Zirconium Oxide Patents (Class 501/103)
  • Patent number: 7842370
    Abstract: A cordierite ceramic is provided, which includes at least zirconium oxide or hafnium oxide, and also includes titanium oxide. The molar ratio of zirconium (Zr), hafnium (Hf) and titanium (Ti) in terms of the moles in the form of the dioxides, respectively which is given by the formula [(ZrO2+HfO2)/TiO2] is in a range of 0.1 to 5. In this cordierite ceramic, the phases of the components are contained mainly as zirconium titanate or hafnium titanate, and no heterogeneity in appearance, caused by change in color and generation of spots occurs. A honeycomb structure made of the cordierite ceramic is also provided.
    Type: Grant
    Filed: November 27, 2007
    Date of Patent: November 30, 2010
    Assignee: NGK Insulators, Ltd.
    Inventors: Yohei Ono, Satoshi Yamazaki, Yuji Katsuda, Shuji Ueda
  • Patent number: 7838453
    Abstract: A ceramic powder contains a principal component that is a perovskite-type complex oxide represented by the formula ANbO3 (A is at least one selected from alkali metal elements and contains 10 mole percent or more of K) and also contains 0.0001 mole or more of an element per mole of the principal component. The element is at least one selected from the group consisting of Yb, Y, In, Nd, Eu, Gd, Dy, Sm, Ho, Er, Tb, and Lu. The ceramic powder preferably further contains at least one selected from the group consisting of Ti, Zr, and Sn. This enables that a non-deliquescent alkali niobate-based ceramic powder is produced at a high yield.
    Type: Grant
    Filed: October 3, 2008
    Date of Patent: November 23, 2010
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Ryoko Katayama, Shinichiro Kawada
  • Publication number: 20100292522
    Abstract: In one aspect, the invention includes a refractory material, said material comprising: (i) at least 20 wt. % of a first grain mode stabilized zirconia based upon the total weight of said material, said first grain mode having a D50 grain size in the range of from 5 to 2000 ?m, said stabilized zirconia including a matrix oxide stabilizer; (ii) at least 1 wt. % of a second grain mode having a D50 grain size in the range of from 0.01 ?m up to not greater than one-fourth the D50 grain size of said first grain mode zirconia, based upon the total weight of said material; and (iii) at least 1 wt. % of a preservative component within at least one of said first grain mode stabilized zirconia, said second grain mode stabilized zirconia, and an optional another grain mode; wherein after sintering, said material has porosity at 20° C. in the range of from 5 to 45 vol %.
    Type: Application
    Filed: May 18, 2009
    Publication date: November 18, 2010
    Inventors: ChangMin Chun, Frank Hershkowitz
  • Publication number: 20100290978
    Abstract: In one aspect, the invention includes a refractory material for a pyrolysis reactor for pyrolyzing a hydrocarbon feedstock, the refractory material comprising an yttria stabilized zirconia, the refractory material comprising at least 21 wt. % yttria based upon the total weight of the refractory material. In another aspect, this invention includes a method for mitigating carbide corrosion while pyrolyzing a hydrocarbon feedstock at high temperature using a pyrolysis reactor system comprising the steps of: (a) providing a pyrolysis reactor system comprising stabilized zirconia in a heated region of the reactor, the stabilized zirconia including at least 21 wt. % yttria and having porosity of from 5 vol. % to 28 vol. %; (b) heating the heated region to a temperature of at least 1500° C.; and (c) pyrolyzing a hydrocarbon feedstock within the heated region.
    Type: Application
    Filed: May 18, 2009
    Publication date: November 18, 2010
    Inventors: ChangMin Chun, Frank Hershkowitz
  • Patent number: 7833469
    Abstract: A method of making a solid electrolyte-YSZ product, where the method includes the step of providing a powdered mixture of zirconia, yttria and about 2%, by wt., or less of a metal oxide, where yttria-stabilized zirconia is not added to the mixture. The method also includes sintering the powdered mixture at about 1500° C. or less, for about 5 hours or less, to form a reaction sintered YSZ. Also, a method of making a fuel cell electrolyte that includes the step of forming a green body that includes zirconia, yttria and about 2%, by wt., or less of a metal oxide, where yttria-stabilized zirconia is not added to the green body. The method also includes shaping the green body into a form of the electrolyte, and sintering the green body at about 1500° C. or less to form a reaction sintered yttria-stabilized zirconia and metal oxide electrolyte.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: November 16, 2010
    Assignee: CoorsTek, Inc.
    Inventors: Ruthie Swartzlander, W. Grover Coors
  • Patent number: 7820577
    Abstract: A biomedical member having high strength, high toughness and high hardness and an artificial joint that uses the same are provided. In addition, a biomedical member that exhibits high wear resistance even in in vivo environment and an artificial joint are provided. Such a composite ceramic is used that contains 65% by weight or more Al2O3, 4 to 34% by weight of ZrO2 and 0.1 to 4% by weight of SrO, while Sr forms a solid solution with part of the ZrO2 grains. The composite ceramics further contains TiO2, MgO and SiO2 as sintering additives, while controlling the amounts to 0.20% by weight or more SiO2, 0.22% by weight or more TiO2 and 0.12% by weight or more MgO, and the total amount of SiO2, TiO2 and MgO within a range from 0.6 to 4.5% by weight.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: October 26, 2010
    Assignee: Kyocera Corporation
    Inventors: Kunihide Shikata, Takefumi Nakanishi, Yucong Wang
  • Patent number: 7806694
    Abstract: Dental articles are produced using relatively low sintering temperatures to achieve high density dental articles exhibiting strengths equal to and greater than about 700 MPa. Ceramic powders comprised of nanoparticulate crystallites are used to manufacture dental articles. The ceramic powders may include sintering agents, binders and other similar additives to aid in the processing of the ceramic powder into a dental article. The ceramic powders may be processed into dental articles using various methods including, but not limited to, injection molding, gel-casting, slip casting, or electroforming, hand, cad/camming and other various rapid prototyping methods. The ceramic powder may be formed into a suspension, pellet, feedstock material or a pre-sintered blank prior to forming into the dental article.
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: October 5, 2010
    Assignee: Pentron Ceramics, Inc.
    Inventors: Dmitri Brodkin, Moisey Y. Gamarnik
  • Publication number: 20100248932
    Abstract: The method of making a transparent ceramic includes making a molded body from a powder mixture of starting materials, which include one or more sintering aids. The sintering aids can include SiO2, TiO2, ZrO2, HfO2, Al2O3 and/or fluorides. The transparent ceramic is made by pre-sintering the molded body at temperatures between 500° C. to 900° C., subsequently sintering in vacuum at temperatures between 1400° C. and 1900° C. and then pressurizing the sintered molded body at a pressure of from 10 to 198 MPa followed by annealing. The optoceramic material contains crystals with a stoichiometry of A2+XBYBYDZE7, wherein ?1.15?x?+1.1, 0?y?3, 0?z?1.6 and 3x+4y+5z=8; and wherein A is a trivalent rare earth cation, B is a tetravalent cation, D is a pentavalent cation and E is a divalent anion.
    Type: Application
    Filed: March 22, 2010
    Publication date: September 30, 2010
    Inventors: Yvonne Menke, Akio Ikesue
  • Patent number: 7799716
    Abstract: The present invention provides a low density and porous zirconia (ZrO2) powder partially alloyed with one or more of yttria, scandia, dysprosia, ytterbia, or any of the oxides of lanthanide or actinide. The total amount of alloying oxides should be less than about 30 weight percent. The powder is manufactured by controlled sintering or light plasma densification of physically agglomerated, or chemically derived zirconia composite powder that contains proper amounts of yttria, scandia, dysprosia, ytterbia, or any of the oxides of lanthanide or actinide, or any combination of the aforementioned oxides. The resulting coating from use of the inventive powder has a monoclinic phase content of less than 5 percent.
    Type: Grant
    Filed: March 3, 2006
    Date of Patent: September 21, 2010
    Assignee: Sulzer Metco (US), Inc.
    Inventors: Michael Mueller, Mitchell R. Dorfman, Liangde Xie
  • Publication number: 20100227754
    Abstract: A sintered yttrium oxide product comprises: • more than 99.5% of yttrium oxide, as a percentage by weight; and • more than 50 ppma and less than 1000 ppma of a dopant selected from Zr&Ogr;2 and/or HfO2; the mean grain size of the doped yttrium oxide product being more than 0.03 ?m and less than 5 ?m.
    Type: Application
    Filed: March 19, 2007
    Publication date: September 9, 2010
    Applicant: Saint-Gobain Centre De Recherches et D'Etudes Europeen
    Inventors: Guillaume Bernard-Granger, Christophe Sinet
  • Publication number: 20100224756
    Abstract: The invention relates to a molding material mixture for production of casting molds for metalworking, to a process for producing casting molds, to casting molds obtained by the process and to the use thereof. For the production of casting molds, a refractory molding matrix and a waterglass-based binder are used. The binder has been admixed with a proportion of a particulate metal oxide which is selected from the group of silicon dioxide, aluminum oxide, titanium oxide and zinc oxide, particular preference being given to using synthetic amorphous silicon dioxide. The molding material mixture comprises a carbohydrate as a further essential constituent. The addition of carbohydrates allows the mechanical strength of casting molds and the surface quality of the casting to be improved.
    Type: Application
    Filed: October 19, 2007
    Publication date: September 9, 2010
    Applicant: ASHLAND-SUDCHEMIE-KERNFEST GMBH
    Inventors: Jens Muller, Diether Koch, Marcus Frohn, Jorg Korschgen, Stefan Schreckenberg
  • Publication number: 20100221530
    Abstract: The invention relates to a sintered product containing: in mass percent based on oxides, more than 99.5% of a material having a cubic crystallographic structure for more than 95% of the mass thereof, known as a material with a cubic structure, and having a refractive index of less than 2.75 in the wavelength range between 0.2 ?m and 5 ?m; and more than 50 ppma of dopants which must contain titanium oxide TiO2 and at least one additional dopant selected from ZrO2, CaO, and MgO, in which said at least one additional dopant is different from the oxide(s) forming the material with a cubic structure, but can be MgO when the material with a cubic structure is spinel MgAl2O4.
    Type: Application
    Filed: June 13, 2008
    Publication date: September 2, 2010
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Guillaume Bernard-Granger, Nassira Benameur
  • Patent number: 7776774
    Abstract: There is provided a strengthened composite material that is able to improve yield, handling, and reliability when it is applied to members of semiconductor manufacturing apparatus. Five to 60 mol % ZrO2 is contained relative to Y2O3, and temperature after a sintering process is maintained between 1,200° C. to 1,500° C. for 5 minutes or longer or temperature falling speed to reach 1,200° C. is adjusted to 200° C./h or slower, thereby producing the composite material containing, as major crystalline phases, a Y2O3 solid solution in which ZrO2 is dissolved in Y2O3 and a ZrO2 solid solution in which Y2O3 is dissolved in ZrO2.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: August 17, 2010
    Assignee: NGK Insulators, Ltd.
    Inventors: Yoshimasa Kobayashi, Yuji Katsuda
  • Patent number: 7758977
    Abstract: Novel, monodispersed, spherical ZrO2 particles in the size range of approximately 10 to approximately 600 nm exhibiting metastable tetragonal crystal structure at room temperature and novel methods of preparation. The ZrO2 particles are approximately 100% in the tetragonal phase at room temperature and can be pure and free of foreign oxides. The novel method can include mixing zirconium-alkoxide and an alcohol, forming preparation one, followed by separately dissolving completely de-ionized water and a polymeric steric stabilizer in an alcohol forming preparation two. Next the preparations can be mixed with vigorous stirring while subjecting the materials to hydrolysis and condensation reactions with very slow stirring. Next, there is waiting for the formation of a sol from the mixture, followed by drying at approximately 80 degrees C. to form resultant material followed by crushing the resultant material.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: July 20, 2010
    Assignee: University of Central Florida Research Foundation, Inc.
    Inventors: Sudipta Seal, Satyajit Shukla
  • Publication number: 20100160143
    Abstract: A solid solution-comprising ceramic article useful in semiconductor processing, which is resistant to erosion by halogen-containing plasmas. The solid solution-comprising ceramic article is formed from a combination of yttrium oxide and zirconium oxide. In a first embodiment, the ceramic article includes ceramic which is formed from yttrium oxide at a molar concentration ranging from about 90 mole % to about 70 mole %, and zirconium oxide at a molar concentration ranging from about 10 mole % to about 30 mole %. In a second embodiment, the ceramic article includes ceramic which is formed from zirconium oxide at a molar concentration ranging from about 96 mole % to about 94 mole %, and yttrium oxide at a molar concentration ranging from about 4 mole % to about 6 mole %.
    Type: Application
    Filed: February 19, 2010
    Publication date: June 24, 2010
    Applicant: Applied Materials, Inc.
    Inventors: Jennifer Y. Sun, Ren-Guan Duan, Jie Yuan, Li Xu, Kenneth S. Collins
  • Publication number: 20100154856
    Abstract: A substrate (1) for thermoelectric conversion modules has a ceramic material as a main component and has flexibility. A thermoelectric conversion module (2) has a plurality of thermoelectric elements (3, 4) arranged in the longitudinal direct of the substrate (1), at least on one surface of the substrate (1), so that the longitudinal directions of the thermoelectric elements (3, 4) are along the width direction of the substrate (1). Electrodes (5), which electrically connect the thermoelectric elements (3, 4) in series, are arranged on the end portions of the thermoelectric elements (3, 4).
    Type: Application
    Filed: March 11, 2008
    Publication date: June 24, 2010
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Yuichi Hiroyama, Yoshio Uchida
  • Patent number: 7741240
    Abstract: This invention relates to new transition metal catalyst compounds represented by the formula (I): where: M and M? are, independently, a group 8, 9, 10 or 11 transition metal, preferably Ni, Co, Pd, Cu or Fe; each R group is, independently, is, hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; R? is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together with R? to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; each X group is, independently, is, hydrogen, a hal
    Type: Grant
    Filed: May 23, 2005
    Date of Patent: June 22, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Gregory A. Solan, Jeremie D. A. Pellettier
  • Patent number: 7723249
    Abstract: The invention is directed to a ceramic material for use in thermal barriers for high temperature cycling applications and high temperature abradable coatings. The material is an alloy formed predominantly from ultra-pure zirconia (ZrO2) and/or hafnia (HfO2) that has uncharacteristically high sintering resistance to achieve a high service lifetime and low thermal conductivity to achieve high operating temperatures. In the material, oxide impurities such as soda (Na2O), silica (SiO2), alumina (Al2O3), titania (TiO2), hematite (Fe2O3), calcia (CaO), and magnesia (MgO) make up no more than 0.15 weight percent. The invention provides materials to produce a coating structure so that the changes in the coating microstructure over the in-service lifetime are either limited or beneficial.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: May 25, 2010
    Assignee: Sulzer Metco (US), Inc.
    Inventors: Jacobus C. Doesburg, Liangde Xie, Mitchell Dorfman
  • Patent number: 7700034
    Abstract: Slip containing at least one aluminium oxide powder and at least one unstabilized zirconium dioxide powder, wherein a) the zirconium dioxide powder i) has a mean particle diameter of less than 300 nm, ii) shows only the monoclinic phase and the tetragonal phase in the X-ray diffraction pattern, with the proportion of tetragonal phase at room temperature being from 20 to 70%, and iii) is present in a proportion of from 2 to 20% by weight, based on the total amount of the slip, b) the aluminium oxide powder i) has a mean particle diameter of more than 300 nm and ii) is present in a proportion of from 80 to 98% by weight, based on the total amount of the slip, and c) the solids content, as the sum of aluminium oxide and zirconium dioxide, is from 50 to 85% by weight, based on the total amount of the slip.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: April 20, 2010
    Assignee: Evonik Degussa GmbH
    Inventors: Monika Oswald, Klaus Deller, Wolfgang Kollenberg, Dieter Nikolay
  • Patent number: 7700508
    Abstract: A composition for thermal barrier coatings exhibiting improved thermal conductivity and toughness is provided. The composition is comprised of a base majority oxide, a first dopant oxide, at least one small rare earth oxide, at least one large rare earth oxide and at least one toughening oxide. Compared to traditional thermal barrier coatings, a composition of the present invention provides approximately twice the toughness one-third to one-half the thermal conductivity.
    Type: Grant
    Filed: August 28, 2006
    Date of Patent: April 20, 2010
    Assignee: The United States of Americas as represented by the Secretary of the Army
    Inventors: Dongming Zhu, Robert A. Miller
  • Publication number: 20100089098
    Abstract: Sintered product produced from a starting charge containing 75 to 99% zircon, and having the following average chemical composition by weight, the percentages by weight being based on the oxides: 60%<ZrO2+HfO2<75%; 27%<SiO2<34%; O<TiO2; O<Y2O3<3.5%; 0.1%<Nb2O5+Ta2O5<=5%; and other oxides: <1.5%; for a total of 100%, The sintered product may be used in a glass furnace.
    Type: Application
    Filed: October 15, 2007
    Publication date: April 15, 2010
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Olivier Citti, Julien Fourcade
  • Publication number: 20100086790
    Abstract: A layer system including a substrate on which a first layer is positioned is provided. The first layer includes a thermographic material. The thermographic material is a pyrochlore phase doped with at least one rare earth material. The rare earth material is selected from the group europium, terbium, erbium, dysprosium, samarium, holmium, praseodymium, ytterbium, neodymium, and thulium. A method of a layer system is also provided.
    Type: Application
    Filed: September 7, 2007
    Publication date: April 8, 2010
    Inventors: Eckart Schumann, Ramesh Subramanian, Berit Wessler
  • Publication number: 20100075147
    Abstract: The invention is directed to a ceramic material for use in thermal barriers for high temperature cycling applications and high temperature abradable coatings. The material is an alloy formed predominantly from ultra-pure zirconia (ZrO2) and/or hafnia (HfO2) that has uncharacteristically high sintering resistance to achieve a high service lifetime and low thermal conductivity to achieve high operating temperatures. In the material, oxide impurities such as soda (Na2O), silica (SiO2), alumina (Al2O3), titania (TiO2), hematite (Fe2O3), calcia (CaO), and magnesia (MgO) make up no more than 0.15 weight percent. The invention provides materials to produce a coating structure so that the changes in the coating microstructure over the in-service lifetime are either limited or beneficial.
    Type: Application
    Filed: September 13, 2006
    Publication date: March 25, 2010
    Inventors: Jacobus C. Doesburg, Liangde Xie, Mitchell Dorfman
  • Publication number: 20100068492
    Abstract: The present invention provides a fused cast refractory block comprising a mean zirconia (ZrO2+HfO2) content of more than 85% as a percentage by weight based on the oxides, and with a standard deviation ? of the local zirconia content divided by the volume of the block of less than 7.5.
    Type: Application
    Filed: February 22, 2008
    Publication date: March 18, 2010
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Yves Boussant-Roux, Edouard Schiavo, Alain Zanoli
  • Publication number: 20100048376
    Abstract: Process for preparing granules of oxidic or nonoxidic metal compounds, characterized in that a dispersion which comprises water, oxidic or nonoxidic metal compounds and at least one dispersant is spray-dried,—where the proportion of oxidic or nonoxidic metal compounds is 40 to 70% by weight and the sum of the proportions of water and the particles is at least 70% by weight and—the particles have a BET surface area of 20 to 150 m2/g and a median of the particle size of less than 100 nm,—where the dispersant is present in the dispersion with a proportion of 0.25 to 10% by weight based on the oxidic or nonoxidic metal compounds and—where the spray-drying is performed by atomization with air in the cocurrent principle or fountain principle, and an air inlet temperature of 170 to 300° C. and an air outlet temperature of 90 to 130° C. are selected.
    Type: Application
    Filed: November 8, 2007
    Publication date: February 25, 2010
    Applicants: EVONIK DEGUSSA GmbH, FRAUNHOFER-GESELL. ZUR FOERD. DER ANG. FORS. E.V.
    Inventors: Monika Oswald, Klaus Deller, Tassilo Moritz, Manfred Nebelung
  • Publication number: 20100041542
    Abstract: A translucent zirconia sintered body, a dental article comprising a shaped, translucent zirconia body, a zirconia green body, and methods of making a translucent zirconia sintered body, methods of making a dental article comprising a shaped, translucent zirconia body, and methods of making a zirconia green body are described.
    Type: Application
    Filed: December 28, 2007
    Publication date: February 18, 2010
    Inventors: Jacqueline C. Rolf, Martin Goetzinger, Holger Hauptmann, Peter Bissinger, Ruediger Franke
  • Publication number: 20100025874
    Abstract: The invention relates to primary particles of oxide-ceramic material, wherein the primary particles have an average particle size in the range from 10 to 1000 nm and are coated with a chromophoric component, a process for their preparation and their use in particular in the preparation of ceramic mouldings and dental restorations. The invention further relates to a suspension based on oxide-ceramic material which contains the primary particles, and a process for the preparation of a ceramic mouldings.
    Type: Application
    Filed: March 4, 2009
    Publication date: February 4, 2010
    Applicant: Ivoclar Vivadent AG
    Inventors: Elke APEL, Christian RITZBERGER, Wolfram HOLAND, Christoph APPERT, Wolfgang WACHTER, Volker M. RHEINBERGER
  • Publication number: 20100029463
    Abstract: Preparation for producing refractory materials, characterized in that it comprises one or more particulate, refractory components and one or more binders, where—the particulate, refractory component has a mean particle diameter of >0.3 m and—the binder is selected from among—from 0.05 to 50% by weight of a very finely particulate binder having a mean particle diameter of from 10 nm to 0.3 m selected from the group consisting of aluminium oxide, titanium dioxide, zirconium dioxide and/or mixed oxides of the abovementioned oxides, —from 0 to 20% by weight of an inorganic binder, from 0 to 20% by weight of a hydraulically setting binder, —from 0 to 15% by weight of an organic, silicon-free binder—and the preparation additionally contains from 0 to 35% by weight of water, where—the proportion of the particulate, refractory component is equal to 100 and the percentages of the further materials in the preparation are based on the particulate component.
    Type: Application
    Filed: September 19, 2007
    Publication date: February 4, 2010
    Applicant: Evonik Degussa GmbH
    Inventors: Tadeusz Von Rymon Lipinski, Christoph Tontrup, Wolfgang Lortz, Christoph Batz-Sohn
  • Patent number: 7655586
    Abstract: Dental articles are produced using relatively low sintering temperatures to achieve high density dental articles exhibiting strengths equal to and greater than about 700 MPa. Ceramic powders comprised of nanoparticulate crystallites are used to manufacture dental articles. The ceramic powders may include sintering agents, binders and other similar additives to aid in the processing of the ceramic powder into a dental article. The ceramic powders may be processed into dental articles using various methods including, but not limited to, injection molding, gel-casting, slip casting, or electroforming, hand, cad/camming and other various rapid prototyping methods. The ceramic powder may be formed into a suspension, pellet, feedstock material or a pre-sintered blank prior to forming into the dental article.
    Type: Grant
    Filed: May 28, 2004
    Date of Patent: February 2, 2010
    Assignee: Pentron Ceramics, Inc.
    Inventors: Dmitri Brodkin, Moisey Y. Gamarnik
  • Publication number: 20100012484
    Abstract: A sintered product made from a starting batch containing 5 to 50% zircon and having the following average chemical composition, in weight percentages on the basis of the oxides and for a total of 100%: silica and zirconia, the zirconia content (ZrO2) being at least 64%, at least 0.2% of a dopant selected from V2O5, Nb2O5, Ta2O5, and mixtures thereof, optionally, a stabilizer selected from Y2O3, MgO, CaO, CeO2, and mixtures thereof, at a content of 6% or less, “other oxides” at a content of 6.7% or less.
    Type: Application
    Filed: December 20, 2007
    Publication date: January 21, 2010
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES
    Inventors: Olivier Citti, Julien Fourcade, Michel Gaubil, Charles Nicholas Mc Garry, Michael J. Seaborne
  • Publication number: 20100009840
    Abstract: The present invention describes a cement free refractory mixture. The mixture comprises a pH buffer and a component containing a metal or fumed silica. Water may impart good flow characteristics to the mixture and can produce an effective low temperature cure. At elevated temperatures, an article formed using this mixture has superior refractory and physical properties.
    Type: Application
    Filed: July 6, 2007
    Publication date: January 14, 2010
    Inventors: Robert A. Pattillo, Sam Bonsall
  • Publication number: 20100003630
    Abstract: The invention relates to the use of a sintered body obtained by subjecting a primary sintered body having a relative density of 95% or higher produced from a fine yttria-containing zirconia powder to HIP sintering at a temperature of 1,200-1,600° C. and a pressure of 50 MPa or higher. This sintered body is either a sintered body which has a total light transmittance, as measured at a thickness of 0.5 mm, of 43% or higher and a three-point bending strength of 1,700 MPa or higher or a zirconia sintered body which has a total light transmittance, as measured at a thickness of 1 mm, of 40% or higher and a three-point bending strength of 500 MPa or higher and which combines high strength and total light transmission.
    Type: Application
    Filed: July 19, 2007
    Publication date: January 7, 2010
    Applicant: TOSOH CORPORATION
    Inventors: Isao Yamashita, Koji Tsukuma, Toru Tsuyoshi
  • Publication number: 20100004114
    Abstract: The invention relates to a fired refractory ceramic product. According to the invention, this generic term encompasses both shaped and unshaped products. Shaped products are ones which have a defined shape so that they can be manufactured in finished form on the premises of the manufacturer. Shaped products include: bricks, nozzles, tubes, stoppers, plates, etc. The term unshaped products includes ones which are usually produced by the user from a corresponding composition. They include bases for furnaces which are cast from a composition but also repair compositions, etc.
    Type: Application
    Filed: August 8, 2007
    Publication date: January 7, 2010
    Applicant: Refractory Intellectual Property GmbH & Co. KG
    Inventors: Boro Djuricic, Franz Reiterer
  • Patent number: 7642210
    Abstract: A zirconia porous body with excellent stability of heat resistance is manufactured. This relates to a zirconia porous body having peaks at pore diameters of 8 to 20 nm and 30 to 100 nm in a pore distribution based on the BJH method, with a total pore volume of 0.4 cc/g or more, and to a zirconia porous body having a peak at a pore diameters of 20 to 110 nm in a pore distribution based on the BJH method, with a total pore volume of 0.4 cc/g or more.
    Type: Grant
    Filed: July 25, 2005
    Date of Patent: January 5, 2010
    Assignee: Daiichi Kigenso Kagaku Kogyo Co., Ltd.
    Inventor: Hiroshi Okamoto
  • Patent number: 7632769
    Abstract: A zirconia porous body with excellent stability of heat resistance is manufactured. This relates to a zirconia porous body having peaks at pore diameters of 8 to 20 nm and 30 to 100 nm in a pore distribution based on the BJH method, with a total pore volume of 0.4 cc/g or more, and to a zirconia porous body having a peak at a pore diameters of 20 to 110 nm in a pore distribution based on the BJH method, with a total pore volume of 0.4 cc/g or more.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: December 15, 2009
    Inventor: Hiroshi Okamoto
  • Patent number: 7625653
    Abstract: A material which conducts protons or oxide ions with high ionic conductivity and is excellent in moisture resistance and reduction resistance is provided. A perovskite oxide represented by the formula (1): BaZraCebM1cL1dO3-???(1) (wherein M1 is at least one member selected from the group consisting of rare earth elements, In, Mn, Fe, Co, Ni, Al and Ga, L1 is at least one member selected from the group consisting of P, B and N and a, b, c, d and a satisfy 0?a<1.2, 0<b<1.2, 0<c<1.2, 0.9<a+b+c<1.2, 0<d<0.1 and 0<?<3) is used as an ionic conductor.
    Type: Grant
    Filed: March 13, 2006
    Date of Patent: December 1, 2009
    Assignee: Panasonic Corporation
    Inventors: Tomohiro Kuroha, Noboru Taniguchi
  • Patent number: 7622411
    Abstract: There is provided a novel thermal barrier coating material which does not have a problem of phase transition, whose melting point is higher than its working temperature range, whose thermal conductivity is smaller than that of zirconia, and whose thermal expansion coefficient is greater than that of zirconia. The thermal barrier coating material comprises as a main component, a composition having an orthorhombic or monoclinic structure derived from perovskite (for example, a tabular perovskite structure expressed by the composition formula A2B2O7), or a tetragonal layer structure having a c axis/a axis ratio equal to or greater than 3 (for example, a K2NiF4 structure, a Sr3Ti2O7 structure, or a Sr4Ti3O10 structure), a composition expressed by the composition formula LaTaO4, or a composition having an olivine type structure expressed by the composition formula M2SiO4 or (MM?)2SiO4 (where M, M? are divalent metal elements).
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: November 24, 2009
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Katsunori Akiyama, Ichiro Nagano, Masato Shida, Satoshi Ota
  • Patent number: 7618731
    Abstract: A ceramic-ceramic nanocomposite electrolyte having enhanced conductivity is provided. The nancomposite electrolyte is formed from chemically stabilized zirconia such as yttria stabilized zirconia or scandia stabilized zirconia and a heterogeneous ceramic dopant material such as Al2O3, TiO2, MgO, BN, or Si3N4. The nanocomposite electrolyte is formed by doping the chemically stabilized zirconia with the ceramic dopant material and pressing and sintering the composite. The resulting electrolyte has a bulk conductivity of from about 0.10 to about 0.50 S/cm at about 600° C. to about 900° C. and may be incorporated into a solid oxide fuel cell.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: November 17, 2009
    Assignee: University of Dayton
    Inventors: Binod Kumar, Christina H. Chen
  • Patent number: 7608552
    Abstract: The disclosure relates to metal oxide powders with a bimodal particle size distribution, to ceramics that can be made from these metal oxide powders, especially milling ceramics for use in dental technology, to a method for the production of the metal oxide powders and of the ceramics, to the use of nanoscale metal oxide powders for the production of the metal oxide powders and of the ceramics as well as to dental ceramic products.
    Type: Grant
    Filed: December 30, 2003
    Date of Patent: October 27, 2009
    Assignee: Chemichl AG
    Inventors: Gerhard Meyer, Thomas Conrad
  • Publication number: 20090215609
    Abstract: The inventive sintered product is produced from an initial feedstock having a zirconium content ranging from 75 to 99% and the following average chemical weight composition, in percentage by weight, based on oxides: 60 %=ZrO2+HfO2=75%, 27%=SiO2=34%, 0.2=TiO2=1.5 %, 0.3<Y2O3=3.5 %, other oxides:=1%, to give a total of 100%. Said product can be used for glassworks.
    Type: Application
    Filed: March 31, 2006
    Publication date: August 27, 2009
    Applicant: SAINT GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEEN
    Inventors: Michel Gaubil, Yves Boussant-Roux, Charles McGarry, Isabelle Cabodi, Olivier Citti
  • Patent number: 7579288
    Abstract: This invention relates to a dense ceramics having ESD dissipative characteristics, tunable volume and surface resistivities in semi-insulative range (103-1011 Ohm-cm), substantially pore free, high flexural strength, light colors, for desired ESD dissipation characteristics, structural reliability, high vision recognition, low wear and particulate contamination to be used as ESD dissipating tools, fixtures, load bearing elements, work surfaces, containers in manufacturing and assembling electrostatically sensitive microelectronic, electromagnetic, electro-optic components, devices and systems.
    Type: Grant
    Filed: July 20, 2005
    Date of Patent: August 25, 2009
    Assignee: Saint-Gobain Ceramics & Plastics, Inc.
    Inventors: Oh-Hun Kwon, Matthew A. Simpson, Roger J. Lin
  • Patent number: 7566674
    Abstract: In dental ceramics containing zirconium dioxide and silicon-dioxide with a Zr/Si ratio of between 0.5 and 1.0, 1 to 12 wt % of aluminum oxide and up to 2 wt % of an alkali- or earth alkali metal oxide, those materials are selectively mixed with yttrium-stabilized zirconium dioxide with a Zr/Si ratio of the mixture being between 0.5 and 1 wt % and also a silicon organic compound as well as a compression aid, and a green body is formed from the mixture by milling, which green body is then sintered.
    Type: Grant
    Filed: February 12, 2007
    Date of Patent: July 28, 2009
    Assignee: Forschungszentrum Karlsruhe GmbH
    Inventors: Joachim Binder, Jürgen Hausselt, Hans-Joachim Ritzhaupt-Kleissl, Nadja Schlechtriemen, Stefan Stolz
  • Patent number: 7563293
    Abstract: Al2O3-rare earth oxide-ZrO2/HfO2 ceramics (including glasses, crystalline ceramics, and glass-ceramics) and methods of making the same. Ceramics according to the present invention can be made, formed as, or converted into glass beads, articles (e.g., plates), fibers, particles, and thin coatings. The particles and fibers are useful, for example, as thermal insulation, filler, or reinforcing material in composites (e.g., ceramic, metal, or polymeric matrix composites). The thin coatings can be useful, for example, as protective coatings in applications involving wear, as well as for thermal management. Certain ceramic particles according to the present invention can be are particularly useful as abrasive particles.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: July 21, 2009
    Assignee: 3M Innovative Properties Company
    Inventor: Anatoly Z. Rosenflanz
  • Patent number: 7553789
    Abstract: A zirconia-containing powder including 2 to 6 weight % of a pigment which has a spinel structure represented by the chemical formula (Co1-xZnx)(Fe1-yAly)2O4(0?x?0.5, 0<y?0.5) or which is a coprecipitated material containing Co, Zn, Fe, and Al and has the same spinel structure after calcination, 0.05 to 6 weight % of Al2O3, and 3.60 to 7.10 weight % of Y2O3; and a black zirconia sintered body obtained by sintering the zirconia-containing powder within a temperature range of 1300 to 1500° C.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: June 30, 2009
    Assignee: Tosoh Corporation
    Inventor: Hiroyuki Fujisaki
  • Patent number: 7541103
    Abstract: A coated plastic substrate module (100) includes a plastic substrate (110), an organic coating (130), and a modulating film (120) sandwiched therebetween. The modulating film is made from partially stabilized zirconia. A method for manufacturing a coated plastic substrate module includes the following steps: providing a plastic substrate; forming a modulating film on the plastic substrate, the modulating film being made from partially stabilized zirconia; forming an organic coating on the modulating film; and annealing the treated plastic substrate having the modulating film and organic coating.
    Type: Grant
    Filed: December 29, 2005
    Date of Patent: June 2, 2009
    Assignee: Hon Hai Precision Industry Co., Ltd.
    Inventor: Charles Leu
  • Patent number: 7538055
    Abstract: A primary sintered body having a density of 95 % or more obtained by sintering a zirconia powder comprising an yttria main component as a stabilizer under ordinary pressure is set in a vessel of a semi-sealed state and subjected to HIP treatment (secondary sintering) at a temperature of from 1,600 to 1,900° C. under a pressure of 50 MPa or higher, and according to need, heated treated in an oxidizing atmosphere, thereby producing a polycrystalline sintered body of zirconia having high transparency of an in-line transmission of 50% or higher.
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: May 26, 2009
    Assignee: Tosoh Corporation
    Inventors: Koji Tsukuma, Isao Yamashita
  • Publication number: 20090130446
    Abstract: A composite article includes a substrate and a protective layer on the substrate. The protective layer includes a non-oxide ceramic matrix and a refractory phase within the non-oxide ceramic matrix.
    Type: Application
    Filed: July 17, 2007
    Publication date: May 21, 2009
    Inventors: Wayde R. Schmidt, Tania Bhatia, Xia Tang, David C. Jarmon, Owen B. Donahue
  • Publication number: 20090111679
    Abstract: A method is disclosed for manufacturing a zircon composition, the method comprising contacting a zircon powder with a sintering aid, wherein the sintering aid is in the form of a liquid, a sol, or a combination thereof. Also disclosed are methods for forming the zircon composition into a desired shape and for firing a composition to produce a ceramic body. The zircon composition and ceramic body produced by the described methods are also disclosed.
    Type: Application
    Filed: October 31, 2007
    Publication date: April 30, 2009
    Inventor: Yanxia Lu
  • Patent number: 7507268
    Abstract: Al2O3—Y2O3—ZrO2/HfO2 ceramics (including glasses, crystalline ceramics, and glass-ceramics) and methods of making the same. Ceramics according to the present invention can be made, formed as, or converted into glass beads, articles (e.g., plates), fibers, particles, and thin coatings. The particles and fibers are useful, for example, as thermal insulation, filler, or reinforcing material in composites (e.g., ceramic, metal, or polymeric matrix composites). The thin coatings can be useful, for example, as protective coatings in applications involving wear, as well as for thermal management. Certain ceramic particles according to the present invention can be are particularly useful as abrasive particles.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: March 24, 2009
    Assignee: 3M Innovative Properties Company
    Inventor: Anatoly Z. Rosenflanz
  • Publication number: 20090075809
    Abstract: The present invention relates to novel binder and slurry formulations used to form molds for casting metal alloys and, more particularly, reactive metal alloys. The shell molds lead to more uniform castings which exhibit limited alpha case as compared to other currently available shell mold systems.
    Type: Application
    Filed: November 19, 2008
    Publication date: March 19, 2009
    Applicant: BUNTROCK INDUSTRIES, INC.
    Inventors: David H. Sturgis, Thomas M. Branscomb