Diverse Layer Between Spherical Core And Cover Patents (Class 473/373)
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Publication number: 20080254914Abstract: The present invention provides a golf ball composed of a core, an outermost cover layer and one or more intermediate layer therebetween. At least one intermediate layer includes a mixture composed of a base polymer made of, in a specific ratio, (a) a metal ion neutralization product of an olefin-unsaturated carboxylic acid random copolymer and/or a metal ion neutralization product of an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester random copolymer, (b) a thermoplastic elastomer selected from the group consisting of thermoplastic polyester elastomers, thermoplastic block copolymers and thermoplastic polyurethanes, and (c) a thermoplastic block copolymer containing end blocks modified by a functional group having reactivity with an ionomer resin, both end blocks being formed of different comonomers.Type: ApplicationFiled: April 13, 2007Publication date: October 16, 2008Applicant: BRIDGESTONE SPORTS CO., LTD.Inventors: Toshihiko Manami, Hiroshi Higuchi
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Publication number: 20080254913Abstract: A golf ball having at least a core and a composite layer comprising a fibrous material and a matrix material is disclosed. The fibrous material may comprise a polymer, glass or metal. The matrix material preferably comprises a translucent polymer. In one embodiment of the present invention, the fibrous material comprises a ferromagnetic material and the golf ball is subjected to induction heating to improve adhesion between adjacent ball layers. The golf ball may additionally comprise a translucent cover layer surrounding the composite layer or an intermediate layer disposed between the composite layer and the core.Type: ApplicationFiled: June 23, 2008Publication date: October 16, 2008Inventor: William E. Morgan
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Publication number: 20080248898Abstract: A golf ball with at least one core layer, at least one intermediate layer, and at least one cover layer. Any combination of the layers of the golf ball may feature a visually enhancing means. The cover layer is preferably translucent and provides a view to the intermediate layer and/or the core layer. The intermediate layer has a non-uniform thickness. The core may comprise a non-spherical insert. The intermediate layer and the core layer may affect the spin rate of the golf ball. The intermediate layer may be used to indicate the alignment of the golf ball.Type: ApplicationFiled: June 17, 2008Publication date: October 9, 2008Inventors: William E. Morgan, Michael J. Sullivan, Matthew F. Hogge
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Patent number: 7431669Abstract: A golf ball (20) in accordance with the principles of the present invention has a core (22) with a low compression, but has at least two additional layers (24, 26) that provide for increased durability and control. The core (22) is formed of a polybutadiene compound that produces a zero (or less) compression. The mantle (24) is molded around the core (22) using terpolymers, which are comprised of ethylene, acrylic acid and n-butyl acrylate, with 100% of the acrylic acid groups neutralized with metal ions. The mantle (24), when molded, yields a deflection of greater than 0.170 inches under an applied static load of 200 lb. This correlates to a PGA compression of between about ?20 and 15. The cover (26) is molded using conventional ionomers and “very low modulus” ionomers (V.L.M.I.), and has a hardness of between about 50 and 75 on a Shore D scale.Type: GrantFiled: March 11, 2005Date of Patent: October 7, 2008Assignee: Wilson Sporting Goods Co.Inventors: Lane D. Lemons, Frank M. Simonutti, Robert T. Thurman
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Patent number: 7427242Abstract: A golf ball comprising a thermoplastic core, the core having an outer diameter of 1.51 inches to 1.59 inches and having an outer surface and a geometric center, each having a hardness; an outer cover layer; and an inner cover layer disposed between the core and the outer cover layer; wherein the thermoplastic core has been exposed to a gradient-initiating solution comprising sufficient amount of plasticizer such that the hardness of the outer surface is less than the hardness of the geometric center to define a “negative” hardness gradient of 5 Shore C or greater.Type: GrantFiled: November 14, 2007Date of Patent: September 23, 2008Assignee: Acushnet CompanyInventors: Michael J. Sullivan, David A. Bulpett, Brian Comeau
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Publication number: 20080220900Abstract: The invention provides a golf ball composed of a core, an intermediate layer which encases the core, and a cover which encases the intermediate layer. The core has a diameter of 36 to 40 mm and a deflection of 3.5 to 4.2 mm, and the intermediate layer has a Shore D hardness of 45 to 55 and a thickness of 0.6 to 1.6 mm. The cover has a Shore D hardness of 63 to 66 and a thickness of 0.6 to 1.6. The ball as a whole has a deflection of 2.6 to 3.5 mm, and the intermediate layer and cover have a combined thickness of 1.8 to 2.8 mm. The ball has a hardness design such that the Shore D hardnesses of the ball components satisfy the relationship core center?core surface?intermediate layer?cover, and the cover is made of a material composed primarily of a thermoplastic resin or a thermoplastic elastomer. The intermediate layer is made of a material that is a resin composition in which at least 90 mol % of the acid groups are neutralized.Type: ApplicationFiled: May 12, 2008Publication date: September 11, 2008Applicant: Bridgestone Sports Co., Ltd.Inventor: Atsushi KOMATSU
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Publication number: 20080207354Abstract: A golf ball is provided. The golf ball includes a hollow metal core made from a work-hardened metal alloy. The golf also includes a mantle layer enveloping the metal core. The mantle layer may be made from a mixture of long-ball resin and soft-ball resin. The golf ball further includes a cover positioned about the mantle layer to protect the mantle layer. A method of manufacturing the golf ball is also provided.Type: ApplicationFiled: February 27, 2007Publication date: August 28, 2008Inventors: Douglas DuFaux, Timothy Owens
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Publication number: 20080194358Abstract: The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, an inorganic filler, and an antioxidant. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer is formed primarily of a polyurethane material and has a thickness of 0.5 to 2.5 mm, a Shore D hardness at the surface of 50 to 70 and a flexural rigidity of 50 to 300 MPa.Type: ApplicationFiled: January 22, 2008Publication date: August 14, 2008Applicant: Bridgestone Sports Co., Ltd.Inventor: Hiroshi Higuchi
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Publication number: 20080194357Abstract: The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, and an inorganic filler. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer is formed primarily of a thermoplastic or thermoset polyurethane material and has a thickness of 0.5 to 2.5 mm, a Shore D hardness at the surface of 50 to 70 and a flexural rigidity of 50 to 300 MPa.Type: ApplicationFiled: February 13, 2007Publication date: August 14, 2008Applicant: BRIDGESTONE SPORTS CO., LTD.Inventor: Hiroshi Higuchi
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Publication number: 20080194359Abstract: The invention provides a solid golf ball having a solid core and a cover layer that encases the core and has an outermost layer on an outside surface of which are formed a plurality of dimples. The solid core is formed of a rubber composition composed of 100 parts by weight of a base rubber that includes from 60 to 100 parts by weight of a polybutadiene rubber having a cis-1,4 bond content of at least 60% and synthesized using a rare-earth catalyst, from 0.1 to 5 parts by weight of an organosulfur compound, an unsaturated carboxylic acid or a metal salt thereof, an inorganic filler, and an antioxidant. The solid core has a deformation, when compressed under a final load of 130 kgf from an initial load of 10 kgf, of from 2.0 to 4.0 mm, and has a specific hardness distribution. The cover layer has a thickness of from 0.5 to 1.9 mm, and a Shore D hardness at the surface of from 50 to 70.Type: ApplicationFiled: January 22, 2008Publication date: August 14, 2008Applicant: Bridgestone Sports Co., Ltd.Inventors: Hiroshi Higuchi, Hiroyuki Nagasawa
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Patent number: 7407450Abstract: A method for making a multilayer golf ball including a solid center having a center hardness, a plurality of laminates cut into a plurality of shapes formed around the center to create an inner ball, and a cover formed around the inner ball, wherein the plurality of layers can include at least a first layer having a hardness greater than the center hardness and a second layer having a hardness greater than the first layer hardness, and optionally a third layer disposed between the first and the second layers having a hardness greater than the first layer hardness.Type: GrantFiled: May 2, 2005Date of Patent: August 5, 2008Assignee: Acushnet CompanyInventors: Jeffrey L. Dalton, Herbert C. Boehm, Christopher Cavallaro
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Patent number: 7402271Abstract: A golf ball comprising a layer made from a liquid rubber composition is disclosed. A castable liquid polybutadiene is the preferred principal rubber component. The molecular weight of the castable liquid polybutadiene is at least about 1,000 and the castable liquid polybutadiene is in a liquid state at room temperature. The castable liquid rubber layer can be a cover layer, a casing layer, an intermediate layer or a core layer.Type: GrantFiled: December 1, 2004Date of Patent: July 22, 2008Assignee: Acushnet CompanyInventor: William E. Morgan
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Patent number: 7402114Abstract: Disclosed herein is novel thermoplastic material and a golf ball utilizing the thermoplastic material. The golf ball (10) preferably comprises a core (12), a cover (16) and optionally a boundary layer (14). At least one of the core (12), cover (16) or boundary layer (14) of the golf ball (10) comprises the thermoplastic material. The thermoplastic material comprises a partially to highly neutralized blend of copolymers additionally comprising a fatty acid or fatty acid salt, and a heavy mass filler in an amount ranging from 10 parts by weight to 50 parts by weight of the material, with the heavy mass filler having a density greater than the copolymer. The golf ball component of the invention has soft feel and resilience that is maintained or improved.Type: GrantFiled: January 15, 2007Date of Patent: July 22, 2008Assignee: Callaway Golf CompanyInventors: Mark L. Binette, Thomas J. Kennedy, III
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Publication number: 20080171616Abstract: The present invention is directed to a golf ball (1) having one or more nanostructured materials, i.e., materials with at least one dimension in the 1-100 nm range. The nanostructured materials are present within the hollow metal core (3), a surrounding polymer layer (4), or both. More particularly, the golf ball (1) may include a sphere comprising a nanostructured steel, a polymer comprising a nanoclay material, or both, which improve durability and performance. The present invention is also directed to a method for making the improved golf ball.Type: ApplicationFiled: June 23, 2006Publication date: July 17, 2008Inventors: Douglas DuFaux, Timothy M. Owens
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Patent number: 7396300Abstract: Disclosed is a process to increase adhesion between two adjacent layers. The process comprises roughening the surface of one layer followed by chlorination of the roughened surface and joining of the layers, or treating the surface of one layer with a silicone-based adhesion promoter and joining the layers. In one preferred embodiment the process comprises roughening the surface of one layer, followed by chlorination of the roughened surface, joining of the layers and post-treatment of the molded layers at an elevated temperature for a predetermined time.Type: GrantFiled: June 24, 2003Date of Patent: July 8, 2008Assignee: Callaway Golf CompanyInventors: Michael J. Tzivanis, William M. Risen, Jr., Robert A. Weiss, Thomas J. Kennedy, III, David M. Melanson
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Patent number: 7396301Abstract: The present invention provides a golf ball comprising a core, an intermediate layer covering the core, and a cover covering the intermediate layer, wherein the intermediate layer contains a 3-dimensional shaped metal oxide having at least three needle-shaped parts. Blending the 3-dimensional shaped metal oxide into the intermediate layer enhances the rigidity of the resultant intermediate layer and the hardness thereof. Making use of this property, it is possible to improve the durability, the flight performance and the shot feeling of the golf ball.Type: GrantFiled: August 24, 2006Date of Patent: July 8, 2008Assignee: SRI Sports LimitedInventors: Keiji Ohama, Kazuhiko Isogawa
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Patent number: 7390852Abstract: In a multi-piece solid golf ball comprising a solid core, a mantle and a cover, the solid core is made of a rubber composition that includes a base rubber containing a polybutadiene synthesized using a rare-earth catalyst, a small amount of organic peroxide, an unsaturated carboxylic acid and/or a metal salt thereof, an organic sulfur compound and an inorganic filler. The mantle is made of a thermoplastic resin composition. The cover is made primarily of a thermoplastic polyurethane material. This construction provides the golf ball with a combination of outstanding flight performance and soft feel with cover's scuff resistance and coating's abrasion resistance, that is unprecedented.Type: GrantFiled: August 11, 2006Date of Patent: June 24, 2008Assignee: Bridgestone Sports Co., Ltd.Inventors: Junji Hayashi, Yasumasa Shimizu, Hiroshi Higuchi, Yasushi Ichikawa
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Patent number: 7390542Abstract: The golf ball includes a core, an intermediate layer for covering the core and a cover layer for covering the intermediate layer, wherein the intermediate layer is formed of a resin composition containing a cation-treated phillosilicate and having a Shore D hardness of 56 or higher. This intermediate layer provides the golf ball excellent in ball distance at a driver shot and in controllability at an iron shot.Type: GrantFiled: August 17, 2005Date of Patent: June 24, 2008Assignee: SRI Sports Ltd.Inventors: Keiji Ohama, Takashi Sasaki
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Publication number: 20080146376Abstract: The invention provides a multi-piece solid golf ball having a core, an envelope layer which encases the core and is composed of an inside layer and an outside layer, an intermediate layer encasing the envelope layer, and a cover which encases the intermediate layer and has formed on a surface thereof a plurality of dimples. The core is formed primarily of a rubber material, and the envelope layer, intermediate layer and cover are each formed primarily of the same or different resin materials. The envelope layer, intermediate layer and cover have thicknesses which satisfy the relationship: cover thickness<intermediate layer thickness<envelope layer total thickness. The envelope layer, intermediate layer and cover have material hardnesses (Durometer D hardness) which satisfy the relationship: hardness of envelope inside layer material<hardness of envelope outside layer material<hardness of intermediate layer material>hardness of cover material.Type: ApplicationFiled: December 13, 2006Publication date: June 19, 2008Applicant: BRIDGESTONE SPORTS CO., LTD.Inventor: Hideo Watanabe
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Patent number: 7388053Abstract: A perimeter weighted golf ball with a low compression core is provided. The core preferably comprises a diene polymer that has low cross-link density or not cross-linked with a reactive co-agent. This core has low compression and low specific gravity. The low specific gravity core is encased within a thin dense layer positioned outside of the centroid radius to provide the ball with a high moment of inertia. The same core can be encased within a plurality of intermediate layers having either increasing hardness or decreasing hardness to provide selective golf balls for either low swing speed players or advanced players. Alternatively, a thin layer of diene polymer highly cross-linked with reactive a co-agent may be incorporated into the ball to increase the hardness of the ball.Type: GrantFiled: October 21, 2005Date of Patent: June 17, 2008Assignee: Acushnet CompanyInventors: Michael J Sullivan, Derek A Ladd, Peter R. Voorheis
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Publication number: 20080132358Abstract: The invention provides a multi-piece solid golf ball having a rubber-based core encased by, in order, an intermediate layer and a cover. The core contains from 0.05 to 0.5 part by weight of sulfur per 100 parts by weight of the rubber base, has a hardness difference between the surface and center thereof, expressed in JIS-C hardness units, of at least 21 but not more than 30, and has a diameter of from 36 to 40 mm. The intermediate layer has a Shore D hardness of at least 47 but not more than 60, and a thickness of from 0.5 to 2.0 mm. The cover has a Shore D hardness of at least 53 but not more than 60, and a thickness of from 0.6 to 1.5 mm. The intermediate layer and cover satisfy the following condition: 120?(Shore D hardness of intermediate layer×thickness of intermediate layer)+(Shore D hardness of cover×thickness of cover)?150. The golf ball of the invention has, in particular, an excellent feel on impact and an excellent flight performance on shots taken with an iron.Type: ApplicationFiled: December 1, 2006Publication date: June 5, 2008Applicant: BRIDGESTONE SPORTS CO., LTDInventor: Atsushi Komatsu
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Patent number: 7381776Abstract: The invention provides crosslinked rubber moldings for golf balls obtained by spherically molding and crosslinking a rubber composition containing a base rubber, a co-crosslinking agent and a crosslinking agent, then impregnating the crosslinked rubber molding with a rubber compounding chemical and inducing a chemical reaction. The rubber compounding chemical-impregnated crosslinked molding has a higher surface hardness than the crosslinked molding prior to impregnation. The invention also provides a method for manufacturing such crosslinked rubber moldings for golf balls. The invention enables a sufficient rise in the surface hardness of the core to be achieved, thus increasing the degree of freedom in the design of the golf ball.Type: GrantFiled: April 8, 2005Date of Patent: June 3, 2008Assignee: Bridgestone Sports Co., Ltd.Inventors: Atsushi Nanba, Jun Shindo
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Publication number: 20080125247Abstract: The present invention is directed to golf balls having at least one layer formed from a polyurea composition. The polyurea is formed by combining a polyurea prepolymer, a polyamine curative, and a tin catalyst. Golf balls of the present invention include one-piece, two-piece, multi-layer, and wound golf balls. The composition may be present in any one or more of a core layer, a cover layer, or an intermediate layer.Type: ApplicationFiled: December 27, 2007Publication date: May 29, 2008Inventors: Murali Rajagopalan, Shawn Ricci, Manjari Kuntimaddi, Shenshen Wu
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Patent number: 7375153Abstract: A golf ball including a solid core formed from a composition comprising a diene rubber, a metallic fatty acid salt present in an amount of from 6.3 parts to 7.5 parts, a cis-to-trans catalyst present in an amount of 2.35 parts or greater, and an organic peroxide present in an amount of 0.8 parts or less; and a cover; wherein the core has a coefficient of restitution of 0.810 or greater and a compression of 58 to 78.Type: GrantFiled: April 21, 2005Date of Patent: May 20, 2008Assignee: Acushnet CompanyInventors: Douglas S. Goguen, Michael J. Sullivan, David A. Bulpett, Murali Rajagopalan
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Patent number: 7375151Abstract: A thermoplastic composition is provided, comprising (a) an acid copolymer, (b) a salt of a high molecular weight, monomeric organic acid; (c) a thermoplastic resin; (d) a cation source; and (e) optionally, a filler. Also provided are one-, two- and three-piece golf balls, and multi-layered golf balls comprising the composition of the invention.Type: GrantFiled: October 12, 2004Date of Patent: May 20, 2008Assignee: E. I. du Pont de Nemours and CompanyInventors: Robert Joseph Statz, John Chu Chen, John Francis Hagman
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Patent number: 7365128Abstract: The present invention is directed to a golf ball having at least one layer which includes a polymer composition containing at least 50 wt % of an acid polymer and at least 0.5 wt % of a polyhydric alcohol, wherein the weight percentages are based on the total polymeric weight of the polymer composition. At least 70% of the acid groups of the acid polymer are neutralized by a cation source or a metal salt thereof.Type: GrantFiled: August 31, 2005Date of Patent: April 29, 2008Assignee: Acushnet CompanyInventor: Michael J. Sullivan
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Patent number: 7357733Abstract: A golf ball with at least one moisture vapor barrier layer is disclosed. The moisture vapor barrier layer is formed from a composition comprising a filler dispersed in a liquid or solven-born polymer of multi-olefin, iso-olefin, or a combination thereof.Type: GrantFiled: January 12, 2004Date of Patent: April 15, 2008Assignee: Acushnet CompanyInventors: Matthew F Hogge, Mitchell E Lutz, Michael J Sullivan
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Patent number: 7354357Abstract: The present invention is directed to an improved multi-layer golf ball displaying enhanced playing characteristics, including high speed, high launch, and low spin. In general the golf ball displays improved performance in areas such as distance and feel for lower swing speed players. The ball has a relatively large solid inner core, with at least one solid outer core layer surrounding the inner core, and a thin cover layer surrounding the outermost core layer. The inner core is softer than the outer core, which in turn is softer than the cover. The ball may be designed such that the coefficient of restitution (COR) gradient is from slow to fast; that is, the inner core has a lower COR than the total core, which has a lower COR than the entire golf ball.Type: GrantFiled: July 24, 2006Date of Patent: April 8, 2008Assignee: Acushnet CompanyInventors: Michael J. Sullivan, Derek A. Ladd, Edmund A. Hebert
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Publication number: 20080081710Abstract: A phase transition golf ball comprises a phase transition material. The phase transition material may optionally include a microwave susceptor or an induction susceptor. The phase transition material preferably comprises an ethylene acid copolymer, or an ionomer of an ethylene acid copolymer. The performance of the phase transition golf ball, for example its hardness or compression, is adjusted by inducing a complete or partial phase transition in the phase transition material. The extent of the adjustment in performance is correlated with the extent of the phase transition. Preferably, the phase transition is reversible and repeatable and takes place at temperatures that might be achieved through the use of common household appliances. Also preferably, the phase transition material returns to its original state over an extended period, for example hours or days.Type: ApplicationFiled: October 3, 2007Publication date: April 3, 2008Inventors: John Chu Chen, Janice V. Granato, Matthew S. Hall, Peter A. Morken
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Patent number: 7344454Abstract: A three-piece solid golf ball having a solid core, an intermediate layer enclosing the solid core, and a cover layer enclosing the intermediate layer and having a large number of dimples formed in its surface, characterized in that the core deforms as much as 3.4 to 4.1 mm under a load which changes from 10 kg to 130 kg, the intermediate layer has a surface hardness of 64 to 69 in terms of Shore D hardness, the cover layer is formed mainly from thermoplastic polyurethane such that it has a lower hardness than the intermediate layer, with the difference in hardness between the cover layer and the intermediate layer being 10 to 16 in terms of Shore D hardness, the intermediate layer and the cover layer have a total thickness of 2.2 to 3.0 mm, the cover layer has a thickness of 0.8 to 1.3 mm, and the dimples have at least four different diameters and/or depths, with the average depth being 0.14 to 0.17 mm, and amount to 250 to 390 in all.Type: GrantFiled: September 13, 2006Date of Patent: March 18, 2008Assignee: Bridgestone Sports Co., Ltd.Inventors: Junji Umezawa, Kazufumi Tabata
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Patent number: 7342073Abstract: The present invention is directed to resilient golf balls and portions thereof including compositions containing zinc dimethacrylate and zinc pentachlorothiophenol, and methods for making same. In particular, the present invention is directed to a golf ball having at least one of a center, cover, or intermediate layer that includes a reaction product that includes a resilient polymer component, a free radical source, zinc dimethacrylate and at least one halogenated organosulfur compound having the following general formula I: where R1-R5 can be substituted or unsubstituted C1-C8 alkyl groups; halogen groups; thiol groups (—SH), carboxylated groups; sulfonated groups; and hydrogen; in any order.Type: GrantFiled: December 22, 2003Date of Patent: March 11, 2008Assignee: Acushnet CompanyInventor: Peter R. Voorheis
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Publication number: 20080026873Abstract: The invention provides a golf ball having a core and a cover of one or more layer, wherein at least one layer of the cover is made of a material obtained by molding a mixture of (a) a metal ion neutralization product of an olefin-unsaturated carboxylic acid random copolymer having a Shore D hardness of at least 60; (b) an unsaturated fatty acid; and (c) a basic inorganic metal compound capable of neutralizing acid groups in components (a) and (b). The golf ball has both a good feel on impact and excellent scuff resistance while retaining a good flight performance.Type: ApplicationFiled: July 27, 2006Publication date: January 31, 2008Inventors: Toshihiko Manami, Eiji Takehana
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Patent number: 7322892Abstract: The present invention provides a golf ball having a resilient core made of rubber, a cover of one or more layer encasing the core, and at least one intermediate layer disposed between the core and the cover, wherein the cover is made primarily of polyurethane, the intermediate layer is made primarily of ionomer, and the core has a surface hardness which is higher than the material hardnesses of the cover and the intermediate layer. The golf ball is able to limit the distance of travel more than official balls currently in use and, in spite of being a limited-distance golf ball, imparts a relatively soft and good ball feel on impact, in addition to which it has an excellent scuff resistance and, by minimizing the extent of decrease in the distance traveled by the ball when hit with an iron, minimizes the effect on golf play by amateur golfers.Type: GrantFiled: August 15, 2006Date of Patent: January 29, 2008Assignee: Bridgestone Sports Co., Ltd.Inventor: Hideo Watanabe
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Patent number: 7314896Abstract: A golf ball comprising a core, an intermediate layer, and a cover. The core, which has a compression of 100 or less and a diameter of between about 1.00 inches and about 1.64 inches, is formed from a first polymer including an acid group fully-neutralized by a salt of an organic acid, a cation source, or a suitable base of the organic acid; and a nano-material having an average particle size of 100 nm or less, present in an amount sufficient to adjust at least one material property of the first polymer by 5% to 50% when compared to the material property of the first polymer comprising a material identical to the nano-material but having an average particle size greater than 1000 nm. The intermediate layer is formed from a second polymer comprising an acid group fully-neutralized by a salt of an organic acid, a cation source, or a suitable base of the organic acid.Type: GrantFiled: February 28, 2005Date of Patent: January 1, 2008Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Michael J. Sullivan
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Patent number: 7278929Abstract: A three-piece solid golf ball composed of a solid core, an intermediate layer which encloses the core, and a cover layer which encloses and is softer than the intermediate layer is characterized in that the solid core undergoes a deflection of 2.8 to 3.6 mm when a load of 130 kg is applied thereto from an initial load of 10 kg and has a surface hardness and a center hardness which differ by at least 15 Shore D hardness units; the intermediate layer has a surface hardness which differs from the surface hardness of the solid core by not more than 12 Shore D hardness units; and the cover layer has a surface hardness which differs from the surface hardness of the intermediate layer by at least 7 Shore D hardness units, is made primarily of a thermoplastic polyurethane, and has a thickness in a range of 0.5 to 1.3 mm. This combination of features provides an overall outstanding golf ball endowed with excellent flight characteristics, excellent controllability and durability, and a soft feel on impact.Type: GrantFiled: May 4, 2005Date of Patent: October 9, 2007Assignee: Bridgestone Sports Co., Ltd.Inventors: Junji Umezawa, Kazufumi Tabata, Hiroyuki Nagasawa, Yoshihiro Yamana, Hidekazu Saito, Hiroki Kimura
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Patent number: 7273424Abstract: A golf ball comprising a core having a Deflection amount of at least 3.0 mm and up to 6.0 mm, an intermediate layer, and a cover exhibits a good profile of rebound, feel and durability suited for low head speed amateur players when it satisfies the requirements that (Shore D hardness of the cover)?(Shore D hardness of the intermediate layer)>0, (initial velocity (in m/s) of the core enclosed with the intermediate layer)?(initial velocity (in m/s) of the core)>?0.2, 0.90?(Deflection amount of the core enclosed with the intermediate layer)/(Deflection amount of the core)?1.00.Type: GrantFiled: June 29, 2005Date of Patent: September 25, 2007Assignee: Bridgestone Sports Co., Ltd.Inventors: Hideo Watanabe, Junji Hayashi, Rinya Takesue
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Patent number: 7270613Abstract: A golf ball having a core, an intermediate layer enclosing the core and a cover enclosing the intermediate layer is characterized in that the intermediate layer and cover are each made from an ionomer resin-containing thermoplastic resin. The golf ball is also characterized in that the core has a diameter of at least 36.7 mm but not more than 40.7 mm, the core has a deflection when subjected to a load of 100 kg of at least 3.5 but not more than 6.0 mm, the intermediate layer has a thickness of at least 0.50 mm but not more than 1.40 mm, the intermediate layer has a Shore D hardness of at least 40 but not more than 55, the cover has a thickness of at least 0.50 mm but not more than 1.40 mm, the cover has a Shore D hardness of at least 60 but not more than 70, the golf ball has a deflection when subjected to a load of 100 kg of at least 2.8 mm but not more than 4.5 mm, and the deflection by the core under 100 kg load minus the deflection by the golf ball under 100 kg load is less than 1.0 mm.Type: GrantFiled: April 26, 2006Date of Patent: September 18, 2007Assignee: Bridgestone Sports Co., Ltd.Inventor: Junji Hayashi
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Patent number: 7271222Abstract: A golf ball comprising a center comprising a polybutadiene having a molecular weight of greater than 200,000 and a resilience index of at least about 40; and a cover layer comprising a polyurethane composition formed from a prepolymer having no greater than 7.5 percent by weight unreacted isocyanate groups.Type: GrantFiled: May 16, 2006Date of Patent: September 18, 2007Assignee: Acushnet CompanyInventors: Shenshen Wu, Edmund A. Hebert, Laurent Bissonnette, David A. Bulpett, Murali Rajagopalan, Peter Voorheis, Mark N. Wrigley
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Patent number: 7270612Abstract: A golf ball having a core, an intermediate layer enclosing the core and a cover enclosing the intermediate layer is characterized in that the core, the intermediate layer and cover is are each made from a specific material. The golf ball is also characterized in that the core has a diameter of at least 36.7 mm but not more than 40.7 mm, the core has a deflection when subjected to a load of 100 kg of at least 3.5 but not more than 6.0 mm, the intermediate layer has a thickness of at least 0.50 mm but not more than 1.50 mm, the intermediate layer has a Shore D hardness of at least 40 but not more than 55, the cover has a thickness of at least 0.50 mm but not more than 1.40 mm, the cover has a Shore D hardness of at least 60 but not more than 70, the golf ball has a deflection when subjected to a load of 100 kg of at least 2.8 mm but not more than 4.5 mm, and the deflection by the core under 100 kg load minus the deflection by the golf ball under 100 kg load is less than 1.0 mm.Type: GrantFiled: April 26, 2006Date of Patent: September 18, 2007Assignee: Bridgestone Sports Co., Ltd.Inventor: Junji Hayashi
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Patent number: 7270611Abstract: A golf ball comprising a core, an intermediate layer, and a cover exhibits a good profile of rebound, feel and durability suited for low head speed amateur players when it satisfies the requirements that (Shore D hardness of the cover)?(Shore D hardness of the intermediate layer)>0, (initial velocity (in m/s) of the core enclosed with the intermediate layer)?(initial velocity (in m/s) of the core)>?0.2, 0.90?(Deflection amount of the core enclosed with the intermediate layer)/(Deflection amount of the core)?1.00.Type: GrantFiled: June 29, 2005Date of Patent: September 18, 2007Assignee: Bridgestone Sports Co., Ltd.Inventors: Hideo Watanabe, Junji Hayashi, Rinya Takesue
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Patent number: 7261647Abstract: A golf ball including a core; a cover having a first water vapor transmission rate; and a vapor barrier layer disposed between the core and the cover, the barrier layer being formed from a polymer including a nano-material having an average particle size of 100 nm or less; wherein the nano-material creates a tortuous path across the barrier layer such that the barrier layer has a second water vapor transmission rate less than the first.Type: GrantFiled: February 18, 2005Date of Patent: August 28, 2007Assignee: Acushnet CompanyInventors: Michael J. Sullivan, Derek A. Ladd, William B. Lacy
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Patent number: 7255655Abstract: A golf ball comprising a spherical solid core covered by a spherical shell cover, the cover made of a composite material including one of a plastic and a rubber compounded with a metallic flake.Type: GrantFiled: August 4, 2003Date of Patent: August 14, 2007Assignee: Element 21 Corp.Inventor: Francis Joseph Gojny
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Patent number: 7247676Abstract: This invention is related to multi-layer golf balls having an inner cover layer comprising a blend of styrene-block copolymer and trans-polyisoprene, an outer cover layer comprising a polyurethane, a polyurea or a mixture thereof, and a core comprising of thermosetting or thermoplastic materials.Type: GrantFiled: October 4, 2004Date of Patent: July 24, 2007Assignee: Acushnet CompanyInventors: William E. Morgan, Michael J. Sullivan, Derek A. Ladd, Douglas E. Jones
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Patent number: 7244194Abstract: A golf ball including a core having a diameter of 0.5 inches to 1.4 inches, a compression of about 45 or less; and a coefficient of restitution of from 0.730 to 0.810; a cast polyurea cover; and an intermediate layer disposed between the core and the cover, the intermediate layer having a thickness of 0.11 inches or greater and being formed from a composition including a highly-neutralized acid polymer having a moisture vapor transmission rate of 8 g·mil/100 in2/day or less; wherein a combination of the core and the intermediate layer results in a compression of from about 70 to about 100, and the golf ball has a coefficient of restitution of from 0.805 to 0.820 when measured at an incoming velocity of 125 ft/s and greater than 0.75 when measured at an incoming velocity of 160 ft/s, and a compression of from 75 to 105.Type: GrantFiled: August 31, 2006Date of Patent: July 17, 2007Assignee: Acushnet CompanyInventor: Michael J. Sullivan
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Patent number: 7238737Abstract: Disclosed are thermoplastic compositions comprising partially or fully neutralized carboxylic acid-based ionomers modified with rosin or rosin derivatives and, optionally, organic acids and salts thereof. Methods of preparing the thermoplastic compositions are also provided. The thermoplastic compositions exhibit higher hardness and stiffness than typical ionomer compositions. Also disclosed are golf balls, sporting equipment, and other non-sport articles comprising said thermoplastic compositions and methods for their preparation.Type: GrantFiled: June 2, 2004Date of Patent: July 3, 2007Assignee: E. I. du Pont de Nemours and CompanyInventor: John Chu Chen
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Patent number: 7232384Abstract: A perimeter weighted golf ball with a low compression core is provided. The core preferably comprises a diene polymer that has low cross-link density or not cross-linked with a reactive co-agent. This core has low compression and low specific gravity. The low specific gravity core is encased within a thin dense layer positioned outside of the centroid radius to provide the ball with a high moment of inertia. The same core can be encased within a plurality of intermediate layers having either increasing hardness or decreasing hardness to provide selective golf balls for either low swing speed players or advanced players. Alternatively, a thin layer of diene polymer highly cross-linked with reactive a co-agent may be incorporated into the ball to increase the hardness of the ball.Type: GrantFiled: September 8, 2003Date of Patent: June 19, 2007Assignee: Acushnet CompanyInventors: Michael J Sullivan, Derek A Ladd, Peter R. Voorheis
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Patent number: 7230045Abstract: A golf ball comprising a single-layer core having a diameter of 0.10 inches to 1.50 inches, a PGA compression of 110 or less and, and comprising a copolymer of ethylene and an ?,?-unsaturated carboxylic acid, the acid being 100% neutralized by a salt of an organic acid, a cation source, or a suitable base of the organic acid; and a thermoplastic or thermoset cover comprising polyurethane, polyurea, epoxy resins, polyamides, polyesters, polycarbonates, or a copolymer comprising urethane and urea segments.Type: GrantFiled: October 6, 2004Date of Patent: June 12, 2007Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Michael J. Sullivan
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Patent number: 7226367Abstract: A golf ball comprises a solid core consisting of a center core and an outer core, wherein at least one of cores is made of a rubber composition comprising 100 parts by weight of a base rubber including. 60 to 100% by weight of a polybutadiene containing at least 60% by weight of cis-1,4-bond, having a Mooney viscosity (ML1+4 (100° C.)) of at least 52, and synthesized using a rare-earth catalyst, 10 to 60 parts by weight of an unsaturated carboxylic acid and/or a metal salt thereof, 5 to 80 parts by weight of an-inorganic filler, and an organic peroxide, and wherein the center core has a JIS-C hardness of 40 to 60 on its center and a JIS-C hardness of 55 to 75 on its surface and the difference therebetween is at least 10, the outer core is harder than the surface hardness of the center core, the cross-sectional hardness of 1 mm outside from the border between the center core and the outer core is from 65 to 85 on a JIS-C hardness, the surface of the outer core has a JIS-C hardness of 75 to 95.Type: GrantFiled: April 12, 2006Date of Patent: June 5, 2007Assignee: Bridgestone Sports Co., Ltd.Inventors: Hiroshi Higuchi, Nobuyuki Kataoka, Atsushi Nanba, Hiroyuki Nagasawa
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Patent number: 7211631Abstract: A golf ball comprising: a core comprising a polybutadiene rubber having a cis-content of greater than 90%, a crosslinking agent, and an initiator, the core having an ATTI compression of less than 20; an inner cover layer comprising ethylene, from 5 weight % to 30 weight % of an ?, ?-ethylenically unsaturated carboxylic acid, and from 5 weight % to 25 weight % of a softening comonomer; and a cover comprising ethylene and from 5 weight % to 35 weight % of an ?, ?-ethylenically unsaturated carboxylic acid; wherein 100% of the carboxylic acid groups of the inner cover layer are neutralized.Type: GrantFiled: September 12, 2005Date of Patent: May 1, 2007Assignee: Acushnet CompanyInventors: Peter R. Voorheis, Murali Rajagopalan
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Patent number: RE40118Abstract: A multi-piece solid golf ball includes a solid core, at least one intermediate layer, and a cover having at least one cover layer. The solid core has a compression deflection of 3.0 mm or more, the intermediate layer is mainly made from a thermoplastic resin and has a Shore D hardness of 45 to 55 and a specific gravity of 1.2 or less, and the cover has a Shore D hardness of 60 or more and a thickness of 1.6 to 2.3 mm. The golf ball further comprises a ratio of the compression deflection of a sphere composed of the solid core covered with the intermediate layer to the compression deflection of the solid core is more than 0.900 and less than 0.970; and a difference in JIS-C hardness between the surface and the center of the solid core is equal to or less than 5.Type: GrantFiled: February 27, 2004Date of Patent: February 26, 2008Assignee: Bridgestone CorporationInventors: Hideo Watanabe, Yasumasa Shimizu, Akira Kimura