And Divalent Metal Oxide Other Than Alkaline Earth Oxide Or Magnesium Oxide Patents (Class 501/138)
-
Patent number: 8906818Abstract: Dielectric compositions that include compound of the formula [(M?)1?x(A?)x][(M?)1?y?z,(B?)y(C?)z]O3??(VO)? and protonated dielectric compositions that include a protonated dielectric compound within the formula [(M?)1?x(A?)x](M?)1?y?z(B?)y(C?)z]O3??+h(Vo)?(H•)2h are disclosed. Composite materials that employ one or more of these dielectric compounds together with an electrolyte also are disclosed. Composite material that employs one or more of these dielectric compounds together with an electrochemally active material also are disclosed.Type: GrantFiled: October 7, 2010Date of Patent: December 9, 2014Assignees: Recapping, Inc., Penn State Research FoundationInventors: Clive A. Randall, Leslie E. Cross, Aram Yang, Niall J. Donnelly, Ramakrishnan Rajagopalan, Amanda Lou Baker
-
Patent number: 8853116Abstract: A method of forming composition-modified barium titanate ceramic particulate includes mixing a plurality of precursor materials and a precipitant solution to form an aqueous suspension. The plurality of precursors include barium nitrate, titanium chelate, and a metal or oxometal chelate. The precipitant solution includes tetraalkylammonium hydroxide and tetraalkylammonium oxalate. The method further includes treating the aqueous suspension at a temperature of at least 150° C. and a pressure of at least 200 psi, and separating particulate from the aqueous suspension after treating.Type: GrantFiled: May 10, 2010Date of Patent: October 7, 2014Assignee: EEStor, Inc.Inventors: Richard D. Weir, Carl W. Nelson
-
Patent number: 8841225Abstract: A dielectric ceramic that includes a sintered body of BaTiO3 based ceramic grains, in which the ceramic grains each include a shell part as a surface layer part and a core part inside the shell part. The ceramic grains contain, as accessory constituents, R (R, which is a rare-earth element, is at least one selected from the group consisting of Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Y) and M (M is at least one selected from the group consisting of Mg, Mn, Ni, Co, Fe, Cr, Cu, Al, Mo, W, and V). R and M are present in the shell part of the ceramic grain, and concentrations of R and M contained in the shell part are increased from a grain boundary toward the core part.Type: GrantFiled: October 2, 2012Date of Patent: September 23, 2014Assignee: Murata Manufacturing Co., Ltd.Inventors: Tomomi Koga, Koichi Banno
-
Patent number: 8841226Abstract: A dielectric ceramic composition includes a component represented by composition formula {?(xBaO.yNd2O3.zTiO2)+?(2MgO.SO2)} as a main component and zinc oxide, boron oxide, and a glass having a softening point equal to or lower than a certain temperature as minor components with respect to the main component. In the dielectric ceramic composition, x, y, and z that respectively represent molar ratios of BaO, Nd2O3, and TiO2 are in certain ranges and ? and ? that represent volume ratios of subcomponents (xBaO.yNd2O3.zTiO2 and 2MgO.SiO2) in the main component are in certain ranges. When the minor components are respectively represented by aZnO, bB2O3, and cglass, a, b, and c that represent mass ratios of the respective minor components to the main component are in certain ranges.Type: GrantFiled: November 15, 2012Date of Patent: September 23, 2014Assignee: TDK CorporationInventors: Raitarou Masaoka, Toshio Sakurai, Tomohiro Arashi, Kyung-Ku Choi, Kiyoshi Hatanaka
-
Publication number: 20140240896Abstract: A multilayer ceramic composition showing good characteristics, even when electric intensity on dielectric layers is high and a stacked number of a multilayer ceramic capacitor is increased, and an electronic device thereof. Said composition comprises: a perovskite compound ABO3, and with respect to 100 moles of said compound, 0.6 or more to 1.4 or less moles of Ra2O3 in which Ra is at least one of Dy, Gd and Tb, 0.2 or more to 0.7 or less moles of Rb2O3 in which Rb is at least one of Ho and Y, and 0.2 or more to 0.7 or less moles of Rc2O3 in which Rc is at least one of Yb and Lu, in terms of each oxide, 0.6 or more to 1.6 or less moles of Mg oxide in terms of Mg, and 0.6 or more to less than 1.2 moles of Si included compound in terms of Si.Type: ApplicationFiled: February 24, 2014Publication date: August 28, 2014Applicant: TDK CorporationInventors: Nobuto MORIGASAKI, Takashi SASAKI, Tomohisa FUKUOKA, Yuhta MATSUNAGA, Kazuhiro KOMATSU
-
Publication number: 20140171289Abstract: A voltage nonlinear resistor ceramic composition comprises zinc oxide, with respect to 100 mol of said zinc oxide, 0.30 to 10 mol of Co oxide in terms of Co, 0.10 to 10 mol of R oxide (note that R is at least one selected from a group consisting of Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) in terms of R, 0.10 to 5 mol of Cr oxide in terms of Cr, 0.10 to 5 mol of oxide of at least one selected from Ca and Sr respectively in terms of Ca or Sr, 0.0005 to 5 mol of oxide of at least one selected from Al, Ga and In respectively in terms of Al, Ga or In, and 0.10 to 5 mol of barium titanate in terms of BaTiO3.Type: ApplicationFiled: December 10, 2013Publication date: June 19, 2014Applicant: TDK CorporationInventors: Takahiro ITAMI, Naoyoshi Yoshida, Kaname Ueda
-
Patent number: 8748329Abstract: A dielectric ceramic composition that contains, as its main constituent, (Ba1-x-yCaxSry)(Ti1-z-wZrzHfw)O3 (in the formula, 0?x+y?0.2, 0?z+w?0.1), and contains CuO and Bi2O3, and the dielectric ceramic composition has a feature that the total content of the CuO and Bi2O3 is 10 parts by weight or more with respect to 100 parts by weight of the main constituent, and the molar ratio CuO/(CuO+Bi2O3) is 0.5 or less.Type: GrantFiled: December 14, 2012Date of Patent: June 10, 2014Assignee: Murata Manufacturing Co., Ltd.Inventors: Masanori Nakamura, Masahiro Otsuka, Shoichiro Suzuki, Koichi Banno, Taisuke Kanzaki, Akihiro Shiota
-
Patent number: 8715575Abstract: This invention relates to a method of making lead-free piezoelectric ceramic films. Specifically, the invention is directed to a method for fabricating lead-free piezoelectric free standing films having enhanced piezoelectric properties. The films may be used for a number of applications including incorporation in microelectronic devices such as energy harvesting devices and sensor technologies.Type: GrantFiled: June 26, 2013Date of Patent: May 6, 2014Assignee: Drexel UniversityInventors: Wei-Heng Shih, Wan Y. Shih, Huidong Li
-
Patent number: 8673799Abstract: A dielectric ceramic composition comprises barium titanate as a main component, and as subcomponents, 1.00 to 2.50 moles of an oxide of Mg, 0.01 to 0.20 mole of an oxide of Mn and/or Cr, 0.03 to 0.15 mole of an oxide of at least one element selected from a group consisting of V, Mo and W, 0.20 to 1.50 mole of an oxide of R1 where R1 is at least one selected from a group consisting of Y and Ho, 0.20 to 1.50 mole of an oxide of R2 where R2 is at least one selected from a group consisting of Eu, Gd and Tb and 0.30 to 1.50 mole of an oxide of Si and/or B, in terms of each oxide with respect to 100 moles of the barium titanate.Type: GrantFiled: March 26, 2012Date of Patent: March 18, 2014Assignee: TDK CorporationInventors: Jun Sato, Fumiaki Satoh, Saori Takeda, Masakazu Hosono
-
Patent number: 8673798Abstract: A dielectric ceramic and a laminated ceramic capacitor using the dielectric ceramic are achieved which provide favorable thermal shock resistance without damaging properties or characteristics such as dielectric properties, insulation properties, temperature characteristics, and characteristics in high temperature loading, even when the dielectric layers are reduced in thickness and the number of stacked layers increased. The dielectric ceramic contains, as its main constituent, a barium titanate based compound represented by the general formula ABO3, and a crystalline oxide containing Al, Mg, and Si is present as secondary phase grains in the dielectric ceramic.Type: GrantFiled: August 1, 2011Date of Patent: March 18, 2014Assignee: Murata Manufacturing Co., Ltd.Inventor: Tomoyuki Nakamura
-
Patent number: 8652984Abstract: A dielectric ceramic composition comprising a main component and at least one or more subcomponent elements has a dielectric particle and a grain boundary. The dielectric particle has a main component phase substantially composed of the main component, and a diffusive phase around the main component phase where at least one selected from the subcomponent elements is diffused, a local minimal value of Cs is located at an outside edge side with respect to a position of the local maximum value of Cs, and Cs is increased from a position of the local minimal value of Cs toward the outside edge, when the dielectric particle is cut on an arbitrary cutting plane including the main component phase, and Cs is defined as a concentration of one or more elements selected from the subcomponent elements in an arbitrary position in the dielectric particle.Type: GrantFiled: March 9, 2012Date of Patent: February 18, 2014Assignee: TDK CorporationInventors: Makoto Endo, Osamu Kido, Hirobumi Tanaka, Taisuke Masuko, Yusuke Sato
-
Patent number: 8638544Abstract: There are provided a reduction-resistant dielectric composition and a ceramic electronic component including the same. The reduction-resistant dielectric composition may include a BaTiO3-based matrix powder, 0.1 to 1.0 moles of a transition metal oxide or transition metal carbonates, based on 100 moles of the matrix powder, and 0.1 to 3.0 moles of a sintering aid including silicon oxide (SiO2). The ceramic electronic component including the reduction-resistant dielectric composition may have a high capacitance and superior reliability.Type: GrantFiled: June 23, 2011Date of Patent: January 28, 2014Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Seok Hyun Yoon, Sung Hyung Kang, Ji Young Park, Kang Heon Hur, Sang Hoon Kwon
-
Publication number: 20140002955Abstract: A dielectric ceramic composition is represented by BaTiO3+aRe2O3+bMnO+cV2O5+dMoO3+eCuO+fB2O3+gLi2O+xSrO+yCaO (wherein Re represents one or more elements selected from among Eu, Gd, Dy, Ho, Er, Yb, and Y; and a-h each represents the mole number of each component with respect to 100 mol of the main component that is composed of BaTiO3). When the molar ratio of (Ba+Sr+Ca)/Ti contained in the dielectric ceramic composition is represented by m, the 0.10?a?0.50, 0.20?b?0.80, 0?c?0.12, 0?d?0.07, 0.04?c+d?0.12, 0?e?1.00, 0.50?f?2.00, 0.6?(100(m?1)+2g)/2f?1.3, and 0.5?100(m?1)/2g?5.1 are satisfied.Type: ApplicationFiled: September 26, 2011Publication date: January 2, 2014Applicant: TAIYO YUDEN CO., LTD.Inventor: Shinsuke Takeoka
-
Patent number: 8609564Abstract: A method for manufacturing a laminated ceramic capacitor by firing a laminated body which includes dielectric ceramic layers containing a dielectric ceramic raw material powder and internal electrodes. The firing is carried out in accordance with a temperature profile in which the average rate of temperature rise is 40° C./second or more from room temperature to a maximum temperature. The dielectric ceramic raw material powder contains a BaTiO3 system as its main constituent, and contains R (R is Sc, etc.), M (M is Mn, etc.), and Mg as accessory constituents, in which, when the total amount of the accessory constituents contained is denoted by D parts by mol with respect to 100 parts by mol of the main constituent, an the specific surface area of the main constituent is denoted by E m2/g, then D/E is 0.2 to 0.8.Type: GrantFiled: February 23, 2012Date of Patent: December 17, 2013Assignee: Murata Manufacturing Co., Ltd.Inventors: Makoto Matsuda, Tomoyuki Nakamura
-
Patent number: 8609017Abstract: Electronically tunable dielectric materials having favorable properties are disclosed. The electronically tunable materials include an electronically tunable dielectric phase such as barium strontium titanate in combination with at least two additional metal oxide phases. The additional metal oxide phases may include, for example, oxides of Mg, Si, Ca, Zr, Ti and Al. The electronically tunable materials may be provided in bulk, thin film and thick film forms for use in devices such as phased array antennas, tunable filters and the like. The materials are useful in many applications, including the area of radio frequency engineering and design.Type: GrantFiled: February 17, 2007Date of Patent: December 17, 2013Assignee: BlackBerry LimitedInventors: Louise C. Sengupta, Xubai Zhang, Luna H. Chiu
-
Patent number: 8592334Abstract: A dielectric ceramic composition comprises, a main component including barium titanate, a first subcomponent including MgO, a second subcomponent including sintering aids of SiO2 compound, a third subcomponent including at least one of V2O5, Nb2O5 and WO3, a fourth A subcomponent including RA oxide (note that, RA is at least one selected from Tb, Gd and Dy), a fourth B subcomponent including RB oxide (note that, RB is at least one selected from Ho, Y and Yb), and a fifth subcomponent including MnO or Cr2O3.Type: GrantFiled: March 30, 2009Date of Patent: November 26, 2013Assignee: TDK CorporationInventors: Kosuke Takano, Mari Miyauchi, Nobuto Morigasaki, Hideaki Seki, Makoto Maeda, Takahiro Yamada
-
Patent number: 8592335Abstract: A dielectric ceramic composition contains a barium titanate based composite oxide as its main constituent, and contains a first accessory constituent including at least Al and a second accessory constituent including one or more elements selected from among Fe, Co, Ni, Cu, and Zn, wherein the content of the Al is 0.02 to 6 parts by mol with respect to 100 parts by mol of the main constituent, and the content ratio of the second accessory constituent to the Al is 0.01 to 0.4 in terms of mols. Dielectric layers are formed from a sintered body of the dielectric ceramic composition. The addition of various types of accessory elements such as rare-earth elements is possible, if necessary. This invention achieves a dielectric ceramic composition which is capable of ensuring favorable DC bias characteristics while ensuring high reliability, and a laminated ceramic capacitor using the dielectric ceramic composition.Type: GrantFiled: February 21, 2012Date of Patent: November 26, 2013Assignee: Murata Manufacturing Co., Ltd.Inventors: Takafumi Okamoto, Noriyuki Inoue, Hitoshi Nishimura
-
Patent number: 8586495Abstract: A dielectric material is provided. The material includes ?[Ca1-x-yBaxSry(Ca1-zCuz)Cu2-pLa2p/3Ti4-qMqO12-?]+(1??)[BarSr1-rTiO3], wherein M is aluminum, chromium, zirconium, or combinations thereof; x can vary between the value of zero and 0.1 such that 0?x?0; y, z, and r can vary between the value of zero and 1 such that 0?y?1, 0?z?1, and 0?r?1; p and q can vary between the value of zero and 0.1 such that 0?p?0.1 and 0?q?0.1; ? can vary between the value of zero and 0.05 such that 0???0.05; and ? can vary between the value of 0.5 and 1 such that 0.5???1, with a proviso that when x=y=0 and z=?=1, p and q are greater than zero; and when x=y=z=0, p and q are not simultaneously zero. A dielectric component including the dielectric material and a system including the dielectric component are provided.Type: GrantFiled: March 30, 2011Date of Patent: November 19, 2013Assignee: General Electric CompanyInventors: Kalaga Murali Krishna, Lohit Matani
-
Patent number: 8557724Abstract: A semiconductor porcelain composition is prepared by separately preparing a composition of (BaR)TiO3 (R is La, Dy, Eu, Gd or Y) and a composition of (BiNa)TiO3, and calcining the composition of (BaR)TiO3 at a temperature of 900° C. through 1300° C. and calcining the composition of (BiNa)TiO3 at a temperature of 700° C. through 950° C., and then mixing, forming and sintering the calcined powders. Similarly, a semiconductor porcelain composition is prepared by separately preparing a composition of (BaM)TiO3 (M is Nb, Ta or Sb) and a composition of (BiNa)TiO3, and calcining the composition of (BaM)TiO3 at a temperature of 900° C. through 1300° C. and calcining the composition of (BiNa)TiO3 at a temperature of 700° C. through 950° C., and then mixing, forming and sintering the calcined powders.Type: GrantFiled: November 27, 2009Date of Patent: October 15, 2013Assignee: Hitachi Metals, Ltd.Inventors: Takeshi Shimada, Koichi Terao, Kazuya Toji
-
Patent number: 8526164Abstract: A laminated ceramic capacitor which provides favorable properties and characteristics such as dielectric characteristics, insulation properties, temperature characteristics, and high temperature load characteristics and provides favorable thermal shock resistance, even when dielectric ceramic layers are reduced in layer thickness to increase the number of layers has dielectric ceramic layers containing, as their main constituent, a barium titanate based compound represented by the general formula ABO3 and internal electrodes containing Ni as their main constituent, which are stacked alternately. A crystalline oxide containing at least Mg and Li is present in at least either one of the internal electrodes and the dielectric ceramic layers. The crystalline oxide is preferably present mostly in contact with Ni in the internal electrodes.Type: GrantFiled: March 3, 2011Date of Patent: September 3, 2013Assignee: Murata Manufacturing Co., Ltd.Inventors: Tomoyuki Nakamura, Tomonori Muraki, Makoto Matsuda, Akihiro Shiota
-
Patent number: 8518844Abstract: Provided are a dielectric ceramic composition suitable for use in a monolithic ceramic capacitor that is employed in high-temperature environments such cars, and a monolithic ceramic capacitor constituted by using the dielectric ceramic composition. The dielectric ceramic composition has a composition formula of 100(Ba1-xCax)TiO3+aR2O3+bV2O5+cZrO2+dMnO (where R is at least one metal element selected from among Y, La, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and Yb, and a, b, c and d denote values in terms of moles), and conditions of 0.03?x?0.20, 0.05?a?3.50, 0.22?b?2.50, 0.05?c?3.0, and 0.01?d?0.30 are substantially satisfied. The dielectric ceramic layers in the monolithic ceramic capacitor are made of a sintered compact of the dielectric ceramic composition.Type: GrantFiled: March 24, 2011Date of Patent: August 27, 2013Assignee: Murata Manufacturing Co., Ltd.Inventors: Jun Ikeda, Shoichiro Suzuki
-
Patent number: 8496893Abstract: A furnace assembly includes first and second sections. The first section includes first and seconds ends, a first joint disposed at the first end, a conical portion at a second end, a first filter disposed between the first and second ends, and a lumen extending through the first section in fluid communication with the first filter. The second section includes first and second ends, a second joint disposed at the first end, an opening disposed at the second end and to receive the conical portion of the first section, a second filter disposed between the first and second ends, and a lumen extending through the second section in fluid communication with the second filter. When engaged, the first and second sections form a chamber between the first and second filters. The chamber is in fluid communication with the respective first ends of the first and second sections.Type: GrantFiled: June 25, 2010Date of Patent: July 30, 2013Assignee: EEStor, Inc.Inventor: Richard D. Weir
-
Patent number: 8496870Abstract: This invention relates to a method of making lead-free piezoelectric ceramic films. Specifically, the invention is directed to a method for fabricating lead-free piezoelectric free standing films having enhanced piezoelectric properties. The films may be used for a number of applications including incorporation in microelectronic devices such as energy harvesting devices and sensor technologies.Type: GrantFiled: June 12, 2012Date of Patent: July 30, 2013Assignee: Drexel UniversityInventors: Wei-Heng Shih, Wan Y. Shih, Huidong Li
-
Patent number: 8492302Abstract: A dielectric ceramic composition includes a compound having perovskite type crystal structure shown by a general formula ABO3, where A is at least one selected from Ba, Ca and Sr, and B is at least one selected from Ti and Zr. The dielectric ceramic composition includes, as subcomponents, an oxide of RA (Dy, Gd and Tb); an oxide of RB (Ho and Y); an oxide of RC (Yb and Lu); Mg oxide and an oxide including Si in terms of RA2O3, RB2O3, RC2O3, Mg and Si, respectively. Also, when contents of the oxide of RA, RB and RC with respect to 100 moles of the compound are defined as “?”, “?” and “?”, respectively, they satisfy relations of 1.2?(?/?)?5.0 and 0.5?(?/?)?10.0.Type: GrantFiled: September 6, 2011Date of Patent: July 23, 2013Assignee: TDK CorporationInventors: Kosuke Takano, Tomohisa Fukuoka, Makoto Maeda, Yuhta Matsunaga, Masahide Ishizuya, Tamotsu Ishiyama, Takahiro Yamada
-
Patent number: 8492301Abstract: A dielectric ceramic composition includes a compound having perovskite type crystal structure shown by a general formula ABO3, where A is at least one selected from Ba, Ca and Sr, and B is at least one selected from Ti and Zr, as a main component. The dielectric ceramic composition includes, as subcomponents, with respect to 100 moles of the compound, 1.0 to 2.5 moles of an oxide of RA (Dy, Gd and Tb); 0.2 to 1.0 mole of an oxide of RB (Ho and Y); 0.1 to 1.0 mole of an oxide of RC (Yb and Lu); 0.8 to 2.0 moles of Mg oxide and 1.2 to 3.0 moles of an oxide including Si in terms of RA2O3, RB2O3, RC2O3, Mg and Si, respectively. Also, when contents of the oxide of RA, RB and RC with respect to 100 moles of the compound are defined as “?”, “?” and “?”, respectively, the “?”, “?” and “?” satisfy relations of 2.5?(?/?)?5.0 and 1.0?(?/?)?10.0. According to the present invention, a dielectric ceramic composition having good properties can be provided.Type: GrantFiled: March 1, 2011Date of Patent: July 23, 2013Assignee: TDK CorporationInventors: Kosuke Takano, Tomohisa Fukuoka, Makoto Maeda, Yuhta Matsunaga, Masahide Ishizuya, Tamotsu Ishiyama, Takahiro Yamada
-
Publication number: 20130162100Abstract: There is provided a dielectric composition, including: a basic powder including BamTiO3(0.995?m?1.010); a first subcomponent including 0.1 to 0.6 mole of zirconium (Zr) oxide or carbide, based on 100 moles of the basic powder; a second subcomponent including 0.8 to 6.0 moles of oxide or carbide including at least one of magnesium (Mg), strontium (Sr), and barium (Ba); a third subcomponent including 0.2 to 1.8 moles of oxide including at least one rare earth element; a fourth subcomponent including 0.05 to 0.30 mole of oxide including at least one transition metal; a fifth subcomponent including 0.05 to 0.35 mole of oxide including at least one of vanadium (V), niobium (Nb), and tantalum (Ta); and a sixth subcomponent including 0.5 to 4.0 moles of oxide including at least one of silicon (Si) and aluminum (Al).Type: ApplicationFiled: September 14, 2012Publication date: June 27, 2013Inventors: Sung Hyung KANG, Du Won Choi, Min Sung Song, Chan Hee Nam
-
Patent number: 8466078Abstract: Disclosed are a glass composition and a dielectric composition enabling low temperature sintering, and a high capacitance multilayer ceramic capacitor using the same. In the glass composition used for sintering, the glass composition may be formed of a formula, aR2O-bCaO-cZnO-dBaO-eB2O3-fAl2O3-gSiO2, and the formula may satisfy a+b+c+d+e+f+g=100, 0?a?7, 1?b?3, 1?c?15, 10?d?20, 3?e?10, 0?f?3, and 55?g?72. Through this, when manufacturing the high capacity multilayer ceramic capacitor, the dielectric substance may enable the lower temperature sintering, thereby enhancing a capacitance and a reliability of the high capacitance multilayer ceramic capacitor.Type: GrantFiled: August 30, 2011Date of Patent: June 18, 2013Assignee: Samhwa Capacitor Co., Ltd.Inventors: Young Joo Oh, Jung Rag Yoon
-
Patent number: 8462539Abstract: A resistive memory element that includes an element body and at least a pair of electrodes opposed to each other with at least a portion of the element body interposed therebetween. The element body is made of an oxide semiconductor which has a composition represented by the general formula: (Ba1-xSrx)Ti1-yMyO3 (wherein M is at least one from among Mn, Fe, and Co; 0?x?1.0; and 0.005?y?0.05). The first electrode of the pair of electrodes is made of a material which can form a Schottky barrier which can develop a rectifying property and resistance change characteristics in an interface region between the first electrode and the element body. The second electrode is made of a material which provides a more ohmic junction to the element body as compared with the first electrode.Type: GrantFiled: August 18, 2011Date of Patent: June 11, 2013Assignee: Murata Manufacturing Co., Ltd.Inventor: Sakyo Hirose
-
Patent number: 8445396Abstract: A laminated ceramic capacitor suitable for intermediate to high voltage applications uses a dielectric ceramic represented by {100(BaTiO3+aBaZrO3)+bR+cMg+dMn+eSi} where R is a rare earth element; 0?a?0.2, 8.0?b?12.0, 1.0?c?10.0, 0.1?d?3.0, and 1.0?e?10.0, and includes first grains of 0.7 ?m or more in grain size and an average first grain size (Aave) and area ratio of the ceramic (SA), and second grains of 0.6 ?m or less in grain size and an average second grain size (Bave) and area ratio (SB), 0.8 ?m?Aave?2.0 ?m, 0.1 ?m?Bave?0.5 ?m, Aave/Bave?3.0, 0.3?SA?0.9, 0.1?SB?0.7, and 0.8?SA+SB?1.0.Type: GrantFiled: September 6, 2011Date of Patent: May 21, 2013Assignee: Murata Manufacturing Co., Ltd.Inventor: Koichi Banno
-
Patent number: 8445397Abstract: A laminated ceramic capacitor which exhibits excellent lifetime characteristics in a high temperature loading test uses a dielectric ceramic constituting the dielectric layers which contains (Ba1-xCax)TiO3 as its main constituent, and contains a parts by mol of Al, b parts by mol of V, c parts by mol of Mg, and d parts by mol of Re with respect to 100 parts by mol of the (Ba1-xCax)TiO3. The Re is at least one metal element selected from among Y, La, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb, and the x, a, b, c, and d respectively satisfy the conditions of 0.050?x?0.150, a?0.15, 0.05?b?0.50, c?0.50, and d?1.00.Type: GrantFiled: September 7, 2011Date of Patent: May 21, 2013Assignee: Murata Manufacturing Co., Ltd.Inventor: Shinichi Yamaguchi
-
Publication number: 20130119827Abstract: There is provided a dielectric composition, including; a base powder including BamTiO3 (0.995?m?1.010); a first sub-component including 0.05 to 4.00 moles of an oxide or carbonate containing at least one rare-earth element based on 100 moles of the base powder; a second sub-component including 0.05 to 0.70 moles of an oxide or carbonate containing at least one transition metal; a third sub-component including 0.20 to 2.00 moles of a Si oxide; a fourth sub-component including 0.02 to 1.00 mole of an Al oxide; and a fifth sub-component including 20 to 140% of an oxide containing at least one of Ba and Ca, based on the third sub-component.Type: ApplicationFiled: October 25, 2012Publication date: May 16, 2013Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventor: Samsung Electro-mechanics Co., Ltd.
-
Publication number: 20130107418Abstract: A dielectric ceramic composition that contains, as its main constituent, (Ba1-x-yCaxSry)(Ti1-z-wZrzHfw)O3 (in the formula, 0?x+y?0.2, 0?z+w?0.1), and contains CuO and Bi2O3, and the dielectric ceramic composition has a feature that the total content of the CuO and Bi2O3 is 10 parts by weight or more with respect to 100 parts by weight of the main constituent, and the molar ratio CuO/(CuO+Bi2O3) is 0.5 or less.Type: ApplicationFiled: December 14, 2012Publication date: May 2, 2013Applicant: Murata Manufacturing Co., Ltd.Inventor: Murata Manufacturing Co., Ltd.
-
Patent number: 8420559Abstract: Disclosed is a multilayer ceramic capacitor which is formed by alternately laminating (i) dielectric layers composed of a dielectric ceramic and (ii) internal electrode layers. The dielectric ceramic is composed of crystal grains mainly composed of barium titanate, while containing predetermined amounts of magnesium, vanadium, manganese and terbium, and at least one rare earth element selected from yttrium, dysprosium, holmium and erbium. In an x-ray diffraction chart of the dielectric ceramic, the diffraction intensity of the (200) plane indicating cubic barium titanate is higher than the diffraction intensity of the (002) plane indicating tetragonal barium titanate. The dielectric ceramic has a Curie temperature of 110-120° C.Type: GrantFiled: March 24, 2009Date of Patent: April 16, 2013Assignee: Kyocera CorporationInventors: Masahiro Nishigaki, Hideyuki Osuzu, Jun Ueno, Hiroaki Mino
-
Patent number: 8420560Abstract: A dielectric ceramic includes a main component and a minor component. The main component includes a BaTi4O9 crystal phase and a Ba2Ti9O20 crystal phase, is represented by BaO.xTiO2, has a molar ratio x of TiO2 to BaO of 4.6 to 8.0, and in X-ray diffraction, and has an X-ray diffraction peak intensity ratio I29/I14 of a maximum diffraction peak intensity (I14) of the BaTi4O9 crystal phase to a maximum diffraction peak intensity (W of the Ba2Ti9O20 crystal phase of 1 or more. The minor component includes a boron oxide and a copper oxide, in which the boron oxide content is in the range of 0.5 to 5.0 parts by mass with respect to 100 parts by mass of the main component, and the copper oxide content is in the range of 0.1 to 3.0 parts by mass with respect to 100 parts by mass of the main component.Type: GrantFiled: March 18, 2011Date of Patent: April 16, 2013Assignee: TDK CorporationInventors: Takahiro Nakano, Yasuharu Miyauchi, Tomoko Nakamura
-
Patent number: 8404607Abstract: A laminated ceramic capacitor which provides favorable life characteristics, even when a high electric field strength is applied while dielectric ceramic layers are reduced in layer thickness to less than 1 ?m, contains a dielectric ceramic a compound represented by: (Ba1-x/100Cax/100)mTiO3 (0?x?20) as its main constituent, and as its accessory constituent, aMg-bSi-cMn-dR (R is at least one of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y, and a, b, c, and d (part by mol) respectively satisfy the conditions of 0.1<a?20.0, 0.5<b?20.0, 0.1<c?10.0, and 1.0<d?30.0 with respect to 100 parts by mol of the main constituent). The average grain size is 20 nm or more and less than 100 nm for crystal grains in a sintered body obtained by firing the dielectric ceramic.Type: GrantFiled: March 2, 2011Date of Patent: March 26, 2013Assignee: Murata Manufacturing Co., Ltd.Inventors: Megumi Fukuda, Takayuki Yao, Makoto Matsuda, Taisuke Kanzaki
-
Patent number: 8383536Abstract: A dielectric ceramic which is capable of achieving a laminated ceramic capacitor with high reliability, in particular, favorable lifetime characteristics in a load test, even when a dielectric ceramic layer is reduced in thickness contains one of (Ba,R)(Ti,Mn)O3 and (Ba,Ca,R)(Ti,Mn)O3 (R being La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and/or Y) as a main component, and M (M being Fe, Co, V, W, Cr, Mo, Cu, Al, and/or Mg) and Si as accessory components. The area of a region in which M is present is 10% or less on average of a cross section of each main component grain.Type: GrantFiled: June 22, 2010Date of Patent: February 26, 2013Assignee: Murata Manufacturing Co., Ltd.Inventors: Megumi Fukuda, Takayuki Yao
-
Patent number: 8383535Abstract: A laminated ceramic capacitor includes a capacitor body of alternately stacked dielectric layers and internal electrode layers, and an external electrode provided on the end face of the capacitor body on which the internal electrode layer is exposed. The dielectric layer has a crystal phase composed mainly of barium titanate and having a cubic system crystal structure. The grain diameter of crystal grains constituting the crystal phase is 0.05 to 0.2 pm. The dielectric layer is formed of a ceramic containing, per mole of barium, 0.0014 to 0.03 moles yttrium, 0.0002 to 0.045 moles manganese, 0.0075 to 0.04 moles magnesium and 0.025 to 0.18 moles ytterbium. The dielectric bonding material is formed of a ceramic containing the same components as those of the main crystal phase of the dielectric ceramic constituting the dielectric layer.Type: GrantFiled: April 24, 2009Date of Patent: February 26, 2013Assignee: Kyocera CorporationInventor: Katsuyoshi Yamaguchi
-
Patent number: 8377606Abstract: The present invention provides a fuel cell in which electricity is generated and a paraffin is converted to an olefin. Between the anode and cathode compartment of the fuel cell is a ceramic membrane of the formula BaCe0.85-eAeLfY0.05-0.25O(3-?) wherein A is selected from the group consisting of Hf and Zr and mixtures thereof, e is from 0.1 to 0.5, L is a lanthanide and f is from 0 to 0.25 and ? is the oxygen deficiency in the ceramic.Type: GrantFiled: December 15, 2010Date of Patent: February 19, 2013Assignee: The Governors of the University of AlbertaInventors: Jingli Luo, Karl Chuang, Alan Rodney Sanger
-
Patent number: 8343883Abstract: A dielectric porcelain composition contains a major component represented by a composition formula (BaO.xTiO2). The dielectric porcelain composition contains also contains a first minor component represented by a composition formula raB2O3 and a second minor component represented by a composition formula rbCuO. In the formulae, x is a molar ratio of TiO2 to BaO and is within a range of 4.6 to 8, ra is a weight ratio of B2O3 with respect to the major component and is within a range of 0.5 to 5% by mass, and rb is a weight ratio of CuO with respect to the major component and is within a range of 0.1 to 3% by mass.Type: GrantFiled: March 23, 2010Date of Patent: January 1, 2013Assignee: TDK CorporationInventors: Yasuharu Miyauchi, Tomoko Nakamura, Toshiyuki Suzuki
-
Patent number: 8335073Abstract: A dielectric ceramic composition includes, as a main component, a compound having perovskite type crystal structure shown by a general formula ABO3, as subcomponents, in terms of respective element with respect to 100 moles of the compound, and 0.6 to 2.0 moles of an oxide of Mg, 0.010 to 0.6 mole of oxide of Mn and/or Cr, 0.010 to 0.2 mole of an oxide of at least one selected from V, Mo and W, 0.10 to 1.0 mole of an oxide of R1 (R1 is at least one selected from Y, Yb, Er and Ho), 0.10 to 1.0 mole of an oxide of R2 (R2 is at least one selected from Dy, Gd and Tb) and 0.2 to 1.5 moles of a component consisting of an oxide of Ba and/or oxide of Ca and an oxide of Si. According to the present invention, even when a dielectric layer is made thinner, a dielectric ceramic composition having good characteristics can be provided.Type: GrantFiled: March 9, 2011Date of Patent: December 18, 2012Assignee: TDK CorporationInventors: Kazuhiro Komatsu, Yoichiro Hoshi, Shuhei Yoshikawa, Yuichiro Sueda
-
Patent number: 8318624Abstract: A dielectric ceramic containing a BaTiO3 based material as its main constituent, and, as accessory constituents, a rare-earth element R(R is at least one selected from Nd, Eu, Gd, Tb, Dy, Ho, Er, Yb, and Y), M (M is at least one selected from Mg, Mn, Ni, Co, Cu, Al, Mo, W, and V), SiO2, and CaO. Among crystal grains included in this dielectric ceramic, the ratio of the number of crystal grains 11 in which Si is present in solid solution is 5% or more.Type: GrantFiled: September 14, 2010Date of Patent: November 27, 2012Assignee: Murata Manufacturing Co., Ltd.Inventors: Kazuo Muto, Kohei Shimada
-
Patent number: 8318623Abstract: Ceramic dielectric materials that can be utilized as electronic components, such as dielectric resonators are disclosed. The material can have a formula Ba12M?(28+a/3)Ti(54?a-b)M?aGebO162, wherein M? is at least one rare earth element selected from the group consisting of lanthanum, neodymium, samarium, gadolinium, and yttrium, M? is at least one element selected from the group consisting of aluminum, gallium, chromium, indium, scandium, and ytterbium, 0?a?6, and 0?b?3. The ceramic dielectric material can also have a formula Ba12M?(28+2x/3)Ti(54?x?y)M??xGeyO162, wherein M? is at least one rare earth element selected from the group consisting of lanthanum, neodymium, samarium, gadolinium, and yttrium, M?? is at least one metal selected from the group consisting of magnesium, zinc, nickel, and cobalt, 0?x?3, and 0?y?3. One or more aspects of the present invention pertain to methods of fabricating a dielectric component. Methods of synthesizing the disclosed ceramic dielectric materials are also disclosed.Type: GrantFiled: December 16, 2009Date of Patent: November 27, 2012Assignee: Skyworks Solutions, Inc.Inventor: Michael D. Hill
-
Patent number: 8315037Abstract: A dielectric ceramic which improves the lifetime characteristics and dielectric breakdown voltage of a laminated ceramic capacitor includes core-shell crystalline grains which have a core-shell structure and homogeneous crystalline grains which have a homogeneous structure. In this dielectric ceramic, the core-shell crystalline grains and the homogeneous crystalline grains are present at an area ratio in the range of 91:9 to 99:1. Preferably, when the mean grain size for the core-shell crystalline grains is represented by R1 and the mean grain size for the homogeneous crystalline grains is represented by R2, the ratio of R2/R1 is 0.8 or more and 3 or less.Type: GrantFiled: January 20, 2010Date of Patent: November 20, 2012Assignee: Murata Manufacturing Co., Ltd.Inventors: Masanori Nakamura, Shinichi Yamaguchi, Toshikazu Takeda
-
Patent number: 8305732Abstract: Disclosed is a dielectric ceramic having crystal grains mainly composed of barium titanate and an intergranular phase formed among the crystal grains. The dielectric ceramic contains certain amounts of manganese and at least one rare earth element (RE) selected from magnesium, gadolinium, terbium, dysprosium, holmium and erbium, in terms of oxides, per 1 mole of barium constituting the barium titanate. The dielectric ceramic also contains a certain amount of yttrium in terms of oxides, per 100 parts by mass of the barium titanate. The crystal grains have an average grain size of 0.05-0.2 ?m. By using the dielectric ceramic as a dielectric layer, there can be obtained a capacitor having high capacity and stable capacitance temperature characteristics.Type: GrantFiled: March 27, 2009Date of Patent: November 6, 2012Assignee: Kyocera CorporationInventor: Katsuyoshi Yamaguchi
-
Lead and cadmium free, low temperature fired X7R dielectric ceramic composition and method of making
Patent number: 8305731Abstract: Multilayer ceramic chip capacitors (MLCC's) which satisfy X7R TCC requirements and which are compatible with silver-palladium internal electrodes. The MLCC's exhibit desirable dielectric properties—high capacitance, low dissipation factor, high insulation resistance, stable TCC—and excellent performance on highly accelerated life testing, and good resistance to dielectric breakdown. The dielectric layers include a lead-free and cadmium-free barium titanate base material doped with other metal oxides such oxides of zinc, boron, bismuth, barium, titanium, praseodymium, cerium, tungsten, neodymium, tungsten, tin, niobium, copper, and/or manganese in various combinations. The dielectric ceramic materials herein can be fired at less than 1150° C. with an inner electrode having 70 wt % or more Ag and 30 wt % or less Pd to form an MLCC.Type: GrantFiled: October 27, 2008Date of Patent: November 6, 2012Assignee: Ferro CorporationInventors: Walter J. Symes, Jr., Mike S. H. Chu -
Publication number: 20120270720Abstract: A dielectric ceramic-forming composition comprising a perovskite (ABO3)-type ceramic raw material powder, and a glass powder containing, on an oxide basis, 35% by weight to 90% by weight of Bi2O3, 2.5% by weight to 20% by weight of ZnO, 1% by weight to 20% by weight of B2O3, 0.5% by weight to 15% by weight of SiO2, 0.5% by weight to 15% by weight of an alkali metal oxide, and 0.1% by weight to 35% by weight of an alkaline earth metal oxide, wherein 1% by weight to 15% by weight of the glass powder is blended with respect to the dielectric ceramic-forming composition, which can be fired at temperature lower than conventional temperature and can provide a dielectric ceramic material having high relative permittivity.Type: ApplicationFiled: October 15, 2010Publication date: October 25, 2012Applicant: Nippon Chemical Industrial Co., LtdInventor: Shinji Tanabe
-
Patent number: 8288301Abstract: A dielectric ceramic containing ABO3 in which A is Ba, possibly with at least one of Ca and Sr, and B is Ti, possibly with at least one of Zr and Hf as its main component, and Si as a accessory component. The dielectric ceramic includes main phase grains containing the ABO3 main component and secondary phase grains having a composition different from that of the main phase grains. The ratio of the Si content in the secondary phase grains to the total content of Si in the dielectric ceramic is 40% or more so that more Si is distributed in the secondary phase grains. It is preferable that the Si content in secondary phase grains be 30 mol % or more.Type: GrantFiled: January 21, 2010Date of Patent: October 16, 2012Assignee: Murata Manufacturing Co., Ltd.Inventor: Masayuki Ishihara
-
Patent number: 8283272Abstract: A purpose of the present invention is to provide a dielectric ceramic composition which is available to obtain a multilayer ceramic capacitor having a high specific permittivity and a small temperature change of capacitance. A dielectric ceramic composition comprises a dielectric main component composed of 86.32 to 97.64 mol % of BaTiO3, 0.01 to 10.00 mol % of Y2O3 and 0.01 to 10.00 mol % of MgO and 0.001 to 0.200 mol % of V2O5, 0.01 to 1.0 mol % of more than one kind of a first additive selected from a group composed of MnO, Cr2O3, Co2O3, 0.5 to 10.0 mol % of a second additive which is {Ba?, Ca (1??)}SiO3 (note, 0???1), and Sr: 10 to 500 ppm, S: 10 to 50 ppm, Al: 10 to 50 ppm, Fe: 10 to 50 ppm, Zr: 100 to 800 ppm, Y: 10 to 100 ppm, Hf: 10 to 100 ppm to 100 parts by weight of BaTiO3.Type: GrantFiled: October 27, 2010Date of Patent: October 9, 2012Assignee: TDK CorporationInventors: Shinsuke Hashimoto, Masato Konno, Momoyo Nitta, Tomohiro Yamashita, Hiroshi Sasaki
-
Patent number: 8264817Abstract: A laminated ceramic capacitor which has a dielectric ceramic with a high dielectric constant and has excellent reliability against changes in temperature and mechanical shocks, even when dielectric ceramic layers are reduced in thickness employs a dielectric ceramic containing (Ba1-xCax)yTiO3 (where 0.045?x?0.15 and 0.98?y?1.05) as its main constituent and containing Re2O3 (where Re is at least one of Gd, Dy, Ho, Yb, and Y), MgO, MnO, V2O5, and SiO2 as accessory constituents, which is represented by the general formula: 100(Ba1-xCax)yTiO3+aRe2O3+bMgO+cMnO+dV2O5+eSiO2, and satisfies each of the following conditions: 0.65?a?1.5; 0.98?y?1.05; 0.15?b?2.0; 0.4?c?1.5; 0.02?d?0.25; and 0.2?e?3.0.Type: GrantFiled: November 3, 2010Date of Patent: September 11, 2012Assignee: Murata Manufacturing Co., Ltd.Inventors: Masanori Nakamura, Toshihiro Okamatsu, Akira Kato, Shinya Isota
-
Patent number: 8248752Abstract: A multilayer ceramic capacitor is provided. In the multilayer ceramic capacitor, a plurality of first and second inner electrodes are formed inside a ceramic sintered body. Ends of the first and second inner electrodes are alternately exposed to both ends of the ceramic sintered body. First and second outer electrodes are formed on both ends of the ceramic sintered body and connected to the first and second inner electrodes. The first and second outer electrodes include a first region having a porosity in the range of 1% to 10%, and a second region having a porosity less than that of the first region.Type: GrantFiled: September 15, 2010Date of Patent: August 21, 2012Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Kang Heon Hur, Sang Hoon Kwon, Doo Young Kim, Eun Sang Na, Byung Gyun Kim, Seok Joon Hwang, Kyoung Jin Jun, Hye Young Choi