Calcium Oxide Containing Patents (Class 501/70)
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Publication number: 20110281099Abstract: A method is described for making a float glass convertible into a glass ceramic, by which a largely crystal fault-free glass can be produced. In this method the glass is cooled from a temperature (TKGmax), at which a crystal growth rate is at a maximum value (KGmax), to another temperature (TUEG), at which practically no more crystal growth occurs, with a cooling rate, KR, in ° C. min?1 according to: KR UEG KGmax ? ? ? ? T UEG KGmax 100 · KGmax , wherein ?T=TKGmax?TUEG, and KGmax=maximum crystal growth rate in ?m min?1. The float glass has a thickness below an equilibrium thickness, a net width of at least 1 m and has no more than 50 crystals with a size of more than 50 ?m, especially no crystals with a size of more than 10 ?m, per kilogram of glass within the net width.Type: ApplicationFiled: July 27, 2011Publication date: November 17, 2011Inventors: Gerhard Lautenschlaeger, Andreas Langsdorf, Ulrich Lange, Bernd Ruedinger, Klaus Schneider, Michael Jacquorie, Friedrich Siebers, Wolfgang Schmidbauer
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Publication number: 20110259053Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.Type: ApplicationFiled: July 1, 2011Publication date: October 27, 2011Applicant: IVOCLAR VIVADENT AGInventors: Elke Apel, Wolfram Höland, Marcel Schweiger, Christian van t'Hoen, Harald Bürke, Volker M. Rheinberger
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Publication number: 20110251044Abstract: To provide a glass substrate which has a high glass transition temperature, which has a thermal expansion coefficient close to that of soda lime glass, which has a low specific gravity, which will hardly undergo yellowing, and which further has good melting characters and is thereby produced with high productivity. A glass substrate which has a composition comprising, as represented by mass percentage based on oxides, SiO2 ??55 to 65%, Al2 O3 ??4 to 8%, MgO ??6 to 9%, CaO ?0.1 to 5%, SrO ?0.5 to 6%, BaO ??0 to 2%, MgO + CaO + SrO + BaO ?6.6 to 19%, Na2 O ??0 to 5%, K2 O ?9.5 to 21%, Na2 O + K2 O ??10 to 22%, ZrO2 ?0.5 to 5%, Fe2 O3 0.06 to 0.15%, which has a specific gravity of at most 2.7, which has an average thermal expansion coefficient from 50 to 350° C. of from 80×10?7/° C. to 90×107/° C., which has a glass transition temperature of at least 640° C.Type: ApplicationFiled: June 20, 2011Publication date: October 13, 2011Applicant: ASAHI GLASS COMPANY LIMITEDInventors: Kensuke NAGAI, Yuichi Kuroki, Kei Maeda
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Patent number: 8027012Abstract: To provide a liquid crystal display panel which can be produced at low cost by using inexpensive alkali glass for at least an opposing glass substrate, which is free from troubles in a liquid crystal display due to panel warpage attributable to the thermal treatment since such treatment is not required in the production process, and further which is free from panel warpage which tends to bring a trouble in a liquid crystal display derived from the difference in the thermal expansion coefficient by change in ambient temperature at the time of use. A liquid crystal display panel comprising an array glass substrate and an opposing glass substrate facing it, in which a liquid crystal is filled between such substrates, and an ultraviolet curable resin is sealed at a peripheral area, wherein the above opposing glass substrate is an alkali glass substrate, and the difference in thermal expansion coefficient between the above array glass substrate and the above opposing glass substrate is at most 35×10?7/° C.Type: GrantFiled: December 18, 2008Date of Patent: September 27, 2011Assignee: Asahi Glass Company, LimitedInventors: Tomoyuki Shimizu, Junichiro Kase
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Patent number: 8017537Abstract: The present invention provides a glass article using a glass composition including a base glass composition and colorants. The base glass composition includes, expressed in mass %: 65 to 80% of SiO2; 0 to 5% of Al2O3; 0 to 10% of MgO; 0 to 15% of CaO; 5 to 15% of MgO+CaO; 10 to 18% of Na2O; 0 to 5% of K2O; 10 to 20% of Na2O+K2O; and 0 to 5% of B2O3, and the colorants consist essentially of, expressed in mass %: 0.6% to 1.0% of T-Fe2O3; 0.026 to 0.8% of TiO2; 0 to 2.0% of CeO2; 0.01 to 0.03% of CoO; 0 to 0.0008% of Se; and 0.06 to 0.20% of NiO. The glass article has a grayish color tone, and has a visible light transmittance in a range of 15% to 40%, which is measured with the illuminant A at a thickness of 3.1 mm.Type: GrantFiled: October 31, 2006Date of Patent: September 13, 2011Assignee: Nippon Sheet Glass Company, LimitedInventors: Hiromitsu Seto, Akihiro Koyama, Yukihito Nagashima
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Patent number: 8017538Abstract: The invention relates to a dark gray soda-lime silicate glass composition which includes a coloring part essentially consisting of the compounds below in contents varying within the following weight limits: Fe2O3 (total iron) 0.7 to 0.95% CoO ?50 to 80 ppm NiO 400 to 700 ppm or Fe2O3 (total iron) 0.7 to 0.95% CoO 200 to 300 ppm NiO 1500 to 1900 ppm? said composition being free of selenium, having a redox of 0.40 or less, and the glass having a light transmission factor (TLA) under illuminant A of 50% or less and an overall energy transmission factor (TE) of less than 45%, these being measured for a thickness of 3.85 mm.Type: GrantFiled: October 29, 2009Date of Patent: September 13, 2011Assignee: Saint-Gobain Glass FranceInventors: Laurent Teyssedre, Lionel Homo
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Patent number: 7993137Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.Type: GrantFiled: November 11, 2010Date of Patent: August 9, 2011Assignee: Ivoclar Vivadent AGInventors: Elke Apel, Wolfram Holland, Marcel Schweiger, Christian Ritzberger, Harald Burke, Volker Rheinberger
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Patent number: 7989375Abstract: An object is to provide a readily fusible glass fiber composition that can alleviate environmental problem and reduce raw material cost by decreasing boron content, and that can facilitate the manufacturing of fine-count glass filament. A glass fiber composition of the present invention is an oxide glass composition, and has compositions of 0.01 to 3% of P2O5, 52 to 62% of SiO2, 10 to 16% of Al2O3, 0 to 8% of B2O3, 0 to 5% of MgO, 16 to 30% of CaO, and 0 to 2% of R2O(R?Li+N+K), which are in terms of oxide represented in mass percentage.Type: GrantFiled: July 3, 2006Date of Patent: August 2, 2011Assignee: Nippon Electric Glass Co., Ltd.Inventor: Toshikatu Tanaka
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Patent number: 7977263Abstract: A glass composition is provided for the production of high temperature glass fibers with oxides comprising 1% to 15% Fe2O3+FeO as a fluidizer to lower liquidous temperature and the fiberizing temperature of a mix of high temperature oxides. The glass composition has therein an appropriate content of high temperature oxides to produce glass fiber with high temperature limits and high burn-through properties.Type: GrantFiled: May 26, 2006Date of Patent: July 12, 2011Assignee: Glass IncorporatedInventor: Albert Lewis
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Glass composition for lamp, lamp, backlight unit and method for producing glass composition for lamp
Patent number: 7977262Abstract: A glass composition which contains Ce ions as a component substantially comprises, in terms of oxides, SiO2: 55 to 75 wt %, B2O3: 6 to 25 wt %, CeO2: 0.01 to 5 wt %, SnO: 0.01 to 5 wt %, Al2O3: 0 to 10 wt %, Li2O: 0 to 10 wt %, Na2O: 0 to 10 wt %, K2O: 0 to 10 wt %, MgO: 0 to 5 wt %, CaO: 0 to 10 wt %, SrO: 0 to 10 wt %, BaO 0 to 10 wt %, TiO2: 0 to 1.0 wt %, Fe2O3: 0.01 to 0.2 wt %, Sb2O3: 0 to 5 wt %, ZrO2: 0.01 to 5 wt %. By having such constituents, the glass composition is capable of suppressing transmission of ultraviolet light and solarization, and thus the glass composition hardly suffers from initial coloring or coloring during lamp production.Type: GrantFiled: March 28, 2006Date of Patent: July 12, 2011Assignee: Panasonic CorporationInventors: Atsushi Motoya, Yasurou Niguma -
Patent number: 7968482Abstract: Provided is a glass substrate, which has a substrate size of 1,100 mm×1,250 mm or more, and a transmittance at a wavelength of 500 to 800 nm and at a route length of 50 mm of 80% or more.Type: GrantFiled: March 5, 2009Date of Patent: June 28, 2011Assignee: Nippon Electric Glass Co., Ltd.Inventors: Hiroshi Komori, Shinkichi Miwa
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Patent number: 7964262Abstract: The disclosure provides a composition including a porous cordierite honeycomb body as defined herein having excellent strength, high thermal shock resistance, and reduced microcrack properties. The disclosure also provides methods of making and using the composition, for example, as a catalyst carrier.Type: GrantFiled: June 28, 2007Date of Patent: June 21, 2011Assignee: Corning IncorporatedInventors: Yves Andre Henri Brocheton, Dilip Kumar Chatterjee, Michele Fredholm, Gregory Albert Merkel, Steven Bolaji Ogunwumi
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Publication number: 20110135938Abstract: The object of the invention is a continuous method for obtaining glass, comprising steps consisting of: charging raw materials upstream of a furnace, along which a plurality of burners is disposed, obtaining a mass of molten glass, and then leading said mass of molten glass to a zone of the furnace situated further downstream, at least one burner disposed in the region of this zone being fed with an over-stoichiometric quantity of oxidant, and then, forming a glass sheet, said glass sheet having a chemical composition that comprises the following constituents in an amount varying within the weight limits defined below: SiO2 60-75%? Al2O3 0-10% B2O3 0-5%, preferably 0? CaO 5-15% MgO 0-10% Na2O 5-20% K2O 0-10% BaO 0-5%, preferably 0, SO3 0.1-0.4%? Fe2O3 (total iron) 0 to 0.015%,?? Redox 0.1-0.3.Type: ApplicationFiled: September 1, 2009Publication date: June 9, 2011Applicant: Saint-Gobain Glass FranceInventors: Byoung-Ouk Kim, Kidong Moon, Junbo Choi, Pedro Silva
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Patent number: 7951312Abstract: The borosilicate glass for pharmaceutical packaging has a transmission ? in the visible range of more than 80% at a wavelength of 400 nm, a transmission ? in the UV range of at most 0.1% at wavelengths under 260 nm (each at a sample thickness of 1 mm), a transformation temperature Tg of 550° C. to 590° C. and a processing temperature VA of 1100° C. to 1200° C. The glass has a composition, in wt. % on an oxide basis, of SiO2, 60-80; B2O3, 5-15; Al2O3, 2-10; TiO2, 0.5-7; ? Li2O+K2O+Na2O, 3-10; ? alkaline earth oxides, 0.5-10; ZrO2, 0-3; and Fe2O3, 0-0.2. The glass is suitable for packaging UV-sensitive substances but nevertheless permits optical quality control.Type: GrantFiled: April 29, 2009Date of Patent: May 31, 2011Assignee: Schott AGInventors: Franz Ott, Joerg Hinrich Fechner, Max Raster, Reinhard Maennl
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Publication number: 20110123832Abstract: An aspect of the present invention relates to glass for a magnetic recording medium substrate, which comprises, denoted as molar percentages, 50 to 75 percent of SiO2, 0 to 5 percent of Al2O3, 0 to 3 percent of Li2O, 0 to 5 percent of ZnO, a total of Na2O and K2O of 3 to 15 percent, a total of MgO, CaO, SrO, and BaO of 14 to 35 percent, a total of ZrO2, TiO2, La2O3, Y2O3, Yb2O3, Ta2O5, Nb2O5, and HfO2 of 2 to 9 percent, with a molar ratio of {(MgO+CaO)/(MgO+CaO+SrO+BaO)} falling within a range of 0.85 to 1, and a molar ratio of {Al2O3/(MgO+CaO)} falling within a range of 0 to 0.30.Type: ApplicationFiled: August 10, 2010Publication date: May 26, 2011Applicant: HOYA CORPORATIONInventors: Naomi Matsumoto, Yoichi HACHITANI, Kinobu OSAKABE
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Patent number: 7946128Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs). The glass compositions possess numerous properties that are compatible with the downdraw process, particularly fusion drawing.Type: GrantFiled: March 16, 2010Date of Patent: May 24, 2011Assignee: Corning IncorporatedInventors: Lauren Kay Cornelius, Adam James Ellison, Shari Elizabeth Koval
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Publication number: 20110118100Abstract: A method of smelting a nickel intermediate product in a smelter that contains a molten bath of metal and slag to produce a nickel product, the method comprising supplying the nickel intermediate product and a solid reductant to the smelter and smelting the nickel intermediate product to produce molten nickel, and controlling the chemistry of the slag so that the slag has (a) a high solubility for elements and compounds in the nickel intermediate product that are regarded as contaminants in the nickel product and (b) a liquidus temperature in the range of 1300-1700 C.Type: ApplicationFiled: February 12, 2009Publication date: May 19, 2011Inventors: Ivan Ratchev, Gregory David Rigby, René Ignacio Olivares, Grant Caffery
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Patent number: 7935649Abstract: Alkali-free glasses are disclosed which can be used to produce substrates for flat panel display devices, e.g., active matrix liquid crystal displays (AMLCDs). The glasses contain iron and tin as fining agents, and preferably are substantially free of arsenic and antimony. In certain embodiments, the glasses are also substantially free of barium. Methods for producing alkali-free glass sheets using a downdraw process (e.g., a fusion process) are also disclosed.Type: GrantFiled: April 8, 2010Date of Patent: May 3, 2011Assignee: Corning IncorporatedInventor: Adam James Gillmar Ellison
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Publication number: 20110098172Abstract: The invention discloses boron-free neutral glasses having the composition (in % by weight, based on oxide) 65-72 SiO2, 11-17 Al2O3, 0.1-8 Na2O, 3-8 MgO, 4-12 CaO and 0-10 ZnO, a ratio CaO/MgO of 1.4 to 1.6, and having a hydrolytic resistance in accordance with DIN ISO 719 in class 1 and an acid resistance in accordance with DIN 12116 and an alkali resistance in accordance with DIN ISO 695 at least in class 2.Type: ApplicationFiled: October 25, 2010Publication date: April 28, 2011Inventor: Peter BRIX
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Patent number: 7932198Abstract: A grey glass composition employing in its colorant portion at least iron (Fe2O3/FeO), cobalt and selenium is provided. The glass allows high visible transmission, and good IR absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe2O3) 0.20 to 0.40% selenium 2-20 ppm cobalt oxide 0.0025 to 0.0060% titanium oxide ??0 to 1.0% glass redox: <=0.30.Type: GrantFiled: November 5, 2007Date of Patent: April 26, 2011Assignee: Guardian Industries Corp.Inventors: Richard Hulme, Scott V. Thomsen
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Publication number: 20110091704Abstract: A process for producing a plate glass for a display device having a thickness of at most 1.5 mm by a float process, wherein the plate glass comprises, as represented by mole percentage based on the following oxides, from 67 to 75% of SiO2, from 0 to 4% of Al2O3, from 7 to 15% of Na2O, from 1 to 9% of K2O, from 6 to 14% of MgO and from 0 to 1.5% of ZrO2, has a total content of SiO2 and Al2O3 of from 71 to 75%, has a total content Na2O+K2O of Na2O and K2O of from 12 to 20%, and has a content of CaO of less than 1% if contained.Type: ApplicationFiled: September 22, 2010Publication date: April 21, 2011Applicant: Asahi Glass Company, LimitedInventors: Shusaku AKIBA, Kazutaka Hayashi
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Publication number: 20110086241Abstract: The provided are a glass for a magnetic recording medium substrate permitting the realization of a magnetic recording medium substrate affording good chemical durability and having an extremely flat surface, a magnetic recording medium substrate comprised of this glass, a magnetic recording medium equipped with this substrate, and methods of manufacturing the same. Glasses for a magnetic recording medium substrate are, glass I comprised of an oxide glass, comprising, denoted as mass percentages: Si 20 to 40 percent, Al 0.1 to 10 percent, Li 0.1 to 5 percent, Na 0.1 to 10 percent, K 0 to 5 percent (where the total content of Li, Na, and K is 15 percent or less), Sn 0.005 to 0.6 percent, and Ce 0 to 1.2 percent; the Sb content is 0 to 0.1 percent; and not comprising As or F; glass II comprised of oxide glass, comprising, as converted based on the oxide, denoted as molar percentages: SiO2 60 to 75 percent, Al2O3 1 to 15 percent, Li2O 0.1 to 20 percent, Na2O 0.Type: ApplicationFiled: March 18, 2009Publication date: April 14, 2011Applicant: HOYA CORPORATIONInventors: Yoichi Hachitani, Kinobu Osakabe
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Publication number: 20110073182Abstract: A solar unit glass plate having a composition comprising the following constituents, the amounts of which are expressed as percentages by weight: SiO2 60-75%; Al2O3 0-5%; Na2O 10-18%; K2O 0-5%; CaO 0-11%; MgO 0-5%; SO3 0-1%; Fe2O3<0.15%; and one or both of: SrO 0-15% and BaO 0-15%, with the proviso that the summed amount of SrO and BaO is greater than 1%. Also a glass plate for use as a cover plate or backing plate for a solar unit, the plate having a composition comprising the following constituents, similarly expressed: SiO2 65-74%; Al2O3 0-3%; Na2O 12-15%; K2O 0-2%; CaO 0-11%; MgO 0-2%; SO3 0-1%; Fe2O3 (total iron)<0.1%; and one or both of: SrO 2-10% and BaO 1.5-10%, with the proviso that the summed amount of SrO and BaO is greater than 2%.Type: ApplicationFiled: June 9, 2009Publication date: March 31, 2011Inventors: Shona Taylor, Neil McSporran
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Publication number: 20110070444Abstract: Disclosed is a glass flake (10) having improved heat resistance and improved chemical durability, which is composed of a glass base material satisfying, as expressed in mass %, 65?SiO2?70, 5?Al2O3?15, 1?MgO?10, 10?CaO?25 and 0.1?(Li2O+Na2O+K2O)?4. The temperature difference ?T obtained by taking the devitrification temperature of the glass base material from the working temperature thereof is preferably within the range of 0° C. to 200° C. The glass transition temperature of the glass base material is preferably within the range of 580° C. to 800° C. Furthermore, it is desirable that the value of ?W, which serves as an index for the acid resistance of the glass base material forming the glass flake (10), is within the range of 0.05 to 0.8 mass %.Type: ApplicationFiled: May 28, 2009Publication date: March 24, 2011Applicant: NIPPON SHEET GLASS COMPANY, LIMITEDInventors: Kosuke Fujiwara, Akihiro Koyama
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Publication number: 20110064951Abstract: Disclosed is a glass flake (10) having improved heat resistance and improved chemical durability, which is composed of a glass base material satisfying, as expressed in mass %, 60?SiO2?70, 5?Al2O3?15, 1?MgO?10, 10?CaO?25 and 4<(Li2O+Na2O+K2O)<9. The temperature difference ?T obtained by taking the devitrification temperature of the glass base material from the working temperature thereof is preferably within the range of 0-200° C. The glass transition temperature of the glass base material is preferably within the range of 560-750° C. It is desirable that the value of ?W, which serves as an index for the acid resistance of the glass base material, is within the range of 0.05-1.2 mass %.Type: ApplicationFiled: May 28, 2009Publication date: March 17, 2011Applicant: NIPPON SHEET GLASS COMPANY, LIMITEDInventors: Kosuke Fujiwara, Akihiro Koyama
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Publication number: 20110059836Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.Type: ApplicationFiled: November 11, 2010Publication date: March 10, 2011Applicant: IVOCLAR VIVADENT AGInventors: Elke Apel, Wolfram Höland, Marcel Schweiger, Christian van t'Hoen, Harald Bürke, Volker M. Rheinberger
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Patent number: 7902097Abstract: The present invention is to provide a neutral gray colored glass composition that has a soda-lime-silica glass base composition containing as major colorants 0.30 to 0.70% by weight Fe2O3; 0 to 30 ppm of Co3O4; 1 to 20 ppm of Se; and 20 to 200 ppm of CuO. The glass provides an illuminant “A” light transmission greater of 65%, a total solar energy transmittance of less than or equal to 60%, a solar ultraviolet transmittance of less than 46%; a dominant wavelength from 490 nm to 600; and an excitation purity of less than 6.Type: GrantFiled: December 8, 2008Date of Patent: March 8, 2011Assignee: Vidrio Plano De Mexico, S.A. De C.V.Inventors: Jose Guadalupe Cid-Aguilar, Miguel Angel Kiyama-Rodriguez
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Publication number: 20110052907Abstract: [Object] To develop a noble glass composition which is based on a known potassium-zinc crystal glass composition suitable for chemical strengthening, in which most of contained ZnO component is replaced with a combination of far inexpensive other oxides, which is easily to melt in a tank and to form by machine into table wares, which satisfies the legal conditions as crystal glass specified in glass composition, refractive index, and density, and which is superior in chemical strengthening suitability; and to provide a chemical strengthened crystal glass article which has high practical strength as a table ware and can be subjected to washing with an alkali.Type: ApplicationFiled: May 2, 2008Publication date: March 3, 2011Inventors: Noriaki Shibata, Hirokazu Toyoda, Keiko Tamamaki
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Publication number: 20110053754Abstract: A glass composition useful in preparing fiberglass comprises 12 to 25 weight % CaO; 12 to 16 weight % Al2O3; 52 to 62 weight % SiO2; 0.05 to 0.8 Fe2O3; and greater than 2 up to about 8 weight % alkali metal oxide.Type: ApplicationFiled: September 1, 2009Publication date: March 3, 2011Inventors: Jeffrey Shock, Elam Leed, Jonathan McCann
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Publication number: 20110045961Abstract: A glass that is down-drawable and ion exchangeable. The glass has a temperature T35kp which the viscosity is 35 kilopoise. T35kp less than the breakdown temperature Tbreakdown of zircon.Type: ApplicationFiled: August 16, 2010Publication date: February 24, 2011Inventors: Matthew John Dejneka, Adam James Ellison, Benjamin Zain Hanson
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Patent number: 7893350Abstract: Certain example embodiments of this invention relate to a high transmission low iron glass, which is highly oxidized and made using the float process, for use in photovoltaic devices such as solar cells or the like. In certain example embodiments, the glass composition used for the glass is made via the float process using an extremely high and positive batch redox in order to reduce % FeO to a low level and permit the glass to consistently realize a combination of high visible transmission (Lta or Tvis), high infrared (IR) transmission, and high total solar (TS) transmission. The glass substrate may be patterned or not patterned in different example embodiments of this invention.Type: GrantFiled: May 5, 2009Date of Patent: February 22, 2011Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Richard Hulme, Leonid M. Landa, Ksenia A. Landa
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Patent number: 7892999Abstract: A float glass for a display substrate, characterized in that its composition consists essentially of, as represented by mass % based on oxide, from 52 to 62% of SiO2, from 5 to 15% of Al2O3, from more than 0% to 9% of MgO, from 3 to 12% of CaO, from 9 to 18% of SrO, from 0 to 13% of BaO, from 25 to 30% of MgO+CaO+SrO+BaO, from 6 to 14% of Na2O+K2O+Li2O, from 0 to 6% of ZrO2 and from 0 to 1% of SO3, the temperature of glass melt corresponding to the viscosity of 102 dPa·s is at most 1,520° C., the temperature of glass melt corresponding to the viscosity of 104 dPa·s is at most 1,120° C., the glass transition temperature is at least 610° C., and the specific gravity is at most 2.9.Type: GrantFiled: November 10, 2008Date of Patent: February 22, 2011Assignee: Asahi Glass Company, LimitedInventors: Kensuke Nagai, Tetsuya Nakashima, Kei Maeda
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Patent number: 7884039Abstract: The invention relates to a dark gray soda-lime silicate glass composition which includes a coloring part essentially consisting of the compounds below in contents varying within the following weight limits: Fe2O3 (total iron) 0.7 to 0.95% CoO 50 to 80 ppm NiO 400 to 700 ppm or Fe2O3 (total iron) 0.7 to 0.95% CoO 200 to 300 ppm NiO 1500 to 1900 ppm said composition being free of selenium, having a redox of 0.40 or less, and the glass having a light transmission factor (TLA) under illuminant A of 50% or less and an overall energy transmission factor (TE) of less than 45%, these being measured for a thickness of 3.85 mm. The invention also relates to glass sheets, optionally thermally toughened, obtained from the aforementioned composition and to glazing comprising at least one of these sheets, especially as “privacy” windows for automobiles.Type: GrantFiled: March 21, 2005Date of Patent: February 8, 2011Assignee: Saint-Gobain Glass FranceInventors: Laurent Teyssedre, Lionel Homo
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Publication number: 20110017297Abstract: Sodium containing aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates or superstrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points?535° C., for example, ?570° C., thermal expansion coefficients of from 8 to 9 ppm/° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.Type: ApplicationFiled: July 21, 2010Publication date: January 27, 2011Inventors: Bruce Gardiner Aitken, James Edward Dickingson, JR., Timothy J. Kiczenski
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Patent number: 7875566Abstract: A method of making refractory alkaline earth silicate fibers from a melt, including the use as an intended component of alkali metal to improve the mechanical properties of the fiber in comparison with a fiber free of alkali metal.Type: GrantFiled: October 31, 2005Date of Patent: January 25, 2011Assignee: The Morgan Crucible Company PLCInventors: Craig John Freeman, Gary Anthony Jubb
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Publication number: 20110014475Abstract: Provided is a tempered glass, which has a compressive stress layer on a surface thereof, comprising, in terms of mol %, 40 to 80% of SiO2, 5 to 15% of Al2O3, 0 to 8% of B2O3, 0 to 10% of Li2O, 5 to 20% of Na2O, 0.5 to 20% of K2O, 0 to 10% of MgO, and 8 to 16.5% of Al2O3+MgO, wherein the glass has, in terms of a molar ratio, a (Li2O+Na2O+K2O)/Al2O3 ratio of 1.4 to 3, an Na2O/Al2O3 ratio of 1 to 3, and an MgO/Al2O3 ratio of 0 to 1, and is substantially free of As2O3, PbO, and F.Type: ApplicationFiled: September 18, 2008Publication date: January 20, 2011Inventor: Takashi Murata
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Patent number: 7871703Abstract: A glass composition for chemical tempering includes oxides in wt % ranges of: SiO2 60 to 75; Al2O3 18 to 28; Li2O 3 to 9; Na2O 0 to 3; K2O 0 to 0.5; CaO 0 to 3; MgO 0 to 3; ZrO2 0 to 3; where MgO+CaO is 0 to 6 wt %; Al2O3+ZrO2 is 18 to 28 wt %, and Na2O+K2O is 0.05 to 3.00 wt %. The glass has a log 10 viscosity temperature in the temperature range of 1328° F. (720° C.) to 1499° F. (815° C.); a liquidus temperature in the temperature range of 2437° F. (1336° C.) to 2575° F. (1413° C.), and a log 7.6 softening point temperature in the temperature range of 1544° F. (840° C.) to 1724° F. (940° C.). The chemically tempered glass has, among other properties, an abraded modulus of rupture of 72 to 78 KPSI, and a modulus of rupture of 76 to 112 KPSI.Type: GrantFiled: June 26, 2009Date of Patent: January 18, 2011Assignee: Schott AGInventors: Larry J. Shelestak, George B. Goodwin, Amarendra Mishra, James M. Baldauff
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Patent number: 7867933Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.Type: GrantFiled: October 17, 2008Date of Patent: January 11, 2011Assignee: Ivoclar Vivadent AGInventors: Elke Apel, Wolfram Holand, Marcel Schweiger, Christian Ritzberger, Harald Burke, Volker M. Rheinberger
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Publication number: 20110003483Abstract: To provide a glass plate for display panels which has a low 8203 content and a low compaction and which can be used as a glass substrate for large TFT panels. A glass plate for display panels, which comprises, as a glass matrix composition as represented by mass% based on oxide: SiO2 50.0 to 73.0, Al2O3 6.0 to 20.0, B2O3 0 to 2.0, MgO 4.2 to 9.0, CaO 0 to 6.0, SrO 0 to 2.0, BaO 0 to 2.0, MgO+CaO+SrO+BaO 6.5 to 11.3, Li2O 0 to 2.0, Na2O 2.0 to 18.0, K2O 0 to 13.0, and Li2O +Na2O+K2O 8.0 to 18.0, and has a heat shrinkage (C) of at most 20 ppm.Type: ApplicationFiled: September 16, 2010Publication date: January 6, 2011Applicant: Asahi Glass Company, LimitedInventors: Manabu NISHIZAWA, Yuya Shimada, Yuichi Kuroki, Kei Maeda
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Patent number: 7863208Abstract: A grey glass composition employing in its colorant portion at least iron (Fe2O3/FeO), cobalt and selenium is provided. The glass allows high visible transmission, and good IR absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe2O3) 0.20 to 0.35% selenium 0.0002 to 0.0020% cobalt oxide 0.0025 to 0.0060% titanium oxide ??0 to 1.0% glass redox: <=.27; or 0.10 to 0.25.Type: GrantFiled: September 4, 2007Date of Patent: January 4, 2011Assignee: Guardian Industries Corp.Inventors: Anna Broughton, Richard Hulme, Scott V. Thomsen
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Patent number: 7846859Abstract: A colored glass has a formula of R?20—RO—SiO2, wherein R? is an alkali metal element and R is an alkaline earth metal element. The colored glass comprises between 0.01 and 1% by weight of molybdenum expressed as MoO3 and between 0.01 and 2.5% by weight of sulfur expressed as SO3. The colored glass further comprises between 7.8 and 14% by weight of potassium expressed as K2O and between 0.68 and 5.42% by weight of sodium expressed as Na2O. The sum of the concentrations of potassium and sodium expressed as K2O and Na2O is between 11 and 17% by weight.Type: GrantFiled: September 21, 2006Date of Patent: December 7, 2010Assignee: Koninklijke Philips Electronics N.V.Inventors: Jean-Sebastien Straetmans, Simon Flink, Theodorus Herman Ketelaar, Raoul Hendrinkus Elisabeth Maria Martens
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Publication number: 20100300535Abstract: Sodium-containing aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points ?540° C., thermal expansion coefficient of from 6.5 to 9.5 ppm/° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.Type: ApplicationFiled: May 26, 2010Publication date: December 2, 2010Inventors: Bruce Gardiner Aitken, James Edward Dickinson, JR., Timothy J. Kiczenski, Michelle Diane Pierson-Stull
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Publication number: 20100304949Abstract: The invention relates to a glass sheet, the composition of which is of the soda-lime-silica type and comprises the following constituents in contents varying within the weight limits defined below: Fe2O3 (total iron) ??0 to 0.02%; and K2O 1.5 to 10%.Type: ApplicationFiled: September 19, 2008Publication date: December 2, 2010Applicant: SAINT-GOBAIN GLASS FRANCEInventors: Dominique Sachot, Octavio Cintora
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Patent number: 7838452Abstract: An ultraviolet ray transmitting glass composition including the following components, in terms of mass % or mass ppm: 60 to 79% SiO2; 0 to 1% B2O3; exceeded 0% but not more than 20% Al2O3; 0 to 10% Li2O; 5 to 20% Na2O; 0 to 15% K2O; 0 to 10% MgO; 0 to 10% CaO; 0 to 15% SrO; 0 to 2% refining agent; 2 to 20 ppm T-Fe2O3 (in which T-Fe2O3 denotes a total iron oxide content obtained by converting all of iron compounds into Fe2O3); and 0 to 200 ppm TiO2. The ultraviolet ray transmitting glass composition is suitable for a glass article, such as a bioanalytical device that is used for analysis using ultraviolet rays.Type: GrantFiled: April 5, 2006Date of Patent: November 23, 2010Assignee: Nippon Sheet Glass Company, LimitedInventors: Junji Kurachi, Koji Fujita, Haruki Niida, Akihiro Koyama
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Patent number: 7833919Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs). In accordance with certain of its aspects, the glasses possess good dimensional stability as a function of temperature.Type: GrantFiled: February 9, 2007Date of Patent: November 16, 2010Assignee: Corning IncorporatedInventors: Paul S. Danielson, Adam J. G. Ellison, Natesan Venkataraman
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Patent number: 7825051Abstract: A glass composition is disclosed. The glass composition includes base glass composition including SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent, and BaO from 0 to 1 weight percent, and a colorant and property modifying portion including total iron from up to 0.02 weight percent, CeO2 from 0.05 weight percent to 1.5 weight percent, CoO up to 50 PPM, Se up to 15 PPM, Cr2O3 up to 500 PPM, CuO up to 0.5 weight percent, V2O5 up to 0.3 weight percent, TiO2 up to 1 weight percent, NiO up to 200 PPM, Er2O3 up to 3 weight percent, MnO2 up to 0.6 weight percent, and Nd2O3 up to 2 weight percent, wherein the glass composition has a redox ratio up to 0.55.Type: GrantFiled: January 12, 2006Date of Patent: November 2, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Dennis G. Smith, Larry J. Shelestak
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Patent number: 7825288Abstract: The present invention provides processes to immobilize radioactive and/or hazardous waste in a borosilicate glass, the waste containing one or more of radionuclides, hazardous elements, hazardous compounds, and/or other compounds. The invention also provides borosilicate glass compositions for use in immobilizing radioactive and/or hazardous waste.Type: GrantFiled: June 22, 2009Date of Patent: November 2, 2010Assignee: GeoMatrix Solutions, Inc.Inventors: Anatoly Chekhmir, Arthur Gribetz
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Publication number: 20100273635Abstract: Disclosed is a glass composition including 60 to 70% by mass of SiO2, 0.5 to 3.0% by mass of Al2O3, 2 to 8% by mass of Na2O, 5 to 15% by mass of K2O, 8 to 13% by mass of MgO, 0 to 5% by mass of CaO, 0 to 8% by mass of SrO and 0.5 to 5% by mass of ZrO2, and substantially excluding BaO and B2O3, wherein a total amount of Na2O and K2O is 8 to 18% by mass, and a total amount of MgO, CaO and SrO is 10 to 22% by mass.Type: ApplicationFiled: December 22, 2008Publication date: October 28, 2010Applicant: CentralGlass Company, LimitedInventors: Tatsuya Tsuzuki, Naoki Mitamura
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Publication number: 20100273631Abstract: The present invention relates to a process for reinforcing a glass-ceramic article, into which a maximum tension is introduced beneath the surface of the glass-ceramic, advantageously in proximity to said surface. The invention also relates to an enamel that can be used for this reinforcement, this enamel being formed from a glass frit having the following composition, the proportions being expressed as weight percentages: SiO2 50-66%? MgO 3-8% Na2O 7-15%? K2O 0-3% Li2O 0-12%? CaO 0-10%? BaO 0-15%? Al2O3 0-3% ZrO2 0-3% ZnO 0-5% B2O3 0-8% the sum of the alkaline-earth metal oxides CaO+BaO moreover being between 8 and 15%, and the sum of the alkali metal oxides Na2O+K2O+Li2O moreover being between 7 and 20%. The invention also relates to the reinforced glass-ceramics obtained.Type: ApplicationFiled: January 16, 2009Publication date: October 28, 2010Applicant: EUROKERA S.N.C.Inventors: Stephanie Pelletier, Marie-Helene Chopinet, Caroline Faillat, Marie-Helene Rouillon, Pablo Vilato
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Patent number: 7820575Abstract: The present invention provides a near-infrared absorbent green glass composition which contains basic glass components and 0.6 to 1.3% total iron oxide amount in terms of Fe2O3 (T-Fe2O3), 0 to 2.0% CeO2 and, 300 ppm or less MnO expressed in units of mass and wherein a mass ratio (FeO ratio) of FeO converted into Fe2O3 relative to the T-Fe2O3 is from 0.21 to 0.35. Further the glass composition satisfies at least one of the following a) and b): a) when the glass composition is formed to have a thickness in the range of 1.3 to 2.Type: GrantFiled: December 24, 2004Date of Patent: October 26, 2010Assignee: Nippon Sheet Glass Company, LimitedInventors: Yukihito Nagashima, Hiromitsu Seto, Harunori Murakami, Hiroyuki Tanaka