Abstract: Multilayer ceramic chip capacitors which satisfy COG requirements and which are compatible with reducing atmosphere sintering conditions so that non-noble metals such as copper and copper alloys thereof may be used for internal and external electrodes are made in accordance with the invention. The capacitors exhibit desirable dielectric properties (high capacitance, low dissipation factor, high insulation resistance), excellent performance on highly accelerated life testing, and very good resistance to dielectric breakdown. The dielectric layers comprise a composite oxide formed by calcining rare earth titanates, barium titanate, together with other metal oxides such as MgO, CaO, ZnO, MnO2, ZrO2, SiO2, Ga2O3, Nd2O3, Nb2O5, and Y2O3.

Abstract: A method of production of a reduction resistant dielectric ceramic composition having a superior low frequency dielectric characteristic and further improved in accelerated lifetime of insulation resistance, specifically a method of production of a dielectric ceramic composition containing a main component including a dielectric oxide of a specific composition, a first subcomponent including a V oxide, a second subcomponent containing an Al oxide, a third subcomponent containing an Mn oxide, and a fourth subcomponent containing a specific sintering aid in a specific ratio, including a step of mixing at least part of the materials of the subcomponents excluding one or both of at least the material of the third subcomponent and material of the fourth subcomponent with the starting materials prepared for obtaining the material of the main component to prepare the pre-reaction material, a step of causing the prepared pre-reaction material to react to obtain a reacted material, and a step of mixing the materials o

Abstract: A porous catalyst layer containing mixed conducting oxide having substantially a perovskite structure and containing a first element selected from Co and Fe, and a second element selected from In, Sn and Y arranged in the B site in the perovskite structure is contiguous to a second surface (1a) of a selective oxygen-permeable dense continuous layer (1) containing mixed conducting oxide. A porous intermediate catalyst layer (3) containing mixed conducting oxide and at least one of Co, Fe, Mn and Pd is contiguous to a first layer (1b) of the dense continuous layer (1). A porous reactive catalyst layer (4) provided with a metal catalyst selected from at least one of Ni, Co, Ru, Rh, Pt, Pd, Ir and Re and a support is continguous to the porous intermediate catalyst layer (3) in a manner to sandwich between the dense continuous layer (1) and the porous reactive catalyst layer (4).

Abstract: Disclosed herein is a small particle oxide powder for dielectrics. The oxide powder has a perovskite structure, an average particle diameter [D50(?m)] of 0.3 ?m or less, a particle size distribution of the average particle diameter within 3%, a particle size distribution satisfying a condition D99/D50<2.5, a content of OH? groups of 0.2 wt % and a C/A axial ratio of 1.006 or more. A method of manufacturing the oxide powder comprises the steps of mixing TiO2 particles and a compound solved with at least one element represented by A of the perovskite structure of ABO3; drying and pulverizing the mixture of TiO2 and the compound; calcining the pulverized mixture; adding the oxide containing the elements of the site A to the coated TiO2 particles and wet-mixing, drying and pulverizing; primarily calcining and pulverizing the pulverized powder under vacuum; and secondarily calcining and pulverizing the powder.

Abstract: This invention provides the three novel La,Fe, La,Cr and Sm,Fe substituted barium titanate solid solution ferroelectric compositions with the formula Ba1?xLnxTi1?xMxO3 wherein when Ln is La, M is Fe or Cr, when Ln is Sm, M is Fe and x is from about 0.02 to about 0.06 and mixtures thereof, the novel La,Fe substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1?ySry)1?xLaxTi1?xFexO3 wherein y is greater than zero and less than about 0.6 and x is from about 0.01 to about 0.06 and the novel La,Al substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1?ySry)1?xLaxTi1?x/4?3a/4Ala}(x?a)/4O3 wherein } denotes a vacancy, y is greater than zero and less than about 0.6, a is from about 0.01 to about 0.06 and x is from 0.02 to about 0.10 with the proviso that x is greater than or equal to a.

Abstract: A dielectric composition for firing at a low temperature having a high dielectric constant ?r, a high Q value, and a low temperature coefficient ?f of the resonance frequency is provided. The dielectric composition includes a main composition of x.BaO-y.TiO2-z1.Nd2O3-z2.La2O3-z3.Sm2O3-t.Bi2O3, (x+y+z1+z2+z3+t=1, 0.070?x?0.300, 0.385?y?0.844, 0.010?z1?0.130, 0.000?z2?0.120, 0.000?z3?0.120, and 0.075<t?0.185). The dielectric composition also includes a glass component containing at least 0.1 weight percent or more of B2O3 in an amount of 0.05 to 20 weight parts with respect to 100 weight parts of the main composition.

Abstract: A perovskite compound of the formula, (Na1/2Bi1/2)1-xMx(Ti1-yM?y)O3±z, where M is one or more of Ca, Sr, Ba, Pb, Y, La, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu; and M? is one or more of Zr, Hf, Sn, Ge, Mg, Zn, Al, Sc, Ga, Nb, Mo, Sb, Ta, W, Cr, Mn, Fe, Co and Ni, and 0.01<x<0.3, and 0.01<y<0.3, and z<0.1 functions as an electromechanically active material. The material may possess electrostrictive or piezoelectric characteristics.

Abstract: Single-phase, non-cubic and single-phase, cubic ferroelectric/paraelectric perovskite-structured materials having reasonably low and fairly temperature insensitive dielectric constants (stable dielectric constants over a wide range of operating temperatures of ?80° C. to 100° C.), reasonable loss tangents (<˜10?1), high tunability, and significantly lowered Curie temperature below the temperature range of operation for previous undoped perovskite structures are provided. The FE/PE materials of the present invention have dilute charge-compensated substitutions in the Ti site of the perovskite structure. This single-phase structure or a variant of it with a Ti rich composition, provided herein, allows for pulsed-laser-deposition of a thin film with uniform transfer of the structure of the target into the deposited film, which enables production of very small, lightweight devices that are extremely efficient and consume little power.

Abstract: A new dielectric material composition with high dielectric constant and low dielectric loss, which includes a quaternary metallic oxide having a pervoskite structure and represented by a general formula, Ba1-xM1xTi1-yM2yOm. It is suitable for Gbit memory devices, embedded capacitance devices in multilayered structures, and modulable capacitors for high frequency devices.

Abstract: Various high quality microwave dielectric composite compositions are prepared by replacing a part of Ba, La or Ti with another element in a dielectric material represented by BanLa4Ti3+nO12+3n. A first embodiment thereof comprises a ceramic composition represented by (Ba1?xAx)nLa4Ti3+nO12+3n, wherein A is an alkaline earth metal element except Ba, and 0.5<n<5 and 0<x<0.5, which is a composite composition being homologous as the former dielectric material and having a chemical formula obtained by replacing a part of Ba with an alkaline earth metal element except Ba. Similarly, a part of La and a part of Ti can be replaced with a rare earth element except La and an element except Ti, respectively. The above various microwave dielectric composite compositions can be used for adjusting microwave dielectric characteristics of a material through replacing a part of a constituent element with another element and thus increasing the variety of the material for a dielectric resonator.

Abstract: The dielectric composition contains a mixture of a ceramic composition containing BaaREbTicO3, wherein RE represents a rare earth element, with 0.05?a?0.25, 0.525?b?0.70, 0.85?c?1.0, and 2a+3b+4c=6, and free from lead and bismuth, a glass composition, and a metal oxide. The glass composition preferably contains ZnO or MgO, SiO2, and at least 10% by weight of Li2O or TiO2. Preferably, the alkaline earth metal oxide is MgO. By preference, the glass composition essentially consists of 50–80% weight of SiO2, 5–25% weight of MgO, and optionally another alkaline earth metal oxide, and 10–25% by weight of Li2O, and is substantially free from boron. The dielectric composition can be sintered in the presence of Cu electrodes at a temperature below the melting point of Cu so as to manufacture an electronic device such as a ceramic multilayer element. After sintering, the dielectric composition has a relative dielectric constant of at least 55.

Abstract: The invention relates to a glass ceramic mass containing at least one oxide ceramic containing barium, titanium and at least one rare earth metal Rek; and at least one glass material containing at least one oxide with boron, at least one oxide with silicon and at least one oxide with at least one bivalent metal Me2+. The glass ceramic mass is characterised in that the glass material contains at least one oxide with bismuth, especially bismuth trioxide. The oxide ceramic is especially a microwave ceramic of formula BaRek2Ti4O12, Rek being neodymium or samarium. The composition of the oxide ceramic remains essentially constant during the sintering of the glass ceramic, enabling the material properties of the glass ceramic mass, such as permittivity (20–80), quality (800–5000) and Tkf (±20 ppm/K) to be specifically predetermined. The glass ceramic mass is characterised by a densification temperature of under 910° C.

Abstract: The present invention relates to a temperature-stable dielectric ceramic composition for multilayer ceramic capacitors. The said dielectric composition comprises barium titanate and additives, wherein the barium titanate ranges from 94 to 99 mol % of the said composition, and the additives range from 1 to 6 mol % of the said composition. The additives comprise oxides of Mg, Ca, Ba, Si and Mn, and oxides of one or more elements selected from the group consisting of Co, Sr, Ti and Fe, and an oxide of Re, or carbonates, hydroxide, oxalates, acetates or nitrates of the above elements. Re represents one or more elements selected from Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu. After being sintered at 1200° C. to 1350° C. under reducing atmosphere, the room-temperature dielectric constant of the composition is 2000 to 3500 and its temperature coefficient of capacitance satisfies X7R characteristic (EIA standards).

Abstract: A high permittivity dielectric ceramic composition wherein a main component includes BaTiO3: 74.24 to 79.97 mol %, BaZrO3: 5.69 to 12.04 mol %, CaTiO3: 7.84 to 12.13 mol %, MgTiO3: 3.11 to 4.72 mol % and Bi2TiO5: 0.10 to 0.60 mol %. With respect to 100 wt % of the main component, 0.1 or less (excepting 0) of NiO, 0.1 wt % or less (excepting 0) of CeO2, and 0.2 wt % or less (excepting 0) of MnO are included. In accordance with need, 0.2 wt % or less (excepting 0) of SiO2 is further included with respect to 100 wt % of the main component. A high relative permittivity, such as 9000 or more, a high AC breakdown voltage, and a small electrostatic capacity change rage with respect to temperature can be obtained.

Abstract: A composition of a plasma display panel (PDP) is disclosed. In order to effectively reduce a jitter, the composition contains a ferroelectric transparent ceramics material.

Abstract: In order to provide dielectric ceramic composition having low IR defect rate and high relative dielectric constant even when the multilayer ceramic capacitor is made thinner, dielectric ceramic composition including a main component expressed by a composition formula {{Ba(1-x)Cax}O}A{Ti(1-y-z)ZryMgz}BO2 and subcomponents of Mn oxide, Y oxide, V oxide and Si oxide is provided. In the above formula, A, B, x, y and z are as follows: 0.995?A/B?1.020, 0.0001?x?0.07, preferably 0.001?x<0.05, 0.1?y?0.3 and 0.0005?z?0.01, preferably 0.003?z?0.01.

Abstract: Lead-free and cadmium-free glass composition that is particularly suitable for use in conductive ink applications. The invention includes a capacitor comprising a copper termination, the copper termination is made by firing an ink including a glass component, the glass component may comprise up to about 65 mole % ZnO, up to about 51 mole % SrO, about 0.1 to about 61 mole % B2O3, up to about 17 mole % Al2O3, about 0.1 to about 63 mole % Sio2, up to about 40 mole % BaO+CaO, and up to about 20 mole % MgO.

Abstract: Dielectric composite materials including an electronically tunable dielectric phase and a calcium and oxygen-containing compound are disclosed. The tunable phase may comprise a material such as barium strontium titanate. The calcium/oxygen compound may comprise CaO or a transition metal-containing compound such as Ca2Nb2O7 or CaTiO3. The material may also include a rare earth oxide dopant such as CeO2. The materials resist dielectric breakdown and possess improved combinations of electronic properties. The materials may be tailored for specific applications.

Abstract: A dielectric ceramic composition having a high maximum relative dielectric constant, a superior temperature characteristic of capacitance and a high AC breakdown voltage, and a capacitor using the same are provided. The dielectric ceramic composition includes a polycrystalline solid solution which contains barium titanate as a primary component and which is represented by the formula (Ba1?xCax)a(Ti1?yZry)bO3 in which 0<x?0.25 and 0<y?0.25 are satisfied. The dielectric ceramic composition also includes, with respect to 100 parts by weight of the primary component, a Y component in the form of Y2O3 in an amount in the range of more than zero to about 5 parts by weight; a Mg component in the form of MgO in an amount in the range of more than zero to about 2 parts by weight, and an Al component in the form of Al2O3 in an amount in the range of more than zero to about 2.5 parts by weight.

Abstract: It is an object of the invention to provide a dielectric ceramic composition which enables its firing temperature to be lowered and which has an excellent electrical properties, particularly temperature dependence of resonance frequencies. A dielectric ceramic composition according to the invention comprises an oxide of a barium titanate family having a composition formula represented as BaTixO2x+1 (3.5?x?5.0); a first chemical element group consisting of at least one kind of alkaline-earth metals, silicon, zinc, aluminium, titanium, copper, bismuth and molybdenum; and a second chemical element group consisting of at least one kind of alkali metals and boron. A weight ratio of a total of each chemical element in the first and second chemical element groups to the oxide (the total of each chemical element/the oxide) is between 45/55 and 65/35 inclusive when the ratio is determined by converting said each chemical element to its oxide.

Abstract: A dielectric ceramic has a ceramic structure of crystal grains and grain boundaries between the crystal grains. The crystal grains are of a main component represented by the formula ABO3 and an additive containing a rare earth element wherein A is at least one of barium, calcium, and strontium, barium being an essential element, and B is at least one of titanium, zirconium, and hafnium, titanium being an essential element. The average rare earth element concentration in the interior of the crystal grains is about 50% or less the average rare earth element concentration at the grain boundaries. Furthermore, about 20% to 70% of the crystal grains have a rare earth element concentration in the center of the crystal grain of at least about 1/50 the maximum rare earth element concentration in a region extending inward from the surface by a distance corresponding to about 5% of the diameter of the crystal grain.

Abstract: The non reducible dielectric ceramic composition comprising a main component of (Ba1-xCax)m(Ti1-yZry)O3, subcomponents of MgO, Re2O3, MO, MnO and V2O5 where Re is one or more elements selected from the group of Y, Dy and Ho and M is one or two elements selected from the group of Ba and Ca, and a sintering aid of SiO2, wherein when the composition is represented by the formula 100(Ba1-xCax)m(Ti1-yZry)O3+bMgO+cRe2O3+dMO+eMnO+fV2O5+gSiO2, the ratio of the components satisfies the conditions of 0.005?x?0.15, 0.995?m?1.03, 0.0005?y?0.005, 0.1?b?3.0, 0.1?c?3.0, 0.05?d?2.0, 0.05?e?50.3, 0.0.?f?0.1, and 0.2?g?3.0 based on the molar ratio.

Abstract: This invention provides the three novel La,Fe, La,Cr and Sm,Fe substituted barium titanate solid solution ferroelectric compositions with the formula Ba1-xLnxTi1-xMxO3 wherein when Ln is La, M is Fe or Cr, when Ln is Sm, M is Fe and x is from about 0.02 to about 0.06 and mixtures thereof, the novel La,Fe substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1-ySry)1-xLaxTi1-xFex O3 wherein y is greater than zero and less than about 0.6 and x is from about 0.01 to about 0.06 and the novel La,Al substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1-ySry)1-xLax Ti1-x/4 3a/4Ala(x-a)/4O3 wherein denotes a vacancy, y is greater than zero and less than about 0.6, a is from about 0.01 to about 0.06 and x is from 0.02 to about 0.10 with the proviso that x is greater than or equal to a.

Abstract: A first inventive microwave dielectric composition comprises a ceramic composition represented by AnR4Ti3+nO12+3n, where a is an alkaline earth metal element, R is a rare earth element and characterized in that a case satisfying A=Ba and a case of R=La is excluded and the compositional ratio n=1,2 or 4. A second inventive microwave dielectric composition comprises a ceramic composition represented by AXR4Ti3+XO12+3X, where A is an alkaline earth metal element, R is a rare earth element and characterized in that the compositional ratio X is within a range of 0.5<X<5 (excluding X=1,2, 4). A variety of small microwave dielectric resonators having excellent transmitting/receiving characters can be mass produced inexpensively from that composition.

Abstract: Tunable dielectric materials including an electronically tunable dielectric ceramic and a low loss glass additive are disclosed. The tunable dielectric may comprise a ferroelectric perskovite material such as barium strontium titanate. The glass additive may comprise boron, barium, calcium, lithium, manganese, silicon, zinc and/or aluminum-containing glasses having dielectric losses of less than 0.003 at 2 GHz. The materials may further include other additives such as non-tunable metal oxides and silicates. The low loss glass additive enables the materials to be sintered at relatively low temperatures while providing improved properties such as low microwave losses and high breakdown strengths.

Abstract: A ceramic powder including ceramic main component particles and additive component particles deposited on the surfaces of the main component particles. The mean particle size of the main component particles is made not more than 1.5 ?m, and the mean particle size of the additive component particles is made not more than 0.31 ?m. The content of the additive composition particles is made 0.1 to 5 wt % with respect to 100 parts by weight of the ceramic powder. The dispersibility of the additive component particles with respect to the main component particles is improved and the uniformity of the structure is promoted to suppress the occurrence of hetero phases. A multilayer ceramic electronic device having a high insulation breakdown voltage and long life even with a thickness of the dielectric layers of not more than 3 ?m are provided.

Abstract: A ceramic material suitable for use as a microwave band filter for telecommunications equipment comprises oxides of titanium, barium, neodymium, samarium, and optionally, bismuth, and containing, on an elemental weight basis: about 28 to about 31 weight % titanium, about 19 to about 21 weight % barium, about 11 to about 18 weight % samarium, about 7 to about 13 weight % neodymium, up to about 3 weight % of bismuth, and the remainder substantially being oxygen. The ceramic compositions have a resonant frequency, f, in the range of about 2000 MHz to about 2300 MHz, a quality factor, Q, of at least about 4000, a dielectric constant, K, in the range of about 50 to about 70, and a temperature coefficient of resonant frequency, Tf, in the range of about 0 ppm to about +20 ppm. Calcined metal oxide powders useful for preparing the microwave ceramic materials, a method of making the ceramic materials, and devices containing the ceramic materials are also described.

Abstract: Disclosed herein are a multilayer ceramic capacitor, a dielectric composition capable of sintering at a lower temperature and having a small variation in dielectric constant, a multilayer ceramic capacitor using the same, and a method thereof. The dielectric composition includes BaTiO3, MgCO3, Y2O3, Cr2O3, Mn2V2O7, and xBaO-yZrO2-zSiO2 acting as a sintering agent (where 0.1?x?0.3, 0.1?y?0.3 and 0.4?z?0.8, x+y+z=1), wherein when representing the composition with the formula aBaTiO3-bMgCO3-cY2O3-dCr2O3-e(Mn2V2O7)-f(xBaO-yZrO2-zSiO2), the ratio of the components satisfies the conditions of a=100, 0.1?b?3.0, 0.3?c?2.0, 0.05?d?0.2, 0.01?e?1.5, 0.5?f?3.0 based on the molar ratio. When manufacturing a multilayer ceramic capacitor of a higher capacitance, which is formed to have the thin layer structure of 4 ?m or less, short circuits between internal electrodes and the deterioration in capacitance due to massing of the electrodes into ball at the ends may be remarkably reduced.

Abstract: A method for manufacturing single crystal ceramic powder is provided. The method includes a powder supply step for supplying powder consisting essentially of ceramic ingredients to a heat treatment area with a carrier gas, a heat treatment step for heating the powder supplied to the heat treatment area at temperatures required for single-crystallization of the powder to form a product, and a cooling step for cooling the product obtained in the heat treatment step to form single crystal ceramic powder. The method provides single crystal ceramic powder consisting of particles with a very small particle size and a sphericity being 0.9 or higher.

Abstract: A low temperature sinterable dielectric ceramic composition and a multilayer ceramic chip capacitor. The dielectric ceramic composition is expressed by the general formula: aBaTiO3-bMgCO3-cY2O3-dCr2O3-eV2O5-f(xZrO2-y(K,Li)2O-zSiO2) (x+y+z=1; 0.05?x?0.18, 0.01?y?0.08, and 0.7.4?z?0.93); in which a, b, c, d, e and f are molar ratios; a=100, 1.0?b?2.0, 0.2?c?2.0, 0.02?d?0.3, 0.02?e?0.3, and 0.5?f<2. The multilayer ceramic chip capacitor is prepared using the dielectric ceramic composition. The dielectric composition according to the present invention can be sintered at a low temperature without decrease of a dielectric constant, making it possible to make ultra thin-layered dielectrics.

Abstract: A dielectric porcelain composition comprising Ba, Nd, Pr, Bi, Ti and at least one of Na and K and satisfying a condition that when the composition is expressed by composition formula: BaO—aNdO3/2—bPrO11/6—cBiO3/2—dTiO2—eAO1/2, wherein A is at least one of Na and K, and a, b, c, d and e represent a molar ratio, a, b, c, d and e are in respective ranges of 1.5?a?2.6, 0.02?b?1.00, 0.2?c?0.6, 4.5?d?5.5 and 0.02?e?0.30.

Abstract: Multilayer ceramic chip capacitors which satisfy X7R requirements and which are compatible with reducing-atmosphere sintering conditions so that non-noble metals such as nickel, copper, and alloys thereof may be used for internal and external electrodes are made in accordance with the invention. The capacitors exhibit desirable dielectric properties (high capacitance, low dissipation factor, high insulation resistance), excellent performance on highly accelerated life testing, and very good resistance to dielectric breakdown. The dielectric layers preferably contain BaTiO3 as the major component and Mn3O4 Y2O3, Ho2O3, CaCO3, SiO2, B2O3, Al2O3, MgO, and CaO as minor constituents. They are batched in a proportion that there are preferably present 99.00 to 98.5 wt. % BaTiO3, 0.336 to 0.505 wt. % Mn3O4, 0.198 to 0.296 wt. % Y2O3, 0.132 to 0.198 wt. % Ho2O3, 0.199 to 0.299 wt. % CaCO3, 0.057 to 0.085 wt. % SiO2, 0.039 to 0.058 wt. % B2O3, 0.018 to 0.027 wt. % Al2O3, 0.016 to 0.025 wt. % MgO and 0.005 to 0.007 wt.

Abstract: A dielectric ceramic includes a principal component which contains Ba, Ca and Ti and which has a perovskite structure represented by the general formula ABO3; additive components containing, for example, La and Mn; and a sintering aid, wherein crystal grains of the dielectric ceramic contain Ca, and the intergranular variation in the average Ca concentration within each grain is about 5% or more, in terms of CV value, or the ratio of the number of crystal grains in which the intragranular variation in the Ca concentration is about 5% or more, in terms of CV value, to the total number of crystal grains containing Ca is about 10% or more. A monolithic ceramic capacitor fabricated using the dielectric ceramic is also disclosed.

Abstract: Various high quality microwave dielectric composite compositions are prepared by replacing a part of Ba, La or Ti with another element in a dielectric material represented by BanLa4Ti3+nO12+3n. A first embodiment thereof comprises a ceramic composition represented by (Ba1−xAx)nLa4Ti3+nO12+3n, wherein A is an alkaline earth metal element except Ba, and 0.5<n<5 and 0<x<0.5, which is a composite composition being homologous as the former dielectric material and having a chemical formula obtained by replacing a part of Ba with an alkaline earth metal element except Ba. Similarly, a part of La and a part of Ti can be replaced with a rare earth element except La and an element except Ti, respectively.

Abstract: It is an object of the invention to provide a dielectric ceramic composition which enables its firing temperature to be lowered and which has an excellent electrical properties, particularly temperature dependence of resonance frequencies. A dielectric ceramic composition according to the invention comprises an oxide of a barium titanate family having a composition formula represented as BaTixO2x+1 (3.5≦x≦5.0); a first chemical element group consisting of at least one kind of alkaline-earth metals, silicon, zinc, aluminium, titanium, copper, bismuth and molybdenum; and a second chemical element group consisting of at least one kind of alkali metals and boron. A weight ratio of a total of each chemical element in the first and second chemical element groups to the oxide (the total of each chemical element/the oxide) is between 45/55 and 65/35 inclusive when the ratio is determined by converting said each chemical element to its oxide.

Abstract: A first inventive microwave dielectric composition comprises a ceramic composition represented by AnR4Ti3+nO12+3n, where a is an alkaline earth metal element, R is a rare earth element and characterized in that a case satisfying A=Ba and a case of R=La is excluded and the compositional ratio n=1,2 or 4.

Abstract: Multilayer ceramic chip capacitors which satisfy X7R requirements and which are compatible with reducing-atmosphere sintering conditions so that non-noble metals such as nickel, copper, and alloys thereof may be used for internal and external electrodes are made in accordance with the invention. The capacitors exhibit desirable dielectric properties (high capacitance, low dissipation factor, high insulation resistance), excellent performance on highly accelerated life testing, and very good resistance to dielectric breakdown. The dielectric layers preferably contain BaTiO3 as the major component and Mn3O4, Y2O3, Ho2O3, CaCO3, SiO2, B2O3, Al2O3, MgO, and CaO as minor constituents. They are batched in a proportion that there are preferably present 99.00 to 98.5 wt. % BaTiO3, 0.336 to 0.505 wt. % Mn3O4, 0.198 to 0.296 wt. % Y2O3, 0.132 to 0.198 wt. % Ho2O3, 0.199 to 0.299 wt. % CaCO3, 0.057 to 0.085 wt. % SiO2, 0.039 to 0.058 wt. % B2O3, 0.018 to 0.027 wt. % Al2O3, 0.016 to 0.025 wt. % MgO and 0.005 to 0.007 wt.

Abstract: A ceramic material suitable for use as a microwave band filter for telecommunications equipment comprises oxides of titanium, barium, neodymium, samarium, and optionally, bismuth, and containing, on an elemental weight basis: about 28 to about 31 weight % titanium, about 19 to about 21 weight % barium, about 11 to about 18 weight % samarium, about 7 to about 13 weight % neodymium, up to about 3 weight % of bismuth, and the remainder substantially being oxygen. The ceramic compositions have a resonant frequency, f, in the range of about 2000 MHz to about 2300 MHz, a quality factor, Q, of at least about 4000, a dielectric constant, K, in the range of about 50 to about 70, and a temperature coefficient of resonant frequency, Tf, in the range of about 0 ppm to about +20 ppm. Calcined metal oxide powders useful for preparing the microwave ceramic materials, a method of making the ceramic materials, and devices containing the ceramic materials are also described.

Abstract: A high-frequency dielectric ceramic composition that has a high Q-factor as well as a large relative dielectric constant, and in which temperature coefficient of the resonant frequency (&tgr;r) can be controlled to around 0 ppm/° C. is provided. The dielectric ceramic composition has a general formula of Ba[(Sn&agr;Zr1-&agr;)xMgy(Nb&bgr;Ta1-&bgr;)z]vOw, wherein molar ratios x, y, and z are within an area defined by points A (0.30, 0.22, 0.48), B (0.60, 0.12, 0.28), C (0.60, 0.14, 0.26), and D (0.30, 0.25, 0.45) in a ternary diagram, and are not on the line between points A and D, x+y+z=1.00, 0.5≦&agr;≦1.0, 0≦&bgr;<1.0, 0.98≦v≦1.03, and w is a positive value to keep the composition electroneutral.

Abstract: A dielectric ceramic composition, comprising a main component including barium titanate, a fourth subcomponent including an oxide of R1 (note that R1 is at least one kind selected from a first element group composed of rare-earth elements having a effective ionic radius of less than 108 pm when having a coordination number of nine), and a fifth subcomponent including an oxide of R2 (note that R2 is at least one kind selected from a second element group composed of rare-earth elements having a effective ionic radius of 108 pm to 113 pm when having a coordination number of nine). According to the composition, a dielectric ceramic composition having excellent reducing resisting property at firing, excellent temperature dependence of capacitance after firing, and improved accelerated lifetime of insulation resistance can be provided.

Abstract: The dielectric composition contains a mixture of a ceramic composition containing BaaREbTicO3, wherein RE represents a rare earth element, with 0.05≦a≦0.25, 0.525≦b≦0.70, 0.85≦c≦1.0, and 2a+3b+4c=6, and free from lead and bismuth, a glass composition, and a metal oxide. The glass composition preferably contains ZnO or MgO, SiO2, and at least 10% by weight of Li2O or TiO2. Preferably, the alkaline earth metal oxide is MgO. By preference, the glass composition essentially consists of 50-80% weight of SiO2, 5-25% weight of MgO, and optionally another alkaline earth metal oxide, and 10-25% by weight of Li2O, and is substantially free from boron. The dielectric composition can be sintered in the presence of Cu electrodes at a temperature below the melting point of Cu so as to manufacture an electronic device such as a ceramic multilayer element. After sintering, the dielectric composition has a relative dielectric constant of at least 55.

Abstract: Provided is a piezoelectric ceramic capable of improving its piezoelectric properties. The piezoelectric ceramic comprises a rhombohedral perovskite structure compound such as (Na0.5Bi0.5)TiO3, a tetragonal perovskite structure compound such as BaTiO3 and (K0.5Bi0.5)TiO3 and an orthorhombic perovskite structure compound such as NaNbO3, KNbO3 and CaTiO3, or the rhombohedral perovskite structure compound, the tetragonal perovskite structure compound and a cubic perovskite structure compound such as SrTiO3. Three kinds of perovskite structure compounds having different crystal structures are comprised, so that the piezoelectric properties can be improved. The three kinds of compounds may perfectly form a solid solution or not.

Abstract: The present invention provides a production method of spherical oxide powder which includes a feeding step in which a granular powder composed of an oxide composition is fed into a combustion flame together with a carrier gas; a melting step in which said fed granular powder is melted in said combustion flame to obtain a melt; and a solidifying step in which said melt is solidified by being moved and placed outside said combustion flame.

Abstract: A nonreducing dielectric ceramic comprising a (Sr, Ca)(Ti, Zr)O3-based perovskite principal crystal phase containing 55 mole percent or more of SrTiO3 and whose powder CuK&agr; X-ray diffraction pattern exhibits a ratio of less than 5% of the maximum peak intensity of the accessory crystal phases being the other crystal phases to the intensity of the maximum peak of the perovskite crystal phase, which is present at 2&thgr;=25° to 35°. This strontium titanate-based nonreducing dielectric ceramic has a high relative dielectric constant of 150 or more, a low third-order harmonic distortion ratio, and an excellent reliability in a high temperature-loading test. Accordingly, it is advantageously used for forming dielectric ceramic layers of a monolithic ceramic capacitor.

Abstract: An object of the present invention is to provide a dielectric composition for firing at a low temperature having a high dielectric constant ∈ r, a high Q value, and a low temperature coefficient &tgr; f of the resonance frequency. A dielectric composition for firing at low temperatures comprises a main composition of x.BaO-y.TiO2-z1.Nd2O3-z2.La2O3-z3.Sm2O3-t.Bi2O3 (x+y+z 1+z 2+z 3+t=1 ; 0.070≦x≦0.300; 0.385≦y ≦0.844; 0.010≦z1≦0.130; 0.000≦z2≦0.120; 0.000≦z3≦0.120; 0.075<t≦0.185), and a glass component containing 0.1 weight percent or more of B2O3 in an amount of 0.05 to 20 weight parts with respect to 10 weight parts of the main composition.

Abstract: Multilayer ceramic chip capacitors which satisfy X5R (−55 to 85° C., &Dgr;C=±15%) requirements and which are compatible with reducing atmosphere sintering conditions so that base metals such as nickel and nickel alloys may be used for internal electrodes are made in accordance with the invention. The multilayer ceramic chip capacitor comprises alternately staked, dielectric ceramic layers and internal electrode layers wherein dielectric ceramic layers comprise per 100 mol of BaTiO3, BaTiO3; MgCO3: 0.2 to 3.0 mol; at least one selected from Y2O3, Ho2O3, Dy2O3 and Yb2O3: 0.05 to 1.5 mol; Cr2O3: 0.1 to 1.5 mol; BaxCa(1−x)SiO3 (provided that 0≦x≦1): 0.2 to 3.0 mol; and Mn2V2O7: 0.01 to 1.5 mol. The multilayer ceramic chip capacitor of the present invention has a high dielectric constant, satisfies X5R characteristics can be sintered at a low temperature of 1,200 to 1,250° C.

Abstract: Electronically tunable dielectric materials having favorable properties are disclosed. The electronically tunable materials include an electronically tunable dielectric phase such as barium strontium titanate in combination with at least two additional metal oxide phases. The additional metal oxide phases may include, for example, oxides of Mg, Si, Ca, Zr, Ti and Al. The electronically tunable materials may be provided in bulk, thin film and thick film forms for use in devices such as phased array antennas, tunable filters and the like. The materials are useful in many applications, including the area of radio frequency engineering and design.

Abstract: A dielectric ceramic composition comprising a main component composed of barium titanate, a first subcomponent including an oxide of AE (note that AE is at least one element selected from Mg, Ca, Ba and Sr), and a second subcomponent including an oxide of R (note that R is at least one element selected from Y, Dy, Ho and Er), wherein ratios of the subcomponents to 100 moles of the main component are, the first subcomponent: 0 mole<the first subcomponent<0.1 mole, and the second subcomponent: 1 mole<the second subcomponent<7 moles. According to the composition, a high specific permittivity can be attained, an insulation resistance lifetime can be maintained, the capacity-temperature characteristic can satisfy the X8R characteristic of the EIA standard, and firing in a reducing atmosphere can be realized.

Abstract: The present invention relates to a temperature-stable dielectric ceramic composition for multilayer ceramic capacitors. The said dielectric composition comprises barium titanate and additives, wherein the barium titanate ranges from 94 to 99 mol % of the said composition, and the additives range from 1 to 6 mol % of the said composition. The additives comprise oxides of Mg, Ca, Ba, Si and Mn, and oxides of one or more elements selected from the group consisting of Co, Sr, Ti and Fe, and an oxide of Re, or carbonates, hydroxide, oxalates, acetates or nitrates of the above elements. Re represents one or more elements selected from Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu. After being sintered at 1200° C. to 1350° C. under reducing atmosphere, the room-temperature dielectric constant of the composition is 2000 to 3500 and its temperature coefficient of capacitance satisfies X7R characteristic (EIA standards).

Abstract: A ceramic mass includes one ceramic material and at least a second different ceramic material. Glass material is arranged between the ceramic materials. The glass material reduces the sintering temperature of the ceramic mass and prevents the various ceramic materials from forming a mixed crystal when the ceramic mass is sintered. The ceramic mass is suitable for use in LTCC technology for the production of capacitors whose permittivity is dependent upon a specific temperature range.