Zirconium Oxide Patents (Class 501/103)
  • Publication number: 20130136893
    Abstract: Disclosed are ceramic articles comprising ceramic honeycomb bodies and an aqueous composition, for example in the form of a cold-set plug, as well as processes for preparing ceramic articles and processes for making an aqueous composition for use with ceramic articles, for example as a cold-set plug composition.
    Type: Application
    Filed: November 30, 2011
    Publication date: May 30, 2013
    Inventors: Keith Norman Bubb, Anthony Joseph Cecce, Thomas Richard Chapman
  • Patent number: 8408902
    Abstract: A material for dentures having a 3-point bending strength of at least 1300 MPa, dentures produced from said type of material, corresponding blank materials, a method for producing blanks, and a method for producing a denture part made from said material or a blank.
    Type: Grant
    Filed: June 18, 2007
    Date of Patent: April 2, 2013
    Assignee: Institut Straumann AG
    Inventors: Stephan Holzner, Gerhard Weber
  • Patent number: 8399372
    Abstract: In one aspect, the invention includes a refractory material, said material comprising: (i) at least 20 wt. % of a first grain mode stabilized zirconia based upon the total weight of said material, said first grain mode having a D50 grain size in the range of from 5 to 2000 ?m, said stabilized zirconia including a matrix oxide stabilizer; (ii) at least 1 wt. % of a second grain mode having a D50 grain size in the range of from 0.01 ?m up to not greater than one-fourth the D50 grain size of said first grain mode zirconia, based upon the total weight of said material; and (iii) at least 1 wt. % of a preservative component within at least one of said first grain mode stabilized zirconia, said second grain mode stabilized zirconia, and an optional another grain mode; wherein after sintering, said material has porosity at 20° C. in the range of from 5 to 45 vol %.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: March 19, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: ChangMin Chun, Frank Hershkowitz
  • Patent number: 8394484
    Abstract: This invention relates to thermally sprayed coatings of a high purity yttria or ytterbia stabilized zirconia powder, said high purity yttria or ytterbia stabilized zirconia powder comprising from about 0 to about 0.15 weight percent impurity oxides, from about 0 to about 2 weight percent hafnium oxide (hafnia), from about 6 to about 25 weight percent yttrium oxide (yttria) or from about 10 to about 36 weight percent ytterbium oxide (ytterbia), and the balance zirconium oxide (zirconia). Thermal barrier coatings for protecting a component such as blades, vanes and seal surfaces of gas turbine engines, made from the high purity yttria or ytterbia stabilized zirconia powders, have a density greater than 88% of the theoretical density with a plurality of vertical macrocracks homogeneously dispersed throughout the coating to improve its thermal fatigue resistance.
    Type: Grant
    Filed: April 27, 2007
    Date of Patent: March 12, 2013
    Assignee: Praxair Technology, Inc.
    Inventors: Thomas Alan Taylor, Danny Lee Appleby, Albert Feuerstein, Ann Bolcavage, Neil Hitchman
  • Publication number: 20130045856
    Abstract: The present invention resides in a refractory composition for use as a cold start slag band. The composition comprises an admixture of partially stabilised zirconia and/or fully stabilised zirconia and monoclinic zirconia, characterised in that the proportion of monoclinic relative to the total zirconia content is at least 40% by weight. The invention also resides in a slag band formed from the composition, a submerged entry nozzle incorporating the slag band and a method of forming such a submerged entry nozzle.
    Type: Application
    Filed: February 12, 2009
    Publication date: February 21, 2013
    Inventors: Norman Edward Rogers, David Kennedy
  • Patent number: 8376318
    Abstract: A powder including: (a) more than 92% of zircon particles; (b) 1% to 2% of silica particles having a size less than 50 microns; (c) 0.3% to 5% of particles comprising one, two, or three oxides selected from CaO, MgO, and Y2O3; (d) less than 1% of particles comprising other oxides; the powder also being such that it includes: more than 5% of zircon aggregate particles having a size greater than 1 mm; and 8% to 20% of zircon matrix particles having a size less than 15 ?m and including, for more than 95% of the weight thereof, a monoclinic phase.
    Type: Grant
    Filed: March 10, 2010
    Date of Patent: February 19, 2013
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Franceline Villermaux, Thibault Champion, Christian His
  • Patent number: 8367227
    Abstract: Specialty ceramic materials which resist corrosion/erosion under semiconductor processing conditions which employ a corrosive/erosive plasma. The corrosive plasma may be a halogen-containing plasma. The specialty ceramic materials have been modified to provide a controlled electrical resistivity which suppresses plasma arcing potential.
    Type: Grant
    Filed: August 2, 2007
    Date of Patent: February 5, 2013
    Assignee: Applied Materials, Inc.
    Inventors: Jennifer Y. Sun, Kenneth S. Collins, Ren-Guan Duan, Senh Thach, Thomas Graves, Xiaoming He, Jie Yuan
  • Patent number: 8357625
    Abstract: An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.
    Type: Grant
    Filed: June 18, 2009
    Date of Patent: January 22, 2013
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Atsushi Okamoto
  • Patent number: 8329296
    Abstract: The invention relates to primary particles of oxide-ceramic material, wherein the primary particles have an average particle size in the range from 10 to 1000 nm and are coated with a chromophoric component, a process for their preparation and their use in particular in the preparation of ceramic moldings and dental restorations. The invention further relates to a suspension based on oxide-ceramic material which contains the primary particles, and a process for the preparation of a ceramic moldings.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: December 11, 2012
    Assignee: Ivoclar Vivadent AG
    Inventors: Elke Apel, Christian Ritzberger, Wolfram Holand, Christoph Appert, Wolfgang Wachter, Volker Rheinberger
  • Patent number: 8329605
    Abstract: The invention relates to a sintered product containing: in mass percent based on oxides, more than 99.5% of a material having a cubic crystallographic structure for more than 95% of the mass thereof, known as a material with a cubic structure, and having a refractive index of less than 2.75 in the wavelength range between 0.2 ?m and 5 ?m; and more than 50 ppma of dopants which must contain titanium oxide TiO2 and at least one additional dopant selected from ZrO2, CaO, and MgO, in which said at least one additional dopant is different from the oxide(s) forming the material with a cubic structure, but can be MgO when the material with a cubic structure is spinel MgAl2O4.
    Type: Grant
    Filed: June 13, 2008
    Date of Patent: December 11, 2012
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Guillaume Bernard-Granger, Nassira Benameur
  • Patent number: 8309015
    Abstract: A translucent zirconia sintered body, a dental article comprising a shaped, translucent zirconia body, a zirconia green body, and methods of making a translucent zirconia sintered body, methods of making a dental article comprising a shaped, translucent zirconia body, and methods of making a zirconia green body are described.
    Type: Grant
    Filed: July 7, 2011
    Date of Patent: November 13, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Jacqueline C. Rolf, Martin Goetzinger, Holger Hauptmann, Peter Bissinger, Ruediger Franke
  • Patent number: 8298329
    Abstract: Unlike conventional dental ceramic powder made by grinding, dental ceramic nanocrystals are formed by vaporization into individual particles. Tetragonal zirconia particles thus formed are not broken into pieces, and so do not transform to weaker monoclinic zirconia and weaker sintered products. The particles created by this approach can be much smaller, and dental prostheses sintered from this powder can be stronger and more realistic. For instance, the smaller size of sintered tetragonal zirconia crystals increases optical translucence by reducing scattering from birefringence, and the small average particle size and tight distribution of sizes and shapes can essentially eliminate pores in a sintered product. Cylindrical and spherical particles can be manufactured by this approach, whereas prior art dental ceramic particles were generally neither.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: October 30, 2012
    Assignee: James R. Glidewell Dental Ceramics, Inc.
    Inventors: Kenneth E. Knapp, Steven M. Maginnis, Wolfgang Friebauer, Robin A. Carden
  • Patent number: 8278231
    Abstract: In one aspect, the invention includes a heat stable, formed ceramic component that includes a multimodal grain distribution including (i) at least 50 wt % of coarse grains including stabilized zirconia, the coarse grains comprising a D50 grain size in the range of from 5 to 800 ?m, based upon the total weight of the component; and (ii) at least 1 wt % of fine grains comprising a D50 average grain size not greater than one-fourth the D50 grain size of the coarse grain, dispersed within the coarse grains, based upon the total weight of the component; wherein after sintering, the component has porosity at ambient temperature in the range of from 5 to 45 vol. %, based on the formed volume of the component.
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: October 2, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Changmin Chun, Frank Hershkowitz
  • Publication number: 20120227445
    Abstract: A refractory object can include at least 10 wt % Al2O3. In an embodiment, the refractory object can further include a dopant including an oxide of a rare earth element, Ta, Nb, Hf, or any combination thereof. In another embodiment, the refractory object may have a property such that the averaged grain size does not increase more than 500% during sintering, an aspect ratio less than approximately 4.0, a creep rate less than approximately 1.0×10?5 ?m/(?m×hr), or any combination thereof. In a particular embodiment, the refractory object can be in the form of a refractory block or a glass overflow forming block. The glass overflow forming block can be useful in forming an Al—Si—Mg glass sheet. In a particular embodiment, a layer including Mg—Al oxide can initially form along exposed surfaces of the glass overflow forming block when forming the Al—Si—Mg glass sheet.
    Type: Application
    Filed: March 9, 2012
    Publication date: September 13, 2012
    Applicant: SAINT-GOBAIN CERAMICS & PLASTICS, INC.
    Inventors: Olivier Citti, Andrea Kazmierczak
  • Patent number: 8242037
    Abstract: Methods of making and compositions of dense sintered ceramic nano- and micro-composite materials that are highly stable in a variety of conditions and exhibit superior toughness and strength. Liquid feed flame spray pyrolysis techniques form a plurality of nanoparticles (e.g., powder), each having a core region including a first metal oxide composition comprising Ce and/or Zr or other metals and a shell region including a second metal oxide composition comprising Al or other metals. In certain aspects, the core region comprises a partially stabilized tetragonal ZrO2 and the shell region comprises an ?-Al2O3 phase. The average actual density of the ceramic after sintering is greater than 50% and up to or exceeding 90% of a theoretical density of the ceramic.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: August 14, 2012
    Assignee: The Regents of the University of Michigan
    Inventors: Richard M. Laine, Min Kim
  • Patent number: 8231961
    Abstract: A low temperature co-fired ceramic material includes a SiO2—BaO—Al2O3-based primary component, and, as secondary components, 0.044 to 0.077 parts by weight of iron in terms of Fe2O3 and 0.30 to 0.55 parts by weight of zirconium in terms of ZrO2 relative to 100 parts by weight of the SiO2—BaO—Al2O3-based primary component. The SiO2—BaO—Al2O3-based primary component preferably includes 47% to 60% by weight of SiO2, 20% to 42% by weight of BaO, and 5% to 30% by weight of Al2O3.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: July 31, 2012
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Tomoya Yokoyama, Yuzo Kawada, Akira Baba, Hiromichi Kawakami, Isao Kato
  • Patent number: 8227365
    Abstract: The present invention provides biocidal ceramic compositions incorporating a bioactive ionic species that is chemically bound in a substantially single-phase, crystalline, [NZP]-type structure, methods for producing the crystalline structures, and articles of manufacture incorporating the crystalline structures, and uses of the articles of manufacture. Bioactive ionic species can be, but are not limited to, Ag, Cu, Ni, Zn, Mn, Sn, Co, H, and combinations thereof.
    Type: Grant
    Filed: June 8, 2006
    Date of Patent: July 24, 2012
    Inventor: Ramachandran Nageswaran
  • Publication number: 20120183790
    Abstract: This invention relates to thermal spray composite coatings on a metal or non-metal substrate. The thermal spray composite coatings comprise a ceramic composite coating having at least two ceramic material phases randomly and uniformly dispersed and/or spatially oriented throughout the ceramic composite coating. At least a first ceramic material phase is present in an amount sufficient to provide corrosion resistance to the ceramic composite coating, and at least a second ceramic material phase is present in an amount sufficient to provide plasma erosion resistance to the ceramic composite coating. This invention also relates to methods of protecting metal and non-metal substrates by applying the thermal spray coatings. The composite coatings provide erosion and corrosion resistance at processing temperatures higher than conventional processing temperatures used in the semiconductor etch industry, e.g., greater than 100° C.
    Type: Application
    Filed: July 12, 2011
    Publication date: July 19, 2012
    Inventors: Christopher Petorak, Graeme Dickinson, Neill Jean McDill
  • Publication number: 20120177836
    Abstract: The present invention provides a high-purity fused and crushed stabilized zirconia powder. The powder—with or without further processing, such as plasma spheroidization—is used in thermal spray applications of thermal barrier coatings (TBCs) and high-temperature abradables. The resulting coatings have a significantly improved high temperature sintering resistance, which will enhance the durability and thermal insulation effect of the coating.
    Type: Application
    Filed: April 25, 2007
    Publication date: July 12, 2012
    Inventors: Jacobus C. Doesburg, Mitchell R. Dorfman, Liangde Xie
  • Publication number: 20120122651
    Abstract: This invention relates to high purity yttria or ytterbia stabilized zirconia powders comprising from about 0 to about 0.15 weight percent impurity oxides, from about 0 to about 2 weight percent hafnium oxide (hafnia), from about 6 to about 25 weight percent yttrium oxide (yttria) or from about 10 to about 36 weight percent ytterbium oxide (ytterbia), and the balance zirconium oxide (zirconia). Thermal barrier coatings for protecting a component such as blades, vanes and seal surfaces of gas turbine engines, made from the high purity yttria or ytterbia stabilized zirconia powders, have a density greater than 88% of the theoretical density with a plurality of vertical macrocracks homogeneously dispersed throughout the coating to improve its thermal fatigue resistance.
    Type: Application
    Filed: April 27, 2007
    Publication date: May 17, 2012
    Inventors: Thomas Alan Taylor, Danny Lee Appleby, Albert Feuerstein, Ann Bolcavage, Neil Hitchman, James Munroe
  • Patent number: 8173562
    Abstract: The invention relates to compositions based on Ce-stabilized ZrO2, and single- and multi-colored blanks made from oxide ceramics, and a process for their preparation, in which oxide ceramic powder is coated with a coloring substance, the coated powders are preferably graded and at least one colored powder is filled into a compression mould, the colored powder or powders are compressed to produce a shaped body, and the compressed shaped body is sintered to produce a blank, and to the use of these blanks for the preparation of dental restorations. The compositions exhibit high fracture toughness and high flexural strength.
    Type: Grant
    Filed: June 13, 2008
    Date of Patent: May 8, 2012
    Assignee: Ivoclar Vivadent AG
    Inventors: Wolfram Höland, Christian Ritzberger, Elke Apel, Frank Rothbrust, Jerome Chevalier, Dmitri Brodkin
  • Patent number: 8173564
    Abstract: A gasifier comprising an interior wall on which a layer is applied or an interior wall protected by an assembly of blocks, said layer or said blocks having at least one region of a sintered material containing: i) at least 25% by weight of chromium oxide Cr2O3; and ii) at least 1% by weight of zirconium oxide, wherein at least 20% by weight of said zirconium oxide ZrO2 is stabilized in the cubic and/or quadratic form.
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: May 8, 2012
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Thibault Pierre Paul Champion, Christian Claude His, Franceline Marguerite Louise Villermaux
  • Patent number: 8168554
    Abstract: The invention relates to a molten ceramic particle, characterized in that it has the following chemical composition in wt % based on oxides and for a total of 100%: 55%<ZrO2+HfO2<70%; 20%<SiO2<30%; 6.5%<MgO<9.5%; Al2O3 in an amount such that the mass ratio MgO/Al2O3 is comprised between 2.4 and 6.6; and less than 0.6% of other oxides.
    Type: Grant
    Filed: October 11, 2007
    Date of Patent: May 1, 2012
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Yves Boussant-Roux, Emmanuel Nonnet
  • Patent number: 8133831
    Abstract: Slip for use in a hot-melt inkjet printing process which contains (A) ceramic particles, (B) wax and (C) at least one radically polymerizable monomer, and use of the slip to prepare dental restorations. Furthermore, a process for the preparation of a green compact is described, in which the slip is molded in layers to the geometrical shape of the green compact and subjected to a radical polymerization in order to obtain a cured green compact.
    Type: Grant
    Filed: July 7, 2009
    Date of Patent: March 13, 2012
    Assignee: Ivoclar Vivadent AG
    Inventors: Jurgen Laubersheimer, Gianluca Zappini, Volker M. Rheinberger
  • Patent number: 8124554
    Abstract: The present invention provides a fused cast refractory block comprising a mean zirconia (ZrO2+HfO2) content of more than 85% as a percentage by weight based on the oxides, and with a standard deviation ? of the local zirconia content divided by the volume of the block of less than 7.5.
    Type: Grant
    Filed: February 22, 2008
    Date of Patent: February 28, 2012
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Yves Boussant-Roux, Edouard Schiavo, Alain Zanoli
  • Patent number: 8114800
    Abstract: There is described a ceramic powder, ceramic layer and layer system having gadolinium/mixed crystal pyrochlore phases and oxides. Besides a good thermal insulation property, thermal insulation layer systems must also have a long lifetime of the thermal insulation layer. The layer system according to the invention has an outer ceramic layer, which comprises a mixed crystal of gadolinium zirconate and gadolinium hafnate.
    Type: Grant
    Filed: May 6, 2008
    Date of Patent: February 14, 2012
    Assignee: Siemens Aktiengesellschaft
    Inventor: Ramesh Subramanian
  • Publication number: 20120034469
    Abstract: A ceramic article useful in semiconductor processing, which is resistant to erosion by halogen-containing plasmas. The ceramic article is formed from a combination of yttrium oxide and zirconium oxide. In a first embodiment, the ceramic article includes ceramic which is formed from yttrium oxide at a molar concentration ranging from about 90 mole % to about 70 mole %, and zirconium oxide at a molar concentration ranging from about 10 mole % to about 30 mole %. In a second embodiment, the ceramic article includes ceramic which is formed from zirconium oxide at a molar concentration ranging from about 96 mole % to about 94 mole %, and yttrium oxide at a molar concentration ranging from about 4 mole % to about 6 mole %.
    Type: Application
    Filed: August 31, 2011
    Publication date: February 9, 2012
    Applicant: Applied Materials, Inc.
    Inventors: Jennifer Y. Sun, Ren-Guan Duan, Jie Yuan, Li Xu, Kenneth S. Collins
  • Publication number: 20120018007
    Abstract: A powder including: (a) more than 92% of zircon particles, (b) 1% to 2% of silica particles having a size less than 50 microns; (c) 0.3% to 5% of particles comprising one, two, or three oxides selected from CaO, MgO, and Y2O3; (d) less than 1% of particles comprising other oxides; the powder also being such that it includes: more than 5% of zircon aggregate particles having a size greater than 1 mm; and 8% to 20% of zircon matrix particles having a size less than 15 ?m and including, for more than 95% of the weight thereof, a monoclinic phase.
    Type: Application
    Filed: March 10, 2010
    Publication date: January 26, 2012
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET' D'ETUDES EUROPEEN
    Inventors: Franceline Villermaux, Thibault Champion, Christian His
  • Patent number: 8084382
    Abstract: There is described a Ceramic Powder, a Ceramic Layer and a Layer System with Pyrochlore Phase and Oxides. Besides a good thermal insulation property, thermal insulation layer systems must also have a long lifetime of the thermal insulation layer. A described layer system has a layer sequence of a metallic bonding layer, an inner ceramic layer and an outer ceramic layer, which are specially matched to one another.
    Type: Grant
    Filed: May 6, 2008
    Date of Patent: December 27, 2011
    Assignee: Siemens Aktiengesellschaft
    Inventor: Ramesh Subramanian
  • Publication number: 20110294651
    Abstract: Method for producing a mold for use in casting reactive metals comprising preparing a slurry of a yttria-based refractory composition and a binder, and using said slurry as a mold facecoat by applying said slurry onto a surface of a mold pattern, wherein said yttria-based refractory composition is obtainable by (a) mixing particles of a yttria-based ceramic material and a fluorine containing dopant, and (b) heating the resulting mixture to effect fluorine-doping of said yttria-based ceramic material.
    Type: Application
    Filed: May 24, 2011
    Publication date: December 1, 2011
    Inventors: Peter JANZ, Sigrun TAUBER
  • Patent number: 8067326
    Abstract: Refractory materials are provided which contain P2O5/R2O3 constituents, where R is Y, Sc, Er, Lu, Yb, Tm, Ho, Dy, Tb, Gd, or a combination thereof, and/or V2O5/R?2O3 constituents where R? is Y, Sc, one or more rare earth elements, or a combination thereof. In certain embodiments, the refractory materials are xenotime-type materials and/or xenotime-stabilized zircon-type materials. The refractory materials can be used in the manufacture of glass and glass-ceramics. For example, the refractory materials, especially those that contain P2O5/R2O3 constituents, can be used as forming structures (“isopipes”) in the fusion process for making flat sheets of glass such as the glass sheets used as substrates in the manufacture of flat panel displays.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: November 29, 2011
    Assignee: Corning Incorporated
    Inventors: Hilary Tony Godard, Cameron Wayne Tanner, Michelle M Wallen, Elizabeth Margaret Wheeler
  • Publication number: 20110269618
    Abstract: Unlike conventional dental ceramic powder made by grinding, dental ceramic nanocrystals are formed by vaporization into individual particles. Tetragonal zirconia particles thus formed are not broken into pieces, and so do not transform to weaker monoclinic zirconia and weaker sintered products. The particles created by this approach can be much smaller, and dental prostheses sintered from this powder can be stronger and more realistic. For instance, the smaller size of sintered tetragonal zirconia crystals increases optical translucence by reducing scattering from birefringence, and the small average particle size and tight distribution of sizes and shapes can essentially eliminate pores in a sintered product. Cylindrical and spherical particles can be manufactured by this approach, whereas prior art dental ceramic particles were generally neither.
    Type: Application
    Filed: April 29, 2010
    Publication date: November 3, 2011
    Inventors: Kenneth E. Knapp, Steven M. Maginnis, Wolfgang Friebauer, Robin A. Carden
  • Publication number: 20110262770
    Abstract: A thermal barrier coating material that exhibits superior high-temperature crystal stability to YSZ, as well as a high degree of toughness and an excellent thermal barrier effect. Also provided are a thermal barrier coating, which has a ceramic layer formed using the thermal barrier coating material and exhibits excellent durability to heat cycling, and a turbine member and a gas turbine which are each provided with the thermal barrier coating. The thermal barrier coating material comprises mainly ZrO2 which contains Yb2O3 and Sm2O3 as stabilizers, wherein the amount of the stabilizers is not less than 2 mol % and not more than 7 mol %, and the amount of the Sm2O3 is not less than 0.1 mol % and not more than 2.5 mol %.
    Type: Application
    Filed: November 27, 2009
    Publication date: October 27, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Taiji Torigoe, Ichiro Nagano, Ikuo Okada, Keizo Tsukagoshi, Koji Takahashi, Yoshifumi Okajima, Soji Kasumi, Eisaku Ito, Kazutaka Mori
  • Patent number: 8034734
    Abstract: A solid solution-comprising ceramic article useful in semiconductor processing, which is resistant to erosion by halogen-containing plasmas. The solid solution-comprising ceramic article is formed from a combination of yttrium oxide and zirconium oxide. In a first embodiment, the ceramic article includes ceramic which is formed from yttrium oxide at a molar concentration ranging from about 90 mole % to about 70 mole %, and zirconium oxide at a molar concentration ranging from about 10 mole % to about 30 mole %. In a second embodiment, the ceramic article includes ceramic which is formed from zirconium oxide at a molar concentration ranging from about 96 mole % to about 94 mole %, and yttrium oxide at a molar concentration ranging from about 4 mole % to about 6 mole %.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: October 11, 2011
    Assignee: Applied Materials, Inc.
    Inventors: Jennifer Y. Sun, Ren-Guan Duan, Jie Yuan, Li Xu, Kenneth S. Collins
  • Publication number: 20110236695
    Abstract: A composite article includes a substrate and a protective layer disposed on the substrate. The protective layer has a silicon-aluminum-carbon-nitrogen solid solution composition and microstructure.
    Type: Application
    Filed: March 29, 2010
    Publication date: September 29, 2011
    Inventor: Wayde R. Schmidt
  • Patent number: 8025824
    Abstract: To provide a process for producing high-purity highly oxidized refractory particles easily with good productivity by treating a spent refractory containing ZrO2 and Al2O3 to reduce components other than ZrO2 and Al2O3 to levels unproblematic for practical use as raw material for electrofused refractories and to increase the content of the ZrO2 and/or Al2O3 component. A process for producing refractory particles, which comprises introducing to and melting in a melting furnace both a spent refractory which contains, by mass % as chemical components, from 75 to 97% of ZrO2 and/or Al2O3, from 2 to 25% of SiO2, from 0.4 to 7% in total of Na2O, K2O and Li2O(Na2O+K2O+Li2O), at most 2% of CaO and at most 2% of MgO, and carbon particles in an amount of from 1 to 8% by outer mass percentage based on the spent refractory, and after the melting, tapping the melt while blowing compressed air against the melt to form refractory particles having the content of ZrO2 and/or Al2O3 increased.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: September 27, 2011
    Assignee: AGC Ceramics Co., Ltd.
    Inventor: Yukihiro Ushimaru
  • Publication number: 20110230340
    Abstract: The present invention provides the use of a doped zirconia ceramic having a mean grain size of about 190 nm or less and consisting of the tetragonal zirconia crystallographic phase as a hydrothermally stable material or in an application that requires the use of a hydrothermally stable material. The present invention also provides a doped zirconia ceramic having a mean grain size of about 190 nm or less and consisting of tetragonal zirconia which does not undergo detectable tetragonal to monoclinic transformation during aging in moisture in an autoclave at a temperature of up to about 245° C. for up to 504 hours at a pressure of up to 7 bar.
    Type: Application
    Filed: November 27, 2009
    Publication date: September 22, 2011
    Inventors: Jon Binner, Balasubramaniam Vaidhyanathan, Ketharam Annapoorani, Anish Paul
  • Patent number: 8002885
    Abstract: Dental articles are produced using relatively low sintering temperatures to achieve high density dental articles exhibiting strengths equal to and greater than about 700 MPa. Ceramic powders comprised of nanoparticulate crystallites are used to manufacture dental articles. The ceramic powders may include sintering agents, binders and other similar additives to aid in the processing of the ceramic powder into a dental article. The ceramic powders may be processed into dental articles using various methods including, but not limited to, injection molding, gel-casting, slip casting, or electroforming, hand, cad/camming and other various rapid prototyping methods. The ceramic powder may be formed into a suspension, pellet, feedstock material or a pre-sintered blank prior to forming into the dental article.
    Type: Grant
    Filed: August 31, 2010
    Date of Patent: August 23, 2011
    Assignee: Pentron Ceramics, Inc.
    Inventors: Dmitri Brodkin, Moisey Y. Gamarnik
  • Publication number: 20110165335
    Abstract: A process for forming a coating on a substrate, such as a turbine engine component, is provided. The process comprises the steps of: providing a first rare earth oxide stabilized zirconia composition; providing a second composition selected from the group consisting of a yttria stabilized zirconia composition, a ceria stabilized zirconia composition, alumina, a chromia-alumina composition, a gadolinia stabilized zirconia composition, and mixtures thereof; blending the first rare earth oxide stabilized zirconia composition with the second composition to form a blended powder; and depositing the blended powder onto the substrate. Articles having the coating formed from the above process are also described.
    Type: Application
    Filed: March 16, 2011
    Publication date: July 7, 2011
    Applicant: UNITED TECHNOLOGIES CORPORATION
    Inventors: Kevin W. Schlichting, Paul H. Zajchowski, Susan Manning Meier
  • Publication number: 20110162374
    Abstract: An article, such as a bucket, a blade, a nozzle, a vane, a strut, a fuel nozzle, a combustion casing, and a transition piece, the article having a damping coating comprising approximately 8 wt % to approximately 15 wt % Y2O3 and approximately 19 wt % to approximately 28 wt % Ta2O5 with the balanced weight of ZrO2 is presented.
    Type: Application
    Filed: January 6, 2010
    Publication date: July 7, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: John McConnell Delvaux, Yuk-Chiu Lau
  • Patent number: 7968485
    Abstract: There is described a Ceramic Powder, a Ceramic Layer and a Layer System of Two Pyrochlore Phases and Oxides. Besides a good thermal insulation property, thermal insulation layer systems must also have a long lifetime of the thermal insulation layer. The layer system has a ceramic layer, which comprises a mixture of two pyrochlore phases.
    Type: Grant
    Filed: May 6, 2008
    Date of Patent: June 28, 2011
    Assignee: Siemens Aktiengesellschaft
    Inventor: Ramesh Subramanian
  • Publication number: 20110151227
    Abstract: Methods are provided to form and stabilize high-? dielectric films by vapor deposition processes using metal-source precursors and titanium-based ?-diketonate precursors according to Formula I: Ti(L)x wherein: L is a ?-diketonate; and x is 3 or 4. Further provided are methods of improving high-? gate property of semiconductor devices by using titanium precursors according to Formula I. High-? dielectric film-forming lattices are also provided comprising titanium precursors according to Formula I.
    Type: Application
    Filed: May 22, 2009
    Publication date: June 23, 2011
    Applicant: SIGMA-ALDRICH CO.
    Inventors: Paul Raymond Chalker, Peter Nicholas Heys
  • Publication number: 20110129784
    Abstract: The present disclosure relates to a silica-based crucible material that includes, before sintering or firing, selected amounts of a thermal expansion stabilizer component (B2O3 and Ca2SiO4) which impart improved thermal shock resistance and enhanced ability to withstand repeated thermal cycling, to a sintered or fired crucible made of the material. An illustrative embodiment of the invention provides a crucible material whose chemical composition comprises, in weight %, about 91% to about 98% SiO2, about 1% to about 8% thermal stabilizer component, and up to about 1.0% of additional oxides including MgO, Al2O3 Fe2O3, CaO and ZrO2.
    Type: Application
    Filed: November 23, 2010
    Publication date: June 2, 2011
    Inventors: James Crawford Bange, Michael E. Collier, David I. Seymour, Ronald Leroy Stewart, Christopher L. Thomas
  • Publication number: 20110107796
    Abstract: The present invention relates to a sintered product elaborated from a starting charge containing 75-99% of zircon, in mass percentage based on the oxides and having the following average weight chemical composition, in mass percentages based on the oxides 60%?ZrO2?72.8%, 27%?SiO2?36%, 0.1%?B2O3+GeO2+P2O5+Sb2O3+Nb2O5+Ta2O5+V2O5, 0.1%?ZnO+PbO+CdO, B2O3+GeO2+P2O5+Sb2O3+Nb2O5+Ta2O5+V2O5+ZnO+PbO+CdO?5% 0% ?Al2O3+TiO2+MgO+Fe2O3+NiO+MnO2+CoO+CuO?5%, other oxides: ?1.5%, for a total of 100%. Notably used in a glass furnace.
    Type: Application
    Filed: April 14, 2009
    Publication date: May 12, 2011
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Olivier Citti, Julien Fourcade
  • Patent number: 7939462
    Abstract: The inventive composition, according to a first embodiment, consists essentially of a cerium oxide and a zirconium oxide. According to a second embodiment, said composition is based on cerium oxide, zirconium oxide and at least one rare earth oxide other than cerium. After a first 4-hour period of calcination at 900 .C followed by a second 10-hour period of at 1000 .C, the specific surface variation thereof is 20% maximum in the first embodiment and 15% maximum in the second embodiment. The inventive composition can be used as a catalyst, i.e. in the treatment of waste gases from internal combustion engines.
    Type: Grant
    Filed: March 17, 2004
    Date of Patent: May 10, 2011
    Assignee: Rhodia Operations
    Inventors: Olivier Larcher, Emmanuel Rohart, David Monin
  • Publication number: 20110105295
    Abstract: The invention relates to the field of synthetic materials and is industrially applicable in the manufacture of wear-resistant construction parts for use under conditions of elevated temperatures, loads, and aggressive media, for cutting and machining tools, and in medical equipment. The technical problem of optimization of the performance parameters of the material, including crack resistance, hardness, and wear resistance, is solved. The objective is achieved by the fact that a material based on zirconium dioxide, containing yttrium and obtained by directed crystallization from batch mixture melted in a cold container, contains at least two tetragonal phases whose axes of tetragonality are 80-90°. The components of the batch mixture for obtaining the material are contained in the following ratio (in mol %): yttrium oxide, 2.8-3.7; zirconium dioxide, the remainder.
    Type: Application
    Filed: December 2, 2009
    Publication date: May 5, 2011
    Applicants: OOO "NOVYE ENERGETICHESKIE TEKHNOLOGII", GOLSEN LIMITED
    Inventors: Mikhail A. Borik, Maria A. Vishnyakova, Vladimir P. Voytsitskiy, Elena E. Lomonova, Vyacheslav V. Osiko, Valentina A. Myzina
  • Patent number: 7915189
    Abstract: An electrostatic chuck that is a member for a semiconductor-manufacturing apparatus contains an yttrium oxide material containing first inorganic particles and second inorganic particles. The first inorganic particles form solid solutions in yttrium oxide, can be precipitated from yttrium oxide, and are present in grains of yttrium oxide. The second inorganic particles can form solid solutions in the first inorganic particles, are unlikely to form any solid solution in yttrium oxide, and are present at boundaries between the yttrium oxide grains. The first inorganic particles contain at least one of ZrO2 and HfO2. The second inorganic particles contain at least one selected from the group consisting of MgO, CaO, SrO, and BaO. The yttrium oxide material is produced in such a manner that solid solution particles are prepared by mixing and firing the first and second inorganic particles and are mixed with yttrium oxide and the mixture is fired.
    Type: Grant
    Filed: March 9, 2009
    Date of Patent: March 29, 2011
    Assignee: NGK Insulators, Ltd.
    Inventors: Yoshimasa Kobayashi, Yuji Katsuda
  • Publication number: 20110027742
    Abstract: A subject of the invention relates to providing a powder for a translucent zirconia sintered body which is necessary for the production of a zirconia sintered body having a high sintered-body density and high strength and giving an excellent sense of translucency, without conducting any special sintering, such as HIP sintering. The invention relates to a technique for obtaining, through normal-pressure sintering, a translucent zirconia sintered body characterized by comprising zirconia which contains 2-4 mol % yttria as a stabilizer and has an alumina content of 0.2 wt % or lower, and by having a relative density of 99.8% or higher and a total light transmittance, as measured at a thickness of 1.0 mm, of 35% or higher. It is preferred that a powder containing 0-0.2 wt % alumina with a particle diameter of 0.01-0.5 ?m, having a BET specific surface area of 5-16 m2/g and an average particle diameter of 0.3-0.7 ?m, and having a rate of sintering shrinkage in normal-pressure sintering (??/?T; g/cm3·° C.) of 0.
    Type: Application
    Filed: April 8, 2009
    Publication date: February 3, 2011
    Applicant: TOSOH CORPORATION
    Inventors: Hiroyuki Fujisaki, Kiyotaka Kawamura, Kohei Imai
  • Patent number: 7867472
    Abstract: An insulating target material for obtaining a conductive complex oxide film represented by a general formula ABO3. The insulating target material includes: an oxide of an element A; an oxide of an element B; an oxide of an element X; and at least one of an Si compound and a Ge compound, the element A being at least one element selected from La, Ca, Sr, Mn, Ba, and Re, the element B being at least one element selected from Ti, V, Sr, Cr, Fe, Co, Ni, Cu, Ru, Ir, Pb, and Nd, and the element X being at least one element selected from Nb, Ta, and V.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: January 11, 2011
    Assignee: Seiko Epson Corporation
    Inventors: Koji Ohashi, Takeshi Kijima, Setsuya Iwashita
  • Publication number: 20100311562
    Abstract: The invention is directed to a material and method for obtaining a ceramic abradable system for high temperature applications. High purity partially stabilized zirconia and/or hafnia base material has higher sintering resistance compared to conventional 6-9 weight percent yttria stabilized zirconia systems. The benefits of these systems are higher service lifetime and low thermal conductivity to achieve high operating temperatures. System includes a superalloy substrate, oxidation resistant bond coat and a thick ceramic abradable top coat. Total coating thickness is about 0.5-5 mm. In some applications an intermediate layer of high purity partially stabilized zirconia or a partially stabilized YSZ/MCrAlY cermet is applied over the oxidation resistant bond coat. In other applications an abradable system is applied on top of a grid. Additional benefits should be reduced blade wear at high operating conditions.
    Type: Application
    Filed: September 13, 2006
    Publication date: December 9, 2010
    Inventors: Liangde Xie, Mitchell Dorfman, Richard Schmid, Jacobus C. Doesburg, Matthew Gold