Barium Titanate Patents (Class 501/137)
  • Patent number: 7498285
    Abstract: A nonreducing dielectric ceramic comprising a (Sr, Ca)(Ti, Zr)O3-based perovskite principal crystal phase containing 55 mole percent or more of SrTiO3 and whose powder CuK? X-ray diffraction pattern exhibits a ratio of less than 5% of the maximum peak intensity of the accessory crystal phases being the other crystal phases to the intensity of the maximum peak of the perovskite crystal phase, which is present at 2?=25° to 35°. This strontium titanate-based nonreducing dielectric ceramic has a high relative dielectric constant of 150 or more, a low third-order harmonic distortion ratio, and an excellent reliability in a high temperature-loading test. Accordingly, it is advantageously used for forming dielectric ceramic layers of a monolithic ceramic capacitor.
    Type: Grant
    Filed: October 19, 2007
    Date of Patent: March 3, 2009
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Toshiyuki Ito, Harunobu Sano
  • Publication number: 20090036293
    Abstract: It is intended to provide a semiconductor ceramic composition containing no Pb, which is capable of shifting the Curie temperate to a positive direction as well as of controlling room temperature resistivity and having an excellent jump characteristic. Since the semiconductor ceramic composition in which a portion of Ba of BaTiO3 is substituted by Bi—Na has a crystal in which a central part and an outer shell part of a crystal grain are different from each other in composition, the composition is capable of improving control of room temperature resistivity and a jump characteristic, and therefore it is optimum as a material for a PTC thermistor, a PTC heater, a PTC switch, a temperature detector, and the like.
    Type: Application
    Filed: February 27, 2007
    Publication date: February 5, 2009
    Inventors: Takeshi Shimada, Kazuya Toji
  • Publication number: 20090011922
    Abstract: Circuit modules and methods of construction thereof that contain composite meta-material dielectric bodies that have high effective values of real permittivity but which minimize reflective losses, through the use of host dielectric (organic or ceramic), materials having relative permittivities substantially less than ceramic dielectric inclusions embedded therein. The composite meta-material bodies permit reductions in physical lengths of electrically conducting elements such as antenna element(s) without adversely impacting radiation efficiency. The meta-material structure may additionally provide frequency band filtering functions that would normally be provided by other components typically found in an RF front-end.
    Type: Application
    Filed: July 21, 2008
    Publication date: January 8, 2009
    Inventor: L. Pierre de Rochemont
  • Publication number: 20080305944
    Abstract: Dielectric ceramics capable of decreasing the displacement causing ringing and a multi-layer ceramic capacitor capable of decreasing occurrence of ringing in which the dielectric ceramics comprise a solid solution represented by: Ba—Ti—Zr—Re-Me-O3 where (Re is at least one metal element selected from La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Y, Me is a metal element selected from Mg, Cr, and Mn, and Zr is an arbitrary ingredient), and SiO2, where Ti:Zr is from 100:0 to 75:25, and Ba is from 97 mol to 103 mol, Re is from 2 mol to 18 mol, Me is from 2 mol to 18 mol, and SiO2 is from 0.5 mol to 10 mol assuming Ti+Zr as 100 mol.
    Type: Application
    Filed: April 8, 2008
    Publication date: December 11, 2008
    Applicant: Yaiyo Yuden Co., Ltd.
    Inventors: Shusaku Ueda, Kazumi Kaneda, Shinichiro Ikemi
  • Publication number: 20080293560
    Abstract: A ceramic electronic device including a dielectric layer, wherein the dielectric layer includes a main component expressed by a composition formula of BamTiO2+m, wherein “m” satisfies 0.995?m?1.010 and a ratio of Ba and Ti satisfies 0.995?Ba/Ti?1.010, and a subcomponent (a sixth subcomponent) including an oxide of Al; and a content of the Al compound is 0 to 4.0 moles (note that 0 is not included) in terms of Al2O3 with respect to 100 moles of the main component; and preferably, the dielectric layer includes a segregation phase, and the segregation phase includes an oxide of Al.
    Type: Application
    Filed: July 24, 2008
    Publication date: November 27, 2008
    Applicant: TDK Corporation
    Inventors: Kazushige Ito, Akira Sato
  • Patent number: 7446068
    Abstract: A dielectric material is provided. The dielectric material includes a main composition including a Ba2Ti9O20 having a weight ranged from 50 to 94.9 wt %; a first sub-composition including a GeO2 and an MnCO3 respectively having a weight ranged from 0.01 to 10 wt %; and a second sub-composition including a glass additive composed of a B2O3, a ZnO, a SiO2 and at least one of a CuO, a CaCO3 and a BaCO3, wherein the glass additive has a weight ranged from 5 to 40 wt %.
    Type: Grant
    Filed: March 5, 2007
    Date of Patent: November 4, 2008
    Assignee: Walsin Technology Corporation
    Inventors: Yiling Wang, Wenjun Wu, Meyiu Zhao, Wei Li, Tsai Tsung Tsai, Akira Sawasaki
  • Publication number: 20080254968
    Abstract: The present invention relates to a dielectric ceramic composition comprising a main component including at least one selected from barium titanate, strontium titanate and calcium titanate, and as a subcomponent, a glass component including an oxide of B, wherein a content of said glass component is 2 to 7 wt % with respect to 100 wt % of said main component. According to the present invention, there are provided a dielectric ceramic composition wherein a layer can be made thinner by relatively decreasing a content of the glass component, etc., as well as having good properties (specific permittivity, loss Q value and insulation resistance), and a complex electronic device such as a multilayer filter or a multilayer ceramic capacitor, which has a dielectric layer composed of the dielectric ceramic composition.
    Type: Application
    Filed: March 28, 2008
    Publication date: October 16, 2008
    Applicant: TDK CORPORATION
    Inventors: Kouichi Kakuda, Takashi Suzuki, Sachiko Takano, Hiroshi Momoi, Shinichi Kondo, Masaki Takahashi
  • Patent number: 7431911
    Abstract: The present invention provides a barium titanate having a small particle size, containing small amounts of unwanted impurities, and exhibiting excellent electric characteristics, which can be employed for forming a dielectric ceramic thin film required for a small-sized capacitor which enables production of a small-sized electronic apparatus; and a process for producing the barium titanate. When a titanium oxide sol is reacted with a barium compound in an alkaline solution containing a basic compound, the basic compound is removed in the form of gas after completion of reaction, and the resultant reaction mixture is fired, a barium titanate having a large BET specific surface area and a high tetragonality content is produced.
    Type: Grant
    Filed: July 3, 2002
    Date of Patent: October 7, 2008
    Assignee: Showa Denko K.K.
    Inventors: Akihiko Shirakawa, Hitoshi Yokouchi
  • Patent number: 7431908
    Abstract: Spherical tetragonal barium titanate particles of the present invention have a perovskite crystal structure, an average particle diameter of 0.05 to 0.5 ?m, a particle size distribution ?g of not less than 0.70, and a ratio of Ba to Ti of 0.99:1 to 1.01:1. The spherical tetragonal barium titanate particles exhibit an excellent dispersibility as well as a high denseness, a high purity and excellent permittivity properties.
    Type: Grant
    Filed: September 13, 2004
    Date of Patent: October 7, 2008
    Assignee: Toda Kogyo Corporation
    Inventors: Toshiharu Harada, Yuji Mishima, Seiji Okazaki, Haruki Kurokawa, Hidetomo Unemoto, Kazuyoshi Murashige, Manabu Matsumoto, Tadashi Kanasaku
  • Publication number: 20080236723
    Abstract: A production method of a dielectric ceramic composition at least including a main component including a dielectric oxide having perovskite-type crystal structure expressed by a formula ABO3 (note that in the formula, “A” indicates one or more elements selected from Ba, Ca, Sr and Mg, and that “B” indicates one or more elements selected from Ti, Zr and Hf) comprises steps of preparing a main component material including said dielectric oxide expressed by ABO3; preparing a subcomponent material including a composite oxide expressed by M4R6O(SiO4)6 (note that “M” indicates at least one selected from Ca and Sr, and that “R” indicates at least one selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu); mixing said main component material and subcomponent material to obtain a dielectric ceramic composition material; and firing said dielectric ceramic composition material.
    Type: Application
    Filed: March 18, 2008
    Publication date: October 2, 2008
    Applicant: TDK CORPORATION
    Inventors: Tomoaki Nonaka, Hiroshi Sasaki, Tsutomu Odashima, Tetsuo Takaishi, Takahiro Harada
  • Publication number: 20080227623
    Abstract: BaTiO3—PbTiO3 series single crystal is single-crystallized by heating BaTiO3—PbTiO3 compact powder member or sintered member having a smaller Pb-containing mol number than Ba-containing mol number, while keeping the powder or substance in non-molten condition. In this way, this single crystal can be manufactured at a crystal growing speed faster still and stabilized more, significantly contributing to improving the dielectric loss and electromechanical coupling coefficient for the provision of excellent BaTiO3—PbTiO3 series single crystal in various properties, as well as for the provision of piezoelectric material having a small ratio of lead content, which is particularly excellent in piezoelectric property and productivity.
    Type: Application
    Filed: May 21, 2008
    Publication date: September 18, 2008
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Hiroshi Aoto, Akira Unno, Tetsuro Fukui, Akio Ikesue
  • Publication number: 20080220964
    Abstract: A ceramic material powder comprised of main ingredient particles formed by barium titanate having on their surfaces a covering layer comprised of a secondary ingredient additive, wherein when an average radius of the main ingredient particles is “r” and an average radius of the covering layer is “?r”, the ?r is controlled to a range of 0.015 r to 0.055 r, thereby enabling acquisition of a multilayer ceramic capacitor or other electronic device satisfying both the X7R characteristic prescribed in the EIAJ standard and B characteristic prescribed in the Japan Industrial Standard (JIS), that is, excellent in temperature stability of the electrostatic capacity, having a good insulation resistance value, relative dielectric constant, or other characteristics, and having a long accelerated life of the insulation resistance.
    Type: Application
    Filed: March 28, 2008
    Publication date: September 11, 2008
    Applicant: TDK Corporation
    Inventors: Yoshinori Fujikawa, Yuji Umeda, Fumikazu Yamane
  • Publication number: 20080200327
    Abstract: The present invention provides a method of producing the barium titanate solid solution single crystals. The crystalline phase of the single crystal is hexagonal. The method of the present invention, a small quantity of metal oxide is added and dissolved into the barium titanate to form a solid solution. The metal oxides are used as single crystal growth aid; and the barium titanate single crystal can be prepared by using a pressureless sintering process composing of one or two stages of heat treatments that require no special expensive equipments, and thus the method can be used for the mass production of the single crystals.
    Type: Application
    Filed: August 2, 2007
    Publication date: August 21, 2008
    Inventors: Wei-Hsing Tuan, Yung-Ching Huang
  • Publication number: 20080193776
    Abstract: A nonreducing dielectric ceramic comprising a (Sr, Ca)(Ti, Zr)O3-based perovskite principal crystal phase containing 55 mole percent or more of SrTiO3 and whose powder CuK? X-ray diffraction pattern exhibits a ratio of less than 5% of the maximum peak intensity of the accessory crystal phases being the other crystal phases to the intensity of the maximum peak of the perovskite crystal phase, which is present at 2?=25° to 35°. This strontium titanate-based nonreducing dielectric ceramic has a high relative dielectric constant of 150 or more, a low third-order harmonic distortion ratio, and an excellent reliability in a high temperature-loading test. Accordingly, it is advantageously used for forming dielectric ceramic layers of a monolithic ceramic capacitor.
    Type: Application
    Filed: October 19, 2007
    Publication date: August 14, 2008
    Applicant: MURATA MANUFACTURING CO., LTD.
    Inventors: Toshiyuki Ito, Harunobu Sano
  • Patent number: 7396791
    Abstract: A dielectric ceramic composition comprising a main component including Ba, Ca and Ti and having a perovskite crystal structure expressed by a general formula ABO3 and a fourth subcomponent including a compound of Zr; wherein a content of the fourth subcomponent with respect to 100 moles of the main component is larger than 0 mole and smaller than 5 moles in terms of Zr and, preferably, a segregation phase including the compound of Zr is provided.
    Type: Grant
    Filed: January 17, 2006
    Date of Patent: July 8, 2008
    Assignee: TDK Corporation
    Inventors: Kazushige Ito, Akira Sato
  • Patent number: 7396790
    Abstract: A translucent ceramic having a high light transmittance is provided. It contains a perovskite compound having a composition represented by a general formula: (Ba1-s-tSrsCat)(MxB1yB2z)vOw (where M contains at least one of Sn, Zr and Hf, B1 represents at least one of Mg, Zn, Y and In, B2 represents at least one of Ta and Nb, each of conditions of 0?s?0.99, 0.01?t?0.45, x+y+z=1, 0<x?0.9, 1.00?z/y?2.40, and 0.97?v?1.05 is satisfied, and w represents a positive number for maintaining electrical neutrality) as a primary component. This translucent ceramic can be used as, for example, an objective lens (2) of an optical pickup (9) to provide advantages. In another aspect some of M is replaced by Ti.
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: July 8, 2008
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Satoshi Kuretake, Yuji Kintaka
  • Patent number: 7351676
    Abstract: A dielectric ceramic composition of the present invention includes 100 parts by mole of BaTiO3, x1 parts by mole of MnO, x2 parts by mole of Cr2O3, x3 parts by mole of Y2O3 and/or Ho2O3, x4 parts by mole of oxide selected from the group consisting of BaO, CaO and SrO, and x5 parts by mole of SiO2 and/or GeO2, where 0.5?x1?4.5, 0.05?x2?1.0, x1+x2?4.55, 0.25?x3?1.5, 0.5 ?x4?6 and 0.5?x5?6. A multilayer ceramic capacitor of the present invention includes a laminated structure of a ceramic dielectric made of such a composition and an electrode made of Ni or Ni alloy.
    Type: Grant
    Filed: August 11, 2004
    Date of Patent: April 1, 2008
    Assignee: Rohm Co., Ltd.
    Inventors: Akihiro Koga, Yukio Tominaga, Tetsuhiro Takahashi
  • Patent number: 7351674
    Abstract: An insulating ceramic composition forming insulating ceramic layers (3) stacked in a multilayer ceramic substrate (2) used in a monolithic ceramic electronic component, such as a multilayer ceramic module (1). The insulating ceramic composition contains a first ceramic powder mainly containing forsterite, a second ceramic powder mainly containing at least one compound selected from the group consisting of CaTiO3, SrTiO3, and TiO2, and a borosilicate glass powder. The borosilicate glass powder contains 3 to 15 percent by weight of lithium in terms of Li2O, 30 to 50 percent by weight of magnesium in terms of MgO, 15 to 30 percent by weight of boron in terms of B2O3, 10 to 35 percent by weight of silicon in terms of SiO2, 6 to 20 percent by weight of zinc in terms of ZnO, and 0 to 15 percent by weight of aluminum in terms of Al2O3. The insulating ceramic composition can be fired at a temperature of 1000° C.
    Type: Grant
    Filed: February 2, 2005
    Date of Patent: April 1, 2008
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Naoya Mori, Yoichi Moriya, Jun Urakawa, Yasutaka Sugimoto
  • Patent number: 7297322
    Abstract: A process for producing powders of metal compound containing oxygen including the steps of: feeding at least one material selected from a liquid material and a solution material obtained by dissolving solid ingredient in organic solvent via a liquid flow controller into a vaporizer; vaporizing the materials in the vaporizer; adding oxygen; heating; cooling; and crystallizing. Also disclosed is the product formed by this process, and apparatus used in performing the process. The process and the apparatus enable easily mass-producing fine powders of metal compound containing oxygen used as materials for optical crystals, nonlinear crystals or magneto-optical crystals with reasonable production cost.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: November 20, 2007
    Assignee: Japan Pionics Co., Ltd.
    Inventors: Yukichi Takamatsu, Koji Kiriyama, Akira Asano, Takafumi Ishii
  • Patent number: 7297650
    Abstract: The production of low-loss, tunable composite ceramic materials with improved breakdown strengths is disclosed. The composite materials comprise ferroelectric perovskites such as barium strontium titanate or other ferroelectric perovskites combined with other phases such as low-loss silicate materials and/or other low-loss oxides. The composite materials are produced in sheet or tape form by methods such as tape casting. The composite tapes exhibit favorable tunability, low loss and tailorable dielectric properties, and can be used in various microwave devices.
    Type: Grant
    Filed: April 13, 2005
    Date of Patent: November 20, 2007
    Assignee: Paratek Microwave, Inc.
    Inventors: Luna H. Chiu, Xubai Zhang, Louise C. Sengupta
  • Patent number: 7294597
    Abstract: A translucent ceramic principally contains a composition represented by the formula Ba{Tix1Mx2(Mg1-tZnt)y(Ta1-uNbu)z}vOw, wherein M is at least one selected from the group consisting of Sn, Zr, and Hf; w is a positive number for maintaining the electrical neutrality; x1+x2+y+z=1; 0.015?x1+x2?0.90; 0<x1?0.90; 0?x2?0.60; 1.60?z/y?2.40; 1.00?v?1.05; 0<t<1; and 0?u?1. The translucent ceramic has high linear transmittance over a wide wavelength range and a large refractive index, is controllable in refractive index and Abbe number in a wide range, and is not birefringent. Therefore, lenses (2) made of the translucent ceramic are suitable for optical pickups (9) and other devices that must be small-sized and thin.
    Type: Grant
    Filed: March 9, 2005
    Date of Patent: November 13, 2007
    Assignee: Murata Manufacturing Co., Ltd.
    Inventor: Yuji Kintaka
  • Patent number: 7291321
    Abstract: A perovskite catalyst is prepared using a ceramic sol-sol methodology comprising preparing slurry in water of an alkaline earth metal salt, a powdered metal salt and a powdered transition metal oxide, adding a polymeric binder to form a paste, drying and comminuting the paste into a powder and heating the powder with a temperature profile to calcination temperatures. In one embodiment the slurry is formed of titanium oxide with barium carbonate and tin chloride in deionized water, and more specifically by a mixture according to Ba (1-0.05x)+TiO2+SnCl2(0.05x) where x is in moles. The perovskite catalyst is preferably used in a process for oxidative coupling of methane. Catalyst performance is enhanced through the addition of halides to the feed gas in the reaction.
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: November 6, 2007
    Assignee: HRD Corp.
    Inventors: Ebrahim Bagherzadeh, Abbas Hassan, Aziz Hassan
  • Publication number: 20070213200
    Abstract: A dielectric material is provided. The dielectric material includes a main composition including a Ba2Ti9O20 having a weight ranged from 50 to 94.9 wt %; a first sub-composition including a GeO2 and an MnCO3 respectively having a weight ranged from 0.01 to 10 wt %; and a second sub-composition including a glass additive composed of a B2O3, a ZnO, a SiO2 and at least one of a CuO, a CaCO3 and a BaCO3, wherein the glass additive has a weight ranged from 5 to 40 wt %.
    Type: Application
    Filed: March 5, 2007
    Publication date: September 13, 2007
    Applicant: WALSIN TECHNOLOGY CORPORATION
    Inventors: Yiling Wang, Wenjun Wu, Meiyu Zhao, Wei Li, T. L. Tsai, Akira Sawasaki
  • Publication number: 20070203015
    Abstract: The present invention discloses a new dielectric material can be used as the dielectric for base-metal electrode multilayer ceramic capacitors. In the present invention, a small amount of fine metallic particles are added into barium titanate based powder. The metallic particles can absorb oxygen to prevent the oxidation of the internal electrode. The metal is then oxidized to result in an oxide that can dissolve into the dielectric. The dielectric material of the present invention can be co-fired with nickel or copper internal electrode in a sintering atmosphere of commercial nitrogen or even of air. After sintering, no post-sintering heat treatment is needed.
    Type: Application
    Filed: February 22, 2007
    Publication date: August 30, 2007
    Inventors: Wei-Hsing Tuan, Yung-Ching Huang
  • Publication number: 20070203014
    Abstract: A dielectric ceramic composition, comprising a main component including a dielectric oxide, and a sintering auxiliary comprising a first component including an oxide of Li and a second component including an oxide of M1 (note that M1 is at least one kind of element selected from group V elements and VI group elements): wherein said dielectric ceramic composition comprises a plurality of dielectric particles and crystal grain boundaries existing between said dielectric particles next to each other; concentration of M1 element becomes lower from a particle surface to inside thereof in the plurality of dielectric particles; and when assuming that a particle diameter of said dielectric particles is D and a content ratio of the M1 element at said crystal grain boundaries is 100%, a content ratio of the M1 element at a depth T50, where a depth from the particle surface is 50% of said particle diameter D, is 3 to 55%.
    Type: Application
    Filed: February 22, 2007
    Publication date: August 30, 2007
    Applicant: TDK CORPORATION
    Inventor: Yasuo Watanabe
  • Patent number: 7247590
    Abstract: The composite dielectric of the present invention contains an aromatic liquid crystal polyester and a dielectric ceramic powder arranged in the aromatic liquid crystal polyester, wherein the dielectric ceramic powder exhibits a Q value greater than 650 at a frequency of 1 GHz by perturbation. A wiring board comprising a composite dielectric sheet made of a composite dielectric having such a characteristic exhibits a high dielectric constant and a low dielectric dissipation factor, thereby yielding less transmission loss, and thus can favorably be used in electronic instruments driven in high-frequency regions.
    Type: Grant
    Filed: July 1, 2004
    Date of Patent: July 24, 2007
    Assignee: TDK Corporation
    Inventors: Kenichi Kawabata, Takaaki Morita
  • Patent number: 7241712
    Abstract: The present invention relates to a low-temperature sintered barium titanate microwave dielectric ceramic material. The host matrix thereof can be represented by BaxTiyMzOx+2y+k, where x is 1˜6, y is 1˜17, z is 0˜1, k is 0˜3, M is an element substituting the Ba or Ti ion, for example selected from an alkali metal, an alkaline-earth metal, a transition group or a rare earth group, and preferably Ba2Ti9O20 or the host matrix containing Zr, Sn, Zn, etc. According to the present invention, a low melting glass is added and a subsequent milling operation is performed to reduce the sintering temperature of the microwave dielectric ceramic material to less than 1,000° C. The low melting glass can be for example the Ba—B—Si—Li glass, Ba—B—Zn—Si—Li glass, Ba—B—Si—Li—Cu glass or Cu—B—Zn—Si—Li glass.
    Type: Grant
    Filed: February 28, 2005
    Date of Patent: July 10, 2007
    Assignee: National Taiwan University Technology
    Inventors: Sea-Fue Wang, Yuh-Ruey Wang, Mei-Hui Hsiao
  • Patent number: 7223378
    Abstract: Process for preparing barium titanate or strontium titanate by reacting titanium alkoxides with barium hydroxide hydrate or strontium hydroxide hydrate in a C1–C8-alcohol or a glycol ether at from 50 to 150° C.
    Type: Grant
    Filed: May 12, 2003
    Date of Patent: May 29, 2007
    Assignee: BASF Aktiengesellschaft
    Inventor: Hans-Josef Sterzel
  • Patent number: 7182930
    Abstract: A method of fabricating barium titanate powders uses titanium tetrachloride and barium hydroxide as reactants in a reaction solution. The pH value of the reaction solution is adjusted to strongly alkaline range by adding potassium hydroxide. Nitrogen is charged into a reaction tank at normal pressure, and the reaction solution is heated at 80–102°. The solution is intensively stirred at constant temperature, and then subjected to a hydro-thermal reflux. Then, the solution is treated through an ion exchange resin and dried to obtain a cubic BaTiO3 powders.
    Type: Grant
    Filed: June 18, 2004
    Date of Patent: February 27, 2007
    Assignee: Chung Shan Institute of Science and Technology
    Inventors: Ming-Tseh Tsay, Zong-Whie Shih, Pao-Yen Lin
  • Patent number: 7179441
    Abstract: The present invention relates to a method for preparing barium titanate based powder. More particularly, the present invention provides a method for preparing barium titanate powder comprising the following steps of precipitation of barium titanyl oxalate (BaTiO(C2O4)2.4H2O) with spraying a mixture of an aqueous barium chloride (BaCl2.2H2O) and titanium tetrachloride (TiCl4) to an aqueous solution of oxalic acid, via a nozzle; wet pulverization by using a beads mill after adding an additive such as an amine; dry; pyrolysis; and re-pulverization.
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: February 20, 2007
    Assignees: Samsung Fine Chemicals Co., Ltd., Samsung Electro-Mechanics Co., Ltd.
    Inventors: Jae Chul Jung, Woo Young Yang, Keon Il Kim, Yun Jung Park, Jun Hee Lee, Kang Heon Hur, Seon Cheol Park, Jai Joon Lee
  • Patent number: 7157396
    Abstract: A method of production of a reduction resistant dielectric ceramic composition having a superior low frequency dielectric characteristic and further improved in accelerated lifetime of insulation resistance, specifically a method of production of a dielectric ceramic composition containing a main component including a dielectric oxide of a specific composition, a first subcomponent including a V oxide, a second subcomponent containing an Al oxide, a third subcomponent containing an Mn oxide, and a fourth subcomponent containing a specific sintering aid in a specific ratio, including a step of mixing at least part of the materials of the subcomponents excluding one or both of at least the material of the third subcomponent and material of the fourth subcomponent with the starting materials prepared for obtaining the material of the main component to prepare the pre-reaction material, a step of causing the prepared pre-reaction material to react to obtain a reacted material, and a step of mixing the materials o
    Type: Grant
    Filed: November 22, 2004
    Date of Patent: January 2, 2007
    Assignee: TDK Corporation
    Inventors: Yasuo Watanabe, Kenta Endoh, Wataru Takahara
  • Patent number: 7151067
    Abstract: A porous catalyst layer containing mixed conducting oxide having substantially a perovskite structure and containing a first element selected from Co and Fe, and a second element selected from In, Sn and Y arranged in the B site in the perovskite structure is contiguous to a second surface (1a) of a selective oxygen-permeable dense continuous layer (1) containing mixed conducting oxide. A porous intermediate catalyst layer (3) containing mixed conducting oxide and at least one of Co, Fe, Mn and Pd is contiguous to a first layer (1b) of the dense continuous layer (1). A porous reactive catalyst layer (4) provided with a metal catalyst selected from at least one of Ni, Co, Ru, Rh, Pt, Pd, Ir and Re and a support is continguous to the porous intermediate catalyst layer (3) in a manner to sandwich between the dense continuous layer (1) and the porous reactive catalyst layer (4).
    Type: Grant
    Filed: October 11, 2002
    Date of Patent: December 19, 2006
    Assignees: Nippon Steel Corporation, Teikoku Oil Co., Ltd.
    Inventors: Tadashi Sakon, Wataru Ito, Hitoshi Dohnomae, Toru Nagai, Hideki Kurimura, Shouichi Kaganoi, Youhei Suzuki, Takashi Ito
  • Patent number: 7149073
    Abstract: An electroceramic component includes a base body, contact layers on the base body, a dielectric layer in the base body that includes a single-phase perovskite ceramic having a composition of Ag(Nb1-xTax)O3, and an electrode layer in the base body containing a precious metal. The electrode layer is sintered with the dielectric layer.
    Type: Grant
    Filed: May 27, 2002
    Date of Patent: December 12, 2006
    Assignee: EPCOS AG
    Inventor: Lutz Kirsten
  • Patent number: 7147835
    Abstract: Disclosed herein is a small particle oxide powder for dielectrics. The oxide powder has a perovskite structure, an average particle diameter [D50(?m)] of 0.3 ?m or less, a particle size distribution of the average particle diameter within 3%, a particle size distribution satisfying a condition D99/D50<2.5, a content of OH? groups of 0.2 wt % and a C/A axial ratio of 1.006 or more. A method of manufacturing the oxide powder comprises the steps of mixing TiO2 particles and a compound solved with at least one element represented by A of the perovskite structure of ABO3; drying and pulverizing the mixture of TiO2 and the compound; calcining the pulverized mixture; adding the oxide containing the elements of the site A to the coated TiO2 particles and wet-mixing, drying and pulverizing; primarily calcining and pulverizing the pulverized powder under vacuum; and secondarily calcining and pulverizing the powder.
    Type: Grant
    Filed: July 12, 2004
    Date of Patent: December 12, 2006
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Dong Hwan Seo, Kang Heon Hur, Sung Hyung Kang, Jin Yung Ryu
  • Patent number: 7105145
    Abstract: Ferroelectric metal oxide crystalline particles are produced by first producing nanoparticles of a ferroelectric metal oxide and dispersing the nanoparticles in a gas phase. Then, the nanoparticles are processed by heat treatment with the nanoparticles being maintained in the gas phase in a dispersed state. The nanoparticles may be produced by using a laser ablation method. The ferroelectric metal oxide may have a perovskite crystal structure.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: September 12, 2006
    Assignee: RIKEN
    Inventors: Kwang-Soo Seol, Kazuo Takeuchi, Takeshi Miyagawa, Yoshimichi Ohki
  • Patent number: 7090785
    Abstract: A perovskite compound of the formula, (Na1/2Bi1/2)1-xMx(Ti1-yM?y)O3±z, where M is one or more of Ca, Sr, Ba, Pb, Y, La, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu; and M? is one or more of Zr, Hf, Sn, Ge, Mg, Zn, Al, Sc, Ga, Nb, Mo, Sb, Ta, W, Cr, Mn, Fe, Co and Ni, and 0.01<x<0.3, and 0.01<y<0.3, and z<0.1 functions as an electromechanically active material. The material may possess electrostrictive or piezoelectric characteristics.
    Type: Grant
    Filed: August 5, 2003
    Date of Patent: August 15, 2006
    Assignee: Massachusetts Institute of Technology
    Inventors: Yet-Ming Chiang, Sossity A. Sheets, Gregory W. Farrey, Nesbitt W. Hagood, IV, Andrey Soukhojak, Haifeng Wang
  • Patent number: 7091154
    Abstract: A perovskite titanium-containing composite oxide particle having a composition represented by general formula (I), where the specific surface area is about 10 to about 200 m2/g, the specific surface area diameter D1 of primary particles defined by formula (II) is about 10 to about 100 nm, and a D2/D1 ratio of the average particle size D2 of secondary particles to D1 is about 1 to about 10: M(TiO3)??(I) wherein M is at least one of Ca, Sr, Ba, Pb, or Mg, D1=6/?S??(II) wherein ? is the density of the particles, and S is the specific surface area of the particles is disclosed. The present invention has a small particle size and excellent dispersion properties, so that the particle is suitable for application to functional materials.
    Type: Grant
    Filed: August 17, 2004
    Date of Patent: August 15, 2006
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Masahiro Ohmori, Akihiko Kotera
  • Patent number: 7087545
    Abstract: A dielectric composition that can be fired at a temperature of below 900° C. The dielectric composition has a dielectric constant of 25–35 and a quality factor (Qxf) of 6,000–20,000 GHz. The composition comprises 3–16 wt % of K2O—Na2O—Li2O—B2O3—SiO2 system glass frit and 84–97 wt % of BaO—TiO2 system dielectric ceramics. The composition can be effectively applied to construct a part of a ceramic multi-layer packaging as a resonator form such as a filter or an antenna, etc.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: August 8, 2006
    Assignee: Korea Institute of Science and Technology
    Inventors: Jae-Hwan Park, Jae-Gwan Park, Dong-Soon Shin, Young-Jin Choi
  • Patent number: 7061748
    Abstract: A multilayer ceramic capacitor containing dielectric layers, in which each of the dielectric layers has a main component containing barium titanate, a first auxiliary component containing at least one kind selected from MgO, CaG, BaO, and SrO, a second auxiliary component containing a silicon oxide as a main component, a third auxiliary component containing at least one kind selected from the group consisting of V2O5, MoO3, and WO3, a fourth auxiliary component containing an oxide of at least one kind of first rare-earth element (R1) selected from Sc, Er, Tm, Yb, and Lu, a fifth auxiliary component containing CaZrO3 or a mixture (CaO+ZrO2) of CaO and ZrO2, and a liquid phase addition of organic metal salts of Zr and Ca.
    Type: Grant
    Filed: June 24, 2005
    Date of Patent: June 13, 2006
    Assignee: TDK Corporation
    Inventors: Kazushige Ito, Akira Sato
  • Patent number: 7057876
    Abstract: A multilayer ceramic capacitor comprises a dielectric layer and an internal electrode layer that are alternately laminated. Barium titanate particles containing an alkaline earth metal component except for Ba in a proportion of not more than 0.2 atomic % (BMTL), and barium titanate particles containing an alkaline earth metal component except for Ba in a proportion of not less than 0.4 atomic % (BMTH) coexist in the dielectric layer in an area ratio of BMTL to BMTH of 0.1 to 9. This provides excellent reliability of capacity temperature characteristic and high-temperature load lifetime, if the dielectric layer is thinned.
    Type: Grant
    Filed: July 28, 2005
    Date of Patent: June 6, 2006
    Assignee: Kyocera Corporation
    Inventors: Yoshihiro Fujioka, Kiyoshi Matsubara
  • Patent number: 7056443
    Abstract: A multilayer piezoelectric element 2 comprising an element body 10 wherein piezoelectric layers 8 and internal electrode layers 4 and 6 are alternately stacked. The piezoelectric layer 8 is composed of a piezoelectric ceramic. The piezoelectric ceramic includes a compound oxide having a perovskite structure. The compound oxide contains at least lead, zirconium and titanium. The method of producing the piezoelectric element includes the steps of producing a piezoelectric layer ceramic green sheet, forming a pre-fired element body by alternately stacking the produced piezoelectric ceramic green sheets and internal electrode layer precursor layers, and forming said element body 10 by performing main firing on the pre-fired element body at a temperature of 1100° C. or lower.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: June 6, 2006
    Assignee: TDK Corporation
    Inventors: Satoshi Sasaki, Masaru Abe
  • Patent number: 7053019
    Abstract: A new dielectric material composition with high dielectric constant and low dielectric loss, which includes a quaternary metallic oxide having a pervoskite structure and represented by a general formula, Ba1-xM1xTi1-yM2yOm. It is suitable for Gbit memory devices, embedded capacitance devices in multilayered structures, and modulable capacitors for high frequency devices.
    Type: Grant
    Filed: June 27, 2003
    Date of Patent: May 30, 2006
    Assignee: Industrial Technology Research Institute
    Inventors: Li-Mei Chen, Chao-Jen Wang, Chien-Hsien Yu, Jen-Po Lin
  • Patent number: 7041269
    Abstract: The present invention provides a barium titanate having a small particle size, containing small amounts of unwanted impurities, and exhibiting excellent electric characteristics, which can be employed for forming a dielectric ceramic thin film required for a small-sized capacitor which enables production of a small-sized electronic apparatus; and a process for producing the barium titanate. When a titanium oxide sol is reacted with a barium compound in an alkaline solution containing a basic compound, the basic compound is removed in the form of gas after completion of reaction, and the resultant reaction mixture is fired, a barium titanate having a large BET specific surface area and a high tetragonality content is produced.
    Type: Grant
    Filed: July 3, 2002
    Date of Patent: May 9, 2006
    Assignee: Showa Denko K.K.
    Inventors: Akihiko Shirakawa, Hitoshi Yokouchi
  • Patent number: 7025824
    Abstract: A chemically bonded ceramic material based on calcium aluminate hydrate with additives of primarily calcium titanate, but also chemically similar compounds. The material is a biocompatible material for implants, particularly for orthopaedic and dental applications. The material possesses the properties required for an orthopaedic biocement. It cures through reaction with water and develops its strength within a short period of time, has good workability prior to curing, is shape stable, has a low heat generation during curing, and is friendly to adjacent tissues.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: April 11, 2006
    Assignee: CerBio Tech AB
    Inventors: Niklas Axén, Leif Hermansson, Tobias Persson, Kajsa Björklund, Lars Kraft
  • Patent number: 7009330
    Abstract: A composition of a plasma display panel (PDP) is disclosed. In order to effectively reduce a jitter, the composition contains a ferroelectric transparent ceramics material.
    Type: Grant
    Filed: December 30, 2003
    Date of Patent: March 7, 2006
    Assignee: LG Electronics Inc.
    Inventor: Yoon Kwan Lee
  • Patent number: 7006345
    Abstract: The invention aims to provide a multilayer ceramic capacitor with high dielectric constant, a high capacitance, and an excellent reliability by eliminating oxygen vacancy in dielectric layers and suppressing oxidation of Ni inner electrodes. The multilayer ceramic capacitor comprises a multilayered dielectric body composed by alternately piling up dielectric layers containing mainly barium titanate and inner electrode layers containing mainly Ni and a first hetero-phase containing Mg—Si—O as constituent elements exists in the capacitor.
    Type: Grant
    Filed: January 7, 2005
    Date of Patent: February 28, 2006
    Assignee: TDK Corporation
    Inventors: Yukie Nakano, Mari Miyauchi, Akira Sato
  • Patent number: 7001585
    Abstract: The present invention provides a method of making barium titanate powder. The method includes adding barium acetate to a solution of oxalic acid and titanium oxychloride to form barium titanyl oxalate and then calcining the barium titanyl oxalate to obtain barium titanate powder.
    Type: Grant
    Filed: April 23, 2003
    Date of Patent: February 21, 2006
    Assignee: Ferro Corporation
    Inventor: Donald Keith Swanson
  • Patent number: 6995968
    Abstract: In order to provide dielectric ceramic composition having low IR defect rate and high relative dielectric constant even when the multilayer ceramic capacitor is made thinner, dielectric ceramic composition including a main component expressed by a composition formula {{Ba(1-x)Cax}O}A{Ti(1-y-z)ZryMgz}BO2 and subcomponents of Mn oxide, Y oxide, V oxide and Si oxide is provided. In the above formula, A, B, x, y and z are as follows: 0.995?A/B?1.020, 0.0001?x?0.07, preferably 0.001?x<0.05, 0.1?y?0.3 and 0.0005?z?0.01, preferably 0.003?z?0.01.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: February 7, 2006
    Assignee: TDK Corporation
    Inventors: Kazushige Ito, Shunichi Yuri, Yukie Nakano, Mari Miyauchi, Takako Hibi, Daisuke Iwanaga, Masakazu Hosono
  • Patent number: 6960546
    Abstract: Dielectric composite materials including an electronically tunable dielectric phase and a calcium and oxygen-containing compound are disclosed. The tunable phase may comprise a material such as barium strontium titanate. The calcium/oxygen compound may comprise CaO or a transition metal-containing compound such as Ca2Nb2O7 or CaTiO3. The material may also include a rare earth oxide dopant such as CeO2. The materials resist dielectric breakdown and possess improved combinations of electronic properties. The materials may be tailored for specific applications.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: November 1, 2005
    Assignee: Paratek Microwave, Inc.
    Inventors: Christopher Caspers, Elijah Underhill, Xubai Zhang
  • Patent number: 6949487
    Abstract: It is an object of the invention to provide a dielectric ceramic composition which enables its firing temperature to be lowered and which has an excellent electrical properties, particularly temperature dependence of resonance frequencies. A dielectric ceramic composition according to the invention comprises an oxide of a barium titanate family having a composition formula represented as BaTixO2x+1 (3.5?x?5.0); a first chemical element group consisting of at least one kind of alkaline-earth metals, silicon, zinc, aluminium, titanium, copper, bismuth and molybdenum; and a second chemical element group consisting of at least one kind of alkali metals and boron. A weight ratio of a total of each chemical element in the first and second chemical element groups to the oxide (the total of each chemical element/the oxide) is between 45/55 and 65/35 inclusive when the ratio is determined by converting said each chemical element to its oxide.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: September 27, 2005
    Assignee: Koninklijke Philips Electronics N.V.
    Inventors: Kazuhiro Ito, Hitoshi Masumura