And Group Ii Metal (i.e., Alkaline Earth, Be, Mg, Zn Cd Or Hg) Patents (Class 502/226)
  • Patent number: 11865522
    Abstract: A method for preparing a zinc ferrite-based catalyst comprising: obtaining a precipitate by bringing a metal precursor solution including a zinc precursor, a ferrite precursor, a solution containing an acid and water into contact with a basic aqueous solution; filtering the precipitate; drying the filtered precipitate; and firing the dried precipitate, wherein the solution containing the acid includes one or more of nitric acid (HNO3) and hydrocarbon acid.
    Type: Grant
    Filed: July 13, 2020
    Date of Patent: January 9, 2024
    Assignee: LG Chem, Ltd.
    Inventors: Sang Jin Han, Dong Hyun Ko, Kyong Yong Cha, Ye Seul Hwang, Sunhwan Hwang
  • Patent number: 11230775
    Abstract: The invention provides electro-catalyst compositions for an anode electrode of an acid mediated proton exchange membrane-based water electrolysis system. The compositions include a noble metal component selected from the group consisting of iridium oxide, ruthenium oxide, rhenium oxide and mixtures thereof, and a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, cooper oxide, zirconium oxide, nickel oxide and mixtures thereof. Further, the non-noble metal component can include a dopant. The dopant can be at least one element selected from Groups III, V, VI and VII of the Periodic Table. The compositions can be prepared using any solution based methods involving a surfactant approach or a sol gel approach. Further, the compositions are prepared using noble metal and non-noble metal precursors.
    Type: Grant
    Filed: September 4, 2019
    Date of Patent: January 25, 2022
    Assignee: UNIVERSITY OF PITTSBURGH—OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION
    Inventors: Prashant N. Kumta, Karan Sandeep Kadakia, Moni Kanchan Datta, Oleg Velikokhatnyi, Prashanth Jampani Hanumantha
  • Patent number: 10125381
    Abstract: The invention relates to the production of aromatic molecules in prokaryotic and eukaryotic hosts such as E. coli, yeasts, filamentous fungi, algae, microalgae, other plant cells.
    Type: Grant
    Filed: March 23, 2017
    Date of Patent: November 13, 2018
    Assignee: RHO RENEWABLES, INC.
    Inventor: Philip J. Barr
  • Patent number: 9782754
    Abstract: The invention relates to a catalyst composition comprising (a) a metal M selected from the group consisting of platinum (Pt), palladium (Pd), rhodium (Rh), rhenium (Re), ruthenium (Ru) and iridium (Ir), (b) tin (Sn), (c) zinc (Zn), (d) alkaline earth metal and (e) a porous metal oxide catalyst support, wherein the amount of each of elements (a), (b) and (d) is independently chosen in the range of from 0.1 to 5 wt. % based on the porous metal oxide catalyst support and wherein the amount of element (c) is chosen in the range of from 0.1 to 2 wt. % based on the porous metal oxide catalyst support. Furthermore, the invention also relates to a process for the preparation of said catalyst composition and its use in non-oxidative dehydrogenation of an alkane, preferably propane.
    Type: Grant
    Filed: July 26, 2013
    Date of Patent: October 10, 2017
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Abdulrahim Al-Zahrani, Lachezar A. Petrov, Mohammad Daous, Mohammad Umar, Mohammed Al-Hazmi, Yahia Al-Hamed
  • Patent number: 9504990
    Abstract: The invention concerns a thioresistant catalyst which comprises an active phase deposited on a support, said active phase comprising at least one noble metal from group VIIIB and at least one metallic oxide from group IB or from group IIB, said support being selected from the group formed by refractory oxides, coal, clays, silica-alumina and/or their mixtures, and said support having a specific surface area in the range 110 to 300 m2/g. The invention also concerns the process for the preparation of said catalysts and their uses in the selective hydrogenation of hydrocarbons comprising acetylenic, dienic and/or alkenylaromatic functions. The invention is applicable to the refining field, and more particularly to the treatment of gasolines obtained by steam cracking (pyrolysis gasoline).
    Type: Grant
    Filed: January 10, 2012
    Date of Patent: November 29, 2016
    Assignee: IFP ENERGIES NOUVELLES
    Inventor: Antoine Fecant
  • Patent number: 9339808
    Abstract: Surface-active solid-phase catalyst activity may be substantially improved by creating deliberate repetitive surface-to-surface contact between portions of the active surfaces of catalyst objects. While they are immersed in reactant material such contact between portions of the active surfaces of catalyst objects can substantially activate the surfaces of many heterogeneous catalysts. Examples are given of such action employing a multitude of predetermined shapes, supported catalyst structures, etc. agitated or otherwise brought into contact to produce numerous surface collisions. One embodiment employs a gear pump mechanism with catalytically active-surfaced gear teeth to create the repetitive transient contacting action during pumping of a flow of reactant. The invention is applicable to many other forms for creating transient catalytic surface contacting action. Optionally catalytic output of such systems may be significantly further improved by employing radiant energy or vibration.
    Type: Grant
    Filed: August 26, 2011
    Date of Patent: May 17, 2016
    Assignee: CCMI Corporation
    Inventor: Mitchell A. Cotter
  • Patent number: 9101863
    Abstract: A filtering medium and method for removing contaminants from an organic-based feed stream which includes the use of a layer of ceramic filter units having a plurality of elliptical or trisoidal openings extending therethrough to filter organic-based feed streams and to provide liquid distribution upstream of the catalyst beds.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: August 11, 2015
    Assignee: Crystaphase Products, Inc.
    Inventor: John N. Glover
  • Patent number: 9000242
    Abstract: The invention is directed to a catalyst for the gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene with HF to give 1-chloro-2,2-difluoroethane which catalyst is prepared by co-depositing FeCl3 and MgCl2 on chromia-alumina, or co-depositing Cr(NO3)3 and Ni(NO3)2 on active carbon, or by doping alumina with ZnCl2, and to a process for the preparation of 1-chloro-2,2-difluoroethane comprising a catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene wherein one of the catalysts according to claim 2 or 3 is used.
    Type: Grant
    Filed: October 11, 2012
    Date of Patent: April 7, 2015
    Assignee: Bayer Intellectual Property
    Inventors: Norbert Lui, Shanthan Rao Pamulaparthy, Srinivas Pvss, Thomas Vijaya, Sridhar Madabhushi, Rambabu Yadla, Narsaiah Banda, Sergii Pazenok
  • Patent number: 8993474
    Abstract: This invention relates to a dehydrogenation catalyst having a macropore size and a high active density of platinum, suitable for use in dehydrogenation of a hydrocarbon gas. This dehydrogenation catalyst having a macropore size and a high active density of platinum is highly active, has high active density per unit catalytic surface area, facilitates material transfer of reactants and products, delays deactivation due to coke formation, keeps the initial activity constant after being regenerated thanks to the disposal of coke, has high strength and so is resistant to external impact, and undergoes neither structural changes due to heat nor changes in the properties of active materials.
    Type: Grant
    Filed: May 25, 2009
    Date of Patent: March 31, 2015
    Assignee: Hyosung Corporation
    Inventors: Jin Soon Choi, Won Il Kim, Hyong Lim Koh, Young Gyo Choi
  • Patent number: 8962896
    Abstract: Catalytic processes to produce a reaction product comprising 1-butanol by contacting a reactant comprising ethanol with a catalyst composition under suitable reaction conditions are provided. The catalyst composition may comprise a hydroxyapatite of the Formula (MwM?xM?yM??z)5(PO4)3(OH), wherein M is Mg; M? is Ca; M? is Sr; M?? is Ba; w is any number between 0 and 1 inclusive; x is any number from 0 to less than 0.5; y is any number between 0 and 1 inclusive; z is any number between 0 and 1 inclusive; and w+x+y+z=1. Base-treated catalyst compositions may be used. Also provided are processes for contacting an initial catalyst composition comprising the hydroxyapatite with a base to produce a base-treated catalyst composition, and the base-treated catalyst compositions so obtained.
    Type: Grant
    Filed: September 10, 2010
    Date of Patent: February 24, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventors: Paul Joseph Fagan, Thomas G. Calvarese, Ronald James Davis, Ronnie Ozer
  • Patent number: 8957237
    Abstract: An improved industrial method for the direct synthesis of alkylhalogenosilanes is described. Specifically, a method is described for preparing alkylhalogenosilanes by reacting, in a fluidized bed reactor, and alkyl halogenide, preferably CH3Cl, with a solid body, which is referred to as a contact body and which includes powdered silicon and a catalytic system including at least one copper catalyst and ?1 and ?2 promoter activities.
    Type: Grant
    Filed: December 18, 2012
    Date of Patent: February 17, 2015
    Assignee: Bluestar Silicones France SAS
    Inventor: Cécile Rosier
  • Publication number: 20150045210
    Abstract: Parallel reactor systems for synthesizing materials are disclosed. The reactor systems may be suitable for synthesizing materials produced from corrosive reagents. Methods for preparing materials by use of such parallel reactor systems are also disclosed.
    Type: Application
    Filed: March 26, 2013
    Publication date: February 12, 2015
    Applicant: FreeSlate, Inc.
    Inventors: Daniel Giaquinta, Robert S. Busacca, Robert K. Rosen, John F. Varni, Jeffrey C. Yoder
  • Publication number: 20150011719
    Abstract: Methods for making olefin polymerization catalysts and methods for making polymers using the catalysts are provided. The method for making the catalyst can include combining one or more supports with one or more magnesium-containing compounds under reaction conditions to form a first reacted product. One or more chlorinating compounds selected from the group consisting of aluminum alkyl chlorides and chloro substituted silanes can be combined with the first reacted product under reaction conditions to form a second reacted product. One or more titanium-containing compounds selected from the group consisting of titanium alkoxides and titanium halides can be combined with the second reacted product under reaction conditions to form a catalyst.
    Type: Application
    Filed: February 18, 2013
    Publication date: January 8, 2015
    Applicant: UNIVATION TECHNOLOGIES, LLC
    Inventors: Wesley R. Mariott, Kevin J. Cann, John H. Moorhouse, Mark G. Goode, Thomas Oswald
  • Publication number: 20150005535
    Abstract: The present invention relates to a structured catalyst based on sintered metal fibers (SMF) coated by a non-acidic metal oxide layer impregnated with Pd and Agnanopartides, characterized in that the ratio of the Pd:Ag is 1:1 to 10:1, as well as the use of such a catalyst in selective catalytic hydrogenations of organic compounds.
    Type: Application
    Filed: October 26, 2012
    Publication date: January 1, 2015
    Applicant: DSM IP ASSETS B.V.
    Inventors: Werner Bonrath, Lioubov Kiwi-Minsker, Igor Iouranov
  • Patent number: 8912110
    Abstract: One embodiment is a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, an alkali or alkaline-earth metal, a lanthanide-series metal, and a support. Generally, an average bulk density of the catalyst is about 0.300 to about 1.00 gram per cubic centimeter. The catalyst has a platinum content of less than about 0.375 wt %, a tin content of about 0.1 to about 2 wt %, a potassium content of about 100 to about 600 wppm, and a cerium content of about 0.1 to about 1 wt %. The lanthanide-series metal can be distributed at a concentration of the lanthanide-series metal in a 100 micron surface layer of the catalyst less than two times a concentration of the lanthanide-series metal at a central core of the catalyst.
    Type: Grant
    Filed: July 12, 2012
    Date of Patent: December 16, 2014
    Assignee: UOP LLC
    Inventors: Manuela Serban, Mark P. Lapinski
  • Patent number: 8907029
    Abstract: An olefin polymerization catalyst is prepared by (a) in a diluent, combining a diorganomagnesium compound with less than 2 molar equivalents of a first source of chloride to produce a “chloride deficient” magnesium chloride support; (b) without isolating any solids, adding a second source of chloride which reduces the amount of soluble un-reacted diorganomagnesium compound present; (c) without isolating any solids present, adding a tetravalent titanium species and; (d) adding an activator. The catalyst is active for solution polymerization of olefins.
    Type: Grant
    Filed: March 8, 2011
    Date of Patent: December 9, 2014
    Assignee: NOVA Chemicals (International) S.A.
    Inventors: Qinyan Wang, Peter Zoricak
  • Publication number: 20140350312
    Abstract: Provided are a fluorination catalyst for preparing 2,3,3,3-tetrafluoropropene and a method using the catalyst for preparing 2,3,3,3-tetrafluoropropene. The catalyst has the following structural formula: Crx(Y,Z)0.005-0.5O0.1-10F1.0-3.0, where Y is one or a combination of two or more among Al, Zn, and Mg, and where Z is a rare earth element having an oxygen-storing/releasing function. The catalyst has in preparing 2,3,3,3-tetrafluoropropene the advantages of increased raw material conversion rate, great product selectivity, and extended catalyst service life.
    Type: Application
    Filed: September 11, 2012
    Publication date: November 27, 2014
    Applicant: SINOCHEM LANTIAN CO., LTD.
    Inventors: Gang Yang, Lei Xu, Huie Yang, En Jiang, Jianping Fan, Xintang Zhao, Changhua Zeng, Wenqing Zhang, Yunlong Lei, Zhong Li, Shukang Chen
  • Patent number: 8889892
    Abstract: A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising (a) ruthenium metal or a ruthenium oxide, (b) manganese oxide and (c) alkaline metal component or alkaline earth metal component.
    Type: Grant
    Filed: May 26, 2011
    Date of Patent: November 18, 2014
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshihiko Ohishi, Anusorn Seubsai, Selim Senkan
  • Publication number: 20140330051
    Abstract: The invention is directed to a catalyst for the gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene with HF to give 1-chloro-2,2-difluoroethane which catalyst is prepared by co-depositing FeCl3 and MgCl2 on chromia-alumina, or co-depositing Cr(NO3)3 and Ni(NO3)2 on active carbon, or by doping alumina with ZnCl2, and to a process for the preparation of 1-chloro-2,2-difluoroethane comprising a catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene wherein one of the catalysts according to claim 2 or 3 is used.
    Type: Application
    Filed: October 11, 2012
    Publication date: November 6, 2014
    Applicant: BAYER INTELLECTUAL PROPERTY GMBH
    Inventors: Norbert Lui, Shanthan Rao Pamulaparthy, Srinivas Pvss, Thomas Vijaya, Sridhar Madabhushi, Rambabu Yadla, Narsaiah Banda, Sergii Pazenok
  • Publication number: 20140274667
    Abstract: Sorbents and methods of using them for removing mercury from flue gases over a wide range of temperatures are disclosed. Sorbent materials of this invention comprise oxy- or hydroxyl-halogen (chlorides and bromides) of manganese, copper and calcium as the active phase for Hg0 oxidation, and are dispersed on a high surface porous supports. In addition to the powder activated carbons (PACs), this support material can be comprised of commercial ceramic supports such as silica (SiO2), alumina (Al2O3), zeolites and clays. The support material may also comprise of oxides of various metals such as iron, manganese, and calcium. The non-carbon sorbents of the invention can be easily injected into the flue gas and recovered in the Particulate Control Device (PCD) along with the fly ash without altering the properties of the by-product fly ash enabling its use as a cement additive.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Applicant: TDA RESEARCH, INC.
    Inventor: Gokhan Alptekin
  • Publication number: 20140221197
    Abstract: A method for producing a selective hydrogenation catalyst for hydrogenating a highly unsaturated hydrocarbon to an unsaturated hydrocarbon comprising contacting an inorganic catalyst support with a chlorine-containing compound to form a chlorided catalyst support and adding palladium to the chlorided catalyst support to form a supported-palladium composition. A selective hydrogenation catalyst for hydrogenating a highly unsaturated hydrocarbon to an unsaturated hydrocarbon formed by the method comprising contacting an inorganic catalyst support with a chlorine-containing compound to form a chlorided catalyst support and adding palladium to the chlorided catalyst support to form a supported-palladium composition.
    Type: Application
    Filed: April 9, 2014
    Publication date: August 7, 2014
    Applicant: Chevron Phillips Chemical Company LP
    Inventors: Tin-Tack Peter Cheung, Joseph Bergmeister, III, Zongxuan Hong
  • Publication number: 20140113805
    Abstract: There is provided methods for making a catalyst composition represented by the formula MX/M?F2 wherein MX is an alkali metal halide; M is an alkali metal ion selected from the group consisting of Li+, Na+, K+, Rb+, and Cs+; X is a halogen ion selected from the group consisting of F?, Cl?, Br?, and I?; M?F2 is a bivalent metal fluoride; and M? is a bivalent metal ion. One method has the following steps: (a) dissolving an amount of the alkali metal halide in an amount of solvent sufficient to substantially dissolve or solubilize the alkali metal halide to form an alkali metal halide solution; (b) adding an amount of the bi-valent metal fluoride to the alkali metal halide solution to form a slurry of the alkali metal halide and bi-valent metal fluoride; and (c) removing substantially all of the solvent from the slurry to form a solid mass of the alkali metal halide and bi-valent metal fluoride.
    Type: Application
    Filed: January 2, 2014
    Publication date: April 24, 2014
    Inventors: HAIYOU WANG, HSUEH SUNG TUNG
  • Patent number: 8647431
    Abstract: A catalyst composition for pozzolan compositions, includes: a) one or more chlorides, selected from the group consisting of: sodium chloride, potassium chloride, magnesium chloride, calcium chloride, strontium chloride, barium chloride and/or ammonium chloride, preferably ammonium chloride; b) aluminum chloride, and c) one or more metal oxides, preferably selected from the group consisting of: oxides from metals from Group II of the Periodic Table, oxides from metals from Group VIII B of the Periodic Table (e.g. iron oxide), more preferably oxides from metals from Group II of the Periodic Table, even more preferably magnesium oxide or calcium oxide, most preferably magnesium oxide. The use of the catalytic composition for addition to cement for oil well cementing, and for lowering the pH of cement, a method for obtaining a composition for reinforcing cement, a binder composition and a construction composition are also described.
    Type: Grant
    Filed: August 15, 2012
    Date of Patent: February 11, 2014
    Assignee: MEGA-TECH Holding B.V.
    Inventor: Robin De La Roij
  • Publication number: 20140000490
    Abstract: A catalyst composition for pozzolan compositions, includes: a) one or more chlorides, selected from the group consisting of: sodium chloride, potassium chloride, magnesium chloride, calcium chloride, strontium chloride, barium chloride and/or ammonium chloride, preferably ammonium chloride; b) aluminum chloride, and c) one or more metal oxides, preferably selected from the group consisting of: oxides from metals from Group II of the Periodic Table, oxides from metals from Group VIII B of the Periodic Table (e.g. iron oxide), more preferably oxides from metals from Group II of the Periodic Table, even more preferably magnesium oxide or calcium oxide, most preferably magnesium oxide. The use of the catalytic composition for addition to cement for oil well cementing, and for lowering the pH of cement, a method for obtaining a composition for reinforcing cement, a binder composition and a construction composition are also described.
    Type: Application
    Filed: August 15, 2012
    Publication date: January 2, 2014
    Applicant: MEGA-TECH HOLDING B.V.
    Inventor: Robin DE LA ROIJ
  • Publication number: 20140005039
    Abstract: A process for preparing a catalyst for production of an olefin oxide containing (a) a copper oxide and (b) a ruthenium oxide, which comprises the step of drying a mixture containing a copper component, a ruthenium component, water, and at least one ion selected from the group consisting of a nitrate ion having a molar ratio to the copper of 3 or more and a halide ion having a molar ratio to the ruthenium of 9 or more, and calcining.
    Type: Application
    Filed: June 28, 2013
    Publication date: January 2, 2014
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Yoshihiko OHISHI, Anusorn Seubsai, Selim Senkan
  • Publication number: 20130261363
    Abstract: One embodiment is a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, an alkali or alkaline-earth metal, a lanthanide-series metal, and a support. Generally, an average bulk density of the catalyst is about 0.300 to about 1.00 gram per cubic centimeter. The catalyst has a platinum content of less than about 0.375 wt %, a tin content of about 0.1 to about 2 wt %, a potassium content of about 100 to about 600 wppm, and a cerium content of about 0.1 to about 1 wt %. The lanthanide-series metal can be distributed at a concentration of the lanthanide-series metal in a 100 micron surface layer of the catalyst less than two times a concentration of the lanthanide-series metal at a central core of the catalyst.
    Type: Application
    Filed: July 12, 2012
    Publication date: October 3, 2013
    Applicant: UOP LLC
    Inventors: Manuela Serban, Mark P. Lapinski
  • Patent number: 8546290
    Abstract: A solid catalyst component for olefin polymerization includes a solid component obtained by causing a magnesium compound (a), a titanium halide compound (b), and an electron donor compound (c) to come in contact with each other, the titanium compound in an amount equivalent to a titanium content of 0.2 to 2.5 wt % in the solid catalyst component being washed away from the solid catalyst component by washing with heptane. A granular or spherical polymer that has high stereoregularity and a narrow particle size distribution can be obtained in high yield while suppressing production of a fine powder by polymerizing an olefin using a catalyst that includes the solid catalyst component.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: October 1, 2013
    Assignee: Toho Titanium Co., Ltd.
    Inventors: Hiroyuki Kono, Takashi Fujita
  • Patent number: 8541638
    Abstract: Disclosed herein are processes in which precipitation permits removal of metal halides (e.g. AlCl3) from ionic liquids. After precipitation, the precipitated metal halides can be physically separated from the bulk ionic liquid. More effective precipitation can be achieved through cooling or the combination of cooling and the provision of metal halide seed crystals. The ionic liquids can be regenerated ionic liquid catalysts, which contain excess metal halides after regeneration. Upon removal of the excess metal halides, they can be reused in processes using ionic liquid catalysts, such as alkylation processes.
    Type: Grant
    Filed: November 26, 2008
    Date of Patent: September 24, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Moinuddin Ahmed, Huping Luo, Krishniah Parimi, Bong-Kyu Chang, Sara Lindsay
  • Publication number: 20130217568
    Abstract: A method of making a dehydrogenation catalyst can comprise: combining precursors in water to form a mixture; adding base to the mixture to form a slurry having a pH of 7 to 8.5; aging the slurry at a temperature of greater than or equal to 40° C. while agitating; filtering a precipitate from the aged slurry to collect a catalyst precursor; drying and calcining the catalyst precursor to form the catalyst; wherein the catalyst has the formula (I) FeZnaCobMgcCadCleMfOx ??(I) wherein the amounts are in mole ratios relative to 1 mole of iron, “a” is 0.07 to 0.7 moles; “b” is 0.01 to 0.20 moles; “c” is less than or equal to 0.40 moles; “d” is less than or equal to 0.40 moles; “e” is less than or equal to 0.10 moles; “f” is less than or equal to 0.20 moles, and wherein greater than about 88% of the initial zinc is recovered.
    Type: Application
    Filed: February 11, 2013
    Publication date: August 22, 2013
    Applicant: Saudi Basic Industries Corporation
    Inventors: Paulette Hazin, Reginald Tennyson
  • Publication number: 20130172601
    Abstract: A solid catalyst comprising an effective amount of iridium and at least one second metal selected from gallium, zinc, indium and germanium associated with a solid support material is useful for vapor phase carbonylation to produce carboxylic acids and esters from alkyl alcohols, esters, ethers or ester-alcohol mixtures. The iridium and at least one second metal are deposited on a support material. In some embodiments of the invention, the catalyst is useful for vapor phase carbonylation.
    Type: Application
    Filed: December 17, 2012
    Publication date: July 4, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130144074
    Abstract: A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising (a) ruthenium metal or a ruthenium oxide, (b) manganese oxide and (c) alkaline metal component or alkaline earth metal component.
    Type: Application
    Filed: May 26, 2011
    Publication date: June 6, 2013
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Yoshihiko Ohishi, Anusorn Seubsai, Selim Senkan
  • Patent number: 8435923
    Abstract: Compositions, materials incorporating the compositions, and methods of use thereof, for the protection and/or decontamination of contaminants are disclosed.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: May 7, 2013
    Assignee: Emory University
    Inventors: Nelya Okun, Craig Hill, Zhen Luo
  • Patent number: 8431512
    Abstract: A catalyst for oxychlorination according to the present invention contains alumina and copper, and a content of copper is in the range from 5 to 20% by weight calculated as that of CuO, while a content of halogen is not more than 5% by weight. The catalyst is produced by the following steps (a) to (c): (a) preparing a slurry for spray-drying by adding an acid and an aqueous solution of cupric nitrate in a pseudo-boehmite alumina slurry; (b) spray-drying the slurry; and (c) burning the particles obtained in step (b).
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: April 30, 2013
    Assignee: JGC Catalysts and Chemicals Ltd.
    Inventor: Kazutaka Egami
  • Patent number: 8431727
    Abstract: The present invention relates to novel processes for the manufacture of chroman derivatives such as ?-tocopherol (TCP) and alkanoates thereof, especially ?-tocopheryl acetate (TCPA), whereby at least one step of the processes is carried out in the presence of a Lewis acid or a mixture of a Lewis acid with a Bronsted acid as the catalyst under pressure, preferably at an absolute pressure of at least 1.1 bar. As starting materials for the manufacture of TCP and its alkanoates either a mixture of 2,3,5-trimethylhydroquinone (TMHQ) or 2,3,6-trimethylhydroquinone-1-alkanoate (TMHQA) and a compound selected from the group consisting of phytol (PH), isophytol (IP) and (iso)phytol derivatives or 2-phytyl-3,5,6-trimethyl-hydroquinone (PTMHQ)/3-phytyl-2,5,6-trimethylhydroquinone-1-alkanoate (PTMHQA) and/or an isomer thereof are used. Suitable Lewis acids are indium(III) salts and scandium(III) salts. Suitable acid mixtures are iron/iron(II) chloride/hydrogen chloride and zinc(II) chloride/hydrogen chloride.
    Type: Grant
    Filed: March 6, 2009
    Date of Patent: April 30, 2013
    Assignee: DSM Assets B.V.
    Inventors: Werner Bonrath, Yann Foricher, Thomas Netscher, Angela Wildermann
  • Publication number: 20130072374
    Abstract: A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.
    Type: Application
    Filed: November 8, 2012
    Publication date: March 21, 2013
    Inventors: Jonathan A. Lane, Jamie R. Wilson, Gervase Maxwell Christie
  • Publication number: 20130030194
    Abstract: The present invention relates to a metal catalyst composition for producing furfural derivatives from raw materials of lignocellulosic biomass, and method for producing furfural derivatives using the composition. The present invention comprises ruthenium chloride (RuCl3) and chromium chloride (CrCl2). The chromium chloride (CrCl2) is from 300 to 500 parts by weight on the basis of 100 parts by weight of the ruthenium chloride (RuCl3). Unlike conventional furfural derivatives producing process that should go through multi step processes such as pre-process, saccharification process, etc, the present invention has an advantage of producing furfural derivatives from lignocellulosic raw material only through simple reaction process in one reaction apparatus by mixing various kinds of metal catalyst at an optimum ratio.
    Type: Application
    Filed: April 14, 2011
    Publication date: January 31, 2013
    Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY
    Inventors: Jin Ku Cho, Sangyong Kim, Dohoon Lee, Bora Kim, Jaewon Jeong
  • Publication number: 20130012672
    Abstract: An olefin polymerization catalyst is prepared by (a) in a diluent, combining a diorganomagnesium compound with less than 2 molar equivalents of a first source of chloride to produce a “chloride deficient” magnesium chloride support; (b) without isolating any solids, adding a second source of chloride which reduces the amount of soluble un-reacted diorganomagnesium compound present; (c) without isolating any solids present, adding a tetravalent titanium species and; (d) adding an activator. The catalyst is active for solution polymerization of olefins.
    Type: Application
    Filed: March 8, 2011
    Publication date: January 10, 2013
    Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A.
    Inventors: Qinyan Wang, Peter Zoricak
  • Publication number: 20120330067
    Abstract: Catalyst compositions of palladium supported on alumina or zirconium oxide supports having low or no silicon dioxide contents and having a specific surface area or modified with alkali, alkaline earth, or phosphine oxide compounds are selective in a vapor phase hydrogenolysis reaction to convert cyclic acetal compounds and/or cyclic ketal compounds in the presence of hydrogen to their corresponding hydroxy ether hydrocarbon reaction products.
    Type: Application
    Filed: June 24, 2011
    Publication date: December 27, 2012
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventors: Thomas James Devon, Damon Ray Billodeaux
  • Publication number: 20120316340
    Abstract: The use of metal-accumulating plants for implementing chemical reactions.
    Type: Application
    Filed: November 18, 2010
    Publication date: December 13, 2012
    Applicants: UNIVERSITE MONTPELLIER 2 SCIENCES ET TECHNIQUES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Claude Grison, Jose Escarre
  • Patent number: 8309782
    Abstract: The invention relates to a process for dehydrogenation of a hydrocarbon feedstock in the presence of a catalyst that comprises a noble metal M that is selected from the group that consists of platinum, palladium, rhodium, and iridium, at least one promoter X1 that is selected from the group that consists of tin, germanium, and lead, and optionally a promoter X2 that is selected from the group that consists of gallium, indium and thallium, an alkaline or alkaline-earth compound and a porous substrate, in which the atomic ratio X1/M and optionally X2/M is between 0.3 and 8, the Hir/M ratio that is measured by hydrogen adsorption is greater than 0.40, and the bimetallicity index BMI that is measured by hydrogen/oxygen titration is greater than 108.
    Type: Grant
    Filed: December 7, 2007
    Date of Patent: November 13, 2012
    Assignee: IFP Energies nouvelles
    Inventors: Fabienne Le Peltier, Sylvie Lacombe, Christophe Chau, Stephane Morin, Lars Fischer, Renaud Revel
  • Publication number: 20120283454
    Abstract: A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising (a) copper oxide, (b) ruthenium metal or ruthenium oxide and (c) alkaline metal component or alkaline earth metal component.
    Type: Application
    Filed: December 14, 2010
    Publication date: November 8, 2012
    Inventors: Selim Senkan, Anusorn Seubsai, Yoshihiko Ohishi
  • Publication number: 20120226057
    Abstract: A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.
    Type: Application
    Filed: May 14, 2012
    Publication date: September 6, 2012
    Inventors: Randall Clayton YEATES, John Robert Lockemeyer, Marek Matusz
  • Publication number: 20120214957
    Abstract: This invention relates to a supported nonmetallocene catalyst and preparation thereof. The supported nonmetallocene catalyst can be produced with a simple and feasible process and is characterized by an easily controllable polymerization activity. This invention further relates to use of the supported nonmetallocene catalyst in olefin homopolymerization/copolymerization, which is characterized by a lowered assumption of the co-catalyst as compared with the prior art.
    Type: Application
    Filed: October 13, 2010
    Publication date: August 23, 2012
    Inventors: Chuanfeng Li, Hongping Ren, Xiaoli Yao, Zhonglln Ma, Feng Guo, Kaixiu Wang, Jingwei Liu, Yaming Wang, Lijuan Yang
  • Patent number: 8236726
    Abstract: The present invention discloses a Ni-based catalyst useful in selective hydrogenation, comprising the following components supported on an alumina support: (a) 5.0 to 40.0 wt. % of metallic nickel or oxide(s) thereof; (b) 0.01 to 20.0 wt. % of at least one of molybdenum and tungsten, or oxide(s) thereof; (c) 0.01 to 10.0 wt. % of at least one rare earth element or oxide(s) thereof; (d) 0.01 to 2.0 wt. % of at least one metal from Group IA or Group IIA of the Periodic Table or oxide(s) thereof; (e) 0 to 15.0 wt. % of at least one selected from the group consisting of silicon, phosphorus, boron and fluorine, or oxide(s) thereof; and (f) 0 to 10.0 wt. % of at least one metal from Group IVB of the Periodic Table or oxide(s) thereof; with the percentages being based on the total weight of the catalyst. The catalyst is useful in the selective hydrogenation of a pyrolysis gasoline.
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: August 7, 2012
    Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology Sinopec
    Inventors: Zhongneng Liu, Zaiku Xie, Xiaoling Wu, Minbo Hou, Xinghua Jiang, Hongyuan Zong
  • Publication number: 20120189681
    Abstract: A layered heterostructured coating has functional characteristics that enable the controlled release of volatile agents. The coating has photocatalytic properties, since it uses titanium dioxide, its derivatives or materials with similar photocatalytic properties (2), which upon solar irradiation open and/or degrade nano or microcapsules (3) and subsequently releases in a controlled form the volatile agents contained in them.
    Type: Application
    Filed: December 11, 2009
    Publication date: July 26, 2012
    Inventors: Carlos José Macedo Tavares, Femando Da Silva Pina
  • Publication number: 20120178888
    Abstract: A Ziegler-Natta procatalyst composition in the form of solid particles and comprising magnesium, halide and transition metal moieties, said particles having an average size (D50) of from 10 to 70 ?m, characterized in that at least 5 percent of the particles have internal void volume substantially or fully enclosed by a monolithic surface layer (shell), said layer being characterized by an average shell thickness/particle size ratio (Thickness Ratio) determined by SEM techniques for particles having particle size greater than 30 ?m of greater than 0.2.
    Type: Application
    Filed: March 22, 2012
    Publication date: July 12, 2012
    Applicant: Union Carbide Chemicals & Plastics Technology LLC
    Inventors: Robert J. Jorgensen, Michael A. Kinnan, Michael D. Turner, Stephanie M. Whited, Laszlo L. Ban, Burkhard E. Wagner
  • Publication number: 20120129687
    Abstract: A process for making a fluorinated olefin and/or catalyst composition. The process has the step of dehydrochlorinating a hydrochlorofluorocarbon having at least one hydrogen atom and at least one chlorine atom on adjacent carbon atoms in the presence of a catalytically effective amount of a catalyst composition. The catalyst composition is represented by the following: n wt. % MX/M?OyFz, wherein 0<y<1 and 0<z<2 and wherein y+z/2=1; M is an alkali metal ion selected from the group consisting of Li+, Na+, K+, Rb+, and Cs+; X is a halogen ion selected from the group consisting of F?, Cl?, Br?, and I?, M? is a bivalent metal ion; wherein n is a weight percentage of about 0.05% to about 50% MX based on the total weight of the MX and M?OyFz, and wherein y and z are the mole fractions of oxygen and fluorine in M?OyFz, respectively.
    Type: Application
    Filed: October 12, 2011
    Publication date: May 24, 2012
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: HAIYOU WANG, HSUEH SUNG TUNG
  • Publication number: 20120116131
    Abstract: A new chromium-containing fluorination catalyst is described. The catalyst comprises an amount of zinc that promotes activity. The zinc is contained in aggregates which have a size across their largest dimension of up to 1 micron. The aggregates are distributed throughout at least the surface region of the catalyst and greater than 40 weight % of the aggregates contain a concentration of zinc that is within ±1 weight % of the modal concentration of zinc in those aggregates.
    Type: Application
    Filed: September 4, 2009
    Publication date: May 10, 2012
    Applicant: Mexichem Amanco Holdings S.A. DE C.V.
    Inventor: Andrew P. Sharratt
  • Publication number: 20120091038
    Abstract: The present invention concerns an optimized reforming catalyst comprising at least platinum, at least one promoter metal selected from the group formed by rhenium and iridium, at least one halogen, and at least one alumina support with a low sulphur and phosphorus content.
    Type: Application
    Filed: October 17, 2011
    Publication date: April 19, 2012
    Applicant: IFP Energies nouvelles
    Inventors: Sylvie LACOMBE, Malika Boualleg, Eric Sanchez
  • Publication number: 20120065055
    Abstract: The present invention relates to a support for silver catalyst used in the ethylene oxide production, a preparation method for the same, a silver catalyst prepared from the same, and its use in the ethylene oxide production. The silver catalyst produced from the silver catalyst support has an improved activity, stability and/or selectivity in the production of ethylene oxide by epoxidation of ethylene.
    Type: Application
    Filed: September 13, 2011
    Publication date: March 15, 2012
    Applicants: Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation, China Petroleum & Chemical Corporation
    Inventors: Jun JIANG, Jianshe CHEN, Jinbing LI, Shuyun LI, Zhixiang ZHANG, Wei LIN, Qian XUE