Abstract: Disclosed are a catalyst electrode for a fuel cell, a method for fabricating the catalyst electrode, and a fuel cell including the catalyst electrode. The presence of an ionomer-ionomer support composite in the catalyst electrode prevents the porous structure of the catalyst electrode from collapsing due to oxidation of a carbon support to avoid an increase in resistance to gas diffusion and can stably secure proton channels. The presence of carbon materials with high conductivity is effective in preventing the electrical conductivity of the electrode from deterioration resulting from the use of a metal oxide in the ionomer-ionomer support composite and is also effective in suppressing collapse of the porous structure of the electrode to prevent an increase in resistance to gas diffusion in the electrode. Based on these effects, the fuel cell exhibits excellent performance characteristics and prevents its performance from deteriorating during continuous operation.

Abstract: Hybrid carbon nanofiber (Cnf) products (e.g., mats, yarns, webs, etc.) and methods of fabricating the same are provided. The hybrid Cnf products are flexible and lightweight and have high thermal conductivity. An electrospinning process can be used to fabricate the hybrid Cnf products and can include preparation of an electrospinning solution, electrospinning, and carbonization (e.g., under a vacuum condition).

Abstract: A superacid polymeric catalyst having both Lewis acidity and Brønsted acidity is described, along with methods of making and methods of using the same.

Abstract: The present application relates to a novel method for reductive degradation of perfluoroalkyl-containing compounds, such as perfluoroalkyl sulfonates, by activated carbon (AC) supported zero valent iron-nickle nanoparticles (nNi0Fe0).

Abstract: A mixed conductor represented by Formula 1: A1±xM2±yO4????Formula 1 wherein, in Formula 1, A is a monovalent cation, and M is at least one of a monovalent cation, a divalent cation, a trivalent cation, a tetravalent cation, a pentavalent cation, or a hexavalent cation, 0?x?1, 0?y?2, and 0???1, with the proviso that when M includes vanadium, 0<??1, and wherein the mixed conductor has an inverse spinel crystal structure.

Abstract: This compound, which absorbs long-wavelength active energy rays and generates with high-efficiency radicals and strong bases, and which has excellent reaction efficiency in a base generating chain reaction, is represented by formula (1), where, in formula (1), R1, R2, R3, R5 and R6 independently represent a hydroxy group, an alkoxy group, or an organic group other than those substituents, the R4's independently represent an organic group including a thioether bond, and ‘A’ represents a substituent represented by formula (1-1) or (1-2), where, in formula (1-1), R7 and R8 independently represent a hydrogen atom, an alkyl group or a heterocyclic group, and where, in formula (1-2), R9 and R10 independently represent an amino group or a substituted amino group. A photopolymerization initiator can include said compound; and a photosensitive resin composition can include said photopolymerization initiator.

Abstract: Disclosed is a composite particle including a plurality of nanoparticles encapsulated in an inorganic material, wherein the plurality of nanoparticles is uniformly dispersed in the inorganic material. Also disclosed is relates to a light emitting material, a support supporting at least one composite particle and/or a light emitting material and an optoelectronic device including at least one composite particle and/or a light emitting material.

Abstract: Methods for forming an interconnected network of solid material and pores, with metal residing only at the air/solid interface of the interconnected network structure are described. In certain embodiments, nanoparticle decorated sacrificial particles can be used as sacrificial templates for the formation of a porous structure having an interconnected network of solid material and interconnected network of pores. The nanoparticles reside predominantly at the air/solid interface and allow further growth and accessibility of the nanoparticles at defined positions of the interconnected structure. SEM and TEM measurements reveal the formation of 3D interconnected porous structures with nanoparticles residing predominantly at the air/solid interface of the interconnected structure.

Abstract: Polymer-monodispersed nano-microspheres for deep profile control and flooding. The polymer-monodispersed nano-microspheres comprise (% wt.): 0.05 to 2.5% of macromolecules A, 0.05 to 2.5% of macromolecules B, 0.002 to 0.05% of an oxygen scavenger, and mineralized water. Macromolecules A comprise a straight-chain water-soluble polymer with an ethyl ether or propyl ether structure. Macromolecules B comprise a water-soluble polymer with a hydroxyl or polyphenolic structure. Macromolecules A and macromolecules B are intermolecularly assembled under the drive of extremely strong hydrogen bonds in aqueous solutions to rapidly construct monodispersed nano-microsphere dispersion glue with a controllable size. The monodispersed nano-microspheres have a good seepage in a porous medium and excellent deep profile control and flooding capabilities.

Abstract: Aspects of the disclosure relate to a transmitting device, which may explicitly or implicitly signal the use of continuous precoding for a resource block (RB) cluster. For example, the transmitting device may implicitly indicate that continuous precoding is applied to an RB cluster by dynamically controlling one or more parameters of a transmission over those RBs. Further, when continuous precoding is applied to an RB cluster, the transmitting device may explicitly or implicitly signal the dynamic control over one or more transmission properties, with an aim to maximize the benefits of such continuous precoding. Other aspects, embodiments, and features are also claimed and described.

Abstract: The present invention discloses a novel magnetic BiOCl—Bi24O31Cl10/MnFe2O4—Fe2O3 semiconductor photocatalyst as a staggered multi-heterojunction nano-photocatalyst for pharmaceutical effluents remediation, and preparation method and use thereof. The semiconductor photocatalysts are at weighted ratios 9:1 4:1, 7:3 and 3:2 of BiOCl—Bi24O31Cl10 and MnFe2O4—Fe2O3 semiconductor. The BiOCl—Bi24O31Cl10/MnFe2O4—Fe2O3 semiconductor photocatalyst with 10% MnFe2O4—Fe2O3 is a solar light activated photocatalyst for pharmaceutical effluents remediation. The pharmaceutical effluents include ofloxacin antibiotic.

Abstract: The invention relates to a catalyst comprising an alumina-, silica- or silica-alumina-based support, at least one group VIII element, at least one group VIB element, and a furan compound. The invention also relates to the method for producing said catalyst and to the use thereof in a hydrotreating and/or hydrocracking method.

Abstract: A method of preparing an amalgamated transition metal layered double hydroxide (LDH)@Y-zeolite hybrid catalyst is provided. The method includes combining a transition metal with aluminum nitrate and precipitating using an alkali under ultrasound irradiation and an inert atmosphere to form a transition metal-containing LDH catalyst. A Y-zeolite is pretreated by an ion exchange process utilizing ammonia prior to calcination at temperature (250-1000° C.) under an inert atmosphere to form an H—Y-zeolite. Followed by refluxing the transition metal-containing LDH catalyst together with the H—Y-zeolite at 50° C. for a predetermined time to form a precipitate. The precipitate is filtering and washing with distilled water to obtain the amalgamated transitional metal LDH@Y-zeolite hybrid catalyst.

Abstract: A 3D structure of the graphite-titanium-nanocomposite complex and a method of preparing the graphite-titanium-nanocomposite complex are disclosed. The Graphite-titanium-nanocomposite complex includes a metal core associated with the two phases, amine functionalized graphite, and amine functionalized titanium. The method of preparation includes amine functionalizing of graphite and titanium with coupling agents to produce amine functionalized titanium and graphite, further mixing with a metal ion solution for synthesizing an ion complex. Trisodium citrate solution and sodium borohydride solution is added to the ion complex to prepare a 3D structure of the graphite-titanium-nanocomposite complex, employed as a catalyst.

Abstract: According to the present disclosure, an isotropic structural colour printing process is provided. The process comprising (a) providing an ink composition comprising ink particles (such as polymeric particles (e.g. polystyrene), metal-organic frameworks (MOFs) (e.g. ZIF-8)) in a liquid reagent; and (b) depositing the ink composition onto a surface of a substrate (e.g. anodic aluminium oxide membrane, photo papers). Due to capillary action and/or absorption of the liquid reagent, the ink particles form an amorphous arrangement of structures that lead to isotropic structural colour. In the preferred embodiment, the ink particles may further be coated with a catechol group (such as polydopamine). An apparatus for detecting a target substance in the gaseous phase, wherein the apparatus comprises a nanostructure capable of exhibiting a change in isotropic structural colour when one or more molecules of the target substance are entrapped as an indication that the target substance is present, is also provided.

Abstract: A method of making carbon nanotubes doped with iron, nitrogen and sulphur for an oxygen reduction reaction catalyst includes the steps of mixing an iron containing oxidising agent with a sulphur-containing dye to form a fibrous fluctuate of reactive templates and using these for in-situ polymerisation of an azo compound to form polymer-dye nanotubes, adding an alkali to precipitate magnetite, and subjecting the nanotubes to pyrolysis, acid leaching, and heat treatment.

Abstract: A painting booth may include: a painting chamber and/or an overspray removal unit. Paint may be sprayed in the painting chamber. The painting chamber may be crossed by an air flow for evacuation of overspray from the painting chamber. When exiting the chamber, the air flow may pass through the overspray removal unit in order to remove the overspray from the air flow. The overspray removal unit may include an incoherent mass of cleaning elements kept in a stirred condition, through which the air flow containing the overspray passes so as to release the overspray onto the cleaning elements. A method for removing overspray from air flow exiting a painting booth may include: passing the air flow through an incoherent mass of cleaning elements which are kept in a stirred condition, so as to release the overspray onto the cleaning elements of the incoherent mass.

Abstract: The invention relates to a method for the preparation of a coating comprising at least one coating layer on a substrate, the method comprising the steps of a. providing monomers of the type R—(N)x-(L)m-(C?C)n-(L?)o-(N?)y—R?, wherein R is a head moiety, R? is a tail moiety, (C?C)n is an oligoyne moiety, L and L? are linker moieties, N and N? independently are branched or unbranched optionally substituted C1-C25 alkyl moieties optionally containing 1 to 5 heteroatoms, x, m, o, and y are independently 0 or 1, n is 4 to 12, and wherein the head moiety allows for an interaction with the surface of the substrate; b. bringing the monomers into contact with the substrate wherein the interaction of the head moieties of the monomers with the surface of the substrate induces at least a part of the monomers to align in a defined manner thereby forming a film on the surface and bringing the oligoyne moieties of the monomers into close contact with each other; c.

Abstract: A system and method for the reduction of NOx and CO contaminants using an ion-exchange resin media having lower-valency ions of the transitional metal elements, such as ferrous ions, cuprous ions and/or manganese ions, such that gases containing NOx and/or CO contaminants may be passed over the media so that the contaminants are absorbed by the lower-valency ions of the transitional metal elements, the media configured so that it can be regenerated to remove the NOx and/or CO contaminants. Regeneration includes exposing the media to a heated stream of hydrogen gas or exposing the media to hydrogen ions in an electrochemical cell.

Abstract: Mesoporous oxide nanoparticles, compositions comprising such nanoparticle, and methods of making and using such nanoparticles. The nanoparticles (e.g., compositions comprising the nanoparticles) have an average size of less than 15 nm and a narrow size distribution. The nanoparticles can be used in imaging applications and delivery of molecular cargo (e.g., a drug) to an individual.

Abstract: The invention is in the field of catalysis. More specifically, the invention relates to a process for preparing a protected metal catalyst on a support; a matrix particle comprising the protected metal catalyst; and, a process for hydrogenating a hydrocarbon resin feedstock using the protected metal catalyst.

Abstract: A 3D structure of the graphite-titanium-nanocomposite complex and a method of preparing the graphite-titanium-nanocomposite complex are disclosed. The Graphite-titanium-nanocomposite complex includes a metal core associated with the two phases, amine functionalized graphite, and amine functionalized titanium. The method of preparation includes amine functionalizing of graphite and titanium with coupling agents to produce amine functionalized titanium and graphite, further mixing with a metal ion solution for synthesizing an ion complex. Trisodium citrate solution and sodium borohydride solution is added to the ion complex to prepare a 3D structure of the graphite-titanium-nanocomposite complex, employed as a catalyst.

Abstract: Method of preparing monolithic SCR catalyst with a plurality of gas flow channels comprising the steps of (a) providing a monolithic shaped substrate with a plurality of parallel gas flow channels; (b) coating the substrate with a wash coat slurry comprising vanadium oxide precursor compounds and titania and optionally tungsten oxide precursor compounds; and (c) drying the thus coated substrate with a drying rate of 5 mm/min or less along flow direction through the gas flow channels; and (d) activating the dried coated substrate by calcining.

Abstract: A photocatalyst according to the present invention has a structure in which the titanium dioxide doped with the transition metals is supported on the support such that a band gap thereof is low and a specific surface area thereof is high, thereby exhibiting an excellent photocatalytic activity even in a visible light region and providing an excellent effect of adsorbing an organic compound and removing the same even under a condition in which light is not emitted.

Abstract: A catalyst and a process for using the catalyst are presented. The catalyst is a heterogeneous catalyst and includes active metal halides bonded to functional groups. The functional groups are bonded to a polymeric backbone to form the structure supporting the catalyst. The catalyst is useful for the dimerization of acetylene to convert the acetylene to a larger hydrocarbon, and in particular to dimerize acetylene to vinylacetylene.

Abstract: The present invention relates generally to an attrition resistant core-in-shell composite adsorbent comprising at least a zeolite-containing CO2 removal adsorbent and a binder on an inert dense core. The attrition resistant core-in-shell composite adsorbent has an attrition loss of less than about 2 wt %. The core-in-shell composite adsorbent is preferably used in a multi-layered adsorption system in a cyclic adsorption process, preferably used in a PSA prepurification process prior to cryogenic air separation.

Abstract: The present invention relates to a process for manufacturing a wood-based board, a wood-based board as use of a liquid coating composition comprising at least one particulate filler material and at least one binder for in-line coating of wood-based boards.

Abstract: A material includes a porous particle that includes a metal ion imprinted polymer. The metal ion imprinted polymer is formed from a hydrophilic co-monomer, a metal containing polymerizable compound, and a cross-linking agent. The metal containing polymerizable compound includes at least one metal chelating ligand. The metal ion imprinted polymer includes a plurality of metal ion selective binding sites. A method includes flowing brine containing a metal ion through a reactor that includes the material. The method further includes discharging the brine from the reactor, contacting the porous particles with water, and pressurizing the reactor with carbon dioxide. The carbon dioxide reacts with the adsorbed metal ions to form a metal carbonate solution. The method further includes depressurizing the reactor to precipitate metal carbonate from the metal carbonate solution and discharging the metal carbonate solution from the reactor.

Abstract: Provided is a method for producing a non-aqueous electrolyte secondary battery with which resistance increase is inhibited during high-temperature storage while good battery properties are retained. The production method of this invention comprises a step of obtaining a positive electrode, a negative electrode and a non-aqueous electrolyte; and a step of placing the positive electrode, the negative electrode and the non-aqueous electrolyte in a battery case. Herein, the non-aqueous electrolyte comprises a fluorine atom-containing supporting salt and a benzothiophene oxide.

Abstract: The present disclosure relates to polymer compounds for use as polymerization agents in coatings, paints or inks. In one embodiment, a polymer compound comprises at least one of a cobalt-bearing urethanized polymer having a cobalt content of no more than 6% by weight and a mean molecular weight of no more than 2500 Da, or a manganese-bearing urethanized polymer having a manganese content of 1% to 6% by weight and a mean molecular weight of no more than 2000 Da.

Abstract: Described is a method for synthesizing polymer compounds (P), preferably polysiloxanes, comprising at least one carboxylic ester group, in particular (meth)acrylate-containing polysiloxanes, said method being carried out in the presence of conversion products (U) of metal salts, in particular chromium(III) salts, and conversion products of aldehydes and primary amines.

Abstract: Macrocyclization of amino acids or linear peptides upon reaction with amphoteric amino aldehydes and isocyanides is provided.

Abstract: The present invention relates to a method for limiting the emission of dust from catalyst grains. Said method comprises the following two consecutive steps: a first step of performing a heat treatment of the catalyst grains at a temperature no lower than 100° C., followed by a second step of coating the surface of the catalyst grains by placing same in contact with one or more coating materials having a melting point T no lower than 45° C. and which are injected in a solid state, said second step being carried out with no further addition of heat, at a temperature of T?60° C. to T?1° C., while remaining no lower than 40° C.

Abstract: X-Ray photoelectron spectroscopy (XPS) is used to assess or predict the catalytic activity of a chromium oxyfluoride catalyst in a reaction wherein a chlorinated compound is converted to a fluorinated compound.

Abstract: Synthesis, fabrication, and application of nanocomposite polymers in different form (as membrane/filter coatings, as beads, or as porous sponges) for the removal of microorganisms, heavy metals, organic, and inorganic chemicals from different contaminated water sources.

Abstract: A process and catalyst for the in situ generation of hydrogen via the microwave irradiation of a ruthenium chitosan composite catalyst has enabled the convenient reduction of nitro compounds in aqueous medium.

Abstract: The present invention relates to ionic liquids for use in chemical applications and capable of serving the dual function of solvent and liquid support. The ionic liquid lends itself to a method of synthesizing oligomers selected from the group consisting of oligopeptides, oligosaccharides and oligonucleotides, comprising contacting a first monomer unit with an ionic liquid at reaction conditions to provide an ionic liquid bound monomer unit; and contacting the ionic liquid bound monomer unit with at least one further monomer unit at reaction conditions to provide an ionic liquid bound oligomer comprising from 2 to 30 monomer units. The method lends itself to large scale manufacture of oligopeptides, oligosaccharides and oligonucleotides.

Abstract: In an embodiment, a method of producing a bisphenol comprises reacting a phenolic compound with a reactant comprising one or both of an aldehyde and a ketone in the presence of a catalyst system and methanol to produce the bisphenol; wherein the methanol is present in an amount of 250 to 5,000 ppm based on the total weight of the reactant; wherein the catalyst system comprises an ion-exchange resin comprising a plurality of sulfonic acid sites; and 5 to 35 mol % of an attached promoter molecule based on the total moles of the sulfonic acid sites in the catalyst system; and wherein the attached promoter molecule comprises at least two thiol groups per attached promoter molecule.

Abstract: There is provided a metal fine particle association suitably applied to an electrode catalyst to achieve even higher output leading to reduction in amount of the catalyst used, and a process for producing the same, that is, a metal fine particle association including a plurality of metal fine particles that have a mean particle diameter of 1 nm to 10 nm and are associated to form a single assembly, an association mixture including the metal fine particle association and a conductive support; a premix for forming an association, including metal fine particles, a metal fine particle dispersant made of a hyperbranched polymer, and a conductive support; and a method for producing the association mixture.

Abstract: The invention relates to a process for producing a particulate, Si-bonded fluidized-bed catalyst having improved abrasion resistance, which comprises the steps I. provision of an aqueous suspension comprising zeolite particles, II. addition of a silicone resin mixture comprising one or more hydrolyzable silicone resin precondensates and mixing of the aqueous suspension and the silicone resin mixture, III. spray drying of the mixture obtained from step II, with the mixture being homogenized before spray drying, and IV. calcination of the spray-dried fluidized-bed catalyst obtained from step III, and an Si-bonded fluidized-bed catalyst which can be produced by this process and also its use for the nonoxidative dehydroaromatization of C1-C4-aliphatics.

Abstract: A method of manufacturing a crosslinked fluororesin powder includes forming a powder mixture by mixing a fluororesin powder as a first powder with a second powder not fusing to the fluororesin powder even under conditions for crosslinking of the fluororesin powder, and conducting a cross-linking treatment to the formed powder mixture.

Abstract: The present invention provides a sonochemical irradiation-based method for the preparation of polydopamine (PDA) nanocapsules having reduced wall thickness and uniform size distribution, which may further comprise at least one payload; nanocapsules obtained by this method; and compositions thereof. Such compositions may be formulated for different purposes, e.g., as pharmaceutical compositions for various therapeutic or diagnostic purposes.

Abstract: A method for lattice design via multivalent linkers (LDML) is disclosed that introduces a rationally designed symmetry of connections between particles in order to achieve control over the morphology of their assembly. The method affords the inclusion of different programmable interactions within one linker that allow an assembly of different types of particles. The designed symmetry of connections is preferably provided utilizing DNA encoding. The linkers may include fabricated “patchy” particles, DNA scaffold constructs and Y-shaped DNA linkers, anisotropic particles, which are preferably functionalized with DNA, multimeric protein-DNA complexes, and particles with finite numbers of DNA linkers.

Abstract: Removing an asphaltene particle from a substrate includes contacting a silicate nanoparticle with a chemical group to form a functionalized silicate nanoparticle, the chemical group includes a first portion; and a second portion comprising an aromatic moiety or a nonaromatic moiety, the first portion being bonded to the silicate nanoparticle; contacting the asphaltene particle with the functionalized silicate nanoparticle, the asphaltene particle being disposed on the substrate; interposing the functionalized silicate nanoparticle between the asphaltene particle and the substrate; and separating the asphaltene particle from the substrate with the functionalized silicate nanoparticle to remove the asphaltene particle. A composition includes a functionalized silicate nanoparticle comprising a reaction product of a silicate nanoparticle and a functionalization compound; and a fluid.

Abstract: The present invention relates to a stabilized monomer dispersion containing inorganic oxide nanoparticles with high refractive index in which the refractive index of the inorganic oxide nanoparticles is greater than 1.65 and the average particle size of the high refractive inorganic oxide nanoparticles ranges from 1 to 100 nm and its content is in a range of from 1.0% by weight to 10.0% by weight based on the total weight of the monomer dispersion. The present invention also relates to a process for preparing the stabilized monomer dispersion containing high refractive inorganic oxide nanoparticles.

Abstract: The present disclosure relates to a method of encapsulating microcapsules containing relatively high temperature phase change materials and the microcapsules so produced. The microcapsules are coated with an inorganic binder, film former and an inorganic filler. The microcapsules may include a sacrificial layer that is disposed between the particle and the coating. The microcapsules may also include an inner coating layer, sacrificial layer and outer coating layer. The microcapsules are particularly useful for thermal energy storage in connection with, e.g., heat collected from concentrating solar collectors.

Abstract: The present invention is directed to improving a catalyst applied to a reaction layer having a structure (PFF structure) in which a polymer electrolyte phase surrounds a periphery of a catalyst with a hydrophilic region interposed therebetween and reducing the amount of catalyst metal particles used. A method for producing a catalyst for a fuel cell, in which a catalyst metal particle is supported on a carrier, includes the steps of: preparing an unmodified catalyst in which a catalyst metal particles is supported on a carrier; and modifying the catalyst metal particle in the unmodified catalyst with at least one type of modifying group selected from a nitric acid group, an amino group, a sulfonic acid group, a hydroxy group, and halogen groups.

Abstract: A gastroretentive composition comprises a mixture comprising an active ingredient component and an excipient component. The excipient component comprises a first water-soluble reaction product produced from a precursor comprising a vinyl group, and a copolymer of a polyalkylene glycol and a second water-soluble reaction product produced from a precursor comprising a vinyl group. A method of forming the gastroretentive composition comprises the steps of providing the active ingredient component and the excipient component, and mixing the active ingredient component and the excipient component to form a mixture. The mixture is aggregated to form an aggregation that is dry granulated to form a plurality of granules. The plurality of granules is processed to form the gastroretentive composition.

Abstract: A liquid composition comprising: a liquid medium comprising at least one aprotic polar organic solvent and less than 25 wt % based on the total weight of the composition of an alcohol; and at least 5 wt % based on the total weight of the composition of at least one fluorinated anion exchange polymer comprising a fluorocarbon backbone and side-chains covalently attached to the backbone having terminal groups of formula (I): —SO2NR1Q+X?, wherein Q+ is a group comprising at least one quaternary nitrogen atom, and R1 is H or a C1-C20 alkyl group, or forms a ring together with a group in Q+, wherein the ring contains 2 to 10 carbon atoms and, optionally, up to 4 heteroatoms; and X? is an anion selected among the group consisting of organic anions and lipophilic inorganic anions is disclosed. The liquid composition is suitable for the preparation of ion exchange membranes and as binders for electrocatalytic layers for use in electrochemical applications.

Abstract: Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced N2 adsorption rates and capacities when used in air separation processes.