Coal Patents (Class 48/210)
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Patent number: 8444724Abstract: A generally upright reactor system for gasifying a feedstock. The reactor system generally includes a main body, at least two inlet projections extending outwardly from the main body, and at least one inlet positioned on each of the inlet projections. Each of the inlets is operable to discharge the feedstock into the reaction zone.Type: GrantFiled: May 31, 2012Date of Patent: May 21, 2013Assignee: Phillips 66 CompanyInventors: Steven L. Douglas, Ronald W. Herbanek, David L. Breton, Steven E. Chichester
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Patent number: 8439993Abstract: A method of operating a gasification facility includes channeling a conveying fluid at a first temperature through at least one first steam heating device to increase the temperature of the conveying fluid to a second predetermined temperature. The method also includes channeling the conveying fluid at the second predetermined temperature through a second steam heating device to increase the temperature of the conveying fluid to a third predetermined temperature. The method further includes channeling the conveying fluid at the third predetermined temperature to a solids conveyance system. Solids become entrained within the conveying fluid. The method also includes transporting at least a portion of the solids to a gasification system.Type: GrantFiled: September 7, 2012Date of Patent: May 14, 2013Assignee: General Electric CompanyInventors: Sunil Ramabhilakh Mishra, Pradeep S. Thacker, Anindra Mazumdar, Vignesh Venkatraman
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Patent number: 8435478Abstract: A process and apparatus for enhancement of syngas production (CO and H2) of a carbon based feedstock with CO2 conversion, which utilized CO2 as an oxygen resource and converts CO2 to CO through chemical reactions. The process includes a thermal plasma reactor and optionally a nonthermal plasma reactor.Type: GrantFiled: January 27, 2011Date of Patent: May 7, 2013Assignee: Southwest Research InstituteInventors: Maoqi Feng, Francis Yu Chang Huang, Richard L. Johnson
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Patent number: 8425638Abstract: Upon cold startup of a gasification facility, a fluidized air 10 is supplied to a combustion furnace 9 to fluidize a combustion-furnace fluidized bed 11 while a preheating fuel 22 is supplied to the combustion furnace to preheat the fluidized bed 11 up to an autoignition temperature of coal. Then, a coal 23 is charged to the combustion furnace 9 to heat the fluidized bed 11 and bed material is circulated between the combustion and gasification furnaces 9 and 1 for heating. Upon startup and shutdown of the gasification facility, steam 2 from an exhaust heat recovery boiler 20 in heat exchange with an exhaust gas 15 from the combustion furnace 9 is supplied to the gasification furnace 1 to purge the gasification furnace 1 and a lead-out passage 6 with the steam 2 utilizing the exhaust heat.Type: GrantFiled: March 18, 2009Date of Patent: April 23, 2013Assignee: IHI CorporationInventors: Hisanori Nukumi, Tomoyuki Katagiri
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Patent number: 8419813Abstract: The invention relates to an integrated method of in-situ oxygen production, chemical looping combustion and gasification of liquid, solid or gaseous fuels allowing combustion of coal, petroleum coke and/or liquid hydrocarbons and notably heavy and/or extra heavy or bituminous residues for production of synthesis gas under pressure and/or energy.Type: GrantFiled: April 29, 2010Date of Patent: April 16, 2013Assignee: IFPInventors: Ali Hoteit, Florent Guillou, Arnold Lambert, John Roesler
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Patent number: 8414668Abstract: In a coal gasification furnace adapted to feed pulverized coal thereinto by the use of inert carrier gas and gasify the same, any startup burner can be unnecessitated thereby eliminating any startup combustion chamber. Further, even in the use of a startup burner, it is smaller and lighter in weight than conventional startup burners, allowing the startup combustion chamber to be compact and limiting the height of the entirety of the gasification furnace. As a characteristic feature, a pulverized coal fuel supply passageway (23) to a combustor burner (9) is provided at its midstream portion with a startup gas supply passageway (29) for supply of a startup combustible gas (NG1).Type: GrantFiled: July 15, 2008Date of Patent: April 9, 2013Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Katsuhiko Yokohama, Hiromi Ishii, Yuichiro Kitagawa
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Patent number: 8414780Abstract: With a method for removing slag, particularly slag that occurs during synthesis gas extraction, from a slag bath situated in a pressurized container, into a collection container for the slag, below the slag bath in the direction of gravity, a device for breaking up the slag is provided below the slag bath, and a sluice valve is provided between the containers. A space filled with a gas bubble, which space stands in contact with the liquid in the containers, particularly a ring space or a separate container, is provided, in which the pressure of the gas bubble is regulated by supplying gas. At least a part of the water situated in the slag sluice/collection space flows through the slag bath valve when the latter is opened, in the direction of the slag bath, counter to the direction of gravity.Type: GrantFiled: January 21, 2009Date of Patent: April 9, 2013Assignee: ThyssenKrupp Uhde GmbHInventors: Johannes Kowoll, Eberhard Kuske
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Patent number: 8409307Abstract: This invention is a process and system for providing hydrogen at a high level of reliability from a gasification system by integrating it with SMR. Carbonaceous feedstock such as petroleum coke or coal or biomass is gasified to co-produce SNG, fuel gas, hydrogen, power and steam in conjunction with hydrogen production through steam methane reforming. Carbon dioxide may also be recovered in this process. The integrated schemes are designed in a way that maximizes the reliability of production of high value products such as hydrogen through gasification and minimizes the impact of high natural gas prices on hydrogen production by SMR.Type: GrantFiled: August 22, 2007Date of Patent: April 2, 2013Assignee: Praxair Technology, Inc.Inventors: Raymond Francis Drnevich, Aqil Jamal
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Patent number: 8398730Abstract: A method of producing substitute natural gas (SNG) includes providing a gasification reactor having a cavity defined at least partially by a first wall. The reactor also includes a first passage defined at least partially by at least a portion of the first wall and a second wall, wherein the first passage is in heat transfer communication with the first wall. The reactor further includes a second passage defined at least partially by at least a portion of the second wall and a third wall. The method also includes coupling the cavity in flow communication with the first and second passages. The method further includes producing a first synthetic gas (syngas) stream within the cavity. The method also includes channeling at least a portion of the first syngas stream to the first and second passages.Type: GrantFiled: July 23, 2008Date of Patent: March 19, 2013Assignee: General Electric CompanyInventors: Paul Steven Wallace, Arnaldo Frydman
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Publication number: 20130047509Abstract: Systems and methods for producing synthetic gas are provided. The method can include gasifying a feedstock within a gasifier to provide a raw syngas. The raw syngas can be processed within a purification system to provide a treated syngas, and the purification system can include a flash gas separator. The treated syngas and a first heat transfer medium can be converted into a synthetic gas, a second heat transfer medium, and a methanation condensate. The methanation condensate can be introduced to the flash gas separator.Type: ApplicationFiled: October 30, 2012Publication date: February 28, 2013Applicant: Kellogg Brown & Root LLCInventor: Kellogg Brown & Root LLC
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Patent number: 8372171Abstract: A process is presented whereby hot Carbon Monoxide (CO) gas is generated under pressure in an external Combustor by the partial oxidation of a carbon-based solid fuel. This pressurized, hot CO gas or CO gas mixture is then transferred to a desulfurizing vessel containing a second carbon-based solid fuel. The hot CO laden gas and solid material contact in a counter-flow arrangement where the CO reacts with and removes sulfur impurities from the second carbon fuel. The temperature of the pressurized CO laden gas from the Combustor is controlled by varying the oxidizer feed gas composition. The Combustor also contains a means for desulfurizing its feed fuel by flowing a portion of the hot CO gas generated up through the inlet solid fuel feed line.Type: GrantFiled: November 23, 2009Date of Patent: February 12, 2013Inventor: Louis Herrington
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Patent number: 8366796Abstract: The present invention provides modular and distributed methods and systems to convert biomass feedstocks into synthesis gas (syngas). The syngas can then be turned into liquid chemicals and fuels such as ethanol. The modular units of the invention bring the conversion process to the biomass source, thereby minimizing feedstock transportation costs. The modules are capable of being connected to, and/or disconnected from, each other to easily adjust the overall feedstock capacity. The present invention also provides methods and systems to determine an optimal number and distribution of modular conversion units spatially located within a region of land. The disclosed methods and systems are flexible, efficient, scalable, and are capable of being cost-effective at any commercial scale of operation.Type: GrantFiled: July 1, 2008Date of Patent: February 5, 2013Assignee: Range Fuels, Inc.Inventors: Mitchell Mandich, William B. Schafer, III
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Patent number: 8365433Abstract: A technique by which various types of organic waste can be easily treated so as to obtain a reusable material. An apparatus is provided which comprises a vessel (20) for introducing organic waste (18) therein, the vessel being equipped with: stirring means (82), (92), and (98) for stirring the organic waste (18); steam supply means (62), (64), and (66) which supply high-temperature high-pressure steam to the vessel (20); evacuation means (77), (78), and (80) which evacuate the vessel (20); and heating means (24), (68), (64), and (66) which heat the organic waste (18) present in the vessel (20). The apparatus has such constitution, in which the organic waste (18) in the vessel (20) is decomposed by hydrolysis and pyrolysis and vacuum dried using those means.Type: GrantFiled: December 14, 2007Date of Patent: February 5, 2013Assignee: Kunitomo Kankyo Plant Co., Ltd.Inventor: Kunio Ogura
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Publication number: 20130025201Abstract: A high energy transport gas and a method to transport the high energy transport gas are used to increase the energy content of a pipeline and other vessels that are designed to carry natural gas under ambient conditions, in a compressed state or in a liquefied state. Methane and other gases are used as the feedstock, with methane from natural gas fields, coal beds or derived from hydrogen reacting with coal being primary energy sources. Also, this gas and method can provide an abundant source for hydrogen production, and the energy from hydrogen can be used for fuel cell applications that generate electricity and power motor vehicles. This gas and method are capable of increasing the energy capacity of current natural gas pipelines and other storage and transport vessels.Type: ApplicationFiled: October 1, 2012Publication date: January 31, 2013Inventor: Robert C. Dalton
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Patent number: 8343242Abstract: A method of controlling an apparatus for generating electric power and apparatus for use in said method, the apparatus comprising a gasifier for biomass material, such as waste, wood chips, straw, etc., said gasifier being of the shaft and updraft fixed bed type, which from the top is charged with the raw material for gasification and into the bottom of which gasifying agent is introduced, and a gas engine driving an electrical generator for producing electrical power, said gas engine being driven by the fuel gas from the gasifier. By supplying the produced fuel gas directly from the gasifier to the gas engine and controlling the production of the fuel gas in the gasifier in order to maintain a constant electrical output power, the necessity of using a gas holder between the gasifier and the gas engine is avoided.Type: GrantFiled: June 29, 2007Date of Patent: January 1, 2013Assignee: Babcock & Wilcox Vølund A/SInventors: Claus Geest, Bjørn Teislev
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Patent number: 8333813Abstract: Embodiments disclosed herein provide hydrocarbon additives and methods of making and using the same. The additives are suitable for use in conjunction with gasifiers, furnaces, or other high-temperature vessels. The additives may be part of an input stream to a reaction vessel of a hydrocarbon gasifier. The additives may include materials that at least partially reduce the infiltration of slag into the refractory material.Type: GrantFiled: February 24, 2012Date of Patent: December 18, 2012Assignee: General Electric CompanyInventors: Peter Joel Meschter, Paul Stephen Dimascio
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Patent number: 8328889Abstract: Systems and processes for producing syngas and power therefrom are provided. One or more feedstocks and one or more oxidants can be combined in a fluidized reaction zone operated at a temperature from 550° C. to 1,050° C. to provide a syngas. Heat can be indirectly exchanged in a first zone from the syngas to a condensate to provide steam. Heat can also be indirectly exchanged in a second zone from the syngas to the steam to provide superheated steam. Heat can then be indirectly exchanged in a third zone from the syngas to provide a cooled syngas and the condensate for the first zone. At least a portion of the superheated steam can be directly supplied to one or more steam turbines to produce power.Type: GrantFiled: December 12, 2007Date of Patent: December 11, 2012Assignee: Kellogg Brown & Root LLCInventor: Ravindra K. Agrawal
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Patent number: 8328887Abstract: A method for producing synthetic gas from biomass by high temperature gasification, by: feeding biomass, carbonizing to yield pyrolysis gas and charcoal, pulverizing the charcoal, and gasifying in a gasifier. The heat source for the carbonizing step comes from a direct combustion reaction between external combustible gas and external oxygen in a carbonization furnace. Also provided is a device for producing synthetic gas from biomass by high temperature gasification, containing at least: a supercharging feeding system for biomass, a carbonization furnace containing at least a burner nozzle, a pulverizing system, a transportation system for charcoal powder, a gasifier, a pneumatic conveying system, and a plurality of connecting pipes therefor; the burner nozzle of the carbonization furnace is connected to an external combustible gas pipe and an external oxygen pipe respectively.Type: GrantFiled: May 19, 2010Date of Patent: December 11, 2012Assignee: Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.Inventors: Zhanchun Yang, Haiqing Zhang, Minxia Cao, Anhe Chen, Hong Li
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Patent number: 8328890Abstract: The present invention relates to processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam and an oxygen-rich gas stream. The processes comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and do not recycle carbon monoxide or hydrogen to the catalytic gasifier.Type: GrantFiled: September 18, 2009Date of Patent: December 11, 2012Assignee: GreatPoint Energy, Inc.Inventors: Vincent G. Reiling, Earl T. Robinson, Nicholas Charles Nahas, Jeffery Smith, Charles Mims
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Patent number: 8328888Abstract: Techniques, systems and material are disclosed for thermochemical regeneration of biomass into renewable engineered fuel, storage of the renewable engineered fuel, respeciation of the renewable engineered fuel and transport. In one aspect, a method includes generating low density hydrogen fuel from biomass dissociation at a first location of a low elevation. The low density hydrogen fuel is self-transported in a pipeline to a second location at a higher elevation than the first location by traveling from the first location to the second location without adding energy of pressure. A high density hydrogen carrier is generated at the second location of higher elevation by reacting the low density hydrogen fuel with at least one of a carbon donor, a nitrogen donor and an oxygen donor harvested from industrial waste. The high density hydrogen carrier is delivered to a third location of a lower elevation than the second location while providing pressure or kinetic energy.Type: GrantFiled: February 14, 2011Date of Patent: December 11, 2012Assignee: McAlister Technologies, LLCInventor: Roy Edward McAlister
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Patent number: 8323481Abstract: A method of sequestering carbon dioxide emissions during recovery of hydrocarbons from hydrocarbonaceous materials can include forming a constructed permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be heated sufficient to remove hydrocarbons therefrom. During heating, the hydrocarbonaceous material is substantially stationary as the constructed infrastructure is a fixed structure. Additionally, during heating, any carbon dioxide that is produced can be sequestered. Removed hydrocarbons can be collected for further processing, use in the process, and/or use as recovered.Type: GrantFiled: February 5, 2010Date of Patent: December 4, 2012Assignee: Red Leaf Resources, Inc.Inventors: Todd Dana, James W. Patten
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Patent number: 8317886Abstract: An apparatus and method for starved air gasification of solid organic materials, including biomass and other wastes, to convert the chemical energy stored in such materials to thermal energy or gaseous products that may be used in biochemical and/or chemical synthesis. Specifically, the system utilizes a gasifier having a “moving bed of ash” hearth wherein the feedstock is partially oxidized at a low temperature (less than 1500 degrees F.) in a square or rectangular chamber having a vaulted, tapered or flat roof.Type: GrantFiled: November 7, 2003Date of Patent: November 27, 2012Assignee: Nexterra Systems Corp.Inventors: Robert G. Graham, Jan Barynin, Kenneth M. Davison, Dave Berner
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Publication number: 20120279128Abstract: A pulse detonation device is provided for delivering a shock wave into a gasification device to promote a localized coal gasification reaction in the gasification device. The pulse detonation device includes a fuel inlet for receiving fuel, an air inlet for receiving air, a pulse detonation chamber wherein the fuel and air are configured to mix, and an ignition device for igniting the mixture of fuel and air. The ignition of the mixture of fuel and air creates a shock wave in the pulse detonation chamber. Further, the pulse detonation chamber is attached to a gasification chamber and is configured to extend into a coal feed tube that extends into the gasification chamber, with the shock wave configured to exit the pulse detonation chamber and interact with coal in the coal feed tube.Type: ApplicationFiled: May 3, 2011Publication date: November 8, 2012Applicant: BHA Group, Inc.Inventors: Tian Xuan Zhang, David Michael Chapin, Robert Warren Taylor
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Patent number: 8303675Abstract: With a system for synthesis gas production, having a reactor as well as a gas cooler/purifier connected with it in terms of flow, a solution is supposed to be created, with which the most compact possible connection between reactor, on the one hand, and the gas cooler or purifier, on the other hand, is made possible, whereby heat expansions that occur due to different temperatures are absorbed. This is accomplished in that the connection between reactor (1) and gas cooler/purifier (7) is formed by a horizontal connection piece (5) having a throttle element (6) configured as a Venturi element.Type: GrantFiled: August 14, 2009Date of Patent: November 6, 2012Assignee: UHDE GmbHInventors: Lothar Semrau, Gregor Hock
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Patent number: 8303916Abstract: A reactor system for the transformation of solid, liquid, gaseous, and related hydrocarbon feedstocks into high-purity, high-pressure gas streams capable of withstanding high temperatures and high pressures. The system comprises a plurality of reactor housings and a plurality of molten-metal bath vessels within the housings, the bath vessels in fluid communication with each other via conduits, with communication facilitated by gravity and temperature/pressure differentials.Type: GrantFiled: January 30, 2009Date of Patent: November 6, 2012Assignee: Oscura, Inc.Inventors: Michael C. Collins, Robert D. Bach
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Patent number: 8298306Abstract: The invention provides a process that comminutes fuel solids in a steam-driven shear field, with controlled water content and catalyst, with gasification of the particles entrained in the vented steam. Unlike conventional gasification methods the invention requires no dioxygen to be present, and produces dry friable ash that has significant marketable value as a material in its own right.Type: GrantFiled: February 10, 2009Date of Patent: October 30, 2012Inventor: David Walker Taylor
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Publication number: 20120266539Abstract: A process for joint entrained-bed gasification of ash-containing solid fuels and liquid fuels which are fed separately of each other to the coal gasification reactor via several burners, said burners having a concentric firing angle of greater than 0 degree such that soot formation is reduced and the conversion efficiency is increased, and the solid is conveyed to the gasification reactor together with an inert gas, and at least part of the ash-containing solid fuel contains fine coal particles which originate from coal mining and are not suited for fixed-bed gasification, and the liquid ash-containing fuel contains residues from a fixed-bed gasification.Type: ApplicationFiled: September 9, 2010Publication date: October 25, 2012Applicant: THYSSENKRUPP UHDE GMBHInventors: Christoph Hanrott, Max Heinritz-Adrian, Adrian Brandl
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Patent number: 8287610Abstract: Methods for carrying out high temperature reactions such as biomass pyrolysis or gasification using solar energy. The biomass particles are rapidly heated in a solar thermal entrainment reactor. The residence time of the particles in the reactor can be 5 seconds or less. The biomass particles may be directly or indirectly heated depending on the reactor design. Metal oxide particles can be fed into the reactor concurrently with the biomass particles, allowing carbothermic reduction of the metal oxide particles by biomass pyrolysis products. The reduced metal oxide particles can be reacted with steam to produce hydrogen in a subsequent process step.Type: GrantFiled: August 29, 2007Date of Patent: October 16, 2012Assignee: The Regents of the University of Colorado, a body corporateInventors: Alan W. Weimer, Christopher Perkins, Dragan Mejic, Paul Lichty
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Patent number: 8277523Abstract: A method of operating a gasification facility includes channeling a conveying fluid at a first temperature through at least one first steam heating device to increase the temperature of the conveying fluid to a second predetermined temperature. The method also includes channeling the conveying fluid at the second predetermined temperature through a second steam heating device to increase the temperature of the conveying fluid to a third predetermined temperature. The method further includes channeling the conveying fluid at the third predetermined temperature to a solids conveyance system. Solids become entrained within the conveying fluid. The method also includes transporting at least a portion of the solids to a gasification system.Type: GrantFiled: January 5, 2010Date of Patent: October 2, 2012Assignee: General Electric CompanyInventors: Sunil Ramabhilakh Mishra, Pradeep S. Thacker, Anindra Mazumdar, Vignesh Venkatraman
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Patent number: 8277525Abstract: A high energy transport gas and a method to transport the high energy transport gas are used to increase the energy content of a pipeline and other vessels that are designed to carry natural gas under ambient conditions, in a compressed state or in a liquefied state. Methane and other gases are used as the feedstock, with methane from natural gas fields, coal beds or derived from hydrogen reacting with coal being primary energy sources. Also, this gas and method can provide an abundant source for hydrogen production, and the energy from hydrogen can be used for fuel cell applications that generate electricity and power motor vehicles. This gas and method are capable of increasing the energy capacity of current natural gas pipelines and other storage and transport vessels.Type: GrantFiled: August 2, 2004Date of Patent: October 2, 2012Inventor: Robert C. Dalton
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Publication number: 20120233921Abstract: A generally upright reactor system for gasifying a feedstock. The reactor system generally includes a main body, at least two inlet projections extending outwardly from the main body, and at least one inlet positioned on each of the inlet projections. Each of the inlets is operable to discharge the feedstock into the reaction zone.Type: ApplicationFiled: May 31, 2012Publication date: September 20, 2012Applicant: PHILLIPS 66 COMPANYInventors: Steven L. Douglas, Ronald W. Herbanek, David L. Breton, Steven E. Chichester
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Patent number: 8268026Abstract: A method for controlling the synthesis gas composition obtained from a steam methane reformer (SMR) that obtains its feedstock as product gas directly from a steam hydro-gasification reactor SHR). The method allows control of the H2/CO syngas ratio by adjusting the hydrogen feed and the water content of feedstock into a steam hydro-gasification reactor that supplies the SMR. The steam and methane rich product gas of the SHR is generated by means of hydro-gasification of a slurry of carbonaceous material and water. The mass percentages of the product stream at each stage of the process are calculated using a modeling program, such as the ASPEN PLUS™ equilibrium process. By varying the parameters of solid to water ratio and hydrogen to carbon ratio, a sensitivity analysis can be performed that enables one determine the optimum composition of the slurry feedstock to the SHR to obtain a desired syngas ratio output of the SMR.Type: GrantFiled: July 16, 2007Date of Patent: September 18, 2012Assignee: The Regents of the University of CaliforniaInventors: Joseph M. Norbeck, Chan Seung Park, Arun Sk Raju
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Publication number: 20120222355Abstract: An apparatus for thermochemical conversion of solid carbonaceous materials into fluid fuels using a fluid source of oxygen and an external source of concentrated radiation includes a reactor having a wall defining a cavity; a radiation inlet positioned in the wall for passing concentrated radiation into the cavity; and at least one inlet for introducing a fluid reactant flow of a source of oxygen and particles of carbonaceous material into direct exposure to the concentrated radiation in the cavity so as to heat and thermochemically convert the particles into fluid fuel. A process and system are also provided. The fluid source of oxygen is preferably steam and the carbonaceous material is preferably particles of petcoke.Type: ApplicationFiled: January 22, 2008Publication date: September 6, 2012Applicants: CIEMAT, ETHZ (SWISS FEDERAL INSTITUTE OF TECHNOLOGY)Inventors: Philipp Haueter, Andreas Z'Graggen, Dominic Trommer, Aldo Steinfeld, Manuel Romero, Juan Carlos De Jesus, Domingo Rodriguez, Alfredo Morales, Julian Blanco
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Patent number: 8257453Abstract: An object of the invention is to enhance gasification efficiency of flammable solid content when high fuel ratio fuel having fixed carbon content in large quantity is to be gasified. A material downcomer 11 for introduction of bed material 10 separated in a material separator 9 and a fuel supply port 21 for introduction of gasification fuel 12 are arranged at one side of a gasification furnace 2; a solid content supply port 19 for supply of flammable solid content 18 and the bed material 10 in the gasification furnace 2 to the combustion furnace 1 is arranged at the other side of the gasification furnace 2. In the gasification furnace 2 and between the one and the other sides of the furnace 2, vertical partition plates 22 are arranged to provide a zigzag curved flow passage 23 with upper and lower turns.Type: GrantFiled: February 22, 2007Date of Patent: September 4, 2012Assignee: IHI CorporationInventors: Takahiro Murakami, Koubun Kyo, Toshiyuki Suda
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Patent number: 8257454Abstract: An apparatus for thermochemical conversion of solid carbonaceous materials into fluid fuels using a fluid source of oxygen and an external source of concentrated radiation includes a reactor having a wall defining a cavity; a radiation inlet positioned in the wall for passing concentrated radiation into the cavity; and at least one inlet for introducing a fluid reactant flow of a source of oxygen and particles of carbonaceous material into direct exposure to the concentrated radiation in the cavity so as to heat and thermochemically convert the particles into fluid fuel. A process and system are also provided. The fluid source of oxygen is preferably steam and the carbonaceous material is preferably particles of petcoke.Type: GrantFiled: January 22, 2008Date of Patent: September 4, 2012Assignee: Intevep, S.A.Inventors: Philipp Haueter, Andreas Z'Graggen, Dominic Trommer, Aldo Steinfeld, Manuel Romero, Juan Carlos De Jesus, Domingo Rodriguez, Alfredo Morales, Julian Blanco
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Patent number: 8252072Abstract: A downdraft-updraft gasifier (1) and method for the gasification of biomass and waste to produce combustible effluent, the gasifier comprising: a fuel valve (22) for loading solid fuel (11) into a first oxidation zone (8); a first throat (2) defining the lower edge of the first oxidation zone (8); a second throat (4) defining the lower edge of a second oxidation zone (14); a reduction zone (5) linking the first oxidation zone (8) to the second oxidation zone (14) and a vortex discharge pipe (18) for the combustible effluent. The method includes steps of: partially oxidising a biomass fuel in the first oxidation zone (8) to produce char; reducing the char in the reduction zone (5) to form ash; further oxidising any char residue in the ash in the second oxidation zone (14); and extracting the combustible effluent produced in the above steps, by the discharge pipe (18).Type: GrantFiled: May 2, 2006Date of Patent: August 28, 2012Assignee: ITI Energy LimitedInventors: Murat Dogru, Galip Akay
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Patent number: 8252074Abstract: Method of operating a fixed bed dry bottom gasifier includes feeding coarse particulate coal with an average particle size of at least 1 mm and an ash fusion temperature increasing agent into a gasification chamber of the gasifier to form a coal bed, feeding a gasification agent into the gasification chamber, and gasifying the coarse particulate coal in the gasification chamber to produce synthesis gas as well as ash. The ash is collected in an ash bed below the coal, and the synthesis gas and the ash are removed from the gasification chamber.Type: GrantFiled: January 26, 2006Date of Patent: August 28, 2012Assignee: Sasol-Lurgi Technology Company (Proprietary) LimitedInventors: Johannes Christoffel Van Dyk, Margaretha Coertzen
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Patent number: 8246700Abstract: An improved process to reduce emissions converts carbon dioxide from the flue gas exhaust from heat or power generators, into synthetic gas which is in-turn reintroduced back into the generator as fuel, is herein disclosed. Hot flue and exhaust gases from power generators, which contain carbon dioxide, would be blown into a gasification reactor, which contains coal, wood chips or other carbon based fuels substances. The process utilizes gasification technology to create a thermochemical reaction between the carbon dioxide and the fuel via a high temperature and no-oxygen atmosphere to produce synthetic gas. The synthetic gas includes carbon monoxide and hydrogen which is then fed back into a heat or power generator as fuel. The process may include two (2) or more reactors, thereby allowing one (1) reactor to be loaded or unloaded while synthetic gas continues to be produced by the other reactor. The synthetic gas may also be further converted into vehicle fuels and other useful chemicals.Type: GrantFiled: December 8, 2008Date of Patent: August 21, 2012Inventor: Leonid Kutsin
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Patent number: 8221513Abstract: Systems and processes for producing synthesis gas. A carbonaceous feedstock can be combined with one or more low-oxygen carrier fluids having a high heating value. The feedstock and carrier fluid, in the presence of one or more oxidants, can be gasified to provide a synthesis gas. In one or more embodiments, at least a portion of the synthesis gas can be recycled for use as the carrier fluid.Type: GrantFiled: January 29, 2008Date of Patent: July 17, 2012Assignee: Kellogg Brown & Root LLCInventors: Siva Ariyapadi, John Abughazaleh, Ravindra K. Agrawal
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Patent number: 8211191Abstract: A generally upright reactor system for gasifying a feedstock. The reactor system generally includes a main body, at least two inlet projections extending outwardly from the main body, and at least one inlet positioned on each of the inlet projections. Each of the inlets is operable to discharge the feedstock into the reaction zone.Type: GrantFiled: August 7, 2007Date of Patent: July 3, 2012Assignee: Phillips 66 CompanyInventors: Steven L. Douglas, Ronald W. Herbanek, David L. Breton, Steven E. Chichester
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Patent number: 8197566Abstract: Embodiments disclosed herein provide hydrocarbon additives and methods of making and using the same. The additives are suitable for use in conjunction with gasifiers, furnaces, or other high-temperature vessels. The additives may be part of an input stream to a reaction vessel of a hydrocarbon gasifier. The additives may include materials that at least partially reduce the infiltration of slag into the refractory material.Type: GrantFiled: December 8, 2008Date of Patent: June 12, 2012Assignee: General Electric CompanyInventors: Peter Joel Meschter, Paul Stephen Dimascio
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Patent number: 8197565Abstract: A system of the interrelated chemical engineering processes that continuously and simultaneously gasify and utilize of an organic-inorganic raw material or municipal solid waste (MSW) and completely or entirely decompose and transform said raw material, synthesize synthetic gas (syngas) and water steam gas mixture, and melt inorganic materials that are made further treatment and correspondingly processed into following consumable and fully marketable materials or products: syngas fuel, electricity, methanol or gasoline, chemical materials, glassy slag and concrete/road filling materials, multi-metal alloy and cast metal goods, greenhouse made green mass, and hot water; said system of chemical engineering processes does not need or use fossil fuel and electric power supplied from external sources; and said system of processes excludes an emission of nitrogen oxide, carcinogenic, and hazardous gases, and air pollutant particles, excludes production of ash or secondhand waste, and makes unsubstantial a carbon diType: GrantFiled: March 31, 2008Date of Patent: June 12, 2012Inventors: Anatoliy Rokhvarger, Vladimir Boyko
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Patent number: 8192514Abstract: A fixed bed coal gasifier (300) includes a coal gasification chamber with a coal lock above the chamber. A static coal distribution device inside the gasification chamber includes a hollow coal distributor which flares downwardly outwardly with a skirt depending downwardly from an inside of the coal distributor so that a gas collection zone is defined between the skirt and the coal distributor. The gasifier (300) has an ash discharge outlet (606) and a rotatable grate (600) above the outlet (606). The rotatable grate (600) includes at least one upwardly projecting finger or disturbing formation (500) to disturb the ash bed formed in use above and around the grate (600).Type: GrantFiled: November 30, 2005Date of Patent: June 5, 2012Assignee: Sasol Technology (Proprietary) LimitedInventors: Jacobus Andreas Stadler, Eric Graham Van De Venter, Paul Smit Baumann
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Patent number: 8182771Abstract: A system comprising a multi-stage reactor. The multi-stage reactor may include a water gas shift (WGS) reactor and a sour methanation reactor configured to generate methane without prior removal of acid gas. Furthermore, the multistage reactor may be a single unit having both the WGS reactor and the methanation reactor.Type: GrantFiled: April 22, 2009Date of Patent: May 22, 2012Assignee: General Electric CompanyInventors: Arnaldo Frydman, Ke Liu
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Publication number: 20120102834Abstract: A gasifier system which includes a reactor; a feedstock inlet; an oxidant inlet; a raw product gas outlet; and a recycle conduit, is provided. The reactor usually includes an upper section, a central section, and a lower section. The feedstock inlet is disposed in the upper section of the reactor to receive a carbonaceous feedstock. The oxidant inlet is disposed in the lower section of the reactor to receive an oxidant. The raw product gas outlet is disposed in the upper section of the reactor. The recycle conduit is configured to couple the raw product gas outlet to the lower section of the reactor, and to recycle a raw product gas from the upper section of the reactor to the lower section of the reactor. A method for converting a carbonaceous stream into a product gas in a gasifier system is also provided.Type: ApplicationFiled: October 29, 2010Publication date: May 3, 2012Applicant: GENERAL ELECTRIC COMPANYInventors: Surinder Prabhjot Singh, Vitali V. Lissianski, Aaron John Avagliano, Wolfgang Madl
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Patent number: 8163048Abstract: The present invention relates to catalyst-loaded coal compositions having a moisture content of less than about 6 wt %, a process for the preparation of catalyst-loaded coal compositions, and an integrated process for the gasification of the catalyst-loaded coal compositions. The catalyst-loaded coal compositions can be prepared by a diffusive catalyst loading process that provides for a highly dispersed catalyst that is predominantly associated with the coal matrix, such as by ion-exchange.Type: GrantFiled: July 23, 2008Date of Patent: April 24, 2012Assignee: Greatpoint Energy, Inc.Inventors: Alkis S. Rappas, George Frederick Salem, Edwin J. Hippo
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Publication number: 20120085079Abstract: Exemplary embodiments of the present technology provide systems and methods for producing power from coalbed methane (CBM) with decreased CO2 emissions. For example, a method of producing power according to an exemplary embodiment includes converting a feedstock from a hydrocarbon source into a gas mixture comprising CO2 and H2. The gas mixture is injected into a coalbed to cause CBM to desorb from the coal and CO2 to adsorb onto the coal. The hydrocarbon source is separate from the coalbed, i.e., does not exchange hydrocarbons with the hydrocarbon source. A gas mixture is produced from the coalbed, wherein the produced gas mixture includes H2 and CH4. The gas mixture may be combusted to generate power, while releasing lower amounts of CO2 than would be released from the combustion of pure CH4.Type: ApplicationFiled: May 13, 2010Publication date: April 12, 2012Inventor: Robert D. Kaminsky
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Patent number: 8152874Abstract: A system and method for producing multiple syngas products. In one embodiment (FIG. 5) a syngas producing system (200) includes a gasifier (210) and a hydrocarbon steam reformer (226). The gasifier (210) is configured to react a solid or liquid carbonaceous material (212) and provide a first syngas product (222). The reformer (226) is coupled to receive sensible heat from the first syngas product (222) and drive an endothermic reaction in which a second syngas product (238) is produced from a liquid or gaseous hydrocarbon supply (150). In a method of processing fuel, a solid or liquid carbonaceous material (212) is provided to a gasifier (210) in the form of a slurry, which is converted into a first syngas product (222) in an exothermic reaction. A liquid or gaseous hydrocarbon supply (150) receives sufficient sensible heat generated during the exothermic reaction to convert the liquid or gaseous hydrocarbon supply (150) into a second syngas product (238).Type: GrantFiled: June 19, 2006Date of Patent: April 10, 2012Assignee: Siemens Energy, Inc.Inventors: Michael S. Briesch, Juan P. Gutierrez
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Patent number: 8152875Abstract: A method for producing methane (69) from a carbonaceous (22) material includes conveying pulverized carbonaceous material (28) entrained in an inert carrier fluid, such as carbon dioxide (36), into a reactor (34). The reactor (34) includes a vortex region (72) for receiving hydrogen gas (38) and imparting a swirling motion to the hydrogen gas (38). The pulverized carbonaceous material (28) is exposed to the swirling stream of hydrogen gas (38) in a first reaction zone (114) within the reactor (34) to form an exit gas (40) that includes methane (69). Remaining unreacted carbonaceous material (28) is further exposed to the hydrogen gas (38) in a second, low velocity, reaction zone (120). The methane rich exit gas (40) is subsequently extracted from the reactor (34) for further processing.Type: GrantFiled: August 18, 2009Date of Patent: April 10, 2012Assignee: Arizona Public Service CompanyInventor: Raymond S Hobbs
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Publication number: 20120056431Abstract: Efficient coal pre-processing systems (69) integrated with gasification, oxy-combustion, and power plant systems include a drying chamber (28), a volatile metal removal chamber (30), recirculated gases, including recycled carbon dioxide (21), nitrogen (6), and gaseous exhaust (60) for increasing the efficiencies and lowering emissions in various coal processing systems.Type: ApplicationFiled: May 24, 2010Publication date: March 8, 2012Applicant: The University of Wyoming Research Corporation d/b/a Western Research InstituteInventors: Alan E. Bland, Kumar Muthusami Sellakumar, Jesse D. Newcomer