustible component to a combustion chamber in a ratio based on zero oxygen balance principle, wherein the oxidizing component has an oxygen balance value of more than zero, and the combustible component has an oxygen balance value of less than zero. The method of burning fuel can reduce overall carbon emissions, even to zero.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: June 5, 2012
    Inventor: Pichang Wei
  • Patent number: 8137419
    Abstract: The invention concerns a composition for use in particular as odorant of a gas fuel, more particularly of natural gas, comprising: 0.1 to 49.9 particles by weight of at least one alkyl sulphur (I) of formula: R1—S—R2, wherein R1 and R2, identical or different, represent: an alkyl radical comprising 1 to 4 carbon atom; or R1 and R2 together with the sulfur atom to which they are bound represent a saturated or unsaturated ring including 3 to 5 carbon atoms, optionally substituted by a C1-C4 alkyl or C1-C4 alkenyl; 50 to 99.8 parts by weight of at least two alkyl acrylates (II) the alkyl radicals of which comprise 1 to 12 carbon atoms, preferably 1 to 8: 0.001 parts by weight of at least compound (III) inhibiting polymerization of the alkyl acrylates (II).
    Type: Grant
    Filed: October 10, 2006
    Date of Patent: March 20, 2012
    Assignee: Arkema France
    Inventor: Patrick Charles
  • Publication number: 20120055080
    Abstract: Compositions containing phenolic antioxidant solutions are provided. The invention further provides methods of making and using such compositions as well as compositions that contain both biodiesel and at least one antioxidant concentrate solutions and blended fuel compositions containing biodiesel blended with other fuels.
    Type: Application
    Filed: November 10, 2011
    Publication date: March 8, 2012
    Applicant: Eastman Chemical Company
    Inventors: Thomas Edward Carter, Joy Lynn Laningham, Phillip Montgomery Hudnall, Sharon Metcalf Cline
  • Publication number: 20110290997
    Abstract: A method for marking a petroleum hydrocarbon, biodiesel fuel or ethanol fuel by adding to the petroleum hydrocarbon, biodiesel fuel or ethanol fuel at least one compound having formula (I) wherein R1 and R2 independently represent at least one substituent selected from the group consisting of hydrogen, C1-C12 alkyl, C1-C12 alkoxy and nitro; and R3 and R4 independently represent hydrogen, methyl or ethyl.
    Type: Application
    Filed: May 23, 2011
    Publication date: December 1, 2011
    Inventors: George David Green, Raymond John Swedo
  • Patent number: 7938867
    Abstract: A fuel composition contains (a) a medium substantially free of to free of sulphur; (b) a detergent/dispersant additive; and (c) a liquid fuel where the medium substantially free of to free of sulphur is an aliphatic hydrocarbon solvent, and where the aliphatic hydrocarbon solvent is present from at least about 50 wt % to about 100 wt % of the total amount of the medium. The fuel composition is prepared by a process and is useful in a process, where the fuel composition includes a medium that is a hydrocarbon or a nonhydrocarbon or a mixture thereof, to increase the efficiency of an exhaust after-treatment device of an internal combustion engine.
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: May 10, 2011
    Assignee: The Lubrizol Corporation
    Inventors: David L. Spivey, Robert H. Barbour, William B. Chamberlin, III, John K. Pudelski
  • Publication number: 20110041387
    Abstract: Provided are additives of formula I for use in hydrocarbonaceous compositions, such as petroleum or liquid fuels: (I) wherein R1, R2, R3, R4, and R5 are as defined herein. The additives improve the corrosion resistance of the compositions. The additives also enhance the antimicrobial efficacy of any added biocides contained in such compositions.
    Type: Application
    Filed: April 29, 2009
    Publication date: February 24, 2011
    Inventors: G. David Green, Sheila M. Tinetti, Patrick E. Brutto, John Pohlman
  • Publication number: 20100319243
    Abstract: The present disclosure relates to a gasoline combustion improver comprising an organic nitro compound with C—NO2 bond dissociation energy of about 60 to about 80 Kcal/mol of compound, wherein the organic nitro compound is selected from the group consisting of nitro-aromatics, heteroatom aromatic ring compounds, heteroatom nonaromatic ring compounds, and nitrated furfuryls, and wherein the organic nitro compound is not nitrotoluene or dinitrotoluene.
    Type: Application
    Filed: June 22, 2009
    Publication date: December 23, 2010
    Applicant: Afton Chemical Corporation
    Inventors: Allen A. ARADI, Joseph W. Roos
  • Patent number: 7491249
    Abstract: An improved fuel additive formulation, method of use, and method of producing the fuel formulation are described. The improved fuel additive of the present invention comprises a mixture of nitroparaffins (comprising nitromethane, nitroethane, and nitropropane), and a combination of modified commercially available ester oil and/or a solubilizing agent, and/or toluene. The ratio of ester oil and/or solubilizing agent and/or toluence to nitroparaffin is preferably less than 20 volume percent, with nitroparaffins comprising the balance of the additive. A method of preparing and using the additive formulation is also provided.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: February 17, 2009
    Assignee: Mazoil Technologies, Ltd.
    Inventors: Arthur R. Foote, Michael Lakin, Peter Wachtel, Albert Schrage
  • Publication number: 20080236031
    Abstract: A fuel composition is provided that contains a major amount of a mixture of hydrocarbons in the gasoline boiling range and a minor amount of a certain aniline additive compound. Use of such aniline additive compound in a combustion engine is also provided.
    Type: Application
    Filed: December 12, 2007
    Publication date: October 2, 2008
    Inventors: Raymond Edward PAGGI, Joseph Michael Russo, Timothy Michael Shea
  • Patent number: 7335238
    Abstract: The present invention relates to the manufacture of ferrous picrate and the preparation of fuel additives containing ferrous picrate. A process for producing ferrous picrate includes dissolving picric acid in a mixture of an aromatic hydrocarbon and an aliphatic alcohol in the presence of a trace amount of water and a metallic iron, thus forming a ferrous picrate solution. The ferrous picrate solution is blended with an organic solvent to form the fuel additive. Ferrous picrate produced by the product is also described.
    Type: Grant
    Filed: July 27, 2004
    Date of Patent: February 26, 2008
    Assignee: RDI Construction
    Inventor: Alan F. Elliott
  • Patent number: 7118605
    Abstract: The present invention relates to a fuel conditioning process for internal combustion engines of motor vehicles. According to the present invention, on board a motor vehicle at a temperature of from 20° C. to 150° C. and at atmospheric pressure, nitrous gases essentially including nitrogen monoxide, nitrogen dioxide, or dinitrogen monoxide, or gaseous mixtures thereof are passed through the liquid fuel of the motor vehicle, nitro compounds being formed in the fuel as a result of the passing through of the nitrous gases through the fuel.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: October 10, 2006
    Assignee: DaimlerChrysler AG
    Inventors: Winfried Degen, Erwin Loeffler, Carsten Plog, Melanie Schnell, Thomas Stengel
  • Publication number: 20040148849
    Abstract: An improved fuel additive formulation, method of use, and method of producing the fuel formulation are described. The improved fuel additive of the present invention comprises a mixture of nitroparaffins (comprising nitromethane, nitroethane, and nitropropane), and a combination of modified commercially available ester oil and/or a solubilizing agent, and/or toluene. The ratio of ester oil and/or solubilizing agent and/or toluence to nitroparaffin is preferably less than 20 volume percent, with nitroparaffins comprising the balance of the additive. A method of preparing and using the additive formulation is also provided.
    Type: Application
    Filed: May 27, 2003
    Publication date: August 5, 2004
    Inventors: Arthur R. Foote, Michael Lakin, Peter Wachtel, Albert Schrage
  • Publication number: 20040088910
    Abstract: The invention is directed to a monopropellant composition for propulsion and/or gas generation, comprising a solution of hydrazinium nitroformate (HNF) and/or ammonium dinitramide (ADN) in water and/or an alkanol.
    Type: Application
    Filed: September 29, 2003
    Publication date: May 13, 2004
    Inventors: Ronald Peter Van Den Berg, Petrus Johannes Maria Elands, Johannes Maria Mul
  • Patent number: 6660050
    Abstract: A method for controlling the deposits in the fuel vaporizer of a fuel reformer used to prepare a liquid hydrocarbon for use as a fuel in a fuel cell which comprises introducing into the fuel vaporizer a liquid hydrocarbon containing an effective deposit controlling amount of a nitrogen-containing detergent additive and a fuel composition suitable for use in a fuel cell which comprises a liquid hydrocarbon having a boiling range at atmospheric pressure falling between about 77 degrees F. (25 degrees C.) and about 437 degrees F. (225 degrees C.), a total sulfur content of less than 3 ppm, and containing an effective deposit controlling amount of a nitrogen-containing detergent additive.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: December 9, 2003
    Assignee: Chevron U.S.A. Inc.
    Inventors: Gunther H. Dieckmann, James D. Kramer, Richard E. Cherpeck
  • Publication number: 20030213167
    Abstract: A process for producing ferrous picrate and a fuel additive containing ferrous picrate involving placing wire composed of an alloy of iron in any solution of picric acid in a solvent that is known in the art for reacting with iron to produce ferrous picrate. The wire can be suspended in the solution or placed upon the bottom of a reaction vessel that holds the solution. Preferably the wire is loosely coiled, at least when placed upon the bottom of a reaction vessel. Also preferably, after a concentrated fuel additive has been prepared, to the concentrate is added so much of a pre-mix solution produced by the steps of (a) dissolving picric acid in the same kind of solvent that was utilized to produce the solution into which the steel wool was placed and (b) removing water from the precursor to the pre-mix solution thus produced and so much of the same kind of alcohol that was utilized to produce the solution into which the steel wool was placed that the final product produced thereby contains approximately 1.
    Type: Application
    Filed: May 16, 2002
    Publication date: November 20, 2003
    Inventor: David M. Stewart
  • Publication number: 20030159335
    Abstract: An emergency fuel for an internal combustion engine comprises a hydrocarbon solvent having a flash point of at least 100° F. (such as about 65-75% paraffins and about 25-35% naphthenes, or about 75-85% paraffins and about 15-25% of C7 or higher alcohols, or an aromatic solvent, or an naphthalene-depleted aromatic solvent) and a cold starting additive. The cold starting additive may be provided in an amount of less than 5,000 ppm, preferably between about 1 ppm and 150 ppm. The cold starting additive is preferably selected from peroxides, azo compounds, cyano compounds, cetane improvers, or combinations of these compounds. When the emergency fuel is added to a cold engine, including one substantially at room temperature, the engine may be easily started.
    Type: Application
    Filed: March 26, 2003
    Publication date: August 28, 2003
    Applicant: Burmah Castrol
    Inventors: Irwin L. Goldblatt, Richard G. Tittel
  • Publication number: 20030110684
    Abstract: The present invention relates to diesel fuel compositions that are extremely stable against thermal degradation, sedimentation, and discoloration. The diesel fuel compositions of the present invention are void or essentially void of certain heteroatomic compounds often present in diesel fuel and which have been discovered to cause the thermal degradation in the presence of nitrate-based cetane improver additives. The specific deleterious heteroatomic compounds include pyrroles, indoles, sulfides, disulfides, mercaptans, thioacids, sulfonic acids, and indolines.
    Type: Application
    Filed: December 18, 2001
    Publication date: June 19, 2003
    Inventor: Timothy J. Henly
  • Patent number: 6319294
    Abstract: An improved fuel additive formulation, method of use, and method of producing the fuel formulation are described. The improved fuel additive of the present invention comprises a mixture of nitroparaffins (comprising nitromethane, nitroethane, and nitropropane), and a combination of modified commercially available ester oil and toluene. The ratio of ester oil and toluene to nitroparaffin is preferably less than 20 volume percent, with nitroparaffins comprising the balance of the additive. A method of preparing and using the additive formulation is also provided.
    Type: Grant
    Filed: July 28, 2000
    Date of Patent: November 20, 2001
    Assignee: Magnum Environmental Technologies, Inc.
    Inventors: Arthur R. Foote, Michael Lakin
  • Patent number: 6117197
    Abstract: A fuel composition comprising a major amount of hydrocarbons boiling in the gasoline or diesel range and a fuel additive composition comprising (a) about 15 to 2,000 parts per million by weight of an aromatic ester of a polyalkylphenoxyalkanol, (b) about 30 to 2,000 parts per million by weight of a poly(oxyalkylene) amine, and (c) about 30 to 2,000 parts per million by weight of an aromatic di- or tri-carboxylic acid ester; wherein the total amount of components (a) and (b) is at least about 70 parts per million by weight, and further wherein the weight ratio of component (c) to the total amount of components (a) and (b) is at least about 0.25 to 1. The fuel compositions of this invention are useful for the prevention and control of engine deposits.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: September 12, 2000
    Assignee: Chevron Chemical Company LLC
    Inventor: Keith Robert Houser
  • Patent number: 6080213
    Abstract: A stabilized aqueous solution of a diazo compound has the formula: ##STR1## where X.sup.1 is selected from nitro and chloro, X.sup.2 is selected from nitro, chloro and hydrogen, and Y is an acid-derived anion. The solution has a pH of about 1.5 or below and a diazo concentration of about 2 wt % or less. The solution is useful as an extractant/developer for petroleum fuel markers.
    Type: Grant
    Filed: September 9, 1998
    Date of Patent: June 27, 2000
    Assignee: Morton International, Inc.
    Inventor: Al Zimin, Sr.
  • Patent number: 6004361
    Abstract: A low emission diesel fuel suitable for use in underground diesel-engined mining equipment comprises a straight run distillate fuel having an end point not greater than 300.degree. C. (about 660.degree. F.), a cetane number in the range of 55 to 60 a specific gravity not greater than 0.83 a sulfur content not greater than 0.1 wt percent and an aromatics content of 18 to 30 wt. percent. The T.sub.90 of the fuels is typically in the range of 255.degree. to 270.degree. C. (about 490.degree. F. to 525.degree. F.), with an initial boiling points typically in the range of 170.degree. to 190.degree. C. (about 340.degree. to 374.degree. F.). Ten percent points (T.sub.10) are typically in the range from about 200.degree. to 220.degree. C. (about 390.degree. to 430.degree. F.). The API gravity of the fuel is at least 38 and is typically in the range of 38 to 42 and the specific gravity is typically in the range of 0.82 to 0.83.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: December 21, 1999
    Assignee: Mobil Oil Corporation
    Inventors: Edward G. Barry, John N. Bennett, Dale B. Heck, Peter Heinze
  • Patent number: 5980594
    Abstract: Reaction products of polymers of C.sub.2 -C.sub.6 -olefins having an average degree of polymerization P of from 5 to 100 and oxides of nitrogen or mixtures of oxides of nitrogen and oxygen are used as additives for fuels, in particular for fuels for gasoline engines.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: November 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5976201
    Abstract: A low emission diesel fuel suitable for use in underground diesel-engined mining equipment comprises a straight run distillate fuel having an end point not greater than 300.degree. C. (about 660.degree. F.), a cetane number in the range of 55 to 60 a specific gravity not greater than 0.83 a sulfur content not greater than 0.1 wt percent and an aromatics content of 18 to 30 wt. percent. The T.sub.90 of the fuels is typically in the range of 255.degree. to 270.degree. C. (about 490.degree. F. to 525.degree. F.), with an initial boiling points typically in the range of 170.degree. to 190.degree. C. (about 340.degree. to 374.degree. F). Ten percent points (T.sub.10) are typically in the range from about 200.degree. to 220.degree. C. (about 390.degree. to 430.degree. F.). The API gravity of the fuel is at least 38 and is typically in the range of 38 to 42 and the specific gravity is typically in the range of 0.82 to 0.83.
    Type: Grant
    Filed: October 28, 1996
    Date of Patent: November 2, 1999
    Assignee: Mobil Oil Corporation
    Inventors: Edward G. Barry, John N. Bennett, Dale B. Heck, Peter Heinze
  • Patent number: 5879420
    Abstract: Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: March 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5849048
    Abstract: Substituted biphenyl poly(oxyalkylene) ethers having the formula: ##STR1## wherein R.sub.1 is hydrogen or hydroxyl; R.sub.2 is hydroxyl, cyano, nitro, amino, aminomethyl, N-alkylamino or N-alkylaminomethyl wherein the alkyl group contains 1 to about 6 carbon atoms, N,N-dialkylamino or N,N-dialkylaminomethyl wherein each alkyl group independently contains 1 to about 6 carbon atoms, with the proviso that R.sub.1 and R.sub.2 are ortho relative to each other and meta or para relative to the adjoining phenyl substitutent; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl having 1 to about 6 carbon atoms and each R.sub.3 and R.sub.4 is independently selected in each --OCHR.sub.3 --CHR.sub.4 -- unit; R.sub.5 is hydrogen, alkyl having 1 to about 100 carbon atoms, phenyl, aralkyl having about 7 to about 100 carbon atoms, alkaryl having about 7 to about 100 carbon atoms; or an acyl group having the formula: ##STR2## wherein R.sub.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: December 15, 1998
    Assignee: Chevron Chemical Company LLC
    Inventor: Richard E. Cherpeck
  • Patent number: 5827333
    Abstract: Substituted biphenyl polyalkyl ethers having the formula: ##STR1## wherein R.sub.1 is hydrogen or hydroxyl; R.sub.2 is hydroxyl, cyano, nitro, amino, aminomethyl, N-alkylamino or N-alkylaminomethyl wherein the alkyl group contains 1 to about 6 carbon atoms, N,N-dialkylamino or N,N-dialkylaminomethyl wherein each alkyl group independently contains 1 to about 6 carbon atoms, with the proviso that R.sub.1 and R.sub.2 are ortho relative to each other and meta or para relative to the adjoining phenyl substitutent; and R.sub.3 is a polyalkyl group having an average molecular weight in the range of about 450 to about 5,000.The subsitituted biphenyl polyalkyl ethers of the present invention are useful as fuel additives for the prevention and control of engine deposits.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: October 27, 1998
    Assignee: Chevron Chemical Company LLC
    Inventor: Richard E. Cherpeck
  • Patent number: 5782937
    Abstract: The present invention relates to fuel compositions containing hydrocarbon fuels in the gasoline boiling range and organic nitrogen-containing compounds selected from organic nitrates and/or organic nitro compounds. The fuel compositions exhibit improved ignition properties, including reduced emissions and reduced misfires.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: July 21, 1998
    Assignee: Ethyl Corporation
    Inventors: William J. Colucci, Isaac L. Smith, Allen A. Aradi
  • Patent number: 5709720
    Abstract: Aromatic ethers of polyalkylphenoxyalkanols having the formula: ##STR1## or a fuel soluble salt thereof, wherein R is hydroxy, nitro or --(CH.sub.2).sub.x -NR.sub.5 R.sub.6, wherein R.sub.5 and R.sub.6 are independently hydrogen or lower alkyl having 1 to carbon atoms, and x is 0 or 1;R.sub.1 is hydrogen, hydroxy, nitro or --NR.sub.7 R.sub.8, wherein R.sub.7 and R.sub.8 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms;R.sub.2 and R.sub.3 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; andR.sub.4 is a polyalkyl group having an average molecular weight in the range of about 450 to 5,000.The compounds of formula I are useful as fuel additives for the prevention and control of engine deposits.
    Type: Grant
    Filed: November 7, 1996
    Date of Patent: January 20, 1998
    Assignee: Chevron Chemical Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5667539
    Abstract: Compounds of the formula I below are useful as additives in oleaginous compositions: ##STR1## wherein B represents an aromatic system, A represents a hydrocarbyl group, R.sup.1 and R.sup.2 are the same or are different and each independently is an aliphatic hydrocarbyl group containing 10-40 carbon atoms, provided that one of R.sup.1 and R.sup.2 may represent hydrogen; z is at least 1 and wherein the aromatic system carries at least one substituent group which is an activating group for the ring system or a derivative of an activating group.
    Type: Grant
    Filed: August 7, 1996
    Date of Patent: September 16, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Graham Jackson, Rachel Evelyn Mary Kenward, Barbara Catherine Brooke
  • Patent number: 5637119
    Abstract: Substituted aromatic polyalkyl ethers having the formula: ##STR1## wherein R.sub.1 is a polyalkyl group having an average molecular weight of about 450 to about 5,000;A is nitro, amino, cyano, aminomethyl, N-alkylamino or N-alkylaminomethyl wherein the alkyl group contains from about 1 to about 6 carbon atoms, or N,N-dialkylamino or N,N-dialkylaminomethyl wherein each alkyl group independently contains from about 1 to about 6 carbon atomsx is an integer from about 0 to about 1; and y is an integer from about 0 to about 10 with the proviso that one of x and y must be 0 and the other must be greater than 0.The substituted aromatic polyalkyl ethers of the present invention are useful as fuel additives for the prevention and control of engine deposits.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: June 10, 1997
    Assignee: Chevron Chemical Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5578091
    Abstract: Compounds of general formula (I) wherein X and Y are the same or different and are selected from the group consisting of SO.sub.3 (--), --CO--, --C(O)O(--), --R.sup.4 --C(O)O--, --NR.sup.3 C(O)--, --R.sup.4 O--, --R.sup.4 --C(O)O--, --R.sup.4 -- and --NC(O)--, R.sup.4 being --(CH.sub.2).sub.m -- where m is from 0 to 5 and R.sup.3 is defined below; X.sup.1 and Y.sup.1 are the same or different and are selected from the group consisting of (a), R.sup.1 and R.sup.2 being independently selected from the group consisting of alkyl, alkoxy alkyl or polyalkoxyalkyl groups that contain at least 10 carbon atoms in their main chain, and R.sup.3 being a hydrocarbyl group, each R.sup.
    Type: Grant
    Filed: October 13, 1992
    Date of Patent: November 26, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Graham Jackson, Rodger F. Andrews
  • Patent number: 5409507
    Abstract: Fuel compositions containing a major amount of hydrocarbons boiling in the gasoline or diesel range and an effective deposit-controlling amount of a poly(oxyalkylene) aromatic ether having the formula: ##STR1## where A.sub.1 is nitro, amino, N-alkylamino wherein the alkyl group contains 1 to 6 carbon atoms, or N,N-dialkylamino wherein each alkyl group independently contains 1 to 6 carbon atoms; R.sub.1 and R.sub.2 are independently hydrogen, hydroxy, lower alkyl, or lower alkoxy; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl and each R.sub.3 and R.sub.4 is independently selected in each --O--CHR.sub.3 --CHR.sub.4 -- unit; R.sub.5 is hydrogen, alkyl having 1 to 100 carbon atoms, phenyl, aralkyl having 7 to 100 carbon atoms or alkaryl having 7 to 100 carbon atoms, or an acyl group of the formula: ##STR2## where R.sub.
    Type: Grant
    Filed: October 28, 1993
    Date of Patent: April 25, 1995
    Assignee: Chevron Chemical Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5087268
    Abstract: A process for producing an additive for hydrocarbon fuels by combining picric acid, powdered iron, an activating acid, and a liquid organic solvent. Alternatively, the powdered iron can first be washed with the activating acid and the rinsed with water or alcohol or water followed by alcohol; subsequently the washed and rinsed iron is combined with the picric acid and the liquid organic solvent. In the case of either alternative, hydroquinone can be added to the mixture in order to control undesired oxidation and corrosion, thereby further enhancing the stability of the additive.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: February 11, 1992
    Inventor: Walter W. Parish