Chalcogen Attached Indirectly To One Of The Nitrogens By Acyclic Nonionic Bonding Patents (Class 44/433)
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Patent number: 11396581Abstract: A demulsifier composition comprises an oxyalkylated polybenzoxazine having repeating units of Formula (I): wherein R1 is hydrogen, a C1-30 alkyl, a C3-30 cycloalkyl, a C6-30 aryl, a C7-30 alkylarylene, a C7-30 arylalkyl, a C5-30 heteroaryl, or a C3-30 heterocycloalkyl; R2 is a C1-30 alkyl, a C3-30 cycloalkyl, a C6-30 aryl, a C7-30 alkylarylene, a C7-30 arylalkyl, a C5-30 heteroaryl, or a C3-30 heterocycloalkyl; R3 is hydrogen or a C1-10 alkyl; each occurrence of R4 is independently hydrogen or a C1-5 alkyl; and p is at least 1.Type: GrantFiled: May 8, 2020Date of Patent: July 26, 2022Assignee: BAKER HUGHES OILFIELD OPERATIONS LLCInventor: Joey Dacula Mangadlao
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Patent number: 10738261Abstract: One or more fatty amines are soluble in a lubricating composition for preventing and/or reducing the metal losses of the parts of an engine, such as a marine engine. The parts are brought into contact with the lubricating composition in order to prevent or reduce the metal losses.Type: GrantFiled: August 3, 2016Date of Patent: August 11, 2020Assignee: TOTAL MARKETING SERVICESInventors: Valérie Doyen, Céline Chalancon
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Publication number: 20150113859Abstract: The use of a polyalkylene glycol of formula HO—(A—O)p—(CH2CH2—O)m—(A—O)q—H wherein A is a C3- to C20-alkylene group or a mixture of such alkylene groups, m is a number of from 2 to 100 and p and q are each numbers of from 1 to 100, as an additive in a fuel for reducing fuel consumption in the operation of an internal combustion engine with this fuel.Type: ApplicationFiled: October 24, 2013Publication date: April 30, 2015Applicant: BASF SEInventors: Ludwig VOELKEL, Markus HANSCH, Thomas HAYDEN, Marc WALTER, Nawid KASHANI-SHIRAZI, Thomas WEISS
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Patent number: 8864853Abstract: An additive mixture for fuels including a) at least one N-formal, b) at least one antioxidant and c) at least one corrosion inhibitor. The additive mixture ensures that the additized fuels and lubricants have biocidal and corrosion-inhibiting additization, especially when they include proportions of renewable raw materials, such as biodiesel, and when they are in contact with copper-containing surfaces.Type: GrantFiled: June 21, 2010Date of Patent: October 21, 2014Assignee: l'Air Liquide Societe Anonyme pour l'etude et L'exploitation des Procedes Georges ClaudeInventors: Wolfgang Beilfuss, Ralf Gradtke, Jennifer Knopf, Ingo Krull
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Publication number: 20130247450Abstract: A gasoline deposit control additive composition for use in a fuel comprising from about 70 to about 95 volume percent of hydrocarbons in the gasoline boiling range and from about 5 to about 30 volume percent of at least one alcohol, comprising the imine or tertiary amine product of the reaction between (a) at least one aldehyde or ketone or mixture thereof having the formula R16CHO, R16CH2CHO, R17(C=0)R18 or R17CH2(C=0)R18, wherein R16, R17, and R18 are the same or different and are each independently a straight or branched chain hydrocarbyl or aryl group that contains from 1 to 18 carbon atoms, and (b) a primary or secondary amine functionality.Type: ApplicationFiled: May 16, 2013Publication date: September 26, 2013Applicant: BUTAMAX ADVANCED BIOFUELS LLCInventor: Leslie R. Wolf
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Patent number: 8231695Abstract: The use of fuel compositions comprising selected hydrocarbon oils as carriers for detergents has been found to reduce deposit formation as well as prolong the functionality of fuel injectors. The selection and utilization of particularly characterized hydrocarbon oils as detergent carriers reduces intake valve deposits and combustion chamber deposits, in comparison to conventionally used carrier fluids.Type: GrantFiled: August 9, 2006Date of Patent: July 31, 2012Assignee: Afton Chemical CorporationInventors: Lawrence J. Cunningham, Beth A. Sloane, Dennis J. Malfer, May Duffield Thomas
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Publication number: 20100299992Abstract: The present invention relates to diesel fuel compositions comprising a performance enhancing additive, wherein the additive is the product of a Mannich reaction between: (a) an aldehyde; (b) a polyamine; and (c) an optionally substituted phenol; wherein the or each substituent of component (c) has an average molecular weight of less than 400.Type: ApplicationFiled: September 25, 2008Publication date: December 2, 2010Inventor: Jacqueline Reid
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Publication number: 20100281760Abstract: A diesel fuel composition comprising a performance enhancing additive, wherein the performance enhancing additive is the product of a Mannich reaction between: (a) an aldehyde; (b) a polyamine; and (c) an optionally substituted phenol; wherein the molar ratio of component (c) to component (b) in the reaction mixture used to prepare the performance enhancing additive is at least 1.5:1.Type: ApplicationFiled: September 25, 2008Publication date: November 11, 2010Applicant: INNOSPEC LIMITEDInventor: Jacqueline Reid
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Publication number: 20100236140Abstract: The present invention relates to novel fuel additives obtainable by reacting carboxylic acids and alkanol amines under specific conditions. Said additives show an improved performance in fuels, like gasoline. The invention also relates to methods of preparing the same; additive packages containing said additives; and methods of improving the storage stability of additive packages comprising a detergent additive in an organic solvent.Type: ApplicationFiled: October 17, 2008Publication date: September 23, 2010Applicant: BASF SEInventors: Ludwig Voelkel, Dietmar Posselt, Alfred Karl Jung, Markus Kummeter, Gero Nordmann, Andrea Misske
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Publication number: 20100154294Abstract: A fuel oil composition comprising a major amount of a fuel oil and a minor amount of a compound being the product of the reaction between (i) a primary or secondary hydrocarbyl-substituted amine or a mixture thereof and (ii) a species containing two or more epoxy groups being: a glycidyl ether (a) or (b), a glycidyl amine (c), a glycidyl ester (d) or a poly-epoxy alkane (e).Type: ApplicationFiled: December 4, 2009Publication date: June 24, 2010Inventor: Robert D. Tack
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Patent number: 7713315Abstract: The invention provides mineral oil distillates having a water content of less than 150 ppm and a conductivity of at least 50 pS/m, which comprise from 0.1 to 200 ppm of at least one alkylphenol-aldehyde resin and from 0.1 to 200 ppm of at least one nitrogen-containing polymer.Type: GrantFiled: July 28, 2006Date of Patent: May 11, 2010Assignee: Clariant Produkte (Deutschland) GmbHInventors: Matthias Krull, Werner Reimann
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Patent number: 7563291Abstract: The present invention relates to the preparation of ?-(dimethylisopropenylbenzylurethane) polyalkylene glycols with ?-alkoxy or ?-dihydroxy groups and to the use thereof as hydrolysis-stable macromonomers for the dispersion and crosslinking of polymers in which, A is C2-C4-alkylene, m is an integer from 5 to 900, and R is C1-C20-alkyl, C6-C18-aryl or a radical according to formula 2a, 2b, 2c, 3a, 3b or 3c which is bonded to the terminal oxygen atom of the alkoxy group (A-O) in formula 1 via the valence denoted by *, and in which A is not exclusively C3- or C4-alkylene.Type: GrantFiled: May 18, 2005Date of Patent: July 21, 2009Assignee: Clariant Produkte (Deutschland) GmbHInventors: Bettina Siggelkow, Dirk Leinweber, Werner Reimann, Ulrike Neuhaus, Renate Braun
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Patent number: 6909018Abstract: Polyalkeneamines of the formula (I) where R1, R2, R3, R4, R5 and R6 may have different meanings, are prepared by a process in which a polyalkene epoxide is reacted with an amine and the amino alcohol is dehydrated and reduced to give the compound of the formula (I).Type: GrantFiled: September 21, 2000Date of Patent: June 21, 2005Assignee: BASF AktiengesellschaftInventors: Johann-Peter Melder, Gerhard Blum, Wolfgang Günther, Dietmar Posselt, Knut Oppenländer
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Patent number: 6872230Abstract: The present invention relates to additives for enhancing the lubricity of hydrocarbon fuel oils, the inventive additive composition including one or more of the reaction products of (i) an alkylated polyamine and (ii) urea or isocyanate, or the salt adducts of these reaction products. More particularly, the present invention provides for a process for improving the lubricity of hydrocarbon fuel oils, which are low in inherent lubricity due to treatment to reduce sulfur and aromatic components for improved emissions.Type: GrantFiled: July 16, 2002Date of Patent: March 29, 2005Assignee: Betzdearborn, Inc.Inventors: Collin W. Cross, Zen-Yu Chang, S. Blake Pruett, Alan E. Goliaszewski
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Patent number: 6840970Abstract: The invention relates to fuel additive compositions for internal combustion engines and to fuels that contain the corresponding additives for internal combustion engines. The inventive fuel additive compositions for internal combustion engines have an excellent performance in keeping the inlet system clean and improved viscosity properties, especially at low temperatures.Type: GrantFiled: May 4, 2001Date of Patent: January 11, 2005Assignee: BASF AktiengesellschaftInventors: Harald Schwahn, Dietmar Posselt
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Patent number: 6736867Abstract: The present invention relates to emulsion compositions for starting a reformer of a fuel cell system. In particular, the invention includes emulsion compositions comprising hydrocarbon fuel, water and ethoxylated alkyl amine surfactants for starting a reformer of a fuel cell system.Type: GrantFiled: December 20, 2002Date of Patent: May 18, 2004Assignee: ExxonMobile Research and Engineering CompanyInventors: Ramesh Varadaraj, Paul Joseph Berlowitz
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Publication number: 20030177692Abstract: The present invention is directed to a method to clean up or keep clean the fuel system of a direct injection spark-ignited engine by operating the engine with a fuel composition that includes a liquid fuel and a fuel additive composition.Type: ApplicationFiled: March 12, 2002Publication date: September 25, 2003Applicant: The Lubrizol CorporationInventors: David C. Arters, Mitchell M. Jackson, Daniel T. Daly, Malcolm G.J. Macduff
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Publication number: 20030140552Abstract: The invention relates to fuel additive compositions for internal combustion engines and to fuels that contain the corresponding additives for internal combustion engines. The inventive fuel additive compositions for internal combustion engines have an excellent performance in keeping the inlet system clean and improved viscosity properties, especially at low temperatures.Type: ApplicationFiled: October 29, 2002Publication date: July 31, 2003Inventors: Harald Schwahn, Dietmar Posselt
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Patent number: 6579329Abstract: A mixture suitable as fuel additive and lubricant additive and comprising essentially (A) at least one amine which carries a hydrocarbon radical having an average molecular weight of from 500 to 10,000, (B) at least one hydrocarbon polymer which has an average molecular weight of from 300 to 10,000 and may be present in unhydrogenated or hydrogenated form and (C) at least one conventional carrier oil has a weight ratio of component A to component B of from 80:20 to 60:40.Type: GrantFiled: May 20, 1996Date of Patent: June 17, 2003Inventors: Jürgen Thomas, Harald Schwahn, Peter Schreyer
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Publication number: 20030079399Abstract: Injector deposits in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble compound having the formula (I): 1Type: ApplicationFiled: September 14, 2001Publication date: May 1, 2003Inventors: Dennis J. Malfer, Scott D. Schwab, Timothy J. Henly
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Patent number: 6525221Abstract: A fuel oil detergent which efficiently constricts precipitate formation and octane number requirement increase in a carburetor, injector, and inlet system of an internal combustion engine, i.e., a hydropoly(oxyalkylene) oxyalkyl amine based compound, a process for preparing the compound, and a fuel oil composition including the compound.Type: GrantFiled: November 21, 2001Date of Patent: February 25, 2003Assignee: Daelim Industrial Co., Ltd.Inventors: Hyun-Ki Youn, Myeong-Seok Kim, Byung-Keel Sohn, Jae-Hoon Uhm, Byeong-Gyu Lim
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Patent number: 6497736Abstract: A fuel composition comprising a major amount of hydrocarbons boiling in the gasoline or diesel range and an effective detergent amount of a hydroxyalkyl-substituted amine which is the reaction product of: (a) a polyolefin epoxide derived from a branched chain polyolefin having an average molecular weight of about 400 to 5,000; and (b) an amine having the formula: wherein R1 and R2 are independently selected from the group consisting of hydrogen and hydrocarbyl of 1 to about 20 carbon atoms and, when taken together, R1 and R2 may form one or more 5- or 6-membered rings containing up to about 20 carbon atoms.Type: GrantFiled: December 23, 1991Date of Patent: December 24, 2002Assignee: Chevron Oronite Company LLCInventor: Edward T. Sabourin
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Patent number: 6488724Abstract: The additive described essentially comprises a selected alkoxylated fatty amine or fatty amine derivative and a special metal salt compound, preferably a metal soap. This additive for heavy oils effects a good emulsification or dispersion of asphaltenes and other higher-molecular weight compounds and, in addition, inter alia, increased storage stability, improved pumpability due to decreased viscosity of the oil and longer service lives of the filter systems. In addition, it also effects enhanced combustion of the heavy oils. The effective amount of additive in these oils is 2 to 2000 ppm. The oils described are suitable, in particular, as furnace fuel for industrial plants and power stations and as engine fuel for marine engines.Type: GrantFiled: October 27, 1997Date of Patent: December 3, 2002Assignee: Clariant GmbHInventors: Günther Hertel, Michael Feustel, Hakan Byström, Geoffrey Richards
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Patent number: 6488723Abstract: A motor fuel additive composition comprises a mixture of: (a) from about 5 to about 50 weight percent, based upon the total weight of the additive, of a detergent component selected from the group consisting of (i) a reaction product of a substituted hydrocarbon and an amino compound, and (ii) a polybutylamine or polyisobutylamine; and (b) a fuel conditioner component comprising (i) from about 2 to about 50 weight percent, based upon the total weight of the additive, of a polar oxygenated hydrocarbon compound and (ii) from about 2 to about 50 weight percent, based upon the total weight of the additive, of an oxygenated compatibilizing agent. The fuel conditioner component may additionally comprise a hydrophilic separant, an aromatic hydrocarbon, or mixtures thereof. Additionally, in some cases the hydrophilic separant may also act as the compatibilizing agent. The additive may also additionally comprise a carrier oil or fluidizer.Type: GrantFiled: February 2, 2001Date of Patent: December 3, 2002Inventors: Alfred Richard Nelson, Mark L. Nelson, Otis L. Nelson, Jr.
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Patent number: 6475251Abstract: A method for controlling engine deposits in a direct injection spark ignition gasoline engine which comprises operating the engine with a fuel composition comprising a major amount of hydrocarbons boiling in the gasoline range and an effective deposit-controlling amount of a fuel additive composition comprising: (a) an aromatic ester compound of the formula: or a fuel soluble salt thereof, wherein R is hydroxy, nitro or —(CH2)x—NR5R6, wherein R5 and R6 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms and x is 0 or 1; R1 is hydrogen, hydroxy, nitro or —NR7R8, wherein R7 and R8 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R2 and R3 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; and R4 is a polyalkyl group having an average molecular weight in the range of about 450 to 5,000; and (b) a poly(oxyalkylene) amine having at least one basic nitrogen atom and a sufficient number of oxyalkylene units to render the pType: GrantFiled: February 28, 2001Date of Patent: November 5, 2002Assignee: Chevron Oronite Company LLCInventor: Majid R. Ahmadi
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Patent number: 6371999Abstract: Fuels for internal combustion engines or lubricants contain small amounts of polyisobutylaminoalcohols of the formulae Ia and Ib where R is polyisobutyl having a number average molecular weight of 500 to 5,000 and in each of the two formulae one of the radicals X is OH and the other is the group where the radicals R1 may be identical or different and are each hydrogen, alkyl, hydroxyalkyl or aminoalkyl which may be substituted by further hydroxyl- or amino-carrying alkyl radicals, or the two radicals R1 may form a nonaromatic ring.Type: GrantFiled: August 21, 1996Date of Patent: April 16, 2002Assignee: BASF AktiengesellschaftInventors: Juergen Mohr, Knut Oppenlaender, Charalampos Gousetis, Ralf Kaestner, Norbert Rieber, Martin Fischer, Juergen Thomas
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Patent number: 6368370Abstract: A fuel composition comprising a major amount of hydrocarbons boiling in the gasoline or diesel range and an effective detergent amount of a hydroxyalkyl-substituted amine which is the reaction product of: (a) a polyolefin epoxide derived from a branched chain polyolefin having an average molecular weight of about 400 to 5,000; and (b) an nitrogen-containing compound selected from ammonia, a monoamine having from 1 to 40 carbon atoms, and a polyamine having from 2 to about 12 amine nitrogen atoms and from 2 to about 40 carbon atoms.Type: GrantFiled: February 6, 1995Date of Patent: April 9, 2002Assignee: Chevron Oronite Company LLCInventors: Edward T. Sabourin, Thomas F. Buckley, III, Curtis B. Campbell, Frank Plavac
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Publication number: 20020029512Abstract: Mixtures of at least one amine, polyamine or alkanolamine and at least one polyetheramine and their use as additives for gasoline engine fuels.Type: ApplicationFiled: July 12, 2001Publication date: March 14, 2002Inventors: Juergen Thomas, Peter Schreyer, Knut Oppenlaender, Wolfgang Guenther, Lothar Franz
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Patent number: 6346129Abstract: A fuel composition comprising a major amount of hydrocarbons boiling in the gasoline or diesel range and an effective detergent amount of a hydroxyalkyl-substituted polyamine which is the reaction product of: (a) a polyolefin epoxide derived from a branched chain polyolefin having an average molecular weight of about 400 to 5,000; and (b) a polyamine having from 2 to about 12 amine nitrogen atoms and from 2 to about 40 carbon atoms.Type: GrantFiled: February 6, 1995Date of Patent: February 12, 2002Assignee: Chevron Oronite Company LLCInventors: Edward T. Sabourin, Thomas F. Buckley, III, Curtis B. Campbell, Frank Plavac, Mary J. Tompkins
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Patent number: 6203584Abstract: A fuel composition comprising a major amount of hydrocarbons boiling in the gasoline range and a fuel consumption reducing amount of a fuel additive composition comprising: (a) at least one amine compound selected from the group consisting of: (1) a fuel-soluble aliphatic hydrocarbyl-substituted amine having at least one basic nitrogen atom where the hydrocarbyl group has a number average molecular weight of about 700 to 3,000, and (2) a poly(oxyalkylene)amine having at least one basic nitrogen atom and a sufficient number of oxyalkylene units to render the poly(oxyalkylene)amine soluble in hydrocarbons boiling in the gasoline range; and (b) an ester of a carboxylic acid and a polyhydric alcohol, wherein the carboxylic acid has from one to about four carboxylic acid groups and from about 8 to about 50 carbon atoms and the polyhydric alcohol has from about 2 to about 50 carbon atoms and from about 2 to about 6 hydroxy groups.Type: GrantFiled: March 31, 1998Date of Patent: March 20, 2001Assignee: Chevron Chemical Company LLCInventors: Peter A. Fuentes-Afflick, Jeffrey A. Gething
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Patent number: 6140276Abstract: A method of reducing the deposition of wax from a crude oil containing wax which comprises adding thereto at least one N-substituted polyalkylene imine which has at least one organic substituent that is a hydroxy-substituted alkyl group of 12-24 carbon atoms.Type: GrantFiled: June 4, 1998Date of Patent: October 31, 2000Assignee: BP Exploration Operating Company LimitedInventors: Simon Neil Duncum, Keith James, Christopher George Osborne
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Patent number: 6117197Abstract: A fuel composition comprising a major amount of hydrocarbons boiling in the gasoline or diesel range and a fuel additive composition comprising (a) about 15 to 2,000 parts per million by weight of an aromatic ester of a polyalkylphenoxyalkanol, (b) about 30 to 2,000 parts per million by weight of a poly(oxyalkylene) amine, and (c) about 30 to 2,000 parts per million by weight of an aromatic di- or tri-carboxylic acid ester; wherein the total amount of components (a) and (b) is at least about 70 parts per million by weight, and further wherein the weight ratio of component (c) to the total amount of components (a) and (b) is at least about 0.25 to 1. The fuel compositions of this invention are useful for the prevention and control of engine deposits.Type: GrantFiled: November 25, 1998Date of Patent: September 12, 2000Assignee: Chevron Chemical Company LLCInventor: Keith Robert Houser
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Patent number: 6090170Abstract: The present invention relates to derivatives of polyalkenyl amine substituted with numerous hydroxy groups of the following formula (I) useful as a novel fuel detergent. ##STR1## wherein polyalkenyl denotes a branched alkyl derived from polyolefin which has a molecular weight of 400.about.5,000 and is prepared with olefin having 2 to 6 carbon atoms; m is an integer ranging from 2 to 10, R.sup.1, R.sup.2 and R.sup.3 may be identical or different, and represent a hydrogen atom or a linear or branched alkyl having 1 to 4 carbon atoms: R.sup.4 and R.sup.5 may be identical or different, and denote a hydrogen atom, a C.sub.1 -C.sub.10 alkyl group, a hydroxyalkyl, a phenyl, naphthyl, an aminoalkyl of formula (II) or a polyaminoalkylene of formula (III) ##STR2## wherein R.sup.6 denotes a C.sub.2 -C.sub.10 alkylene group: R.sup.7 and R.sup.8 may be identical or different, and denote a hydrogen atom, a C.sub.1 -C.sub.10 alkyl group, a phenyl, a naphthyl or a C.sub.1 -C.sub.Type: GrantFiled: December 31, 1998Date of Patent: July 18, 2000Assignee: Daelim Industrial Co., Ltd.Inventors: Hyun-ki Yun, Jung-jin Kim, Yong-hwa Yeom, Il-seung Kim, Myeong-seog Kim, Byung-keel Sohn, Kyu-shon Jung
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Patent number: 5976202Abstract: Reaction products of polyolefins having predominantly a terminal double bond and a number average molecular weight of from 250 to 10,000, which possess an aliphatic hydrocarbon skeleton which is straight-chain or carries C.sub.1 -C.sub.4 -alkyl side chains, with from 1 to 10 mol, per equivalent of double bond, of one or more vinyl esters I ##STR1## are obtainable by reacting the stated polyolefins with the vinyl esters I in the presence of a free radical initiator at from 80 to 200.degree. C., it being possible for these reaction products subsequently to have been hydrolyzed to the corresponding alcohols or converted into the corresponding amines by reductive amination with amines II ##STR2## .Type: GrantFiled: July 20, 1995Date of Patent: November 2, 1999Assignee: BASF AktiengesellschaftInventors: Hans Peter Rath, Helmut Mach, Harald Schwahn, Hans-Joachim Muller, Wolfgang Reif, Thomas Ruhl
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Patent number: 5945388Abstract: A lubricating oil composition suitable for use in a low or medium speed diesel engine comprising a fuel oil with a residual oil content is characterised in that the lubricating oil composition further comprises a hydrocarbyl substituted amine or polyamine. The effect of such an amine is to reduce deposits due to the residual oil. A method of reducing deposits in a low or medium speed diesel engine is also disclosed.Type: GrantFiled: April 23, 1996Date of Patent: August 31, 1999Assignee: Lubrizol Adibis Holdings (UK) Ltd.Inventors: Stephen J. Cook, Sean P. O'Connor
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Patent number: 5853435Abstract: Polymeric amine sulfur-containing heterocyclic reaction products have been found to be effective antiwear and corrosion inhibiting additives for fuels, including gasolines, and lubricants with excellent high temperature decomposing, cleanliness and detergency/dispersancy features.Type: GrantFiled: December 30, 1994Date of Patent: December 29, 1998Assignee: Mobil Oil CorporationInventors: Noyes L. Avery, Joan C. Axelrod, James T. Carey, Liehpao O. Farng, Andrew G. Horodysky
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Patent number: 5851242Abstract: A fuel additive composition comprising:(a) a polyalkylphenoxyaminoalkane having the formula: ##STR1## or a fuel soluble salt thereof, wherein R is a polyalkyl group having an average molecular weight in the range of about 600 to 5,000;R.sub.1 and R.sub.2 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; andA is amino, N-alkyl amino having about 1 to about 20 carbon atoms in the alkyl group, N,N-dialkyl amino having about 1 to about 20 carbon atoms in each alkyl group, or a polyamine moiety having about 2 to about 12 amine nitrogen atoms and about 2 to about 40 carbon atoms; and(b) a poly(oxyalkylene) amine having at least one basic nitrogen atom and a sufficient number of oxyalkylene units to render the poly(oxyalkylene) amine soluble in hydrocarbons boiling in the gasoline or diesel fuel range.The fuel additive compositions of this invention are useful as fuel additives for the prevention and control of engine deposits.Type: GrantFiled: April 30, 1997Date of Patent: December 22, 1998Assignee: Chevron Chemical CompanyInventors: Richard E. Cherpeck, Jack E. Morris, Majid R. Ahmadi
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Patent number: 5849048Abstract: Substituted biphenyl poly(oxyalkylene) ethers having the formula: ##STR1## wherein R.sub.1 is hydrogen or hydroxyl; R.sub.2 is hydroxyl, cyano, nitro, amino, aminomethyl, N-alkylamino or N-alkylaminomethyl wherein the alkyl group contains 1 to about 6 carbon atoms, N,N-dialkylamino or N,N-dialkylaminomethyl wherein each alkyl group independently contains 1 to about 6 carbon atoms, with the proviso that R.sub.1 and R.sub.2 are ortho relative to each other and meta or para relative to the adjoining phenyl substitutent; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl having 1 to about 6 carbon atoms and each R.sub.3 and R.sub.4 is independently selected in each --OCHR.sub.3 --CHR.sub.4 -- unit; R.sub.5 is hydrogen, alkyl having 1 to about 100 carbon atoms, phenyl, aralkyl having about 7 to about 100 carbon atoms, alkaryl having about 7 to about 100 carbon atoms; or an acyl group having the formula: ##STR2## wherein R.sub.Type: GrantFiled: September 30, 1997Date of Patent: December 15, 1998Assignee: Chevron Chemical Company LLCInventor: Richard E. Cherpeck
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Patent number: 5749929Abstract: A fuel additive composition comprising: (a) an aromatic ester compound of the formula: ##STR1## or a fuel soluble salt thereof, wherein R is hydroxy, nitro or --(CH.sub.2).sub.x --NR.sub.5 R.sub.6, wherein R.sub.5 and R.sub.6 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms and x is 0 or 1;R.sub.1, is hydrogen, hydroxy, nitro or --NR.sub.7 R.sub.8, wherein R.sub.7 and R.sub.8 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms;R.sub.2 and R.sub.3 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; andR.sub.4 is a polyalkyl group having an average molecular weight in the range of about 450 to 5,000; and(b) a poly(oxyalkylene) amine having at least one basic nitrogen atom and a sufficient number of oxyalkylene units to render the poly(oxyalkylene) amine soluble in hydrocarbons boiling in the gasoline or diesel fuel range.The fuel additive compositions of this invention are useful as fuel additives for the prevention and control of engine deposits.Type: GrantFiled: April 7, 1997Date of Patent: May 12, 1998Assignee: Chevron Chemical CompanyInventors: Richard E. Cherpeck, Jack E. Morris, Majid R. Ahmadi
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Patent number: 5660601Abstract: Fuels for gasoline engines contain small amounts of polyetheramines IR.sup.1 --(OBu).sub.n --NR.sup.2 R.sup.3 (I)whereR.sup.1 is C.sub.2 -C.sub.30 -alkyl,R.sup.2 and R.sup.3, independently of one another, are each hydrogen, C.sub.1 -C.sub.8 -alkyl, aminoalkylene of the general formula II--R.sup.4 --NR.sup.5 R.sup.6 (II)or polyaminoalkylene of the general formula III--(R.sup.4 --NR.sup.5).sub.m --R.sup.6 (III)whereR.sup.4 is C.sub.2 -C.sub.10 -alkylene, R.sup.5 and R.sup.6, independently of one another, are each hydrogen or C.sub.1 -C.sub.8 -alkyl and m is from 2 to 8,Bu is a butylene radical derived from butylene oxide andn is from 12 to 28.Type: GrantFiled: September 11, 1995Date of Patent: August 26, 1997Assignee: BASF AktiengesellschaftInventors: Knut Oppenlander, Wolfgang Gunther, Andreas Henne, Volkmar Menger, Rainer Becker, Wolfgang Reif, Jurgen Thomas, Harald Schwahn, Erhard Henkes
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Patent number: 5601624Abstract: Oxygenated alkyl amines synthesized using carbonyl coupling reactions have combustion chamber deposit reducing properties and oxidative stability characteristics beneficial for dispersant/detergent applications in fuels and lubricants.Type: GrantFiled: April 10, 1995Date of Patent: February 11, 1997Assignee: Mobil Oil CorporationInventors: James T. Carey, John Hiebert, Andrew G. Horodysky
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Patent number: 5558684Abstract: The invention provides a stabilized fuel additive composition comprising a major portion of the reaction product of a 4-alkyl-2-morpholinone and an alkylphenoxypolyoxyalkylene amine and a minor portion of a stabilizing agent sufficient to prevent the formation of haze in the additive composition comprising a compound selected from polypropyleneoxide diamines of formula H.sub.2 N(CH.sub.2 CHCH.sub.3 O).sub.n NH.sub.2 where n is a number between about 4 and about 25, and triethylene tetramine. A method of stabilizing a fuel additive composition is also provided.Type: GrantFiled: December 26, 1995Date of Patent: September 24, 1996Assignee: Texaco Inc.Inventors: Thomas F. DeRosa, Joseph M. Russo, Benjamin J. Kaufman, Joseph T. Mastropierro
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Patent number: 5554794Abstract: The invention includes a compound of formula I ##STR1## where R' is hydrogen, an alkyl, or aryl group; R"O is derived from R"OH which is a polyether mono-ol or hydrocarbyl mono-ol; and R"' independently is a hydrogen, an alkyl group or a substituted alkyl group. The invention also includes an unleaded fuel composition containing a compound of formula I and a process for making the compound of formula I.Type: GrantFiled: August 18, 1994Date of Patent: September 10, 1996Assignee: Shell Oil CompanyInventor: Thomas H. Johnson
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Patent number: 5478367Abstract: The addition to diesel or jet fuel of macrocyclic polyamines, especially those derived from PIBSA, or hydrocarbyl polyamines reduces particle emission, especially in association with organic nitrate cetane improvers.Type: GrantFiled: December 9, 1992Date of Patent: December 26, 1995Assignee: Exxon Chemical Patents Inc.Inventors: Michael D. Sexton, Anthony K. Smith, Antonio Gutierrez, Stanley J. Brois
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Patent number: 5407453Abstract: It has been found that a composition comprising an alkoxy alcohol, an aliphatic alcohol, a liquid petroleum distillate, a liquid fatty acid, a volatile nitrogen base, polyisobutenyl aminoethylethanolamine, and water may be used as an engine deposit cleaner which removes air and fuel induction system deposits, valve deposits, and combustion chamber deposits. The inventive composition may be introduced into the engine in lieu of fuel, or in conjunction with fuel while the engine is operating.Type: GrantFiled: March 19, 1993Date of Patent: April 18, 1995Assignee: The Lubrizol CorporationInventors: G. Frederick Pierce-Ruhland, Stephen H. Stoldt
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Patent number: 5354343Abstract: The invention includes a compound of formula I ##STR1## where R' is hydrogen, an alkyl, or aryl group; R"O is derived from R"OH which is a polyether mono-ol or hydrocarbyl mono-ol; and R'" independently is a hydrogen, an alkyl group or a substituted alkyl group. The invention also includes an unleaded fuel composition containing a compound of formula I and a process for making the compound of formula I.Type: GrantFiled: November 19, 1993Date of Patent: October 11, 1994Assignee: Shell Oil CompanyInventor: Thomas H. Johnson
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Patent number: 5334228Abstract: A fuel additive having detergency, solubility and thermal stability comprises a detergent component, e.g., polyalkenyl succinimide, and a carrier fluid obtained from a diamondoid fluid comprising an compound selected from the group consisting of adamantane, diamantane, triamantane, tetramantane, and the alkyl-substituted derivatives thereof.Type: GrantFiled: October 18, 1993Date of Patent: August 2, 1994Assignee: Mobil Oil CorporationInventors: Henry Ashjian, Matthew P. Miller, Dong-Ming Shen, Margaret M. Wu
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Patent number: 5306316Abstract: Poly(alkylene ether) amines having the formula: ##STR1## wherein A is an amine moiety having at least one basic nitrogen atom; R.sub.1 is a hydrocarbyl group having a sufficient number of carbon atoms to render the poly(vinyl ether) amine soluble in hydrocarbons boiling in the gasoline or diesel fuel range; R.sub.2 is an alkylene group having 2 to about 8 carbon atoms; R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are each independently hydrogen or a lower alkyl group having 1 to about 4 carbon atoms; R.sub.9 is an alkyl group having 1 to about 10 carbon atoms; m is 0 or 1; n is an integer from 5 to 99; and W is a hydroxy(oxypropylene) group having the formula: ##STR2## or mixtures thereof. The poly(vinyl ether) amines of formula I are useful as fuel additives for the prevention and control of engine deposits.Type: GrantFiled: April 1, 1993Date of Patent: April 26, 1994Assignee: Chevron Research and Technology CompanyInventor: Richard E. Cherpeck
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Patent number: 5298038Abstract: An additive for fuel oil comprises a compound comprising (a) an alkyl group having 9 to 37 carbon atoms and containing a branched alkyl having 3 to 18 carbon atoms and (b) an amine group having at least one polyoxyalkylene having 2 to 4 carbon atoms or an amineoxide having at least one polyoxyalkylene having 2 to 4 carbon atoms. This additive is effective for cleaning the injection nozzle of coking.Type: GrantFiled: September 25, 1991Date of Patent: March 29, 1994Assignee: Kao CorporationInventors: Jiro Hashimoto, Shogo Nomoto
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Patent number: 5230714Abstract: Improved additives/detergents for lubricant and fuel compositions are obtained by condensing a hydroxyalkyl or hydroxyaryl compound with an amine compound. The condensates according to the present invention are produced by the acid catalyzed condensation of the amine reactant with the hydroxy reactant.Type: GrantFiled: August 27, 1992Date of Patent: July 27, 1993Assignee: The Lubrizol CorporationInventor: Thomas F. Steckel