Abstract: When local heating by use of laser sealing or the like is applied, the bonding strength between glass substrates and a sealing layer is improved to provide an electronic device having increased reliability. An electronic device includes a first glass substrate, a second glass substrate, and a sealing layer to seal an electronic element portion disposed between these glass substrates. The sealing layer is a layer obtained by locally heating a sealing material by an electromagnetic wave, such as laser light or infrared light, to melt-bond the sealing material, the sealing material containing sealing glass, a low-expansion filler and an electromagnetic wave absorber. In the first and second glass substrates, each reacted layer is produced to have a maximum depth of at least 30 nm from an interface with the sealing layer.

Abstract: A crystallizing glass solder for high-temperature applications, which is free of PbO and contains, in % by weight on an oxide basis: 45% to 60% of BaO; 25% to 40% of SiO2; 5% to 15% of B2O3; 0 to <2% of Al2O3; 2 to 7.0, preferably 4.4 to 7.0%, of MgO; and at least one alkaline earth metal oxide from the group consisting of MgO, CaO and SrO, wherein CaO is 0% to 5% and the sum of the alkaline earth metal oxides MgO, CaO and SrO is 2% to 15%. Preferred embodiments of the glass solder contain from 3 to 15 wt. % of Y2O3 and have low porosity and high stability with respect to a moist fuel gas environment.

Abstract: Certain example embodiments of this invention relate to a frit slurry paste for use in assemblies (e.g., a vacuum insulated glass unit or a plasma display panel), and methods of making the same. Frit powder, binder material, and a water-based solvent are mixed together to form an intermediate mixture. The frit powder is substantially lead free, and the water-based solvent is provided at a first temperature. Additional water-based solvent is added to the intermediate mixture to form a frit slurry paste. The additional water-based solvent is provided at a second temperature, with the second temperature being lower than the first temperature. The binder material is provided at a concentration of 0.001%-20% by weight with respect to the frit slurry paste or the frit slurry paste absent the frit powder. The frit slurry paste has a bulk viscosity of 2,000-200,000 cps.

Abstract: Provided is a glass composition that has a low reactivity with the constituent materials forming a solid oxide fuel cell while having a thermal expansion coefficient suitable for sealing a solid oxide fuel cell, and a glass composition and sealing material that are suitable for sealing a solid oxide fuel cell. The present invention, which relates to a sealing glass composition, is a sealing glass composition used for sealing a solid oxide fuel cell, characterized by having a composition ratio of, expressed in terms of oxide, 40 to 55% by mass of SiO2, 0 to 5.0% by mass of Al2O3, 0 to 8.0% by mass of B2O3, 20 to 30% by mass of MgO, and 10 to 24% by mass of CaO, wherein a total of the MgO and the CaO is 40 to 54% by mass.

Abstract: The present invention aims at providing a lead-free glass composition that can be soften and flowed at a firing temperature that is equal to or lower than that of conventional low melting point lead glass. Furthermore, the present invention aims at providing a lead-free glass composition having fine thermal stability and fine chemical stability in addition to that property. The lead-free glass composition according to the present invention is characterized by comprising at least Ag2O, V2O5 and TeO2 when the components are represented by oxides, wherein the total content ratio of Ag2O, V2O5 and TeO2 is 75 mass % or more. Preferably, the lead-free glass composition comprises 10 to 60 mass % of Ag2O, 5 to 65 mass % of V2O5, and 15 to 50 mass % of TeO2.

Abstract: The present invention is a composite encapsulating material which consists of silicon dioxide, aluminum oxide, yttrium oxide and zinc oxide and has glass transition temperature between 694° C. and 833° C. as well as expansion coefficient between 7.0 and 8.5×10?6/° C. The ratio of the number of moles of silicon dioxide plus aluminum oxide (yttrium oxide or zinc oxide) to the total number of moles is 41.88˜62.22% (10.48˜26.67% or 11.11˜47.64%); the ratio of the number of moles of aluminum oxide to the total number of moles is 5.23˜17.78%. The ratios of aluminum oxide to silicon dioxide, yttrium oxide to silicon dioxide, and zinc oxide to silicon dioxide are 0.14˜0.40, 0.29˜0.60, and 0.25˜1.30, respectively.

Abstract: An antimony-free glass comprising TeO2 and/or Bi2O3 suitable for use in a frit for producing a hermetically sealed glass package is described. The hermetically sealed glass package, such as an OLED display device, is manufactured by providing a first glass substrate plate and a second glass substrate plate and depositing the antimony-free frit onto the first substrate plate. OLEDs may be deposited on the second glass substrate plate. An irradiation source (e.g., laser, infrared light) is then used to heat the frit which melts and forms a hermetic seal that connects the first glass substrate plate to the second glass substrate plate and also protects the OLEDs disposed therein. The antimony-free glass has excellent aqueous durability, good flow, and low glass transition temperature.

Abstract: A sealing glass composition includes from about 10 molar percent to about 30 molar percent barium oxide, from about 15 molar percent to about 30 molar percent aluminum oxide, from about 40 molar percent to about 60 molar percent boron oxide and from about 1 molar percent to about 20 molar percent yttrium oxide. Methods for preparing the sealing glass and a sodium battery cell are also provided.

Abstract: The glass-ceramic joining material, which is suitable for bonding or joining at low processing temperatures, especially less than 800° C., is composed of a BaO—SiO2—CaO—B2O3—Al2O3 system and has a coefficient of thermal expansion ?(20-300)?9.5·10?6 K?1.

Abstract: A vitreous or glass-ceramic jointing material, which has a coefficient of thermal expansion ?(20-750) of ?7·10?6 K?1 and is free of BaO and SrO except for at the most impurities and is suitable for producing joint connections between chromium-containing alloys or chromium-containing steels.

Abstract: The invention includes a composition for sealing agent, generally in the form of glass frit, lead-free, comprising by weight over the total weight of the composition: 30-80% Bi2O3; 2-10% ZnO; 2-10% B2O3; 0-5% Na2O; 1-10% SiO2; 1-8% Al2O3; 0-7% BaO; and 0-8% MgO. The composition for sealing agent as defined above can be added with a filler in a quantity up to 20% by weight over the total weight of the resulting mixture. The invention also includes a sealing paste containing the composition for sealing agent, the optional filler, an organic binder and optionally an organic solvent. The invention also includes methods for producing and using the composition for sealing agent and the sealing paste, as well as an electronic device sealed with the sealing paste.

Abstract: A low softening point glass composition, which is substantially free from lead, bismuth and antimony and comprises oxides of vanadium, phosphorous, tellurium and iron, a softening point of the composition being 380° C. or lower.

Abstract: A method for sealing an organic light emitting diode (OLED) device is disclosed wherein the OLED device comprises a color filter. A color filter is deposited on a first glass plate or substrate and a glass-based frit is then deposited in a loop around the color filter, The deposited fit loop is then heated by electromagnetic energy to evaporate organic constituents and to sinter the fit in a pre-sintering step. An OLED device may then be assembled by positioning a second glass plate comprising an organic light emitting material deposited thereon in overlying registration with the first glass plate, with the color filer and the organic light emitting material positioned between the plates. The fit is then heated with a laser to form a hermetic seal between the first and second glass plates.

Abstract: An antimony-free glass suitable for use in a frit for producing a hermetically sealed glass package is described. The hermetically sealed glass package, such as an OLED display device, is manufactured by providing a first glass substrate plate and a second glass substrate plate and depositing the antimony-free frit onto the first substrate plate. OLEDs may be deposited on the second glass substrate plate. An irradiation source (e.g., laser, infrared light) is then used to heat the frit which melts and forms a hermetic seal that connects the first glass substrate plate to the second glass substrate plate and also protects the OLEDs. The antimony-free glass has excellent aqueous durability, good flow, low glass transition temperature and low coefficient of thermal expansion.

Abstract: The ceramic product provided by the present invention is provided with at least two ceramic members bonded to each other, and the bond parts between these ceramic members bonded to each other are formed from glass having leucite crystals precipitated within the glass matrix.

Abstract: Provided is a refractory filler powder, comprising particles, each of which has precipitates of willemite and gahnite.

Abstract: Hot-melt sealing glass compositions that include one or more glass frits dispersed in a polymeric binder system. The polymeric binder system is a solid at room temperature, but melts at a temperature of from about 35° C. to about 90° C., thereby forming a flowable liquid dispersion that can be applied to a substrate (e.g., a cap wafer and/or a device wafer of a MEMS device) by screen printing. Hot-melt sealing glass compositions according to the invention rapidly re-solidify and adhere to the substrate after being deposited by screen printing. Thus, they do not tend to spread out as much as conventional solvent-based glass frit bonding pastes after screen printing. And, because hot-melt sealing glass compositions according to the invention are not solvent-based systems, they do not need to be force dried after deposition.

Abstract: A glass composition substantially free from lead and bismuth and containing vanadium oxide and phosphor oxide as main ingredients, wherein the sintered glass of the glass composition exhibits 109 ?cm or more at 25° C.

Abstract: A lead-free glass material for sealing organic EL elements is provided with which satisfactory sealing quality is obtained through laser sealing without requiring the addition of a metallic powder. The lead-free glass material for sealing organic EL elements has a glass composition which comprises, in terms of mol %, 30-60% V2O5, 5-20% ZnO, 5-20% BaO, 15-40% TeO2, 0-7% Nb2O5, 0-7% Al2O3, 0-5% SiO2, 0-5% MgO, 0-5% Sb2O3, 0-4% CuO, and 0-4% SnO and in which Nb2O5+Al2O3 is 0.5-10%, SiO2+MgO+Sb2O3 is 0-5%, and CuO+SnO is 0-4%. The glass material has low-temperature softening properties, melt stability, and a low coefficient of thermal expansion and is inhibited from thermally adversely affecting organic EL elements The glass material can attain high sealing properties and high sealing strength in high yield.

Abstract: Provided is a glass composition that has a low reactivity with the constituent materials forming a solid oxide fuel cell while having a thermal expansion coefficient suitable for sealing a solid oxide fuel cell, and a glass composition and sealing material that are suitable for sealing a solid oxide fuel cell. The present invention, which relates to a sealing glass composition, is a sealing glass composition used for sealing a solid oxide fuel cell, characterized by having a composition ratio of, expressed in terms of oxide, 40 to 55% by mass of SiO2, 0 to 5.0% by mass of Al2O3, 0 to 8.0% by mass of B2O3, 20 to 30% by mass of MgO, and 10 to 24% by mass of CaO, wherein a total of the MgO and the CaO is 40 to 54% by mass.

Abstract: A method is described herein for controlling the oxygen level within an oven while sintering a frit to a glass plate where the sintered frit and glass plate are subsequently sealed to another glass plate to form a sealed glass package. Examples of the sealed glass package include a light-emitting device (e.g., organic light emitting diode (OLED) device), a photovoltaic device, a food container, and a medicine container.

Abstract: Certain example embodiments relate to seals for glass articles. Certain example embodiments relate to a composition used for sealing an insulted glass unit. In certain example embodiments the composition includes vanadium oxide, barium oxide, zinc oxide, and at least one additional additive. For instance, another additive that is a different metal oxide or different metal chloride may be provided. In certain example embodiments, a composition may be combined with a binder solution that substantially or completely burns out by the time the composition is melted. In certain example embodiments, a CTE filler is included with a frit material. In certain example embodiments, a vacuum insulated glass unit includes first and second glass substrates that are sealed together with a seal that includes the above-described composition.

Abstract: Hot-melt sealing glass compositions that include one or more glass frits dispersed in a polymeric binder system. The polymeric binder system is a solid at room temperature, but melts at a temperature of from about 35° C. to about 90° C., thereby forming a flowable liquid dispersion that can be applied to a substrate (e.g., a cap wafer and/or a device wafer of a MEMS device) by screen printing. Hot-melt sealing glass compositions according to the invention rapidly re-solidify and adhere to the substrate after being deposited by screen printing. Thus, they do not tend to spread out as much as conventional solvent-based glass frit bonding pastes after screen printing. And, because hot-melt sealing glass compositions according to the invention are not solvent-based systems, they do not need to be force dried after deposition.

Abstract: Disclosed is a glass composition which is adapted to use in providing a hermetic seal between a metal and a ceramic, a metal and a metal, and a ceramic and a ceramic, to form crystallized glass having high strength and high thermal expansion which allow it to be used at high temperatures of 950° C. and over. The glass composition is substantially free of alkali metals, and contains, as calculated as oxide, 15-30 mass % of SiO2, 0-5 mass % of Al2O3, 20-35 mass % of B2O3, 10-25 mass % of CaO, 25-40 mass % of MgO, 3-8 mass % (3.0% excluded) of ZrO2, and 0-3 mass % of CeO2, wherein the crystallized glass which is formed by firing a glass powder made of the glass composition at a temperature of 850-1050° C. has a thermal expansion coefficient of 90-110×10?7/° C. at 50-550° C. and flexural strength of not less than 80 MPa.

Abstract: Provided is a cover coating composition for a glass lining comprising a frit constituting the composition which mainly includes 65 to 75 mol % of SiO2, 2 to 8 mol % of ZrO2, 10 to 22 mol % of R2O where R represents Li, K, or Cs, and 2 to 12 mol % of R?O where R? represents Mg, Ca, Sr, or Ba, and the frit is free of Na2O, and said cover coating composition for a glass lining may further contain a metal fiber.

Abstract: Certain example embodiments relate to seals for glass articles. Certain example embodiments relate to a composition used for sealing an insulted glass unit. In certain example embodiments the composition includes vanadium oxide, barium oxide, zinc oxide, and at least one additional additive. For instance, another additive that is a different metal oxide or different metal chloride may be provided. In certain example embodiments, a composition may be combined with a binder solution that substantially or completely burns out by the time the composition is melted. In certain example embodiments, a CTE filler is included with a frit material. In certain example embodiments, a vacuum insulated glass unit includes first and second glass substrates that are sealed together with a seal that includes the above-described composition.

Abstract: The invention relates to the use of and method of forming Low Temperature Cofired Ceramic (LTCC) circuits for high frequency applications. Furthermore, the invention relates to the novel LTCC thick film compositions and the structure itself.

Abstract: The present invention relates to a self-healing vitreous composition containing a particulate vandium additive, to a method for preparing same, and to the use thereof as a self-healing material, in particular for making seals in devices operating at a high temperature such as fuel oils and steam electrolyzers.

Abstract: An antimony-free glass suitable for use in a frit for producing a hermetically sealed glass package is described. The hermetically sealed glass package, such as an OLED display device, is manufactured by providing a first glass substrate plate and a second glass substrate plate and depositing the antimony-free frit onto the first substrate plate. OLEDs may be deposited on the second glass substrate plate. An irradiation source (e.g., laser, infrared light) is then used to heat the frit which melts and forms a hermetic seal that connects the first glass substrate plate to the second glass substrate plate and also protects the OLEDs. The antimony-free glass has excellent aqueous durability, good flow, low glass transition temperature and low coefficient of thermal expansion.

Abstract: A lead-free glass for covering electrodes including, as represented by mass % based on the following oxides, from 30 to 50% of B2O3, from 21 to 25% of SiO2, from 10 to 35% of ZnO, from 7 to 14% in total of K2O and either one or both of Li2O and Na2O, from 0 to 10% of Al2O3, and from 0 to 10% of ZrO2, wherein when it contains at least one component selected from the group consisting of MgO, CaO, SrO and BaO, the total of their contents is at most 5%, and when the molar fractions of Li2O, Na2O and K2O are represented by l, n and k, respectively, l is at most 0.025, and l+n+k is from 0.07 to 0.17.

Abstract: To provide a glass containing little B2O3, whereby when its powder is fired, its thermal expansion curve does not have an inflection point, a non-lead glass is provided containing, as represented by mol % based on the following oxides, from 35 to 41.5% of SiO2, from 8 to 25% of MgO, more than 27 to 35% of CaO, from 0 to 2% of SrO, from 0 to 4% of BaO, from 5 to 15% of ZnO and from 4.5 to 10% of Al2O3, wherein the total content of these components is at least 97%, and when SrO and BaO are contained, the total content of SrO and BaO is at most 2%; as well as a non-lead glass containing, as represented by mol % based on the following oxides, from 39.5 to 41.5% of SiO2, from 10 to less than 13% of MgO, from 18 to 22% of CaO, more than 12 to 15% of SrO, from 0 to 1% of BaO, from 6 to 11% of ZnO and from 4.5 to 7% of Al2O3, wherein the total content of these components is at least 97%.

Abstract: A method is described herein for sintering a frit to a glass plate where the sintered frit and glass plate are subsequently sealed to another glass plate to form a sealed glass package. Examples of the sealed glass package include a light-emitting device (e.g., organic light emitting diode (OLED) device), a photovoltaic device, a food container, and a medicine container.

Abstract: Disclosed are cements for ceramic honeycomb bodies. Such cements can be applied to a fired ceramic honeycomb body then fired, or can be applied to an unfired (green) honeycomb body and co-fired with the green honeycomb body. The cement can also be used to plug one or more cells in a honeycomb body, wherein the cement can be inserted into a green or a fired ceramic honeycomb body, then fired. Also disclosed are methods of manufacturing a ceramic honeycomb article with the cement.

Abstract: The present invention relates to a sealing glass composition for an intermediate-temperature planar SOFC, and a composition herein comprises a mixture of BaO, Al2O3, B2O3 and SiO2 in a particular mixing ratio and a metal oxide such as CeO2, Fe2O3, Mn2O3 and Cr2O3, thereby enabling the SOFC to efficiently operate at an intermediate temperature. The composition for a planar SOFC satisfies thermal properties, mechanical properties and electric properties that are required as a sealing glass for an intermediate-temperature SOFC, and also prevents the mixing between fuel gas and air, thereby being useful for the commercialization of SOFCs.

Abstract: Transition metal doped Sn phosphate glass compositions and methods of making transition metal doped Sn phosphate glass compositions are described which can be used for example, in sealing applications.

Abstract: A crystallizing glass solder for high-temperature applications, containing, in % by weight on an oxide basis: 45% to 60% of BaO, 25% to 40% of SiO2, 5% to 15% of B2O3, 0 to <2% of Al2O3, and at least one alkaline earth metal oxide from the group consisting of MgO, CaO and SrO, wherein CaO is 0% to 5% and the sum of the alkaline earth metal oxides MgO, CaO and SrO is 0% to 20%, preferably 2% to 15%. The glass solder is preferably free from TeO2 and PbO. Preferred embodiments of the glass solder contain from 3 to 15 wt. % of Y2O3 and have low porosity and high stability with respect to a moist fuel gas environment.

Abstract: A glass bonding material contains vanadium and phosphor as main glass components, and comprises in amounts converted as oxides of the elements in the components, 45 to 60% by weight of V2O5, 15 to 30% by weight of P2O5, 5 to 25% by weight of BaO, or contains a glass comprising at least vanadium, phosphor, barium and antimony, wherein the glass comprises in amounts converted as oxides, 15 to 35% by weight of BaO and Sb2O3 in total, and a weight ratio of BaO/Sb2O3 or Sb2O3/BaO is 0.3 or less.

Abstract: A sealing glass of a low melting point phosphate glass composition contains 15 to 35% of BaO and Sb2O3 (in total) and the ratio by weight of BaO to Sb2O3 or Sb2O3 to BaO is 0.3 or less. Particularly the transition metal is vanadium and the glass contains V2O5 of 45 to 60 wt % as vanadium oxide and P2O5 of 15 to 30 wt % as phosphorus oxide. The bonding material is a mixture of a filler and a vanadate-phosphate glass that contains V2O5 of 45 to 60%, P2O5 of 20 to 30%, BaO of 5 to 15%, TeO2 of 0 to 10%, Sb2O3 of 5 to 10%, and WO3 of 0 to 5%. The particle size of the filler is in the range of 1 to 150 ?m and the ratio of filler is 80% by volume or less of the adhesive glass.

Abstract: A hermetically sealed glass package and method for manufacturing the hermetically sealed glass package are described herein using an OLED display as an example. Basically, the hermetically sealed OLED display is manufactured by providing a first substrate plate and a second substrate plate and depositing a frit onto the second substrate plate. OLEDs are deposited on the first substrate plate. An irradiation source (e.g., laser, infrared light) is then used to heat the frit which melts and forms a hermetic seal that connects the first substrate plate to the second substrate plate and also protects the OLEDs. The frit is glass that was doped with at least one transition metal and possibly a CTE lowering filler such that when the irradiation source heats the frit, it softens and forms a bond. This enables the frit to melt and form the hermetic seal while avoiding thermal damage to the OLEDs.

Abstract: Sealing materials for use with membrane supports, and in particular to sealing materials that can be used to form a glassy coating on the exterior surface of a membrane support to prevent gases from entering or exiting the support via the support's exterior walls.

Abstract: A coating for a reinforcing material, such as metal rebar, that increases the adhesion between the reinforcing material and a matrix, such as a cement-based mortar or concrete, in which the reinforcing material is embedded. The coating may comprise a glass frit mixed with a refractory material, such as dry Type I-II portland cement. The coating is bonded, typically by heat, to the surface of the reinforcing material. The reaction of the refractory component, e.g., portland cement, when the reinforcement, e.g., metal re-bar, is embedded in a matrix, e.g., fresh mortar or concrete, prevents the formation of soft precipitates at the interface of the matrix and its reinforcement. One coating comprises portland cement Type I-II combined with a commercial alkali-resistant glass frit. This coating is applied to a steel rebar and fired to bond to the rebar.

Abstract: A sealing glass for an energy storage device is provided. The sealing glass includes silicon dioxide, boron oxide, aluminum oxide, sodium oxide and zirconium oxide. Methods for preparing the sealing glass and the energy storage device incorporating the sealing glass are also provided.

Abstract: A seal structure is provided for an energy storage device. The seal structure includes a sealing glass joining an ion-conducting first ceramic to an electrically insulating second ceramic. The sealing glass has a composition that includes about 48 weight percent silica, about 20 weight percent to about 25 weight percent boria, about 20 weight percent to about 24 weight percent alumina, and about 8 weight percent to about 12 weight percent sodium oxide based on the total weight of the sealing glass composition. A method for making the seal structure is provided. An article comprising the seal structure is also provided.

Abstract: The present invention relates to a rosamine derivative compound, as described herein, having the following structure: Also disclosed are methods of making such compounds and for using them for detection and imaging.

Abstract: A bonding glass containing V2O5: 25 to 50 wt %, TeO2: 20 to 40 wt % and BaO: 5 to 30 wt %, and not containing lead.

Abstract: A sealing material for solid oxide fuel cells is provided, which is composed of around 60% to 80% by weight of glass, around 20% to 30% by weight of alcohol, around 0.5% to 3% by weight of ethyl celluloid as a binder, and around 0.01% to 0.1% by weight of polyethylene glycol as a plasticizer.

Abstract: Sealing materials for use with membrane supports, and in particular to sealing materials that can be used to form a glassy coating on the exterior surface of a membrane support to prevent gases from entering or exiting the support via the support's exterior walls.

Abstract: A solid oxide fuel cell device includes layers of solid electrolyte, cathode plates, anode plates, a frame and a non-contaminating, electrochemically stable sealing material. The sealing material may have a CTE of about 95×10?7/° C. to about 115×10?7/° C. The sealing material may include from about 65 wt % to about 100 wt % of glass frit and from about 0 wt % to about 35 wt % of a filler material. The glass frit may include from about 0 mol % to about 43 mol % of a metal oxide expressed as RO wherein R comprises magnesium, calcium, strontium, barium, zinc and/or combinations thereof. The glass frit may also include from about 0 mol % to about 5 mol % Al2O3; from about 0 mol % to about 7 mol % TiO2; and from about 41 mol % to about 60 mol % SiO2.

Abstract: Hot-melt sealing glass compositions that include one or more glass frits dispersed in a polymeric binder system. The polymeric binder system is a solid at room temperature, but melts at a temperature of from about 35° C. to about 90° C., thereby forming a flowable liquid dispersion that can be applied to a substrate (e.g., a cap wafer and/or a device wafer of a MEMS device) by screen printing. Hot-melt sealing glass compositions according to the invention rapidly re-solidify and adhere to the substrate after being deposited by screen printing. Thus, they do not tend to spread out as much as conventional solvent-based glass frit bonding pastes after screen printing. And, because hot-melt sealing glass compositions according to the invention are not solvent-based systems, they do not need to be force dried after deposition.

Abstract: A ceramic compact having a patterned conductor is obtained by coating the patterned conductor with a slurry and then by hardening the slurry. The slurry is prepared by mixing a thermosetting resin precursor, a ceramic powder, and a medium. In the ceramic compact, an isocyanate- or isothiocyanate-containing gelling agent and a hydroxyl-containing polymer are reacted and hardened to produce a thermosetting resin. The hydroxyl-containing polymer is preferably a butyral resin, an ethylcellulose-based resin, a polyethyleneglycol-based resin, or a polyether-based resin.