Alkaline Earth Metal Compound Containing Patents (Class 501/123)
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Patent number: 5728719Abstract: The present invention is a method for controlling ectoparasites. More particularly, the invention relates to a method of treatment in which the warm blooded animal is dosed with an ovicidally effective amount of a heterocyclic nitrogen compound selected from the group represented by the formula: ##STR1## wherein R.sub.1, is either one of the following groups: ##STR2## in which R.sub.7, R.sub.8, R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13, R.sub.14, R.sub.15, R.sub.16, and R.sub.17 are, the same or different, each a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.4 alkoxy group, a C.sub.1 -C.sub.4 alkylthio group, a trifluoro methyl group or a vitro group, R.sub.18, R.sub.19, R.sub.20 and R.sub.21 are, the same or different, each a hydrogen atom or a methyl group, k is an integer of 0 to 1 and 1 is an integer of 0 to 3; R.sub.2 and R.sub.3 are, the same or different, each a hydrogen atom, a halogen atom or a methyl group; R.sub.4 is a halogen atom or a methyl group; R.sub.5 and R.sub.Type: GrantFiled: March 14, 1995Date of Patent: March 17, 1998Assignee: Virbac, Inc.Inventor: Thomas A. Miller
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Patent number: 5725801Abstract: New oxide phosphors based on doped gallium oxides, alkaline earth gallates and germanates for electroluminescent display materials. Bright orange red electroluminescence has been obtained in amorphous and crystalline oxides Ga.sub.2 O.sub.3 :Eu for the first time. SrGa.sub.2 O.sub.4 and SrGa.sub.4 O.sub.9 doped with 1-8 mole % of Eu and Tb, CaGa.sub.2 O.sub.4, Ca.sub.3 Ga.sub.2 O.sub.6 and CaGa.sub.4 O.sub.7 doped with 1-4 mole % of Eu, Tb, Pr and Dy, BaGa.sub.2 O.sub.4 doped with 1-2 mole % of Eu and Tb, have been prepared using RF magnetron sputtering onto ceramic dielectric substrates and annealed at 600.degree. C.-950.degree. C. in air or Ar for 1-2 hours. Bright electroluminescent (EL) emission was obtained with wavelengths covering the visible spectrum from 400 to 700 nm, and infrared emission above 700 nm with spectral peaks characteristic of rare earth transitions. The films of CaGa.sub.2 O.sub.4 with 1 mole % Eu achieved 22 fL (75 cd/m.sup.2) at 60 Hz and had a maximum efficiency of 0.Type: GrantFiled: July 3, 1996Date of Patent: March 10, 1998Assignee: Adrian H. KitaiInventors: Adrian H. Kitai, Tian Xiao, Guo Liu
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Patent number: 5723074Abstract: Preparation, structure, and properties of mixed metal oxide compositions and their uses are described. Mixed metal oxide compositions of the invention have stratified crystalline structure identifiable by means of powder X-ray diffraction patterns. In the form of dense ceramic membranes, the present compositions demonstrate an ability to separate oxygen selectively from a gaseous mixture containing oxygen and one or more other volatile components by means of ionic conductivities.Type: GrantFiled: April 1, 1996Date of Patent: March 3, 1998Assignee: Amoco CorporationInventors: Uthamalingam Balachandran, Mark S. Kleefisch, Thaddeus P. Kobylinski, Sherry L. Morissette, Shiyou Pei
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Patent number: 5723394Abstract: The present invention pertains to a refractory ceramic mass, consisting of 50 to 97 wt. % of sintered MgO as well as 3 to 50 wt. % of a spinel of the hercynite type.Type: GrantFiled: September 17, 1996Date of Patent: March 3, 1998Assignee: Veitsch-Radex Aktiengesellschaft Fur Feuerfeste ErzeugnisseInventors: Harald Harmuth, Roland Heindl, Josef Deutsch
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Patent number: 5679294Abstract: A high purity .alpha.-tricalcium phosphate ceramic having a superior biocompatibility for use mainly as a bone filler, is produced by shaping a powder material formed by a wet method, followed by sintering it and then cooling at a predetermined rate.Type: GrantFiled: March 1, 1995Date of Patent: October 21, 1997Assignee: Kabushiki Kaisya AdvanceInventors: Yoshikazu Umezu, Osamu Hayashi, Kazutaka Yoshizawa
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Patent number: 5674815Abstract: An oxide superconductor composed of Cu, O and M (M is Ba, Sr and/or Ca) and including alternately arranged at least one rock-salt structure section and at least one infinite layer structure section, wherein the rock-salt structure section consists of two atomic layers each consisting of O and M and each having an atomic ratio O/M of 1 or less, and the infinite layer structure section consists of alternately arranged, first and second atomic layers. Each of the first atomic layers consists of O and Cu and has an atomic ratio O/Cu of 2, while each of the second atomic layers consists of the element M. The infinite layer structure section may consist of only one first atomic layer.Type: GrantFiled: March 6, 1996Date of Patent: October 7, 1997Assignees: International Superconductivity Technology Center, Matsushita Electric Industrial Co., Ltd.Inventors: Seiji Adachi, Hisao Yamauchi, Shoji Tanaka, Nobuo Mouri
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Patent number: 5670434Abstract: Process for preparing a high-T.sub.c superconductor as a precursor material for the oxide-powder-in-tube method (OPIT). The present invention relates to a process for preparing a high-T.sub.c superconductor as a precursor material for the oxide-powder-in-tube method, which involves mixing the oxides of the elements Bi, Sr, Ca and Cu and completely melting them at temperatures of >1000.degree. C., then casting the melt onto a substrate which is kept at room temperature, and disintegrating the cooled melt block and grinding it into a powder.Type: GrantFiled: January 30, 1996Date of Patent: September 23, 1997Assignee: Hoechst AktiengesellschaftInventors: Marc Neubacher, Joachim Bock, Christoph Lang, Eberhard Preisler, Helga Weis
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Patent number: 5665662Abstract: A high-temperature superconductor material based on the Bi--Sr--Ca--Cu--O system has the nominal composition:(Bi.sub.1-u Pb.sub.u).sub.2 (Sr.sub.1-x-y Ca.sub.x Bi.sub.y).sub.4 Cu.sub.3 O.sub.10+d (d=delta)wherein 0.01<x<0.50.ltoreq.y<x<0.50.ltoreq.d0.ltoreq.u.The high-temperature superconductor material has a transition temperature greater than 90.degree. K.Type: GrantFiled: November 8, 1990Date of Patent: September 9, 1997Assignee: Siemens AktiengesellschaftInventor: Oliver Eibl
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Patent number: 5650121Abstract: The disclosed invention provides a method of forming refractory linings for maintaining refractory linings against attack by corrosive materials such as those present in steel manufacture. The method entails spraying an aqueous mixture of a refractory composition that includes at least one refractory material onto the working surface of a refractory lining. Spraying is performed to provide one or more layers of the refractory composition on the refractory lining after each exposure of the lining to corrosive materials such as those incurred in steel manufacture.Type: GrantFiled: June 6, 1995Date of Patent: July 22, 1997Assignee: Minerals Technologies, Inc.Inventors: Julie Annette Dody, Charles R. Rumpeltin, Jr.
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Patent number: 5641718Abstract: Disclosed is a sintered aluminum nitride composition and a circuit substrate for use in semiconductor device. The sintered aluminum nitride composition comprises: aluminum nitride; a first component given by a compound containing an element which is selected from the group consisting of alkaline earth elements and group IIIa elements of the periodic table; a second component made of either a simple silicon or a silicon-containig compound; and a third component made of either a simple manganese or a manganese-containing compound. The circuit substrate has an insulating layer which is compoesd of the above-described sintered aluminum nitride composition, and an electrically conductive layer containing an electrically conductive material and the same components as those of the insulating layer.Type: GrantFiled: August 30, 1995Date of Patent: June 24, 1997Assignee: Kabushiki Kaisha ToshibaInventors: Akihiro Horiguchi, Katsuyoshi Oh-Ishi, Mitsuo Kasori, Hiroyasu Sumino, Fumio Ueno, Jun Monma, Kazuo Kimura
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Patent number: 5639437Abstract: Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented bySr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta.where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.Type: GrantFiled: September 3, 1996Date of Patent: June 17, 1997Assignee: Amoco CorporationInventors: Uthamalingam Balachandran, Mark S. Kleefisch, Thaddeus P. Kobylinski, Sherry L. Morissette, Shiyou Pei
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Patent number: 5639572Abstract: An interconnector material for use in electrochemical cells having Y.sub.2 O.sub.3 -stabilized ZrO.sub.2 as a solid electrolyte, said interconnector material comprising a lanthanum chromite material of the following general formula:(La.sub.1-x Sr.sub.x)(Cr.sub.1-y M.sub.y)O.sub.3,where M is Zr or Ti, x is in the range of 0.1 to 0.2, and y is in the range of 0.05 to 0.2.Type: GrantFiled: August 11, 1995Date of Patent: June 17, 1997Assignee: Mitsubishi Jukogyo Kabushiki KaishaInventors: Kazutaka Mori, Hitoshi Miyamoto, Tsuneaki Matsudaira
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Patent number: 5624542Abstract: Enhancement of mechanical properties of ceramic membranes by introduction of a uniformly distributed high-temperature oxidation-resistant metal phase into the brittle ceramic phase to achieve mechanically strong ceramic/metal composites operable in an oxidation atmosphere and at elevated temperatures.Type: GrantFiled: June 12, 1995Date of Patent: April 29, 1997Assignee: Gas Research InstituteInventors: Yousheng Shen, Ashok V. Joshi, Dale M. Taylor, Michael J. Boettcher, Kevin Krist, Anil V. Virkar
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Patent number: 5618762Abstract: An antibacterial ceramic contains an antibacterial material produced by loading an antibacterial metal such as silver on a calcium ceramic carrier and an inorganic material such as cordierite, and has a bulk density of 0.6-1.2 g/cm.sup.3. An antibacterial ceramic filter contains an antibacterial material produced by loading an antibacterial metal such as silver on a calcium ceramic carrier, an aggregate such as mullite, and a binder such as frit, and has a porosity of 20% or more. The light-weight antibacterial ceramic is suitably applicable to a roof garden or the like. The antibacterial ceramic filter can remove and extirpate various bacteria and suspensions.Type: GrantFiled: May 11, 1995Date of Patent: April 8, 1997Assignees: NGK Insulators, Ltd., NGK Adrec Co. Ltd., Sangi Co. Ltd.Inventors: Hiroshi Shirakawa, Osamu Yamakawa, Hiroaki Nihonmatsu, Kiminori Atsumi
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Patent number: 5616223Abstract: Composite ceramic mixed ionic and electronic conducting materials having high ambipolar activity which can be fabricated into thin membranes for high efficiency oxygen separation from air at intermediate temperatures. The mixed conducting materials have composite non-homogeneous microstructures of a separate predominantly oxygen ion conductive phase and a predominantly electronic conductive phase. Preferred predominantly oxygen ion conducting phases include bismuth, cerium and zirconium oxide based materials and predominantly electronic conducting phases include at least one metal electronic conductor material.Type: GrantFiled: April 22, 1994Date of Patent: April 1, 1997Assignee: Gas Research InstituteInventors: Yousheng Shen, Ashok V. Joshi, Kevin Krist, Meilin Liu, Anil V. Virkar
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Patent number: 5614127Abstract: An improved ceramic interconnect component for a solid oxide fuel cell having good electrical conductivity thermodynamic stability in the presence of fuel and a coefficient of thermal expansion matching closely that of zirconia electrolytes is disclosed. The interconnect is a lanthanum strontium chromate material containing minor quantities of calcia, and iron and, optionally, very minor quantities of cobalt, as dopants.Type: GrantFiled: February 28, 1995Date of Patent: March 25, 1997Assignee: Gas Research InstituteInventors: Ashok C. Khandkar, Christopher E. Milliken, S. Elangovan
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Patent number: 5612266Abstract: Disclosed is a decorative, non-combustible, synthetic fire-log for use in a gas or oil burning fireplace or stove. This synthetic fire-log has a density ranging from 15 to 45 lb/pi.sup.3. It is made by pouring a mineral foam into a mold shaped as a natural wood-log and letting this foam harden in the mold to form the synthetic fire-log prior to unmolding the same and letting it dry. The foam that is used for such a molding comprises 1 part by weight of a solution of phosphoric acid in which polyvinyl alcohol is dissolved in such an amount as to make the solution viscous; from 0.03 to 6 parts by weight of wollastonite containing from 0.5 to 4% by weight of a carbonate salt; from 0.2 to 10 parts by weight of water optionally one or more pigments to give a natural wood-like aspect to the synthetic fire-log; and, optionally also, a small amount of reinforcing glass fibers. The synthetic fire-log that is so-obtained looks like a natural wood-log and has the same glowing aspect in use.Type: GrantFiled: March 21, 1996Date of Patent: March 18, 1997Assignee: Cerminco Inc.Inventors: Pierre Delvaux, Normand Lesmerises, Marcel Gouin
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Patent number: 5609675Abstract: An inorganic composition comprises (A) 60 to 99% by weight of spherical inorganic oxide particles having a mean particle diameter greater than 0.1 .mu.m but not greater than 1 .mu.m, and (B) 40 to 1% by weight of inorganic oxide fine particles having a mean particle diameter not greater than 0.1 .mu.m, wherein a volume of micro pores due to strongly aggregated particles having pore diameters not smaller than 0.08 .mu.m is not greater than 0.1 cc per gram of the inorganic composition. The inorganic composition, when mixed with a polymerizable monomer and a catalyst, provides a composite useful for dental applications which has excellent surface smoothness, can be polished in a short time, exhibits improved bending strength, compressive strength, surface hardness and wear resistance and causes little wear on an antagonistic tooth.Type: GrantFiled: June 30, 1995Date of Patent: March 11, 1997Assignee: Tokuyama CorporationInventors: Masaki Noritake, Shigeki Yuasa
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Patent number: 5610786Abstract: A non-magnetic material for a magnetic head and a magnetic head produced with the use of such material. For improving the head efficiency and resistance against partial abrasion, the guard piece 11 is mainly composed of CaO, TiO.sub.2 and NiO, with the molar mixing ratio CaO/TiO.sub.2 being 30/70 to 50/50 and the NiO content being 5 to 30 mol %. The head efficiency may be improved, while the partial abrasion may be decreased and the service life of magnetic head may be improved sufficiently.Type: GrantFiled: June 22, 1995Date of Patent: March 11, 1997Assignee: Sony CorporationInventors: Fusashige Tokutake, Fumio Kurosawa, Takashi Tamura, Kimio Takahashi, Kazuhiro Yagihashi, Yukari Nihei, Akira Urai
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Patent number: 5607658Abstract: A metal oxide manufacturing method includes the steps of preparing the metal oxide expressed by a general formula of AXBYCZDn, (where A represents at least one element selected from a group consisting of a rare earth element, yttrium and an element obtained either by substituting part of rare earth elements with alkali metals or alkali earth metals or by substituting part of yttrium with alkali metals or alkali earth metals, B represents an alkali earth metal, C represents copper or an element obtained by substituting part of copper with transition metals, and D represents oxygen, and where when X=1, Y=2 to 4, Z=2.7 to 6 and n=6 to 13), reducing the metal oxide expressed by the general formula, and halogenating the reduced metal oxide. Part of oxygen (D) of the metal oxide expressed by the general formula is substituted with the halogen elements.Type: GrantFiled: September 5, 1995Date of Patent: March 4, 1997Assignee: Canon Kabushiki KaishaInventors: Norio Kaneko, Tamaki Kobayashi
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Patent number: 5583096Abstract: A process of manufacturing a superconducting compound including mixing stoichiometric amounts of a metallic oxide, copper oxide and a metallic carbonate wherein the metal of the metallic oxide is one other than yttrium and is selected and identified by its intrinsic massivity which is close in value to the intrinsic massivity of yttrium and wherein the interplanar distance on the C axis between Cu--O planes that exchange electrons through the electron-hopping mechanism in the ceramic perovskite is within the range of 1.97 .ANG. and 1.01 .ANG.. The mixture is subjected to pressure to form pellets and the pellets are then heated in forming the compound. The compound produced by the process and ceramic compositions having the formulas Mn Sr.sub.2 Cu.sub.3 O.sub.7-x and Mn.sub.2 Sr.sub.2 Cu.sub.3 O.sub.7-x.Type: GrantFiled: February 22, 1995Date of Patent: December 10, 1996Inventor: Ramon G. Cavazos
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Patent number: 5583093Abstract: Provided is a metal oxide material represented by the composition formula of Ln.sub.a Sr.sub.b Cu.sub.3-x M.sub.x O.sub.c, where 2.7.ltoreq.a+b.ltoreq.3.3; 0.8 .ltoreq.a.ltoreq.1.2; 6.ltoreq.c.ltoreq.9; and 0.05 .ltoreq.x.ltoreq.0.7, Ln is at least one element selected from the group of elements of Y and lanthanoids or an atomic group consisting of said elements, and M is at least one element selected from the group of elements of Ti, V, Ga, Ge, Mo, W and Re or an atomic group consisting of said elements.Type: GrantFiled: June 7, 1995Date of Patent: December 10, 1996Assignee: Canon Kabushiki KaishaInventors: Tohru Den, Tamaki Kobayashi
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Patent number: 5580497Abstract: Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented bySr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta.where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.Type: GrantFiled: March 18, 1994Date of Patent: December 3, 1996Assignee: Amoco CorporationInventors: Uthamalingam Balachandran, Mark S. Kleefisch, Thaddeus P. Kobylinski, Sherry L. Morissette, Shiyou Pei
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Patent number: 5573987Abstract: The present invention pertains to a refractory ceramic mass, consisting of a pure magnesia component A and a component B, which consists of granules of pure magnesia, wherein the magnesia granules of component B have a ceating consisting of a refractory material whose granule size is fine compared with that of the magnesia granules and is chemically extensively inert with respect to the magnesia granule or reacts with the magnesia granule and/or itself consists of a plurality of components that are chemically reactive with one another.Type: GrantFiled: February 7, 1995Date of Patent: November 12, 1996Assignee: Veitsch-Radex Aktiengesellschaft fur feuerfeste ErzeugnisseInventors: Harald Harmuth, Roland Heindl, Josef Deutsch
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Patent number: 5569631Abstract: The present invention pertains to a refractory ceramic mass, consisting of 50 to 97 wt. % of sintered MgO as well as 3 to 50 wt. % of a spinel of the hercynite type.Type: GrantFiled: February 7, 1995Date of Patent: October 29, 1996Assignee: Veitsch-Radex Aktiengesellschaft Fur Feuerfeste ErzeugnisseInventors: Harald Harmuth, Roland Heindl, Josef Deutsch
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Patent number: 5556830Abstract: Improved superconducting oxides are provided having the general formula (Hg.sub.1-x Tl.sub.x)Ba.sub.2 Ca.sub.n-1 Cu.sub.n O.sub.2n+2+.alpha. where x is from about 0.05-0.5 and n is 1, 2, 3 or 4, and .alpha. is an oxygen enrichment factor. The Tl-doped oxides exhibit very high T.sub.c and J.sub.c values.Type: GrantFiled: May 31, 1994Date of Patent: September 17, 1996Assignee: Midwest Superconductivity, Inc.Inventors: Guifu Sun, Kai W. Wong, Ying Xin
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Patent number: 5549850Abstract: Processes are provided for forming composites comprising a LaMnO.sub.3 perovskite coatings (or a related perovskite) on a mat of ceramic particles (e.g., fibers, microballoons, or mixtures thereof) or LaMnO.sub.3 -family sol-gel binders infused into the mat to form the connecting, rigidifying bridges.Type: GrantFiled: September 15, 1992Date of Patent: August 27, 1996Assignee: The Boeing CompanyInventor: Darryl F. Garrigus
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Patent number: 5545610Abstract: An oxide-based superconductor ccmprising Tl, Pb, Sr, Ca and Cu or Tl, Pb, Ba, Sr, Ca and Cu, prepared by subjecting a low melting point composition comprising the superconductor-constituting elements and a solid composition comprising the superconductor-constituting elements, prepared in advance, to reaction under melting conditions for the low melting point composition, has distinguished current pass characteristics in a high magnetic field due to improvement of electric contact among grains through reduction of non-superconductor phase, increase in crystal grain sizes (reduction of crystal boundaries), orientation of crystal and cleaning of crystal boundaries.Type: GrantFiled: September 2, 1993Date of Patent: August 13, 1996Assignee: Hitachi, Ltd.Inventors: Kazutoshi Higashiyama, Toshiya Doi, Takesi Ozawa, Seizi Takeuchi, Tomoichi Kamo, Shinpei Matsuda, Yutaka Yoshida
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Patent number: 5538657Abstract: A method of producing a ferrite magnet which comprises the steps of wet-grinding ferrite powder contained in a slurry to prepare a slurry of fine ferrite particles; concentrating the slurry of fine ferrite particles to have a predetermined solid content; kneading the concentrated slurry to disperse the fine ferrite particles; wet-compacting the kneaded slurry to form a green body; and sintering the green body to obtain the ferrite magnet. The ferrite powder having the following composition:MO.multidot.nFe.sub.2 O.sub.3wherein M is at least one element selected from the group consisting of Ba, Sr and Pb, and n is the number from 5 to 6. By employing the kneading process prior to the wet-compacting process, a high degree of particle orientation is achieved during the wet compacting in a magnetic field, enabling to produce a ferrite magnet having high magnetic properties.Type: GrantFiled: August 11, 1994Date of Patent: July 23, 1996Assignee: Hitachi Metals, Ltd.Inventors: Yasunobu Ogata, Mikio Yamamoto
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Patent number: 5536705Abstract: A family of mercury-containing Sr-(Ca.cndot.Y)-Cu-O superconducting materials having a zero-resistance temperature, T.sub.c(zero), greater than 90 K so that they can be cooled to and maintain the desired superconducting characteristics using relatively less expensive liquid nitrogen, are disclosed. The high-temperature superconductor is represented by the formula of: (Pb.sub.0.5 Hg.sub.0.5)(Sr.sub.2-x Ba.sub.x)(Ca.sub.0.7 Y.sub.0.3)Cu.sub.2 O.sub.7-.delta. ; wherein the value of x ranges between about 0.1 and about 0.6, preferably between about 0.2 and about 0.3. These superconducting materials are prepared by first grinding and mixing in open air constituent oxide powders of PbO, HgO, SrO.sub.2, BaO.sub.2, CaO, Y.sub.2 O.sub.3, and CuO. After mixing, the powder mixture is pressed under a pressure of about 5 ton/cm.sup.2 to form a pellet having a diameter of 8 mm and a thickness of 3 mm. Thereafter, the pressed pellet is wrapped with a gold foil (with a thickness of 0.Type: GrantFiled: July 31, 1995Date of Patent: July 16, 1996Assignee: Industrial Technology Research InstituteInventors: Ru-shi Liu, Der-Shiuh Shy, Chung-Ho Tai, Hui-Wen Lee
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Patent number: 5536449Abstract: A sintering ceramic for stable high-temperature thermistors includes a system of matter containing manganese (IV) and a content of a basic oxide. A method for producing a sintering ceramic for stable high-temperature thermistors includes calcining a mixture of SrCO.sub.3 and Mn.sub.2 O.sub.3 or Mn.sub.3 O.sub.4 ; adding an oxide hydroxide of a dopant in a molar quantity x to an aqueous suspension of the calcined oxide mixture; and then carrying out a compacting densification of the system of matter.Type: GrantFiled: August 15, 1994Date of Patent: July 16, 1996Assignee: Siemens AktiengesellschaftInventors: Adalbert Feltz, Ralph Kriegel, Franz Schrank
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Patent number: 5523270Abstract: The present invention broadly relates to novel complex oxidation reaction products such as perovskite bodies, including shaped complex oxidation reaction products. This invention also includes complex oxidation reaction products which exhibit superconducting properties.Type: GrantFiled: June 16, 1994Date of Patent: June 4, 1996Assignee: Lanxide Technology Company, LPInventors: Robert A. Rapp, Andrew W. Urquhart, Alan S. Nagelberg, Marc S. Newkirk
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Patent number: 5523284Abstract: In accordance this invention, there is provided a process for making a bulk superconductive material. In the first step of this process, a diffusion couple is formed from superconductor oxide and impurity oxide. Thereafter, the diffusion couple is heated to a temperature in excess of 800 degrees Centigrade, cooled at a controlled rate, and annealed.Type: GrantFiled: September 30, 1994Date of Patent: June 4, 1996Assignee: Alfred UniversityInventors: James G. Fagan, Jr., Vasantha R. W. Amarakoon
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Patent number: 5518972Abstract: Disclosed are ceramic materials and methods of making the same comprising yttrium, barium, silver, and either selenium or sulfur. Those ceramic materials show changes in magnetic susceptibility at around 373.degree. K. with selenium and 195.degree. K. with sulfur.Type: GrantFiled: December 21, 1993Date of Patent: May 21, 1996Assignee: Finch International LimitedInventors: Basil D. Shepherd, David L. Shaw
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Patent number: 5512538Abstract: Provided is a metal oxide material represented by the composition formula of Ln.sub.a Sr.sub.b Cu.sub.3-x M.sub.x O.sub.c, where 2.7.ltoreq.a+b.ltoreq.3.3; 0.8.ltoreq.a.ltoreq.1.2; 6.ltoreq.c.ltoreq.9; and 0.05 .ltoreq.x.ltoreq.0.7, Ln is at least one element selected from the group of elements of Y and lanthanoids or an atomic group consisting of said elements, and M is at least one element selected from the group of elements of Ti, V, Ga, Ge, Mo, W and Re or an atomic group consisting of said elements.Type: GrantFiled: June 27, 1994Date of Patent: April 30, 1996Assignee: Canon Kabushiki KaishaInventors: Tohru Den, Tamaki Kobayashi
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Patent number: 5512542Abstract: A novel metallic oxide of a Ln-Ca-Sr-Ba-Cu-B-O type and a process for manufacturing such a metallic oxide. The above metallic oxide has a composition expressed by the following formula (I):(Ln.sub.1-a Ca.sub.a)(Sr.sub.2-b Ba.sub.b)(Cu.sub.3-c B.sub.c)O.sub.d(I)wherein Ln is one or more kinds of elements selected from the group consisting of Y and lanthanoid elements except for Ce and Tb and wherein the following conditions are met: 0.1.ltoreq.a.ltoreq.0.5, 0.7.ltoreq.b.ltoreq.1.7, 0.1.ltoreq.c.ltoreq.0.5, and 6.5.ltoreq.d.ltoreq.7.5. A process for manufacturing the metallic oxide has the following steps. A mixture of materials including H.sub.3 BO.sub.3 used as a starting material of B is prepared. The resultant mixture is heated at a rate of 5.degree. C. or lower per minute up to 900.degree. C. or lower. Then, it is heated in an oxygen atmosphere at a range from 900.degree.-1050.degree. C.Type: GrantFiled: August 30, 1994Date of Patent: April 30, 1996Assignee: Canon Kabushiki KaishaInventors: Tohru Den, Norio Kaneko, Tamaki Kobayashi
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Patent number: 5508253Abstract: The present invention is characterized in that oxides of Y, Ba and Cu having a superconductive substance-forming composition are melted, the melt is rapidly cooled and solidified, the obtained sheet is heated at a temperature of 1000.degree. to 1350.degree. C. to produce a partially melted state thereof, and the sheet is gradually cooled at a rate lower than 200.degree. C./hr, whereby a micro-structure in which precipitates of the RE.sub.2 BaCuO.sub.5 phase having a diameter smaller than 20 .mu.m are dispersed in the REBa.sub.2 Cu.sub.3 O.sub.7-y crystal is obtained.Type: GrantFiled: April 17, 1995Date of Patent: April 16, 1996Assignee: Nippon Steel CorporationInventors: Mitsuru Morita, Katsuyoshi Miyamoto, Masato Murakami, Shoichi Matsuda
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Patent number: 5502015Abstract: The present invention provides an infrared ray transmitting material, even large-sized one being manufacturable at a low price, consisting of a polycrystal not liable to cleavage, which makes only a slight absorption of infrared rays all over the region of 8-11 .mu.m wave lengths, thus being highly transmissive. The material is a polycrystalline barium fluoride sintered body excellent in transmission to infrared region of 8-11 .mu.m wave lengths, one that is most excellent in the infrared transmission being produced by a method comprising the hot press sintering and the HIP treatment in combination, one that gives somewhat inferior transmission but which is low-priced by a method comprising the CIP molding and the normal pressure sintering in combination, and one that regarded as intermediate between the aforementioned two by a method comprising the CIP molding, normal-pressure sintering and the HIP treatment in combination, in all cases entirely without addition of any binder or sintering aid.Type: GrantFiled: February 16, 1995Date of Patent: March 26, 1996Assignee: Sumitomo Electric Industries, Ltd.Inventors: Kenichiro Shibata, Akihito Fujii, Toshihiro Sakamoto
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Patent number: 5502029Abstract: Superconductors using oxide superconducting materials having pinning centers inside crystal grains are enhanced in transmissible critical current density and allowed to have a high critical current density even in the magnetic field. A superconductor is produced comprising superconducting materials having a high irreversible magnetic field where the c axes of their crystals are oriented in one direction. This can be practically realized by heat-treating a superconducting material having the composition (Tl.sub.1-X1-X2 Pb.sub.X1 Bi.sub.X2)(Sr.sub.1-X3 Ba.sub.X3).sub.2 Ca.sub.2 Cu.sub.3 O.sub.9+X4 together with Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.8 having a tendency of growing in the form of plate crystal. Various apparatuses capable of working under cooling with liquid nitrogen let alone with liquid helium and having a high superconducting critical current density even in a high magnetic field can be produced.Type: GrantFiled: January 26, 1994Date of Patent: March 26, 1996Assignee: Hitachi, Ltd.Inventors: Toshiya Doi, Atsuko Soeta, Seizi Takeuchi, Tomoichi Kamo, Shinpei Matsuda
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Patent number: 5502014Abstract: The present invention relates to non-magnetic ceramic substrate material for magnetic head having similar thermal expansivity to the metal magnetic thin film, abrasion resistance during contact traveling of the magnetic tape and good processability and thus increasing lifetime by preventing exfoliation and crack of the magnetic thin film. The material comprises 10-35 mol % of CaO, 10-40 mol % of TiO.sub.2, 10-60 mol % of NiO and 10-50 mol % of CoO.Type: GrantFiled: November 22, 1994Date of Patent: March 26, 1996Assignee: Goldstar Co., Ltd.Inventor: Won H. Lee
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Patent number: 5500041Abstract: A composition for the preparation of articles of calcium oxide, comprising calcined calcium oxide and an organic phase consisting of at least one polyol in an anhydrous medium. The composition may be used to form linings for molds and crucibles intended to come into contact with molten metals of groups IV and V of the periodic table.Type: GrantFiled: September 30, 1993Date of Patent: March 19, 1996Assignees: Institut National des Science Appliquees de Rennes, Microsteel S.A.Inventors: Jean Debuigne, Serge Prigent
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Mercury-thallium-barium-calcium-strontium-copper-oxide 1223 superconductor and method of making same
Patent number: 5492885Abstract: Mercury-thallium based superconductors with the formula Hg.sub.1-x Tl.sub.x Ba.sub.2 (Ca.sub.1-y Sr.sub.y).sub.2 Cu.sub.3 O.sub.8+.delta. ; change "their preparing method, in particular characterized in that it" to and a method for preparing them. The new superconductors are prepared by reacting respective ternary oxides, such as Ba.sub.2 CuO.sub.3+x and Ca.sub.1-y Sr.sub.y CuO.sub.2, to reduce the formation of an impure phase and by substituting thallium (Ti) a portion of the mercury (Hg) conventionally used in mercury-based superconductors of similar structure, in order to thermally stabilize the superconductor and provide it with a high critical current density characteristic.Type: GrantFiled: August 17, 1994Date of Patent: February 20, 1996Assignee: Korea Research Institute of Standards and ScienceInventors: Yong H. Hur, Yong K. Park, Jong C. Park -
Patent number: 5488018Abstract: Three families of ceramic compositions having the given formula: .phi..sub.1+X Zr.sub.4 P.sub.6-2X Si.sub.2X O.sub.24, .phi..sub.1+X Zr.sub.4-2X Y.sub.2X P.sub.6 O.sub.24 and .phi..sub.1+X Zr.sub.4-X Y.sub.X P.sub.6-2X Si.sub.X O.sub.24 wherein .phi. is either Strontium or Barium and X has a value from about 0.2 to about 0.8 have been disclosed. Ceramics formed from these compositions exhibit very low, generally near neutral, thermal expansion over a wide range of elevated temperatures.Type: GrantFiled: April 21, 1989Date of Patent: January 30, 1996Inventor: Santosh Y. Limaye
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Patent number: 5478498Abstract: A disordered fluorite-type photochemical hole burning crystal contains Sm.sup.2+ as active ions, and a composition except Sm.sup.2+ is represented by a general formula .alpha.-(MALn)F.sub.6-v X.sub.v where 0.ltoreq.v.ltoreq.1, and M is an element selected from Ca, Sr and Ba, A is an element selected from Na, K, Rb and Cs, Ln is an element selected from Y, La, Gd and Ce, and X is an element selected from Cl, Br and I. Stable hole burning occurs at the room temperature to create narrow holes. The crystal can be used as a superior optical recording material for a room temperature operation.Type: GrantFiled: December 2, 1994Date of Patent: December 26, 1995Assignee: Tosoh CorporationInventors: Nobuhiro Kodama, Kazuyuki Hirao, Shinichi Hara, Yuka Inoue
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Patent number: 5457088Abstract: To prepare a phase-pure, ceramic oxide superconductor which contains, in addition to copper, at least one alkaline earth metal from the group comprising Ba, Sr and Ca, and at least one metal from the group comprising Y, La, Tl, Pb and the rare earths, for example of YBa.sub.2 Cu.sub.3 O.sub.7-x, a solution is prepared which contains the metal components in the atomic ratios of the superconductor. The metals are precipitated as oxalates by combining this solution with an oxalic acid solution, the mixture of the oxalates is separated off, dried and decomposed to form the oxides, and the latter are subsequently sintered at temperatures of from 700.degree. to 900.degree. C. in the presence of oxygen to form the superconductor. In this process, the heating of the metal oxalates and the oxides formed therefrom up to 700.degree. C. is carried out at a maximum oxygen partial pressure of 50 mbar, preferably in an inert gas.Type: GrantFiled: September 7, 1990Date of Patent: October 10, 1995Assignee: Hoechst AktiengesellschaftInventor: Winfried Becker
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Patent number: 5433778Abstract: Compounds that satisfy the general formula A.sub.1-Y.sup.4+ A.sub.Y.sup.1+ A.sub.Y.sup.3+ V.sub.2-X E.sub.X O.sub.7 exhibit isotropic NTE behavior above a temperature of about 100.degree. C. Y is from about 0.0 to about 0.4, and more preferably is about 0.2. X is from about 0.6 to about 1.4, and is more preferably about 1. Particularly suitable NTE compounds have X about 1 and Y about 0. A.sup.4+ is selected from the group consisting of Hf, Zr, Zr.sub.a M.sub.b, Hf.sub.a M.sub.b and mixtures thereof wherein a plus b equals one and M is selected from the group consisting of Ti, Ce, Th, U, Mo, W, Pb, Sn, Ge and Si. More preferably, A.sup.4+ is selected from the group consisting of Hf and Zr. A.sup.1+ is selected from the group consisting of the alkali earth metals, A.sup.3+ is selected from the group consisting of the rare earth metals, and E is selected from the group consisting of P and As. The NTE materials may be incorporated into compositions such as epoxy and ceramic compositions.Type: GrantFiled: May 11, 1994Date of Patent: July 18, 1995Assignee: The State of Oregon Acting By and Through the State Board of Higher Education on Behalf of Oregon State UniversityInventor: Arthur W. Sleight
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Patent number: 5432024Abstract: A porous sintered body composed mainly of lanthanum manganite in which a part of lanthanum atoms at A-sites of the lanthanum manganite are substituted by atoms of a metal selected from the group consisting of alkaline earth metals and rare earth metals. The dimensional shrinkage amount of the porous sintered body in heat cycling between room temperature and 1,000.degree. C. is not more than 0.01% per one heat cycle.Type: GrantFiled: October 12, 1993Date of Patent: July 11, 1995Assignee: NGK Insulators, Ltd.Inventors: Takao Soma, Tomonori Takahashi, Shinji Kawasaki, Kazuyo Mori, Yoshihiro Ito, Katsuki Yoshioka
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Patent number: 5432143Abstract: A method of producing a microcrystalline RBa.sub.2 Cu.sub.3 O.sub.y structure where R denotes a lanthanide chosen from Y, La, Nd, Sm, Eu, Gd, Tb, Ho, Er, Tm, Yb and Lu and where y has a value between 6.9 and 7 starts with a powder of composition [x(123) ; (1-x) (7BaO--18CuO] where (123) denotes the 123 phase of RBaB.sub.2 Cu.sub.3 O.sub.y and where the value of x is between 0.01 and 1. The powder is compressed and sintered at a temperature below 920.degree. C. (the BaCuO.sub.2 and CuO binary eutectic temperature) to form a sample. The sample is placed on an oxide of the lanthanide R. The sample and its support undergo heat treatment enabling chemical reaction between the liquid part of the sample and its support whereby substantially all of the liquid part is consumed and highly regular 123 monocrystals are obtained. Cooling is applied. At least one annealing is carried out in pure oxygen at a temperature between 350.degree. C. and 500.degree. C. to obtain the orthorhombic form characteristic of RBa.sub.2 Cu.Type: GrantFiled: January 11, 1994Date of Patent: July 11, 1995Assignee: Alcatel Alsthom Compagnie Generale D'ElectriciteInventors: Nadia Pellerin, Philippe Odier
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Patent number: 5423995Abstract: The invention relates to a piezoelectric ceramic material based on lead zirconate titanate and further additives, which contains as additives complex compounds having the formulaA(W.sub.1/3.sup.6+ Ni.sub.2/3.sup.3+)O.sub.3 or A(W.sub.1/2.sup.6+ Ni.sub.1/2.sup.2+)O.sub.3with A=Pb, Sr, Ba or Ca as ternary or quaternary solid solutions in an amount from 1 to 10 mol %, based on the total amount of ceramic material. The ceramic material of the invention can be advantageously used in sound or ultrasound transducers for acoustics or underwater sound applications or in actuators.Type: GrantFiled: March 10, 1994Date of Patent: June 13, 1995Assignee: Hoechst AktiengesellschaftInventors: Gunter Helke, Hans-Joachim Langer
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Patent number: 5413981Abstract: A method for manufacturing the oxide superconductor according to the present invention comprises the steps of: mixing a starting material including Bi, Sr, Ca and Cu such that a mole ratio of Bi, Sr, Ca and Cu is 2:2+a:1+b:2+c, wherein a.gtoreq.0, b.gtoreq.0, c.gtoreq.0, and 0<a+b+c<3; melting the mixed material at a temperature of 900.degree. C.-1500.degree. C.; quenching rapidly the molten material; and annealing the quenched material at a partial molten temperature of 800.degree. C.-1000.degree. C. This method gives product wherein a precipitate of at least one compound in the group SrO, CuO and (Ca.sub.1-x Sr.sub.x).sub.2 CuO.sub.3 (wherein 0.gtoreq.x<1) is finely dispersed in the superconducting crystal of Bi.sub.2 Sr.sub.2 Ca.sub.1 Cu.sub.2 O.sub.y (wherein y is about 8). The precipitates act as flux pinning centers.Type: GrantFiled: July 19, 1993Date of Patent: May 9, 1995Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Kunihiko Egawa, Toshio Umemura, Shinichi Kinouchi, Mitsunobu Wakata, Shin Utsunomiya, Ayumi Nozaki