Of Lanthanide Series (i.e., Atomic Number 57 To 71 Inclusive) Patents (Class 502/302)
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Patent number: 10800665Abstract: Thermochemical storage materials having the general formula AxA?1-xByB?1-yO3-?, where A=La, Sr, K, Ca, Ba, Y and B=Mn, Fe, Co, Ti, Ni, Cu, Zr, Al, Y, Cr, V, Nb, Mo, are disclosed. These materials have improved thermal storage energy density and reaction kinetics compared to previous materials. Concentrating solar power thermochemical systems and methods capable of storing heat energy by using these thermochemical storage materials are also disclosed.Type: GrantFiled: June 1, 2016Date of Patent: October 13, 2020Assignee: National Technology & Engineering Solutions of Sandia, LLCInventors: Sean M. Babiniec, Andrea Ambrosini, Eric N. Coker, James E. Miller
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Patent number: 10759943Abstract: Provided are a black mixed oxide that contains chromium per se of any valency as a main component, and fails to contain cobalt as the main component material, and has a high safety, an excellent color tone and economical efficiency, and a method for producing the same, and various products using the black mixed oxide material. The mixed oxides comprise oxides containing La, Mn and Cu as main components but containing neither Cr nor Co as a main component, wherein the contents of La, Mn and Cu in the mixed oxides satisfy the following ratios, as oxide equivalent amount with respect to 100% by weight of the oxide equivalent amount: the La content as La2O3 being 35-70 wt %; the Mn content as MnO2 being 25-60 wt %; and the Cu content as CuO being 0.5-10 wt %.Type: GrantFiled: June 7, 2018Date of Patent: September 1, 2020Assignees: Nakashima Sangyo Co., Ltd., Okuno Chemical Industries Co., Ltd.Inventors: Mikio Nakashima, Takashi Kato
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Patent number: 10730036Abstract: A process for preparing an oxidative dehydrogenation catalyst or oxidative dehydrogenation catalyst precursor that includes mixing solutions of molybdenum and tellurium at a pH from about 3.3 to 7.5; adjusting the pH of the resulting solution back to about 5 and adding VOSO4 and adding a solution of Nb2O5 and oxalic acid and treating the resulting precursor slurry in a controlled pressure hydrothermal process to obtain the catalyst.Type: GrantFiled: January 30, 2019Date of Patent: August 4, 2020Assignee: NOVA Chemicals (International) S.A.Inventors: Xiaoliang Gao, Vasily Simanzhenkov, Marie Barnes, David Sullivan, Hanna Drag, Yoonhee Kim, Perry de Wit
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Patent number: 10677124Abstract: Provided is a GPF capable of exhibiting better than conventional three-way purification function. A gasoline particulate filter (GPF) that is provided in an exhaust pipe of an engine and that performs purification by capturing particulate matter (PM) in exhaust gas is provided with a filter substrate in which a plurality of cells extending from an exhaust gas inflow-side end face to an outflow-side end face are defined by porous partition walls and in which openings at the inflow-side end face and openings at the outflow-side end face of the cells are alternately sealed; and a three-way catalyst (TWC) supported by the partition wall. The three-way catalyst is the GPF comprising a catalytic metal containing at least Rh, and a composite oxide having an oxygen storage capacity and containing Nd and Pr in a crystal structure.Type: GrantFiled: September 24, 2015Date of Patent: June 9, 2020Assignee: HONDA MOTOR CO., LTD.Inventors: Shinichiro Otsuka, Noritaka Masumitsu, Ryoko Yamada
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Patent number: 10576420Abstract: The object of the present invention is to provide an exhaust gas purifying catalyst that can achieve high purification performance while suppressing H2S emissions. The object is solved by an exhaust gas purifying catalyst in which the lower layer of the catalyst coating layer comprises a ceria-zirconia composite oxide having a pyrochlore-type ordered array structure, in which the ceria-zirconia composite oxide contains at least one additional element selected from the group consisting of praseodymium, lanthanum, and yttrium at 0.5 to 5.0 mol % in relation to the total cation amount, and the molar ratio of (cerium+additional element):(zirconium) is within the range from 43:57 to 48:52.Type: GrantFiled: December 11, 2015Date of Patent: March 3, 2020Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATIONInventors: Isao Chinzei, Hiromasa Suzuki, Takeru Yoshida, Masahide Miura, Yuki Aoki, Mitsuyoshi Okada, Toshitaka Tanabe, Akihiko Suda, Yoshinori Saito, Hirotaka Ori, Kosuke Iizuka, Akira Morikawa
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Patent number: 10569258Abstract: The invention relates to a method for preparing a catalyst or catalyst precursor comprising a catalytically active material and a carrier material. The invention relates to a catalyst particle and catalyst precursor thereof obtainable by said method. The catalyst may be used in a process for synthesising hydrocarbons.Type: GrantFiled: December 21, 2015Date of Patent: February 25, 2020Assignee: SHELL OIL COMPANYInventors: Andreas Klemt, László Domokos, Frank Peter Friedel, Stefan Boettcher, Erwin Roderick Stobbe
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Patent number: 10557672Abstract: The present disclosure relates to a heat transfer tube having rare-earth oxide deposited on a surface thereof and a method for manufacturing the same, in which the rare-earth oxide can be deposited on the surface of the heat transfer tube to implement a superhydrophobic surface even under the high temperature environment and a plurality of assembled heat transfer tubes can be coated by coating a complex shape by depositing rare-earth oxide using a method for dipping a surface of the heat transfer tube and coating the same, thereby reducing or preventing the heat transfer tubes from being damaged during the assembling of the heat transfer tubes after the coating.Type: GrantFiled: September 20, 2017Date of Patent: February 11, 2020Assignee: Doosan Heavy Industries Construction Co., LtdInventors: Hyun Sik Kim, Hyun Gee Kim, Jin Bum Kim, Young Suk Nam, Jae Hwan Shim
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Patent number: 10544363Abstract: [Objective] To provide a ceramic emitter that exhibits high radiation intensity and excellent wavelength selectivity. [Solution] A ceramic emitter includes a polycrystalline body that has a garnet structure represented by a compositional formula R3Al5O12 (R: rare-earth element) or R3Ga5O12 (R: rare-earth element) and has pores with a porosity of 20-40%. The pores have a portion where the pores are connected to one another but not linearly continuous, inside the polycrystalline body.Type: GrantFiled: September 11, 2015Date of Patent: January 28, 2020Assignee: NEC CorporationInventor: Akinobu Shibuya
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Patent number: 10478807Abstract: The invention relates to CeO2 and La2O3 for catalyzing Fe2O3—Al2O3 based chemical-looping reforming of CH4 with CO2 (CL-DRM). The reaction performance of all the composite oxygen carriers was evaluated in a fixed-bed reactor at atmospheric pressure condition. The influencing factors, including temperature and time-on-stream (TOS) were investigated. The characteristics of the oxygen carriers were checked with Brunauer-Emmett-Teller (BET) analysis and X-ray diffraction (XRD). The reducibility of the composite materials was elucidated with temperature-programmed reduction by CH4 (CH4-TPR). Preliminary experimental observations suggest that the simultaneous presence of CeO2 and La2O3 can not only enhance the reactivity of Fe2O3—Al2O3 toward CH4 oxidation and its oxygen releasing rate for fast reaction kinetics, but also improve the reactivity of its reduced form toward CO2 splitting.Type: GrantFiled: May 30, 2017Date of Patent: November 19, 2019Inventors: Maohong Fan, Mingchen Tang
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Patent number: 10483000Abstract: Methods, systems, and devices are disclosed for administering a medicament to a patient. In one aspect, a system includes an injection pen device in wireless communication with a mobile communication device. The injection pen device includes a housing including a chamber to encase a cartridge containing medicine, a dose setting and dispensing mechanism to set the mechanism to dispense a particular dose of the medicine from the loaded cartridge, a sensor unit to detect a dispensed dose based on positions and/or movements of the dose setting and dispensing mechanism, and an electronics unit in communication with the sensor unit to process the detected dispensed dose and time data associated with a dispensing event and to wirelessly transmit the dose data to a user's device. The mobile communication device provides a software application to provide the user with health information using the processed dose data.Type: GrantFiled: April 30, 2018Date of Patent: November 19, 2019Assignee: Companion Medical, Inc.Inventors: Sean Saint, Arnold Holmquist, Cory McCluskey, Jack Pryor, Jasper Benke
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Patent number: 10414972Abstract: A treatment fluid comprising a peroxide source and a perovskite family catalyst is useful in processes for breaking the gelled component of a gelled fluid used in downhole operations. In particular, the treatment fluid can be useful in fracturing operations where it can not only break the gelled component of the fracturing fluid but the gaseous oxygen generated by the peroxide source and perovskite family catalyst can be used to further fracture a subterranean formation.Type: GrantFiled: October 30, 2015Date of Patent: September 17, 2019Assignee: Halliburton Energy Services, Inc.Inventors: Sandeep Vasant Chavan, Vilas Ramtenki, Rajender Salla
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Patent number: 10401023Abstract: The effects of different perovskite catalysts, catalytic active materials with a crystal structure of ABO3, on matrix stabilized combustion in a porous ceramic media are explored. Highly porous silicon carbide ceramics are used as a porous media for a catalytically enhanced matrix stabilized combustion of a lean mixture of methane and air. A stainless steel combustion chamber was designed incorporating a window for direct observation of the flame within the porous media. Perovskite catalytic enhancement of SiC porous matrix with La0.75Sr0.25Fe0.6Cr0.35Ru0.05O3; La0.75Sr0.25Fe0.6Cr0.4O3; La0.75Sr0.25Fe0.95Ru0.05O3; La0.75Sr0.25Cr0.95Ru0.05O3; and LaFe0.95Ru0.05O3, for example, were used to enhance combustion. The flammability limits of the combustion of methane and air were explored using both inert and catalytically enhanced surfaces of the porous ceramic media. By coating the SiC porous media with perovskite catalysts it was possible to lower the minimum stable equivalence ratio.Type: GrantFiled: March 17, 2015Date of Patent: September 3, 2019Assignee: UNIVERSITY OF CENTRAL FLORIDA RESEARCH FOUNDATION, INC.Inventors: Nina Orlovskaya, Ruey-Hung Chen, Manuel Robayo
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Patent number: 10384163Abstract: The object of the present invention is to provide an exhaust gas purifying catalyst that can achieve high purification performance while suppressing H2S emissions. The object is solved by an exhaust gas purifying catalyst in which the lower layer of the catalyst coating layer comprises a ceria-zirconia composite oxide having a pyrochlore-type ordered array structure, in which the ceria-zirconia composite oxide contains at least one additional element selected from the group consisting of praseodymium, lanthanum, and yttrium at 0.5 to 5.0 mol % in relation to the total cation amount, and the molar ratio of (cerium+additional element):(zirconium) is within the range from 43:57 to 48:52.Type: GrantFiled: December 11, 2015Date of Patent: August 20, 2019Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATIONInventors: Isao Chinzei, Hiromasa Suzuki, Takeru Yoshida, Masahide Miura, Yuki Aoki, Mitsuyoshi Okada, Toshitaka Tanabe, Akihiko Suda, Yoshinori Saito, Hirotaka Ori, Kosuke Iizuka, Akira Morikawa
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Patent number: 10350240Abstract: The present invention is a method of producing a lanthanum carbonate hydroxide or lanthanum oxycarbonate which has improved properties. The method involves the use of a water soluble lanthanum and a water soluble non-alkali metal carbonate or bicarbonate. The resulting material can be used as a phosphate binder individually or for treating patients with hyperphosphatemia.Type: GrantFiled: December 12, 2013Date of Patent: July 16, 2019Inventors: Ashok Yeshwant Gore, Milind Dixit, Ravichandran Mahalingam, Edward A. Schauer, Matthew Stewart, Rajendra Tandale, Ramsharan Singh
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Patent number: 10352893Abstract: A gas sensor control apparatus including a gas sensor element, a heater for heating the gas sensor element, and heater energization control means for feedback controlling the supply of electric current to the heater such that the internal resistance of the gas sensor element coincides with a target resistance. The gas sensor element has a solid electrolyte member and an electrode portion including an outside electrode and an inside electrode. At least a portion of the electrode portion is formed of an electrically conductive oxide whose main component is (i) a first perovskite phase which is represented by a composition formula of LaCo1?xNixO3±d (0.300?x?0.600, 0?d?0.4) and has a perovskite-type crystal structure, or (ii) a second perovskite phase which is represented by a composition formula of LaFe1?yNiyO3±d (0.450?y?0.700, 0?d?0.4) and has a perovskite-type crystal structure.Type: GrantFiled: August 29, 2016Date of Patent: July 16, 2019Assignee: NGK SPARK PLUG CO., LTD.Inventors: Keisuke Nakagawa, Shigehiro Ohtsuka, Hisashi Kozuka, Kazuma Ito, Ippei Kato
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Patent number: 10329984Abstract: An oxygen storage/release material includes: a ceria-zirconia composite oxide porous body that has at least one ordered phase of a pyrochlore phase and a ? phase, and that has a central pore diameter of 70 nm to 1 ?m as measured by a mercury penetration method, and in which a cumulative pore volume of pores that each have a pore diameter in the range of 0.5 times to 2 times the central pore diameter is 40% or more of the cumulative pore volume of pores that each have a pore diameter in the range of 10 nm to 10 ?m as measured by the mercury penetration method.Type: GrantFiled: March 5, 2018Date of Patent: June 25, 2019Assignee: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Miho Hatanaka, Akihiko Suda
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Patent number: 10322403Abstract: A catalyst coating for use in a hydrolysis catalyst (H-catalyst) for the reduction of nitrogen oxides, a manufacturing method for such a coating, a catalyst structure and its use are described. The H-catalyst includes alkaline compounds, which are capable of adsorbing HNCO and/or nitrogen oxides and which include alkali and alkaline earth metals, lanthanum and/or yttrium and/or hafnium and/or prasedium and/or gallium, and/or zirconium for promoting reduction, such as for promoting the hydrolysis of urea and the formation of ammonia and/or the selective reduction of nitrogen oxides.Type: GrantFiled: February 14, 2013Date of Patent: June 18, 2019Assignee: DINEX ECOCAT OYInventor: Teuvo Maunula
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Patent number: 10239049Abstract: The presently disclosed and claimed inventive concept(s) generally relates to a solid catalyst component comprising a zeolite with a modifier and at least one Group VIII meal alloyed with at least one transition metal. The presently disclosed and claimed inventive concept(s) further relates to a method of making the solid catalyst component and a process of converting mixed waste plastics into low molecular weight organic compounds using the solid catalyst component.Type: GrantFiled: June 28, 2016Date of Patent: March 26, 2019Assignee: AMG Chemistry and Catalysis Consulting, LLCInventor: Anne Mae Gaffney
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Patent number: 10066170Abstract: The present invention provides a metal passivator/trap comprising a rare earth oxide dispersed on a matrix containing a calcined hydrous kaolin.Type: GrantFiled: May 1, 2017Date of Patent: September 4, 2018Assignee: BASF CORPORATIONInventors: Qi Fu, Walter Babbitt, Mark Schmalfeld, Chandrashekhar Pandurang Kelkar
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Patent number: 10030559Abstract: Provided is: an oxidation catalyst having excellent ability to combust diesel fuel intermittently sprayed from a nozzle disposed in an exhaust pipe, the oxidation catalyst being incorporated into an exhaust gas purification device having a diesel particulate filter (DPF) or a catalyst soot filter (CSF) for collecting particulate matter from a diesel engine; and an exhaust gas purification device that uses the oxidation catalyst. An oxidation catalyst for exhaust gas purification in which a precious metal component is carried on an inorganic matrix, wherein the inorganic matrix is one or more inorganic oxides selected from the group consisting of alumina, titania, zirconia, silica, and silica-alumina, the oxidation catalyst being characterized in the use of a material in which the activation energy of diesel fuel combustion performance is 72 kJ/mol or less.Type: GrantFiled: February 28, 2014Date of Patent: July 24, 2018Assignee: N.E. CHEMCAT CORPORATIONInventors: Tomoaki Ito, Makoto Nagata
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Patent number: 10022714Abstract: The invention relates to a catalyst molded body for preparing maleic anhydride by gas-phase oxidation of a hydrocarbon having at least four carbon atoms using a catalytically active composition containing vanadium, phosphorus and oxygen. The shaped catalyst body has an essentially cylindrical body having a longitudinal axis. The cylindrical body has at least two parallel internal holes which are essentially parallel to the cylinder axis of the body and go right through the body. The catalyst molded body has a large outer surface area, a lower pressure loss and sufficient mechanical stability.Type: GrantFiled: August 11, 2015Date of Patent: July 17, 2018Assignee: BASF SEInventors: Cornelia Katharina Dobner, Stefan Altwasser, Hagen Wilmer, Frank Rosowski
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Patent number: 9983165Abstract: The present teaching rekates to providing a NOx decomposition agent having an excellent NOx decomposition rate. The NOx decomposition agent containing a perovskite oxide represented by ABx-1MxO3, wherein A represents one or more elements selected from the group consisting of La, Sr, Mg, Ca and Ba, B represents Mn, M represents a combination of one or more first metal elements selected from the group consisting of Ti, Zr, Hf, Nb, Ta, Cr, Mo, W and Ce, and one or two second metal elements selected from the group consisting of Ca and Mg, and x represents a number greater than or equal to 0 and less than 1.Type: GrantFiled: March 4, 2014Date of Patent: May 29, 2018Assignees: JAPAN FINE CERAMICS CENTER, TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Taro Ueda, Seiji Takahashi, Toyoharu Kaneko, Tatsuhiro Hashida, Keiichiro Aoki
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Patent number: 9901915Abstract: The composition according to the invention includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminium or manganese, in the form of particles dispersed on an alumina or aluminium oxyhydroxide substrate, characterized in that after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The composition according to the invention can be used in the field of catalysis.Type: GrantFiled: February 4, 2015Date of Patent: February 27, 2018Assignee: Rhodia OperationsInventors: Simon Ifrah, Olivier Larcher, Rui Jorge Coelho Marques, Michael Lallemand, Julien Hernandez
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Patent number: 9878308Abstract: An exhaust gas purification catalyst includes: a first catalyst unit that consists of a hydrogen generating catalyst including a noble metal and an oxide that contains lanthanum, zirconium and an additional element such as neodymium; a second catalyst unit that consists of an oxygen storage/release material and a perovskite oxide disposed in contact with the oxygen storage/release material and represented by the general formula LaxM11-xM2O3-?, where La is lanthanum, M1 is at least one element selected from the group consisting of barium (Ba), strontium (Sr) and calcium (Ca), M2 is at least one element selected from the group consisting of iron (Fe), cobalt (Co) and manganese (Mn), x satisfies 0<x?1, and ? satisfies 0???1; and a holding material that holds the first catalyst unit and the second catalyst unit in a mutually separated state.Type: GrantFiled: January 16, 2015Date of Patent: January 30, 2018Assignee: NISSAN MOTOR CO., LTD.Inventors: Junji Ito, Yasunari Hanaki, Tetsuro Naito, Misaki Akaishi
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Patent number: 9855550Abstract: An exhaust gas-purifying catalyst includes a support and a catalytic metal as one or more precious metals supported by the support. The support includes a composite oxide having a composition represented by a general formula AB?C?O3, wherein A represents one or more elements selected from the group consisting of lanthanum, neodymium, and yttrium, B represents iron or a combination of iron and aluminum, C represents one or more elements selected from the group consisting of iridium, ruthenium, tantalum, niobium, molybdenum, and tungsten, ? and ? each represents a numerical value within a range of more than 0 and less than 1, and ? and ? satisfy relational formulae of ?>? and ?+??1.Type: GrantFiled: January 20, 2017Date of Patent: January 2, 2018Assignee: CATALER CORPORATIONInventors: Satoshi Matsueda, Akimasa Hirai, Kenichi Taki, Sho Hoshino
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Patent number: 9855551Abstract: The present invention provides a catalyst precursor and a catalyst suitable for preparing multi-wall carbon nanotubes. The resulting multi-wall carbon nanotubes have a narrow distribution as to the number of walls forming the tubes and a narrow distribution in the range of diameters for the tubes. Additionally, the present invention provides methods for producing multi-wall carbon nanotubes having narrow distributions in the number of walls and diameters. Further, the present invention provides a composition of spent catalyst carrying multi-wall nanotubes having narrow distribution ranges of walls and diameters.Type: GrantFiled: June 16, 2015Date of Patent: January 2, 2018Assignee: Southwest Nanotechnologies, Inc.Inventors: Ricardo Prada Silvy, Yongqiang Tan
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Patent number: 9808793Abstract: Differing from the startup temperature of partial oxidation of butane (POB) reaction stimulated by conventional rhodium-based or nickel-based catalyst reaches 700° C. or above, the present invention particularly discloses a novel catalyst consisting of fluorite-type oxide support and Ni active metal for being applied in hydrogen production by low temperature partial oxidation of light hydrocarbon (POLH), so as to effectively reduce the startup temperature of the POLH reaction. In the present invention, the said light hydrocarbon means methane, ethane, propane, or butane. Moreover, a variety of experimental data have proved that this novel catalyst makes the startup temperature of POB reactions be lowered to 250° C. On the other hand, the experimental data have also proved that, the carbon deposition formed on the catalyst during POB reaction can be obviously improved after adding a few amount of platinum into the constituting ingredients of the novel catalyst.Type: GrantFiled: December 13, 2016Date of Patent: November 7, 2017Assignee: National Tsing Hua UniversityInventors: Yu-Chen Huang, Hsin-Yi Liu
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Patent number: 9795947Abstract: A preparation method of perovskite catalyst, represented by the following Chemical Formula 1: LaxAg(1-x)MnO3 (0.1?x?0.9), includes the steps of 1) preparing a metal precursor solution including a lanthanum metal precursor, a manganese metal precursor and a silver metal precursor, 2) adding maleic or citric acid to the metal precursor solution, 3) drying the mixture separately several times with sequentially elevating the temperature in the range of 160 to 210° C., and 4) calcining the dried mixture at 600 to 900° C. for 3 hours to 7 hours.Type: GrantFiled: December 4, 2015Date of Patent: October 24, 2017Assignee: HYUNDAI MOTOR COMPANYInventors: Jin Woo Choung, Pyung Soon Kim
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Patent number: 9732648Abstract: An exhaust gas purification catalytic device 1 contains Pt, Pd, and Rh as catalytic metals. The catalytic metal Pt is loaded on silica-alumina which serves as a support, and Pt-loaded silica-alumina obtained by loading the Pt on the silica-alumina is contained in a catalytic layer with which an exhaust gas contacts first.Type: GrantFiled: October 15, 2014Date of Patent: August 15, 2017Assignee: MAZDA MOTOR CORPORATIONInventors: Hiroshi Yamada, Masahiko Shigetsu, Hisaya Kawabata, Yasuhiro Matsumura, Kazuya Yokota, Toshihiko Ohsumi, Takeo Yamauchi, Yusuke Koike
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Patent number: 9498770Abstract: Disclosed is a Ce-based composite oxide catalyst for selective catalytic reducing nitrogen oxides with ammonia, which comprises Ce oxide and at least one oxide of transition metal except Ce. The Ce-based composite oxide catalyst is prepared by a simple method which uses non-toxic and harmless raw materials, and it has the following advantages: high catalytic activity, and excellent selectivity for generating nitrogen etc. The catalyst can be applied in catalytic cleaning plant for nitrogen oxides from mobile and stationary sources.Type: GrantFiled: November 9, 2011Date of Patent: November 22, 2016Assignee: Research Center for Eco-Environmental Sciences, Chinese Academy of SciencesInventors: Hong He, Wenpo Shan, Fudong Liu, Xiaoyan Shi, Changbin Zhang, Shaoxin Wang
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Patent number: 9433924Abstract: Mixed metal oxide catalysts (ZnO, CeO, La2O3, NiO, Al203, Si02, TiO2, Nd2O3, Yb2O3, or any combination of these) supported on zirconia (ZrO2) or hydrous zirconia are provided. These mixed metal oxide catalysts can be prepared via coprecipitation, impregnation, or sol-gel methods from metal salt precursors with/without a Zirconium salt precursor. Metal oxides/ZrO2 catalyzes both esterification and transesterification of oil containing free fatty acids in one batch or in single stage. In particular, these mixed metal oxides supported or added on zirconium oxide exhibit good activity and selectivity for esterification and transesterification. The low acid strength of this catalyst can avoid undesirable side reaction such as alcohol dehydration or cracking of fatty acids. Metal oxides/ZrO2 catalysts are not sensitive to any water generated from esterification. Thus, esterification does not require a water free condition or the presence of excess methanol to occur when using the mixed metal oxide catalyst.Type: GrantFiled: November 8, 2010Date of Patent: September 6, 2016Assignee: WAYNE STATE UNIVERSITYInventors: Manhoe Kim, Steven O. Salley, K. Y. Simon Ng
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Patent number: 9433897Abstract: A process for producing a diffusion barrier or blocking layer includes providing aluminum oxide on a metal sheet formed of a base material including at least iron, chromium and aluminum. A process for producing an exhaust gas treatment unit includes providing a honeycomb body and a housing in which at least one of the honeycomb body or the housing is formed of the metal sheet and the metal sheet is formed of a base material including at least iron, chromium and aluminum. The metal sheet thus includes, at least in a subregion, a surface layer including at least aluminum oxide and a metal from the group including cobalt and nickel. An exhaust gas treatment unit and a motor vehicle are also provided.Type: GrantFiled: May 30, 2014Date of Patent: September 6, 2016Assignee: EMITEC Gesellschaft fuer Emissionstechnologie mbHInventor: Dieter Lutz
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Patent number: 9403681Abstract: The present invention relates to a catalytically active component of a catalyst, which comprises single phase oxides, based on a metal doped yttrium ortho-cobaltate oxide systems, methods for the oxidation of ammonia 5 and hydrocarbon in the presence of said catalytically active component and the use thereof.Type: GrantFiled: January 24, 2014Date of Patent: August 2, 2016Assignee: YARA INTERNATIONAL ASAInventors: David Waller, Marianne Søbye Grønvold, Nibal Sahli
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Patent number: 9399605Abstract: The inventing relates to hydrocarbon conversion, and more particularly to catalytically converting alkane in the presence of oxygen released from an oxygen storage material. Conversion products include C2 hydrocarbon, such as C2+ olefin. The hydrocarbon conversion process can be an oxidative coupling reaction, which refers to the catalytic conversion of methane in the presence of oxidant to produce the olefin product. Flow-through reactors can be used to carry out oxygen storage and the oxidative coupling reaction. Reverse-flow reactors are examples of flow-through reactors, which can be used to carry out oxygen storage and the oxidative coupling reaction.Type: GrantFiled: August 26, 2014Date of Patent: July 26, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: Juan D. Henao, Paul F. Keusenkothen
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Patent number: 9394214Abstract: Disclosed are reactors and reaction processes for contacting hydrocarbon reactant in the presence of oxygen stored and released within a thermal mass region of the reactor, and catalytically converting at least a portion of alkane, e.g., methane, in the hydrocarbon reactant to produce a reaction mixture comprising a C5+ composition. Oxygen storage and release for carrying out the catalytic conversion is achieved by including an oxygen storage material in a thermal mass region of the reactor. Flow-through reactors can be used to carry out oxygen storage and the hydrocarbon conversion reactions. Reverse-flow reactors are examples of flow-through reactors, which can be used to carry out oxygen storage and the hydrocarbon conversion reactions.Type: GrantFiled: August 26, 2014Date of Patent: July 19, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventors: Juan D. Henao, Paul F. Keusenkothen
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Patent number: 9352301Abstract: An exhaust gas purification catalyst contains a first catalyst in which an oxide of general formula (1): LaxM1-xM?O3-? (where La is lanthanum, M is at least one selected from a group consisting of barium (Ba), strontium (Sr) and calcium (Ca), M? is at least one selected from a group consisting of iron (Fe), cobalt (Co), nickel (Ni) and manganese (Mn), ? is the amount of oxygen defect, and x and ? satisfy 0<x?1 and 0???1) is supported by an oxide capable of occluding and releasing oxygen, and a second catalyst containing a noble metal. The particle size of the oxide capable of occluding and releasing oxygen is within the range from 1 to 50 nm. The particle size of the oxide of the general formula (1) is within the range from 1 to 30 nm.Type: GrantFiled: July 18, 2013Date of Patent: May 31, 2016Assignee: NISSAN MOTOR CO., LTD.Inventors: Junji Ito, Yasunari Hanaki, Tetsuro Naito, Misaki Akaishi, Hironori Wakamatsu
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Patent number: 9346038Abstract: A method is described for preparing a catalyst precursor suitable for use in the Fischer-Tropsch synthesis of hydrocarbons including 10 to 40% by weight of cobalt oxide crystallites and 0.05 to 0.5% by weight of a precious metal promoter, dispersed over the surface of a porous transition alumina wherein the surface of the transition alumina has been modified by inclusion of 0.25 to 3.5% wt magnesium, including the steps of: (a) forming a modified catalyst support by impregnating a transition alumina with a magnesium compound, drying and calcining the impregnated alumina in a first calcination at a temperature ?600° C. to convert the magnesium compound into oxidic form, and (b) forming a catalyst precursor by impregnating the modified catalyst support with a cobalt compound and precious metal promoter compound, drying and calcining the impregnated catalyst support in a second calcination to convert the cobalt compound to cobalt oxide.Type: GrantFiled: October 3, 2012Date of Patent: May 24, 2016Assignee: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Gary Bevan Combes, John Bleddyn Claridge, James Robin Gallagher, Matthew J Rosseinsky, Paul Boldrin
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Patent number: 9346036Abstract: An oxide catalyst for use in an oxidation reaction of an olefin and/or an alcohol, the oxide catalyst comprising: the oxide catalyst contains molybdenum, bismuth, iron, cobalt, and cerium; an atomic ratio a of bismuth to 12 atoms of molybdenum is 2?a?6, an atomic ratio b of iron to 12 atoms of molybdenum is 2.5<b?5, an atomic ratio c of cobalt to 12 atoms of molybdenum is 2?c?8, an atomic ratio d of cerium to 12 atoms of molybdenum is 0.5?d?6, and an atomic ratio of iron/cobalt is 0.4?b/c?2.5; wherein when a spacing d of a complex oxide of cerium and molybdenum showing a peak at 33.50° in a X-ray diffraction is taken as a reference, a change rate of d is 5000 to 9000 ppm.Type: GrantFiled: June 13, 2012Date of Patent: May 24, 2016Assignee: ASAHI KASEI CHEMICALS CORPORATIONInventors: Jun Yoshida, Tatsuo Yamaguchi, Kenji Izumiyama
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Catalyst composition for exhaust gas purification and exhaust gas purifying catalyst for automobiles
Patent number: 9339794Abstract: The present invention is to provide a catalyst composition for exhaust gas purification, which is superior in purification performance for nitrogen oxides (NOx), carbon monoxide (CO) and hydrocarbons (HC) in exhaust gas to be discharged from an internal combustion engine of a gasoline vehicle or the like; and an catalyst for exhaust gas purification for automobiles. The present invention is a catalyst composition for exhaust gas purification for purifying nitrogen oxides, carbon monoxide, and hydrocarbons in exhaust gas, which includes a catalyst composition wherein rhodium is supported, together with an ?-alumina particle, on a zirconia-type base material, characterized in that average particle size of the ?-alumina particle is 10 nm to 1 ?m, and also is smaller than average particle size of the zirconia (ZrO2)-type base material.Type: GrantFiled: May 28, 2013Date of Patent: May 17, 2016Assignee: N.E. CHEMCAT CORPORATIONInventor: Ken Nagashima -
Patent number: 9339793Abstract: An exhaust gas purification catalyst composition and a catalyst for exhaust gas purification for automobile, superior in purification performance of a carbon monoxide (CO), a hydrocarbon (HC) and nitrogen oxides (NOx) in exhaust gas discharged from an internal combustion engine of a gasoline vehicle or the like. The exhaust gas purification catalyst composition for purifying a carbon monoxide (CO), a hydrocarbon (HC) and nitrogen oxides (NOx) in automobile exhaust gas, includes a catalyst composition where a rhodium particle (A) is supported on alumina (C) together with a neodymium oxide particle (B), or the like. The neodymium oxide particle (B) having an average particle diameter of 100 nm or smaller, exists at the neighborhood of the rhodium particle (A), as a transfer inhibiting material.Type: GrantFiled: January 8, 2013Date of Patent: May 17, 2016Assignee: N.E. CHEMCAT CORPORATIONInventors: Ryuji Ando, Takashi Yamada, Hiroyuki Hara
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Patent number: 9221034Abstract: A process for manufacturing a catalyst composition comprises the steps of (i) precipitating one or more metal compounds from solution using an alkaline precipitant, preferably comprising an alkaline carbonate, optionally in the presence of a thermostabilizing material, ii) ageing the precipitated composition, and (iii) recovering and drying the aged composition, wherein the ageing step is performed using a pulse-flow reactor.Type: GrantFiled: October 18, 2007Date of Patent: December 29, 2015Assignee: Johnson Matthey PLCInventors: Graeme Douglas Campbell, Gordon James Kelly, Fiona Mary Campbell, Brian Peter Williams
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Patent number: 9186656Abstract: The present invention relates to a catalyst composition for the synthesis of multi-walled carbon nanotube having high apparent density in a manner of high yield. More particularly, this invention relates to a multi-component metal catalyst composition comprising i) main catalyst of Fe and Mo, ii) inactive support of Al and iii) optional co-catalyst at least one selected from Co, Ni, Ti, Mn, W, Sn or Cu. Further, the present invention affords multi-walled carbon nanotube having 5˜15 nm of fibrous diameter and 0.5˜4 ?m bundle diameter.Type: GrantFiled: November 5, 2012Date of Patent: November 17, 2015Assignee: KOREA KUMHO PETROCHEMICAL CO., LTD.Inventors: Sang Kyu Choi, Sang Hyo Ryu, Ho Soo Hwang, Chung Heon Jeong, Dong Hoon Oh, Yeon Ja Lee, Youngchan Jang
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Patent number: 9114384Abstract: The purpose of the present invention is to provide an exhaust gas purification catalyst which can decrease a NOx reduction temperature and comprises rhodium and gold. An exhaust gas purification catalyst which carries two-element microparticles each comprising rhodium and gold, said catalyst being characterized in that the rhodium and the gold are phase-separated from each other and the content ratio of the rhodium to the gold (i.e., rhodium:gold) is (30-99.9 at. %):(70-0.1 at. %) in the two-element microparticles.Type: GrantFiled: August 17, 2012Date of Patent: August 25, 2015Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Shogo Shirakawa, Naoto Nagata, Kimiyasu Ono
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Patent number: 9089833Abstract: In one aspect, a heterogeneous catalyst comprises calcium hydroxide and lanthanum hydroxide, wherein the catalyst has a specific surface area of more than about 10 m2/g. In another aspect, a heterogeneous catalyst comprises a calcium compound and a lanthanum compound, wherein the catalyst has a specific surface area of more than about 10 m2/g, and a total basicity of about 13.6 mmol/g. In further another aspect, a heterogeneous catalyst comprises calcium oxide and lanthanum oxide, wherein the catalyst has a specific surface area of more than about 10 m2/g. In still another aspect, a process for preparing a catalyst comprises introducing a base precipitant, a neutral precipitant, and an acid precipitant to a solution comprising a first metal ion and a second metal ion to form a precipitate. The process further comprises calcining the precipitate to provide the catalyst.Type: GrantFiled: November 5, 2009Date of Patent: July 28, 2015Assignee: WAYNE STATE UNIVERSITYInventors: K.Y. Simon Ng, Shuli Yan, Steven O. Salley
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Publication number: 20150148567Abstract: Disclosed herein are catalyst compositions useful in selective decomposition of organic oxygenates. A feed comprising an organic oxygenate may be contacted with a catalyst comprising (a) at least 0.1 wt % of an oxide of an element selected from Group 3 of the Periodic Table of Elements, wherein Group 3 includes the Lanthanide series; (b) at least 0.1 wt % of an oxide of an element selected from Group 6 of the Periodic Table of Elements; and (c) at least 0.1 wt % of an oxide of at least one element selected from Group 4 of the Periodic Table of Elements, wherein the wt % s are based upon the total combined weight of the oxides in (a) through (c) and excludes any other components.Type: ApplicationFiled: August 29, 2012Publication date: May 28, 2015Applicant: ExxonMobil Chemical Patents Inc.Inventors: Kun Wang, Roberto Garcia, Charles Morris Smith, Doron Levin, James C. Vartuli
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Patent number: 9034269Abstract: The present invention relates to a diesel oxidation catalyst comprising a carrier substrate, and a first washcoat layer disposed on the substrate, the first washcoat layer comprising palladium supported on a support material comprising a metal oxide, gold supported on a support material comprising a metal oxide, and a ceria comprising compound, as well as a process for the preparation of such catalyst.Type: GrantFiled: November 27, 2013Date of Patent: May 19, 2015Assignee: BASF SEInventors: Marcus Hilgendorff, Alfred H. Punke, Torsten W. Müller-Stach, Gerd Grubert, Torsten Neubauer, Jeffrey B. Hoke
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Patent number: 9034286Abstract: An exhaust system for a compression ignition engine comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from the compression ignition engine, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component; and a substrate, wherein the platinum group metal (PGM) component, the alkaline earth metal component and the support material are disposed on the substrate.Type: GrantFiled: November 21, 2013Date of Patent: May 19, 2015Assignee: Johnson Matthey Public Limited CompanyInventors: David Bergeal, Andrew Francis Chiffey, John Benjamin Goodwin, Daniel Hatcher, Francois Moreau, Agnes Raj, Raj Rao Rajaram, Paul Richard Phillips, Cathal Prendergast
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Publication number: 20150111725Abstract: Novel photocatalytic devices are disclosed, that utilize ultrathin titania based photocatalytic materials formed on optical elements with high transmissivity, high reflectivity or scattering characteristics, or on high surface area or high porosity open cell materials. The disclosure includes methods to fabricate such devices, including MOCVD and ALD. The disclosure also includes photocatalytic systems that are either standalone or combined with general illumination (lighting) utility, and which may incorporate passive fluid exchange, user configurable photocatalytic optical elements, photocatalytic illumination achieved either by the general illumination light source, dedicated blue or UV light sources, or combinations thereof, and operating methodologies for combined photocatalytic and lighting systems.Type: ApplicationFiled: October 21, 2014Publication date: April 23, 2015Inventors: Peter C. Van Buskirk, Jeffrey F. Roeder
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Patent number: 9012353Abstract: Disclosed are three-way catalysts that are able to simultaneously convert nitrogen oxides, carbon monoxide, and hydrocarbons in exhaust gas emissions into less toxic compounds. Also disclosed are three-way catalyst formulations comprising palladium (Pd)-containing oxygen storage materials. In some embodiments, the three-way catalyst formulations of the invention do not contain rhodium. Further disclosed are improved methods for making Pd-containing oxygen storage materials. The relates to methods of making and using three-way catalyst formulations of the invention.Type: GrantFiled: August 8, 2012Date of Patent: April 21, 2015Assignee: Clean Diesel Technologies, Inc.Inventors: Stephen J. Golden, Randal Hatfield, Jason D. Pless, Johnny T. Ngo
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Patent number: 9011784Abstract: The invention generally relates to three-way catalysts and catalyst formulations capable of simultaneously converting nitrogen oxides, carbon monoxide, and hydrocarbons into less toxic compounds. Such three-way catalyst formulations contain ZrO2-based mixed-metal oxide support oxides doped with an amount of lanthanide. Three-way catalyst formulations with the support oxides of the present invention demonstrate higher catalytic activity, efficiency and longevity than comparable catalysts formulated with traditional support oxides.Type: GrantFiled: August 8, 2012Date of Patent: April 21, 2015Assignee: Clean Diesel Technologies, Inc.Inventors: Stephen J. Golden, Randal Hatfield, Jason D. Pless