Diverse Layer Between Spherical Core And Cover Patents (Class 473/373)
  • Patent number: 7563180
    Abstract: In the present invention, by optimizing the balance of Shore D hardness between the intermediate layer and the cover, the balance of Shore D hardness between the surface and the center in the core, the balance of initial velocity between the core and the sphere, and the balance of Deflection amount between the core and the sphere are optimized, and the total thickness of the intermediate layer and the cover, the inventive golf ball is given a good profile of rebound, feel, controllability and durability.
    Type: Grant
    Filed: April 20, 2007
    Date of Patent: July 21, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hideo Watanabe, Rinya Takesue, Junji Hayashi
  • Publication number: 20090170634
    Abstract: A golf ball comprising: (a) a core; (b) an inner mantle layer; (c) an intermediate mantle layer; (d) an outer mantle layer; and (e) at least one cover layer; wherein the core has a PGA compression of less than 70, and the core/inner mantle layer/intermediate mantle layer combined construct has a PGA compression of at least 30.
    Type: Application
    Filed: December 23, 2008
    Publication date: July 2, 2009
    Inventors: Eric M. Loper, Dean A. Snell
  • Publication number: 20090170635
    Abstract: A method of making a golf ball comprising the steps of providing an untreated golf ball core comprising a thermoset rubber composition, the untreated golf ball core comprising an untreated outer surface having a hardness; treating the untreated outer surface of the untreated golf ball core with a surface-softening material comprising at least one fatty acid or fatty acid salt composition to form a golf ball core comprising a treated outer surface having a hardness less than the hardness of the untreated outer surface; and forming at least one cover layer about the core to form the golf ball. Also, the untreated core may comprise a geometric center and an untreated outer surface, each having a hardness such that the hardness of the treated outer surface is less than both the hardness of the untreated geometric center and the hardness of the untreated outer surface.
    Type: Application
    Filed: February 27, 2009
    Publication date: July 2, 2009
    Inventors: Michael J. Sullivan, Mark L. Binette, Brain Comeau
  • Patent number: 7550535
    Abstract: In a golf ball composed of a core and a cover having a plurality of layers that encloses the core, at least a first layer of the cover is formed primarily of a heated mixture of (A) a metal ion neutralization product of an olefin-unsaturated carboxylic acid copolymer and/or a metal ion neutralization product of an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer, (B) at least one type of olefin-unsaturated carboxylic acid copolymer and/or olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having the same content of unsaturated carboxylic acid as component A, and (C) a thermoplastic polyurethane elastomer; and at least one other cover layer adjoining the at least first cover layer is formed primarily of a non-ionomeric thermoplastic elastomer.
    Type: Grant
    Filed: November 3, 2005
    Date of Patent: June 23, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventor: Rinya Takesue
  • Patent number: 7549936
    Abstract: A multilayer golf ball with at least one layer made from an expandable polymeric composition is disclosed. In accordance to one aspect of the invention, the expandable polymeric composition comprises a film-forming binder polymer latex, a dispersing agent, a plurality of polyspheres encapsulating expandable volatile substance, and at least one additive. The additive can be a defoaming agent, a solvent, a thickener, a plasticizer, or any combination thereof. Another expandable polymeric composition comprises a curable silicone composition comprising a liquid diorganopolysiloxane, a liquid organosilicon compound, a condensation catalyst and a blowing agent. Another the expandable polymeric composition comprises an aqueous acrylic based latex emulsion and an unencapsulated blowing agent.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: June 23, 2009
    Assignee: Acushnet Company
    Inventors: Derek A. Ladd, Matthew F. Hogge
  • Publication number: 20090156330
    Abstract: Disclosed herein is a multi-layer golf ball having a soft outer cover. The golf ball has an inner cover layer with a Shore D hardness of 60 or more, and an outer cover with a Shore D hardness of 55 or less, and more preferably 50 or less. In a particularly preferred form of the invention, the outer cover comprises one or more polyurethane materials. The golf ball of the invention has exceptionally soft feel and high spin rates on short shots of 80 yards or less, and particularly, 40 yards or less, while maintaining good distance and average spin on full shots.
    Type: Application
    Filed: February 23, 2009
    Publication date: June 18, 2009
    Applicant: CALLAWAY GOLF COMPANY
    Inventors: THOMAS J. KENNEDY, III, MICHAEL J. TZIVANIS, VIKTOR KELLER, WILLIAM M. RISEN, JR., MARK L. BINETTE, JOHN L. NEALON
  • Publication number: 20090137341
    Abstract: An all rubber golf ball with one or more thermosetting rubber core layers and one or more thermosetting rubber cover layer. At least one of the ball's layers has moisture vapor barrier property, and in one aspect the moisture vapor barrier layer is an intermediate layer. In one embodiment, the thermosetting rubber layers follow a cis- or a trans-polybutadiene gradient from the center of the ball to its cover.
    Type: Application
    Filed: January 29, 2009
    Publication date: May 28, 2009
    Inventors: Eric D. Bartsch, Michael J. Sullivan
  • Patent number: 7534838
    Abstract: An ionomer modified by an amine-functionalized chemical for use in sporting equipment. The ionomer modified by an amine-functionalized chemical facilitates high COR, compression, durability, and ease of processing.
    Type: Grant
    Filed: May 12, 2004
    Date of Patent: May 19, 2009
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Patent number: 7534834
    Abstract: This invention is directed to A composition for forming a golf ball, the composition comprising polyurethane gel composite particles and at least one base material selected from the group consisting of synthetic resins and elastomers, the polyurethane gel composite particles consisting of colloidal polyurea particles precipitated from a non-aqueous solvent solution of colloidal polyurea and polyurethane gel particles covered with the polyurea particles, the polyurethane gel particles being three-dimensionally crosslinked and each of the polyurethane gel particles being formed of a polyisocyanate compound and a polyethylene oxide group-free, active-hydrogen-containing compound, at least one of the compounds being trifunctional or higher valency, and is also directed to a multi-piece golf ball having one or more layers formed of this composition.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: May 19, 2009
    Assignee: Mizuno Corporation
    Inventors: Kenji Onoda, Masao Ogawa, Yuri Naka, Norikazu Ninomiya
  • Publication number: 20090124416
    Abstract: A golf ball comprising a thermoplastic inner core layer that has a geometric center hardness greater than its surface hardness to define a “negative” hardness gradient. An outer core layer is disposed about the inner core and is formed from a substantially homogenous thermoset composition, typically rubber, and has an inner surface hardness substantially less than its outer surface hardness to define a “positive” hardness gradient. An inner cover layer is disposed about the outer core layer and an outer cover layer is disposed about the inner cover layer. The “negative” hardness gradient of the inner core is typically ?1 to ?5 Shore C and the “positive” hardness gradient of the core layer is typically at least 25 Shore C. The difference between the inner core surface hardness and the outer core inner surface hardness, ?h, should be at least 25 Shore C.
    Type: Application
    Filed: December 19, 2008
    Publication date: May 14, 2009
    Inventors: Michael J. Sullivan, Brian Comeau, William B. Lacy
  • Publication number: 20090124417
    Abstract: A golf ball comprising a thermoplastic inner core layer that has a geometric center hardness greater than its surface hardness to define a “negative” hardness gradient. An outer core layer is disposed about the inner core and is formed from a substantially homogenous thermoset composition, typically rubber, and has an inner surface hardness less than its outer surface hardness to define a “positive” hardness gradient. An inner cover layer is disposed about the outer core layer and an outer cover layer is disposed about the inner cover layer. The “negative” hardness gradient of the inner core is typically ?1 to ?5 Shore C and the “positive” hardness gradient of the core layer is less than 25 Shore C points. The difference between the inner core surface hardness and the outer core inner surface hardness, ?h, should be less than 25 Shore C points.
    Type: Application
    Filed: December 23, 2008
    Publication date: May 14, 2009
    Inventors: Michael J. Sullivan, Brian Comeau, William B. Lacy
  • Publication number: 20090124414
    Abstract: A golf ball comprising a thermoplastic inner core layer that has a geometric center hardness greater than its surface hardness to define a first “negative” hardness gradient. An outer core layer is disposed about the inner core and is formed from a substantially homogenous thermoset composition, typically rubber, and has an inner surface hardness greater than its outer surface hardness to also define a “negative” hardness gradient. An inner cover layer is disposed about the outer core layer and an outer cover layer is disposed about the inner cover layer. The “negative” hardness gradient of the inner core is typically ?1 to ?5 Shore C and the “negative” hardness gradient of the core layer is typically at least ?7 Shore C. The difference between the inner core surface hardness and the outer core inner surface hardness, ?h, should be at least ?3 Shore C.
    Type: Application
    Filed: December 16, 2008
    Publication date: May 14, 2009
    Inventors: Michael J. Sullivan, Brian Comeau, William B. Lacy
  • Publication number: 20090124415
    Abstract: A golf ball comprising a thermoplastic inner core layer that has a geometric center hardness greater than its surface hardness to define a first “negative” hardness gradient. An outer core layer is disposed about the inner core and is formed from a substantially homogenous thermoset composition, typically rubber, and has an inner surface hardness greater than its outer surface hardness to also define a “negative” hardness gradient. An inner cover layer is disposed about the outer core layer and an outer cover layer is disposed about the inner cover layer. The “negative” hardness gradient of the inner core is typically ?1 to ?5 Shore C and the “negative” hardness gradient of the core layer is typically at least ?1 Shore C but less than ?7 Shore C. The difference between the inner core surface hardness and the outer core inner surface hardness, ?h, should be at least ?3 Shore C.
    Type: Application
    Filed: December 18, 2008
    Publication date: May 14, 2009
    Inventors: Michael J. Sullivan, Brian Comeau, William B. Lacy
  • Publication number: 20090124413
    Abstract: A golf ball including a thermoplastic core having an outer diameter of 1.51 inches to 1.59 inches; an outer cover layer; and an inner cover layer between the core and the outer cover layer. The thermoplastic core has been exposed to a gradient-initiating solution comprising a solvent, free radical initiator, and a reactive co-agent comprising a metal salt of an acrylic or methacrylic acid, a mono- or multi-functional acrylate or methacrylate, or having the chemical structure where R=linear, branched, or aromatic C1-C14 and n=1-5, such that the hardness of the outer surface is different than the hardness of the geometric center to define a positive or negative hardness gradient of 5 Shore C or greater.
    Type: Application
    Filed: November 14, 2007
    Publication date: May 14, 2009
    Inventors: Michael J. Sullivan, David A. Bulpett, Brian Comeau
  • Publication number: 20090118039
    Abstract: The present invention relates to a golf ball having a core, a cover of at least one layer encasing the core, and a surface on which a plurality of dimples are formed. The cover has an outermost layer with a thickness of at least 1.2 mm and a Shore D hardness of at least 50 but not more than 65. The ball surface has a lightness L value, expressed in the Lab color system as defined by JIS Z8730, of at least 89, an a value of at least 2 but not more than 10, and a b value of ?20 or above. Increasing the reddish coloring of a white golf ball enhances the fashionability of the ball and improves the way the ball looks and feels to the golfer when it is played.
    Type: Application
    Filed: November 2, 2007
    Publication date: May 7, 2009
    Applicant: Bridgestone Sports Co., Ltd.
    Inventor: Hirotaka Shinohara
  • Publication number: 20090118038
    Abstract: The present invention relates to a golf ball having a ball component made of a material molded under heat from a rubber composition which includes: (A) at least 1 wt % but less than 30 wt % of a modified polybutadiene which is obtained by a modification reaction wherein a polybutadiene having a vinyl content of from 0 to 2%, a cis-1,4 bond content of at least 80% and an active end is modified at the active end with at least one type of alkoxysilane compound, and which has a Mooney viscosity of less than 40, and (B) at least 70 parts by weight of a diene rubber other than ingredient A. The rubber composition additionally includes the following per 100 parts by weight of ingredients A and B combined: (C) from 10 to 50 parts by weight of an unsaturated carboxylic acid and/or a metal salt thereof, (D) from 5 to 80 parts by weight of an inorganic filler, and (E) from 0.1 to 10 parts by weight of an organic peroxide.
    Type: Application
    Filed: November 1, 2007
    Publication date: May 7, 2009
    Applicant: Bridgestone Sports Co., Ltd.
    Inventors: Jun Shindo, Takahiro Hayashi
  • Publication number: 20090118040
    Abstract: Disclosed are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compressions greater than 100. Also disclosed is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.
    Type: Application
    Filed: October 30, 2008
    Publication date: May 7, 2009
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventor: JAMES R. DE GARAVILLA
  • Publication number: 20090111610
    Abstract: The present invention provides a multi-piece solid golf ball having a core, an envelope layer encasing the core, an intermediate layer encasing the envelope layer, and a cover which encases the intermediate layer and has formed on a surface thereof a plurality of dimples. The core is formed primarily of a rubber material, the envelope layer and the intermediate layer are each formed primarily of the same or different resin materials, and the cover is formed primarily of a thermoplastic resin or a thermoplastic elastomer. The envelope layer, intermediate layer and cover have thicknesses which satisfy the condition: cover thickness<intermediate layer thickness<envelope layer thickness, and the condition: (cover thickness+intermediate layer thickness)<envelope layer thickness.
    Type: Application
    Filed: October 29, 2007
    Publication date: April 30, 2009
    Applicant: BRIDGESTONE SPORTS Co., LTD.
    Inventors: Hideo WATANABE, Akira Kimura
  • Publication number: 20090111608
    Abstract: The present invention provides a multi-piece solid golf ball having a core, an envelope layer encasing the core, an intermediate layer encasing the envelope layer, and a cover which encases the intermediate layer and has formed on a surface thereof a plurality of dimples. The core is composed overall of an inner layer and an outer layer which are each formed primarily of a rubber material, with the outer core layer being harder than the inner core layer. The envelope layer, intermediate layer and cover have respective thicknesses which satisfy the condition: cover thickness<intermediate layer thickness<envelope layer thickness, and have respective material hardnesses (Shore D hardness) which satisfy the condition: envelope layer material hardness<intermediate layer material hardness>cover material hardness. The golf ball has a lower spin rate on full shots with a driver, further increasing the distance traveled by the ball.
    Type: Application
    Filed: October 29, 2007
    Publication date: April 30, 2009
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventors: Hideo WATANABE, Akira Kimura
  • Publication number: 20090111611
    Abstract: The present invention provides a multi-piece solid golf ball having a core, an envelope encasing the core, an intermediate layer encasing the envelope, and a cover which encases the intermediate layer and has formed on a surface thereof a plurality of dimples. The envelope is composed of at least two layers. The core is formed primarily of a rubber material. The envelope, intermediate layer and cover are each formed primarily of the same or different resin materials. The envelope layers and the intermediate layer have a combined thickness which is at least 5.0 times thicker than the cover. An optimized surface hardness relationship exists between the core, a Sphere I composed of the core encased by the envelope layers, a Sphere II composed of the core encased by the envelope layers and the intermediate layer, and a Sphere III composed of the core encased by the envelope layers, the intermediate layer and the cover.
    Type: Application
    Filed: October 29, 2007
    Publication date: April 30, 2009
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventors: Akira Kimura, Hideo Watanabe
  • Publication number: 20090111609
    Abstract: The present invention provides a multi-piece solid golf ball having a core, an envelope layer encasing the core, an intermediate layer encasing the envelope layer, and a cover which encases the intermediate layer and has formed on a surface thereof a plurality of dimples. The core is composed overall of an inner layer and an outer layer which are each formed primarily of a rubber material, with the outer core layer being harder than the inner core layer. The envelope layer, intermediate layer and cover have respective thicknesses which satisfy the condition: cover thickness<intermediate layer thickness<envelope layer thickness, and have respective material hardnesses (Shore D hardness) which satisfy the condition: envelope layer material hardness<intermediate layer material hardness>cover material hardness. The golf ball has a lower spin rate on full shots with a driver, further increasing the distance traveled by the ball.
    Type: Application
    Filed: October 29, 2007
    Publication date: April 30, 2009
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventors: Hideo WATANABE, Akira KIMURA
  • Publication number: 20090111612
    Abstract: The present invention provides a three-piece solid golf ball having a core molded under heat from a specific rubber composition and inner and outer cover layers encasing the core. By optimizing the core deflection under a specific load and the overall thickness of the cover layers, by forming the inner cover layer of a highly neutralized ionomer resin composition, and by optimizing within specific ranges the Shore D hardnesses of the inner cover layer and the outer cover layer, the spin rate of the ball on shots with a driver can be sufficiently reduced, enabling an increased distance to be achieved.
    Type: Application
    Filed: October 31, 2007
    Publication date: April 30, 2009
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventors: Atsushi Nanba, Hiroshi Higuchi, Toru Ogawana
  • Patent number: 7517943
    Abstract: Compositions for golf balls including oxirane functional endcapped polymers and, in particular, compositions formed from polyurethane-based or polyurea-based prepolymers that are endcapped with an oxirane functional group. The oxirane functionality is opened with a suitable curing agent to provide a composition that has flexibility via the prepolymer backbone and stiffness via the oxirane functional endcaps.
    Type: Grant
    Filed: December 6, 2005
    Date of Patent: April 14, 2009
    Assignee: Acushnet Company
    Inventors: Manjari Kuntimaddi, Shenshen Wu, Murali Rajagopalan, Matthew F. Hogge, Steven R. Zawacky, Michael A. Mayo
  • Patent number: 7513837
    Abstract: A three-piece solid golf ball having a solid core, an intermediate layer enclosing the solid core, and a cover layer enclosing the intermediate layer and having a large number of dimples formed in its surface, characterized in that the core deforms as much as 2.6 to 3.2 mm under a load which changes from 10 kg to 130 kg, the cover layer is formed mainly from thermoplastic polyurethane such that it has a lower hardness than the intermediate layer, a surface hardness of the cover layer being 58 to 64 in terms of Shore D hardness, with the difference in hardness between the cover layer and the intermediate layer being 4 to 10 in terms of Shore D hardness, the intermediate layer and the cover layer have a total thickness of 2.2 to 3.0 mm, the cover layer has a thickness of 0.8 to 1.3 mm, and the dimples have at least four different diameters and/or depths, with the average depth being 0.125 to 0.150 mm, and amount to 250 to 390 in all.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: April 7, 2009
    Assignee: Bridgestone Sports Co., Ltd
    Inventors: Junji Umezawa, Kazufumi Tabata
  • Patent number: 7514505
    Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.
    Type: Grant
    Filed: August 3, 2005
    Date of Patent: April 7, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 7510487
    Abstract: A multi-piece solid golf ball comprises a core having a structure consisting of at least two layers and a cover on the core consisting of outer and inner cover layers. The core has a diameter in the range of 35 to 41 mm. The inner sphere of the core is formed of a rubber material based on polybutadiene and an outer layer is formed of a thermoplastic or rubber based material. The outer cover layer has a Shore D hardness of up to 53 degrees and lower than that of the outer cover layer. The ball's carry is comparable to conventional solid golf balls and spin receptivity is approximate to wound golf balls while the ball is durable and offers pleasant feel.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: March 31, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hisashi Yamagishi, Hiroshi Higuchi, Yasushi Ichikawa, Junji Hayashi
  • Patent number: 7510488
    Abstract: The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes from 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, from 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, an inorganic filler, and an antioxidant. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer has a thickness of from 0.5 to 1.9 mm, and a Shore D hardness at the surface of from 50 to 70.
    Type: Grant
    Filed: January 22, 2008
    Date of Patent: March 31, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroshi Higuchi, Hiroyuki Nagasawa
  • Patent number: 7494427
    Abstract: Disclosed herein is a multi-layer golf ball having a soft outer cover. The golf ball has an inner cover layer with a Shore D hardness of 60 or more, and an outer cover with a Shore D hardness of 55 or less, and more preferably 50 or less. In a particularly preferred form of the invention, the outer cover comprises one or more polyurethane materials. The golf ball of the invention has exceptionally soft feel and high spin rates on short shots of 80 yards or less, and particularly, 40 yards or less, while maintaining good distance and average spin on full shots.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: February 24, 2009
    Assignee: Callaway Golf Company
    Inventors: Thomas J. Kennedy, III, Michael J. Tzivanis, Viktor Keller, William M. Risen, Jr., Mark L. Binette, John L. Nealon
  • Publication number: 20090042669
    Abstract: The present invention is directed to an improved golf ball displaying the desired spin profile and having a generally rigid, thermoset polybutadiene outer core surrounding a relatively soft, low compression inner core. In general, this golf ball has an inner core and at least one outer core layer surrounding the inner core. The inner core has a hardness less than a hardness of the outer core and a specific gravity less than or equal to the outer core specific gravity. Overall the inner core compression and outer core are formulated to provide a combined overall core compression of greater than about 50, preferably greater than about 70. A cover layer is provided to surround and to cover the outer core layer.
    Type: Application
    Filed: October 17, 2008
    Publication date: February 12, 2009
    Inventors: Michael J. Sullivan, Derek A. Ladd, Antonio U. DeSimas
  • Publication number: 20090042668
    Abstract: A golf ball composition having a copolymer with an acid content modified by a nucleating agent is described. The nucleating agent modifies the flexural modulus of the acid copolymer.
    Type: Application
    Filed: October 17, 2008
    Publication date: February 12, 2009
    Inventor: Michael D. Jordan
  • Patent number: 7488779
    Abstract: A golf ball which is formed from a vulcanized rubber compound composed of 100 parts by weight of a rubber base material, 10 to 60 parts by weight of an unsaturated carboxylic acid and/or a metal salt thereof, 0.1 to 5 parts by weight of an organosulfur compound, 5 to 80 parts by weight of an inorganic filler, and 0.1 to 3 parts by weight of an organic peroxide, the rubber base material being composed of a first polybutadiene accounting for 50 to 95 wt % and a second polybutadiene accounting for 5 to 50 wt %, both polybutadiene being synthesized by using a rare earth element-based catalyst, the first polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) no lower than 50 and the second polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) no higher than 45. The golf ball is characterized by good rebound resilience and good workability with which it is produced.
    Type: Grant
    Filed: April 19, 2007
    Date of Patent: February 10, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroshi Higuchi, Nobuyuki Kataoka, Atsushi Nanba, Hiroto Sasaki
  • Publication number: 20090036232
    Abstract: The present invention provides a multi-piece solid golf ball having a core obtained by molding under heat a specific rubber composition and having a cover of at least three layers which is composed of a thermoplastic resin material and encases the core. By optimizing the deflection of the core under a specific load, optimizing the hardness at the center of the core and the hardnesses of the innermost cover layer, outermost cover layer and intermediate cover layer, setting the combined thickness of the cover layers to at least a specific value, and forming the innermost cover layer of a highly neutralized ionomer resin composition, the spin rate of the ball on shots taken with a driver can be significantly reduced, enabling the distance traveled by the ball to be increased. Moreover, the ball has a good feel on shots with a driver.
    Type: Application
    Filed: July 14, 2008
    Publication date: February 5, 2009
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventors: Atsushi Nanba, Tooru Ogawana, Hiroshi Higuchi
  • Publication number: 20090036231
    Abstract: The present invention provides a multi-piece solid golf ball having a core obtained by molding under heat a specific rubber composition and having a cover of at least three layers which encases the core. By optimizing the deflection of the core under a specific load, optimizing the hardness at the center of the core and the hardnesses of the innermost cover layer, outermost cover layer and intermediate cover layer, setting the combined thickness of the cover layers to at least a specific value, and forming the innermost cover layer of a highly neutralized ionomer resin composition, a sufficient reduction in the spin rate of the ball on shots taken with a driver can be achieved, enabling the distance traveled by the ball to be increased.
    Type: Application
    Filed: July 31, 2007
    Publication date: February 5, 2009
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventors: Atsushi Nanba, Toru Ogawana, Hiroshi Higuchi
  • Publication number: 20090036233
    Abstract: The present invention provides a multi-piece solid golf ball having a core obtained by molding under heat a specific rubber composition and having a cover of at least three layers which encases the core. By optimizing the deflection of the core under a specific load, optimizing the hardness at the center of the core and the hardnesses of the innermost cover layer, outermost cover layer and intermediate cover layer, setting the combined thickness of the cover layers to at least a specific value, and forming the innermost cover layer of a highly neutralized ionomer resin composition, a sufficient reduction in the spin rate of the ball on shots taken with a driver can be achieved, enabling the distance traveled by the ball to be increased.
    Type: Application
    Filed: August 1, 2008
    Publication date: February 5, 2009
    Applicant: Bridgestone Sports Co., Ltd.
    Inventors: Atsushi Nanba, Hiroshi Higuchi, Tooru Ogawana
  • Publication number: 20090023516
    Abstract: A golf ball including an inner core layer formed from a thermoset rubber composition and having a first surface hardness; a thermoplastic outer core layer having a second surface hardness, an inner surface hardness, and being formed from a copolymer of ethylene and an ?,?-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to fully-neutralize the acid groups of the copolymer; an inner cover layer; and an outer cover layer; wherein the first surface hardness is less than the second surface hardness by at least 5 Shore C and less than the inner surface hardness by at least 5 Shore C.
    Type: Application
    Filed: September 26, 2008
    Publication date: January 22, 2009
    Inventors: Murali Rajagopalan, Michael J. Sullivan
  • Publication number: 20090023517
    Abstract: A golf ball including an inner core layer formed from a thermoset rubber composition and having a first surface hardness; a thermoplastic outer core layer having a second surface hardness, an inner surface hardness, and being formed from a copolymer of ethylene and an ?,?-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to fully-neutralize the acid groups of the copolymer; an inner cover layer; and an outer cover layer; wherein the first surface hardness is substantially the same as the second surface hardness and the inner surface hardness.
    Type: Application
    Filed: September 26, 2008
    Publication date: January 22, 2009
    Inventors: Murali Rajagopalan, Michael J. Sullivan
  • Publication number: 20090011860
    Abstract: A golf ball includes an inner core layer formed from a first rubber composition having a first Shore D hardness; an intermediate core layer formed from a second rubber composition; and a thermoplastic outer core layer having a second Shore D hardness. The outer core layer includes a copolymer of ethylene and an ?,?-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to fully-neutralize the acid groups of the copolymer. An inner cover layer surrounds the multi-layer core and an outer cover layer is disposed about the inner cover layer. The inner core layer hardness differs from the outer core hardness by at least 10 points.
    Type: Application
    Filed: September 11, 2008
    Publication date: January 8, 2009
    Inventors: Michael J. Sullivan, Derek A. Ladd, Michael D. Jordan
  • Publication number: 20090011858
    Abstract: Disclosed herein is novel thermoplastic material and a golf ball utilizing the thermoplastic material. The golf ball (10) preferably comprises a core (12), a cover (16) and optionally a boundary layer (14). At least one of the core (12), cover (16) or boundary layer (14) of the golf ball (10) comprises the thermoplastic material. The thermoplastic material comprises a partially to highly neutralized blend of copolymers additionally comprising a fatty acid or fatty acid salt, and a heavy mass filler in an amount ranging from 10 parts by weight to 50 parts by weight of the material, with the heavy mass filler having a density greater than the copolymer. The golf ball component of the invention has soft feel and resilience that is maintained or improved.
    Type: Application
    Filed: July 22, 2008
    Publication date: January 8, 2009
    Applicant: CALLAWAY GOLF COMPANY
    Inventors: MARK L. BINETTE, THOMAS J. KENNEDY, III
  • Publication number: 20090011857
    Abstract: A golf ball including an inner core having a first outer surface and a geometric center, the inner core having a hardness of 35 to 55 Shore C; an outer core layer adjacent the inner core having a second outer surface and an inner surface, the outer core layer having a hardness of 55 to 90 Shore C; and a cover layer; wherein the hardness of the first outer surface is substantially the same as or lower than the hardness of the geometric center to define a first negative hardness gradient, and the hardness of the second outer surface is substantially the same as or lower than the hardness of the inner surface to define a second negative hardness gradient.
    Type: Application
    Filed: July 27, 2007
    Publication date: January 8, 2009
    Inventors: David A. Bulpett, Brian Comeau, Derek A. Ladd, Michael J. Sullivan
  • Publication number: 20090011859
    Abstract: A golf ball includes an inner core having a first outer surface and a geometric center and is formed from a first substantially homogenous formulation throughout such that the inner core has a hardness of 30 Shore C to 45 Shore C. An outer core layer is formed around the inner core and has a second outer surface and an inner surface and is formed from a second substantially homogenous formulation throughout such that the outer core layer has a hardness of 60 Shore C to 95 Shore C. A cover layer is formed around the outer core layer. The hardness of the first outer surface is lower than the hardness of the geometric center to define a negative hardness gradient, and the hardness of the second outer surface is greater than the hardness of the inner surface to define a positive hardness gradient.
    Type: Application
    Filed: August 6, 2008
    Publication date: January 8, 2009
    Inventors: David A. Bulpett, Brian Comeau, Derek A. Ladd, Michael J. Sullivan
  • Patent number: 7473192
    Abstract: This invention provides a multi-piece golf ball composed of a core, an intermediate layer enclosing the core, and a cover layer which encloses the intermediate layer and has on an outside surface thereof a plurality of dimples. The cover layer is harder than the intermediate layer. Letting A be the thickness of the intermediate layer, B be the thickness of the cover layer and C be the diameter of the core, 65?C/A?30 and 65?C/B?30. In addition, a specific gravity of the core ranges from 1.0 to 1.2, a specific gravity of the intermediate layer ranges from 0.88 to 1.00, and the ball has an initial velocity, as measured by a method set forth in the Rules of Golf using an initial velocity measuring apparatus of the same type as the USGA drum rotation-type initial velocity instrument, of at least 77.0 m/s.
    Type: Grant
    Filed: December 10, 2007
    Date of Patent: January 6, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Shinya Makino, Hideo Watanabe
  • Publication number: 20080318710
    Abstract: The present invention provides a golf ball material which is a thermoplastic ionomer blend composition of an acid-containing ethylene-based terpolymer having a weight-average molecular weight Mw of at least about 100,000, an acid-containing ethylene-based copolymer and/or terpolymer having a Mw of about 1,500 to about 95,000, and a low-molecular-weight acid-containing compound having a molecular weight of up to about 1,000, at least some portion of which composition is neutralized. The golf ball material is soft and resilient, and has a good durability and improved moldability.
    Type: Application
    Filed: June 19, 2007
    Publication date: December 25, 2008
    Applicant: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana, Kae Yamazaki
  • Publication number: 20080305890
    Abstract: The invention provides a multi-piece solid golf ball comprising a core, an envelope layer encasing the core, an intermediate layer encasing the envelope layer, and a cover which encases the intermediate layer and has formed on a surface thereof a plurality of dimples. The core is formed primarily of a rubber material, has a diameter of at least 31 mm, and has a hardness which gradually increases from a center to a surface thereof, the hardness difference in JIS-C hardness units between the core center and the core surface being at least 15 and, letting (I) be the average value for cross-sectional hardnesses at a position 15 mm from the core center and at the core center and letting (II) be the cross-sectional hardness at a position 7.5 mm from the core center, the hardness difference (I)-(II) therebetween in JIS-C units being not more than ±2. The envelope layer and the intermediate layer are each formed primarily of the same or different resin materials.
    Type: Application
    Filed: August 18, 2008
    Publication date: December 11, 2008
    Applicant: BRIDGESTONE SPORTS CO.,LTD
    Inventors: Hideo WATANABE, Akira Kimura
  • Publication number: 20080293517
    Abstract: A golf ball comprising a layer made from a liquid rubber composition is disclosed. A castable liquid polybutadiene is the preferred principal rubber component. The molecular weight of the castable liquid polybutadiene is at least about 1,000 and the castable liquid polybutadiene is in a liquid state at room temperature. The castable liquid rubber layer can be a cover layer, a casing layer, an intermediate layer or a core layer.
    Type: Application
    Filed: June 23, 2008
    Publication date: November 27, 2008
    Inventor: William E. Morgan
  • Publication number: 20080287217
    Abstract: A mixture having good thermal stability, flow and moldability and suitable as a golf ball-forming material is obtained when a base resin comprising a (metal ion-neutralized) olefin-unsaturated carboxylic acid-unsaturated carboxylate ternary random copolymer and optionally a (metal ion-neutralized) olefin-unsaturated carboxylic acid binary random copolymer is blended with specific proportions of a fatty acid and/or fatty acid derivative and a basic inorganic metal compound capable of neutralizing acidic groups left unneutralized in the base resin and fatty acid. Using the same material, high-rebound golf balls can be effectively manufactured.
    Type: Application
    Filed: July 22, 2008
    Publication date: November 20, 2008
    Inventors: Rinya Takesue, Yasushi Ichikawa
  • Patent number: 7452289
    Abstract: The present invention is directed to a golf ball having at least one layer formed from a moisture resistant, highly neutralized acid polymer composition. Highly neutralized acid polymers of the present invention are produced with a cation source selected from ions and compounds of lithium, ions and compounds of zinc, and combinations thereof. Golf balls of the present invention include one-piece, two-piece, multi-layer, and wound golf balls. The composition may be present in any one or more of a core layer, a cover layer, or an intermediate layer.
    Type: Grant
    Filed: August 31, 2006
    Date of Patent: November 18, 2008
    Assignee: Acushnet Company
    Inventor: Brian Comeau
  • Publication number: 20080274826
    Abstract: The present invention provides a golf ball composed of a core, an outermost cover layer and one or more intermediate layer therebetween. At least one intermediate layer includes a mixture composed of a base polymer made of, in a specific ratio, (a) a metal ion neutralization product of an olefin-unsaturated carboxylic acid random copolymer and/or a metal ion neutralization product of an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester random copolymer, (b) a thermoplastic elastomer selected from the group consisting of thermoplastic polyester elastomers, thermoplastic block copolymers and thermoplastic polyurethanes, and (c) a thermoplastic block copolymer containing end blocks modified by a functional group having reactivity with an ionomer resin, both end blocks being formed of different comonomers.
    Type: Application
    Filed: July 17, 2008
    Publication date: November 6, 2008
    Inventors: Toshihiko Manami, Hiroshi Higuchi
  • Patent number: 7445565
    Abstract: The invention provides a multi-piece solid golf ball having a rubber-based core encased by, in order, an intermediate layer and a cover. The core contains from 0.05 to 0.5 part by weight of sulfur per 100 parts by weight of the rubber base, has a hardness difference between the surface and center thereof, expressed in JIS-C hardness units, of at least 21 but not more than 30, and has a diameter of from 36 to 40 mm. The intermediate layer has a Shore D hardness of at least 47 but not more than 60, and a thickness of from 0.5 to 2.0 mm. The cover has a Shore D hardness of at least 53 but not more than 60, and a thickness of from 0.6 to 1.5 mm. The intermediate layer and cover satisfy the following condition: 120?(Shore D hardness of intermediate layer×thickness of intermediate layer)+(Shore D hardness of cover×thickness of cover)?150. The golf ball of the invention has, in particular, an excellent feel on impact and an excellent flight performance on shots taken with an iron.
    Type: Grant
    Filed: December 1, 2006
    Date of Patent: November 4, 2008
    Assignee: Bridgestone Sports Co., Ltd
    Inventor: Atsushi Komatsu
  • Patent number: 7442736
    Abstract: A golf ball composition having a copolymer with an acid content modified by a nucleating agent is described. The nucleating agent modifies the flexural modulus of the acid copolymer.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: October 28, 2008
    Assignee: Acushnet Company
    Inventor: Michael D. Jordan
  • Patent number: 7438651
    Abstract: The present invention is directed to an improved golf ball displaying the desired spin profile and having a generally rigid, thermoset polybutadiene outer core surrounding a relatively soft, low compression inner core. In general, this golf ball has an inner core and at least one outer core layer surrounding the inner core. The inner core has a hardness less than a hardness of the outer core and a specific gravity less than or equal to the outer core specific gravity. Overall the inner core compression and outer core are formulated to provide a combined overall core compression of greater than about 50, preferably greater than about 70. A cover layer is provided to surround and to cover the outer core layer. A moisture barrier layer is provided between the outer core layer and the cover layer to protect the inner and outer cores from degradation due to exposure to water.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: October 21, 2008
    Assignee: Acushnet Company
    Inventors: Michael J. Sullivan, Derek A. Ladd, Antonio U. DeSimas