Binary, Ternary, Quaternary, Etc., Metal Silicate Crystalline Phase (e.g., Mullite, Diopside, Sphene, Plagioclase, Slagcerams Free Of Alumina, Etc.) Patents (Class 501/5)
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Patent number: 11833003Abstract: The invention relates to a method for the production of a blank of a ceramic material, wherein a first ceramic material and then a second ceramic material of different compositions are filled into a mold and wherein the materials are pressed and after pressing are sintered. Thereby, a layer of the first ceramic material is filled into the mold, a first open cavity is formed in the layer, the second ceramic material is filled into the first open cavity and the materials are pressed together and are then heat-treated. Both the first ceramic material and the second ceramic material contain, or consists of, lithium silicate glass ceramic.Type: GrantFiled: October 17, 2017Date of Patent: December 5, 2023Assignee: DENTSPLY SIRONA INC.Inventors: Markus Vollmann, Lothar Volkl, Stefan Fecher, Carsten Wiesner
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Patent number: 11583374Abstract: The invention relates to a process for the preparation of a glass-ceramic blank for dental purposes with lithium silicate as crystal phase, in which lithium silicate blanks that are no longer required and in particular residues thereof are used as starting material and which allows the production of a homogeneous starting glass within a short time.Type: GrantFiled: August 14, 2019Date of Patent: February 21, 2023Assignee: Ivoclar Vivadent AGInventor: Christian Ritzberger
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Patent number: 11440834Abstract: The invention relates to glass ceramics and glasses with a europium content, containing the following components: Component wt.-% SiO2 30.0 to 75.0 Al2O3 10.0 to 45.0 Europium, calculated as Eu2O3 0.05 to 5.0? and which are suitable in particular for the production of restorations, the fluorescence properties of which largely correspond to those of natural teeth.Type: GrantFiled: February 7, 2020Date of Patent: September 13, 2022Assignee: Ivoclar Vivadent AGInventors: Marc Dittmer, Ronny Hengst, Christian Ritzberger
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Patent number: 11254618Abstract: A process for producing a glazed ceramic body, in which a glazing material is applied to a non-densely sintered substrate material and the substrate material and the glazing material are subjected to a heat treatment in order to obtain the glazed body.Type: GrantFiled: March 23, 2018Date of Patent: February 22, 2022Assignee: Ivoclar Vivadent AGInventors: Frank Rothbrust, Ronny Hengst, Sebastian Krolikowski, Christian Ritzberger, Diana Tauch
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Patent number: 11166795Abstract: Provided is a block body that makes it possible to quickly produce a dental prosthesis with a good accuracy. A material of the block body including SiO2 in an amount of 60.0 mass % to 80.0 mass %, Li2O in an amount of 10.0 mass % to 20.0 mass %, Al2O3 in an amount of 5.1 mass % to 10.0 mass %, wherein the block body is formed in a column, and a main crystalline phase of the block body is lithium disilicate.Type: GrantFiled: July 9, 2019Date of Patent: November 9, 2021Assignee: GC CORPORATIONInventors: Tomohiro Hoshino, Go Mashio, Tatsuya Fujimoto, Masatoshi Yoshinaga, Hayato Yokohara, Daisuke Ohta
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Patent number: 11005237Abstract: An ignition plug comprising: an insulator having a through hole extending from a rear-end side toward a forward-end side; a center electrode inserted at least partially into a portion of the through hole on the forward-end side; a metal terminal member inserted at least partially into a portion of the through hole on the rear-end side; and a seal disposed within the through hole and in contact with the center electrode and an inner circumferential surface of the insulator. The seal contains a glass and an electrically conductive substance, and the glass contained in the seal contains Si in an amount of 50 mass % or more as reduced to SiO2 and Na in an amount of 0.1 mass % or more and less than 1 mass % as reduced to Na2O.Type: GrantFiled: June 16, 2020Date of Patent: May 11, 2021Assignee: NGK SPARK PLUG CO., LTD.Inventors: Seiji Nakano, Kengo Fujimura, Shoma Tsumagari
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Patent number: 10765496Abstract: The invention relates to glass-ceramics based on the lithium silicate system which can be mechanically machined easily in an intermediate step of crystallisation and, after complete crystallisation, represent a very strong, highly-translucent and chemically-stable glass-ceramic. Likewise, the invention relates to a method for the production of these glass-ceramics. The glass-ceramics according to the invention are used as dental material.Type: GrantFiled: December 20, 2018Date of Patent: September 8, 2020Assignees: FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V., VITA ZAHNFABRIK H. RAUTER GMBH & CO. KG, DEGUNDENT GMBHInventors: Bernhard Durschang, Jörn Probst, Norbert Thiel, Joachim Bibus, Markus Vollmann, Udo Schusser
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Patent number: 10702948Abstract: A method provides for producing modifications in or on a transparent workpiece using a laser processing device. The laser processing device has a short pulse or ultrashort pulse laser that emits laser radiation having a wavelength in the transparency range of the workpiece and which has a beam-shaping optical unit for beam shaping for focusing the laser radiation. The transparent workpiece is composed of a material that has a plurality of phases, of which at least two phases have different dielectric constants, of which in turn the one phase is a phase embedded in the form of particles, which phase is substantially surrounded by the other phase, and wherein the product of the volume of the particles specified in cubic nanometers and the ratio of the absolute value of the difference of the two different dielectric constants to the dielectric constant of the surrounding phase is greater than 500.Type: GrantFiled: December 29, 2017Date of Patent: July 7, 2020Assignee: Schott AGInventors: Andreas Ortner, Niklas Bisch, Fabian Wagner, Albrecht Seidl, Frank-Thomas Lentes
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Patent number: 10629513Abstract: The disclosed concept relates to electrical isolation between power electronic and cooling and/or mounting components and, in particular, a ceramic layer positioned at the interface of the power electronic and cooling and/or mounting components to provide electrical isolation, as well as, a thermally conductive path to remove heat produced by the power electronic component.Type: GrantFiled: June 4, 2015Date of Patent: April 21, 2020Assignee: EATON INTELLIGENT POWER LIMITEDInventors: David Glenn Woolard, Paul Thomas Murray
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Patent number: 10590028Abstract: Lithium silicate-wollastonite glass ceramics are described which are characterized by a controllable translucence and can be easily machined and therefore can be used in particular as restoration material in dentistry.Type: GrantFiled: September 2, 2016Date of Patent: March 17, 2020Assignee: Ivoclar Vivadent AGInventors: Marc Dittmer, Wolfram Höland, Markus Rampf, Marcel Schweiger
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Patent number: 10562815Abstract: The present invention relates to structure including an interfacial seal between a glass-ceramic component and a metal component, as well as methods for forming such structures. In particular embodiments, the interfacial seal includes a metal oxide. Such interfacial seals can be beneficial for, e.g., hermetic seals between a glass-ceramic component and a metal component.Type: GrantFiled: November 1, 2016Date of Patent: February 18, 2020Assignee: National Technology & Engineering Solutions of Sandia, LLCInventor: Steve Xunhu Dai
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Patent number: 10551590Abstract: Example methods of manufacturing a glass mirror apparatus includes the step of providing a chemically strengthened glass sheet with a thickness of less than or equal to about 2 mm. The method further includes the step of applying a reflective layer to the second major surface of the glass sheet to provide a first glass mirror. In further examples, a glass mirror apparatus comprises a chemically strengthened glass sheet with a thickness of less than or equal to about 2 mm. A reflective layer applied to the second major surface of the glass sheet to provide a first glass mirror.Type: GrantFiled: February 26, 2014Date of Patent: February 4, 2020Assignee: CORNING INCORPORATEDInventors: Christopher Alan Nitz, Michael Aaron McDonald, Chunhe Zhang
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Patent number: 10501367Abstract: Ceramics and glass-ceramics have low and/or negative coefficients of thermal expansion. Crystalline phases of the formula AM2Si2-yGeyO7 (A=Sr and Ba and M=Zn, Mg, Ni, Co, Fe, Cu, Mn, with Sr, Ba and Zn necessarily having to be present) can be produced by conventional ceramic processes or by crystallization from glasses. The compositions form solid solutions, where the elements indicated as component M can be replaced by one another in virtually any concentration but the concentration of Zn must always be at least 50% of the sum of all components indicated under M. The stoichiometry of these silicates and also their structure can differ to a greater or lesser extent.Type: GrantFiled: July 5, 2016Date of Patent: December 10, 2019Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.Inventors: Christian Thieme, Christian Ruessel
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Patent number: 10427967Abstract: The present invention relates to a process for the manufacture of a glass container that comprises the steps of: a) providing a first glass element; b) providing a second element made of a material selected from: glass, ceramic, metal and metallic alloy; said first element and said second element, joined together, defining a containment cavity of said glass container; c) depositing a sealing composition comprising at least one glass frit dispersed in at least one dispersing liquid on at least one surface of at least one of said first element and said second element; d) positioning said first element and said second element in contact with each other so that said sealing composition is arranged between said first element and said second element; e) heating said sealing composition so as to melt said glass frit and form a sealing layer between said first element and said second element. The present invention further relates to a glass container, such as, for example, a bottle, a cup or a jar, and related uses.Type: GrantFiled: February 2, 2016Date of Patent: October 1, 2019Assignee: BORMIOLI LUIGI S.P.A.Inventor: Simone Baratta
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Patent number: 10206761Abstract: Pre-sintered blanks based on lithium metasilicate glass ceramic are described which are suitable in particular for the preparation of dental restorations.Type: GrantFiled: August 15, 2017Date of Patent: February 19, 2019Assignee: Ivoclar Vivadent AGInventors: Harald Bürke, Christian Ritzberger, Marcel Schweiger, Volker Rheinberger, Diana Tauch
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Patent number: 9926223Abstract: A method of bonding a high-strength zirconia post serving as a core in a glass-ceramic block, a method of bonding a metal link fastened with an implant fixture to the zirconia post, and glass-ceramic bondable to the zirconia post and a preparation method thereof, when preparing artificial teeth through a CAD/CAM processing method by using the glass-ceramic block as an artificial-teeth material. The lithium disilicate glass-ceramics containing cristobalite crystalline includes glass-ceramics composition including 10 to 15 wt % Li2O, 68 to 76 wt % SiO2, 2 to 5 wt % P2O5 working as a nuclei formation agent, 0 to 5 wt % Al2O3 to increase glass transition temperature and softening temperature and increase chemical durability of the glass, 2 to 3 wt % ZrO2, 0.5 to 3 wt % CaO for enhancing a thermal expansion coefficient of the glass, 0.5 to 5 wt % Na2O, 0.5 to 5 wt % K2O, and 1 to 2 wt % colorants, and 0 to 2.0 wt % mixture of MgO, ZnO, F, and La2O3.Type: GrantFiled: May 16, 2016Date of Patent: March 27, 2018Assignee: HASS CO., LTD.Inventors: Yong su Kim, Hyun jun Jeon, Hyung Bong Lim, Kyung Sik Oh, Sung ho Ha, Young pyo Hong, Joon hyung Kim, Cheol young Kim
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Patent number: 9780357Abstract: Disclosed herein is a silicon-based anode active material, comprising a silicon phase, a SiOx (0<x<2) phase and a carbon dioxide phase. Also disclosed is a secondary battery, which comprises a cathode comprising a cathode active material, an anode active material comprising an anode active material, and a separator, wherein the anode active material comprises a silicon phase, an SiOx (0<x<2) phase and a silicon dioxide phase.Type: GrantFiled: August 3, 2012Date of Patent: October 3, 2017Assignees: LG Chem, Ltd., UNIST (Ulsan National Institute of Science and Technology)Inventors: Yong Ju Lee, Soo Jin Park, Hye Ran Jung, Jung In Lee, Je Young Kim, Mi Rim Lee, Jae Phil Cho
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Patent number: 9757217Abstract: Pre-sintered blanks based on lithium metasilicate glass ceramic are described which are suitable in particular for the preparation of dental restorations.Type: GrantFiled: May 10, 2013Date of Patent: September 12, 2017Assignee: Ivoclar Vivadent AGInventors: Harald Bürke, Christian Ritzberger, Marcel Schweiger, Volker Rheinberger, Diana Tauch
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Patent number: 9731995Abstract: Exemplary embodiments of the present disclosure provide a lithium silicate crystalline or amorphous glass overlaying the top surfaces of zirconia and the manufacturing process thereof. More specifically, exemplary embodiments of the present disclosure provide a lithium silicate glass or lithium silicate crystalline glass with high light transmittance and good coloring characteristics and the manufacturing process thereof, which overlays the top surface of zirconia with high mechanical strength, frameworks, or copings. The lithium silicate crystalline or amorphous glass may include 10-15 wt % Li2O, 71.1-85.0 wt % SiO2, 2-5 wt % P2O5 working as nuclear formation agent, 1-5 wt % Al2O3 to increase glass transition temperature and softening temperature, as well as chemical durability of the glass, and 0.01-1.0 wt % ZrO2 which increases the binding strength of the zirconia substructure.Type: GrantFiled: October 14, 2014Date of Patent: August 15, 2017Assignee: Hass Co., Ltd.Inventors: Yong su Kim, Hyun jun Jeon, Hyung bong Lim, Kyung sik Oh, Sung ho Ha, Jin su Jeong, Cheol young Kim
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Patent number: 9701575Abstract: The present invention relates to a glass ceramic powder comprising i) a glass material formed from a glass mixture containing a lithium and oxygen containing compound selected from Li2O and/or Li2CO3, SiO2, K2O, La2O3, and ii) seed particles comprising Li2SiO3 crystals and/or Li2Si2O5 crystals. The present invention also relates to a method of manufacturing of said glass ceramic powder, a method for preparing compacted and sintered bodies from the glass ceramic powder and bodies obtainable by said method.Type: GrantFiled: October 17, 2014Date of Patent: July 11, 2017Assignee: HARRYSON CONSULTING GMBHInventor: Sigvald Harryson
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Patent number: 9440877Abstract: The present disclosure relates to fusion formable highly crystalline glass-ceramic articles whose composition lies within the SiO2—R2O3—Li2O/Na2O—TiO2 system and which contain a silicate crystalline phase comprised of lithium aluminosilicate (?-spodumene and/or ?-quartz solid solution) lithium metasilicate and/or lithium disilicate. Additionally, these silicate-crystal containing glass-ceramics can exhibit varying Na2O to Li2O molar ratio extending from the surface to the bulk of the glass article, particularly a decreasing Li2O concentration and an increasing Na2O concentration from surface to bulk. According to a second embodiment, disclosed herein is a method for forming a silicate crystalline phase-containing glass ceramic.Type: GrantFiled: October 23, 2014Date of Patent: September 13, 2016Assignee: Corning IncorporatedInventors: George Halsey Beall, Nicholas Francis Borrelli, Charlene Marie Smith, Steven Alvin Tietje
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Patent number: 9248078Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools.Type: GrantFiled: March 15, 2013Date of Patent: February 2, 2016Assignee: Ivoclar Vivadent AGInventors: Marcel Schweiger, Volker Rheinberger, Harald Burke, Wolfram Höland, Elke Apel, Christian Ritzberger, Dmitri Brodkin
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Patent number: 9125967Abstract: The present invention provides a highly-sintered fluorapatite glass-ceramic comprising a high Ca/Al or Sr/Al mole-ratio, that possesses a microstructure that induces apatite/bone deposition.Type: GrantFiled: November 8, 2013Date of Patent: September 8, 2015Assignee: University of Iowa Research FoundationInventors: Isabelle Denry, Julie Holloway
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Patent number: 9101439Abstract: Lithium silicate glass ceramics and glasses comprising specific oxides of monovalent elements are described which crystallize at low temperatures and are suitable in particular as dental materials.Type: GrantFiled: October 11, 2012Date of Patent: August 11, 2015Assignee: Ivoclar Vivadent, AGInventors: Christian Ritzberger, Elke Apel, Wolfram Höland, Volker Rheinberger
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Patent number: 8987153Abstract: The invention is directed to veneer ceramics for dental restorations of framework ceramics comprising yttrium-stabilized zirconium dioxide. It is the object of the invention to make possible a translucent veneer ceramic which has high flexural strength as well as excellent adhesion to the framework ceramic of yttrium-stabilized zirconium dioxide. According to the invention, this object is met in a veneer ceramic for dental restorations made of yttrium-stabilized zirconium dioxide which is produced from the following components: a) SiO2 58.0-74.0 percent by weight b) Al2O3 4.0-19.0 percent by weight c) Li2O 5.0-17.0 percent by weight d) Na2O 4.0-12.0 percent by weight e) ZrO2 0.5-6.0 percent by weight.Type: GrantFiled: October 16, 2013Date of Patent: March 24, 2015Assignee: Ivoclar Vivadent AGInventors: Martina Johannes, Roland Ehrt
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Patent number: 8956987Abstract: The invention relates to glass-ceramics based on the lithium disilicate system which can be mechanically machined easily in an intermediate step of crystallization and, after complete crystallization, represent a very strong, highly-translucent and chemically-stable glass-ceramic. Likewise, the invention relates to a method for the production of these glass-ceramics. The glass-ceramics according to the invention are used as dental material.Type: GrantFiled: December 23, 2010Date of Patent: February 17, 2015Assignees: Fraunhofer-Gesellschaft zur Förderung der Angewandten Forschung E.V., Vita Zahnfabrik H. Rauter GmbH & Co. KG, Degudent GmbHInventors: Bernhard Durschang, Jorn Probst, Norbert Thiel, Joachim Bibus, Markus Vollmann, Udo Schusser
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Patent number: 8940651Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.Type: GrantFiled: July 12, 2013Date of Patent: January 27, 2015Assignee: Ivoclar Vivadent AGInventors: Elke Signer-Apel, Wolfram Höland, Marcel Schweiger, Christian Ritzberger, Harald Bürke, Volker Rheinberger
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Patent number: 8936732Abstract: A white light emitting glass-ceramic. The chemical formula of the glass-ceramic is aSiO2.bAl2O3.cNaF.dCeF3.nDyF3.mAg, wherein a, b, c, d, n and m are, by mol part, 25-50, 15-30, 10-30, 10-25, 0.01-1 and 0.01-1, respectively, and a+b+c+d-100. A method for producing said glass-ceramic is also provided. Silver ion is doped in the glass-ceramic in the form of silver particles by means of sintering and reduction annealing treatment, and thus the luminescence properties of rare earth ion is improved.Type: GrantFiled: July 22, 2010Date of Patent: January 20, 2015Assignee: Ocean's King Lighting Science & Technology Co., Ltd.Inventors: Mingjie Zhou, Wenbo Ma, Fangyi Weng
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Publication number: 20150004418Abstract: A bonded ceramic component which is resistant to reactive halogen-containing plasmas, said component comprising ceramic portions which are bonded together by a bonding material which includes an oxyfluoride glass-ceramic-comprising transition area between interfaces of the ceramic portions, where the transition area includes from at least 0.1 volume % amorphous phase up to about 50 volume % amorphous phase.Type: ApplicationFiled: September 8, 2014Publication date: January 1, 2015Applicant: Applied Materials, Inc.Inventors: Jennifer Y. Sun, Ren-Guan Duan, Kenneth S. Collins
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Patent number: 8883663Abstract: The present disclosure relates to fusion formable highly crystalline glass-ceramic articles whose composition lies within the SiO2—R2O3—Li2O/Na2O—TiO2 system and which contain a silicate crystalline phase comprised of lithium aluminosilicate (?-spodumene and/or ?-quartz solid solution) lithium metasilicate and/or lithium disilicate. Additionally, these silicate-crystal containing glass-ceramics can exhibit varying Na2O to Li2O molar ratio extending from the surface to the bulk of the glass article, particularly a decreasing Li2O concentration and an increasing Na2O concentration from surface to bulk. According to a second embodiment, disclosed herein is a method for forming a silicate crystalline phase-containing glass ceramic.Type: GrantFiled: November 29, 2011Date of Patent: November 11, 2014Assignee: Corning IncorporatedInventors: George Halsey Beall, Nicholas Francis Borrelli, Charlene Marie Smith, Steven Alvin Tietje
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Patent number: 8871664Abstract: Provided is a manufacturing method for a refractory filler, comprising melting a raw material batch and cooling the resultant melt to precipitate willemite as a main crystal phase.Type: GrantFiled: April 18, 2011Date of Patent: October 28, 2014Assignee: Nippon Electric Glass Co., Ltd.Inventors: Tomoko Enomoto, Hiroyuki Okamura, Nobutoshi Ito
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Patent number: 8865606Abstract: The invention relates to a process for preparing dental restorations, wherein a lithium silicate glass ceramic or a lithium silicate glass is used which contains at least 8.5 wt.-% transition metal oxide selected from the group consisting of oxides of yttrium, oxides of transition metals with an atomic number from 41 to 79 and mixtures of these oxides.Type: GrantFiled: September 26, 2011Date of Patent: October 21, 2014Assignee: Ivoclar Vivadent AGInventors: Christian Ritzberger, Wolfram Höland, Marcel Schweiger, Volker Rheinberger
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Publication number: 20140296053Abstract: A glass-ceramics composite material suitable for a low-temperature firing use, which has high moisture resistance and thermal conductivity, is provided. In the glass-ceramics composite material which contains aluminum nitride (AlN) particles as a filler, even in a case where boron oxide (B2O3) is blended as a flux of a glass phase, by adjusting the composition of raw materials which forms the glass phase to a specific conditions to make the crystal phase which contains boron (B) precipitate at the time of firing of the glass-ceramics composite material.Type: ApplicationFiled: March 11, 2014Publication date: October 2, 2014Applicant: NGK Insulators, Ltd.Inventors: Shinsuke YANO, Yoshihiro TANAKA, Naoto OHIRA, Hirofumi YAMAGUCHI
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Publication number: 20140206522Abstract: An easily-administered technology which demonstrates the intrinsic thermal conductivity improvement effect by addition of non-oxide system compound crystal phase (filler particles) and makes it possible to sufficiently raise the thermal conductivity of a glass-ceramics composite material is provided. In the glass phase which constitutes a glass-ceramics composite material, the quantity of aluminum oxide (Al2O3) component is increased under a condition where at least either of zinc oxide (ZnO) component or magnesium oxide (MgO) component exists in a predetermined quantity or more. Thereby, the unintended reaction between a non-oxide system compound crystal phase and a glass phase can be suppressed, and the intrinsic thermal conductivity improvement effect by addition of non-oxide system compound crystal phase (filler particles) can be demonstrated.Type: ApplicationFiled: March 21, 2014Publication date: July 24, 2014Applicant: NGK Insulators, Ltd.Inventors: Shinsuke YANO, Yoshihiro TANAKA, Tsutomu NANATAKI, Hirofumi YAMAGUCHI, Natsumi SHIMOGAWA, Naoto OHIRA
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Patent number: 8778075Abstract: Lithium silicate glass ceramics and glasses are described which can advantageously be applied to zirconium oxide ceramics in particular by pressing-on in the viscous state and form a solid bond with these.Type: GrantFiled: August 5, 2013Date of Patent: July 15, 2014Assignee: Ivoclar Vivadent AGInventors: Christian Ritzberger, Ricardo Dellagiacomo, Marcel Schweiger, Harald Bürke, Wolfram Höland, Volker Rheinberger
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Patent number: 8772188Abstract: A glass-ceramic having at least two crystal phases, wherein at least one crystal phase has a positive temperature dependence of the resonance frequency ?f, at least one crystal phase has a negative temperature dependence of the resonance frequency ?f and the glass-ceramic has a resulting temperature dependence of the resonance frequency ?f of 0 ppm/K with a maximum deviation of +/?20 ppm/K, is described. Furthermore, a process for producing such a glass-ceramic and the use of the glass-ceramic are described.Type: GrantFiled: March 12, 2012Date of Patent: July 8, 2014Assignee: Schott AGInventors: Martin Letz, Stephan Knoener, Martina Dressler, Daniela Seiler, Bernd Hoppe, Michael Kluge
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Patent number: 8759237Abstract: The invention relates to a lithium silicate glass ceramic, which contains at least 8.5 wt.-% transition metal oxide selected from the group consisting of oxides of yttrium, oxides of transition metals with an atomic number from 41 to 79 and mixtures of these oxides. The invention also relates to a corresponding lithium silicate glass, a process for the preparation of the glass ceramic and of the glass as well as their use.Type: GrantFiled: April 4, 2011Date of Patent: June 24, 2014Assignee: Ivoclar Vivadent AGInventors: Christian Ritzberger, Wolfram Holand, Marcel Schweiger, Volker Rheinberger
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Publication number: 20140066283Abstract: A glass ceramic composition that contains a first ceramic including at least one of MgAl2O4 and Mg2SiO4; a second ceramic including BaO, RE2O3 (RE is a rare-earth element), and TiO2; glass containing each of 44.0 to 69.0 weight % of RO (R is an alkaline-earth metal), 14.2 to 30.0 weight % of SiO2, 10.0 to 20.0 weight % of B2O3, 0.5 to 4.0 weight % of Al2O3, 0.3 to 7.5 weight % of Li2O, and 0.1 to 5.5 weight % of MgO; and MnO.Type: ApplicationFiled: November 11, 2013Publication date: March 6, 2014Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Kazuhiro Kaneko, Sadaaki Sakamoto, Hiroshige Adachi, Satoru Adachi, Seiji Fujita
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Patent number: 8664131Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit ?-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li3O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2 ? O + Na 2 ? O + K 2 ? O + MgO + ZnO _ ] ? [ Al 2 ? O 3 + B 2 ? O 3 ] between 0.7 to 1.5; b. a ratio: [ TiO 2 + SnO 2 _ ] ? [ SiO 2 + B 2 ? O 3 ] greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ?about 85% over the wavelength range of 400-700 nm for an about 0.Type: GrantFiled: July 2, 2013Date of Patent: March 4, 2014Assignee: Corning IncorporatedInventors: George Halsey Beall, Marie Jacqueline Monique Comte, George Owen Dale, Linda Ruth Pinckney, Charlene Marie Smith, Ronald Leroy Stewart, Steven Alvin Tietje
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Patent number: 8592330Abstract: The invention is directed to veneer ceramics for dental restorations of framework ceramics comprising yttrium-stabilized zirconium dioxide. It is the object of the invention to make possible a translucent veneer ceramic which has high flexural strength as well as excellent adhesion to the framework ceramic of yttrium-stabilized zirconium dioxide. According to the invention, this object is met in a veneer ceramic for dental restorations made of yttrium-stabilized zirconium dioxide which is produced from the following components: a) SiO2 58.0-74.0 percent by weight b) Al2O3 ?4.0-19.0 percent by weight c) Li2O ?5.0-17.0 percent by weight d) Na2O ?4.0-12.0 percent by weight e) ZrO2 ?0.5-6.0 percent by weight.Type: GrantFiled: March 6, 2008Date of Patent: November 26, 2013Assignee: Ivoclar Vivadent AGInventors: Martina Johannes, Roland Ehrt
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Patent number: 8546280Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.Type: GrantFiled: July 1, 2011Date of Patent: October 1, 2013Assignee: Ivoclar Vivadent AGInventors: Elke Apel, Wolfram Höland, Marcel Schweiger, Christian Ritzberger, Harald Bürke, Volker M. Rheinberger
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Patent number: 8444756Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools.Type: GrantFiled: July 9, 2010Date of Patent: May 21, 2013Assignee: Ivoclar Vivadent AGInventors: Marcel Schweiger, Volker Rheinberger, Harald Burke, Wolfram Holand, Elke Apel, Christian Ritzberger, Dmitri Brodkin
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Patent number: 8431498Abstract: The invention provides a crystallizable glass, a crystallized glass, and manufacturing methods thereof. The crystallizable glass can be crystallized in a short period of time, and can maintain its glass shape and its surface condition during a crystallization process. The crystallized glass has good mechanical strength, an adequate thermal expansion coefficient that allows the crystallized glass to be used as a construction material, less content of alkali-metal oxides, and good chemical durability. The MgO—Al2O3—SiO2-based crystallizable glass and crystallized glass contain, by mass percent, 55.0-65.0% SiO2, 8.0-14.0% Al2O3, 10.0-20.0% MgO, 1.5-6.0% CaO, 1.0-2.2% Li2O, 0.7-3.0% Na2O, 2.5-4.0% K2O, and 1.5-3.0% F.Type: GrantFiled: October 25, 2010Date of Patent: April 30, 2013Assignees: Huzhou Ta Hsiang Glass Products Co., Ltd., Ta Hsiang Containers Inc. Do., Ltd.Inventors: Kuo-Chuan Hsu, Chao Qu
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Patent number: 8283268Abstract: The colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are compounds containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are compounds containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former.Type: GrantFiled: April 23, 2008Date of Patent: October 9, 2012Assignee: Schott AGInventors: Meike Schneider, Thilo Zachau, Friedrich Siebers, Wolfgang Schmidbauer
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Patent number: 8282878Abstract: Embodiments of the present invention disclosed herein include a sintering aid composition that has a material useful for sintering, an amine, and optionally a carboxylic acid.Type: GrantFiled: January 27, 2011Date of Patent: October 9, 2012Assignee: Huntsman Petrochemical LLCInventors: Alan P. Croft, David C. Lewis
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Patent number: 8263508Abstract: A phosphosilicate glass ceramic with nanoscale fluoroapatite and leucite crystals. The glass ceramic is very similar to natural tooth material in terms of its optical properties. The glass ceramic has a low linear thermal expansion coefficient and a low pressing temperature and is therefore particularly suitable for pressing on metal alloys to produce dental restoration.Type: GrantFiled: December 3, 2009Date of Patent: September 11, 2012Assignee: Ivoclar Vivadent AGInventors: Urs Bolle, Marcel Schweiger, Elke Apel, Wolfram Höland, Volker Rheinberger
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Patent number: 8162664Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.Type: GrantFiled: July 1, 2011Date of Patent: April 24, 2012Assignee: Ivoclar Vivadent AGInventors: Elke Apel, Wolfram Holland, Marcel Schweiger, Christian Ritzberger, Harald Burke, Volker Rheinberger
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Patent number: 8158261Abstract: A glass-ceramic composite encapsulation material composed of glass matrix materials of SiO2, Al2O3, BaO and B2O3, and at least one glass filler selected from the group consisting of kaliophilite (KAlSiO4), leucite (KAlSi2O6), magnesium oxide (MgO). The glass-ceramic composite encapsulation material according to the invention comprises a high temperature type glass matrix (softening point: 750-850° C.) and a intermediate temperature type glass matrix (softening point: 650-750° C.), and glass filler mixed therein, wherein said glass filler in the high temperature type glass matrix comprises 5% to 20% by volume of the total volume of said glass matrix and glass filler, and the glass filler in the intermediate temperature type glass matrix comprises 0% to 40% by volume of the total volume of said glass matrix and glass filler, and wherein said glass filler has an effect of adjusting the expansion coefficient.Type: GrantFiled: April 22, 2009Date of Patent: April 17, 2012Assignee: National Taipei University TechnologyInventors: Sea-Fue Wang, Yun-Ruey Wang, Ching-Chin Chuang, Chun-Ting Yeh
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Patent number: 8133828Abstract: Glass-ceramic compositions exhibiting high reliability and tensile strength are described. The compositions can include crystal phases including roedderite and/or potassium fluorrichterite. The glass-ceramic compositions are bioactive, and can be used as components of a wide variety of biomedical devices such as dental restorations.Type: GrantFiled: May 13, 2009Date of Patent: March 13, 2012Assignee: The Ohio State University Research FoundationInventors: Isabelle L. Denry, Julie A. Holloway
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Patent number: 8114795Abstract: For providing glass-ceramics having properties suitable for use as a substrate of an information storage medium of next generation such as one for the perpendicular magnetic recording system without employing arsenic and antimony components which adversely affect human beings and the environment, there are provided glass-ceramics comprising SiO2, Li2O and Al2O3 on oxide basis, comprising lithium disilicate as a crystal phase, and comprising one or more elements selected from the group consisting of Sn, Ce, Mn, W, Ta, Bi, Nb, S, Cl and F.Type: GrantFiled: December 15, 2008Date of Patent: February 14, 2012Assignee: Ohara Inc.Inventors: Toshitaka Yagi, Naoyuki Goto