And Trivalent Metal Oxide Patents (Class 501/139)
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Patent number: 7521390Abstract: Multilayer ceramic chip capacitors which satisfy X7R and BX requirements and which are compatible with silver-palladium internal electrodes are made in accordance with the invention. The capacitors exhibit desirable dielectric properties (high capacitance, low dissipation factor, high insulation resistance), excellent performance on highly accelerated life testing, and very good resistance to dielectric breakdown. The dielectric layers comprise a lead-free and cadmium-free barium titanate base material doped with other metal oxides such oxides of zinc, boron, bismuth, cerium, tungsten, copper, manganese, neodymium, niobium, silver, barium, silicon and nickel in various combinations. The dielectric ceramic materials herein can be sintered together (fired) at less than 1000° C. with an inner electrode having more than 80 wt % Ag and less than 20 wt % Pd to form a multilayer ceramic capacitor (MLCC).Type: GrantFiled: March 5, 2007Date of Patent: April 21, 2009Assignee: Ferro CorporationInventors: Walter J. Symes, Jr., Mike S. H. Chu
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Patent number: 7517823Abstract: A dielectric porcelain composition here contains as main components BaO, Nd2O3, TiO2, MgO and SiO2 at the given ratios and as subordinate components ZnO, B2O3 and CuO at given ratios, so that it can have a low-temperature sintering capability stable and reliable enough to permit a conductor formed of Ag, an alloy containing Ag as a main component or the like to be used as an internal conductor. It is also possible to obtain a dielectric porcelain composition that has limited resonance frequency changes with temperature changes and a specific dielectric constant lower than that of a BaO-rare earth oxide-TiO2 base dielectric porcelain composition, and so is suitable for multilayer type device formation.Type: GrantFiled: September 29, 2005Date of Patent: April 14, 2009Assignee: TDK CorporationInventors: Tomohiro Arashi, Yasuharu Miyauchi
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Publication number: 20090088315Abstract: The present invention relates to a dielectric ceramic composition comprising BaTiO3, BaZrO3, and the oxide of R wherein, when A is the content of BaZrO3, and C is the content of the oxide R, with respect to 100 moles of BaTiO3, then A is 40?A?65 moles and C is 4?C?15 moles; plus said dielectric composition satisfies the equation (1) and (2). The present invention can provide a dielectric ceramic composition good in IR lifetime, and capable to be suitably used for medium-high voltage which has a high rated voltage (for example, 100V or more). 0.0038A?0.147?B?0.004A+0.04??Equation (1) (note that, B is a ratio of the X-ray diffraction maximum intensity among peaks of said BaZrO3 with respect to the X-ray diffraction maximum intensity among peaks of said BaTiO3). 0.0041C?0.0115?D?0.0046C+0.084??Equation (2) (note that, D is a ratio of the X-ray diffraction maximum intensity among peaks of the oxide of said R with respect to the X-ray diffraction maximum intensity among peaks of said BaTiO3).Type: ApplicationFiled: September 25, 2008Publication date: April 2, 2009Applicant: TDK CORPORATIONInventors: Hideaki Seki, Sanshiro Aman, Mari Miyauchi
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Publication number: 20090075119Abstract: An embodiment of the present invention provides a method of making an electronically tunable dielectric material comprising mixing particles of at least one electronically tunable dielectric phase and particles of at least one compound of low loss complex perovskites, and particles of optional one other family of materials; and sintering the material.Type: ApplicationFiled: October 2, 2008Publication date: March 19, 2009Inventors: Xubai Zhang, Louise C. Sengupta, Elijah Aaron Underhill
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Patent number: 7505249Abstract: The present invention aims to provide an electronic component capable of reducing the occurrence of cracks at the joining portion to a board etc. A capacitor 1 (laminated ceramic capacitor) being one example of the electronic component is provided with an element assembly 10 (ceramic) and a pair of external electrodes 20 formed on both side surfaces of the element assembly 10. In the element assembly 10, a dielectric layer 12 and an internal electrode 14 are laminated alternately. The external electrode 20 has such constitution that a first electrode layer connected with the internal electrode, a second electrode layer (electroconductive resin layer) including a hardened product of thermohardening resin containing a polyphenol compound having a side chain composed of an aliphatic group, a third electrode layer composed of Ni and a fourth electrode layer composed of Sn are formed in this order from the element assembly side.Type: GrantFiled: February 23, 2007Date of Patent: March 17, 2009Assignee: TDK CorporationInventors: Takashi Komatsu, Kouji Tanabe
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Patent number: 7501371Abstract: Dielectric ceramic having a high dielectric constant of 5,500 or more and exhibiting good dielectric constant temperature characteristic, and a small, high-capacitance monolithic ceramic capacitor having an electrostatic capacitance temperature characteristic satisfying the X5R characteristic are provided. The dielectric ceramic includes a BaTiO3 based or (Ba,Ca)TiO3 based primary component, a rare-earth element and Cu, and has a structure composed of crystal grains and grain boundaries between the crystal grains.Type: GrantFiled: January 19, 2007Date of Patent: March 10, 2009Assignee: Murata Manufacturing Co., Ltd.Inventors: Takehisa Sasabayashi, Masayuki Ishihara, Tomoyuki Nakamura, Harunobu Sano
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Patent number: 7498285Abstract: A nonreducing dielectric ceramic comprising a (Sr, Ca)(Ti, Zr)O3-based perovskite principal crystal phase containing 55 mole percent or more of SrTiO3 and whose powder CuK? X-ray diffraction pattern exhibits a ratio of less than 5% of the maximum peak intensity of the accessory crystal phases being the other crystal phases to the intensity of the maximum peak of the perovskite crystal phase, which is present at 2?=25° to 35°. This strontium titanate-based nonreducing dielectric ceramic has a high relative dielectric constant of 150 or more, a low third-order harmonic distortion ratio, and an excellent reliability in a high temperature-loading test. Accordingly, it is advantageously used for forming dielectric ceramic layers of a monolithic ceramic capacitor.Type: GrantFiled: October 19, 2007Date of Patent: March 3, 2009Assignee: Murata Manufacturing Co., Ltd.Inventors: Toshiyuki Ito, Harunobu Sano
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Patent number: 7482299Abstract: The present invention provides a dielectric ceramic composition, which is, in addition to having superior resistance to reduction during firing, superior capacitance temperature characteristics after firing and superior dielectric characteristics, also demonstrates an enhanced lifetime for insulation resistance. The present invention is a dielectric ceramic composition comprising 0.18 to 0.5 part by weight of Yb2O3, 0.6 to 1.5 parts by weight of MgO, 0.4 to 1.5 parts by weight of CaSiO3, 0.02 to 0.2 part by weight of WO3, 0.1 to 0.4 part by weight of MnCO3 and 0.02 to 0.2 part by weight of MoO3 based on 100 parts by weight of (BaO)m.TiO2 (wherein, m is from 0.990 to 0.995).Type: GrantFiled: June 12, 2006Date of Patent: January 27, 2009Assignee: Namics CorporationInventors: Hitoshi Masumura, Satoshi Asahi, Masatoshi Kobayashi
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Publication number: 20090011923Abstract: The present invention provides a dielectric porcelain composition comprising 100 parts by weight of a barium titanate-based dielectric material and 4 to 10 parts by weight in total of Bi2O3 and at least one compound selected from the group of consisting of CuO, ZnO and MgO.Type: ApplicationFiled: September 4, 2008Publication date: January 8, 2009Applicants: NGK Insulators, Ltd., Soshin Electric Co., Ltd.Inventors: Tomoyuki Hasegawa, Yoshinori Ide, Tadashi Otagiri
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Publication number: 20080303720Abstract: A dielectric ceramic composition has a dielectric constant, K, of at least 200 and a dielectric loss, DF, of 0.0006 or less at 1 MHz. The dielectric ceramic composition may be formed by sintering by firing in air without a controlled atmosphere. The dielectric ceramic composition may have a major component of 92.49 to 97.5 wt. % containing 60.15 to 68.2 wt. % strontium titanate, 11.02 to 23.59 wt. % calcium titanate and 7.11 to 21.32 wt. % barium titanate; and a minor component of 2.50 to 7.51 wt. % containing 1.18 to 3.55 wt. % calcium zirconate, 0.50 to 1.54 wt. % bismuth trioxide, 0.2 to 0.59 wt. % zirconia, 0.02 to 0.07 wt. % manganese dioxide, 0.12 to 0.35 wt. % zinc oxide, 0.12 to 0.35 wt. % lead-free glass frit, 0.24 to 0.71 wt. % kaolin clay and 0.12 to 0.35 wt. % cerium oxide. UHF antennas and monolithic ceramic components may use the dielectric ceramic composition.Type: ApplicationFiled: June 7, 2007Publication date: December 11, 2008Applicant: VISHAY INTERTECHNOLOGY, INC.Inventors: ELI BERSHADSKY, MARINA KRAVCHIK, REUVEN KATRARO, DAVID BEN-BASSAT, DANI ALON
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Publication number: 20080297979Abstract: A dielectric ceramic composition comprising BamTiO2+m (note that “m” satisfies 0.99?m?1.01) and BanZrO2+n (note that “n” satisfies 0.99?n?1.01), an oxide of Mg, an oxide of R (note that R is at least one selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu), an oxide of at least one element selected from Mn, Cr, Co and Fe, and an oxide of at least one element selected from Si, Li, Al, Ge and B. With respect to 100 moles of said BamTiO2+m, 35 to 65 moles of BanZrO2+n, 4 to 12 moles of an oxide of Mg, 4 to 15 moles of an oxide of R, 0.5 to 3 moles of an oxide of Mn, Cr, Co and Fe, and 3 to 9 moles of an oxide of Si, Li, Al, Ge and B are included therein.Type: ApplicationFiled: February 21, 2008Publication date: December 4, 2008Applicant: TDK CORPORATIONInventors: Sanshiro Aman, Takashi Kojima, Mari Miyauchi, Masakazu Hosono, Dan Sakurai, Kosuke Takano, Nobuto Morigasaki
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Patent number: 7446997Abstract: A multi-layer ceramic capacitor includes a plurality of dielectric ceramic layers; internal electrodes formed between the dielectric ceramic layers; and end termination electrodes electrically connected to the internal electrodes, wherein the dielectric ceramic layer is a sintered body constituted of a primary component that, when it is expressed by ABO3+aRe2O3+bMnO, satisfies 1.000?A/B?1.035, 0.05?a?0.75 and 0.25?b?2.0; and a subcomponent that includes at least one kind of B, Li or S in the range of 0.16 to 1.6 parts by mass in total in terms of B2O3, Li2O and SiO2; and the internal electrode is constituted of Cu or a Cu alloy.Type: GrantFiled: July 31, 2007Date of Patent: November 4, 2008Assignee: Taiyo Yuden Co., Ltd.Inventors: Kazumi Kaneda, Shinsuke Takeoka
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Patent number: 7446068Abstract: A dielectric material is provided. The dielectric material includes a main composition including a Ba2Ti9O20 having a weight ranged from 50 to 94.9 wt %; a first sub-composition including a GeO2 and an MnCO3 respectively having a weight ranged from 0.01 to 10 wt %; and a second sub-composition including a glass additive composed of a B2O3, a ZnO, a SiO2 and at least one of a CuO, a CaCO3 and a BaCO3, wherein the glass additive has a weight ranged from 5 to 40 wt %.Type: GrantFiled: March 5, 2007Date of Patent: November 4, 2008Assignee: Walsin Technology CorporationInventors: Yiling Wang, Wenjun Wu, Meyiu Zhao, Wei Li, Tsai Tsung Tsai, Akira Sawasaki
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Patent number: 7439203Abstract: A dielectric ceramic composition comprising a main component including barium titanate and an oxide of Al, wherein the dielectric ceramic composition includes a plurality of dielectric particles, concentration of Al in each of the dielectric particles becomes lower from a particle surface to inside thereof, and each of the dielectric particles has an Al non-dispersed region substantially not including Al at least at a center portion of the particle.Type: GrantFiled: March 28, 2006Date of Patent: October 21, 2008Assignee: TDK CorporationInventors: Kazushige Ito, Akira Sato
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Patent number: 7431908Abstract: Spherical tetragonal barium titanate particles of the present invention have a perovskite crystal structure, an average particle diameter of 0.05 to 0.5 ?m, a particle size distribution ?g of not less than 0.70, and a ratio of Ba to Ti of 0.99:1 to 1.01:1. The spherical tetragonal barium titanate particles exhibit an excellent dispersibility as well as a high denseness, a high purity and excellent permittivity properties.Type: GrantFiled: September 13, 2004Date of Patent: October 7, 2008Assignee: Toda Kogyo CorporationInventors: Toshiharu Harada, Yuji Mishima, Seiji Okazaki, Haruki Kurokawa, Hidetomo Unemoto, Kazuyoshi Murashige, Manabu Matsumoto, Tadashi Kanasaku
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Publication number: 20080226944Abstract: A dielectric ceramic composition comprises a main component including BaTiO3, a first subcomponent including BaZrO3, a second subcomponent including an oxide of Mg, a third subcomponent including an oxide of rare earth, a fourth subcomponent including an oxide of at least one element selected from Mn, Cr, Co and Fe, and a fifth subcomponent including an oxide of at least one element selected from Si, Al, Ge, B and Li. At least a part of dielectric particles constituting the dielectric ceramic composition comprises a surface diffusion structure comprised of a central layer and a diffusion layer therearound. CR and CRmax, respectively defined as a concentration of said “R” in a proximity point to a boundary face of the dielectric particle and a maximum concentration of the “R” in the diffusion layer, satisfy a relation of CRmax/CR>1.Type: ApplicationFiled: February 21, 2008Publication date: September 18, 2008Applicant: TDK CORPORATIONInventors: Sanshiro Aman, Takashi Kojima, Mari Miyauchi, Masakazu Hosono, Dan Sakurai, Kosuke Takano, Nobuto Morigasaki
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Patent number: 7419927Abstract: A ceramic electronic device including a dielectric layer, wherein the dielectric layer includes a main component expressed by a composition formula of Bam TiO2+m, wherein “m” satisfies 0.995?m?1.010 and a ratio of Ba and Ti satisfies 0.995?Ba/Ti?1.010, and a subcomponent (a sixth subcomponent) including an oxide of Al; and a content of the Al compound is 0 to 4.0 moles (note that 0 is not included) in terms of Al2O3 with respect to 100 moles of the main component; and preferably, the dielectric layer includes a segregation phase, and the segregation phase includes an oxide of Al.Type: GrantFiled: August 29, 2005Date of Patent: September 2, 2008Assignee: TDK CorporationInventors: Kazushige Ito, Akira Sato
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Publication number: 20080169530Abstract: Multilayer ceramic chip capacitors which satisfy X8R requirements and which are compatible with reducing atmosphere sintering conditions so that non-noble metals such as nickel and nickel alloys thereof may be used for internal and external electrodes are made in accordance with the invention. The capacitors exhibit desirable dielectric properties (high capacitance, low dissipation factor, high insulation resistance), excellent performance on highly accelerated life testing, and very good resistance to dielectric breakdown. The dielectric layers comprise a barium titanate base material doped with other metal oxides such as BaO, Y2O3, ZrO2, SiO2, MgO, MnO, MoO3, CaO, Lu2O3, Yb2O3, or WO3 in various combinations.Type: ApplicationFiled: January 17, 2007Publication date: July 17, 2008Applicant: FERRO CORPORATIONInventors: Gerhardus W. Koebrugge, Knuth Albertsen, Willibrordus J. L. M. J. Coppens
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Patent number: 7399724Abstract: A production method of a dielectric ceramic composition using a reacted material obtained by making a main component including barium titanate react with a fourth subcomponent including an oxide of R (note that R is at least one selected from Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu). According to the invention, a dielectric ceramic composition capable of improving the specific permittivity without deteriorating other electric characteristics (for example, a temperature characteristic of the capacitance, insulation resistance, accelerated lifetime of the insulation resistance and dielectric loss), and the production method can be provided.Type: GrantFiled: December 13, 2005Date of Patent: July 15, 2008Assignee: TDK CorporationInventors: Miyuki Yanagida, Haruya Hara, Yasuo Watanabe, Akira Sato
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Patent number: 7396791Abstract: A dielectric ceramic composition comprising a main component including Ba, Ca and Ti and having a perovskite crystal structure expressed by a general formula ABO3 and a fourth subcomponent including a compound of Zr; wherein a content of the fourth subcomponent with respect to 100 moles of the main component is larger than 0 mole and smaller than 5 moles in terms of Zr and, preferably, a segregation phase including the compound of Zr is provided.Type: GrantFiled: January 17, 2006Date of Patent: July 8, 2008Assignee: TDK CorporationInventors: Kazushige Ito, Akira Sato
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Patent number: 7397649Abstract: A dielectric ceramic includes a compound represented by the general formula: (Ba1-tCat)m(Ti1-u-xZruCux)O3 (where 0.96?m?1.02, 0.001?x?0.03, 0?t?0.1, and 0?u?0.06) as a primary component, a rare earth element Re such as Dy, a metal element M such as Mn, Mg, and Si. In the dielectric ceramic, the Cu is uniformly and dispersedly present in the primary phase grain forming the primary component, and the contents of the accessory components with respect to 100 molar parts of the primary component are 0.1 to 1.5 molar parts of Re, 0.1 to 0.6 molar parts of M, 0.1 to 1.5 molar parts of Mg and 0.1 to 2.0 molar parts of Si. Accordingly, a multilayer ceramic capacitor can be realized which has a high dielectric constant, superior temperature properties, and a high reliability, and also has a small change in electrostatic capacitance with time.Type: GrantFiled: November 29, 2007Date of Patent: July 8, 2008Assignee: Murata Manufacturing Co., Ltd.Inventors: Kazuo Muto, Tomoyuki Nakamura, Harunobu Sano
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Patent number: 7381672Abstract: A dielectric ceramic material comprising the composition: 100(Ba1-xCax)mTiO3+aMnO+bCuO+cSiO2+dMgO+eRO (wherein coefficients 100, a, b, c, d, and e each represent mols; m represents the molar ratio of (Ba1-xCax) to Ti; and RO represents at least one rare-earth element oxide selected from Y2O3, La2O3, 2CeO2, Nd2O3, Sm2O3, Eu2O3, Gd2O3, Tb2O3, Dy2O3, Ho2O3, Er2O3, Tm2O3, Yb2O3 and Lu2O3), wherein m, x, a, b, c, d, and e satisfy the relationships: 0.998?m?1.030, 0.04?x?0.15, 0.01?a?5, 0.05?b?5, 0.2?c?8, 0.05?d?3.0, and 0.05?e?2.5, and the dielectric ceramic material has an average grain size of 0.3 ?m to 0.7 ?m, is used to make reliable multilayer ceramic capacitors including dielectric ceramic layers each having a small thickness of about 1 ?m.Type: GrantFiled: January 4, 2007Date of Patent: June 3, 2008Assignee: Murata Manufacturing Co., LtdInventors: Takashi Hiramatsu, Teppei Akiyoshi, Masahiro Otsuka
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Patent number: 7358208Abstract: A dielectric ceramic composition comprising a predetermined main component and a fifth subcomponent including an oxide of A (note that A is at least one king selected from a cation element group having an effective ionic radius of 0.065 nm to 0.085 nm at the time of 6 coordination); and the dielectric ceramic composition comprises a plurality of crystal grains including Ca elements and, when assuming that an average value of a concentration of entire Ca exiting in said respective crystal grains is grain Ca concentration, at least unevenness exists in said grain Ca concentration between said crystal grains and it is 5% or higher in a CV value.Type: GrantFiled: January 17, 2006Date of Patent: April 15, 2008Assignee: TDK CorporationInventors: Kazushige Ito, Akira Sato
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Patent number: 7351676Abstract: A dielectric ceramic composition of the present invention includes 100 parts by mole of BaTiO3, x1 parts by mole of MnO, x2 parts by mole of Cr2O3, x3 parts by mole of Y2O3 and/or Ho2O3, x4 parts by mole of oxide selected from the group consisting of BaO, CaO and SrO, and x5 parts by mole of SiO2 and/or GeO2, where 0.5?x1?4.5, 0.05?x2?1.0, x1+x2?4.55, 0.25?x3?1.5, 0.5 ?x4?6 and 0.5?x5?6. A multilayer ceramic capacitor of the present invention includes a laminated structure of a ceramic dielectric made of such a composition and an electrode made of Ni or Ni alloy.Type: GrantFiled: August 11, 2004Date of Patent: April 1, 2008Assignee: Rohm Co., Ltd.Inventors: Akihiro Koga, Yukio Tominaga, Tetsuhiro Takahashi
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Patent number: 7336476Abstract: The invention relates to a dielectric ceramic composition, which can be sintered at a low temperature as well as achieve a high dielectric constant with excellent thermal stability, and a multilayer ceramic capacitor using the same. The dielectric ceramic composition comprises a main component of (Ba1?xCax)mTiO3; and sub-components including MgCO3, RE2O3, MO, MnO, V2O5, Cr2O3 and a sintering additive of SiO2. RE2O3 is at least one selected from the rare earth oxide group consisting of Y2O3, Dy2O3 and Ho2O3, and MO is one of Ba and Ca. The dielectric ceramic composition is expressed by a following formula: a(Ba1?xCax)mTiO3-bMgCO3-cRE2O3-dMO-eMnO-fSiO2-gV2O5-hCr2O3. Here, a, b, c, d, e, f, g, and h satisfy following relationships: in mole fraction, a=100, 0.1?b?3.0, 0.1?c?3.0, 0.1?d?3.0, 0.05?e?1.0, 0.2?f?3.0, 0.01?g?1.0, and 0.01?h?1.0, and x and m satisfy following relationships: 0.005?x?0.15, and 0.995?m?1.03.Type: GrantFiled: July 27, 2006Date of Patent: February 26, 2008Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Chan Kong Kim, Kang Heon Hur, Eun Sang Na, Sung Bum Sohn, Tae Ho Song, Han Seong Jung
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Patent number: 7323428Abstract: A highly reliable ceramic electronic device having an excellent temperature characteristic of a capacitance and a low IR temperature dependency, comprising a dielectric layer: wherein the dielectric layer includes a main component expressed by a composition formula of BamTiO2+m, wherein “m” satisfies 0.995?m?1.010 and a ratio of Ba and Ti satisfies 0.995?Ba/Ti?1.010, and, as subcomponents, an oxide of Al and an oxide of Si or an oxide of R (note that R is at least one kind selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu); and includes a secondary phase composed of at least a part of the oxide of Al and at least a part of the oxide of Si or the oxide of R and being different from a main phase mainly composed of the main component; and the production method are provided.Type: GrantFiled: October 12, 2005Date of Patent: January 29, 2008Assignee: TDK CorporationInventors: Kazushige Ito, Akira Sato
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Publication number: 20070287625Abstract: A production method of a dielectric ceramic composition comprising a main component including a compound having a perovskite-type crystal structure expressed by a composition formula (Ba1-xCax) (Ti1-yZry)O3 (note that 0?x?0.2, 0?y?0.2), and a fourth subcomponent including an oxide of R (note that R is at least one selected from Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu); comprising steps of obtaining a post-reaction material by bringing a material of the main component to react in advance with a part of a material of the fourth subcomponent to be included in the dielectric ceramic composition, and adding rest of material of the fourth subcomponent to be included in the dielectric ceramic composition into the post-reaction material. According to the present invention, both of a dielectric ceramic composition capable of improving the specific permittivity and a temperature characteristic of capacitance can be preferable, and the production method can be provided.Type: ApplicationFiled: June 11, 2007Publication date: December 13, 2007Applicant: TDK CORPORATIONInventors: Miyuki Yanagida, Akira Sato
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Publication number: 20070284792Abstract: A production method of a dielectric ceramic composition comprising a main component including a compound having a perovskite-type crystal structure expressed by a general formula ABO3 (note that “A” is Ba alone or a composite of Ba and Ca, and “B” is Ti alone or a composite of Ti and Zr), and a fourth subcomponent including an oxide of R (note that R is at least one selected from Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu); comprising steps of dividing a material of the main component to a first main component material and a second main component material, obtaining a post-reaction material by bringing the material of the first main component to react in advance with a part of the fourth subcomponent material to be included in the dielectric ceramic composition, and adding the material of the second main component and rest of the fourth subcomponent material to be included in the dielectric ceramic composition into the post-reaction material; wherein, when assuming that number of moles oType: ApplicationFiled: June 11, 2007Publication date: December 13, 2007Applicant: TDK CORPORATIONInventors: Miyuki Yanagida, Akira Sato
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Patent number: 7307828Abstract: A dielectric ceramic position having at least a main component including barium titanate, a first subcomponent including at least one type of compound selected from MgO, CaO, BaO, a SrO, a second subcomponent including at least one type of compound selected from Al2O3, Li2O, and B2O3, a third subcomponent including at least one type of compound selected from V2O5, MoO3, and WO3, a fourth subcomponent including an oxide of R1 (where R1 is at least one type of element selected from Sc, Er, Tm, Yb, and Lu), and a fifth subcomponent including CaZrO3 or CaO+ZrO2.Type: GrantFiled: March 27, 2006Date of Patent: December 11, 2007Assignee: TDK CorporationInventors: Kazushige Ito, Akira Sato
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Patent number: 7297650Abstract: The production of low-loss, tunable composite ceramic materials with improved breakdown strengths is disclosed. The composite materials comprise ferroelectric perovskites such as barium strontium titanate or other ferroelectric perovskites combined with other phases such as low-loss silicate materials and/or other low-loss oxides. The composite materials are produced in sheet or tape form by methods such as tape casting. The composite tapes exhibit favorable tunability, low loss and tailorable dielectric properties, and can be used in various microwave devices.Type: GrantFiled: April 13, 2005Date of Patent: November 20, 2007Assignee: Paratek Microwave, Inc.Inventors: Luna H. Chiu, Xubai Zhang, Louise C. Sengupta
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Publication number: 20070232480Abstract: Dielectric particles including a main component including barium titanate and R oxide (where R is at least one element selected from Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu), wherein when defining the size of the dielectric particles as “D” and defining the region of a depth from the particle surface of 0% to 10% of said D as a surface region, a region of a depth from the particle surface of more than 10% to less than 40% of the D as an intermediate region, and a region of a depth from the particle surface of 40% to 50% of the D as a center region, in the surface region, the ratio of content of the R oxide decreases from the surface side toward the center of the dielectric particles and in the center region, the ratio of content of the R oxide increases from the surface side toward the center of the dielectric particles.Type: ApplicationFiled: March 20, 2007Publication date: October 4, 2007Applicant: TDK CORPORATIONInventors: Miyuki Yanagida, Mitsuru Kojima, Tomoyoshi Fujimura, Akira Sato
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Publication number: 20070225154Abstract: A production method of a dielectric ceramic composition, comprising a main component comprised of barium titanate, a fourth subcomponent comprised of an oxide of R1 (note that R1 is at least one kind selected from a first element group composed of rare earth elements having a value of effective ionic radius for coordination number 9 of less than 108 pm) and a fifth sub component comprised of an oxide of R2 (note that R2 is at least one kind selected from a second element group composed of rare earth elements having a value of effective ionic radius for coordination number 9 of 108 pm to 113 pm); comprising the steps of obtaining a post-reaction material by bringing the main component material reacting with a part of the fourth subcomponent material and/or a part of the fifth subcomponent material, and adding remaining materials of the fourth subcomponent and the fifth subcomponent to be included in the dielectric ceramic composition to the post-reaction material; wherein a ratio M1/M2 of the number of moles MType: ApplicationFiled: March 19, 2007Publication date: September 27, 2007Applicant: TDK CORPORATIONInventors: Miyuki Yanagida, Akira Sato
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Patent number: 7273825Abstract: The dielectric ceramic has a composition represented by general formula 100(Ba1-x-ySrxCay)m(Ti1-zZrz)O3+aBaO+bR2O3+cMgO+dMnO+eCuO+fV2O5+gXuOv (where R is a rare-earth element such as La, Ce or Pr; and XuOv is an oxide group including at least Si); and 0?x?0.05, 0?y?0.08 (preferably 0.02?y?0.08), 0?z?0.05, 0.990?m, 100.2?(100 m+a)?102, 0.05?b?0.5, 0.05?c?2, 0.05?d?1.3, 0.1?e?1.0, 0.02?f?0.15, and 0.2?g?2. With this composition, a monolithic ceramic capacitor retaining good dielectric characteristics and temperature characteristics even if a high field strength voltage is applied by further thinning the dielectric layers thereof and having excellent reliability achieving good isolating property, dielectric strength, and high-temperature load life is obtained.Type: GrantFiled: January 25, 2007Date of Patent: September 25, 2007Assignee: Murata Manufacturing Co., Ltd.Inventors: Kazuo Muto, Tomoyuki Nakamura, Akira Kato, Harunobu Sano, Takehisa Sasabayashi, Takashi Hiramatsu
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Patent number: 7271115Abstract: A dielectric ceramic composition contains a substance represented by general formula 100(Ba1?xCax)mTiO3+aMnO+bCuO+cROn (wherein the coefficients 100, a, b, and c each represent mols; R represents at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; and n represents a number determined by the valence of the rare-earth element R and is a positive number required for maintaining electroneutrality) and a sintering aid. The dielectric ceramic composition satisfies the relationships 0.990?m?1.050; 0.01?x?0.20; 0.5?a?3.5; 0.1?b?5.0; and 10?c?20, and the amount of the sintering aid represented by d in terms of parts by weight per 100 parts by weight of the compound represented by (Ba1?xCax)mTiO3 satisfies 0.8?d?5.0 Furthermore, VO3/2 may be added to increase the breakdown field.Type: GrantFiled: January 8, 2007Date of Patent: September 18, 2007Assignee: Murata Manufacturing Co., Ltd.Inventor: Shoichiro Suzuki
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Patent number: 7265072Abstract: A dielectric ceramic composition includes a main component including a dielectric oxide expressed by a composition formula of {(Ca1-xSrx)O}m.(Zr1-yTiy)O2, wherein m, x and y indicating composition mole ratios in the composition formula are in relationships of 0.8?m?1.3, 0x?1.00 and 0.1?y?0.8; a first subcomponent including a V oxide; and a second subcomponent including an Al oxide; wherein ratios of respective components with respect to 100 moles of said main component are the first subcomponent: 0 mole<first subcomponent<7 moles (wherein the value is a V oxide value in terms of V2O5); and the second subcomponent: 0 mole<second subcomponent<15 moles (wherein the value is an Al oxide value in terms of Al2O3).Type: GrantFiled: February 17, 2004Date of Patent: September 4, 2007Assignee: TDK CorporationInventors: Yasuo Watanabe, Wataru Takahara
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Publication number: 20070203016Abstract: A production method of a dielectric ceramic composition comprising a main component including barium titanate expressed by a composition formula of BamTiO2+m, wherein “m” satisfies 0.990<m<1.010, and a fourth subcomponent including an oxide of R (note that R is at least one kind selected from Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu); comprising the step of obtaining a post-reaction material by bringing a material of said main component react with at least a part of a material of said fourth subcomponent in advance: by which it is possible to provide a dielectric ceramic composition having improved specific permittivity without deteriorating other electric characteristics (for example, a temperature characteristic of capacitance, insulation resistance, an accelerated lifetime of insulation resistance and a dielectric loss).Type: ApplicationFiled: February 23, 2007Publication date: August 30, 2007Applicant: TDK CORPORATIONInventors: Mitsuru Kojima, Miyuki Yanagida, Haruya Hara, Yasuo Watanabe, Akira Sato
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Patent number: 7262146Abstract: A dielectric ceramic composition, comprising a main component including barium titanate; a first subcomponent including at least one kind selected from MgO, CaO, BaO and SrO; a second subcomponent functioning as a sintering auxiliary agent; a third subcomponent including at least one kind selected from V2O5, MoO3 and WO3; a fourth subcomponent including an oxide of R1 (note that R1 is at least one kind selected from Sc, Er, Tm Yb and Lu); a fifth subcomponent including CaZrO3 or CaO+ZrO2; and an eighth subcomponent including an oxide of A (note that A is at least one kind selected from a cation element group having an effective ionic radius at the time of 6 coordination of 0.065 nm to 0.085 nm); wherein a ratio of the eighth subcomponent with respect to 100 moles of the main component is 0 to 4 moles (note that 0 mole and 4 moles are excluded, and the value is in terms of an A oxide).Type: GrantFiled: August 22, 2005Date of Patent: August 28, 2007Assignee: TDK CorporationInventors: Kazushige Ito, Akira Sato
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Publication number: 20070191211Abstract: A dielectric ceramic composition comprising a main component including BaTiO3, a fourth subcomponent including an oxide of R1 (note that R1 is at least one selected from Y, Ho, Er, Tm, Yb and Lu) and a fifth subcomponent including an oxide of R2 (note that R2 is at least one selected from Dy, Tb, Gd and Eu); wherein a total number of moles of R1 and R2 with respect to 100 moles of the main component is 2 to 6 moles when calculated as a conversion of the R1 and a conversion of the R2, and a ratio of the fifth subcomponent to the total number of moles of R1 and R2 with respect to 100 moles of the main component is in a relationship of 0.5?R2/(R1+R2)?0.75 when calculated as a conversion of the R1 and a conversion of the R2. According to the present invention, a high temperature load lifetime and capacity-temperature characteristics can be well balanced even when the dielectric layer of the electronic device is made thin, so that a sufficiently reliable dielectric ceramic composition can be provided.Type: ApplicationFiled: February 9, 2007Publication date: August 16, 2007Applicant: TDK CORPORATIONInventors: Masakazu Hosono, Toshihiro Iguchi, Dan Sakurai, Jun Satoh, Mitsuru Kojima, Takashi Kojima
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Patent number: 7241712Abstract: The present invention relates to a low-temperature sintered barium titanate microwave dielectric ceramic material. The host matrix thereof can be represented by BaxTiyMzOx+2y+k, where x is 1˜6, y is 1˜17, z is 0˜1, k is 0˜3, M is an element substituting the Ba or Ti ion, for example selected from an alkali metal, an alkaline-earth metal, a transition group or a rare earth group, and preferably Ba2Ti9O20 or the host matrix containing Zr, Sn, Zn, etc. According to the present invention, a low melting glass is added and a subsequent milling operation is performed to reduce the sintering temperature of the microwave dielectric ceramic material to less than 1,000° C. The low melting glass can be for example the Ba—B—Si—Li glass, Ba—B—Zn—Si—Li glass, Ba—B—Si—Li—Cu glass or Cu—B—Zn—Si—Li glass.Type: GrantFiled: February 28, 2005Date of Patent: July 10, 2007Assignee: National Taiwan University TechnologyInventors: Sea-Fue Wang, Yuh-Ruey Wang, Mei-Hui Hsiao
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Patent number: 7242571Abstract: A dielectric ceramic is obtained by the steps of obtaining a reaction product composed of a barium titanate base composite oxide represented by the general formula (Ba1?h?i?mCahSriGdm)k(Ti1?y?j?nZryHfjMgn)O3, in which 0.995?k?1.015, 0?h?0.03, 0?i?0.03, 0.015?m?0.035, 0?y<0.05, 0?j<0.05, 0?(y+j)<0.05, and 0.015?n?0.035 hold; mixing less than 1.5 moles of Ma (Ba or the like), less than 1.0 mole of Mb (Mn or the like), and 0.5 to 2.0 moles of Mc (Si or the like) with respect to 100 moles of the reaction product; and firing the mixture thus obtained. This dielectric ceramic has superior humidity resistance, satisfies the F characteristic of the JIS standard and the Y5V characteristic of the EIA standard, has a relative dielectric constant of 9,000 or more, and has superior high-temperature reliability.Type: GrantFiled: January 30, 2004Date of Patent: July 10, 2007Assignee: Murata Manufacturing Co. Ltd.Inventors: Toshihiro Okamatsu, Harunobu Sano
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Patent number: 7232527Abstract: A sintered body for thermistor device comprising: at least one element selected from elements of group 3 in a periodic table proviso that La is excluded; at least one element selected from elements of group 2 in a periodic table; Mn; Al; and oxygen, and being substantially free from any transition metal other than Mn and the at least one element selected from elements of group 3 in the periodic table.Type: GrantFiled: December 1, 2003Date of Patent: June 19, 2007Assignee: NGK Spark Plug Co., Ltd.Inventors: Takaaki Chosokabe, Masaki Iwaya, Naoki Yamada
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Patent number: 7230817Abstract: Multilayer ceramic chip capacitors which satisfy Y5V requirements and which are compatible with reducing atmosphere sintering conditions so that non-noble metals such as nickel, copper, and alloys thereof may be used for internal and external electrodes are made in accordance with the invention. The capacitors exhibit desirable dielectric properties (high capacitance, low dissipation factor, high insulation resistance), excellent performance on highly accelerated life testing, and very good resistance to dielectric breakdown. The dielectric layers comprise BaTiO3 doped with other metal oxides such as MgO, CaO, ZnO, MnO2, ZrO2, SiO2, Nd2O3, Nb2O5, and Y2O3.Type: GrantFiled: April 15, 2005Date of Patent: June 12, 2007Assignee: Ferro CorporationInventors: Mohammed H. Megherhi, Mike S. H. Chu, Daniel E. McCauley, Elizabeth W. Römer, Willibrordus J. Coppens, Knuth Albertsen
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Patent number: 7226882Abstract: A dielectric material comprising: a composition represented by aBaO.bTiO2.cREO3/2.dBiO3/2, wherein a, b, c and d each independently represent a molar ratio satisfying the following requirements: a+b+c+d=1, 0.09?a?0.16, 0.54?b?0.62, 0.20?c?0.34 and 0?d?0.10; and RE represents a rare earth metal; and from 5 to 50 parts by mass, per 100 parts by mass of the composition, of a glass containing a component represented by kBaO.lZnO.mB2O3.nSiO2, wherein k, l, m and n each independently represent a composition percentage satisfying the following requirements: k+l+m+n=100, 25?k?55, 5?1?30, 15?m?35 and 5?n?30.Type: GrantFiled: June 8, 2004Date of Patent: June 5, 2007Assignee: NGK Spark Plug Co., Ltd.Inventors: Hisashi Kozuka, Yuji Yasunishi, Kiyoshi Matsuda
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Patent number: 7220691Abstract: A dielectric ceramic composition comprising 100 moles of barium titanate as the main component, and furthermore comprising with respect to 100 moles of the main component 0.1 to 3 moles of a first subcomponent including a magnesium oxide, 0.01 to 0.5 mole (note that 0.5 is not included) of a second subcomponent including a yttrium oxide, 0.01 to 0.2 mole of a third subcomponent including a vanadium oxide, and 0.5 to 10 moles of a glass component including a silicon oxide as the main component; wherein a manganese oxide and a chrome oxide are substantially not included, and an average particle diameter of dielectric particles is 0.35 ?m or smaller.Type: GrantFiled: September 27, 2006Date of Patent: May 22, 2007Assignee: TDK CorporationInventors: Tomoaki Nonaka, Hiroshi Sasaki, Tsutomu Odashima, Takahiro Harada, Matsumi Watanabe, Tetsuo Takaishi, Shinsuke Hashimoto
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Patent number: 7203055Abstract: Disclosed herein is a method of manufacturing a multilayered ceramic capacitor by a spin coating process, and a multilayered ceramic capacitor obtained by the above method. The method of the current invention provides a plurality of dielectric layers formed by spin coating, in which the process of coating the dielectric layer and the process of printing the inner electrode can be provided as a single process. Therefore, the thickness of the dielectric layer is easily controlled while the dielectric layer is formed to be thin. Further, since the dielectric layers and the inner electrodes are formed successively, the processes of separating and layering the dielectric layers, and the process of compressing the ceramic multilayered body can be omitted. Thereby, the ceramic multilayered body need not be compressed, and thus, a pillowing phenomenon does not occur in the multilayered ceramic capacitor.Type: GrantFiled: December 15, 2004Date of Patent: April 10, 2007Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Hyo Soon Shin, Seung Hyun Ra, Yong Suk Kim, Hyoung Ho Kim, Ho Sung Choo, Jung Woo Lee
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Patent number: 7179441Abstract: The present invention relates to a method for preparing barium titanate based powder. More particularly, the present invention provides a method for preparing barium titanate powder comprising the following steps of precipitation of barium titanyl oxalate (BaTiO(C2O4)2.4H2O) with spraying a mixture of an aqueous barium chloride (BaCl2.2H2O) and titanium tetrachloride (TiCl4) to an aqueous solution of oxalic acid, via a nozzle; wet pulverization by using a beads mill after adding an additive such as an amine; dry; pyrolysis; and re-pulverization.Type: GrantFiled: May 6, 2002Date of Patent: February 20, 2007Assignees: Samsung Fine Chemicals Co., Ltd., Samsung Electro-Mechanics Co., Ltd.Inventors: Jae Chul Jung, Woo Young Yang, Keon Il Kim, Yun Jung Park, Jun Hee Lee, Kang Heon Hur, Seon Cheol Park, Jai Joon Lee
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Patent number: 7176156Abstract: A production method of a dielectric ceramic composition having a step of firing dielectric material including a main component ingredient and a subcomponent ingredient, wherein said main component ingredient before firing is barium titanate ingredient powder having the perovskite type crystal structure expressed by ABO3, and a ingredient powder having a ratio A/B of A site components and B site components of 1.006?A/B?1.035 and the specific surface area of 8 to 50 m2/g is used. According to the invention, a dielectric ceramic composition having preferable electric characteristics and temperature characteristic can be provided even in the case of being composed of fine particle and a capacitor made to be a thin layer.Type: GrantFiled: November 16, 2004Date of Patent: February 13, 2007Assignee: TDK CorporationInventors: Yuji Umeda, Akira Sato
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Patent number: 7160828Abstract: A dielectric composition that can be fired at a temperature of below 900° C. The dielectric composition has a dielectric constant of 25–35 and a quality factor (Qxf) of 6,000–20,000 GHz. The composition comprises 3–16 wt % of K2O—Na2O—Li2O—B2O3—SiO2 system glass frit and 84–97 wt % of BaO—TiO2 system dielectric ceramics. The composition can be effectively applied to construct a part of a ceramic multi-layer packaging as a resonator form such as a filter or an antenna, etc.Type: GrantFiled: March 1, 2006Date of Patent: January 9, 2007Assignee: Korea Institute of Science and TechnologyInventors: Jae-Hwan Park, Jae-Gwan Park, Dong-Soon Shin, Young-Jin Choi
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Patent number: 7160827Abstract: A dielectric ceramic composition that includes a main component expressed as 100BamTiO3+xCuO+aROn+bMnO+cMgO (wherein coefficients 100, x, a, b, and c represent molar ratios; m represents the ratio of Ba to Ti (Ba/Ti); R represents at least one metal element selected from Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; and n represents a positive number required to maintain electroneutrality and is determined by the valence number of R), wherein m, x, a, b, and c meet the following relationships: 0.990?m?1.050; 0.1?x?5.0; 9.0?a?20.0; 0.5?b?3.5; and 0<c?4.0, and the dielectric ceramic composition contains 0.8 to 5.0 parts by weight of a sintering additive with respect to 100 parts by weight of the main component.Type: GrantFiled: July 28, 2006Date of Patent: January 9, 2007Assignee: Murata Manufacturing Co., Ltd.Inventor: Koichi Banno
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Patent number: 7160829Abstract: A dielectric composition that can be fired at a temperature of below 900° C. The dielectric composition has a dielectric constant of 25–35 and a quality factor (Qxf) of 6,000–20,000 GHz. The composition comprises 3–16 wt % of K2O—Na2O—Li2O—B2O3—SiO2 system glass frit and 84–97 wt % of BaO—TiO2 system dielectric ceramics. The composition can be effectively applied to construct a part of a ceramic multi-layer packaging as a resonator form such as a filter or an antenna, etc.Type: GrantFiled: March 1, 2006Date of Patent: January 9, 2007Assignee: Korea Institute of Science and TechnologyInventors: Jae-Hwan Park, Jae-Gwan Park, Dong-Soon Shin, Young-Jin Choi