Magnesium Aluminosilicate (e.g., Cordierite, Etc.) Patents (Class 501/9)
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Patent number: 11670459Abstract: A multilayer capacitor includes a capacitor body including dielectric layers and first and second internal electrodes, the capacitor body having first to sixth surfaces, the first internal electrode being exposed through the third, fifth, and sixth surfaces, and the second internal electrode being exposed through the fourth, fifth, and sixth surfaces, a first side portion and a second side portion, respectively disposed on the fifth surface and the sixth surface of the capacitor body, and a first external electrode and a second external electrode, respectively be connected to the first internal electrode and the second internal electrode. The first and second side portions comprise an acicular second phase including a glass comprising aluminum (Al) and silicon (Si), manganese (Mn), and phosphorus (P), and a volume of the second phase is 30% or more with respect to the entire first and second side portions.Type: GrantFiled: November 18, 2021Date of Patent: June 6, 2023Assignee: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Sim Chung Kang, Yong Park, Woo Chul Shin, Ki Pyo Hong
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Patent number: 11309132Abstract: A multilayer capacitor includes a capacitor body including dielectric layers and first and second internal electrodes, the capacitor body having first to sixth surfaces, the first internal electrode being exposed through the third, fifth, and sixth surfaces, and the second internal electrode being exposed through the fourth, fifth, and sixth surfaces, a first side portion and a second side portion, respectively disposed on the fifth surface and the sixth surface of the capacitor body, and a first external electrode and a second external electrode, respectively be connected to the first internal electrode and the second internal electrode. The first and second side portions comprise an acicular second phase including a glass comprising aluminum (Al) and silicon (Si), manganese (Mn), and phosphorus (P), and a volume of the second phase is 30% or more with respect to the entire first and second side portions.Type: GrantFiled: April 27, 2020Date of Patent: April 19, 2022Assignee: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Sim Chung Kang, Yong Park, Woo Chul Shin, Ki Pyo Hong
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Patent number: 11193219Abstract: The present disclosure relates to tellurite crystals, growing methods of the same, and applications thereof; the crystals a chemical formula of MTe3O8, wherein M=Ti, Zr, Hf, which belongs to an Ia-3 space group of a cubic crystal system, wherein a transmittance waveband ranges from visible light to infrared light, with a transparency ?70%. According to the present disclosure, a growing method of a tellurite crystal is provided, wherein the crystal may be grown using a flux method, a Czochralski method, or a Bridgman-Stockbarger method. The tellurite crystals may be used as an acousto-optic crystal for fabricating an optical modulation device. The present disclosure takes the lead internationally in growing the tellurite single crystals, the size and quality of which sufficiently meet the demands of practical applications of the tellurite single crystals.Type: GrantFiled: September 30, 2017Date of Patent: December 7, 2021Assignee: SHANDONG UNIVERSITYInventors: Xutang Tao, Weiqun Lu, Zeliang Gao, Youxuan Sun, Qian Wu
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Patent number: 9409814Abstract: Provided is a crystallizable glass composition which exhibits a high coefficient of thermal expansion after undergoing thermal treatment, has excellent fluidity during the thermal treatment, and is less likely to deteriorate the hermeticity and adhesiveness at bonded portions and volatilize glass components even when exposed to high temperatures for a long period after the thermal treatment. A crystallizable glass composition capable of precipitating MgO-based crystals as main crystals by thermal treatment, the crystallizable glass composition containing, in terms of % by mole in glass component composition, 0.1 to 30% La2O3+Nb2O5+Y2O3+Ta2O5+Yb2O3.Type: GrantFiled: August 13, 2012Date of Patent: August 9, 2016Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventor: Yoshihisa Takayama
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Patent number: 8685290Abstract: Disclosed is a plurality of glass-crystalline particles, wherein at least a portion of the glass-crystalline particles comprise a glass component and a crystalline component, and wherein the crystalline component comprises one or more metal oxides wherein the metal is selected from the group consisting of: Zn, Ca, Sr, Mg, Ba, and mixtures thereof.Type: GrantFiled: September 27, 2010Date of Patent: April 1, 2014Assignee: E I du Pont Nemours and CompanyInventors: Eric Lee Brantley, John T. Chaplinsky, Howard David Glicksman, James J. Krajewski, Brian J. Laughlin, Kurt Richard Mikeska, Lawrence V. Triboletti
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Publication number: 20140066283Abstract: A glass ceramic composition that contains a first ceramic including at least one of MgAl2O4 and Mg2SiO4; a second ceramic including BaO, RE2O3 (RE is a rare-earth element), and TiO2; glass containing each of 44.0 to 69.0 weight % of RO (R is an alkaline-earth metal), 14.2 to 30.0 weight % of SiO2, 10.0 to 20.0 weight % of B2O3, 0.5 to 4.0 weight % of Al2O3, 0.3 to 7.5 weight % of Li2O, and 0.1 to 5.5 weight % of MgO; and MnO.Type: ApplicationFiled: November 11, 2013Publication date: March 6, 2014Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Kazuhiro Kaneko, Sadaaki Sakamoto, Hiroshige Adachi, Satoru Adachi, Seiji Fujita
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Patent number: 8431498Abstract: The invention provides a crystallizable glass, a crystallized glass, and manufacturing methods thereof. The crystallizable glass can be crystallized in a short period of time, and can maintain its glass shape and its surface condition during a crystallization process. The crystallized glass has good mechanical strength, an adequate thermal expansion coefficient that allows the crystallized glass to be used as a construction material, less content of alkali-metal oxides, and good chemical durability. The MgO—Al2O3—SiO2-based crystallizable glass and crystallized glass contain, by mass percent, 55.0-65.0% SiO2, 8.0-14.0% Al2O3, 10.0-20.0% MgO, 1.5-6.0% CaO, 1.0-2.2% Li2O, 0.7-3.0% Na2O, 2.5-4.0% K2O, and 1.5-3.0% F.Type: GrantFiled: October 25, 2010Date of Patent: April 30, 2013Assignees: Huzhou Ta Hsiang Glass Products Co., Ltd., Ta Hsiang Containers Inc. Do., Ltd.Inventors: Kuo-Chuan Hsu, Chao Qu
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Patent number: 8394732Abstract: Disclosed is the preparation of sintered cordierite-based glass-ceramic bodies via a procedure which uses three all natural starting materials which are white sand, kaolin clay and magnesite. These three raw materials are combined in relative amounts which form, upon subsequent mixing and heating, a specific mixture of oxides of silicon, aluminum and magnesium. Upon melting at 1500-1550° C., this combination of raw materials forms transparent brown glass which after solidification by quenching is then crushed and reduced to grains having a median particle size less than 65 microns. These brown glass grains are consolidated, for example by compaction, to form a green body for sintering. Sintering of the green body at temperatures between about 1000° C. and 1375° C. for from 2 to 5 hours produces glass-ceramic bodies containing a polycrystalline material which comprises mostly material of the cordierite crystal structure.Type: GrantFiled: January 12, 2012Date of Patent: March 12, 2013Assignee: King Abdulaziz City for Science and TechnologyInventors: Omar A. Alharbi, Esmat M. Hamzawy
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Patent number: 8187691Abstract: A honeycomb structure includes at least one honeycomb unit. The at least one honeycomb unit has a longitudinal direction and includes zeolite and an inorganic binder. A content of the zeolite per apparent unit volume of the at least one honeycomb unit is about 230 g/L or greater. The at least one honeycomb includes plural cell walls extending from one end face to another end face along the longitudinal direction to define plural cell walls. A porosity of substantially all pores in the cell walls is about 40% or less. A porosity of pores having diameters in a range of about 0.005 ?m through about 0.02 ?m in the cell walls is about 5% or greater. A porosity of pores having diameters in a range of about 0.05 ?m through about 0.2 ?m in the cell walls is about 17.5% or greater.Type: GrantFiled: January 23, 2009Date of Patent: May 29, 2012Assignee: Ibiden Co., Ltd.Inventors: Kazushige Ohno, Masafumi Kunieda, Takahiko Ido
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Patent number: 8143180Abstract: Disclosed are cements for ceramic honeycomb bodies. Such cements can be applied to a fired ceramic honeycomb body then fired, or can be applied to an unfired (green) honeycomb body and co-fired with the green honeycomb body. The cement can also be used to plug one or more cells in a honeycomb body, wherein the cement can be inserted into a green or a fired ceramic honeycomb body, then fired. Also disclosed are methods of manufacturing a ceramic honeycomb article with the cement.Type: GrantFiled: October 22, 2008Date of Patent: March 27, 2012Assignee: Corning IncorporatedInventors: David A Earl, Tonia Havewala Fletcher, Robert John Paisley
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Patent number: 8038759Abstract: A method of manufacturing a fibrous material includes mixing at least two cordierite precursor materials to form a mixture. One or more of the at least two cordierite precursor materials is in a form of a fiber and the mixture includes about 43% to about 51% by weight SiO2, about 36% to about 41% by weight Al2O3, and about 12% to about 16% by weight MgO. The method also includes extruding the mixture to create a fibrous body, and heat treating the fibrous body, at a temperature of about 1200° C. to about 1420° C., to form the fibrous material including about 50% to about 95% by weight cordierite. A fibrous body includes an extruded substrate having a plurality of fibers including about 50% to about 95% by weight cordierite. The extruded substrate has a coefficient of thermal expansion in at least one direction of less than about 3.8·10?6 per ° C.Type: GrantFiled: July 12, 2008Date of Patent: October 18, 2011Assignee: Geoz Technologies, Inc.Inventors: James Jenq Liu, Bilal Zuberi, Rachel A. Dahl, William M. Carty
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Patent number: 7938876Abstract: A fibrous ceramic material comprises a plurality of fibers having a RxMg2Al4+xSi5?xO18 or RxMg2?xAl4Si5O18 compositional structure. The fibrous ceramic material is form by combining two or more RxMg2Al4+xSi5?xO18 or RxMg2?xAl4Si5O18 precursors in which at least one of the two or more RxMg2Al4+xSi5?xO18 or RxMg2?xAl4Si5O18 precursors is in fiber form. The fibrous ceramic material is shaped to form a fibrous body in which at least about 20% of all fibers therein are aligned in a substantially common direction.Type: GrantFiled: April 17, 2008Date of Patent: May 10, 2011Assignee: GE02 Technologies, Inc.Inventors: James Jenq Liu, William M. Carty, Bilal Zuberi, Sunilkumar C. Pillai
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Patent number: 7906444Abstract: The invention relates to a glass ceramic armour material consisting (in % by weight in relation to oxide base) of 5-33 SiO2, 20-50 Al2O3, 5-40 MgO, 0-15 B2O3, 0.1-30 Y2O3, Ln2O3, As2O3, Nb2O3 and/or Sc2O3 and 0-10 P2O5. The inventive armour material can also be reinforced with inorganic reinforcing fibres in a quantity of 5-65% by weight, preferably consisting of C, SiC, Si3N4, Al2O3, ZrO2 or Sialon. Said armour material is characterised in that it exhibits a high elasticity modulus and is producible from green glass without to fear a premature crystallisation.Type: GrantFiled: August 2, 2006Date of Patent: March 15, 2011Assignee: Schott AGInventors: Rainer Liebald, Wolfram Beier, Jochen Alkemper, Thilo Zachau, Dirk Sprenger
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Publication number: 20100273630Abstract: The invention relates to synthetic hybrid rock compositions, articles of manufacture and related processes employing mineral waste starting materials such as mine tailings, mine development rock, ash, slag, quarry fines, and slimes, to produce valuable articles of manufacture and products, which are characterized by superior physical and structural characteristics, including low porosity, low absorption, increased strength and durability, and retained plasticity. The resulting materials are compositionally and chemically distinct from conventional synthetic rock materials as demonstrated by scanning electron microprobe analysis, and are useful in a wide variety of applications, particularly with respect to commercial and residential construction.Type: ApplicationFiled: April 26, 2010Publication date: October 28, 2010Applicant: CERAMEXT, LLCInventors: Ross GUENTHER, James L. Wood, Carl E. Frahme, Ian I. Chang, Robert D. Villwock
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Patent number: 7727918Abstract: An optical glass that contains Si, Al, Mg, and O is provided. The optical glass contains Si in an amount of 40% or more and 60% or less, in cation percent, Al in an amount of 10% or more and 35% or less, in cation percent, and Mg in an amount of 20% or more and 35% or less, in cation percent. In the optical glass, the total amount of Si, Al, and Mg is 99.5% or more, in cation percent. Furthermore, the optical glass contains Fe and Na each in an amount of 0.01 wtppm or less and has a transmittance to a light having a wavelength of 248 nm of 40% or more at a thickness of 5 mm.Type: GrantFiled: October 31, 2007Date of Patent: June 1, 2010Assignee: Canon Kabushiki KaishaInventors: Tomohiro Watanabe, Taihei Mukaide, Hidenosuke Itoh
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Patent number: 7674735Abstract: The invention is directed to highly crystalline, frit-sintered glass-ceramic materials and seals made using them that are suitable for solid oxide fuel cell applications. The seals have a coefficient of thermal expansion in the range of 70-130×10?7° C., preferably 85-115×10?7° C. The glass-ceramic materials have a crystalline component and a glass component, the crystalline component being >50% of the glass-ceramic and the glass component being <50%. In one preferred embodiment the crystalline component is >75%. Regarding the crystalline component only, >50% of the crystals in the crystalline component of the glass-ceramic has a structure selected from the structural groups represented by walstromite, cyclowollastonite, ?-(Ca,Sr)SiO3, kalsilite, kaliophilite and wollastonite (the primary crystalline phase) and the remaining <50% of the crystalline component is at least one secondary crystalline phase.Type: GrantFiled: November 18, 2008Date of Patent: March 9, 2010Assignee: Corning IncorporatedInventors: Michael Edward Badding, Sasha Marjanovic, Linda Ruth Pinckney, Dell Joseph St Julien
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Patent number: 7618699Abstract: Substantially non-microcracked, porous, cordierite ceramic honeycomb bodies are provided. Although exhibiting moderately high thermal expansion (CTE) between 7×10?7 to 16×10?7/° C. (25-800° C.), the honeycomb bodies exhibit relatively high thermal shock parameter (TSP), such as TSR?525° C. by virtue of a high MOR/E ratio, and/or low Eratio=ERT/E1000° C. and well interconnected porosity, as witnessed by a relatively high pore connectivity factor (PCF). A method of manufacturing the honeycomb ceramic structure is also provided.Type: GrantFiled: June 28, 2007Date of Patent: November 17, 2009Assignee: Corning IncorporatedInventors: Douglas Munroe Beall, Isabelle Marie Melscoet-Chauvel, Gregory Albert Merkel, Tinghong Tao, David John Thompson
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Patent number: 7605110Abstract: A ceramic body, a ceramic catalyst body, a ceramic catalyst body and related manufacturing methods are disclosed wherein a cordierite porous base material has a surface, formed with acicular particles made of a component different from that of cordierite porous base material, which has an increased specific surface area with high resistance to a sintering effect. The ceramic body is manufactured by preparing a slurry containing an acicular particle source material, preparing a porous base material, applying the slurry onto a surface of the porous base material and firing the porous base material, whose surface is coated with the slurry, to cause acicular particles to develop on the surface of the porous base material. A part of or a whole of surfaces of the acicular particles is coated with a constituent element different from that of the acicular particles.Type: GrantFiled: April 5, 2007Date of Patent: October 20, 2009Assignees: Denso Corporation, Nippon Soken, Inc.Inventors: Keiichi Yamada, Kazuhiko Koike, Katsumi Yoshida, Hideki Kita, Naoki Kondo, Hideki Hyuga
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Patent number: 7575794Abstract: Porous, non-microcracked cordierite ceramic bodies having high strength, high strain tolerance, and high thermal shock resistance are produced from cordierite powder batch mixtures of controlled powder particle size fired according to a schedule that prevents objectionable cordierite grain growth, maintaining a small cordierite crystalline domain size in order to minimize or prevent microcracking in the product.Type: GrantFiled: August 29, 2007Date of Patent: August 18, 2009Assignee: Corning IncorporatedInventors: Margaret Kathleen Faber, Weiguo Miao, Tinghong Tao
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Patent number: 7520911Abstract: A porous cordierite ceramic honeycomb article with increased mechanical strength and thermal shock resistance. The porous cordierite ceramic honeycomb article has MA<2220, or MT>2660 wherein MA=3645(IA)?106(CTE)+19(d90)+17(% porosity), MT=4711(IT)+116(CTE)?26(d90)?28(% porosity), and a CTE?9×10?7/° C. in at least one direction. A method of manufacturing is also disclosed wherein the inorganic raw material mixture contains talc, an alumina-forming source, a silica-forming source, and 0-18 wt. % of a kaolin or calcined kaolin containing not more than 8 wt. % of a fine kaolin source having a median particle diameter of less than 7 ?m, wherein the fired porous ceramic cordierite honeycomb article has a porosity<54% . Alternatively, if greater than 8 wt. % of the fine kaolin source is used, then a slow ramp rate is utilized from 1200° C. to 1300° C. of not more than 20° C./hr.Type: GrantFiled: November 30, 2005Date of Patent: April 21, 2009Assignee: Corning IncorporatedInventors: Douglas Munroe Beall, Gregory Albert Merkel, David John Thompson
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Patent number: 7507683Abstract: A glass-ceramic material, particularly for elements in laser systems, and a method for preparing same. The glass-ceramic material may be used for an optical fiber for communication systems and laser systems. The glass-ceramic may include gahnite crystals and optionally ?-quartz-like solid solution, or a petalite-like crystals, spinel, and zirconia crystals. The elements may comprise a host material glass-ceramic, where the glass-ceramic is doped with appropriate ions.Type: GrantFiled: September 21, 2007Date of Patent: March 24, 2009Assignee: Elop Electro-Optics Industries Ltd.Inventors: Marina Sirota, Ehud Galun, Adrian Goldshtein, Alla Buch, Vladimir Krupkin, Rami Cohen, Alexander Glushko, Elena Luria
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Publication number: 20090069163Abstract: An internally nucleated, toughened cordierite glass-ceramic is disclosed. The cordierite glass-ceramic has good oxidation resistance and fracture toughness and coefficient of thermal expansion rivaling that of silicon nitride. The glass-ceramic may be cast as a liquid. Annealing produces a material of high crystallinity combining high hardness, high Young's modulus, good thermal stability, high strength, low density and good dielectric properties. The glass-ceramic comprises interlocking crystalline phases dominated by cordierite and a second phase having an elongated or acicular structure. A third phase may comprise a crystalline ceramic that promotes acicularity of the second phase. The third phase is preferably capable of twinning.Type: ApplicationFiled: November 7, 2008Publication date: March 12, 2009Inventor: George Halsey Beall
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Patent number: 7470640Abstract: The invention is directed to highly crystalline, frit-sintered glass-ceramic materials and seals made using them that are suitable for solid oxide fuel cell applications. The seals have a coefficient of thermal expansion in the range of 70-130×10?7° C., preferably 85-115×10?7° C. The glass-ceramic materials have a crystalline component and a glass component, the crystalline component being>50% of the glass-ceramic and the glass component being<50%. In one preferred embodiment the crystalline component is >75%. Regarding the crystalline component only,>50% of the crystals in the crystalline component of the glass-ceramic has a structure selected from the structural groups represented by walstromite, cyclowollastonite, ?-(Ca,Sr)SiO3, kalsilite, kaliophilite and wollastonite (the primary crystalline phase) and the remaining <50% of the crystalline component is at least one secondary crystalline phase.Type: GrantFiled: October 11, 2006Date of Patent: December 30, 2008Assignee: Corning IncorporatedInventors: Michael Edward Badding, Sasha Marjanovic, Linda Ruth Pinckney, Dell Joseph St Julien
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Patent number: 7465687Abstract: An internally nucleated, toughened cordierite glass-ceramic is disclosed. The cordierite glass-ceramic has good oxidation resistance and fracture toughness and coefficient of thermal expansion rivaling that of silicon nitride. The glass-ceramic may be cast as a liquid. Annealing produces a material of high crystallinity combining high hardness, high Young's modulus, good thermal stability, high strength, low density and good dielectric properties. The glass-ceramic comprises interlocking crystalline phases dominated by cordierite and a second phase having an elongated or acicular structure. A third phase may comprise a crystalline ceramic that promotes acicularity of the second phase. The third phase is preferably capable of twinning.Type: GrantFiled: May 31, 2006Date of Patent: December 16, 2008Assignee: Corning IncorporatedInventor: George Halsey Beall
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Publication number: 20080248707Abstract: The invention is based on the object of providing armoring that is lightweight and exhibits a denser microstructure that is improved as against ceramic composite materials. To this end, armoring against high dynamic impulsive loads is provided that comprises a composite material having at least two phases, the first phase forming a matrix for the second phase, and the first phase being a glass or a glass ceramic, and the second phase being embedded and distributed in the form of particles and/or fibers in the matrix formed by the material of the first phase.Type: ApplicationFiled: November 14, 2007Publication date: October 9, 2008Applicant: SCHOTT AGInventors: Rainer Liebald, Wolfram Beier, Jochen Alkemper, Ulrich Schiffner
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Patent number: 7306845Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.Type: GrantFiled: October 29, 2004Date of Patent: December 11, 2007Assignee: NeoPhotonics CorporationInventors: Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
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Publication number: 20070281850Abstract: An internally nucleated, toughened cordierite glass-ceramic is disclosed. The cordierite glass-ceramic has good oxidation resistance and fracture toughness and coefficient of thermal expansion rivaling that of silicon nitride. The glass-ceramic may be cast as a liquid. Annealing produces a material of high crystallinity combining high hardness, high Young's modulus, good thermal stability, high strength, low density and good dielectric properties. The glass-ceramic comprises interlocking crystalline phases dominated by cordierite and a second phase having an elongated or acicular structure. A third phase may comprise a crystalline ceramic that promotes acicularity of the second phase. The third phase is preferably capable of twinning.Type: ApplicationFiled: May 31, 2006Publication date: December 6, 2007Inventor: George Halsey Beall
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Patent number: 7300896Abstract: A glass ceramic comprises (in wt.-% on oxide basis): SiO2 35 to 60, B2O3>4 to 10, P2O5 0 to 10, Al2O3 16.5 to 40, TiO2 1 to 10, Ta2O5 0 to 8, Y2O3 0 to 6, ZrO2 1 to 10, MgO 6 to 20, CaO 0 to 10, SrO 0 to 4, BaO 0 to 8, ZnO 0 to 4, SnO2+CeO2 0 to 4, SO42?+Cl? 0 to 4, wherein the total content (SnO2+CeO2+SO42?+Cl?) is between 0.01 and 4 wt.-%. The glass ceramic may be processed by the float glass method, may be transparent and is, inter alia, suitable as a substrate for thin film semiconductors, in particular for display applications, solar cells etc.Type: GrantFiled: September 29, 2004Date of Patent: November 27, 2007Assignee: Schott AGInventors: Thilo Zachau, Rainer Liebald, Dirk Sprenger, Meike Lohmann
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Patent number: 7291571Abstract: The invention relates to crystallizable aluminosilicate magnesium-containing glass which is used for producing extremely solid and break-resistant glass-ceramics having an easily polished surface. The inventive crystallizable glass contains 5-33 mass % of SiO2, 25-40 mass % of Al2O3, 5-25 mass % of MgO, 0-15 mass % of B2O3, 0.1-30 mass % of Y2O3, Ln2O3, As2O3 and/or Nb2O5 and 0.1-10 mass % of P2O5.Type: GrantFiled: September 26, 2003Date of Patent: November 6, 2007Assignee: Schott AGInventors: Dirk Sprenger, Thilo Zachau, Rainer Liebald
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Patent number: 7172649Abstract: The disclosure relates to a leucite glass ceramic doped with nanoscale metal oxide, to a doped leucite glass ceramic powder suitable for its production, to a method for producing the doped leucite glass ceramic, to its use as dental material, to a dental product containing it and to the use of the nanoscale metal oxide powders for the production of the doped glass ceramic or of the doped leucite glass ceramic powder.Type: GrantFiled: December 30, 2003Date of Patent: February 6, 2007Assignees: Chemichl AGInventors: Thomas Conrad, Gerhard Meyer
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Patent number: 7087293Abstract: The present invention relates to a Cd-free and Pb-free glass composition comprising, based in mol %, 1–10% MO where M is selected from Ba, Sr, Ca and mixtures thereof, 5–30% MgO, 0.3–5% CuO, 0–2.5% P2O5, 0–2.5% ZrO2, 24–45% ZnO, 2–10% Al2O3, 35–50% SiO2 and 0.1–3% A2O where A is selected from the group of alkali elements and mixtures thereof wherein the glass composition is useful in thick paste dielectric materials which are compatible with AlN substrates.Type: GrantFiled: December 1, 2005Date of Patent: August 8, 2006Assignee: E. I. du Pont de Nemours and CompanyInventors: Yong Cho, Kenneth Warren Hang
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Patent number: 6984261Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.Type: GrantFiled: February 5, 2003Date of Patent: January 10, 2006Assignee: 3M Innovative Properties CompanyInventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
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Patent number: 6953756Abstract: A glass ceramic sintered body containing gahnite and cordierite as crystal phases, having a thermal expansion coefficient at 40 to 400° C. of not larger than 5×10?6/° C., a dielectric constant of not larger than 7 and a Young's modulus of not larger than 150 GPa. A wiring board having an insulating substrate made of the glass ceramic sintered body features very high reliability in the primary mounting and in the secondary mounting.Type: GrantFiled: October 22, 2003Date of Patent: October 11, 2005Assignee: Kyocera CorporationInventors: Shinya Kawai, Toshifumi Higashi
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Patent number: 6914023Abstract: The object of the present invention is to provide a flat-panel-display substrate which is high in heat resistance, of which the coefficient of thermal expansion is approximated to that of a thick film dielectric layer, which is low at high temperatures in reactivity with the lead-doped thick film dielectric layer, and which can be made to have a large area. The substrate of the present invention is obtained by sintering a body comprising glass powder and a filler made of metal and/or semi-metal oxide, and is constituted by the sintered body and whose average coefficient of linear thermal expansion is from 7 to 9.5 ppm/° C. in the temperature range of 25 to 700° C. The glass powder includes alkaline-earth oxide, 15 to 50% by weight of silicon oxide, and no greater than 2% by weight of boron oxide. Furthermore, the filler is at a concentration of 10 to 30% by volume of the total amount of the glass powder and the filler in the mould.Type: GrantFiled: July 16, 2003Date of Patent: July 5, 2005Assignee: TDK CorporationInventors: Takaji Shimosaka, Yukihiko Shirakawa, Shirou Ootsuki
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Patent number: 6849334Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.Type: GrantFiled: March 15, 2002Date of Patent: February 1, 2005Assignee: NeoPhotonics CorporationInventors: Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
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Publication number: 20040176235Abstract: A ceramic material has a thermal expansion coefficient of 50×10−7/° C. or less, an absolute value of the difference between the relative refractive indexes of silica glass and the ceramic material of 0.2 or less at a wavelength of 1550 nm, and a light attenuation coefficient of 0.3 dB/cm or more.Type: ApplicationFiled: December 26, 2003Publication date: September 9, 2004Inventor: Akihiko Sakamoto
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Patent number: 6774072Abstract: Enclosed are crystallized glasses suitable for a substrate for an information recording medium such as a magnetic disc, optical disc, or optomagnetic disc, a substrate for information recording medium using such a crystallized glass substrate, and an information recording medium using such a substrate for information recording medium. The crystallized glasses are capable of providing a glass substrate having a high Young's modulus, as well as excellent mechanical strength, surface flatness, and heat resistance and having an excellent surface smoothness upon polishing. Glass substrate having an excellent surface smoothness using such a crystallized glass are also disclosed.Type: GrantFiled: February 25, 2003Date of Patent: August 10, 2004Assignee: Hoya CorporationInventors: Xuelu Zou, Kouji Azegami
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Patent number: 6753070Abstract: An insulating ceramic compact is provided which can be obtained by low-temperature firing, has a low relative dielectric constant and superior high frequency characteristics, and can be co-sintered with a material having a high coefficient of thermal expansion. The insulating ceramic compact is a fired mixture of an MgAl2O4-based ceramic and a borosilicate glass, in which an MgAl2O4 crystal phase and at least one of an Mg3B2O6 crystal phase and an Mg2B2O5 crystal phase are precipitated as primary crystal phases.Type: GrantFiled: July 11, 2001Date of Patent: June 22, 2004Assignee: Murata Manufacturing Co., Ltd.Inventors: Naoya Mori, Yasutaka Sugimoto, Osamu Chikagawa
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Patent number: 6736875Abstract: Composite cordierite honeycomb structures especially suitable for diesel exhaust filtration applications comprise a non-oxide polycrystalline phase constituting 10-70% by weight, with the remainder of the ceramic material constituting a cordierite phase, the non-oxide polycrystalline phase being selected from the group consisting of carbides, nitrides, and borides. Preferably the non-oxide phase is either polycrystalline silicon carbide or polycrystalline silicon nitride and has a particle aspect ratio of less than 3. Inventive ceramic bodies are porous with an open porosity of at least 30%, preferably between 40% and 60%, and a median pore size of at least 5 micrometers, more preferably greater than 8 micrometers and less than 12 micrometers.Type: GrantFiled: December 13, 2001Date of Patent: May 18, 2004Assignee: Corning IncorporatedInventors: Kishor P. Gadkaree, Yanxia Lu, Joseph F. Mach, Christopher J. Warren, Yuming Xie
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Publication number: 20040087427Abstract: A glass ceramic sintered body containing gahnite and cordierite as crystal phases, having a thermal expansion coefficient at 40 to 400° C. of not larger than 5×10−6/° C., a dielectric constant of not larger than 7 and a Young's modulus of not larger than 150 GPa. A wiring board having an insulating substrate made of the glass ceramic sintered body features very high reliability in the primary mounting and in the secondary mounting.Type: ApplicationFiled: October 22, 2003Publication date: May 6, 2004Applicant: KYOCERA CORPORATIONInventors: Shinya Kawai, Toshifumi Higashi
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Publication number: 20030228967Abstract: The present invention refers to glass-ceramics consisting of the mixtures (I): ZrO2—SiO2—MeIIO, or (II) SiO2—MeIIIO2—MeIIO, wherein: MeII is chosen in the group consisting of: Ca, Ba, Mg, Zn or mixture thereof; MeIII is chosen in the group consisting of Al, B or mixtures thereof; each of the above said constituents being present in determined quantities; the invention refers also to a process for preparing the glass-ceramics above defined; porcelain stonewares and glazes containing them and their use for preparing ceramic items.Type: ApplicationFiled: June 12, 2003Publication date: December 11, 2003Inventors: Marco Bitossi, Giovanni Baldi, Davide Settembre Blundo, Enrico Generali
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Patent number: 6660670Abstract: Ceramics containing a diopside crystal phase and a cordierite phase, the remainder being a glass phase and/or other ceramic crystal phases, and having an open porosity of not larger than 1%. The ceramics is obtained by firing at from 800 to 1050° C., and exhibits a dielectric constant of not larger than 7 and a small dielectric loss in a high-frequency region, a ceramic strength of not smaller than 250 MPa, and a coefficient of thermal expansion close to those of the chips such as of Si and Ga—As and of the printed board.Type: GrantFiled: November 29, 2001Date of Patent: December 9, 2003Assignee: Kyocera CorporationInventors: Yoshitake Terashi, Hiromi Iwachi, Tsutae Iryo
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Patent number: 6649549Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.Type: GrantFiled: April 2, 2001Date of Patent: November 18, 2003Assignee: Minolta Co., Ltd.Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
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Patent number: 6645892Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.Type: GrantFiled: April 2, 2001Date of Patent: November 11, 2003Assignee: Minolta Co., Ltd.Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
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Patent number: 6645888Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.Type: GrantFiled: April 2, 2001Date of Patent: November 11, 2003Assignee: Minolta Co., Ltd.Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
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Patent number: 6645889Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.Type: GrantFiled: April 2, 2001Date of Patent: November 11, 2003Assignee: Minolta Co., Ltd.Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
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Patent number: 6645891Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.Type: GrantFiled: April 2, 2001Date of Patent: November 11, 2003Assignee: Minolta Co., Ltd.Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
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Patent number: 6645890Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.Type: GrantFiled: April 2, 2001Date of Patent: November 11, 2003Assignee: Minolta Co., Ltd.Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
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Patent number: RE38888Abstract: A ceramic comprising predominately a cordierite-type phase approximating the stoichiometry Mg2Al4Si5O18 and having a coefficient of thermal expansion (25-800° C.) of greater than 4×10?7/° C. and less than 13×10?7/° C. and a permeability and a pore size distribution which satisfy the relation 2.108 (permeability)+18.511 (total pore volume)+0.1863 (percentage of total pore volume comprised of pores between 4 and 40 micrometers)>24.6. The ceramic is suitable in the fabrication of cellular, wall-flow, diesel particulate filters having a pressure drop in kPa that at an artificial carbon soot loading of 5 grams/liter and a flow rate of 26 scfm is less than 8.9-0.035 (number of cells per square inch)+300 (cell wall thickness in inches), a bulk filter density of at least 0.60 g/cm3 and a volumetric heat capacity of at least 0.67 J cm?3 K?1 as measured at 500° C.Type: GrantFiled: September 22, 2003Date of Patent: November 22, 2005Assignee: Corning IncorporatedInventors: Douglas M. Beall, David L. Hickman, Gregory A. Merkel
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Patent number: RE39120Abstract: Low thermal expansion ceramics contains a cordierite crystal phase, wherein a phase of a crystalline compound containing at least one element selected from the group consisting of an alkaline earth element other than Mg, a rare earth element, Ga and In, is precipitated in the grain boundaries of said crystal phase, said ceramics has a relative density of not smaller than 95%, a coefficient of thermal expansion of not larger than 1×10?6/° C. at 10 to 40° C., and a Young's modulus of not smaller than 130 GPa. That is, the ceramics has a small coefficient of thermal expansion, is deformed very little depending upon a change in the temperature, has a very high Young's modulus and is highly rigid and is resistance against external force such as vibration. Accordingly, the ceramics is very useful as a member for supporting a wafer or an optical system is a lithography apparatus that forms high resolution circuit patterns on a silicon wafer.Type: GrantFiled: April 16, 2002Date of Patent: June 6, 2006Assignees: Kyocera Corporation, Nikon CorporationInventors: Yoshihisa Sechi, Masahiro Sato, Hiroshi Aida, Shoji Kohsaka, Yutaka Hayashi