Chemically Specified Frit Compositions Patents (Class 501/21)
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Patent number: 11014846Abstract: A scaling resistant ceramic glaze and a functional overglaze for Q345 hot rolled alloy steel double sided enameling. The components and the weight percentage of each component of the ground glaze of the enamel are as follows: 3-6% of Al2O3, 60-70% of SiO2; 10-15% of B2O3, 10-15% of Na2O+K2O+Li2O, 3-6% of CaF2, 3-6% of ZrO2, 2-5% of CoO+NiO, 1-3% of BaMoO4+Sb2O3, 0.3-1.5 of WO3. The ground glaze is prepared by formulating chemical raw materials in a weight ratio converted by the described chemical composition, stirring thoroughly and mixing uniformly, melting same in a rotary furnace at 1200-1350° C., and then quenching the melt. The provided scaling resistant ceramic glaze and functional overglaze for Q345 hot rolled alloy steel double sided enameling can be applied to Q345 steel that contains C, P, S and the like which are considered harmful elements and contains a variety of common alloy elements.Type: GrantFiled: January 15, 2019Date of Patent: May 25, 2021Assignee: Jiangxi Kosen Entech Co., Ltd.Inventors: Lihua Kang, Wei Sheng, Xiaofang Huang
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Patent number: 10566584Abstract: An electrical storage system is provided that has a thickness of less than 2 mm and includes comprises at least one sheet-like discrete element. At least one surface of the at least one sheet-like discrete element is designed to be chemically reactive to a reduced degree, inert, and/or permeable to a reduced degree, and/or impermeable with respect to materials coming into contact with the surface. Also provided are a sheet-like discrete element and to the production and use thereof.Type: GrantFiled: December 21, 2016Date of Patent: February 18, 2020Assignee: SCHOTT AGInventors: Thorsten Damm, Ulrich Peuchert, Nikolaus Schultz, Miriam Kunze, Clemens Ottermann
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Patent number: 9269742Abstract: A cover glass for semiconductor package having thermal expansion coefficient conformable to plastic packages and allowing accurate detection of existence of foreign substances, dusts, etc. in an imaging test always having a low emission amount of alpha-ray, and a related production method. The cover glass comprises, in terms of percentage by mass, of from 58 to 75% of SiO2, of from 1.1 to 20% of Al2O3, of from 0 to 10% of B2O3, of from 0.1 to 20% of Na2O, of from 0 to 11% of K2O, and of from 0 to 20% of alkaline earth metal oxide. The cover glass has average thermal expansion coefficient of from 90 to 180×10?7/° C. in the temperature range of from 30 to 380° C., a Young's modulus of 68 GPa or more, and an emission amount of alpha-ray from the glass of 0.05 c/cm2·hr or less.Type: GrantFiled: September 8, 2011Date of Patent: February 23, 2016Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Takako Komai, Takashi Murata, Masahiro Yodogawa
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Patent number: 9029278Abstract: An alumino-borosilicate glass for the confinement, isolation of a radioactive liquid effluent of medium activity, and a method for treating a radioactive liquid effluent of medium activity, wherein calcination of said effluent is carried out in order to obtain a calcinate, and a vitrification adjuvant is added to said calcinate.Type: GrantFiled: December 23, 2009Date of Patent: May 12, 2015Assignee: Areva NCInventors: Jean-Luc Dussossoy, Agnés Grandjean, Thierry Advocat, Nicolas Bousquet, Sophie Schuller
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Patent number: 9016090Abstract: A method for manufacturing a plurality of glass microspheres comprises: melting a batch into a first glass melt in a melter system, processing the first glass melt into a second glass, pulverizing the second glass into a plurality of glass fragments, thermally processing the plurality of glass fragments into a plurality of glass microspheres, providing at least one of a plurality of redox reactions and a plurality of events in at least one of the first glass melt and a melt of the second glass, and the plurality of redox reactions and the plurality of events are induced by a plurality of redox active group (RAG) components.Type: GrantFiled: June 12, 2013Date of Patent: April 28, 2015Inventors: Hamid Hojaji, Laura Gabriela Kocs
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Patent number: 9011720Abstract: Embodiments are directed to glass frits containing phosphors that can be used in LED lighting devices and for methods associated therewith for making the phosphor containing glass frit and their use in glass articles, for example, LED devices.Type: GrantFiled: March 28, 2013Date of Patent: April 21, 2015Assignee: Corning IncorporatedInventors: Bruce Gardiner Aitken, Michael Edward Badding, Nicholas Francis Borrelli, Nadja Teresia Lonnroth, Mark Alejandro Quesada
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Patent number: 8999869Abstract: The glass-ceramic joining material, which is suitable for bonding or joining at low processing temperatures, especially less than 800° C., is composed of a BaO—SiO2—CaO—B2O3—Al2O3 system and has a coefficient of thermal expansion ?(20-300)?9.5·10?6 K?1.Type: GrantFiled: April 22, 2013Date of Patent: April 7, 2015Assignee: Schott AGInventor: Dieter Goedeke
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Patent number: 8986841Abstract: A process for reinforcing a glass-ceramic article, into which a maximum tension is introduced beneath the surface of the glass-ceramic, advantageously in proximity to said surface. The invention also relates to an enamel that can be used for this reinforcement, this enamel being formed from a glass frit having the following composition, the proportions being expressed as weight percentages: SiO2 50-66% MgO 3-8% Na2O ?7-15% K2O 0-3% Li2O ?0-12% CaO ?0-10% BaO ?0-15% Al2O3 0-3% ZrO2 0-3% ZnO 0-5% B2O3 0-8% the sum of the alkaline-earth metal oxides CaO+BaO moreover being between 8 and 15%, and the sum of the alkali metal oxides Na2O+K2O+Li2O moreover being between 7 and 20%. The reinforced glass-ceramics obtained by the process.Type: GrantFiled: January 10, 2014Date of Patent: March 24, 2015Assignee: Eurokera S.N.C.Inventors: Stephanie Pelletier, Marie-Helene Chopinet, Caroline Faillat, Marie-Helene Rouillon, Pablo Vilato
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Patent number: 8980776Abstract: Disclosed is a lead-free, low melting point glass composition, which is characterized by being substantially free from a lead component and comprising 0-8 mass % of SiO2, 2-12 mass % of B2O3, 2-7 mass % of ZnO, 0.5-3 mass % of RO (MgO+CaO+SrO+BaO), 0.5-5 mass % of CuO, 80-90 mass % of Bi2O3, 0.1-3 mass % of Fe2O3, and 0.1-3 mass % of Al2O3. This glass composition is not easily crystallized at high temperatures and is stable. Therefore, it is useful as an insulating coating material and a sealing material for electronic material substrates.Type: GrantFiled: June 9, 2011Date of Patent: March 17, 2015Assignee: Central Glass Company, LimitedInventor: Jun Hamada
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Publication number: 20150068249Abstract: This invention relates to lead free and cadmium free copper-containing glass frits that can be used as pigments to color other glass frits or to impart color to solid substrates such as glass, ceramic or metals, or to impart color to a thermoplastic mass. The compositions comprise silica, alkali metal oxides, alkaline earth metal oxides, tin oxide and copper oxide. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates, generally imparting a red color.Type: ApplicationFiled: November 7, 2014Publication date: March 12, 2015Applicant: FERRO CORPORATIONInventors: Enos A. Axtell, III, George E. Sakoske, Andreas Schulz, Juergen Hanich, Lothar Heck, Dietrich Speer, Martin Baumann
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Publication number: 20150050419Abstract: The invention relates to a process for producing a paste-like SiO2 composition using an SiO2 slip which allows simple intermediate storage and transport conditions without the processability of the slip to give the paste-like SiO2 composition being impaired thereby. According to the invention, it is for this purpose proposed that a homogeneous SiO2 base slip be subjected to a drying step to form a dry SiO2 composition and subsequently be processed further by means of a remoistening step to give the paste-like SiO2 composition, where the remoistening step comprises the addition of liquid to the dry SiO2 composition to form a paste-like kneadable SiO2 composition having a solids content of more than 85% by weight. The invention further relates to the use of a paste-like SiO2 composition as repair composition.Type: ApplicationFiled: March 7, 2013Publication date: February 19, 2015Inventors: Jürgen Weber, Norbert Traeger, Gerrit Scheich, Waltraud Werdecker, Christian Schenk, Joachim Peekhaus, Kerstin Meyer-Merget, Sebastian Pankalla
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Patent number: 8946102Abstract: This invention relates to lead free and cadmium free copper-containing glass fits that can be used as pigments to color other glass fits or to impart color to solid substrates such as glass, ceramic or metals, or to impart color to a thermoplastic mass. The compositions comprise silica, alkali metal oxides, alkaline earth metal oxides, tin oxide and copper oxide. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates, generally imparting a red color.Type: GrantFiled: June 16, 2010Date of Patent: February 3, 2015Assignee: Ferro CorporationInventors: Enos A. Axtell, III, George E. Sakoske, Andreas Schulz, Juergen Hanich, Lothar Heck, Dietrich Speer, Martin Baumann
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Patent number: 8945715Abstract: The present invention relates to a low-V2O5-content and even V2O5-free porcelain enamel with improved dish-washer resistance, very good acid resistance and good adherence on various substrates. The invention moreover relates to a transparent low-V2O5-content and even V2O5-free porcelain enamel frit for application of enamel coatings with infinite color range on a substrate made of aluminum, cast aluminum, aluminum alloy, aluminum-magnesium alloy, cast aluminum alloy, copper, austenitic stainless steel and mild steel, presenting improved dish-washer resistance, good acid resistance and good adherence on the substrate. The composition of the porcelain enamel in question comprises about 30 wt-% to about 50 wt-% SiO2, about 30 wt-% to about 40 wt-% R2O, about 15 wt-% to about 25 wt-% TiO2, about 0 wt-% to about 5 wt-% RO, about 0 wt-% to about 4 wt-% V2O5, about 0.Type: GrantFiled: August 12, 2009Date of Patent: February 3, 2015Assignee: Pemco Brugge BVBAInventors: Efimenko Svetlana, Nancy Crevits, Christian Schlegel
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Patent number: 8937026Abstract: Novel glass compositions and method for producing a glass/metal join, in which the novel glass comprises: Oxide (%) B2O3 ??8-13.5 Al2O3 5-9 Na2O 3-9 K2O 0-5 CaO 2-4 MgO 0-4 ZnO 0-4 SiO2 Up to 100 depending on the necessary requirements, owing to the significance thereof the thermal expansion coefficient, such that this thermal expansion coefficient is adjusted to match that of the metal part or alloy with which the glass/metal weld is to be achieved, which makes it possible to satisfactorily produce said weld which results in a strong glass/metal join, that is free from tensile stresses and that is durable over time and may be used, inter alia, to obtain parts that form part of solar collectors.Type: GrantFiled: August 12, 2010Date of Patent: January 20, 2015Assignee: Abengoa Solar New Technologies, S.A.Inventors: Noelia Martí´nez Sanz, José Luis Oteo Mazo, Jaun Rubio Alonso, Fausto Rubio Alonso, Alejandra Mazo Fernández
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Patent number: 8901018Abstract: The present invention is a composite encapsulating material which consists of silicon dioxide, aluminum oxide, yttrium oxide and zinc oxide and has glass transition temperature between 694° C. and 833° C. as well as expansion coefficient between 7.0 and 8.5×10?6/° C. The ratio of the number of moles of silicon dioxide plus aluminum oxide (yttrium oxide or zinc oxide) to the total number of moles is 41.88˜62.22% (10.48˜26.67% or 11.11˜47.64%); the ratio of the number of moles of aluminum oxide to the total number of moles is 5.23˜17.78%. The ratios of aluminum oxide to silicon dioxide, yttrium oxide to silicon dioxide, and zinc oxide to silicon dioxide are 0.14˜0.40, 0.29˜0.60, and 0.25˜1.30, respectively.Type: GrantFiled: January 24, 2013Date of Patent: December 2, 2014Assignee: National Taipei University of TechnologyInventors: Sea-Fue Wang, Chieh-Sheng Cheng, Yung-Fu Hsu
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Patent number: 8871661Abstract: Provided is a bonding material which can bond base materials or substrates having different linear thermal expansion coefficients, and can have heat resistance against temperatures of 300° C. or higher, vacuum airtightness and bonding strength, further which has excellent handleability and workability. The bonding material is produced by mixing, in a content ratio of 0.01 to 60 mass % (to the whole), a metal Ga, and/or at least one metal or alloy powder selected from the group consisting of a metal powder mixture of a combination of Bi and Sn or an alloy powder thereof, and a metal powder mixture of a combination of Bi, Sn and Mg or an alloy powder thereof with a Bi2O3-based glass frit powder having an average particle diameter of 200 ?m or less. The bonding material may be formed in a paste form by adding a solvent thereto. This feature makes it possible to bond together substrates having different thermal expansion coefficients without causing a crack or unsticking.Type: GrantFiled: September 7, 2010Date of Patent: October 28, 2014Assignee: Sophia Product Co.Inventor: Minoru Yamada
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Patent number: 8808582Abstract: A conductive paste material containing a SiO2-B2O3—ZnO—RO—R2O type lead-free low-melting-point glass that contains, by wt %, 2 to 10% of SiO2, 18 to 30% of B2O3, 0 to 10% of Al2O3, 0 to 25% of ZnO, 20-50% of RO where RO represents one or more of MgO, CaO, SrO, and BaO, and 10 to 17% of R2O where R2O represents one or more of Li2O, Na2O, and K2O.Type: GrantFiled: June 14, 2011Date of Patent: August 19, 2014Assignee: Central Glass Company, LimitedInventor: Jun Hamada
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Publication number: 20140221190Abstract: Provided is a crystallizable glass composition which exhibits a high coefficient of thermal expansion after undergoing thermal treatment, has excellent fluidity during the thermal treatment, and is less likely to deteriorate the hermeticity and adhesiveness at bonded portions and volatilize glass components even when exposed to high temperatures for a long period after the thermal treatment. A crystallizable glass composition capable of precipitating MgO-based crystals as main crystals by thermal treatment, the crystallizable glass composition containing, in terms of % by mole in glass component composition, 0.1 to 30% La2O3+Nb2O5+Y2O3+Ta2O5+Yb2O3.Type: ApplicationFiled: August 13, 2012Publication date: August 7, 2014Applicant: NIPPON ELECTRIC GLASS CO., LTD.Inventor: Yoshihisa Takayama
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Patent number: 8778469Abstract: When local heating by use of laser sealing or the like is applied, the bonding strength between glass substrates and a sealing layer is improved to provide an electronic device having increased reliability. An electronic device includes a first glass substrate, a second glass substrate, and a sealing layer to seal an electronic element portion disposed between these glass substrates. The sealing layer is a layer obtained by locally heating a sealing material by an electromagnetic wave, such as laser light or infrared light, to melt-bond the sealing material, the sealing material containing sealing glass, a low-expansion filler and an electromagnetic wave absorber. In the first and second glass substrates, each reacted layer is produced to have a maximum depth of at least 30 nm from an interface with the sealing layer.Type: GrantFiled: September 13, 2012Date of Patent: July 15, 2014Assignee: Asahi Glass Company, LimitedInventors: Sohei Kawanami, Yoshinori Ami, Yoko Mitsui
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Patent number: 8741792Abstract: Provided is a glass composition that has a low reactivity with the constituent materials forming a solid oxide fuel cell while having a thermal expansion coefficient suitable for sealing a solid oxide fuel cell, and a glass composition and sealing material that are suitable for sealing a solid oxide fuel cell. The present invention, which relates to a sealing glass composition, is a sealing glass composition used for sealing a solid oxide fuel cell, characterized by having a composition ratio of, expressed in terms of oxide, 40 to 55% by mass of SiO2, 0 to 5.0% by mass of Al2O3, 0 to 8.0% by mass of B2O3, 20 to 30% by mass of MgO, and 10 to 24% by mass of CaO, wherein a total of the MgO and the CaO is 40 to 54% by mass.Type: GrantFiled: February 24, 2011Date of Patent: June 3, 2014Assignee: Nihon Yamamura Glass Co., Ltd.Inventors: Takafumi Akamatsu, Yoshitaka Mayumi
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Patent number: 8685872Abstract: A low softening point glass composition, which is substantially free from lead, bismuth and antimony and comprises oxides of vanadium, phosphorous, tellurium and iron, a softening point of the composition being 380° C. or lower.Type: GrantFiled: May 22, 2013Date of Patent: April 1, 2014Assignee: Hitachi Chemical Co., Ltd.Inventors: Takashi Naito, Shinichi Tachizono, Kei Yoshimura, Yuji Hashiba, Keiichi Kanazawa, Shinji Yamada, Satoru Amou, Hiroki Yamamoto, Takuya Aoyagi
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Patent number: 8673461Abstract: A process for reinforcing a glass-ceramic article, into which a maximum tension is introduced beneath the surface of the glass-ceramic, advantageously in proximity to said surface. The invention also relates to an enamel that can be used for this reinforcement, this enamel being formed from a glass frit having the following composition, the proportions being expressed as weight percentages: SiO2 50-66%? MgO 3-8% Na2O 7-15%? K2O 0-3% Li2O 0-12%? CaO 0-10%? BaO 0-15%? Al2O3 0-3% ZrO2 0-3% ZnO 0-5% B2O3 0-8% the sum of the alkaline-earth metal oxides CaO+BaO moreover being between 8 and 15%, and the sum of the alkali metal oxides Na2O+K2O+Li2O moreover being between 7 and 20%. The reinforced glass-ceramics obtained by the process.Type: GrantFiled: January 16, 2009Date of Patent: March 18, 2014Assignee: Eurokera S.N.C.Inventors: Stephanie Pelletier, Marie-Helene Chopinet, Caroline Faillat, Marie-Helene Rouillon, Pablo Vilato
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Patent number: 8664134Abstract: A crystallizing glass solder for high-temperature applications, containing, in % by weight on an oxide basis: 45% to 60% of BaO, 25% to 40% of SiO2, 5% to 15% of B2O3, 0 to <2% of Al2O3, and at least one alkaline earth metal oxide from the group consisting of MgO, CaO and SrO, wherein CaO is 0% to 5% and the sum of the alkaline earth metal oxides MgO, CaO and SrO is 0% to 20%, preferably 2% to 15%. The glass solder is preferably free from TeO2 and PbO. Preferred embodiments of the glass solder contain from 3 to 15 wt. % of Y2O3 and have low porosity and high stability with respect to a moist fuel gas environment.Type: GrantFiled: September 21, 2011Date of Patent: March 4, 2014Assignee: Schott AGInventors: Dieter Goedeke, Peter Brix, Olaf Claussen, Joern Besinger, Bastian Schoen
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Patent number: 8658549Abstract: A crystallizing glass solder for high-temperature applications, containing, in % by weight on an oxide basis: 45% to 60% of BaO, 25% to 40% of SiO2, 5% to 15% of B2O3, 0 to <2% of Al2O3, and at least one alkaline earth metal oxide from the group consisting of MgO, CaO and SrO, wherein CaO is 0% to 5% and the sum of the alkaline earth metal oxides MgO, CaO and SrO is 0% to 20%, preferably 2% to 15%. The glass solder is preferably free from TeO2 and PbO. Preferred embodiments of the glass solder contain from 3 to 15 wt. % of Y2O3 and have low porosity and high stability with respect to a moist fuel gas environment.Type: GrantFiled: March 30, 2010Date of Patent: February 25, 2014Assignee: Schott AGInventors: Dieter Goedeke, Peter Brix, Olaf Claussen, Joern Besinger, Bastian Schoen
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Patent number: 8618005Abstract: Provided are a glass powder represented as aLi2O-bK2O-cBaO-dB2O3-eSiO2wherein a+b+c+d+e=1, and 0.01?a?0.1, 0.01?b?0.1, 0.01?c?0.1, 0.05?d?0.3, and 0.3?e?0.7 are satisfied in terms of mol %, a method of manufacturing the same, and a multi-layered ceramic material using the same. Therefore, a nano glass powder having an average particle size of 100nm or less and uniform particle size distribution can be manufactured using liquid phase deposition, specifically, a sol-gel method. In addition, the glass powder can be used as sintering additives to decrease a sintering temperature by about 100° C. in comparison with conventional glass upon manufacture of a ceramic material such as MLCC and MLCI, which can be sintered at a low temperature, contributing to improvement of dielectric capacity and inductance capacity of the parts and increasing quality coefficient.Type: GrantFiled: May 9, 2011Date of Patent: December 31, 2013Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Sungyong An, Jeongwook Kim, Sungbum Sohn, Jinwoo Hahn, Soonmo Song
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Patent number: 8507098Abstract: The various embodiments of the present invention are directed to wear resistant coatings, tiles having the wear resistant coatings disposed thereon, and to methods of making the coatings and tiles. A wear resistant coating generally includes a strontium aluminosilicate glass-ceramic composition that is formed from a glaze. The glaze can include a crystallizing component, which itself can include strontium, aluminum, and silicon, but also comprises less than about 2 weight percent each of lithium, boron, barium, sodium, iron, titanium, zirconium, and carbon, based on a total weight of the crystallizing component.Type: GrantFiled: May 13, 2009Date of Patent: August 13, 2013Assignees: Mohawk Carpet Corporation, Intercolor S.p.A.Inventors: Thomas Long, Claudio Ansaloni, Massimo Sernesi, David A. Earl
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Patent number: 8470723Abstract: A low softening point glass composition, which is substantially free from lead, bismuth and antimony and comprises oxides of vanadium, phosphorous, tellurium and iron, a softening point of the composition being 380° C. or lower.Type: GrantFiled: January 14, 2010Date of Patent: June 25, 2013Assignee: Hitachi Powdered Metals Co., Ltd.Inventors: Takashi Naito, Shinichi Tachizono, Kei Yoshimura, Yuji Hashiba, Keiichi Kanazawa, Shinji Yamada, Satoru Amou, Hiroki Yamamoto, Takuya Aoyagi
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Patent number: 8440479Abstract: A method for sealing an organic light emitting diode (OLED) device is disclosed wherein the OLED device comprises a color filter. A color filter is deposited on a first glass plate or substrate and a glass-based frit is then deposited in a loop around the color filter, The deposited fit loop is then heated by electromagnetic energy to evaporate organic constituents and to sinter the fit in a pre-sintering step. An OLED device may then be assembled by positioning a second glass plate comprising an organic light emitting material deposited thereon in overlying registration with the first glass plate, with the color filer and the organic light emitting material positioned between the plates. The fit is then heated with a laser to form a hermetic seal between the first and second glass plates.Type: GrantFiled: March 30, 2010Date of Patent: May 14, 2013Assignee: Corning IncorporatedInventors: Kelvin Nguyen, Butchi R. Vaddi, Lu Zhang
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Patent number: 8434328Abstract: An antimony-free glass suitable for use in a frit for producing a hermetically sealed glass package is described. The hermetically sealed glass package, such as an OLED display device, is manufactured by providing a first glass substrate plate and a second glass substrate plate and depositing the antimony-free frit onto the first substrate plate. OLEDs may be deposited on the second glass substrate plate. An irradiation source (e.g., laser, infrared light) is then used to heat the frit which melts and forms a hermetic seal that connects the first glass substrate plate to the second glass substrate plate and also protects the OLEDs. The antimony-free glass has excellent aqueous durability, good flow, low glass transition temperature and low coefficient of thermal expansion.Type: GrantFiled: May 16, 2012Date of Patent: May 7, 2013Assignee: Corning IncorporatedInventors: Lisa A. Lamberson, Robert M. Morena
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Patent number: 8367573Abstract: A glass composition substantially free from lead and bismuth and containing vanadium oxide and phosphor oxide as main ingredients, wherein the sintered glass of the glass composition exhibits 109 ?cm or more at 25° C.Type: GrantFiled: February 6, 2009Date of Patent: February 5, 2013Assignee: Hitachi Powdered Metals Co., Ltd.Inventors: Takashi Naito, Shinichi Tachizono, Kei Yoshimura, Hiroki Yamamoto, Hiroshi Yoshida, Shinji Yamada, Katsumi Mabuchi
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Patent number: 8349750Abstract: The glass of the glass-metal bond contains the following ingredients in the following amounts: SiO2, 72-80 wt %; B2O3, 4-<6 wt %; Al2O3, 2-5 wt %; Na2O, 4-7 wt %; K2O, 0-3 wt %; CaO, 2.5-8 wt %; MgO, 0-2 wt %; BaO, 0-4 wt %; TiO2, 0-5 wt %; CeO2, 0-2 wt %; Fe2O3, 0-0.1 wt %; F, 0-2 wt %; and the ratio of the sum total amount of Al2O3 and B2O3 (in mol %) to the sum total amount of MgO, CaO and BaO (in mol %) in the glass is less than 5. The glass-metal bond advantageously includes a KOVAR® alloy and the glass of the aforesaid composition and connects the glass envelope tube with an inner metal absorber tube in a tube collector.Type: GrantFiled: August 18, 2010Date of Patent: January 8, 2013Assignee: Schott AGInventors: Joerg Hinrich Fechner, Christof Kass
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Publication number: 20120325297Abstract: Disclosed is a constitution formed from an oxide of an element having a smaller work function than aluminum. This oxide is comprises an oxide of vanadium (V), an oxide of an alkaline earth metal and an oxide of an alkali metal. The elements for the alkaline earth metal are comprise one or more elements out of the elements calcium (Ca), strontium (Sr) and barium (Ba) and at least contain barium. The elements for the alkali metal include at least one or more of sodium (Na), potassium (K), rubidium (Rb) and cesium (Cs). When the element vanadium is included as vanadium pentoxide (V2O5), the vanadium pentoxide content is 40-70 wt %. Thus, a glass composition for aluminum electrode wiring with an apparent work function for electrode wiring that is smaller than the work function for aluminum (Al) can be provided without the inclusion of lead.Type: ApplicationFiled: February 17, 2011Publication date: December 27, 2012Applicants: HITACHI CHEMICAL COMPANY, LTD., HITACHI, LTD.Inventors: Takashi Naito, Takuya Aoyagi, Shinichi Tachizono, Kei Yoshimura, Yuji Hashiba
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Publication number: 20120318022Abstract: A glass composition, characterized in that it is selected from the group consisting of: a glass composition (A) with the following molar percentages: 70 to 76% of SiO2, 7 to 8% of B2O3, 5 to 6% of Al2O3, and 10 to 17% of Na2O; and a glass composition (B) with the following molar percentages: 63 to 76% of SiO2, 5 to 12% of ZrO2, 0 to 12% of B2O3, 0 to 2% of La2O3, 11 to 14% of Na2O, and 3 to 5% of K2O. The glass composition can be used in a method for assembling parts, in particular for a method of manufacturing high-temperature electrolyzers (HTEs) or high-temperature fuel cells (SOFCs).Type: ApplicationFiled: June 29, 2010Publication date: December 20, 2012Inventors: Hélène Nonnet, Agnès Grandjean, Charlène Vallat, Daniel Coillot, Lionel Montagne
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Patent number: 8329303Abstract: A method is described herein for controlling the oxygen level within an oven while sintering a frit to a glass plate where the sintered frit and glass plate are subsequently sealed to another glass plate to form a sealed glass package. Examples of the sealed glass package include a light-emitting device (e.g., organic light emitting diode (OLED) device), a photovoltaic device, a food container, and a medicine container.Type: GrantFiled: February 28, 2012Date of Patent: December 11, 2012Assignee: Corning IncorporatedInventors: Andrew Douglas Banks, Heather Debra Boek, Jason Arthur Howles
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Patent number: 8309784Abstract: The present invention relates to a process for the manufacture of a glass frit for the containment by vitrification of a material comprising at least one oxidizable or reducible chemical species, and also to a process for the containment of said material by vitrification. The process for the manufacture of the glass frit comprises a step of incorporating into a raw glass frit at least one redox couple, the nature and the amount of which make it possible to maintain said at least one chemical species in its oxidized or reduced state. The containment process comprises mixing and hot melting the resulting glass frit and the material to be contained. The present invention makes it possible to optimize the containment of pollutants such as radionucleides, metals and metalloids. The material may be nuclear waste or a material derived from the incineration of household refuse.Type: GrantFiled: July 11, 2006Date of Patent: November 13, 2012Assignee: Commissariat a l'Energie AtomiqueInventors: Olivier Pinet, Thierry Blisson, Agnès Grandjean, Sophie Schuller
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Patent number: 8304357Abstract: A ceramic material composition comprising from 20 to 50 mass % of a borosilicate glass powder, from 25 to 55 mass % of an alumina filler powder and from 10 to 45 mass % of a filler powder (a high refractive index filler powder) having a refractive index higher than the alumina filler powder, wherein the borosilicate glass powder comprises, as calculated as oxides, from 30 to 70 mass % of SiO2, from 5 to 28 mass % of B2O3, from 5 to 30 mass % of Al2O3, from 3 to 35 mass % of CaO, from 0 to 25 mass % of SrO, from 0 to 25 mass % of BaO, from 0 to 10 mass % of Na2O, from 0 to 10 mass % of K2O, from 0.5 to 10 mass % of Na2O+K2O and from 3 to 40 mass % of CaO+SrO+BaO, and satisfies the following conditions: in the borosilicate glass powder, as represented by mass %, the value of “three times the B2O3 content”+“twice (the CaO content+the SrO content+the BaO content)”+“ten times (the Na2O content+the K2O content)”, is within a range of from 105 to 165.Type: GrantFiled: September 30, 2010Date of Patent: November 6, 2012Assignee: Asahi Glass Company, LimitedInventors: Kenji Imakita, Toshihisa Okada, Kazuo Watanabe
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Patent number: 8304356Abstract: The present invention relates to a color adapting composition used for coloring and color adapting porcelain for ceramic crown such as dental restorations and prosthetics, and aluminosilicate glass appropriate for using in a color adapting composition. More specifically, a color adapting composition for dental porcelains are prepared by blending two or more kinds of glass frits having different sintering temperatures from each other and an inorganic pigment or a colored glass obtained by previously dispersing inorganic pigments in glass.Type: GrantFiled: February 17, 2012Date of Patent: November 6, 2012Assignee: Kabushiki Kaisha ShofuInventors: Yukio Fukatani, Keiji Takahashi, Ryuichi Yoshimoto
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Publication number: 20120275986Abstract: The present invention is a glass frit comprising 60 to 80% by weight of SiO2, 9 to 20% by weight of Al2O3, 3 to 12% by weight of K2O, and 3 to 12% by weight of Na2O, expressed on oxide basis.Type: ApplicationFiled: September 28, 2010Publication date: November 1, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Kentaro Iwasaki, Akiyoshi Nemoto, Tetsuro Tohma
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Patent number: 8288298Abstract: Disclosed is a glass composition which is adapted to use in providing a hermetic seal between a metal and a ceramic, a metal and a metal, and a ceramic and a ceramic, to form crystallized glass having high strength and high thermal expansion which allow it to be used at high temperatures of 950° C. and over. The glass composition is substantially free of alkali metals, and contains, as calculated as oxide, 15-30 mass % of SiO2, 0-5 mass % of Al2O3, 20-35 mass % of B2O3, 10-25 mass % of CaO, 25-40 mass % of MgO, 3-8 mass % (3.0% excluded) of ZrO2, and 0-3 mass % of CeO2, wherein the crystallized glass which is formed by firing a glass powder made of the glass composition at a temperature of 850-1050° C. has a thermal expansion coefficient of 90-110×10?7/° C. at 50-550° C. and flexural strength of not less than 80 MPa.Type: GrantFiled: August 21, 2008Date of Patent: October 16, 2012Assignee: Nihon Yamamura Glass Co., Ltd.Inventors: Yoshitaka Mayumi, Hideyuki Kuribayasi
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Patent number: 8278229Abstract: Provided is a cover coating composition for a glass lining comprising a frit constituting the composition which mainly includes 65 to 75 mol % of SiO2, 2 to 8 mol % of ZrO2, 10 to 22 mol % of R2O where R represents Li, K, or Cs, and 2 to 12 mol % of R?O where R? represents Mg, Ca, Sr, or Ba, and the frit is free of Na2O, and said cover coating composition for a glass lining may further contain a metal fiber.Type: GrantFiled: January 26, 2012Date of Patent: October 2, 2012Assignee: Ikebukuro Horo Kogyo Co., Ltd.Inventors: Yoshihiro Iizawa, Masahiro Shirasaki, Takashi Kawashima, Osamu Mori
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Patent number: 8263230Abstract: A ceramic composition is prepared to contain a B2O3—SiO2—Al2O3-MO based glass composition (M: Ca, Mg, Sr and/or Ba, B2O3: 4 to 17.5 weight %, SiO2: 28 to 50 weight %, Al2O3: 0 to 20 weight %, and MO: 36 to 50 weight %): 24 to 40 weight %, SrTiO3 and/or CaTiO3: 46 to 75.4 weight %, CuO: 0.1 to 5.0 weight %, CaO: 0.5 to 7.0 weight %, and MnO, ZnO and/or CoO: 10 weight % or more (however, including 0% by weight). The ceramic composition is subjected to firing to produce a ceramic sintered body, and obtain a composite LC component including the ceramic sintered body. While suppressing the shrinkage behavior during firing, dielectric properties can be improved dramatically as compared with conventional cases, and moreover reliability can be ensured.Type: GrantFiled: May 17, 2011Date of Patent: September 11, 2012Assignee: Murata Manufacturing Co., Ltd.Inventors: Kazuhiro Kaneko, Satoshi Oga
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Publication number: 20120196126Abstract: This invention relates to lead free and cadmium free copper-containing glass fits that can be used as pigments to color other glass fits or to impart color to solid substrates such as glass, ceramic or metals, or to impart color to a thermoplastic mass. The compositions comprise silica, alkali metal oxides, alkaline earth metal oxides, tin oxide and copper oxide. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates, generally imparting a red color.Type: ApplicationFiled: June 16, 2010Publication date: August 2, 2012Applicant: FERRO CORPORATIONInventors: Enos A. Axtell, III, George E. Sakoske, Andreas Schulz, Juergen Hanich, Lothar Heck, Dietrich Speer, Martin Baumann
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Patent number: 8198203Abstract: An antimony-free glass suitable for use in a frit for producing a hermetically sealed glass package is described. The hermetically sealed glass package, such as an OLED display device, is manufactured by providing a first glass substrate plate and a second glass substrate plate and depositing the antimony-free frit onto the first substrate plate. OLEDs may be deposited on the second glass substrate plate. An irradiation source (e.g., laser, infrared light) is then used to heat the frit which melts and forms a hermetic seal that connects the first glass substrate plate to the second glass substrate plate and also protects the OLEDs. The antimony-free glass has excellent aqueous durability, good flow, low glass transition temperature and low coefficient of thermal expansion.Type: GrantFiled: November 20, 2009Date of Patent: June 12, 2012Assignee: Corning IncorporatedInventors: Lisa A. Lamberson, Robert M. Morena
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Patent number: 8178453Abstract: To provide a glass containing little B2O3, whereby when its powder is fired, its thermal expansion curve does not have an inflection point, a non-lead glass is provided containing, as represented by mol % based on the following oxides, from 35 to 41.5% of SiO2, from 8 to 25% of MgO, more than 27 to 35% of CaO, from 0 to 2% of SrO, from 0 to 4% of BaO, from 5 to 15% of ZnO and from 4.5 to 10% of Al2O3, wherein the total content of these components is at least 97%, and when SrO and BaO are contained, the total content of SrO and BaO is at most 2%; as well as a non-lead glass containing, as represented by mol % based on the following oxides, from 39.5 to 41.5% of SiO2, from 10 to less than 13% of MgO, from 18 to 22% of CaO, more than 12 to 15% of SrO, from 0 to 1% of BaO, from 6 to 11% of ZnO and from 4.5 to 7% of Al2O3, wherein the total content of these components is at least 97%.Type: GrantFiled: January 28, 2010Date of Patent: May 15, 2012Assignee: Asahi Glass Company, LimitedInventors: Masamichi Tanida, Yuki Yokoyama, Shinji Honda
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Patent number: 8168551Abstract: Provided is a cover coating composition for a glass lining comprising a frit constituting the composition which mainly includes 65 to 75 mol % of SiO2, 2 to 8 mol % of ZrO2, 10 to 22 mol % of R2O where R represents Li, K, or Cs, and 2 to 12 mol % of R?O where R? represents Mg, Ca, Sr, or Ba, and the frit is free of Na2O, and said cover coating composition for a glass lining may further contain a metal fiber.Type: GrantFiled: August 2, 2007Date of Patent: May 1, 2012Assignee: Ikebukuro Horo Kogyo Co., Ltd.Inventors: Yoshihiro Iizawa, Masahiro Shirasaki, Takashi Kawashima, Osamu Mori
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Patent number: 8162005Abstract: A zirconium- and alumina-containing silicate glass suitable for use as a frit with refractory materials such as alumina is disclosed, the silicate glass comprising a glass composition in mole percent (mol %) of: 2<B2O3<7 mol % 75<SiO2<80 mol % 3<Al2O3<5 mol % 2<ZrO2<5 mol% 9<Na2O+K2O<15 mol % 0<alkali earth+lanthanide<15 mol % and wherein the total mole percent of SiO2, AlO3 and ZrO2 together is greater than 82 but less than 86, and wherein the total mole percent of B2O3, Na2O, K2O, alkali earths and lanthanides together is greater than 13 and less than 18. Frits (200,600), composites (600) and microfluidic devices (12) comprising the glass are also disclosed.Type: GrantFiled: November 24, 2008Date of Patent: April 24, 2012Assignee: Corning IncorporatedInventor: Paulo Gaspar Jorge Marques
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Patent number: 8147976Abstract: A method is described herein for sintering a frit to a glass plate where the sintered frit and glass plate are subsequently sealed to another glass plate to form a sealed glass package. Examples of the sealed glass package include a light-emitting device (e.g., organic light emitting diode (OLED) device), a photovoltaic device, a food container, and a medicine container.Type: GrantFiled: June 29, 2011Date of Patent: April 3, 2012Assignee: Corning IncorporatedInventors: Heather Debra Boek, John W Botelho, Jason Arthur Howles
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Patent number: 8133829Abstract: The present invention provides a frit containing substantially no lead, which is applicable to a member having ? of at most 50×10?7/° C. A frit comprising a low-melting point glass powder and a refractory filler powder, containing substantially no lead, having a thermal expansion coefficient of at most 50×10?7/° C., and being processable at 500° C. or lower, wherein the above low-melting point glass powder satisfies a softening pour point range of at least 30° C., and the above refractory filler powder satisfies the following relationship: 1<S×?<10 S: specific surface area (m2/g) ?: density (g/cm3).Type: GrantFiled: March 27, 2009Date of Patent: March 13, 2012Assignee: Asahi Glass Company, LimitedInventor: Asahi Ide
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Patent number: 8110035Abstract: An integrated dental porcelain system for making dental prostheses and restorations is provided. The system includes three universal major components: a) opaque porcelain composition; b) pressable dentin ingot; and c) veneering porcelain composition that can be used interchangeably for making restorations. Techniques for making the prostheses and restorations include porcelain fused-to-metal (PFM), press-to-metal (PTM), and either pressed and/or machined all-ceramic methods. The system uses both a hand-layering of veneering porcelain (PFM technique) and a hot-pressing process (PTM and all-ceramic technique) to fabricate the prostheses and restorations.Type: GrantFiled: May 30, 2008Date of Patent: February 7, 2012Assignee: DENTSPLY International Inc.Inventors: Christopher Chu, Slawomir Banasiak, Victoriya Shtessel-Nemzer
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Patent number: 8106294Abstract: A dye-sensitized solar cell having high long-term reliability is provided by inventing a glass composition, which is hardly eroded by an iodine electrolyte solution and has a low-melting point property, and a material using the glass composition. The glass composition for a dye-sensitized solar cell of the present invention is characterized by including as a glass composition, in terms of mass %, 20 to 70% of V2O5 and 10 to 50% of P2O5.Type: GrantFiled: December 30, 2010Date of Patent: January 31, 2012Assignee: Nippon Electric Glass Co., Ltd.Inventors: Masahiro Sawada, Masaaki Hayashi, Kouji Amano, Tomoko Yamada