Magnesium Patents (Class 502/251)
  • Patent number: 11033849
    Abstract: The honeycomb structure includes a pillar-shaped honeycomb structure body that includes a porous partition wall. When the thickness (?m) of the partition wall is defined as T1 and, among pores formed in the partition wall, the value of an average pore diameter (?m) of specific pores whose pore diameters measured by a mercury press-in method are 20 to 100 ?m is defined as D(20 to 100), T1/D(20 to 100) that is a value obtained by dividing T1 by D(20 to 100) is not less than 2.4, a ratio of a pore volume of the specific pores to an overall pore volume of the partition wall is 5 to 45%, and a ratio of a pore volume of large pores whose pore diameters are not less than 100 ?m to the overall pore volume of the partition wall is not more than 5%.
    Type: Grant
    Filed: March 11, 2019
    Date of Patent: June 15, 2021
    Assignee: NGK Insulators, Ltd.
    Inventors: Tomohiro Ishioka, Hirotaka Yamamoto
  • Patent number: 10010870
    Abstract: Embodiments of a method of synthesizing a metathesis and isomerization catalyst or metathesis catalyst or isomerization catalyst comprises forming a catalyst precursor solution comprising a diluent and a catalyst precursor where the catalyst precursor comprises at least one of a silica precursor and an alumina precursor for the isomerization catalyst and additionally an oxometallate precursor or metal oxide precursor for the metathesis catalyst or the metathesis and isomerization catalyst, where the catalyst precursor solution is absent a surfactant; aerosolizing the catalyst precursor solution; drying the aerosolized catalyst precursor mixture to form a dried catalyst precursor; and reacting the dried catalyst precursor to yield the metathesis and isomerization catalyst or the metathesis catalyst or the isomerization catalyst, the metathesis and isomerization catalyst comprising a silica and alumina support with an oxometallate or a metal oxide distributed within the silica and alumina support.
    Type: Grant
    Filed: August 31, 2016
    Date of Patent: July 3, 2018
    Assignee: Saudi Arabian Oil Company
    Inventors: Michele L. Ostraat, Brian S. Hanna
  • Patent number: 9688590
    Abstract: A process for the production of jet and other heavy fuels, the process including: contacting at least one C3 to C5 isoalkanol with a first catalyst to convert at least a portion of the isoalkanol to isoalkene, isoalkene dimers, and water; contacting at least a portion of the isoalkene dimers with a second catalyst to convert at least a portion of the isoalkene dimers to isoalkene trimers; hydrotreating the isoalkene trimers to form isoalkanes useful as a jet fuel, kerosene, or other heavy fuels.
    Type: Grant
    Filed: May 10, 2011
    Date of Patent: June 27, 2017
    Assignee: Catalytic Distillation Technologies
    Inventors: William M. Cross, Jr., Gary G. Podrebarac
  • Patent number: 9079798
    Abstract: Porous composites of mullite and cordierite are formed by firing an acicular mullite body in the presence of a magnesium source and a silicon source. In some variations of the process, the magnesium and silicon sources are present when the acicular mullite body is formed. In other variations, the magnesium source and the silicon source are applied to a previously-formed acicular mullite body. Surprisingly, the composites have coefficients of linear thermal expansion that are intermediate to those of mullite and cordierite alone, and have higher fracture strengths than cordierite at a similar porosity. Some of the cordierite forms at grain boundaries and/or points of intersection between mullite needles, rather than merely coating the needles. The presence of magnesium and silicon sources during acicular mullite formation does not significantly affect the ability to produce a highly porous network of mullite needles.
    Type: Grant
    Filed: September 22, 2014
    Date of Patent: July 14, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Daniel Grohol, Chan Han, Aleksander J. Pyzik
  • Patent number: 9029285
    Abstract: A catalyst including: a support, the support including a mixture of SiO2 and ZrO2; an active ingredient including copper; a first additive including a metal, an oxide thereof, or a combination thereof; and a second additive including Li, Na, K, or a combination thereof. The metal is Mg, Ca, Ba, Mn, Fe, Co, Zn, Mo, La, or Ce. Based on the total weight of the catalyst, the weight percentages of the different components are as follows: SiO2=50-90 wt. %; ZrO2=0.1-10 wt. %; copper=10-50 wt. %; the first additive=0.1-10 wt. %; and the second additive=0.1-5 wt. %.
    Type: Grant
    Filed: May 28, 2013
    Date of Patent: May 12, 2015
    Assignee: Tianjin University
    Inventors: Xinbin Ma, Jing Lv, Yujun Zhao, Shengping Wang, Jinlong Gong, Baowei Wang, Zhenhua Li, Yan Xu
  • Publication number: 20150080605
    Abstract: What is described is a catalyst for preparation of an ?,?-unsaturated carboxylic acid by gas phase oxidation of an ?,?-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q ) ? S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an ?,?-unsaturated carboxylic acid by gas phase oxidation of an ?,?-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.
    Type: Application
    Filed: September 16, 2014
    Publication date: March 19, 2015
    Applicant: BASF SE
    Inventors: Cathrin Alexandra WELKER-NIEUWOUDT, Cornelia Katharina Dobner, Holger Borchert, Ulrich Hammon, Josef Macht, Andrey Karpov, Christian Walsdorff
  • Patent number: 8945689
    Abstract: A method of preparing hydrotalcite for a PVC stabilizer, which comprises: forming crystals of hydrotalcite represented by a formula of M(II)XM(III)Y(OH)N(Am—)Z. nH2O, wherein M(II) is a divalent metal selected from Mg2+, Ni2+ and Zn2+; M(III) is a trivalent metal selected from Al3+, Fe3+, Cr3+ and Co3+; and Am— is an anion selected from CO32-, OH—, NO3-, SO42- and halides; and depositing zinc (Zn) onto the hydrotalcite by using any one method of electrode-position, chloride ion deposition, and plasma deposition to provide zinc-deposited hydrotalcite.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: February 3, 2015
    Inventor: Dae Hee Lee
  • Patent number: 8889078
    Abstract: A porous oxide catalyst includes porous oxide, and an oxygen vacancy-inducing metal which induces an oxygen vacancy in a lattice structure of a porous metal oxide.
    Type: Grant
    Filed: March 15, 2011
    Date of Patent: November 18, 2014
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Sang-min Ji, Hyun-chul Lee, Doo-hwan Lee, Seon-ah Jin
  • Patent number: 8871676
    Abstract: Porous composites of mullite and cordierite are formed by firing an acicular mullite body in the presence of a magnesium source and a silicon source. In some variations of the process, the magnesium and silicon sources are present when the acicular mullite body is formed. In other variations, the magnesium source and the silicon source are applied to a previously-formed acicular mullite body. Surprisingly, the composites have coefficients of linear thermal expansion that are intermediate to those of mullite and cordierite alone, and have higher fracture strengths than cordierite at a similar porosity. Some of the cordierite forms at grain boundaries and/or points of intersection between mullite needles, rather than merely coating the needles. The presence of magnesium and silicon sources during acicular mullite formation does not significantly affect the ability to produce a highly porous network of mullite needles.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: October 28, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Daniel Grohol, Chan Han, Aleksander J. Pyzik
  • Publication number: 20140296605
    Abstract: The invention relates to a catalyst composition suitable for the non-oxidative dehydrogenation of alkanes having 2-8 carbon atoms comprising silico-zinc aluminate, wherein the relative molar ratios of the elements comprised in said composition are represented by SixZn1-xAl2O4, wherein x stands for a number in the range from 0.003 to 0.76. The invention also relates to a process for the preparation of said catalyst composition, to a process for the non-oxidative dehydrogenation of alkanes, preferably isobutane using said catalyst and to the use of said catalyst in a process for the non-oxidative dehydrogenation of alkanes.
    Type: Application
    Filed: September 27, 2013
    Publication date: October 2, 2014
    Applicant: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Subhash Chandra Laha, Antonisamy Selvanathan, Sandeep Negi
  • Patent number: 8841498
    Abstract: The present invention relates to a catalyst for the hydrogenation of unsaturated hydrocarbons, in particular aromatics with a broad molecular weight range, a process for the production thereof and a process for hydrogenating unsaturated hydrocarbons.
    Type: Grant
    Filed: July 18, 2013
    Date of Patent: September 23, 2014
    Assignee: Shell Oil Company
    Inventors: Peter Birke, Reinhard Geyer, Jurgen Hunold, Peter Kraak, Rainer Schoedel
  • Patent number: 8734743
    Abstract: Described is a nitrogen oxide storage catalyst comprising: a substrate; a first washcoat layer provided on the substrate, the first washcoat layer comprising a nitrogen oxide storage material, a second washcoat layer provided on the first washcoat layer, the second washcoat layer comprising a hydrocarbon trap material, wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing selective catalytic reduction, preferably wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing a reaction wherein nitrogen oxide is reduced to N2, said catalyst further comprising a nitrogen oxide conversion material which is either comprised in the second washcoat layer and/or in a washcoat layer provided between the first washcoat layer and the second washcoat layer.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: May 27, 2014
    Assignee: BASF SE
    Inventors: Torsten W. Müller-Stach, Susanne Stiebels, Edith Schneider, Torsten Neubauer
  • Patent number: 8673806
    Abstract: The invention concerns catalysts comprising (i) a cladded catalyst support comprising (a) a core which comprises alumina particles and (b) about 1 to about 40 weight percent silica cladding, based on the weight of the cladded catalyst support, on the surface of the core; the catalyst support having a BET surface area of greater than 20 m2/g and a porosity of at least about 0.2 cc/g; and (ii) 0.1 to 10 weight percent, based on the weight of the catalyst, of catalytically active transition metal on the surface of the cladded catalyst support; wherein the catalyst support has a normalized sulfur uptake (NSU) of up to 25 ?g/m2. The invention also concerns the production and use of such catalysts.
    Type: Grant
    Filed: January 7, 2010
    Date of Patent: March 18, 2014
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Stephen R. Schmidt, David M. Chapman, Manoj M. Koranne, Michael D. Jensen
  • Patent number: 8637719
    Abstract: The invention concerns a catalyst comprising a porous support, palladium, at least one metal selected from the group constituted by alkalis and alkaline-earths, in which: the specific surface area of the porous support is in the range 50 to 210 m2/g; the palladium content in the catalyst is in the range 0.05% to 2% by weight; at least 80% by weight of the palladium is distributed in a crust at the periphery of the support, the thickness of said crust being in the range 20 to 200 ?m; the metallic dispersion D is in the range 25% to 70%; the density of the palladium particles in the crust is in the range 1500 to 4100 particles of palladium per ?m2; and said alkali and/or alkaline-earth metal is distributed homogeneously across the support. The invention also concerns the preparation of the catalyst and its use in selective hydrogenation.
    Type: Grant
    Filed: October 24, 2008
    Date of Patent: January 28, 2014
    Assignee: IFP Energies nouvelles
    Inventors: Lars Fischer, Carine Petit-Clair, Cecile Thomazeau, Lois Sorbier, Catherine Verdon
  • Publication number: 20130331257
    Abstract: The invention relates to a method for producing micro-nano combined active systems in which nanoparticles of a first component are bonded to microparticles of a second component, comprising the following steps: (a) producing a low-ligand colloidal suspension containing nanoparticles of the first component, (b) adding microparticles to the colloidal suspension containing the nanoparticles or adding the colloidal suspension containing the nanoparticles to a dispersion containing the microparticles and intensively mixing so that the nanoparticles adsorb onto the microparticles, (c) separating the microparticles and the nanoparticles bonded thereto from the liquid and drying the microparticles and the nanoparticles bonded thereto.
    Type: Application
    Filed: December 16, 2011
    Publication date: December 12, 2013
    Applicant: LASER ZENTRUM HANNOVER E.V.
    Inventors: Stephan Barcikowski, Philipp Wagener, Andreas Schwenke
  • Publication number: 20130296164
    Abstract: Catalysts and processes for forming catalysts for use in hydrogenating acetic acid to form ethanol. In one embodiment, the catalyst comprises a first metal, a silicaceous support, and at least one metasilicate support modifier. Preferably, the first metal is selected from the group consisting of copper, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, titanium, zinc, chromium, rhenium, molybdenum, and tungsten. In addition the catalyst may comprise a second metal preferably selected from the group consisting of copper, molybdenum, tin, chromium, iron, cobalt, vanadium, tungsten, palladium, platinum, lanthanum, cerium, manganese, ruthenium, rhenium, gold, and nickel.
    Type: Application
    Filed: June 12, 2013
    Publication date: November 7, 2013
    Inventors: Victor J. Johnston, Barbara F. Kimmich, John L. Potts, Heiko Weiner, Radmila Wollrab, James H. Zink, Josefina T. Chapman, Laiyuan Chen
  • Patent number: 8518851
    Abstract: The present invention relates to a catalyst for the hydrogenation of unsaturated hydrocarbons, in particular aromatics with a broad molecular weight range, a process for the production thereof and a process for hydrogenating unsaturated hydrocarbons.
    Type: Grant
    Filed: October 17, 2008
    Date of Patent: August 27, 2013
    Assignee: Shell Oil Company
    Inventors: Peter Birke, Reinhard Geyer, Jürgen Hunold, Peter Kraak, Rainer Schoedel
  • Publication number: 20130172177
    Abstract: A catalyst comprising (i) a support, (ii) metal particles and (iii) a shell which is arranged between the metal particles, wherein the shell (iii) comprises silicon oxide.
    Type: Application
    Filed: September 13, 2011
    Publication date: July 4, 2013
    Applicant: BASF SE
    Inventors: Imme Domke, Wolfgang Rohde, Piotr Antoni Bazula, Norbert Mronga, Yong Liu, Martin Dieterle, Stanley Roth, Curtis Zimmermann, Xinyi Wei, Philipp Raff, Stephan Andreas Schunk, Olga Gerlach, Andreas Strasser, Michael Paul
  • Patent number: 8415267
    Abstract: Core-shell nanoparticles having a core material and a mesoporous silica shell, and a method for manufacturing the core-shell nanoparticles are provided.
    Type: Grant
    Filed: June 4, 2012
    Date of Patent: April 9, 2013
    Assignee: Korea University Research and Business Foundation
    Inventor: Kwangyeol Lee
  • Patent number: 8389430
    Abstract: Porous spodumene-cordierite honeycomb bodies of high strength but low volumetric density, useful for the manufacture of close-coupled engine exhaust converters, gasoline engine particulate exhaust filters, and NOx integrated engine exhaust filters, are provided through the reactive sintering of batches comprising sources of magnesia, alumina and silica together with a lithia source, such as a spodumene or petalite ore.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: March 5, 2013
    Assignee: Corning Incorporated
    Inventors: Gregory Albert Merkel, Cameron Wayne Tanner
  • Patent number: 8343885
    Abstract: Extruded isomerization catalysts comprising MgO, a metal silicate clay binder and a stabilizer and methods of forming such isomerization catalysts are disclosed. Also disclosed are isomerization catalysts that exhibit a fresh isomerization rate and an aged isomerization rate that is at least 50% of the fresh isomerization rate. Embodiments of the isomerization catalysts disclosed herein include metal silicate clay binders that include a layered structure and metal silicate. The metal silicate clay binder may be present in an amount in the range from about 5 wt % to about 20 wt %. Exemplary stabilizers include one or more of ZrO2, tetravalent rare earth metal and a trivalent rare earth metal. Stabilizers may be present in an amount up to about 40 wt %. One or more improved properties, such as piece crush strength and isomerization performance, are exhibited by the catalyst article.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: January 1, 2013
    Assignee: BASF Corporation
    Inventors: Wolfgang Ruettinger, Ahmad Moini, Bala Ramachandran, Sukwon Choi
  • Publication number: 20120322650
    Abstract: One exemplary embodiment can be a layered catalyst for use in a selective hydrogenation of acetylenes and diolefins to olefins. The layered catalyst may include an inner core having an inert material, an outer layer including a metal oxide bonded to the inner core, and a metal deposited on the outer layer. Generally, the metal is an IUPAC Group 8-10 metal and the layered catalyst has an accessibility index of about 3- about 500.
    Type: Application
    Filed: June 15, 2011
    Publication date: December 20, 2012
    Applicant: UOP, LLC
    Inventors: Gregory J. Gajda, Bryan K. Glover, Antoine Negiz, John Joseph Senetar, Erik Holmgreen, Mark G. Riley
  • Patent number: 8288306
    Abstract: The present invention provides a preparation process of complex oxides catalyst containing Mo, Bi, Fe and Co, which comprising steps as following: dissolving precursor compounds of the components for catalyst and complexing agent in water to obtain a solution, and then drying, molding and calcining the solution to obtain catalyst. The catalyst is used for gas phase oxidation of light alkenes to unsaturated aldehydes. The catalyst has high activity, selectivity and stability. The reaction condition is mild. The preparation process of the catalyst is easy to operate and can be used for mass production.
    Type: Grant
    Filed: January 20, 2010
    Date of Patent: October 16, 2012
    Assignee: Shanghai Huayi Acrylic Acid Co., Ltd.
    Inventors: Ge Luo, Xin Wen, Xiaoqi Zhao, Xuemei Li, Yan Zhuang, Jianxue Ma, Jingming Shao
  • Patent number: 8216961
    Abstract: Core-shell nanoparticles having a core material and a mesoporous silica shell, and a method for manufacturing the core-shell nanoparticles are provided.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: July 10, 2012
    Assignee: Korea University Research and Business Foundation
    Inventor: Kwangyeol Lee
  • Patent number: 8207327
    Abstract: The invention relates to a shell catalyst containing ruthenium as an active metal, alone or together with at least one other metal of the auxiliary group IB, VIIB or VIII of the periodical system of the elements (CAS version), and applied to a carrier containing silicon dioxide as a carrier material. The invention also relates to a method for producing said shell catalyst, and to a method for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols, using the inventive shell catalyst. The invention further relates to the use of the inventive shell catalyst for hydrogenating an organic compound containing hydrogenable groups, preferably for hydrogenating a carbocyclic aromatic group to form the corresponding carbocyclic aliphatic groups or for hydrogenating aldehydes to form the corresponding alcohols.
    Type: Grant
    Filed: June 20, 2006
    Date of Patent: June 26, 2012
    Assignee: BASF SE
    Inventors: Frederik Van Laar, Michael Becker, Ekkehard Schwab, Jochem Henkelmann, Peter Polanek
  • Patent number: 8207083
    Abstract: The present invention relates to a catalyst nickel, silica, alumina and magnesium, wherein the nickel to magnesium atomic ratio is 5-75. In particular the present invention relates to a catalyst comprising nickel, silica, alumina and magnesium, wherein the nickel to silicium atomic ratio (Ni/Si) is 2 to 30 to nickel to aluminum atomic ratio (Ni/Al) is 9 to 40 and the nickel to magnesium atomic ratio (Ni/Mg) is 5-75. The invention further relates to a method for preparing such a catalyst. The invention further relates to a process for hydrogenating unsaturated organic compounds.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: June 26, 2012
    Assignee: BASF Corporation
    Inventors: Pieter Hildegardus Berben, Tjalling Rekker
  • Publication number: 20120142520
    Abstract: A catalyst system is disclosed for catalytic pyrolysis of a solid biomass material. The system comprises an oxide, silicate or carbonate of a metal or a metalloid. The specific combined meso and macro surface area of the system is in the range of from 1 m2/g to 100 m2/g. When used in a catalytic process the system provides a high oil yield and a low coke yield. The liquid has a relatively low oxygen content.
    Type: Application
    Filed: April 22, 2010
    Publication date: June 7, 2012
    Applicant: KIOR INC.
    Inventors: Robert Bartek, Michael Brady, Dennis Stamires
  • Patent number: 8148297
    Abstract: A porous ceramic material is disclosed having a principal cordierite phase, the porous ceramic material exhibiting a normalized strength greater than 20 MPa. The cordierite phase has a reticular microstructure. A method for forming a porous ceramic body having a predominant phase of cordierite is provided which includes forming a body from a plasticized mixture of inorganic ceramic-forming ingredients that include a magnesia source, a silica source, and an alumina source, the alumina source including alumina-containing elongated particles, wherein at least 90 wt % of the alumina-containing elongated particles have a length of 50 to 150 ?m, and then firing the body.
    Type: Grant
    Filed: November 30, 2009
    Date of Patent: April 3, 2012
    Assignee: Corning Incorporated
    Inventors: Monika Backhaus-Ricoult, Christopher Raymond Glose, James William Zimmermann
  • Publication number: 20120071614
    Abstract: The invention concerns catalysts comprising (i) a cladded catalyst support comprising (a) a core which comprises alumina particles and (b) about 1 to about 40 weight percent silica cladding, based on the weight of the cladded catalyst support, on the surface of the core; the catalyst support having a BET surface area of greater than 20 m2/g and a porosity of at least about 0.2 cc/g; and (ii) 0.1 to 10 weight percent, based on the weight of the catalyst, of catalytically active transition metal on the surface of the cladded catalyst support; wherein the catalyst support has a normalized sulfur uptake (NSU) of up to 25 ?g/m2. The invention also concerns the production and use of such catalysts.
    Type: Application
    Filed: January 7, 2010
    Publication date: March 22, 2012
    Inventors: Stephen R. Schmidt, David M. Chapman, Manoj M. Koranne, Michael D. Jensen
  • Patent number: 8071655
    Abstract: A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM?(1?x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.
    Type: Grant
    Filed: November 17, 2005
    Date of Patent: December 6, 2011
    Assignees: IFP Energies Nouvelles, ENI S.p.A.
    Inventors: Fabrice Diehl, François Hugues, Marie-Claire Marion, Denis Uzio
  • Publication number: 20110257443
    Abstract: A catalyst comprising a first metal, a silicaceous support, and at least one metasilicate support modifier, wherein at least 1 wt. % of the at least one metasilicate support modifier is crystalline in phase, as determined by x-ray diffraction. The invention also relates to processes for forming such catalysts, to supports used therein, and to processes for hydrogenating acetic acid in the presence of such catalysts.
    Type: Application
    Filed: February 1, 2011
    Publication date: October 20, 2011
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventors: Heiko Weiner, Victor J. Johnston
  • Publication number: 20110212829
    Abstract: A process for making a ceramic catalyst material includes mixing a catalyst precursor material with a mineral particulate to form a mixture; adding a binder, silicon carbide, and a parting agent to the mixture to form unfired spheroids; and heating the unfired spheroids at a temperature effective to oxidize the silicon carbide and the catalyst precursor material to form the ceramic catalyst material. In another embodiment, the process includes the addition of a catalyst metal oxide salt to an aluminosilicate hydrogel aggregate mixture. Once the mixture sets, the set mixture is heated to a temperature to effective to produce a high surface area ceramic catalyst material.
    Type: Application
    Filed: March 16, 2011
    Publication date: September 1, 2011
    Inventor: Felice DiMascio
  • Publication number: 20110172482
    Abstract: A catalyst that comprises at least one binder and at least one crystallized material with hierarchized and organized porosity in the fields of microporosity and mesoporosity is described, whereby said crystallized material consists of at least two elementary spherical particles, each of said particles comprising a mesostructured silicon-oxide-based matrix that has a mesopore diameter of between 1.5 and 30 nm and that has microporous and crystallized walls with a thickness of between 1 and 60 nm, whereby said elementary spherical particles have a maximum diameter of 200 microns. Said catalyst is used in a process for oligomerization of an olefinic feedstock that contains hydrocarbon molecules that have 2 to 12 carbon atoms per molecule.
    Type: Application
    Filed: April 28, 2009
    Publication date: July 14, 2011
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Amandine Cabiac, Alexandra Chaumonnot, Laurent Simon
  • Patent number: 7967976
    Abstract: A method for treating crude or residual fuel oil includes extracting vanadium from the fuel oil by contacting the fuel oil with an adsorbent and a solvent. The adsorbent may be modified with a compound having both acidic functionality and basic functionality. The method provides effective removal of vanadium from crude or residual fuel oil at moderate temperatures.
    Type: Grant
    Filed: January 12, 2007
    Date of Patent: June 28, 2011
    Assignee: General Electric Company
    Inventors: James Manio Silva, Grigorii Lev Soloveichik
  • Patent number: 7909986
    Abstract: Reduced emissions of gas phase reduced nitrogen species in the off gas of an FCC regenerator operated in a partial or incomplete mode of combustion is achieved by contacting the off gas with an oxidative catalyst/additive composition having the ability to reduce gas phase nitrogen species to molecular nitrogen and to oxidize CO under catalytic cracking conditions. The oxidative catalyst/additive composition is used in an amount less than the amount necessary to prevent afterburn. Fluidizable particles of the oxidative catalyst/additives are circulated throughout the partial or incomplete burn FCC unit along with the FCC catalyst inventory. The flue gas having a reduced content of gas phase reduced nitrogen species and NOx is passed to a downstream CO boiler, preferably a low NOx CO boiler. In the CO boiler, as CO is oxidized to CO2, a reduced amount of gas phase reduced nitrogen species is oxidized to NOx, thereby providing an increase in the overall reduction of NOx emitted into the environment.
    Type: Grant
    Filed: May 6, 2009
    Date of Patent: March 22, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: George Yaluris, John Allen Rudesill
  • Patent number: 7906015
    Abstract: Reduced emissions of gas phase reduced nitrogen species in the off gas of an FCC regenerator operated in a partial or incomplete mode of combustion is achieved by contacting the off gas with an oxidative catalyst/additive composition having the ability to reduce gas phase nitrogen species to molecular nitrogen and to oxidize CO under catalytic cracking conditions. The oxidative catalyst/additive composition is used in an amount less than the amount necessary to prevent afterburn. Fluidizable particles of the oxidative catalyst/additives are circulated throughout the partial or incomplete burn FCC unit along with the FCC catalyst inventory. The flue gas having a reduced content of gas phase reduced nitrogen species and NOx is passed to a downstream CO boiler, preferably a low NOx CO boiler. In the CO boiler, as CO is oxidized to CO2, a reduced amount of gas phase reduced nitrogen species is oxidized to NOx, thereby providing an increase in the overall reduction of NOx emitted into the environment.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: March 15, 2011
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: George Yaluris, John Allen Rudesill
  • Patent number: 7902112
    Abstract: A fluidized bed catalyst for producing acrylonitrile capable of maintaining a high yield of acrylonitrile over a long time, and a process for producing acrylonitrile using the catalyst are provided. A fluidized bed catalyst for producing acrylonitrile having a composition represented by a following general formula: MoaBibFecWdNieMgfAgBhCiDjEkFlGmOn(SiO2)p In the formula, A represents Ce and La, B represents Ca, Sr, Ba, Mn, Co, Cu, Zn and Cd, C represents Y, Pr, Nd, Sm, Al, Cr, Ga and In, D represents Ti, Zr, V, Nb, Ta, Ge, Sn, Pb and Sb, E represents Ru, Rh, Pd, Re, Os, Ir, Pt and Ag, F represents P, B and Te, G represents Li, Na, K, Rb, Cs and Tl, SiO2 represents silica, when a=10, b=0.1 to 1.5, c=0.5 to 3, d=0.1 to 1.5, e=0.1 to 8, f=0.1 to 5, g=0.1 to 1.5, h=0 to 8, i=0 to 3, j=0 to 3, k=0 to 3, l=0 to 3, m=0.01 to 2, p=10 to 200 and n is the atomic ratio of oxygen required to satisfy the valence of each of the elements excluding silicon, and (a×2+d×2)/(b×3+c×3+e×2+f×2+g×3+h×2+i×3+m×1)=0.90 to 1.00).
    Type: Grant
    Filed: October 23, 2007
    Date of Patent: March 8, 2011
    Assignee: Dia-Nitrix Co., Ltd.
    Inventors: Motoo Yanagita, Kenichi Miyaki, Hirokazu Watanabe
  • Publication number: 20110039689
    Abstract: The present invention relates to a shaped catalyst body comprising a core and a first catalytically active layer arranged on sections of the core, characterized in that the total density of the core is greater than the total density of the catalytically active layer. The invention further relates to the use of said shaped catalyst body as an oxidation catalyst in the cleaning of exhaust gases or for reducing and decomposing nitrogen oxides and nitrous oxide.
    Type: Application
    Filed: April 21, 2008
    Publication date: February 17, 2011
    Inventors: Arno Tissler, Hans-Christoph Schwarzer, Roderik Althoff
  • Publication number: 20110028308
    Abstract: A method includes a providing a molten glass fiber core and disposing a plurality of nanoparticles that include a transition metal oxide on the molten glass fiber core at or above the softening temperature of the glass fiber core, thereby forming a nanoparticle-laden glass fiber. The plurality of nanoparticles are embedded at the surface of said glass fiber core. A method includes providing a mixture of molten glass and a plurality of nanoparticles. The plurality of nanoparticles include a transition metal. The method further includes forming nanoparticle-laden glass fibers, in which the plurality of nanoparticles are embedded throughout the glass fibers.
    Type: Application
    Filed: July 29, 2010
    Publication date: February 3, 2011
    Applicant: Lockheed Martin Corporation
    Inventors: Tushar K. SHAH, Harry C. Malecki
  • Publication number: 20100331571
    Abstract: An object of the present invention is to provide a molding and a method for producing the same; a catalyst for the production of an unsaturated aldehyde and an unsaturated carboxylic acid, and a method for producing the same; and a catalyst for the production of methacrylic acid, and a method for producing the same. The molding of the present invention shows a shape including a plurality of columnar portions disposed with a predetermined gap; and bridge portions which are provided at both ends in longitudinal directions of two adjacent columnar portions and join adjacent columnar portions each other; and including through holes surrounded by a plurality of columnar portions in the longitudinal directions of the columnar portions, and openings formed on a peripheral surface by a gap between the plurality of adjacent columnar portions.
    Type: Application
    Filed: June 24, 2010
    Publication date: December 30, 2010
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Hirofumi Saito, Yuya Takahashi, Toyohisa Hoshikawa, Kazuya Tsuchimoto, Osamu Yamanishi
  • Patent number: 7855162
    Abstract: The present invention provides a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a base material is a high specific surface area porous cordierite body that is stable at high temperatures, and also provides methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body. The present invention relates to a needle-shaped ceramic body and needle-shaped ceramic catalyst body in which a base material is a high temperature-stable, high specific surface area porous cordierite body comprising a porous structure having a prescribed porosity and formed of a needle-shaped cordierite crystal phase, and further relates to methods of producing this needle-shaped ceramic body and needle-shaped ceramic catalyst body, and by using porous cordierite constituted of needle-shaped crystals as a catalyst-supporting honeycomb structure, the present invention is able to inhibit sintering-induced reduction in the specific surface area.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: December 21, 2010
    Assignees: National Institute of Advanced Industrial Science and Technology, Denso Corporation, Nippon Soken, Inc.
    Inventors: Jayaseelan Daniel Doni, Hideki Kita, Naoki Kondo, Shunkichi Ueno, Tatsuki Ohji, Shuzo Kanzaki, Kazuhiko Koike, Takumi Suzawa, Tomohiko Nakanishi
  • Patent number: 7838460
    Abstract: A nanoporous metal oxide material comprising two or more metal oxides, wherein the nanoporous metal oxide material has ceria content of 10 to 60 weight %, zirconia content of 20 to 90 weight %, and alumina content of 70 weight % or less, and has nanopores whose diameters are 10 nm or less, and the metal oxides are homogeneously dispersed in a wall constituting the nanopores.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: November 23, 2010
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Takashi Shimazu, Ryusuke Tsuji, Hideo Sobukawa, Yoshiki Seno
  • Patent number: 7811652
    Abstract: A formed article is made of cordierite. The cordierite has a plurality of domains and a plurality of crystal grains placed in each domain to form a domain structure. The crystal grains in each domain are substantially aligned in the same direction, and an average size of the domains ranges from 40 ?m to 150 ?m. The article of cordierite is formed in a honeycomb structure having a plurality of cell walls arranged in a honeycomb form, and a plurality of cells divided by the cell walls are formed. The article of cordierite has a porosity ranging from 36% to 38%, a coefficient of linear thermal expansion equal to or lower than 0.2×106/K and a mechanical strength equal to or higher than 60×106 Pa.
    Type: Grant
    Filed: March 20, 2009
    Date of Patent: October 12, 2010
    Assignees: Denso Corporation, Nippon Soken, Inc.
    Inventors: Kentaro Makino, Kazushige Uchiyama, Yoshihide Segawa, Tomohiko Nakanishi, Yuichi Kobayashi
  • Publication number: 20100233051
    Abstract: Nitrogen oxide storage catalysts are used to remove nitrogen oxides from the exhaust gas of internal combustion engines operated predominantly under lean burn conditions. When these catalysts are used in diesel vehicles, the increased sulfur content in the fuel during operation results in poisoning of the catalyst, which is reversible at high temperatures under reduced exhaust gas conditions. In the case of conventional nitrogen oxide storage catalysts, temperatures of more than 600° C. have to be obtained for desulfurization. This is not always possible in diesel vehicles with a nitrogen oxide storage catalyst in the underbody area. The invention presents a process whose application allows the desulfurization temperature of conventional nitrogen oxide storage catalysts which comprise a platinum component and at least one nitrogen oxide storage material to be lowered. The basicity of the chemical environment of the platinum is lowered, while the nitrogen oxide storage material can remain unchanged as such.
    Type: Application
    Filed: April 14, 2010
    Publication date: September 16, 2010
    Inventors: Ina GRISSTEDE, Friedemann ROHR, Stephan ECKHOFF, Wilfried MUELLER, Thomas KREUZER
  • Patent number: 7790651
    Abstract: A recyclable esterification or transesterification catalyst and methods for making and using the same are provided herein. The catalyst can be used to prepare biodiesel or methyl soyate from various feedstocks, including vegetable oils and animal fats. The catalyst can both esterify free fatty acids and transesterify mono-, di-, and triglycerides. The catalyst can also be combined with a metal oxide, and optionally calcined, prior to carrying out a catalytic reaction.
    Type: Grant
    Filed: August 18, 2006
    Date of Patent: September 7, 2010
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Victor Shang-Yi Lin, Jennifer A. Nieweg, John G. Verkade, Chinta Reddy Venkat Reddy, Carla Kern
  • Patent number: 7790650
    Abstract: The present invention relates to catalysts comprising at least one support and at least one layer applied to said support, said layer containing a) 20 to 95% by weight of at least one aluminum, silicon, titanium or magnesium oxide compound or a silicon carbide or a carbon support or mixtures thereof, and b) 5 to 50% by weight of at least one nanocarbon. The catalysts can be used to produce unsaturated hydrocarbons by means of the oxidative dehydrogenation of alkylaromatics, alkenes and alkanes in the gas phase.
    Type: Grant
    Filed: July 13, 2005
    Date of Patent: September 7, 2010
    Assignee: NanoC Sdn. Bhd.
    Inventors: Robert Schlogl, Gerhard Mestl
  • Patent number: 7785555
    Abstract: Methods of converting olivine to lizardite without formation of chrysotile or brucite are disclosed. The methods comprise heating a mixture of olivine, silica, water, and a caustic agent. The addition of silica allows for complete conversion of the olivine to lizardite through a more thermodynamically favorable reaction. The olivine and silica are preferably of small particle size to increase reactivity.
    Type: Grant
    Filed: April 9, 2008
    Date of Patent: August 31, 2010
    Assignee: Unimin Corporation
    Inventors: David D. Kragten, Chris Capobianco
  • Publication number: 20100209325
    Abstract: Catalysts for the decomposition of N2O into nitrogen and oxygen in the gas phase, which comprises a porous support composed of polycrystalline or vitreous inorganic material, a cerium oxide functional layer applied thereto and a layer of oxidic cobalt-containing material applied thereto are described. The catalysts can be used, in particular, as secondary or tertiary catalysts in nitric acid plants.
    Type: Application
    Filed: August 11, 2008
    Publication date: August 19, 2010
    Inventors: Meinhard Schwefer, Rolf Siefert, Frank Seifert, Frank Froehlich, Wolfgang Burckhardt
  • Publication number: 20100207069
    Abstract: A catalyst for catalytic partial oxidation of hydrocarbon, having high thermal shock resistance, and a process for producing a synthesis gas using the catalyst are provided. A catalyst for catalytic partial oxidation of hydrocarbon is used in producing a synthesis gas containing carbon monoxide and hydrogen by adding oxygen and steam to a raw material hydrocarbon, thereby subjecting the raw material hydrocarbon to catalytic partial oxidation, and comprises a carrier comprising an inorganic oxide and an active metal supported thereon. In the catalyst, the total of volume of pores having a pore diameter in a first range of from 0.1 ?m to less than 1.0 ?m is 32% or more of the whole pore volume, and the total of volume of pores having a pore diameter in a second range of from 1.0 ?m to 10 ?m or less is 14% or more of the whole pore volume.
    Type: Application
    Filed: June 18, 2009
    Publication date: August 19, 2010
    Inventors: Hirokazu Fujie, Yoshiyuki Watanabe
  • Patent number: 7772147
    Abstract: A solid catalyst carrier substrate coated with a surface area-enhancing washcoat composition including a catalytic component, a metal oxide and a refractory fibrous or whisker-like material having an aspect ratio of length to thickness in excess of 5:1.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: August 10, 2010
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Paul John Collier, Alison Mary Wagland