And Group Iii Metal Containing (i.e., Sc, Y, Al, Ga, In Or Tl) Patents (Class 502/323)
  • Patent number: 9034782
    Abstract: The present invention relates to a catalyst composition for conversion of vegetable oils to hydrocarbon products in the diesel boiling range, comprising a porous support; Group III A or VA element in the range of 1-10 wt %; Group VI B elements in the range of 1 to 20 wt %; Group VIII B elements in range of 0.01 to 10 wt %. The present invention further provides the process for preparing the catalyst composition for conversion of vegetable oils to hydrocarbon products in the diesel boiling range. The present invention also provides the process for conversion of vegetable oils to hydrocarbon products in the diesel boiling range using the catalyst composition or discarded refinery spent hydro-treating catalyst.
    Type: Grant
    Filed: October 31, 2012
    Date of Patent: May 19, 2015
    Assignee: Bharat Petroleum Corporation Limited
    Inventors: Chiranjeevi Thota, Pragya Rai, N. Jose, Dattatraya Tammannashastri Gokak, Poyyamani Swaminathan Viswanathan
  • Patent number: 8889078
    Abstract: A porous oxide catalyst includes porous oxide, and an oxygen vacancy-inducing metal which induces an oxygen vacancy in a lattice structure of a porous metal oxide.
    Type: Grant
    Filed: March 15, 2011
    Date of Patent: November 18, 2014
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Sang-min Ji, Hyun-chul Lee, Doo-hwan Lee, Seon-ah Jin
  • Publication number: 20140171299
    Abstract: A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.
    Type: Application
    Filed: December 14, 2012
    Publication date: June 19, 2014
    Inventors: Julie Chabot, Bo Kou, Alexander Kuperman
  • Publication number: 20140171298
    Abstract: A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.
    Type: Application
    Filed: December 14, 2012
    Publication date: June 19, 2014
    Inventors: Julie Chabot, Bo Kou, Alexander Kuperman
  • Patent number: 8728973
    Abstract: The present invention relates to a photocatalytic material having a visible light activity which includes a tungsten-doped titanium oxide or a tungsten/gallium-codoped titanium oxide, and a divalent copper salt and/or a trivalent iron salt supported on a surface of the doped or codoped titanium oxide, and a process for producing the photocatalytic material.
    Type: Grant
    Filed: July 29, 2010
    Date of Patent: May 20, 2014
    Assignees: The University of Tokyo, Showa Denko K.K.
    Inventors: Kazuhito Hashimoto, Hiroshi Irie, Huogen Yu, Yasushi Kuroda, Yasuhiro Hosogi
  • Patent number: 8664146
    Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminum, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurization and hydrodenitrification.
    Type: Grant
    Filed: November 17, 2011
    Date of Patent: March 4, 2014
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
  • Patent number: 8633131
    Abstract: A mesoporous oxide-catalyst complex including: a mesoporous metal oxide; and a catalyst metal supported on the mesoporous metal oxide, wherein the catalyst on the mesoporous metal oxide has a degree of dispersion of about 30 to about 90 percent.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: January 21, 2014
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Doo-hwan Lee, Hyun-chul Lee, Sang-min Ji, Kyo-sung Park, Seung-jae Lee, Seon-ah Jin
  • Patent number: 8609575
    Abstract: A catalyst of one or more complex oxides having a nominal composition as set out in formula (1): AxB1-y-zMyPzOn (1) wherein A is selected from one or more group III elements including the lanthanide elements or one or more divalent or monovalent cations; B is selected from one or more elements with atomic number 22 to 24, 40 to 42 and 72 to 75; M is selected from one or more elements with atomic number 25 to 30; P is selected from one or more elements with atomic number 44 to 50 and 76 to 83; x is defined as a number where 0<x?1; y is defined as a number where 0?y<0.5; and z is defined as a number where 0<z<0.2.
    Type: Grant
    Filed: April 12, 2007
    Date of Patent: December 17, 2013
    Assignee: Very Small Particle Company Limited
    Inventors: Peter Cade Talbot, Jose Antonio Alarco, Geoffrey Alan Edwards
  • Patent number: 8586786
    Abstract: A catalyst for use in the production of an unsaturated aldehyde and/or an unsaturated carboxylic acid, the catalyst comparing (or, preferably, being composed of) a mixed oxide containing molybdenum, bismuth and iron, which has improved methanical strength, is produced by a method including the steps of (1) drying an aqueous solution or an aqueous slurry containing raw materials of the catalyst and then firstly calcining a dried product in a molecular oxygen-containing gas atmosphere to obtain a calcined product; (2) heating the calcined product obtained in Step (1) in the presence of a reducing material to obtain a reduced product having a mass loss of 0.05 to 6%; and (3) secondly calcining the reduced product obtained in Step (2) in a molecular oxygen-containing gas atmosphere.
    Type: Grant
    Filed: July 23, 2012
    Date of Patent: November 19, 2013
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Naoki Miura, Eiichi Shiraishi, Koichi Nagai
  • Patent number: 8563460
    Abstract: A catalyst unit is described comprising a cylinder with a length C and a diameter D, wherein said unit has five holes arranged in a pentagonal pattern extending longitudinally therethrough, with five flutes running along the length of the unit, said flutes positioned equidistant adjacent holes of said pentagonal pattern. The catalyst may be used particularly in steam reforming reactors.
    Type: Grant
    Filed: August 24, 2009
    Date of Patent: October 22, 2013
    Assignee: Johnson Matthey PLC
    Inventors: David James Birdsall, Mileta Babovic, Mikael Per Uno Carlsson, Samuel Arthur French, Michiel Nijemeisland, William Maurice Sengelow, Edmund Hugh Stitt
  • Patent number: 8557728
    Abstract: A catalyst unit is described in the form of a cylinder having a length C and diameter D, which has one or more holes extending therethrough, wherein said cylinder has domed ends of lengths A and B, such that (A+B+C)/D is in the range 0.50 to 2.00, and (A+B)/C is in the range 0.40 to 5.00. The catalyst or catalyst unit preferably has one or more flutes miming along its length. The catalyst may be used particularly in steam reforming reactors.
    Type: Grant
    Filed: August 24, 2009
    Date of Patent: October 15, 2013
    Assignee: Johnson Matthey PLC
    Inventors: David James Birdsall, Mileta Babovic, Mikael Per Uno Carlsson, Samuel Arthur French, Michiel Nijemeisland, William Maurice Sengelow, Edmund Hugh Stitt
  • Patent number: 8557729
    Abstract: A catalyst unit is described in the form of a cylinder having a length C and diameter D, which has two or more flutes running along its length, wherein said cylinder has domed ends of lengths A and B, such that (A+B+C)/D is in the range 0.50 to 2.00, and (A+B)/C is in the range 0.40 to 5.00. The catalyst may be used particularly in reactions where hydrogen is a reactant such as hydroprocessing, hydrogenation, water-gas shift reactions, methanation, hydrocarbon synthesis by the Fischer-Tropsch reaction, methanol synthesis and ammonia synthesis.
    Type: Grant
    Filed: August 24, 2009
    Date of Patent: October 15, 2013
    Assignee: Johnson Matthey PLC
    Inventors: Daniel Lee Cairns, Mileta Babovic, Terence James Fitzpatrick, Elizabeth Margaret Holt, Colin William Park, William Maurice Sengelow, Edmund Hugh Stitt
  • Publication number: 20130261322
    Abstract: The present invention relates to an improved process for preparing mono and poly epoxy functionalized fatty acids, their esters and mixtures thereof using solid catalyst i.e. supported group VIb metal oxide, said support comprising silica, alumina and mixtures thereof, optionally with a promoter from group VA wherein the group VIB metal oxide content in the catalyst is 5-20 wt % of support.
    Type: Application
    Filed: September 22, 2011
    Publication date: October 3, 2013
    Applicant: Council of Scientific and Industrial Research
    Inventors: Srinivas Darbha, Jitendra Kumar Satyarthi
  • Patent number: 8546634
    Abstract: There is provided a method for production of a conjugated diene from a monoolefin having four or more carbon atoms by a fluidized bed reaction. The method for production of a conjugated diolefin includes bringing a catalyst in which an oxide is supported on a carrier into contact with a monoolefin having four or more carbon atoms in a fluidized bed reactor in which the catalyst and oxygen are present, wherein the method satisfies the following (1) to (3): (1) the catalyst contains Mo, Bi, and Fe; (2) a reaction temperature is in the range of 300 to 420° C.; and (3) an oxygen concentration in a reactor outlet gas is in the range of 0.05 to 3.0% by volume.
    Type: Grant
    Filed: September 29, 2010
    Date of Patent: October 1, 2013
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Hideo Midorikawa, Hiroyuki Yano, Takashi Kinoshita
  • Patent number: 8507403
    Abstract: A process is described for producing a powder batch comprises a plurality of particles, wherein the particles include (a) a first catalytically active component comprising at least one transition metal or a compound thereof; (b) a second component different from said first component and capable of removing oxygen from, or releasing oxygen to, an exhaust gas stream; and (c) a third component different from said first and second components and comprising a refractory support. The process comprises providing a precursor medium comprising a liquid vehicle and a precursor to al least one of said components (a) to (c) and heating droplets of said precursor medium carried in a gas stream to remove at least part of the liquid vehicle and chemically convert said precursor to said at least one component.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: August 13, 2013
    Assignee: Cabot Corporation
    Inventors: Miodrag Oljaca, Toivo T. Kodas, Ranko P. Bontchev, Klaus Kunze, Kenneth C. Koehlert
  • Patent number: 8475921
    Abstract: A composite material includes an aggregate which contains a first metal particle constituting a core and second metal oxide particulates surrounding the first metal particle and having an average primary particle diameter ranging from 1 to 100 nm.
    Type: Grant
    Filed: July 20, 2006
    Date of Patent: July 2, 2013
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Tomoyuki Kayama, Kouzi Banno, Kiyoshi Yamazaki, Koji Yokota
  • Publication number: 20130072379
    Abstract: A method of preparing a catalyst coating solution may realize high purification performance by preventing the active surface of a catalyst from being reduced, and may greatly improve the durability of a catalyst by preventing soot from directly coming into contact with a catalyst layer containing a precious metal so that the catalyst layer can continuously exhibit proper purification performance. A method of manufacturing a catalyst body using the catalyst coating solution, and a catalyst body manufactured by the method are also described.
    Type: Application
    Filed: December 11, 2011
    Publication date: March 21, 2013
    Applicant: Hyundai Motor Company
    Inventor: Young Kee YOUN
  • Patent number: 8372777
    Abstract: Method of contacting a hydrocarbon feed with a catalyst that includes one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Column 6 of the Periodic Table and a support. The support comprises from 0.01 grams to 0.2 gram of silica and from 0.80 grams to 0.99 grams of alumina per gram of support. The catalyst has a surface area of at least 340 m2/g, a pore size distribution with a median pore diameter of at most 100 ?, and at least 80% of its pore volume in pores having a pore diameter of at most 300 ? or the catalyst exhibits one or more peaks between 35 degrees and 70 degrees, and at least one of the peaks has a base width of at least 10 degrees, as determined by x-ray diffraction at 2-theta.
    Type: Grant
    Filed: March 22, 2012
    Date of Patent: February 12, 2013
    Assignee: Shell Oil Company
    Inventors: Opinder Kishan Bhan, Scott Lee Wellington
  • Patent number: 8357625
    Abstract: An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.
    Type: Grant
    Filed: June 18, 2009
    Date of Patent: January 22, 2013
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Atsushi Okamoto
  • Publication number: 20120325226
    Abstract: A low sidestream smoke cigarette comprises a conventional tobacco rod, and a combustible treatment paper having a sidestream smoke treatment composition. The treatment composition comprises in combination, an oxygen storage and donor metal oxide oxidation catalyst and an essentially non-combustible finely divided porous particulate adjunct for said catalyst.
    Type: Application
    Filed: August 24, 2012
    Publication date: December 27, 2012
    Applicant: ROTHMANS, BENSON & HEDGES, INC.
    Inventors: Stanislav M. Snaidr, E. Robert Becker
  • Publication number: 20120316056
    Abstract: In one embodiment, an aqueous dispersion liquid contains at least one particles selected from tungsten oxide particles and tungsten oxide composite particles. A mean primary particle diameter (D50) of the particles is in the range of 1 nm to 400 nm. In the aqueous dispersion liquid, concentration of the particles is in the range of 0.1 mass % to 40 mass %, and pH is in the range of 1.5 to 6.5. The aqueous dispersion liquid excels in dispersibility of particles and capable of maintaining good liquidity for a long period.
    Type: Application
    Filed: August 23, 2012
    Publication date: December 13, 2012
    Inventors: Kayo NAKANO, Akira SATO, Yasuhiro SHIRAKAWA, Keiichi FUSE, Shinya KASAMATSU, Akito SASAKI
  • Patent number: 8318000
    Abstract: A method of producing a crude product from a hydrocarbon feed is provided. A hydrocarbon feed is contacted with a catalyst containing a Col. 6-10 metal or compound thereof to produce the crude product, where the catalyst has a pore size distribution with a median pore diameter ranging from 105 ? to 150 ?, with 60% of the total number of pores in the pore size distribution having a pore diameter within 60 ? of the median pore diameter, with at least 50% of its pore volume in pores having a pore diameter of at most 600 ?, and between 5% and 25% of its pore volume in pores having a pore diameter between 1000 ? and 5000 ?.
    Type: Grant
    Filed: January 11, 2012
    Date of Patent: November 27, 2012
    Assignee: Shell Oil Company
    Inventors: Opinder Kishan Bhan, Scott Lee Wellington
  • Publication number: 20120292231
    Abstract: A method of making a high activity catalyst composition suitable for use in the hydrodesulfurization of a middle distillate feed, such as diesel fuel, having a high concentration of sulfur, to thereby provide a low sulfur middle distillate product. The method comprises heat treating aluminum hydroxide under controlled temperature conditions thereby converting the aluminum hydroxide to gamma-alumina to give a converted aluminum hydroxide, and controlling the fraction of converted aluminum hydroxide that is gamma-alumina. A catalytic component is incorporated into the converted aluminum hydroxide to provide an intermediate, which is heat treated to provide the high activity catalyst composition. The high activity catalyst composition can suitably be used in the hydrodesulfurization of a middle distillate feed containing a high sulfur concentration.
    Type: Application
    Filed: July 25, 2012
    Publication date: November 22, 2012
    Applicant: SHELL OIL COMPANY
    Inventor: Opinder Kishan BHAN
  • Patent number: 8309487
    Abstract: An exhaust gas purifying catalyst (1) is composed of: a noble metal (2); a first compound (3); and a second compound (4). The noble metal (2) is supported on the first compound (3). The exhaust gas purifying catalyst (1) includes units having a structure in which the first compound (3) supporting the noble metal (2) is surrounded by the second compound (4), and the first compound (3) supporting the noble metal (2) is isolated from one another by the second compound (4). The noble metal (2) is one or more selected from [Pt, Pd and Rh], the first compound (3) contains Ti as a main component, and the second compound (4) contains, as a main component, one or more selected from [Al and Si].
    Type: Grant
    Filed: June 4, 2009
    Date of Patent: November 13, 2012
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Kazuyuki Shiratori, Masanori Nakamura, Hironori Wakamatsu, Katsuo Suga
  • Publication number: 20120245023
    Abstract: A catalyst for hydrotreating and/or hydroconverting heavy metal-containing hydrocarbon feeds, comprises a support in the form of mainly irregular and non-spherical alumina-based agglomerates the specific shape. The catalyst is prepared by a specific order of steps: crushing, calcining, acidic autoclaving, drying, further calcining and impregnation with catalytic metals.
    Type: Application
    Filed: May 3, 2012
    Publication date: September 27, 2012
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Stephane KRESSMANN, Magalie ROY-AUBERGER, Jean Luc LELOARER, Denis GUILLAUME, Jean Francois CHAPAT
  • Patent number: 8252714
    Abstract: A catalyst for use in the production of an unsaturated aldehyde and/or an unsaturated carboxylic acid, the catalyst comparing (or, preferably, being composed of) a mixed oxide containing molybdenum, bismuth and iron, which has improved mechanical strength, is produced by a method including the steps of (1) drying an aqueous solution or an aqueous slurry containing raw materials of the catalyst and then firstly calcining a dried product in a molecular oxygen-containing gas atmosphere to obtain a calcined product; (2) heating the calcined product obtained in Step (1) in the presence of a reducing material to obtain a reduced product having a mass loss of 0.05 to 6%; and (3) secondly calcining the reduced product obtained in Step (2) in a molecular oxygen-containing gas atmosphere.
    Type: Grant
    Filed: May 15, 2009
    Date of Patent: August 28, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Naoki Miura, Eiichi Shiraishi, Koichi Nagai
  • Patent number: 8207084
    Abstract: According to at least one aspect of the present invention, a urea-resistant catalytic unit is provided. In at least one embodiment, the catalytic unit includes a catalyst having a catalyst surface, and a urea-resistant coating in contact with at least a portion of the catalyst surface, wherein the urea-resistant coating effectively reduces urea-induced deactivation of the catalyst. In at least another embodiment, the urea-resistant coating includes at least one oxide from the group consisting of titanium oxide, tungsten oxide, zirconium oxide, molybdenum oxide, aluminum oxide, silicon dioxide, sulfur oxide, niobium oxide, molybdenum oxide, yttrium oxide, nickel oxide, cobalt oxide, and combinations thereof.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: June 26, 2012
    Assignee: Ford Global Technologies, LLC
    Inventors: Yisun Cheng, Yinyan Huang, Christine Kay Lambert
  • Patent number: 8178003
    Abstract: A hydrocarbon-reforming catalyst comprising a composite oxide having a composition represented by the following formula (I) in which Co, Ni and M are dispersed in the composite oxide and a process for producing a synthesis gas by using the catalyst are provided. aM.bCo.cNi.dMg.eCa.fO??(I) wherein a, b, c, d, e, and f are molar fractions, a+b+c+d+e=1, 0.0001<a?0.20, 0<b?0.20, 0?c?0.20, 0.001<(b+c)?0.20, 0.60?(d+e)?0.9989, 0<d<0.9989, 0<e<0.9989, f=the number necessary for element to keep charge equilibrium with oxygen. And M is at least one element among Group 3B elements and Group 6A elements in the Periodic Table. The reforming catalyst is able to maintain a high catalytic activity over a long period in reforming hydrocarbons.
    Type: Grant
    Filed: October 8, 2008
    Date of Patent: May 15, 2012
    Assignee: Japan Petroleum Exploration Co., Ltd.
    Inventors: Katutoshi Nagaoka, Yuusaku Takita, Toshiya Wakatsuki
  • Patent number: 8178468
    Abstract: A catalyst that includes one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Column 6 of the Periodic Table and a support. The support comprises from 0.01 grams to 0.2 gram of silica and from 0.80 grams to 0.99 grams of alumina per gram of support. The catalyst has a surface area of at least 315 m2/g, a pore size distribution with a median pore diameter of at most 100 ?, and at least 80% of its pore volume in pores having a pore diameter of at most 300 ?. The catalyst exhibits one or more peaks between 35 degrees and 70 degrees, and at least one of the peaks has a base width of at least 10 degrees, as determined by x-ray diffraction at 2-theta. Methods of preparation of such catalyst are described herein. Methods of contacting a hydrocarbon feed with hydrogen in the presence of such catalyst to produce a crude product. Uses of crude products obtained. The crude product composition is also described herein.
    Type: Grant
    Filed: April 10, 2009
    Date of Patent: May 15, 2012
    Assignee: Shell Oil Company
    Inventors: Opinder Kishan Bhan, Scott Lee Wellington
  • Patent number: 8143187
    Abstract: A process for preparing supported catalyst in pellet or coated monolith form is disclosed the method includes the steps of: forming a mixed metal carbonate complex having at least two metals by subjecting a first metal carbonate containing compound to ion exchange with desired metal cations; heat treating the resulting mixed metal carbonate complex to form a mixed oxide which consists of active metal oxides supported on a catalyst support; forming the resulting supported catalysts into pellets or coating the resulting supported catalyst onto a monolithic support. The catalysts may be used for treating effluents containing organic material in the presence of an oxidising agent.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: March 27, 2012
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Manh Hoang, Kingsley Opoku-Gyamfi
  • Publication number: 20120041246
    Abstract: Nanowires useful as heterogeneous catalysts are provided. The nanowire catalysts are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane to ethylene. Related methods for use and manufacture of the same are also disclosed.
    Type: Application
    Filed: May 24, 2011
    Publication date: February 16, 2012
    Applicant: Siluria Technologies, Inc.
    Inventors: Erik C. Scher, Fabio R. Zurcher, Joel M. Cizeron, Wayne P. Schammel, Alex Tkachenko, Joel Gamoras, Dmitry Karshtedt, Greg Nyce
  • Patent number: 8114806
    Abstract: A catalyst and a method of preparation of said catalyst is described herein. The catalyst includes one or more metals from Columns 6-10 of the Periodic Table and/or one or more compounds of one or more metals from Columns 6-10 of the Periodic Table, a pore size distribution with a median pore diameter ranging from 105 ? to 150 ?, with 60% of the total number of pores in the pore size distribution having a pore diameter within 60 ? of the median pore diameter, with at least 50% of its pore volume in pores having a pore diameter of at most 600 ?, and between 5% and 25% of its pore volume in pores having a pore diameter between 1000 ? and 5000 ?. Methods of producing said catalyst are described herein. Crude products and products made from said crude products are described herein.
    Type: Grant
    Filed: April 10, 2009
    Date of Patent: February 14, 2012
    Assignee: Shell Oil Company
    Inventors: Opinder Kishan Bhan, Scott Lee Wellington
  • Publication number: 20120015802
    Abstract: Disclosed is a catalyst which can be used in the process for producing hydrogen by decomposing ammonia, can generate heat efficiently in the interior of a reactor without requiring excessive heating the reactor externally, and can decompose ammonia efficiently and steadily by utilizing the heat to produce hydrogen. Also disclosed is a technique for producing hydrogen by decomposing ammonia efficiently utilizing the catalyst. Specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising an ammonia-combusting catalytic component and an ammonia-decomposing catalytic component. Also specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising at least one metal element selected from the group consisting of cobalt, iron, nickel and molybdenum.
    Type: Application
    Filed: March 17, 2010
    Publication date: January 19, 2012
    Inventors: Junji Okamura, Masanori Yoshimune, Masaru Kirishiki, Hideaki Tsuneki, Shinya Kitaguchi
  • Patent number: 8088707
    Abstract: A supported catalyst with a solid sphere structure of the present invention includes an oxide supporting body and a metal such as Ni, Co, Fe, or a combination thereof distributed on the surface and inside of the supporting body. The supported catalyst with a solid sphere structure can maintain a spherical shape during heat treatment and can be used with a floating bed reactor due to the solid sphere structure thereof.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: January 3, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Byeong Yeol Kim, Yun Tack Lee, Seung Yong Bae, Young Sil Lee
  • Patent number: 8088706
    Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminum, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurization and hydrodenitrification.
    Type: Grant
    Filed: April 29, 2009
    Date of Patent: January 3, 2012
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
  • Patent number: 8062990
    Abstract: A pliable refractory metal carrier (46) may have coated thereon an anchor layer (47) to improve adherence to the carrier (46) of a catalytic coating (48). The conformable catalyst member (26, 82, 82?, 126, 226, 326) may be bent to conform to a curved or bent exhaust pipe (20, 220, 320) within which it is mounted. The pliable metal carrier may be in the form of a tube such as carrier (46) having perforations (54) formed therein, or it may be a metal strip (76) which is folded into accordion pleats (80) and has perforations (78) formed therein. The perforations (54, 78) serve to permit the passage of exhaust gas therethrough. A series of interior closures (58) and annular baffles (60) may be provided to import a serpentine flow path to gases flowed through an exhaust pipe (22) containing a conformable catalyst member (226) therein. A mounting member (68) may be supplied to fasten one end of the conformable catalyst member (226) to the discharge end of an exhaust pipe (220).
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: November 22, 2011
    Assignee: BASF Corporation
    Inventors: Michael P. Galligan, Joseph C. Dettling, Shau-Lin F. Chen, Matthew P. Larkin
  • Patent number: 8053386
    Abstract: The present invention relates to a heteropoly acid catalyst which is used for the production of methacrylic acid by gas phase oxidation of methacrolein and a preparing method thereof. The present invention, thereby, provides a novel heteropoly acid catalyst having excellent methacrolein conversion rate, methacrylic acid selectivity and yield.
    Type: Grant
    Filed: November 29, 2007
    Date of Patent: November 8, 2011
    Assignee: LG Chem, Ltd.
    Inventors: Gyo-hyun Hwang, Min-ho Kil, Hyun-kuk Noh, Won-ho Lee, Min-suk Kim
  • Patent number: 8048821
    Abstract: The present invention relates to a catalyst composition for the synthesis of thin multi-walled carbon nanotube (MWCNT) and a method for manufacturing a catalyst composition. More particularly, this invention relates to a multi-component metal catalyst composition comprising i) main catalyst of Fe and Al, ii) inactive support of Mg and iii) optional co-catalyst at least one selected from Co, Ni, Cr, Mn, Mo, W, V, Sn, or Cu. Further, the present invention affords thin multi-walled carbon nanotube having 5˜20 nm of diameter and 100˜10,000 of aspect ratio in a high yield.
    Type: Grant
    Filed: May 27, 2009
    Date of Patent: November 1, 2011
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Sang-Hyo Ryu, Dong Hwan Kim, Wan Sung Lee, Namsun Choi, Hyun-Kyung Sung, Youngchan Jang
  • Publication number: 20110237758
    Abstract: The present invention provides a urethane-forming reaction catalyst which is useful for catalyzing a reaction between an isocyanate compound, in particular, an aliphatic isocyanate and a hydroxyl group-containing compound to form a urethane material, which does not affect the performance of the urethane material, and which can be easily removed from the resulting urethane material, and a method for producing a metal compound-free urethane material using the urethane-forming reaction catalyst. The catalyst of the present invention is a urethane-forming reaction catalyst for producing a urethane material by allowing a hydroxyl group-containing compound to react with an isocyanate compound, the catalyst being at least one solid acid catalyst selected from the group consisting of a (A) composite metal oxide in which a metal oxide (A-2) or a non-metal compound (A-3) is carried on a surface of a metal oxide carrier (A-1), (B) zeolite, and a (C) heteropoly acid.
    Type: Application
    Filed: September 16, 2009
    Publication date: September 29, 2011
    Applicant: DIC Corporation
    Inventors: Hironobu Oki, Yasuyuki Watanabe, Youichi Abe
  • Patent number: 7985830
    Abstract: Methods for synthesizing dimeric or polymeric reaction products of nitrogen aromatics comprise contacting a composition comprising the nitrogen aromatic with a catalyst composition. The catalyst comprises a first metal substrate having a second reduced metal coated on the substrate.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: July 26, 2011
    Assignee: GM Global Technology Operations LLC
    Inventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui, Charlene A. Hayden
  • Publication number: 20110098519
    Abstract: A catalyst composition for dehydration of an alcohol to prepare an alkene is provided. The catalyst composition comprises a catalyst and a modifying agent which is phosphoric acid, sulfuric acid or tungsten trioxide, or a derivative thereof. A process for preparing an alkene by dehydration of an alcohol is also provided. The process comprises mixing one or more alcohols and optionally water and the catalyst composition.
    Type: Application
    Filed: August 12, 2008
    Publication date: April 28, 2011
    Inventors: Kanaparthi Ramesh, Armando Borgna
  • Patent number: 7915196
    Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.
    Type: Grant
    Filed: October 7, 2005
    Date of Patent: March 29, 2011
    Assignee: Alliance for Sustainable Energy, LLC
    Inventors: Yves O. Parent, Kim Magrini, Steven M. Landin, Marcus A. Ritland
  • Patent number: 7910518
    Abstract: A geometrically shaped solid carrier is provided that improves the performance and effectiveness of an olefin epoxidation catalyst for epoxidizing an olefin to an olefin oxide. In particular, improved performance and effectiveness of an olefin epoxidation catalyst is achieved by utilizing a geometrically shaped refractory solid carrier in which at least one wall thickness of said carrier is less than 2.5 mm.
    Type: Grant
    Filed: March 10, 2008
    Date of Patent: March 22, 2011
    Assignee: SD Lizenzverwertungsgesellschaft mbH & Co. KG
    Inventors: Serguei Pak, Andrzej Rokicki, Howard Sachs
  • Publication number: 20100304963
    Abstract: An improved catalyst for hydrodemetallization of heavy crude oils and residua is disclosed. The catalyst is adopted for fixed bed hydroprocessing units. The invention is characterized for having a large pore diameter catalyst principally for hydrodemetallization of heavy oil and residue in a first reactor of a multi-reactor process. The catalyst has high demetallizing activity and high metal deposition capacity which results in good stability with time on stream (TOS). The hydrorefining catalyst is obtained by kneading a porous starting powder principally composed of gamma-alumina and having a pore capacity of 0.3-0.6 ml/g or larger and a mean pore diameter of 10 to 26 nm, extrudating and calcining, and after that supported with active metals component of elements belonging to groups VIIIB and VIB of the periodic table.
    Type: Application
    Filed: May 26, 2008
    Publication date: December 2, 2010
    Inventors: Mohan Singh, Jorge Ancheyta Juarez, Patricia Rayo Mayoral, Samir Kumar Maity
  • Publication number: 20100292075
    Abstract: In one embodiment, a visible light responsive photocatalyst powder has organic gas decomposition performance that responds nonlinearly to an amount of irradiated light under visible light in an illuminance range of not less than 200 lx nor more than 2500 lx. The visible light responsive photocatalyst powder has a gas decomposition rate of 20% or more, for example, when visible light having only a wavelength of not less than 380 nm and an illuminance of 2500 lx is irradiated, the gas decomposition rate (%) being set as a value calculated based on [formula: (A?B)/A×100], where A represents a gas concentration before light irradiation and B represents a gas concentration when not less than 15 minutes have elapsed from the light irradiation and, at the same time, the gas concentration is stable, the gas concentrations being measured while allowing an acetaldehyde gas having an initial concentration of 10 ppm to flow into a flow-type apparatus in which 0.2 g of a sample is placed.
    Type: Application
    Filed: July 27, 2010
    Publication date: November 18, 2010
    Inventors: Kayo NAKANO, Akira Sato, Yasuhiro Shirakawa, Keiichi Fuse, Masami Okamura, Shinya Kasamatsu, Yumi Ito
  • Patent number: 7833929
    Abstract: The present invention refers to a continuous process for the manufacture of methyl mercaptan using Mo—O—K-based catalysts. It is further described that the total selectivity of methylmercaptan can be increased by at least 1% by lowering the total gas hourly space velocity. The invention further refers to a process for the preparation of a solid, preformed catalyst system.
    Type: Grant
    Filed: July 24, 2009
    Date of Patent: November 16, 2010
    Assignee: Evonik Degussa GmbH
    Inventors: Yiquan Yang, Qi Wang, Renchun Lin, Hongbin Zhang, Youzhu Yuan, Weiping Fang, Quanxing Zheng, Shenjun Dai, Xingguo Yan, Aiping Chen, Jan-Olaf Barth, Christoph Weckbecker, Klaus Huthmacher, Hubert Redlingshöfer, Sabine Ackermann
  • Patent number: 7824656
    Abstract: The present invention relates to catalysts for the production of hydrogen using the water gas shift reaction and the carbon dioxide reforming of hydrocarbon-containing fuels. The catalysts nickel and/or copper on a ceria/zirconia support, where the support is prepared using a surfactant templating method. The invention also includes processes for producing hydrogen, reactors and hydrogen production systems utilizing these catalysts.
    Type: Grant
    Filed: March 14, 2006
    Date of Patent: November 2, 2010
    Assignee: University of Regina
    Inventors: Raphael Oyom Idem, Prashant Kumar, Yanping Sun
  • Publication number: 20100273646
    Abstract: A purifying catalyst includes catalyst powder composed of a transition metal oxide of which an average particle diameter is within 1 nm to 2 ?m and in which an electron binding energy of oxygen is shifted to an energy side lower than 531.3 eV. The purifying catalyst shows good purification performance even when noble metal is not contained as an essential component.
    Type: Application
    Filed: November 20, 2008
    Publication date: October 28, 2010
    Inventors: Hirofumi Yasuda, Yasunari Hanaki, Toru Sekiba, Shigeru Chida, Junji Ito
  • Patent number: 7816299
    Abstract: A stacked bed catalyst system comprising at least one first catalyst selected from conventional hydrotreating catalyst having an average pore diameter of greater than about 10 nm and at least one second catalyst comprising a bulk metal hydrotreating catalyst comprised of at least one Group VIII non-noble metal and at least one Group VIB metal and optionally a binder material.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: October 19, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gary P. Schleicher, Kenneth L. Riley
  • Patent number: 7815792
    Abstract: A process and catalyst for the selective hydrodesulfurization of a naphtha containing olefins. The process produces a naphtha stream having a reduced concentration of sulfur while maintaining the maximum concentration of olefins.
    Type: Grant
    Filed: October 26, 2009
    Date of Patent: October 19, 2010
    Assignee: UOP LLC
    Inventors: Lorenz J. Bauer, Suheil F. Abdo, Laura E. Leonard, Peter Kokayeff