Zinc Containing Patents (Class 501/26)
  • Publication number: 20090189126
    Abstract: Glass frits, conductive inks and articles having conductive inks applied thereto are described. According to one or more embodiments, glass frits with no intentionally added lead comprise TeO2 and one or more of Bi2O3, SiO2 and combinations thereof. One embodiment of the glass frit includes B2O3, and can further include ZnO, Al2O3 and/or combinations thereof. One embodiment provides for conductive inks which include a glass frit with no intentionally added lead and comprising TeO2 and one or more of Bi2O3, SiO2 and combinations thereof. Another embodiment includes articles with substrates such as semiconductors or glass sheets, having conductive inks disposed thereto, wherein the conductive ink includes glass frits having no intentionally added lead.
    Type: Application
    Filed: January 30, 2008
    Publication date: July 30, 2009
    Inventor: Robert Prunchak
  • Patent number: 7560401
    Abstract: Frits, obscuration enamel compositions including frits and automotive windshields having obscuration enamel compositions applied thereto are described. According to one or more embodiments, the obscuration enamel composition comprises a paste component and a frit component having Bi2O3, SiO2 and B2O3 and being substantially free of Na2O. In other embodiments, a reducing agent is included in the frit component. Obscuration enamels of some embodiments have a total solids content of at least 80% by weight.
    Type: Grant
    Filed: April 20, 2007
    Date of Patent: July 14, 2009
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Robert Prunchak, Matthew Sgriccia
  • Patent number: 7470640
    Abstract: The invention is directed to highly crystalline, frit-sintered glass-ceramic materials and seals made using them that are suitable for solid oxide fuel cell applications. The seals have a coefficient of thermal expansion in the range of 70-130×10?7° C., preferably 85-115×10?7° C. The glass-ceramic materials have a crystalline component and a glass component, the crystalline component being>50% of the glass-ceramic and the glass component being<50%. In one preferred embodiment the crystalline component is >75%. Regarding the crystalline component only,>50% of the crystals in the crystalline component of the glass-ceramic has a structure selected from the structural groups represented by walstromite, cyclowollastonite, ?-(Ca,Sr)SiO3, kalsilite, kaliophilite and wollastonite (the primary crystalline phase) and the remaining <50% of the crystalline component is at least one secondary crystalline phase.
    Type: Grant
    Filed: October 11, 2006
    Date of Patent: December 30, 2008
    Assignee: Corning Incorporated
    Inventors: Michael Edward Badding, Sasha Marjanovic, Linda Ruth Pinckney, Dell Joseph St Julien
  • Patent number: 7452607
    Abstract: Provided is a nonlead glass for covering an electrode, which comprises, in mol %, B2O3 15-65%, SiO2 2-38%, MgO 2-30%, MgO+CaO+SrO+BaO 5-45%, Li2O 1-15%, Li2O+Na2O+K2O 2-25% and others, and which comprises ZnO 0-15%. Provided is a nonlead glass for covering an electrode, which comprises, in mol %, B2O3 25-65%, SiO2 2-38%, MgO 2-30%, MgO+CaO+SrO+BaO 5-45%, Li2O+Na2O+K2O 2-25%, Al2O3 0-30, TiO 0-10% and ZnO 0-15%.
    Type: Grant
    Filed: November 21, 2007
    Date of Patent: November 18, 2008
    Assignee: Asahi Glass Company, Limited
    Inventors: Hitoshi Onoda, Yu Goshima, Yumiko Aoki
  • Patent number: 7439201
    Abstract: The invention is directed to lead-free glass frit compositions that can be used as sealing frits, the compositions being a blend of: (1) at least one of two glass families which are SnO—ZnO—P2O5 and alkali-ZnO—P2O5 glasses; and (2) at least one cerammed filler material having a crystalline phase selected from the group consisting of beta-quartz, beta-eucryptite, cordierite, and beta-spodumene. The blends of the invention have flow characteristics that enable them to be used at sealing temperatures in the range of 450-550° C., and a CTE value in the range of 60-90×10?7/° C.
    Type: Grant
    Filed: August 29, 2006
    Date of Patent: October 21, 2008
    Assignee: Corning Incorporation
    Inventors: Melinda Ann Drake, Sasha Marjanovic, Lisa A. Lamberson, Robert Michael Morena
  • Patent number: 7425518
    Abstract: Provided with a glass composition including a network-former oxide composed of any one of or both of B2O3 and V2O5 of 20-80% by weight, ZnO of 0-60% by weight and BaO of 0-80% by weight, wherein at least one of ZnO and BaO is included as an essential ingredient. The present invention is a glass material for use in sealing, which is of lead-free series, can be used for sealing at a low processing temperature and within a wide temperature range, has a low thermal expansion coefficient, superior adhesion, superior sealing processability, superior adherence, superior chemical stability, superior strength and the like and comprises sufficient practical performance to substitute for lead glass.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: September 16, 2008
    Assignee: Yamato Electronic Co., Ltd.
    Inventors: Masahiro Yoshida, Yasuo Hatate, Tsugumitsu Sarata, Yoshimitsu Uemura, Tomoyuki Honda, Hiroyuki Fukunaga, Masahiro Iwashita
  • Patent number: 7410921
    Abstract: The invention is directed to highly crystalline, frit-sintered glass-ceramic compositions having a coefficient of thermal expansion in the range of 85-115×10?7° C. The primary crystal phases of the glass-ceramics of the invention possess a cyclosilicate structure. The glass-ceramic of the invention are useful as metal-to-metal, metal-to-ceramic and ceramic-to-ceramic sealing agents, and also as high-performance coating for metals and ceramics. In their broadest composition the glass-ceramic contain, in weight percent, 30-55% SiO2, 5-40% CaO, 0-50% BaO, 0.1-10% Al2O3, and 0-40% SrO, wherein the sum of CaO+BaO+SrO is in the range of 35-65 wt. %. Optionally, the glass-ceramic compositions may contain at least one from the group of >0-15 wt. % MgO and >0-10 wt. % ZnO. Also optionally, the glass ceramic compositions may contain >0-10 wt. % of at least one transition metal or rare earth metal oxide.
    Type: Grant
    Filed: February 20, 2007
    Date of Patent: August 12, 2008
    Assignee: Corning Incorporated
    Inventors: Linda Ruth Pinckney, Steven Alvin Tietje
  • Patent number: 7378361
    Abstract: The invention is directed to highly crystalline, frit-sintered glass-ceramic compositions having a coefficient of thermal expansion in the range of 85-115×10?7° C. The primary crystal phases of the glass-ceramics of the invention possess a cyclosilicate structure. The glass-ceramic of the invention are useful as metal-to-metal, metal-to-ceramic and ceramic-to-ceramic sealing agents, and also as high-performance coating for metals and ceramics.
    Type: Grant
    Filed: April 11, 2006
    Date of Patent: May 27, 2008
    Assignee: Corning Incorporated
    Inventors: Linda Ruth Pinckney, Steven Alvin Tietje
  • Publication number: 20080081103
    Abstract: The invention relates to a glass for dental applications which can be used as a glazing material of dental restorations and resists high temperatures, and thus does not tend to flow.
    Type: Application
    Filed: May 10, 2007
    Publication date: April 3, 2008
    Applicant: Ivoclar Vivadent AG
    Inventors: Diana Tauch, Harald Burke, Volker M. Rheinberger
  • Patent number: 7341964
    Abstract: The present invention provides glass compositions and glass coating systems for use on glass substrates in several industrial applications. It relates to a lead-free and cadmium-free glass enamel coating made primarily by utilizing at least one or more of lead-free and cadmium-free glass compositions comprising in weight percent from about 26% to about 63% SiO2, from about 2% to about 10.5% ZnO, from about 8% to about 20% B2O3, from about 0.1% to about 10% Bi2O3, up to about 12% Na2O, from about 0.1% to about 17% K2O, up to about 6% Li2O, from about 0.1% to about 22% of Ta2O5, from about 0.0% to about 22% of Nb2O5, up to about 8% from each of Al2O3, TiO2, ZrO2, BaO and SrO, from about 0.1% to about 7% Sb2O3, up to about 7% F2, up to about 4% from each of CaO, Mo2O3 and MgO, and from about 0.1% to about 4% of one or more of La2O3, Nd2O3, Pr2O3 and Ce2O3.
    Type: Grant
    Filed: July 28, 2005
    Date of Patent: March 11, 2008
    Assignee: Shepherd Color Company
    Inventor: Hasan B. Emlemdi
  • Patent number: 7326367
    Abstract: This invention is related to thick film conductor compositions comprising electrically conductive gold powder, one or more glass frit or ceramic oxide compositions and an organic vehicle. It is further directed to the composition's uses for LTCC (low temperature co-fired ceramic) tape, for fabrication of multilayer electronic circuits and in high frequency microelectronic applications.
    Type: Grant
    Filed: April 5, 2006
    Date of Patent: February 5, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Patricia J. Ollivier, Kenneth Warren Hang
  • Patent number: 7291573
    Abstract: A low melting glass, which contains substantially no lead and contains 70-90% of Bi2O3, 1-20% of ZnO, 2-12% of B2O3, 0.1-5% of Al2O3, 0.1-5% of CeO2, 0-5% of CuO, 0-0.2% of Fe2O3 and 0.05-5% of CuO+Fe2O3 in mass %, wherein a content of alkali metal oxides in the glass composition is less than 0.1%, and the glass does not crystallize by pre-baking at a sealing temperature or more, can be used for sealing later, and can suppress deterioration of a material such as platinum or platinum-rhodium to provide a stable melting operation for a long period.
    Type: Grant
    Filed: November 1, 2005
    Date of Patent: November 6, 2007
    Assignee: Asahi Techno Glass Corporation
    Inventor: Asahi Ide
  • Patent number: 7250178
    Abstract: An antimicrobial ceramic glazing composition comprising zinc borate for imparting antimicrobial characteristics to numerous ceramic products. A method for producing the antimicrobial glazing composition and ceramic products incorporating the antimicrobial glazing composition.
    Type: Grant
    Filed: January 21, 2005
    Date of Patent: July 31, 2007
    Assignee: Microban Products Company
    Inventors: Anders Olsson, Howard Wayne Swofford
  • Patent number: 7208430
    Abstract: A glass composition for covering electrodes of the present invention contains: 0 to 15 wt % SiO2; 10 to 50 wt % B2O3; 15 to 50 wt % ZnO; 0 to 10 wt % Al2O3; 2 to 40 wt % Bi2O3; 0 to 5 wt % MgO; 5 to 38 wt % CaO+SrO+BaO; 0 to 0.1 wt % Li2O+Na2O+K2O; 0 to 4 wt % MoO3; and 0 to 4 wt % WO3, and the total of the contents of MoO3 and WO3 is in the range of 0.1 to 8 wt %. The glass composition for covering electrodes of the present invention may contain: 0 to 2 wt % SiO2; 10 to 50 wt % B2O3; 15 to 50 wt % ZnO; 0 to 10 wt % Al2O3; 2 to 40 wt % Bi2O3; 0 to 5 wt % MgO; 5 to 38 wt % CaO+SrO+BaO; 0 to 4 wt % MoO3; and 0 to 4 wt % WO3, and the total of the contents of MoO3 and WO3 may be in the range of 0.1 to 8 wt %.
    Type: Grant
    Filed: August 16, 2006
    Date of Patent: April 24, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Shinya Hasegawa, Osamu Inoue, Seiji Toyoda
  • Patent number: 7087293
    Abstract: The present invention relates to a Cd-free and Pb-free glass composition comprising, based in mol %, 1–10% MO where M is selected from Ba, Sr, Ca and mixtures thereof, 5–30% MgO, 0.3–5% CuO, 0–2.5% P2O5, 0–2.5% ZrO2, 24–45% ZnO, 2–10% Al2O3, 35–50% SiO2 and 0.1–3% A2O where A is selected from the group of alkali elements and mixtures thereof wherein the glass composition is useful in thick paste dielectric materials which are compatible with AlN substrates.
    Type: Grant
    Filed: December 1, 2005
    Date of Patent: August 8, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Yong Cho, Kenneth Warren Hang
  • Patent number: 6946414
    Abstract: Glass-ceramic consisting of: SiO2: ?30-70 wt %; A12O3: 8-45 wt %; M2O:8-30 wt %; MO: 0-30 wt %; B2O3: 0-15 wt %; P2O5: 0-15 wt %; Zr2O: 0-12 wt %; TiO2: 0-12 wt %, wherein M is chosen in the group consisting of: Li, NA, K or mixture thereof; M? is chosen in the group consisting of: Be, Mg, Ca, Ba, Sr, Zn, Pb or mixture thereof are described.
    Type: Grant
    Filed: July 18, 2001
    Date of Patent: September 20, 2005
    Assignee: Colorbbia Italia S.p.A.
    Inventors: Marco Bitossi, Giovanni Baldi, Enrico Generali, Davide Settembre Blundo
  • Patent number: 6936556
    Abstract: The present invention provides partially crystallizing lead-free and cadmium-free glass enamel composition that fuse at low temperatures. Glass enamel compositions according to the present invention form predominantly bismuth titanate and optionally zinc titanate crystals upon firing. Preferably, glass enamel compositions according to the invention include a glass component that includes by weight from about 11% to about 52% SiO2, from 10.2% to about 40% TiO2, from about 5% to about 75% Bi2O3, up to about 8% B2O3, up to about 14% BaO+SrO, and up to about 45% by weight ZnO, where the sum of Bi2O3 and ZnO comprises from about 30% to about 85% of the glass component by weight.
    Type: Grant
    Filed: April 7, 2003
    Date of Patent: August 30, 2005
    Assignee: Ferro Corporation
    Inventors: Srinivasan Sridharan, George C. Korn, Jérôme Anquetil, Robert Blonski, Ivan H. Joyce
  • Patent number: 6911408
    Abstract: Objects of the present invention are: a lead-free enamel composition comprising finely divided glass particles, finely divided pigment particles and an organic binder, characterised in that the glass of said particles is a lead-free mineral glass, essentially having the composition below, which is expressed in percentages by weight of oxides: SiO2 45-60 CaO ?0-12 B2O3 ?0-10 BaO 13-27 Al2O3 ?6-17 ZnO ?3-17 Na2O 0- 7 MgO 0- 9 K2O 0-7 TiO2 0-2 Li2O 0- 7 ZrO2 0- 7 with Na2O + K2O + Li2O > 4 the enamel able to be obtained by firing of said composition; glass-ceramic articles, which are decorated with said enamel; and new lead-free mineral glasses.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: June 28, 2005
    Assignee: EuroKera
    Inventors: Lionel Beunet, Sebastien Hyvart, Fabrice Minier, Sophie Peschiera, Christophe Remy
  • Patent number: 6897171
    Abstract: The present invention refers to glass-ceramics consisting of the mixtures (I): ZrO2—SiO2—MeIIO, or (II) SiO2—MeIIIO2—MeIIO, wherein: MeII is chosen in the group consisting of: Ca, Ba, Mg, Zn or mixture thereof; MeIII is chosen in the group consisting of Al, B or mixtures thereof; each of the above said constituents being present in determined quantities; the invention refers also to a process for preparing the glass-ceramics above defined; porcelain stonewares and glazes containing them and their use for preparing ceramic items.
    Type: Grant
    Filed: June 12, 2003
    Date of Patent: May 24, 2005
    Assignee: Colorobbia Italia S.p.A.
    Inventors: Marco Bitossi, Giovanni Baldi, Davide Settembre Blundo, Enrico Generali
  • Patent number: 6881690
    Abstract: New decorating materials suitable for the decoration of ceramic materials comprise a lead-free glass flux and at least one pigment. The glass flux comprises two lead-free glass compositions. One of the two glass compositions comprises, in weight percent, SiO2: 45 to 60%, Al2O3: 5 to 20%, B2O3: 15 to 30%, and one or more alkali metal oxides: 5 to 10%, provided that Li2O is contained in an amount of 2% or more, with the proviso that the total amount of said oxides is 90% or more of the total weight of the composition. The other of the two glass compositions comprises, in weight percent, SiO2: 60 to 75%, Al203: 5 to 20%, at least one of MgO, CaO, ZnO: 5 to 20% in total, and one or more alkali metal oxides: 0.5 to 5%, provided that Li2O is contained in an amount of 0.5% or more, with the proviso that the total amount of said oxides is 90% or more of the total weight of the composition.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: April 19, 2005
    Assignee: Noritake Co., Ltd.
    Inventors: Takuya Kawamura, Hiromichi Hayashi, Nobuhiro Inoko
  • Patent number: 6849301
    Abstract: The present invention relates to a process for manufacturing recyclable black enamels that contain at least zinc, in which process glass forming materials comprising at least bismuth, silicon, boron and manganese are melted, at temperatures greater than about 900° C., and then a glass frit comprising at least zinc is added to the mixture obtained after this direct melting. The invention also relates to zinc-based recyclable black enamel compositions.
    Type: Grant
    Filed: August 13, 2002
    Date of Patent: February 1, 2005
    Assignee: Saint-Gobain Glass France
    Inventors: André Beyrle, Daniel Dages
  • Patent number: 6841495
    Abstract: A glass containing no lead and comprising, calculated as oxides: 40-60 wt. % ZnO, 15-35 wt. % B2O3, 1-16 wt. % SiO2, 1-10 wt. % Al2O3, 2-15 wt. % MnO2, and at least one selected from the group consisting of Li2O, Na2O and K2O in their total of 0.5-10 wt. %, and a glass with the above-described components where a total of at least one selected from the group consisting of Li2O, Na2O and K2O is 0-5 wt. %, and at least one selected from the group consisting of MgO, CaO, TiO2, Cr2O3, ZrO2, Ta2O5, SnO2, and Fe2O3 is further included in their total of 0.1-5 wt. %. A conductive paste using such a glass as an inorganic binder has a superior binder removal ability and a good sinterability and can form dense conductors with excellent characteristics with respect to resistance to plating solutions, adhesive strength, resistance to thermal shocks, etc.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: January 11, 2005
    Assignee: Shoei Chemical Inc.
    Inventors: Tetsuya Tanaka, Nobuko Morinaga, Yuko Koyama, Yoshiko Morinaga, Mikio Yamazoe, Megumi Kawahara, Kenji Morinaga
  • Patent number: 6835680
    Abstract: A ceramic color composition comprising, as represented by mass percentage, from 60 to 85% of a low melting point glass powder, from 15 to 40% of a heat-resistant pigment powder, from 0 to 15% of heat-resistant whiskers, and from 0 to 15% of a refractory powder, wherein Fe3O4: 1 to 35%, MnO2: 1 to 24%, Cr2O3+CuO≧1%, and Cr2O3/8.5+CuO/23+NiO/3.3+CoO/0.71+V2O/56+Se/0.45≦1%.
    Type: Grant
    Filed: March 8, 2004
    Date of Patent: December 28, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Shuji Taguchi, Shiro Ootaki, Toru Kudo
  • Patent number: 6815385
    Abstract: A tungsten sealing glass for use in a fluorescent lamp, said glass having a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0.1-5% TiO2, 0.1-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, wherein Na2O/(Na2O+K2O)≦0.6.
    Type: Grant
    Filed: July 15, 2003
    Date of Patent: November 9, 2004
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
  • Patent number: 6809049
    Abstract: The present invention provides glass compositions that can be used instead of known glass compositions containing a large amount of PbO in applications such as coating ceramic substrates, e.g., alumina, or sealing fluorescent tubes or the like. The invention also provides glass forming materials containing the glass compositions as a primary component for glass formation. Glass compositions provided by the present invention are comprises essentially of primary oxide components. The primary oxide components include ZnO, B2O3 and P2O5 as essential components and Al2O3, MgO, CaO and BaO as optional components. The amount of the primary oxide components is 85 wt % or more (preferably 90 wt % or more) of the total weight of the glass composition. Typically, the primary oxide components include 45 to 80% of ZnO, 5 to 45% of B2O3, 1 to 35% of P2O5, 0 to 10% of Al2O3, 0 to 15% of MgO, 0 to 10% of CaO, and 0 to 5% of BaO.
    Type: Grant
    Filed: November 21, 2002
    Date of Patent: October 26, 2004
    Assignee: Noritake Co., Ltd.
    Inventor: Jun Hirose
  • Patent number: 6777358
    Abstract: A glass composition for a seal consists essentially of 70-75 wt % of PbO, 3-7 wt % of PbF2, 5-8 wt % of Bi2O3, 5-7 wt % of B203, 2-5 wt % of ZnO, 1-3 wt % of Fe2O3, 0-2 wt % of CuO, 0-2% of TeO2, and a trace <0.2% of MnO2, the composition having a flow temperature of <350° C. Such seals can be flowed at low temperatures, using different and less environmentally damaging constituents to those used before. Damage to temperature sensitive materials near the seals, can be reduced. Low flow temperatures can be achieved without excessive degradation of properties such as low viscosity, low expansion coefficient, good adhesion to glass and metals, low permeability of air, good long term hydrolytic stability. A filler such as a ceramic powder, is added to match the temperature expansion coefficient to the materials being sealed. It can be used to fix silica fiber into electro-optic devices to achieve hermetic joints with high mechanical stability.
    Type: Grant
    Filed: July 25, 2002
    Date of Patent: August 17, 2004
    Assignee: Nortel Networks Limited
    Inventors: Kenneth Snowdon, Christopher Tanner, Timothy Durrant, Christopher Woodend
  • Publication number: 20040152579
    Abstract: A glaze composition can be used to provide a glaze layer having excellent antifouling performance and visual beauty. The glaze composition contains a glaze forming material, which has a composition determined such that a baked product obtained by baking the glaze composition comprises 55.0 to 67.0 wt % of SiO2; 8.0 to 11.0 wt % of Al2O3; 2.0 to 8.0 wt % of SnO2; 15.0 to 21.0 wt % of a divalent metal oxide; and 4.0 to 6.0 wt % of a monovalent metal oxide, with respect to a total weight of the baked product. When a glaze layer is formed by use of this glaze composition, it resists contamination. Even when a dirt deposits on the glaze layer, the dirt can be easily removed from the glaze layer. In addition, the glaze composition can provide a beautiful semi-opaque glaze layer with luster and a reduction in pore generation amount.
    Type: Application
    Filed: April 6, 2004
    Publication date: August 5, 2004
    Inventors: Shigeru Ishiki, Masayuki Ishihara, Kazuhiko Matsuura, Kanjanatanom Othong
  • Patent number: 6635592
    Abstract: A tungsten sealing glass for use in a fluorescent lamp has a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, where Na2O/(Na2O+K2O)≦0.6.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: October 21, 2003
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
  • Patent number: 6589894
    Abstract: In a composition for use in formation of barrier ribs in a plasma display panel, comprising glass powder, the glass powder is powder of PbO free and alkali metal oxide free glass which consists essentially of, by molecular percent, 5-40% BaO, 20-55% ZnO, 15-50% B2O3, 0-25% SiO2. The glass has a softening point of 630° C. or less. Ceramics powder is mixed with the glass powder. The composition can also be provided in a form of paste, alternatively in a form of a green sheet.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: July 8, 2003
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Takayuki Mito, Hiroyuki Oshita, Masahiko Ouji, Kazuo Hadano
  • Publication number: 20030125185
    Abstract: The present invention provides glass compositions that can be used instead of known glass compositions containing a large amount of PbO in applications such as coating ceramic substrates, e.g., alumina, or sealing fluorescent tubes or the like. The invention also provides glass forming materials containing the glass compositions as a primary component for glass formation. Glass compositions provided by the present invention are comprises essentially of primary oxide components. The primary oxide components include ZnO, B2O3 and P2O5 as essential components and Al2O3, MgO, CaO and BaO as optional components. The amount of the primary oxide components is 85 wt % or more (preferably 90 wt % or more) of the total weight of the glass composition. Typically, the primary oxide components include 45 to 80% of ZnO, 5 to 45% of B2O3, 1 to 35% of P2O5, 0 to 10% of Al2O3, 0 to 15% of MgO, 0 to 10% of CaO, and 0 to 5% of BaO.
    Type: Application
    Filed: November 21, 2002
    Publication date: July 3, 2003
    Inventor: Jun Hirose
  • Publication number: 20030119647
    Abstract: The present invention provides a ceramic color composition which comprises, as a solid powder, 50 to 90 wt. % of a mixture containing 5 to 95 parts by weight of a first lead-free glass powder comprising at least SiO2, ZnO, and B2O3 as glass components, and 5 to 95 parts by weight of a second lead-free glass powder comprising at least SiO2, Bi2O3, and B2O3 as glass components, 10 to 40 wt. % of an inorganic pigment, and 0 to 10 wt. %0 of an inorganic filler.
    Type: Application
    Filed: December 20, 2002
    Publication date: June 26, 2003
    Inventors: Shigehiro Sanichi, Nokami Yoshito
  • Patent number: 6498117
    Abstract: The present invention relates to a process for manufacturing recyclable black enamels that contain at least zinc, in which process glass forming materials comprising at least bismuth, silicon, boron and manganese are melted, at temperatures greater than about 900° C., and then a glass frit comprising at least zinc is added to the mixture obtained after this direct melting. The invention also relates to zinc-based recyclable black enamel compositions.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: December 24, 2002
    Assignee: Saint-Gobain Vitrage
    Inventors: André Beyrle, Daniel Dages
  • Patent number: 6492289
    Abstract: A lead-free glaze that can be fired at a low temperature, a spark plug for which it is used, and a spark plug production method are provided. The lead-free glaze is for coating onto ceramic materials. This lead-free glaze contains 16-49 wt % of SiO2, 15-35 wt % of B2O3, 0-10 wt % of Al2O3 and 0-10 wt % of ZnO. A spark plug is provided that comprises coating the lead-free glaze onto the surface of an insulator and firing.
    Type: Grant
    Filed: May 23, 2000
    Date of Patent: December 10, 2002
    Assignee: Denso Corporation
    Inventors: Hirofumi Suzuki, Toshiya Nakamura, Yoshiki Morita
  • Patent number: 6450652
    Abstract: Motor vehicle windshields and safety glazing material, suitable for use as motor vehicle windshields and safety glazing material for automobiles, trucks, buses, motorcycles, locomotives. sport utility vehicles, all terrain vehicles, and vans. The motor vehicle windshields and safety glazing material contains Neodymium Oxide, a rare earth compound. The Neodymium Oxide filters out the yellow portion of the spectrum, reducing glare. Incorporation of yellow light in the spectrum desaturates colors and reduces contrast. Improvement in contrast and a reduction in glare permits, for example, a motor vehicle driver to better discriminate the contrast of objects when there is no daylight and the only illumination is artificial. For drivers, in particular, elimination of the yellow light lessens eye strain currently resulting from light emitted by the conventional headlights of oncoming vehicles during hours of darkness. Neodymium Oxide can also be added to safety glazing materials for use in bullet resistant shields.
    Type: Grant
    Filed: May 24, 2001
    Date of Patent: September 17, 2002
    Inventor: Daniel Nathan Karpen
  • Publication number: 20020119884
    Abstract: Glass frit compositions, calculated in mole percent on an oxide basis, consisting essentially of 24.5 to 29.0% P2O5; 1.0 to 5.0% B2O3; 1.0 to 2.0% Al2O3; and sufficient amounts of SnO and ZnO (51.5 to 66.5% SnO, and 5.0-12.0% ZnO), wherein the molar ratio of SnO:ZnO is in the range of about 5.0:1 to 12: 1, and 0.0 to 2.0% SiO2. The glass compositions exhibit, under NMR spectroscopic analysis of 11B nuclei, a signal containing at least two peaks at a chemical shift in the range of approximately −18 to −25 ppm. The frit compositions exhibit long term stability, durability, and resistance to attack against moisture in high temperature and humidity conditions and are capable of attaching optical fiber Bragg gratings without the use of a hermetic chamber and the like. An optoelectronic device that employs a sealing material that comprises a frit made from the glass compositions.
    Type: Application
    Filed: December 21, 2000
    Publication date: August 29, 2002
    Inventors: Carol L. Buhrmaster, Robert Morena, Kamjula P. Reddy, Randall E. Youngman
  • Patent number: 6439943
    Abstract: The object of the present invention is to provide a high-intensity, reliable plasma display panel even when the cell structure is fine by resolving the problems such as a low visible light transmittance and low voltage endurance of a dielectric glass layer. The object is realized by forming the dielectric glass layer in the manner given below. A glass paste including a glass powder is applied on the front glass substrate or the back glass substrate, according to a screen printing method, a die coating method, a spray coating method, a spin coating method, or a blade coating method, on each of which electrodes have been formed, and the glass powder in the applied glass paste is fired. The average particle diameter of the glass powder is 0.1 to 1.5 &mgr;m and the maximum particle diameter is equal to or smaller than three times the average particle diameter.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: August 27, 2002
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Masaki Aoki, Yasuhisa Ishikura, Katsuyoshi Yamashita, Shinya Fujiwara, Yasuyuki Akata
  • Patent number: 6432851
    Abstract: A durable low Tg Sb-stabilized Mo+W phosphate based glass composition exhibiting superior resistance to attack by boiling water, humidity and acids resulting from the addition of Sb to Mo+W phosphate based glass compositions. Specifically, the present invention discloses a glass composition comprising in mol % on the oxide basis, of 0-40% R2O where R includes the alkali metals (Li, Na, K, Rb or Cs) as well as Ag and Tl, 0-20% XO where X includes the alkaline earth metals (Mg, Ca, Sr or Ba) as well as Cu, Zn, Cd and Pb, 15-80% MoO3+WO3, 0.5-60% Sb2O3, and 10-40% P2O5. Additionally, the Sb-stabilized Mo+W phosphate based glass composition can contain a total of 0-5%, in mole percent (mol %) on the oxide basis, of glass forming oxides including, but not limited to, B2O3, Al2O3, SiO2, TeO2, Ga2O3, GeO2, transition metal and rare earth metal oxides, or mixtures thereof.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: August 13, 2002
    Assignee: Corning Incorporated
    Inventor: Bruce G. Aitken
  • Patent number: 6428614
    Abstract: Opaque porcelains for use with metal cores in the manufacture of PFM restorations. The porcelains exhibit a coefficient of thermal expansion (CTE) substantially equal to or slightly above the CTE of the metal to which it is applied. The porcelains exhibit a CTE equal to or up to about 1.5×10−6/° C. higher than the dental alloys to which they are applied as the opaque. The porcelains are fabricated from a mixture of two frit compositions. A high expansion, leucite containing frit is combined with a low melting glass frit to provide a porcelain having an expansion in the range of 16.9 to about 18×10−6/° C. in the temperature range of 25°-500° C.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: August 6, 2002
    Assignee: Jeneric/Pentron, Inc.
    Inventors: Dmitri Brodkin, Carlino Panzera, Paul Panzera
  • Patent number: 6410633
    Abstract: An antibacterial glass is a ZnO—B2O3—SiO2 glass and includes 0-6 wt % Na2O. Typically, the antibacterial glass is used as an antibacterial agent which is filled into a resin.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: June 25, 2002
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hajime Hikata, Kazuyoshi Shindo, Toshio Yamanaka
  • Patent number: 6403506
    Abstract: The invention relates to a glass powder, where at least one oxidizing agent or one reducing agent is added to the glass powder. The glass powder is preferably used as dental glass powder.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: June 11, 2002
    Assignee: Schott Glas
    Inventors: Susanne Kessler, Hartmut Paschke, Hans-Werner Beudt, Susanne Kiermayer
  • Patent number: 6403507
    Abstract: The lead-free bismuth-containing silicate glasses, which are particularly suitable for use as funnel glass or neck glass for cathode ray tubes and as soldering glass, have the following respective compositions (in % by weight, based on oxide): SiO2 40-60; Bi2O3, 10-30; ZrO2, 0-3; Al2O3, 0.5-5; MgO, 0-6; CaO, 0.5-5; SrO, 1-15; BaO, 0-15; sum of the alkaline earth metal oxides, 2-20; ZnO, 0-2; Li2O, 0-10; Na2O, 1-10; K2O, 2-10; Cs2O, 0-3, sum of the alkali metal oxides, 5-20; CeO2, 0-8; WO3, 0.5-5; MoO3, 0-5 and Sb2O3, 0-0.6; and SiO2 30-50; Bi2O3, 20-40; ZrO2, 0-3; Al2O3, 0.5-5; MgO, 0-4; CaO, 0.5-4; SrO, 1-15; BaO, 0-15; sum of the alkaline earth metal oxides, 2-20; ZnO, 0-2; Li2O, 0-5; Na2O, 1-12; K2O, 2-15; Cs2O, 0-3, sum of the alkali metal oxides, 5-20; CeO2, 0-8; WO3, 0.5-5; MoO3, 0-5 and Sb2O3, 0-0.6.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: June 11, 2002
    Assignee: Schott Glas
    Inventors: Karin Naumann, Magdalena Winkler-Trudewig, Ute Woelfel, Christian Kunert
  • Patent number: 6387832
    Abstract: Transition metal NZP type compounds are synthesized. Examples of these compounds include MnZr4(PO4)6, FeZr4(PO4)6, CoZr4(PO4)6, NiZr4(PO4)6, and CuZr4(PO4)6. These compounds are synthesized by the Xerogel process. These transition metal NZP type compounds can be used as colorants in applications such as ceramic glazes where high thermal stability of the colorant is important.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: May 14, 2002
    Assignee: The Penn State Research Foundation
    Inventors: Sridhar Komarneni, William W. Gould
  • Patent number: 6387833
    Abstract: A sealing composition having at least one member from &agr;-4PbO.B2O3 crystal powder and Pb3O4 powder incorporated in a total amount of from 0.0001 to 3 parts by weight to 100 parts by weight of a composition comprising at least 80 wt % and less than 98.99 wt % of a powder of PbO—ZnO—B2O3—SiO2 type crystalline low melting point glass, from 0.01 to 5 wt % of a zircon powder, more than 1 wt % and not more than 19.99 wt % of an &agr;-alumina powder and from 0 to 10 wt % of a low expansion ceramic filler.
    Type: Grant
    Filed: August 2, 2000
    Date of Patent: May 14, 2002
    Assignee: Asahi Glass Company, Limited
    Inventors: Ryuichi Tanabe, Hiroshi Usui, Yutaka Segawa, Yuichi Kuroki, Eiji Ichikura
  • Patent number: 6383961
    Abstract: A composition of a dielectric for a plasma display panel in user for fabricating a dielectric thick film for a front substrate having a low sintering temperature, a low thermal expensive coefficient, a high dielectric constant and a high withstand voltage. The composition of a dielectric is a P2O5—ZnO—PbO glass having composition ratios of 30˜60 wt % of P2O5, 5˜40 wt % of PbO, 0˜5 wt % of MgO, 0˜5 wt % of CaO, 0˜10 wt % of La2O3, 0˜5 wt % of SrO, 1˜5 wt % of Al2O3, 0˜2 wt % of Sb2O3, 0˜2 wt % of As2O3, 5˜25 wt % of BaO, and 0˜5 wt % of TeO2.
    Type: Grant
    Filed: May 17, 2000
    Date of Patent: May 7, 2002
    Assignee: LG Electronics Inc.
    Inventor: Byung-Gil Ryu
  • Patent number: 6355187
    Abstract: There is provided a conductive paste comprising a conductive component, a glass frit, and a vehicle, wherein the glass frit comprises a glass and at least one of alumina (Al2O3), silica (SiO2), titania (TiO2) and zirconia (ZrO2). The conductive paste is capable of being baked at a low temperature with sufficient coloring, and is suitable for forming a circuit on a glass substrate, the glass circuit substrate suitable for application in a defogging glass for an automobile window formed therewith.
    Type: Grant
    Filed: July 28, 1999
    Date of Patent: March 12, 2002
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Tomoki Sanada, Haruhiko Kano, Fumiya Adachi
  • Patent number: 6348426
    Abstract: An electrically conductive composition for forming an electrically conductive film through firing. The composition includes metal powder and glass frit as solid components. The glass frit contains a first glass frit which assumes a molten state at least at the maximum temperature during firing and a second glass frit which maintains a glass-ceramic state at the maximum temperature during firing. The first frit has a softening point 100° C. or more lower than the maximum temperature during firing. The content of the first glass frit based on the total amount of glass frit lies within the range of about 25-90 wt. %, and the total amount of glass frit based on the total solid component including metal powder lies within a range of about 3-10 wt. %. Also disclosed are ceramic electronic components and a production process of the components.
    Type: Grant
    Filed: September 15, 1999
    Date of Patent: February 19, 2002
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Yukio Sanada, Shinichiro Kuroiwa, Kyoumi Tsukida
  • Patent number: 6346493
    Abstract: The present invention provides a new and improved lead-free and cadmium-free glass enamel composition that displays good flow at traditional glass enamel firing temperatures and upon firing produces an enamel finish that displays no cracking, good chemical resistance, good weatherability, and improved color values. The glass enamel composition of the present invention includes a glass component, an oxidizer, a pigment system, and optional vehicles and fillers. The presence of the oxidizer in the composition, which can be included as part of the glass component, as a separately added material, or both, improves the color values of the fired enamel as compared to enamels formed using similar glass enamel compositions having no oxidizer present.
    Type: Grant
    Filed: October 27, 1999
    Date of Patent: February 12, 2002
    Assignee: Ferro Corporation
    Inventors: Galina Kniajer, Jeffrey David Cosby, Ivan H. Joyce, Srinivasan Sridharan, John J. Maloney
  • Patent number: 6309989
    Abstract: A tin-borophosphate glass of the present invention has main components of SnO, B2O3, and P2O5, consists essentially of, by mole % representation, 30-70% SnO, 5-30% B2O3, and 24-45% (24% exclusive) P2O5, and satisfies a condition of B2O3/P2O5≧0.20 by mole ratio.
    Type: Grant
    Filed: November 29, 1999
    Date of Patent: October 30, 2001
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Takemi Kikutani
  • Patent number: 6306784
    Abstract: Alkali silicate glasses are described which, in view of their good chemical stability and their optical properties and processing properties, are particularly suitable as a coating or veneering material for ceramic dental frameworks and hence for the production of all-ceramic dental restorations such as crowns or bridges.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: October 23, 2001
    Assignee: Ivoclar AG
    Inventors: Helga Drescher, Martin Frank, Volker Rheinberger, Wolfram Höland
  • Patent number: 6306783
    Abstract: A tin borophosphate glass for use in sealing materials includes, by mole, 30 to 80% of SnO, 5 to 60% of B2O3, and 5 to 24% of P2O5 as main components. The glass is free of lead but is of equal quality to those of conventional lead-containing sealing glasses. The glass can provide a satisfactory sealing material.
    Type: Grant
    Filed: February 2, 2000
    Date of Patent: October 23, 2001
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Toshio Yamanaka