Coal Patents (Class 48/101)
  • Patent number: 7083658
    Abstract: A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction.
    Type: Grant
    Filed: May 29, 2003
    Date of Patent: August 1, 2006
    Assignee: ALSTOM Technology Ltd
    Inventors: Herbert E. Andrus Jr., Michael S. McCartney
  • Patent number: 6911057
    Abstract: An apparatus for burning coal to produce substantially pure hydrogen for use in fuel cells, together with “sequestration ready” carbon dioxide and a stream of oxygen depleted air for powering gas turbines. The apparatus includes two fluidized bed reactors and a third transfer line reactor. The first reactor is supplied with coal particles or “char” and fluidized with high temperature steam. The second reactor is fluidized with high temperature steam and the third reactor is fluidized by compressed air. Solids circulated among these three reactors include a mixture of materials containing coal, calcium compounds (present as CaO, CaCO3 and mixtures thereof) and iron compounds (present as FeO, Fe2O3 and mixtures thereof).
    Type: Grant
    Filed: September 30, 2003
    Date of Patent: June 28, 2005
    Assignee: General Electric Company
    Inventor: Richard K. Lyon
  • Publication number: 20040261316
    Abstract: A PCPG (Pulverized Coal Pressurized Gasifier) including improved fuel distribution means among burners, better burner feeding, enhanced flame retention burner, and improved process control. The flame retention burner has a both a rapidly spinning air flow to create a tornado effect plus a Coanda effect from the swirled air causing traverse eddies into the burning air/fuel mixture and induced circulation eddies of hot gas to prolong exposure of coal particles to hot flame conditions near the ignition area to achieve increased multiple chances to mate air with coal particles. This burner coupled to individualized fuel feed and precise measurements and controls and two-stage PCPG entrained flow and ash bed reactor spaces minimizes carbon in the ash and maximizes gas-making efficiency.
    Type: Application
    Filed: April 20, 2004
    Publication date: December 30, 2004
    Inventor: Lloyd E. Weaver
  • Publication number: 20040244289
    Abstract: The present invention relates to a combustible gas reforming method, a combustible gas reforming apparatus, and a gasification apparatus for gasifying a combustible material such as coal, biomass, municipal wastes, industrial wastes, RDF (refuse-derived fuel), waste plastics, and the like, and reforming a generated combustible gas. According to a combustible gas reforming method of the present invention, combustibles are gasified in a gasification apparatus (11), a generated gas (GA) produced by gasifying the combustibles is reformed in a gas reforming apparatus (12) using a catalyst to produce a product gas (GB), and a catalyst (CA′) degraded by the gas reforming apparatus (11) is regenerated in a catalyst regenerating apparatus (13). Waste heat (TP) of the combustible gas reforming process is used as heat to regenerate the catalyst in the catalyst regenerating apparatus (13).
    Type: Application
    Filed: March 26, 2004
    Publication date: December 9, 2004
    Inventors: Fumiaki Morozumi, Katsutoshi Naruse, Kaori Sasaki, Yuki Iwadate
  • Patent number: 6827751
    Abstract: An apparatus which is capable of supporting a process for gasifying a variety of hydrocarbon-containing materials. The resulting hydrogen-containing gas is suitable for use in various combustion processes and for petrochemical processes. A hydrocarbon-containing material is mixed with natural gas (or other suitable hydrocarbon gas) under pressure. The suspended material and gas are then injected under pressure into an acceleration/gasification tube. Intense heat (provided by an external energy source) is applied to the mixture as it travels through this tube, resulting in the cracking of the hydrocarbon chains and the release of additional energy. The released bond energy, along with the addition of the external energy, rapidly expands the gas and causes the velocity of the moving mixture to rise sharply as it proceeds down the tube. The acceleration/gasification tube is connected to a diffuser, which is essentially an expansion nozzle with a series of heat exchangers to cool the rapidly expanding gas.
    Type: Grant
    Filed: October 28, 2003
    Date of Patent: December 7, 2004
    Inventors: Thomas W. Kaufman, Verner Christensen
  • Publication number: 20040237404
    Abstract: A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction.
    Type: Application
    Filed: May 29, 2003
    Publication date: December 2, 2004
    Applicant: ALSTOM (Switzerland) Ltd
    Inventors: Herbert E. Andrus, Michael S. McCartney
  • Publication number: 20040231243
    Abstract: An ash melting system of the present invention includes a slagging combustion furnace (10) for melting ash into molten slag; and a slag separating apparatus (50) for bringing the molten slag (121) discharged from the slagging combustion furnace into contact with slag cooling water (152) to produce water-quenched slag (122), and separating the water-quenched slag from the slag cooling water. The ash melting system further includes a gas blowing means for blowing air or inert gas (132) between a slag discharge port (14) of the slagging combustion furnace and the surface of the slag cooling water.
    Type: Application
    Filed: January 30, 2004
    Publication date: November 25, 2004
    Inventors: Chikao Goke, Nobuya Azuma, Masaaki Irie, Kazuo Takano, Tetsuhisa Hirose, Kazuaki Watanabe
  • Publication number: 20040182003
    Abstract: Facility for producing synthesis gas from a solid feedstock including organic matter, said facility including means for circulating a heat-carrying solid providing the heat necessary for such production, and several stages including gasification means (Z1, Z3), intermediate separation means (Z2, Z4) for separating the effluents coming from each stage, and combustion means (Z5).
    Type: Application
    Filed: February 24, 2004
    Publication date: September 23, 2004
    Inventors: Jerome Bayle, Eric Marty
  • Publication number: 20040182001
    Abstract: Tire pyrolysis systems and processes are provided which include feeding tire shreds to a pyrolysis reactor, pyrolyzing the shreds in a pyrolysis reactor to produce a hydrocarbon-containing gas stream and carbon-containing solid, removing the carbon-containing solid from the reactor, directing the hydrocarbon-containing gas stream into a separator, contacting the hydrocarbon-containing gas stream with an oil spray in the separator thereby washing particulate from the hydrocarbon-containing gas stream and condensing a portion of the gas stream to oil, removing and cooling the oil from the separator, directing non-condensed gas from the gas stream away from the separator, and directing a portion of the cooled oil removed from the separator to an inlet of the separator for use as the separator oil spray.
    Type: Application
    Filed: January 30, 2004
    Publication date: September 23, 2004
    Applicant: Renaissance Recycling, Inc.
    Inventors: Blaine Masemore, Robert Zarrizski
  • Publication number: 20040107638
    Abstract: An apparatus and method for starved air gasification of solid organic materials, including biomass and other wastes, to convert the chemical energy stored in such materials to thermal energy or gaseous products that may be used in biochemical and/or chemical synthesis. Specifically, the system utilizes a gasifier having a “moving bed of ash” hearth wherein the feedstock is partially oxidized at a low temperature (less than 1500 degrees F.) in a square or rectangular chamber having a vaulted, tapered or flat roof. Combustion gases from the gasifier are held at temperature using a recovery and regeneration chamber, and then undergo secondary oxidation in an oxidizer. The high temperature gases produced by the system can be utilized to advantage, for example, as the thermal energy source for a conventional heat recovery device such as a heat exchanger, steam generator, hot oil or air heater, or steam boiler.
    Type: Application
    Filed: November 7, 2003
    Publication date: June 10, 2004
    Applicant: Nexterra Energy Corporation
    Inventors: Robert G. Graham, Jan Barynin
  • Patent number: 6746497
    Abstract: A waste is dry-distilled in a gasification furnace and generated combustible gas is combusted in a combustion furnace. A temperature in the combustion furnace is set to be substantially constant at a first preset temperature or more. When the temperature in the combustion furnace is greater than the first preset temperature by combustion of other fuels, the combustible gas is introduced. When the temperature in the combustion furnace reaches a second preset temperature or more by the combustion of only the combustible gas, the combustion of the other fuels is finished. When the temperature in the combustion furnace falls below a third preset temperature the combustion of the other fuels is resumed. When the temperature in the gasification furnace falls below a fourth preset temperature, the combustion of the other fuels is finished.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: June 8, 2004
    Assignee: Kinsei Sangyo Co., Ltd.
    Inventor: Masamoto Kaneko
  • Publication number: 20040060236
    Abstract: The present invention provides a relatively small scale apparatus for gasifying solid fuel in which pyrolysis gas produced in a pyrolyzer by thermal-decomposition reaction of the solid fuel can be reformed to crude fuel gas. The apparatus comprises a solid fuel pyrolyzer 1 and a steam reformer 5, and thermally decomposes the solid fuel with a combustion reaction of a low oxygen density to produce the pyrolysis gas, and reforms the pyrolysis gas to produce the crude fuel gas. The pyrolyzer has an air inlet 18 positioned at a bottom part thereof and upwardly blowing combustion air into the pyrolyzer; a bed of pyrolyzer 30 located above the air inlet; and a pyrolysis gas exit positioned at an upper part of a body of the pyrolyzer and conducting the pyrolysis gas out of the pyrolyzer. The bed is made by a layered stack of many spherical heat-resistant materials 32 which form a number of narrow gaps for draft of the combustion air over the whole bed.
    Type: Application
    Filed: July 17, 2003
    Publication date: April 1, 2004
    Inventors: Kunio Yoshikawa, Narumi Suzuki
  • Publication number: 20040060237
    Abstract: A process for burning coal to produce substantially pure hydrogen for use in fuel cells, together with “sequestration ready” carbon dioxide and a stream of oxygen depleted air for powering gas turbines, characterized by using a combination of two fluidized bed reactors and a third transfer line reactor, the first reactor being supplied with coal particles or “char” and fluidized with high temperature steam; the second reactor being fluidized with high temperature steam and the third reactor being fluidized by compressed air. Solids circulated among these three reactors include a mixture of materials containing calcium compounds (present as CaO, CaCO3 and mixtures thereof) and iron compounds (present as FeO, Fe2O3 and mixtures thereof). The coal is gasified by the steam in the presence of CaO to produce CaCO3 and relatively pure hydrogen for use in fuel cells per a CO2 acceptor process.
    Type: Application
    Filed: September 30, 2003
    Publication date: April 1, 2004
    Applicant: General Electric Company
    Inventor: Jerald A. Cole
  • Publication number: 20040055216
    Abstract: According to a method for gasifying solid materials (waste materials, biomass (wood), coal containing sulphur) in a fluidized bed (5), water vapour and oxygen are blown into the fluidized bed as gasifying agents. Small energy losses are achieved by strongly superheating the water vapour with hot reaction gases, the superheater functioning with a low differential pressure load. The reaction gases that leave the fluidized bed (5) are post-gasified in the open area (9) above the fluidized bed (5) in the reactor (1), with a supply of additional oxygen. A molar ratio of water vapour supplied and carbon contained in the material to be gasified of at least 2.1 is established.
    Type: Application
    Filed: September 2, 2003
    Publication date: March 25, 2004
    Inventors: Bruno Berger, Ernst Rudelstorfer
  • Publication number: 20040025437
    Abstract: A solid fuel gasifier includes first wall structure (12) defining a gasification chamber (14) and means (50, 52) to collect particulate solid residue from gasification in the gasification chamber. Second wall structure (16) defines a gas combustion chamber (17) and means (19) is arranged for admitting a flow of hot gases from the gasification chamber to the gas combustion chamber as combustion takes place. Also provided is means (178, 170) to conduct hot gases from the gasification chamber and/or gas combustion chamber into thermal contact with said collected particulate solid residue, for facilitating post-combustion and/or post-reduction of the solid residue. Also disclosed are an agitator bed (52, 182) for fine particulate material, and a method of gasification of solid fuel.
    Type: Application
    Filed: June 20, 2003
    Publication date: February 12, 2004
    Inventor: Paul Douglas Williams
  • Publication number: 20040006917
    Abstract: A fuel preparation apparatus in which coal or coal and other carbon containing material is converted to an environmentally acceptable fuel gas by the reaction with air and steam at a pressure of from 20 to 90 pounds per square inch absolute suitable for providing fuel to a gas turbine, or a stoker type or other boiler having a coal delivery system, a coal crusher, coal storage bins, lock hoppers, a gasifier vessel of two stages, liquid and solid separator vessels, heat and steam recovery vessels, equipment to control the flow of steam and air to the gasifier so as to maintain fuel quality, and a gas clean up plant that will remove environmentally unacceptable components of the gas such as hydrogen sulphide and other sulphur containing compounds and tars and light oils.
    Type: Application
    Filed: July 9, 2002
    Publication date: January 15, 2004
    Inventors: David W. Wakefield, Robert Glover Jackson
  • Patent number: 6669917
    Abstract: A process for burning coal to produce substantially pure hydrogen for use in fuel cells, together with “sequestration ready” carbon dioxide and a stream of oxygen depleted air for powering gas turbines, characterized by using a combination of two fluidized bed reactors and a third transfer line reactor, the first reactor being supplied with coal particles or “char” and fluidized with high temperature steam; the second reactor being fluidized with high temperature steam and the third reactor being fluidized by compressed air. Solids circulated among these three reactors include a mixture of materials containing calcium compounds (present as CaO, CaCO3 and mixtures thereof) and iron compounds (present as FeO, Fe2O3 and mixtures thereof). The coal is gasified by the steam in the presence of CaO to produce CaCO3 and relatively pure hydrogen for use in fuel cells per a CO2 acceptor process.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: December 30, 2003
    Assignee: General Electric Co.
    Inventor: Richard K. Lyon
  • Publication number: 20030140559
    Abstract: A method serves for the pyrolysis and gasification of substance mixtures containing organic constituents. The organic substances (4) or the substance mixture containing the organic constituents are brought into contact with a heat transfer medium, for preference the ash (5) from a combustion reactor (2) in a pyrolysis reactor (1), for preference a shaft reactor and pyrolysed. The pyrolysis coke (10) derived from the pyrolysis is combusted in a combustion reactor (2), for preference a fluidised bed reactor, under the admission of air (11).
    Type: Application
    Filed: January 10, 2003
    Publication date: July 31, 2003
    Inventors: Wolfgang Krumm, Gunter Funk, Stefan Hamel, Christian Mertens
  • Publication number: 20030079411
    Abstract: A device for decomposing an organic compound, which heats and decomposes organic compounds in at least one pyrolysis zone in a gas phase is disclosed. The pyrolysis zone comprises at least one high-frequency induction-heating device provided within a gas passage.
    Type: Application
    Filed: July 22, 2002
    Publication date: May 1, 2003
    Applicant: Ken KANSA
    Inventors: Ken Kansa, Yoshihide Mukouyama, Masatoshi Matsuba
  • Publication number: 20030029088
    Abstract: A process for burning coal to produce substantially pure hydrogen for use in fuel cells, together with “sequestration ready” carbon dioxide and a stream of oxygen depleted air for powering gas turbines, characterized by using a combination of two fluidized bed reactors and a third transfer line reactor, the first reactor being supplied with coal particles or “char” and fluidized with high temperature steam; the second reactor being fluidized with high temperature steam and the third reactor being fluidized by compressed air. Solids circulated among these three reactors include a mixture of materials containing calcium compounds (present as CaO, CaCO3 and mixtures thereof) and iron compounds (present as FeO, Fe2O3 and mixtures thereof). The coal is gasified by the steam in the presence of CaO to produce CaCO3 and relatively pure hydrogen for use in fuel cells per a CO2 acceptor process.
    Type: Application
    Filed: July 31, 2001
    Publication date: February 13, 2003
    Inventor: Richard K. Lyon
  • Publication number: 20030005634
    Abstract: A method for producing clean energy from coal by feeding the coal in a reactor which is sealed to the atmosphere and moving the coal in the reactor while injecting oxygen to combust a portion of the coal in a substoichiometric mode to devolatilize the coal and yield a pressurized hydrogen rich raw gas which contains coal-derived cancer causing distillates and hydrocarbons together with a hot char. The distillates and the hydrocarbons are cracked to result in a cracked gas of essentially 2H2 and 1CO which after desulfurization becomes an ideal synthesis gas that can be synthesized to a liquid fuel for heating and transportation as an alternate to petroleum.
    Type: Application
    Filed: July 9, 2001
    Publication date: January 9, 2003
    Inventors: Albert Calderon, Terry James Laubis
  • Patent number: 6206941
    Abstract: An apparatus for converting carbonaceous raw materials into a carbonized product and activating the product, includes a device for heating the carbonaceous raw materials to form a carbonized product, and equipment for activating the carbonized product and supplying by-product of the activation to the device to help in the heating. The device heats a column of carbonaceous raw materials to pyrolize it and form a carbonized product and vapors and gases. Upward flow of the gases and vapors is restrained so that they flow, with the carbonized product, out of the bottom of the column where they are burned in a combustion box and the resultant hot gases used to heat the column through a tube defining the column. Descending carbonized materials pass rapidly through the combustion box into the equipment which through electical resistance heating and steam, activates the carbonized materials and passes gas and vapor by-products thereby created up into the combustion box to help fuel the heating of the raw materials.
    Type: Grant
    Filed: January 2, 1998
    Date of Patent: March 27, 2001
    Inventor: Cornelius J. Du Plessis
  • Patent number: 5968212
    Abstract: A device for utilizing combustion, residual and waste materials containing carbon and ash by gasification with an oxygen-containing oxidizing agent at temperatures above the melting point of the inorganic parts in a reaction chamber and at a pressure between ambient pressure and 60 bar. The reaction chamber contour is formed in part by a refractory-grade lining and in part by a cooling system comprising cooling coils connected in a gas-tight manner. The coils are coated with a thin layer of a ceramic mass that conducts heat well on a side facing the reaction chamber. The cooling coils are operated, while being cooled by pressurized water, below or above the boiling point of the cooling water.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: October 19, 1999
    Assignee: Noell-KRC Energie-und Umwelttechnik GmbH
    Inventors: Helmut Peise, Manfred Schingnitz, Dietmar Degenkolb
  • Patent number: 5861046
    Abstract: There is described a method of recovering energy and/or combustible gas by thermally gasifying fuel during its partial combustion, wherein the fuel and an oxygen-containing gas are delivered to a reactor (1) and caused to circulate in a closed circuit of reactants and reaction products during partial combustion of the fuel. Circulation is effected by virtue of the fact that the reactor (1) is configured as an ejector (9) at the location of the oxygen-containing gas inlet (8), so that the gas delivered to the reactor will function to drive reactants and reaction products around the closed circuit. The invention also relates to a reactor for carrying out the inventive method.
    Type: Grant
    Filed: May 22, 1996
    Date of Patent: January 19, 1999
    Assignee: General Process AA AB
    Inventor: Alf Ove Andersson
  • Patent number: 5857421
    Abstract: Combustible gases from a solid fuel are produced by pyrolyzing the fuel in a pyrolyzer which also produces carbonaceous material. The carbonaceous material from the pyrolyzer is combusted in a furnace to produce combustion products that include hot flue gases and ash particulate. The combustion products are separated into a plurality of streams, one of which contains flue gases, and another of which contains hot ash which is directed into the pyrolyzer. Finally, the stream of flue gases from the furnace is used to dry the fuel that is supplied to said pyrolyzer.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: January 12, 1999
    Assignee: Ormat, Inc.
    Inventors: Benjamin Doron, Daniel Goldman, Eli Yaffe
  • Patent number: 5851497
    Abstract: A gasifier (10) for partially combusting a carbonaceous fuel mixture in the combustion chamber (13) of the gasifier (10). The latter includes a water bath (26) into which the hot effluent or the products of combustion are immersed, including a synthetic gas. The products of combustion are directed into the bath (26) by way of a constricted throat section (31). To avoid excessive erosion action and/or thermal shock to the throat section (31) as a result of exposure to the effluent's high temperatures, the throat section (31) is structured with an internal framework of pipes (32). The flamework (32) is communicated with a pressurized source of a cooling fluid (42), preferably water, whereby to cool the throat section (31) sufficiently to counteract the ill effects of exposure to contact with the high temperature effluent.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: December 22, 1998
    Assignee: Texaco Inc.
    Inventors: Donald Duane Brooker, James Samuel Falsetti, James Kenneth Wolfenbarger, Dinh-Cuong Vuong
  • Patent number: 5725615
    Abstract: According to the apparatus and method, combustible gas having a stable composition can be formed even if the load is charged. Burners are provided in the upper and the lower regions of an entrained bed coal gasification reactor. The temperature of the product gas is kept low in the upper region and high in the lower region. The volumes of the upper and lower regions are changed to meet the load so that the rate of heat loss becomes constant even if the load changes. Since the rate of heat loss can be kept constant and consequently variation of the composition of the product gas can be suppressed small, the efficiency of the coal gasification electric power generating system can be kept constant.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: March 10, 1998
    Assignees: Hitachi, Ltd., Babcock-Hitachi Kabushiki Kaisha
    Inventors: Atsushi Morihara, Takanori Kudo, Sinji Tanaka, Shuntaro Koyama, Eiji Kida
  • Patent number: 5505144
    Abstract: Combustible gases from a solid fuel are produced by pyrolyzing the fuel in a pyrolyzer which also produces carbonaceous material. The carbonaceous material from the pyrolyzer is combusted in a furnace to produce combustion products that include hot flue gases and ash particulate. The combustion products are separated into a plurality of streams, one of which contains flue gases, and another of which contains hot ash which is directed into the pyrolyzer. Finally, the stream of flue gases from the furnace is used to dry the fuel that is supplied to said pyrolyzer.
    Type: Grant
    Filed: October 5, 1994
    Date of Patent: April 9, 1996
    Assignee: Ormat, Inc.
    Inventors: Benjamin Doron, Daniel Goldman, Eli Yaffe
  • Patent number: 5501160
    Abstract: A portion of solid fuel is pyrolyzed in a pyrolyzer to produce combustible gases and carbonaceous material, the carbonaceous material being supplied from the pyrolyzer to a furnace. A further portion of the solid fuel is added to a furnace and is combusted with the carbonaceous material therein to produce combustion products that include hot flue gases and ash particulate. The combustion products are separated into a plurality of streams, one of which contains coarse ash and another of which contains flue gases and fine ash. A portion of the coarse ash is directed into the pyrolyzer while a further portion is disposed of, preferably by being used to heat air entering the furnace.
    Type: Grant
    Filed: July 13, 1994
    Date of Patent: March 26, 1996
    Assignee: Ormat Industries Ltd
    Inventors: Daniel Goldman, Boris Siniakevith, Benjamin Doron, Lucien Y. Bronicki, Eli Yaffe
  • Patent number: 5439491
    Abstract: Apparatus is disclosed for the allothermic gasification of coal with steam. The gasifier is horizontally arranged with heat exchange tubes in separate gasification and pyrolysis zones so that a heat exchange medium is used in both zones.
    Type: Grant
    Filed: April 21, 1994
    Date of Patent: August 8, 1995
    Assignee: Bergwerksverband GmbH
    Inventors: Helmut Kubiak, Hans J. Schroter, Gunther Gappa, Heinrich Kalwitzki, Klaus Knop
  • Patent number: 5388534
    Abstract: Combustible gases are produced from a solid fuel by pyrolizing the fuel in a pyrolyzer containing a low grade solid fuel producing combustible gases, and carbonaceous material that is combusted in a furnace to produce hot products that include hot flue gases and particulate material. The hot products are separated into a plurality of streams, one of which contains comparatively coarse ash which is directed into the pyrolyzer for effecting the pyrolyzation of the fuel. A stream of reaction gases is applied to the pyrolyzer in such a way that the stream of reaction gases bubbles through the carbonaceous material in the pyrolyzer without fluidizing such material. In effect, the reaction gases activate the void fraction in the pyrolyzer thereby reducing the residence time of the material therein.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: February 14, 1995
    Assignee: Ormat Inc.
    Inventors: Benjamin Doron, Daniel Goldman, Eli Yaffe
  • Patent number: 5243922
    Abstract: A process and apparatus for generating electricity from coal comprising a vertically stacked, three-stage combustor in which a sorbent is calcined in a calciner zone of the combustor and transferred to a carbonizer zone disposed below the calciner zone, coal introduced into the carbonizer zone is carbonized, producing char and spent sorbent, both of which are transferred to a combustor zone disposed below the carbonizer zone, in which the char is combusted at a substoichemetic air-to-coal ratio, producing a fuel gas. The fuel gas is cleaned and combusted in a turbine combustor, producing a flue gas which is introduced into a gas turbine for producing electricity.
    Type: Grant
    Filed: July 31, 1992
    Date of Patent: September 14, 1993
    Assignee: Institute of Gas Technology
    Inventors: Amirali G. Rehmat, Lev Dorfman
  • Patent number: 4981089
    Abstract: In a process to reduce the nitrogen monoxide emissions generated during the combustion of solid fuels, before the combustion takes place, the entire amount of solid fuel is degasified inside a performance combustion area (2). At least part of the gas obtained during the degasification of the solid fuel is utilized as reduction gas in one or several reduction areas (3) that have been placed following the performance combustion area (2). In an installation for the implementation of the process the degasification device for solid fuel has been configured as a degasification section (5) for the continuous passage of fuel and has been arranged inside the combustion unit (1), within the flue gas current.
    Type: Grant
    Filed: August 8, 1989
    Date of Patent: January 1, 1991
    Assignee: Saarbergwerke Aktiengesellschaft
    Inventors: Heinz Spliethoff, Hartmut Spliethoff
  • Patent number: 4917024
    Abstract: A coal fired power plant includes a coal gasification zone where coal is gasified in the presence of an oxidant-lean atmosphere under partial coal gasifying conditions to produce a carbonaceous char and a crude gas stream, an acid separating zone where sulfur-containing compounds are separated from the crude gas stream to produce a combustible gas stream, and a converting zone where the sulfur-containing compounds are converted to elemental sulfur. The combustible gas stream and the carbonaceous char are fed into a boiler which drives a generator to produce electricity; portions of the carbonaceous char product and the combustible gas stream are diverted into a gypsum desulfurization zone. SO.sub.2 -containing flue gas from the boiler is fed into a flue gas desulfurization zone. There, the SO.sub.2 -containing flue gas is contacted with lime and limestone to produce gypsum.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: April 17, 1990
    Assignee: Florida Institute of Phosphate Research
    Inventors: Jerome H. Marten, G. Michael Lloyd
  • Patent number: 4907565
    Abstract: An improved gasifier and engine system which includes an air compressor, a fixed-bed gasifier, a gas cleansing device and a diesel-cycle internal combustion engine. Ambient air is compressed by the compressor to a predetermined first pressure and is directed to a chamber of the gasifier which contains a batch loaded charge of coal and/or other expendable conditioning materials such as water, limestone and sand. The gasifier partially burns the charge and produces high pressure and temperature fuel gas which is cleaned up prior to exiting the gasifier chamber. The cleaned hot fuel gas is directed to the engine where an injection device injects the fuel gas into a combustion chamber of the engine during a later portion of a compression phase of the diesel cycle. The injected fuel gas is ignited in the engine combustion chamber by a glow plug or other ignition-assist device.
    Type: Grant
    Filed: February 22, 1989
    Date of Patent: March 13, 1990
    Assignee: Caterpillar Inc.
    Inventors: John M. Bailey, Abraham L. Zadoks
  • Patent number: 4538528
    Abstract: A gas converter is disclosed, especially for the treatment, including dissociation, of gases produced in the pyrolysis of waste materials. The converter includes a feeder for airtight feeding of fuel from the upper region of the reactor tower to the bed of hot fuel, a gas outlet, and a slag removal system. The reactor tower is furnished at its lower end near the conduits for the admission of air and gases with a rotating distributor member. The feeder is provided by a bucket-wheel valve arrangement.
    Type: Grant
    Filed: May 16, 1984
    Date of Patent: September 3, 1985
    Assignee: PKA Pyrolyse Kraftanlagen GmbH
    Inventor: Erich Faehnle
  • Patent number: 4367075
    Abstract: A thrust containment apparatus is disclosed for use with a pressurized rotary kiln gasifier. The thrust containment apparatus maintains stationary hoods mounted on both ends of the kiln shell in fixed positions by relieving the hoods of forces generated by high pressures within the kiln. The thrust containment device comprises braces mounted on the hoods on the sides remote from the kiln shell. Tie members, or tie rods, extending along the exterior of the kiln shell connect the braces. An expandable bellows is provided between one brace and its adjacent hood. As tie members deform through thermal and tensile expansion, the bellows accomodates the expansion while maintaining a gas-tight seal between the hood and the brace.
    Type: Grant
    Filed: November 16, 1981
    Date of Patent: January 4, 1983
    Assignee: Allis-Chalmers Corporation
    Inventor: Walter J. Hartwig
  • Patent number: 4310333
    Abstract: An improvement in the process for the gasification of a solid fuel wherein the solid fuel is at least partially oxidized at a temperature above the melting point of ash of the solid fuel and at a pressure of 10-200 bar where the resultant synthesis gas is thereafter cooled in the presence of combustion residues of the solid fuel, and the combustion residues are thereafter discharged directly, the improvement residing in carrying out the gasification in a gasification zone disposed vertically over and in fluid communication with a radiation zone comprising cooling surfaces, the radiation zone have disposed at the bottom thereof and in fluid communication with the radiation zone a water containing bath. The radiation zone is cylindrical or conical, widens by 0 to 15 degrees towards the bottom, is made in a finned wall construction with a relation of height to diameter of .ltoreq.6:1 and comprises cooling surfaces.
    Type: Grant
    Filed: March 17, 1980
    Date of Patent: January 12, 1982
    Assignee: Ruhrchemie Aktiengesellschaft
    Inventors: Volkmar Schmidt, Bernhard Lieder, Heinrich Scheve, Hans Dohren
  • Patent number: 4304574
    Abstract: The retort chamber for generating gas by applying hot steam to coal in a fluidized bed is heated by meandering tubes, dipping into the bed, and being suspended from long, hollow boxes which, in turn, are particularly suspended in the retort chamber. The boxes support also manifold tubes connected to the heating tubes and being further connected to a heating fluid feed and distribution as well as a collecting and discharge system.
    Type: Grant
    Filed: March 17, 1980
    Date of Patent: December 8, 1981
    Assignees: Mannesmannrohren-Werke AG, Bergwerksverband GmbH
    Inventors: Guenter Buchner, Johannes Alkemper, Rainer Durrfeld, Heinz Gaessler
  • Patent number: 4183733
    Abstract: A hydro gas plant with utilization of the residual coke, comprising a gasifier into which raw coal is introduced for hydro gasification that results in the production of methane; a furnace for cracking the methane into hydrogen and carbon monoxide; and means for utilizing the combustion heat of the residual coke obtained during the operation of the gasifier, or a low-BTU gas produced from the coke, in at least the cracking furnace but optionally also in a steam generator. The use of exhaust gases from the cracking furnace is also suggested, namely in a preheater through which hydrogen is fed to the gasifier.
    Type: Grant
    Filed: February 21, 1978
    Date of Patent: January 15, 1980
    Inventor: Walter Jager
  • Patent number: 4165971
    Abstract: A process and apparatus for material processing, in particular for producing gas from carbon-containing material, are disclosed. Feed material comprising particulate material is continuously formed into briquettes and is simultaneously introduced into a processing compartment. The feed material is formed into briquettes by one or more pressure wheels forcing the material through channels in a die.
    Type: Grant
    Filed: May 17, 1977
    Date of Patent: August 28, 1979
    Assignee: Projektierung Chemische Verfahrenstechnik GmbH
    Inventors: Walter Kaimann, Karl-Heinz Brachthauser
  • Patent number: 4126519
    Abstract: An apparatus and method for performing a continuous thermal treatment of organic carbonaceous materials under controlled pressure in which the feed material is introduced into the system in the form of a slurry, and the level of liquid is maintained at a preselected operating level, serving as a gas-tight seal. The feed material is conveyed upwardly of the liquid operating level and is thereafter introduced into a reaction chamber in which it is heated to within a controlled elevated temperature range under controlled pressure in a manner to effect vaporization of at least a portion of the volatile substances therein, forming a gaseous phase composed of condensible and noncondensible vapors.
    Type: Grant
    Filed: September 12, 1977
    Date of Patent: November 21, 1978
    Assignee: Edward Koppelman
    Inventor: Robert G. Murray
  • Patent number: 4105419
    Abstract: A fluidized bed apparatus suitable for the combustion of fuel has a baffle assembly arranged in the freeboard above the fluidized bed level. The assembly is in the form of a perforate duct which defines within it a passage connecting with the gas exit of the apparatus. Gases issuing from the bed, in use, and carrying bed material impinge upon the duct and are arranged to follow a vortical path around the duct, resulting in a deceleration of the particles which fall back into the bed. The gases pass into the duct for exhaust substantially free from contamination by bed material. The baffle assembly is of particular value where a gas flows horizontally to a gas exit and prevents or substantially reduces elutriation.
    Type: Grant
    Filed: March 11, 1977
    Date of Patent: August 8, 1978
    Assignee: Coal Industry (Patents) Limited
    Inventors: John Highley, Michael A. Vickers
  • Patent number: 4080181
    Abstract: A gas generator is provided for the production of gas from fuel and steam under conditions of high pressure and temperature. The requisite temperature is preferably provided by a nuclear reactor. The gas generator includes a cylinder wth a hollow interior. Extending transversely through the hollow interior of the cylinder is a container. Tubular heat exchangers are vertically arranged over the length, width and height of the cylinder in such a manner that the density of heating surfaces decreases along the length of the container.
    Type: Grant
    Filed: November 8, 1976
    Date of Patent: March 21, 1978
    Assignee: Bergwerksverband GmbH
    Inventors: Paul Peter Feistel, Karl Heinrich Van Heek, Harald Juntgen, Rainer Durrfeld
  • Patent number: 4062656
    Abstract: A fluidized bed apparatus having an outer vessel provided at a lower region with a plenum chamber as well as a grid situated directly above the plenum chamber and carrying a plurality of nozzles through which gas flows from the plenum chamber into the space in the vessel above the grid. These nozzles provide a given pressure drop in the gas flowing therethrough while as the gas flows from the plenum chamber through each nozzle there is also provided by way of a suitable structure a preliminary pressure drop, so that a two-stage pressure drop is provided in the gas flowing through each nozzle from the plenum chamber into the vessel above the grid. In this way it is possible to achieve a flow of gas above the grid sufficient to maintain the particles suspended in the fluidized bed while attrition of the particles is maintained at a minimum so that very little if any fines flow out of the vessel with gas which is formed therein.
    Type: Grant
    Filed: May 12, 1976
    Date of Patent: December 13, 1977
    Assignee: Exxon Research and Engineering Company
    Inventors: Don E. Blaser, Arthur C. Worley
  • Patent number: 4057400
    Abstract: Apparatus for the gasification under pressure of bituminous coal, especially fine coal, comprising a generator which has a container to receive the coal to be gasified and a feed device which supplies the coal to the container, while keeping the container closed off so as to maintain the pressure in the generator. The feed device includes a device for agglomerating the coal to be gasified located on the container, and a continuously operable screw conveyor which feeds the coal to be gasified to the agglomerating device which delivers the formed agglomerates, in a green condition, into the container. The feed device is encapsulated and, together with the fine coal and agglomerates within it, forms a gas tight closure for the container to maintain the pressure therein.
    Type: Grant
    Filed: September 7, 1976
    Date of Patent: November 8, 1977
    Inventors: Walter Kaimann, Rudolf Pasternak, Jochen Bauer
  • Patent number: 4030895
    Abstract: A reactor for generating combustible fuel gases comprising a chamber, an inclined grate extending from adjacent the top of the chamber to near the bottom and sloping forwardly within the chamber from the top to the bottom, said grate dividing the chamber into a primary chamber at the forward side of the grate and an antechamber at the rear side, a conveyor for delivering a solid fuel such as wood chips and other chopped-up woody material to the upper end of the grate at a rate to maintain a continuous bed of fuel from top to bottom, a blower for delivering primary air to a plenum chamber at the downwardly facing side of the grate to sustain combustion of the fuel at the lower end of the bed and to generate sufficient heat above the place of combustion to effect destructive distillation of a portion of the fuel in the bed above the place of combustion said primary air at said place of combustion converting the charcoal remaining after distillates have passed off descending from the place of distillation to CO
    Type: Grant
    Filed: March 17, 1976
    Date of Patent: June 21, 1977
    Inventor: Robert A. Caughey
  • Patent number: 4004895
    Abstract: A vertical shaft furnace having a diameter substantially equal to the height thereof is employed for the clean combustion of coal to convert the coal virtually stoichiometrically to carbon monoxide. After providing a supporting bed of coke in the base of the furnace a mixture of coal and limestone is introduced through the top of the furnace and combustion takes place adjacent a plurality of circumferentially located tuyeres adjacent the top of the coke bed through which a moderate air blast is introduced. The resulting carbon dioxide is completely converted to carbon monoxide as it passes upwardly through the coal and the reducing atmosphere prevents the oxidation of the sulfur in the coal while the decomposed limestone combines with the sulfur to produce sulfur bearing compounds.
    Type: Grant
    Filed: April 29, 1975
    Date of Patent: January 25, 1977
    Inventor: Louis Gold
  • Patent number: 3988210
    Abstract: A furnace for manufacturing a high-calorific gas and coke from coal, provided with two walls 1 perforated in their upper portion, which form a rectangular chamber 2 filled with a coal charge. These walls are provided with channels 3 with inlet pipes 4 for supplying hot combustion gases and the furnace is furnished in its upper zone with inlet pipes 6 for delivering coal to the furnace and ramming pistons 7 having imparted free reciprocating motions. At the side of the furnace in its upper zone are inlet pipes 8 for supplying a hot circulating gas to the direct heating chamber where a coal charge is directly heated. Inside of the gas chamber 10 of the furnace there is an outlet pipe 9 for withdrawing cold circulating gas to a blower 14, which then becomes successively heated to the required temperature in a heat exchanger 13.
    Type: Grant
    Filed: February 28, 1975
    Date of Patent: October 26, 1976
    Assignee: Politechnika Slaska im Wincentego Pstrowskiego
    Inventors: Jerzy Pikon, Piotr Wasilewski, Boleslaw Mitka
  • Patent number: 3985520
    Abstract: In addition to introducing steam and/or oxygen in the heated airblast through the tuyeres of a conventional blast furnace to provide a blast furnace gas enriched with carbon monoxide and hydrogen, air and/or steam can be forced through the molten pig iron which has been withdrawn from the blast furnace into a separate reactor having a modified construction similar to the basic oxygen furnace for the purpose of producing large volumes of hydrogen. The blast furnace gasses can be combined with the gasses from the reactor to provide a clean burning fuel for use in power plants and the like or the hydrogen from the reactor can be utilized directly in fuel-cell technology. The resulting iron oxides (magnetite, etc.) which result from the pig iron-steam reaction can then be recycled through the blast furnace.
    Type: Grant
    Filed: June 26, 1975
    Date of Patent: October 12, 1976
    Inventor: Louis Gold