Containing Metal Patents (Class 473/372)
  • Patent number: 8492470
    Abstract: Disclosed are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compressions greater than 100. Also disclosed is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: July 23, 2013
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: James R. De Garavilla
  • Publication number: 20130178310
    Abstract: The present invention is directed to a golf ball comprising a core, a cover and optionally an intermediate layer disposed between the core and the cover, wherein at least one of the core, the at least one intermediate layer, and the cover comprises at least one of an ionomer and an acid copolymer and has at least one treated region that is treated with and comprises a reaction product of an organometallic composition and the at least one ionomer and/or acid copolymer, such that: the at least one treated region has an internal property gradient; or at least two treated regions, in tandem, have an external property gradient; or the at least one treated region and an untreated region, in tandem, have an external property gradient.
    Type: Application
    Filed: January 9, 2012
    Publication date: July 11, 2013
    Inventors: Robert Blink, David A. Bulpett
  • Patent number: 8481621
    Abstract: Disclosed embodiments concern using at least one triazine, typically an amine or polyamine triazine (referred to as amino triazines), in combination with at least one ionomer or ionomer precursor to form compositions useful for making sporting equipment, such as golf ball components. The ionomer or ionomer precursor typically includes plural acid functional groups, such as carboxyl or carboxylate groups, that react or form salts with the amino triazine. Specific examples, without limitation, of suitable amino triazines include guanamine, 6-methyl-1,3,5-triazine-2,4-diamine(acetoguanamine), 6-nonyl-1,3,5-triazine-2,4-diamine(nonylguanamine), 6-phenyl-1,3,5-triazine-2,4-diamine(benzoguanamine) and 2,4,6-triamino-triazine(melamine).
    Type: Grant
    Filed: July 6, 2012
    Date of Patent: July 9, 2013
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20130172110
    Abstract: An object of the present invention is to provide a golf ball excellent in a shot feeling and resilience. The present invention provides a golf ball resin composition comprising (A) at least one resin component selected from the group consisting of (a-1) a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms, (a-2) an ionomer resin consisting of a metal ion-neutralized product of the binary copolymer, (a-3) a ternary copolymer composed of the binary copolymer components and an ?,?-unsaturated carboxylic acid ester, and (a-4) an ionomer resin consisting of a metal ion-neutralized product of the ternary copolymer components; and (B) a basic metal salt of a fatty acid, and having a spin-lattice relaxation time (T1) of 13C nucleus of 5.56 seconds or shorter measured by a High resolution solid state nuclear magnetic resonance (NMR) method.
    Type: Application
    Filed: December 27, 2012
    Publication date: July 4, 2013
    Applicant: DUNLOP SPORTS CO., LTD.
    Inventor: DUNLOP SPORTS CO., LTD.
  • Publication number: 20130172112
    Abstract: The present invention provides a golf ball resin composition comprising (A) an ionomer resin component and (B) a compound having an anionic part within a molecule thereof, wherein with respect to a metal ion contained in the golf ball resin composition, (A) the ionomer resin component and (B) the compound having the anionic part within the molecule thereof, following coordinate energies obtained by ab initio molecular orbital calculation method using a basis function B3LYP/6-31G(d) satisfy the following expression: 0.3?(A?C)/(B?C)?0.6, wherein coordinate energy A is the coordinate energy between the metal ion and the anionic part of (B) component, coordinate energy B is the coordinate energy between the metal ion and the carboxyl ion of (A) component, and coordinate energy C is the coordinate energy between the metal ion and the olefin of (A) the ionomer resin component.
    Type: Application
    Filed: December 28, 2012
    Publication date: July 4, 2013
    Applicant: Dunlop Sports Co. Ltd.
    Inventor: Dunlop Sports Co. Ltd.
  • Publication number: 20130172111
    Abstract: An object of the present invention is to provide a golf ball having a low spin rate on driver shots. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) base rubber, (b) an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator and (d) a carboxylic acid having a benzene ring and/or a salt thereof, provided that the rubber composition further contains (e) a metal compound in case of containing only (b) the ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent.
    Type: Application
    Filed: December 27, 2012
    Publication date: July 4, 2013
    Applicant: Dunlop Sports Co., Ltd.
    Inventor: Dunlop Sports Co., Ltd.
  • Publication number: 20130172115
    Abstract: A golf ball resin composition that is excellent in resilience includes (A) at least one resin component selected from the group consisting of (a-1) a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms, (a-2) an ionomer resin consisting of a metal ion-neutralized product of a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms, (a-3) a ternary copolymer composed of an olefin, an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and an ?,?-unsaturated carboxylic acid ester, and (a-4) an ionomer resin consisting of a metal ion-neutralized product of a ternary copolymer composed of an olefin, an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and an ?,?-unsaturated carboxylic acid ester, and (B) a basic metal salt of a fatty acid.
    Type: Application
    Filed: December 27, 2012
    Publication date: July 4, 2013
    Applicant: DUNLOP SPORTS CO., LTD.
    Inventor: DUNLOP SPORTS CO., LTD.
  • Publication number: 20130172108
    Abstract: The invention provides a solid golf ball having a core and a cover. The core is formed of a rubber composition containing a base rubber, a co-crosslinking agent, a crosslinking initiator and a metal oxide. The base rubber contains polybutadiene, a styrene-butadiene rubber and, optionally, an isoprene rubber. The co-crosslinking agent is methacrylic acid, and the rubber composition includes a specific waste material in the form of a powder. The core deflection and the cover material are optimized. Utilizing a waste material in a solid golf ball conserves resources and thus is beneficial to the global environment. Even during prolonged use, the golf ball maintains its basic performance attributes (feel, flight, durability) at a high level.
    Type: Application
    Filed: October 1, 2012
    Publication date: July 4, 2013
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventor: BRIDGESTONE SPORTS CO., LTD.
  • Publication number: 20130172107
    Abstract: The invention provides a solid golf ball having a core and a cover. The core is formed of a rubber composition containing a base rubber, a co-crosslinking agent, a crosslinking initiator and a metal oxide. The co-crosslinking agent is methacrylic acid, and the rubber composition includes a specific waste material in the form of a powder. The core deflection and the cover material are optimized. Utilizing a waste material in a solid golf ball conserves resources and thus is beneficial to the global environment. Even during prolonged use, the golf ball maintains its basic performance attributes (feel, flight, durability) at a high level.
    Type: Application
    Filed: October 1, 2012
    Publication date: July 4, 2013
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventor: Bridgestone Sports Co., Ltd.
  • Publication number: 20130172109
    Abstract: An object of the present invention is to provide a golf ball resin composition excellent in shot feeling and resilience. The golf ball resin composition includes (A) at least one resin component selected from the group consisting of (a-1) a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms, (a-2) an ionomer resin consisting of a metal ion-neutralized product of the binary copolymer components, (a-3) a ternary copolymer composed of the binary copolymer components and an ?,?-unsaturated carboxylic acid ester, and (a-4) an ionomer resin consisting of a metal ion-neutralized product of the ternary copolymer components; and (B) a basic metal salt of a fatty acid, and having a storage modulus E? (Pa) and a loss modulus E? (Pa) satisfying a following expression; log(E?/E?2)??5.84 when measured in a tensile mode using a dynamic viscoelasticity measuring apparatus.
    Type: Application
    Filed: December 27, 2012
    Publication date: July 4, 2013
    Applicant: DUNLOP SPORTS CO. LTD.
    Inventor: Dunlop Sports Co. Ltd.
  • Publication number: 20130172106
    Abstract: The invention provides a solid golf ball which has a core of at least one layer and a cover of at least one layer. At least one layer of the core is formed primarily of polybutadiene and includes at least 0.05 part by weight each of (I) a rubber powder obtained by granulating a rubber material containing acrylic acid or a metal salt of acrylic acid and (II) a polyurethane resin powder per 100 parts by weight of rubber component. At least one layer of the cover is formed primarily of polyurethane.
    Type: Application
    Filed: December 30, 2011
    Publication date: July 4, 2013
    Applicant: Bridgestone Sports Co., Ltd.
    Inventor: Hirotaka SHINOHARA
  • Publication number: 20130165263
    Abstract: The present invention provides a resin composition for a golf ball and a golf ball which have high resilience while maintaining soft compression and also have low spin on driver shots, and therefore can achieve a long flight distance. The present invention relates to a resin composition for a golf ball, including an ionomer resin consisting of a metal ion-neutralized copolymer of (A) a C3-8 ?,?-unsaturated carboxylic acid and (B) a C3-8 ?,?-unsaturated carboxylic acid ester, the ionomer resin having a mass ratio of (A)/(B) of 10/90 to 25/75, and a degree of neutralization of 30 to 105 mol %.
    Type: Application
    Filed: December 26, 2012
    Publication date: June 27, 2013
    Applicant: DUNLOP SPORTS CO. LTD.
    Inventor: Dunlop Sports Co. Ltd.
  • Publication number: 20130165262
    Abstract: This invention pertains to a golf ball which includes a core, optionally one or more intermediate layers; and an outer cover layer, and where one or more of the outer cover or intermediate layers includes a carboxylated elastomer composition, which has an elastomer backbone and one or more pendant carboxy groups.
    Type: Application
    Filed: December 18, 2012
    Publication date: June 27, 2013
    Applicant: Taylor Made Golf Company, Inc.
    Inventor: Taylor Made Golf Company, Inc.
  • Publication number: 20130157779
    Abstract: This invention pertains to a golf ball which includes a core, optionally one or more intermediate layers; and an outer cover layer. The outer cover layer and/or one or more intermediate layers includes a blend of a) 2 to 60 wt % (based on the total weight of the blend composition) of a cyclic olefin polymer which includes a norbornene-based monomer having the general formula; where R18 to R21 independently represent a hydrogen atom, a halogen atom or a hydrocarbon group and m is from 0 to about 3; and b) about 40 to about 98 wt % (based on the total weight of the blend composition) of one or more additional polymer components. The blend composition has a melt flow index (MFI) from 1 to 80 g/10 min., a material hardness of 30 to 90 Shore D, and a flex modulus of 10 to 120 kpsi.
    Type: Application
    Filed: December 19, 2011
    Publication date: June 20, 2013
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20130157780
    Abstract: This invention pertains to a golf ball which includes a core, optionally one or more intermediate layers; and an outer cover layer. The outer cover layer and/or one or more intermediate layers (if present) includes a blend of from about 2 to about 60 wt % (based on the total weight of the blend composition) of an liquid crystalline polymer (“LCP”) having the general formula; and from about 40 to about 98 wt % (based on the total weight of the blend composition) of one or more additional polymer components.
    Type: Application
    Filed: December 18, 2012
    Publication date: June 20, 2013
    Applicant: Taylor Made Golf Company, Inc.
    Inventor: Taylor Made Golf Company, Inc.
  • Publication number: 20130157778
    Abstract: This invention pertains to a golf ball which includes a core, optionally one or more intermediate layers; and an outer cover layer. The outer cover layer and/or one or more intermediate layers includes a blend of a) about 2 to about 40 wt % (based on the total weight of the blend composition) of an aramid polymer and b) about 60 to about 98 wt % (based on the total weight of the blend composition) of one or more additional polymer components. The blend composition has a melt flow index (MFI) from about 1 to about 80 g/10 min., a material hardness of about 30 to about 90 Shore D, and a flex modulus of about 10 to about 120 kpsi.
    Type: Application
    Filed: December 19, 2011
    Publication date: June 20, 2013
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20130150185
    Abstract: A golf ball having a good rebound and excellent flight performance can be obtained using a golf ball composition which contains a diene polymer having an aluminum catalyst residue content of not more than 650 ppm.
    Type: Application
    Filed: March 14, 2012
    Publication date: June 13, 2013
    Applicants: BRIDGESTONE CORPORATION, BRIDGESTONE SPORTS CO., LTD.
    Inventors: Hideo Takeichi, Takashi Ohira, Yuichiro Ozawa, Tsuyoshi Nakajima, Satoru Tamaki, Yusuke Yamagata, Teppei Mori
  • Publication number: 20130137534
    Abstract: Provided are a resin composition for a golf ball which is excellent in resilience, flexibility and fluidity, and a golf ball excellent in resilience and shot feeling. The present invention relates to a resin composition for a golf ball, including (A) a resin component and (B) a nonionic surfactant, the resin component (A) including at least one selected from the group consisting of (a-1) a binary copolymer of an olefin and a C3-8 ?,?-unsaturated carboxylic acid; (a-2) a metal ion-neutralized product of a binary copolymer of an olefin and a C3-8 ?,?-unsaturated carboxylic acid; (a-3) a ternary copolymer of an olefin, a C3-8 ?,?-unsaturated carboxylic acid, and an ?,?-unsaturated carboxylic acid ester; and (a-4) a metal ion-neutralized product of a ternary copolymer of an olefin, a C3-8 ?,?-unsaturated carboxylic acid, and an ?,?-unsaturated carboxylic acid ester.
    Type: Application
    Filed: November 27, 2012
    Publication date: May 30, 2013
    Applicant: DUNLOP SPORTS CO. LTD.
    Inventor: DUNLOP SPORTS CO. LTD.
  • Publication number: 20130137535
    Abstract: An object of the present invention is to provide a golf ball with improved durability and/or resilience by improving the adhesion between a constituent member comprising an ionomer resin and a constituent member comprising a polyurethane. The present invention provides a golf ball material composed of a multi-block copolymer having a block A that has an acid functional group neutralized with a metal ion and a block B that has lower polarity than the block A.
    Type: Application
    Filed: November 21, 2012
    Publication date: May 30, 2013
    Applicant: DUNLOP SPORTS CO., LTD.
    Inventor: DUNLOP SPORTS CO., LTD.
  • Patent number: 8425350
    Abstract: Golf balls and a system for finding golf balls and methods for making golf balls and methods for using such balls. In the case of one exemplary golf ball, the ball includes a shell and a core material which is encased in the shell and a tag which is disposed within the core material and which has at least one perforation. The tag includes a diode and an antenna which are coupled together. Another exemplary golf ball includes a shell and a core material which is encased within the shell and a tag which is within the core material and which includes an electrical element which is coupled to an antenna; the tag is detectable over a range of at least 20 feet from a handheld device, and the golf ball has high durability and substantially complies with the golf ball specifications of the United States Golf Association.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: April 23, 2013
    Assignee: RF Corporation
    Inventors: Chris Savarese, Lauro C. Cadorniga, Forrest F. Fulton, Noel H. C. Marshall, John Glissman, Kenneth P. Gilliland, Marvin L. Vickers, Gerald Latus
  • Publication number: 20130095955
    Abstract: The invention provides a solid golf ball having a core and a cover, the core being formed of a rubber composition containing a base rubber, a co-crosslinking agent, a crosslinking initiator and a metal oxide. The base rubber is a mixture of polybutadiene and a styrene-butadiene rubber, the styrene-butadiene rubber having a styrene bond content of not more than 35 wt %. The co-crosslinking agent is methacrylic acid. The core deflection under specific loading and the VR value for dimples on the ball surface are set within specific ranges.
    Type: Application
    Filed: October 1, 2012
    Publication date: April 18, 2013
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventor: BRIDGESTONE SPORTS CO., LTD.
  • Publication number: 20130072322
    Abstract: Multi-piece golf balls having at least one component made of a rubber composition comprising substantially oriented nanostructures are provided. For example, the nanostructures may be in the form of nanofibers, nanorods, nanotubes, and nanoparticles. The multi-piece golf ball contains a core, which may have a dual-core construction including a center and surrounding outer core layer or other multi-layered structure. Preferably at least one of the core layers is formed from a polybutadiene rubber composition comprising the nanostructures. The polybutadiene rubber may be chemically or non-chemically modified. The polybutadiene preferably has a cis-bond content of at least 80%.
    Type: Application
    Filed: September 15, 2011
    Publication date: March 21, 2013
    Inventors: William E. Morgan, Brian Comeau, Michael J. Sullivan
  • Patent number: 8399549
    Abstract: Described are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compression greater than 100. Also described is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.
    Type: Grant
    Filed: April 10, 2012
    Date of Patent: March 19, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventor: James R. De Garavilla
  • Publication number: 20130053178
    Abstract: Multi-piece golf balls having at least one component made of a composition comprising a polymerized substituted imidazolium liquid ionomer are provided. The multi-piece golf ball contains a core, which may have a dual-core construction including a center and surrounding outer core layer or other multi-layered structure. Preferably at least one of the core layers is formed from a composition comprising a rubber material or highly neutralized acid copolymer (HNP) and the liquid ionomer. The resulting golf ball has high resiliency.
    Type: Application
    Filed: August 24, 2011
    Publication date: February 28, 2013
    Inventors: Michael J. Sullivan, Mark L. Binette
  • Publication number: 20130053179
    Abstract: A golf ball includes a spherical core and a cover covering the spherical core, wherein the cover is formed from a polyurethane composition containing a polyurethane elastomer as a resin component, the polyurethane composition has a shear loss modulus G? of more than 5.03×106 Pa and 1.17×108 Pa or less when measured in a shear mode using a dynamic viscoelasticity measuring apparatus at the conditions of the temperature of 0° C., and the oscillation frequency of 10 Hz, the golf ball has a hardness distribution that R2 of a linear approximate curve determined by a least-squares method is 0.95 or more, when plotting center hardness (JIS-C) of the spherical core, hardness (JIS-C) measured at intervals of 2.5 mm from the center of the spherical core, surface hardness (JIS-C) of the spherical core, and slab hardness (JIS-C) of the cover versus distances from the center of the spherical core.
    Type: Application
    Filed: August 30, 2012
    Publication date: February 28, 2013
    Inventors: Toshiyuki TARAO, Chiemi Mikura, Kazuhisa Fushihara
  • Publication number: 20130017905
    Abstract: An object of the present invention is to provide a golf ball showing a great flight distance on driver shots. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) base rubber, (b) an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator and (d) a branched carboxylic acid and/or a salt thereof, provided that the rubber composition further contains (e) a metal compound in case of containing only (b) the ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent.
    Type: Application
    Filed: July 10, 2012
    Publication date: January 17, 2013
    Inventors: Ayaka SHINDO, Chiemi Mikura, Shun Kurihara, Kazuhisa Fushihara
  • Publication number: 20130017906
    Abstract: The present invention relates to golf balls and golf ball components comprising a blend of one or more ionomers mixed with one or more metal or ammonium salts of chelating agent. The resulting modified ionomer compositions have improved proccessability as shown by the increase in melt flow index (12) as compared to the unmodified ionomer analogs while demonstrating an increase in resiliency or speed as shown by increasing COR, while maintaining or showing only a slight increase in hardness as measured by Shore D.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 17, 2013
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20130012335
    Abstract: An object of the present invention is to provide a soft golf ball resin composition excellent in the shot feeling and resilience. The present invention provides a golf ball resin composition comprising: (A) 100 parts by mass of at least one resin component selected from the group consisting of (a-1) a binary copolymer, (a-2) a binary ionomer resin, (a-3) a ternary copolymer, and (a-4) a ternary ionomer resin, (B) 1 part to 25 parts by mass of a phosphate ester and/or a salt thereof; and (C) 0 part to 200 parts by mass of a basic inorganic metal compound. The golf ball of the present invention comprises a constituent member formed from the golf ball resin composition.
    Type: Application
    Filed: July 6, 2012
    Publication date: January 10, 2013
    Applicant: DUNLOP SPORTS CO., LTD.
    Inventors: Kazuyoshi SHIGA, Ryo MURAKAMI
  • Publication number: 20130012337
    Abstract: Compositions comprising the reaction product of: (a) a polyalkenamer; and (b) an organic modifier that includes at least one carbon to carbon unsaturated bond and at least one functional group selected from carboxyl, hydroxyl, amino, epoxy, (meth)acrylate, vinyl, ester, isocyanate, carbonyl, urethane, anhydride, or a metal salt thereof. Also disclosed are golf balls that include (i) a core, (ii) at least one intermediate layer, and (iii) at least one cover layer, wherein at least one of the core, intermediate layer or cover layer includes the polyalkenamer/functionalized organic modifier composition as a majority ingredient.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 10, 2013
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20130012336
    Abstract: A golf ball 2 includes a spherical core 4, a mid layer 6 positioned outside the core 4, and a cover 8 positioned outside the mid layer 6. The core 4 includes a spherical center 10 and an envelope layer 12 positioned outside the center 10. The center 10 has a diameter of 1 mm or greater and 15 mm or less. The center 10 has a JIS-C hardness H1, at its central point, of 20 or greater and 50 or less. The difference (H4?H3) between the JIS-C hardness H4 of the core 4 at its surface and the JIS-C hardness H3 of the envelope layer 12 at its innermost portion is equal to or greater than 10. The cover 8 has a flexural modulus of 300 MPa or greater and 1000 MPa or less, and has a tensile modulus of 400 MPa or greater and 1500 MPa or less.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 10, 2013
    Inventors: Hirotaka NAKAMURA, Keiji OHAMA, Kazuhiko ISOAGAWA, Satoko OKABE
  • Publication number: 20130005506
    Abstract: A golf ball 2 includes a core 4, amid layer 6 positioned outside the core 4, a reinforcing layer 8 positioned outside the mid layer 6, and a cover 10 positioned outside the reinforcing layer 8. The core 4 is obtained by a rubber composition being crosslinked. The rubber composition includes a base rubber, a co-crosslinking agent, a crosslinking initiator, and a carboxylate. The co-crosslinking agent is: (1) an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms; and/or (2) a metal salt of an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms. The amount of the carboxylate is equal to or greater than 1.0 parts by weight but less than 40 parts by weight per 100 parts by weight of the base rubber. A hardness of the mid layer 6 is greater than a hardness of the cover 10.
    Type: Application
    Filed: April 13, 2012
    Publication date: January 3, 2013
    Inventors: Kazuhiko Isogawa, Yoshiko Matsuyama, Kosuke Tachibana
  • Publication number: 20130005505
    Abstract: A golf ball 2 includes a spherical core 4 and a cover 6 covering the core 4 and including an inner cover 8 and an outer cover 10 positioned outside the inner cover 8. The core 4 is obtained by crosslinking a rubber composition. The rubber composition includes a base rubber (a), a co-crosslinking agent (b), a crosslinking initiator (c), and a carboxylate (d). The co-crosslinking agent (b) is: (b1) an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms; or (b2) a metal salt of an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms. The amount of the carboxylate (d) is equal to or greater than 1 parts by weight but less than 40 parts by weight per 100 parts by weight of the base rubber (a). A hardness of an innermost layer of the cover is equal to or less than a surface hardness of the core.
    Type: Application
    Filed: April 26, 2012
    Publication date: January 3, 2013
    Inventors: Takahiro Sajima, Hirotaka Nakamura
  • Publication number: 20120329574
    Abstract: An object of the present invention is to provide a golf ball showing a great flight distance on driver shots. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) base rubber, (b) an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator and (d) a carboxylic acid having 1 to 14 carbon atoms, provided that the rubber composition further contains (e) a metal compound in case of containing only (b) the ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent.
    Type: Application
    Filed: June 22, 2012
    Publication date: December 27, 2012
    Inventors: Chiemi MIKURA, Ayaka SHINDO, Shun KURIHARA, Kazuhisa FUSHIHARA
  • Publication number: 20120329575
    Abstract: An object of the present invention is to provide a golf ball showing a great flight distance on driver shots. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) base rubber, (b) an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator and (d) a salt of a carboxylic acid having 1 to 13 carbon atoms, provided that the rubber composition further contains (e) a metal compound in case of containing only (b) the ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent.
    Type: Application
    Filed: June 22, 2012
    Publication date: December 27, 2012
    Inventors: Chiemi Mikura, Ayaka Shindo, Shun Kurihara, Kazuhisa Fushihara
  • Publication number: 20120329573
    Abstract: Provided herein are compositions comprising an ionomer and a polyamine or a tertiary polyamide. The polyamine and the tertiary polyamide have a molecular weight of greater than 500 Da and do not contain an ester moiety or a primary amine moiety. The polyamine comprises at least three moieties that are tertiary amines or hindered secondary amines, and the polyamide comprises tertiary amide moieties and no secondary or primary amide moieties. The compositions may optionally include a filler. Further provided are articles such as golf balls and films containing these compositions.
    Type: Application
    Filed: December 20, 2011
    Publication date: December 27, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: PETER A. MORKEN, CHARLES JOHN TALKOWSKI
  • Publication number: 20120302372
    Abstract: The invention is directed to a golf ball providing improved UV resistance, abrasion resistance and hydrophobicity comprising cerium oxide nanoparticles having a particle size within the wavelength of visible light. The golf ball of the invention may comprise the cerium oxide nanoparticles in any or all of outer core layers, intemiediate layers, inner cover layers, outer cover layers and even as a coating composition in an amount of from about 0.5 wt % to about 10 wt % of the respective layer. The cerium oxide nanoparticles may be randomly dispersed within a layer or coating, or alternatively, the cerium oxide nanoparticles may be ordered in an array within the layer or coating.
    Type: Application
    Filed: May 27, 2011
    Publication date: November 29, 2012
    Inventors: Shawn Ricci, Randy Petrichko
  • Patent number: 8318840
    Abstract: A golf ball composition having a copolymer with an acid content modified by a nucleating agent is described. The nucleating agent modifies the flexural modulus of the acid copolymer and is preferably selected from the group consisting of sodium succinate, sodium glutarate, sodium caproate, sodium 4-methylvalerate, aluminum phenyl acetate, sodium cinnamate, and combinations thereof.
    Type: Grant
    Filed: December 13, 2011
    Date of Patent: November 27, 2012
    Assignee: Acushnet Company
    Inventor: Michael D. Jordan
  • Publication number: 20120289364
    Abstract: A golf ball comprising a core and at least one layer, wherein at least the core or the layer includes a polyurethane ionomer made by reacting a multi-functional modified ionomer with an isocyanate, wherein the multi-functional modified ionomer is a product of reacting an ionomer with a multi-functional modifier wherein the multi-functional modifier includes at least one carboxyl functional group and at least two additional types of functional groups.
    Type: Application
    Filed: December 27, 2011
    Publication date: November 15, 2012
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20120283039
    Abstract: Disclosed is a composition comprising, or produced from, a dicarboxylic acid-modified ionomer. Also disclosed are articles produced from the composition, such as golf balls. A particular multi-piece golf ball has an intermediate layer between the cover and the core, wherein the intermediate layer comprises the dicarboxylic acid-modified ionomer composition.
    Type: Application
    Filed: November 2, 2011
    Publication date: November 8, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventor: JOHN CHU CHEN
  • Patent number: 8257201
    Abstract: A golf ball including an inner core layer formed from a thermoset rubber composition and having a first surface hardness; a thermoplastic outer core layer having a second surface hardness, an inner surface hardness, and being formed from a copolymer of ethylene and an ?,?-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to fully-neutralize the acid groups of the copolymer; an inner cover layer; and an outer cover layer; wherein the first surface hardness is less than the second surface hardness by at least 5 Shore C and less than the inner surface hardness by at least 5 Shore C.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: September 4, 2012
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Michael J. Sullivan
  • Patent number: 8221267
    Abstract: A golf ball including an inner core layer formed from a thermoset rubber composition and having a first surface hardness; a thermoplastic outer core layer having a second surface hardness, an inner surface hardness, and being formed from a copolymer of ethylene and an ?,?-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to fully-neutralize the acid groups of the copolymer; an inner cover layer; and an outer cover layer; wherein the first surface hardness is less than the second surface hardness by at least 5 Shore C and less than the inner surface hardness by at least 5 Shore C.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: July 17, 2012
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Michael J. Sullivan
  • Patent number: 8221265
    Abstract: A golf ball including an inner core layer having an Atti compression of 30 or less and formed from a first rubber composition and having a first surface hardness; an outer core layer including a second rubber composition; a thermoplastic layer having a second surface hardness, an inner surface hardness, and comprising a copolymer of ethylene and an ?,?-unsaturated carboxylic acid, and sufficient amount of an organic acid or a salt of the organic acid and a cation source to neutralize the acid groups of the copolymer by about 80% or greater; an inner cover layer having a hardness of about 40 Shore D to 70 Shore D; and an outer cover layer. The first surface hardness is less than the second surface hardness by at least 5 Shore C.
    Type: Grant
    Filed: September 4, 2009
    Date of Patent: July 17, 2012
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Michael J. Sullivan
  • Publication number: 20120172150
    Abstract: An object of the present invention is to provide a golf ball having a great flight distance on driver shots. The present invention provides a golf ball having a spherical core and at least one cover layer covering the spherical core, wherein when JIS-C hardness, which is measured at nine points obtained by dividing a radius of the spherical core into equal parts having 12.5% intervals therebetween, is plotted against distance (%) from a core center, the spherical core is such that R2 of a linear approximation curve obtained from the least square method is 0.95 or higher, and a hardness difference between a core surface hardness and a core central hardness is 15 or higher in JIS-C hardness.
    Type: Application
    Filed: December 28, 2011
    Publication date: July 5, 2012
    Applicant: SRI SPORTS LIMITED
    Inventors: Chiemi MIKURA, Kazuhisa FUSHIHARA, Mikio YAMADA
  • Publication number: 20120172151
    Abstract: An object of the present invention is to provide a golf ball traveling a great distance of a driver shot. The present invention provides a golf ball having a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) a base rubber, (b) an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, (d) a carboxylic acid and/or a salt thereof, and (e) an organic sulfur compound having a naphthalene ring, provided that the rubber composition further contains (e) a metal compound in the case of containing only (b) the ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent.
    Type: Application
    Filed: December 28, 2011
    Publication date: July 5, 2012
    Applicant: SRI SPORTS LIMITED
    Inventors: Chiemi MIKURA, Kazuhisa FUSHIHARA, Mikio YAMADA
  • Publication number: 20120172149
    Abstract: An object of the present invention is to provide a golf ball having a low spin rate on driver shots and excellent in flight distance performance. The present invention provides a golf ball having a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) a base rubber, (b) an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, and (d) a salt of a carboxylic acid, provided that the rubber composition further contains (e) a metal compound in the case of containing only (b) the ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent.
    Type: Application
    Filed: December 27, 2011
    Publication date: July 5, 2012
    Applicant: SRI SPORTS LIMITED
    Inventors: Chiemi MIKURA, Kazuhisa FUSHIHARA, Mikio YAMADA, Shun KURIHARA, Ayaka SHINDO
  • Publication number: 20120165121
    Abstract: An object of the present invention is to provide a golf ball resin composition excellent in resilience. Another object of the present invention is to provide a golf ball excellent in a shot feeling and resilience. The golf ball resin composition of the present invention is characterized in that a storage modulus E? (Pa) and a loss modulus E? (Pa) satisfy a following expression; log(E?/E?2)??6.08 when measured at the conditions of the temperature of 12° C., the oscillation frequency of 10 Hz, and a strain of 0.05% in a tensile mode using a dynamic viscoelasticity measuring apparatus.
    Type: Application
    Filed: November 23, 2011
    Publication date: June 28, 2012
    Inventors: Kazuyoshi SHIGA, Ryo MURAKAMI, Takahiro SHIGEMITSU
  • Publication number: 20120165119
    Abstract: The present invention provides a golf ball resin composition comprising (A) at least one resin component selected from the group consisting of (a-1) a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms, (a-2) an ionomer resin consisting of a metal ion-neutralized product of a binary copolymer, (a-3) a ternary copolymer composed of an olefin, an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and an ?,?-unsaturated carboxylic acid ester, and (a-4) an ionomer resin consisting of a metal ion-neutralized product of a ternary copolymer; and (B) an anionic surfactant containing sulfur. The present invention further provides a golf ball comprising a constituting member formed from the above golf ball resin composition.
    Type: Application
    Filed: November 23, 2011
    Publication date: June 28, 2012
    Inventors: Ryo Murakami, Kazuyoshi Shiga, Takahiro Shigemitsu
  • Publication number: 20120165120
    Abstract: An object of the present invention is to provide a golf ball resin composition excellent in resilience. Another object of the present invention is to provide a golf ball excellent in a shot feeling and resilience. The present invention provides a golf ball resin composition having the spin-lattice relaxation time (T1) of 13C nucleus measured by a High resolution solid state carbon nuclear magnetic resonance (NMR) method of 7.3 seconds or shorter.
    Type: Application
    Filed: November 23, 2011
    Publication date: June 28, 2012
    Inventors: Kazuyoshi SHIGA, Ryo Murakami, Hideaki Kimura, Tomoka Kitago, Takahiro Shigemitsu
  • Publication number: 20120165122
    Abstract: The present invention relates to golf ball where at least one of the outer cover layer and the intermediate layer (if present) includes a blend composition of about 2 to about 40 wt % of a polyamide and about 60 to about 98 wt % of one or more of either a block copolymer, an acidic copolymer; an acidic terpolymer; an ionomer, or a multi component blend composition (“MCBC”); and where the polyamide has a melting point which is greater than about 5 and less than about 200° C. above the melting point of the other blend component.
    Type: Application
    Filed: December 19, 2011
    Publication date: June 28, 2012
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20120157231
    Abstract: Golf balls containing a core having at least one layer and cover having at least one layer are provided. A thermoplastic ionomeric composition is used to form at least one layer of the ball. The composition is prepared by providing a masterbatch comprising cycloalkene (polyalkenamer) rubber and neutralizing agent and mixing the masterbatch with ethylene acid copolymer. The acid groups are neutralized to 30 weight percent or greater, preferably 50% or greater, and more preferably 70% or greater. The resulting ball has high resiliency and rebounding properties along with a soft feel.
    Type: Application
    Filed: December 20, 2010
    Publication date: June 21, 2012
    Inventors: Mark L. Binette, Brian Comeau, Douglas S. Goguen, Robert Blink, Michael J. Sullivan, David A. Bulpett