Abstract: A flow-through substrate having a treated activated carbon surface, useful, for example, in the removal of a toxic metal from a fluid.

Abstract: The present invention relates to a modified inorganic material with excellent cation exchange capacity. In addition, the invention relates to a method of preparing the modified inorganic material, a composite electrolyte membrane comprising the modified inorganic material powder that has excellent methanol-repelling ability, and a fuel cell comprising the composite electrolyte membrane. The modified inorganic material includes an inorganic material, and a cation exchanger bonded to the inorganic material.

Abstract: A method for manufacturing a packing material includes a first step of reacting an inorganic particle having a hydroxyl group with a silane coupling agent including a silane coupling agent having an alkenyl group with a carbon number of 2 or more and 8 or less and/or an alkynyl group with a carbon number of 2 or more and 7 or less and a second step of reacting the inorganic particle having reacted with the silane coupling agent, with a compound represented by a general formula of: (in the formula, R1 is an alkyl group with a carbon number of 4 or more and 50 or less or an aryl group with a carbon number of 6 or more and 30 or less and each of R2 and R3 is independently a hydrogen atom, a chloro group, or an alkyl group with a carbon number of 1 or more and 4 or less.).

Abstract: Methods of making thin, defect-free, mesoporous silica coatings on polymeric hollow fibers are provided, along with membranes, devices and applications employing same.

Abstract: The present invention relates to a method for producing a porous metal-organic framework material comprising the step reacting a reaction mixture in the liquid phase of at least one copper compound having at least one at least bidentate, organic compound which can bind by coordination to the copper in the presence of a nonaqueous solvent, the at least one at least bidentate, organic compound being derived from a polycarboxylic acid having at least three carboxyl groups, and the reaction proceeding at atmospheric pressure above 80° C.

Abstract: The invention relates to an oxygen scavenger/indicator which contains at least one substance with combined scavenger and indicator function for oxygen, which can absorb oxygen under the effect of moisture in basic conditions, and also to at least one basically reacting compound. The indicator effect is effected by a change in at least one physical property of the substance with combined scavenger and indicator function for oxygen, the change being triggered by the effect of moisture.

Abstract: A method for separating a sulphur compound from a gas mixture. The method includes contacting a gas mixture with an adsorbent which includes a metal-organic framework (MOF) comprising a tridimensional succession of motifs having the formula: MmOkXlLp wherein, inter glia, M is a metal ion selected from the group consisting of Ti4+, V4+, Zr4+, Mn4+, Si4+, Al3+, Cr3+, V3+, Ga3+, In3+, Mn3+, Mn2+ and Mg2+, L is a spacer ligand including a radical having one or more carboxylate groups.

Abstract: A gas sorbing system is formed by gas sorbing components which are dispersed in a polymeric matrix which is porous or permeable to the gases to be sorbed. The gas sorbing components include a central nucleus, selected among a silica particle, polyhedral oligomeric silsesquioxane and a spherosilicate, to which there are bound at least one organic or metalorganic radical carrying a functional group, which is able to chemically fix the gas to be sorbed, and at least one anchoring organic radical including a chain of carbon atoms, which has the functionality of fixing the nucleus in the matrix polymer.

Abstract: Provided is a process of manufacturing an oil adsorption foaming sheet for preventing or recovering pollution of ocean or soil by oil or hydrocarbon. The oil adsorption foaming sheet is manufactured by mixing polyurethane prepolymer with refined peat moss, lecithin as a dispersion and surfactant agent, N-methylmorpline as a foaming agent, and triethylenamin as a catalyst, to thereby form a foaming composite, foaming the foaming composite, to thereby obtain a soft continuous air bubble foaming body, slicing the foaming body, and drying the sliced foaming body into a moisture content of 2 wt % or below.

Abstract: An optical isomer separating filler wherein a polysaccharide derivative is chemically bonded onto a support. This optical isomer separating filler is characterized in that the halogen content in the filler is 3.0 to 5.0%.

Abstract: An adsorbent composition and method of using the adsorbent composite is described. The method for removing heavy metals from contaminated water is done by mixing contaminated water having a concentration of one or more heavy metals with an adsorbent composite comprising granules of a mixture of 50.363 wt % kaolin clay, a 4.477 wt % roasted date pits powder, a 5.54 wt % silica powder a 14.99 wt % magnesite powder and a 24.623 wt % water. After reacting the contaminated water and adsorbent composite together for a specific time the water is filtered and was found to contain reduced amount of heavy metals. The cleaned water can further be used for industrial cooling systems or watering gardens.

Abstract: Absorbent hydrogels are formed by reacting a protein meal base, a radical initiator and a polymerizable monomer. Optionally, a cross-linking agent and/or a radical accelerant, such as tetramethylethylenediamine (TMEDA) or sodium bisulfite (NaHSO3), is also added to the mixture. Preferably, the radical initiator is ammonium persulfate (APS) or potassium persulfate (KPS), and the cross-linking agent is preferably trifunctional trimethylolpropane trimethacrylate (TMPTMA) or methylene bis acrylamide (MBA). The polymerizable monomer is preferably acrylic acid, or a combination of acrylic acid and acrylamide. The as-formed hydrogel is washed in order to extract non-reactant components from the gel and then dried. The resultant absorbent and superabsorbent hydrogels have high water uptake ratios, and can be utilized for a variety of applications.

Abstract: Metal-organic framework (MOF) materials are provided and are selectively adsorbent to xenon (Xe) over another noble gas such as krypton (Kr) and/or argon (Ar) as a result of having framework voids (pores) sized to this end. MOF materials having pores that are capable of accommodating a Xe atom but have a small enough pore size to receive no more than one Xe atom are desired to preferentially adsorb Xe over Kr in a multi-component (Xe—Kr mixture) adsorption method. The MOF material has 20% or more, preferably 40% or more, of the total pore volume in a pore size range of 0.45-0.75 nm which can selectively adsorb Xe over Kr in a multi-component Xe—Kr mixture over a pressure range of 0.01 to 1.0 MPa.

Abstract: A method for individualizing a trichome from an epidermis of a non-seed portion of a trichome-bearing plant in the Stachys genus to form a fibrous structure is provided. The method comprises contacting the plant with a device to separate the trichome from the epidermis and incorporating the separated trichome into a fibrous structure.

Abstract: The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for their preparation and separations devices containing the chromatographic materials. The preparation of the inorganic/organic hybrid materials of the invention wherein a surrounding material is condensed on a porous hybrid core material will allow for families of different hybrid packing materials to be prepared from a single core hybrid material. Differences in hydrophobicity, ion-exchange capacity, surface charge or silanol activity of the surrounding material may be used for unique chromatographic separations of small molecules, carbohydrates, antibodies, whole proteins, peptides, and/or DNA.

Abstract: The present invention relates to a method for hydrothermal preparation of a solid made up of a metal-organic framework (MOF) of crystallised, porous aluminium carboxylates, in an aqueous medium. The invention also relates to solids made up of metal-organic frameworks (MOF) of porous, crystallised aluminium carboxylates capable of being obtained by the method of the invention as well as to the uses thereof for the storage of liquid or gaseous molecules, for selective separation of gas and for catalysis.

Abstract: The invention is a surface coating which will reduce the aldehyde concentration in a room via a aldehyde reactive material contained in the coating. Upon reaction, the aldehyde becomes part of the reactive molecule and, thus, is permanently held within the coating.

Abstract: Porous block nano-fiber composite (110), a filtration system (10) and methods of using the same are disclosed. An exemplary porous block nano-fiber composite (110) includes a porous block (100) having one or more pores (200). The porous block nano-fiber composite (110) also includes a plurality of inorganic nano-fibers (211) formed within at least one of the pores (200).

Abstract: An oil sorbent material particularly for removing an oil slick from water is hydrophobic, in the form of a free-flowing dry powder, and preferentially absorbs oil from the slick, forming buoyant clumps which are easily skimmed or screened from water. Absorbed oil can be recovered from the clumps of sorbent material by several methods including solvent extraction, and heating to liquefy or vaporize the absorbed oil, allowing recovery of a significant fraction of oil spilled on or in water.

Abstract: The present invention relates to the development and manufacture of sorbent products and devices suitable for use in hydrocarbon, universal and hazmat applications that are composed of structural components and/or sorbent materials that are fully biodegradable and landfill friendly. The structural components and/or sorbents may be derived from biodegradable polypropylene or biodegradable natural materials and combined in different sizes, shapes and configurations.

Abstract: A method of scavenging oil from an oil-water mixture includes providing a plurality of functionalized fly ash particles having functionalized surfaces including reactive groups or reactive materials having hydrophobic groups covalently bound to the reactive groups or reactive materials. The oil-water mixture is contacted with the plurality of functionalized fly ash particles. The plurality of functionalized fly ash particles absorb oil from the oil-water mixture to form oil-laden fly ash particles. The oil-laden fly ash particles can be fed into a combustion process to generate heat from oil absorbed thereon, or absorbed oil from the oil-laden fly ash particles can be separated using a desorption process, and the oil recovered after separating.

Abstract: An odor control composition includes (a) at least one fragrance and (b) a halo active aromatic sulfonamide compound of Formula (I): wherein R1, R2, R3, R4, and R5 are independently selected from hydrogen, COOR?, CON(R?)2, alkoxy, CN, NO2, SO3R?, halogen, substituted or unsubstituted phenyl, sulfonamide, halosulfonamide, and substituted or unsubstituted C1-C12 alkyl; R? is hydrogen, an alkali metal, an alkaline earth metal, substituted C1-C12 alkyl, or unsubstituted C1-C12 alkyl; and R? is hydrogen or substituted or unsubstituted C1-C12 alkyl, where the two R? groups in CON(R?)2 may be independently selected; X is halogen; M is an alkali or alkaline earth metal; and n is the number of water molecules per molecule of the sulfonamide compound.

Abstract: A flow-through substrate comprising a sulfur-containing compound distributed throughout the flow-through substrate structure. The flow-through substrate may be used, for example, in the removal of a heavy metal from a fluid such as a gas stream.

Abstract: A parallel passage fluid contactor structure for chemical reaction processes has one or more segments, where each segment has a plurality of substantially parallel fluid flow passages oriented in an axial direction; cell walls between each adjacent fluid flow passages and each cell wall has at least two opposite cell wall surfaces. The structure also includes at least one active compound in the cell walls and multiple axially continuous conductive filaments either embedded within the cell walls or situated between the cell wall surfaces. The conductive filaments are at least one of thermally and electrically conductive, are oriented in axially, and are in direct contact with the active compound, and are operable to transfer thermal energy between the active material and the conductive filaments. Heating of the conductive filaments may be used to transfer heat to the active material in the cell walls. Methods of manufacturing the structure are discussed.

Abstract: An underwater oleophilic hydrophobic oil-capturing water permeable drag-net with the porous oil-capturing water-repelling and water-permeable component positioned in the back of and connected to the drag-net that can be dragged vertically through the underwater oil spill area of the Gulf to remove oil is presented. The invention is made of various sizes depending on the area of the oil spill area; including 100 ft high (north to south), 100 ft wide (east to west) and 10 ft deep (front to back). The net mesh-like material is made from threads and wires knotted, twisted, and woven to form a regular pattern with fine spaces between the threads with each strand of a metal, plastic, wire and fiber net-type material made of and covered with organic and inorganic Oleophilic hydrophobic and superhydrophobic, oil attracting and oil bonding molecules, materials or sorbents including Superhydrophobic materials.

Abstract: An environmental remediation material and method for making the same which include processing an organic material to increase the internal surface and surface pore area thereof through pyrolysis, coating the pyrolyzed material with a non-polar substance to enhance the material's oleophilicity, and applying secondary processing treatments designed to optimize the material for preselected chemical remediation applications. The remediation material is insoluble in aqueous environments, free of environmentally hazardous chemicals or compounds and readily transportable and disposable following use.

Abstract: The invention provides a conductive substance-adsorbing resin film on which a conductive layer being excellent in adhesion to the resin film and having less unevenness at the interface with the resin film can easily be formed, a method for producing the same, a metal layer-coated resin film on which a high definition wiring excellent in adhesion to the insulating resin film can easily be formed, which is obtained by using the conductive substance-adsorbing resin film of the invention, and a method for producing a metal layer-coated resin film that is a material capable of easily producing a printed-wiring board having a high definition wiring. The invention also provides a conductive substance-adsorbing resin film including at least two resin layers, wherein at least one of the resin layers is an adsorbing resin layer having a property of adsorbing a conductive substance or a metal.

Abstract: A high pressure hydrogen confinement apparatus according to one embodiment includes carbon nanotubes capped at one or both ends thereof with a hydrogen-permeable membrane to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough. A hydrogen confinement apparatus according to another embodiment includes an array of multi-walled carbon nanotubes each having first and second ends, the second ends being capped with palladium (Pd) to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough as a function of palladium temperature, wherein the array of carbon nanotubes is capable of storing hydrogen gas at a pressure of at least 1 GPa for greater than 24 hours. Additional apparatuses and methods are also presented.

Abstract: A gas adsorption material comprising: a porous metal-organic framework and a plurality of functionalized fullerenes or fullerides provided in the pores of the metal-organic framework. The metal-organic framework includes a plurality of metal clusters, each metal cluster including one or more metal ions, and a plurality of charged multidentate linking ligands connecting adjacent metal clusters.

Abstract: Disclosed is a boron removal method which can remove boron from boron-containing water satisfactorily by using a small amount of a chemical agent, and which generates small amount of precipitate. Also disclosed is a boron-removing agent which is easy to handle and has excellent boron-adsorption ability. A xerogel of an organic polymeric compound having a cis-type diol structure and a water-soluble salt of an alkaline earth metal are added to a boron-containing water under alkaline conditions.

Abstract: The present invention relates to the selective separation of hydrogen (“H2”) hydrocarbons in streams containing both hydrogen and hydrocarbons (e.g. methane, ethylene, ethane, propylene, propane, etc.) utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in either a pressure swing adsorption process, a temperature swing adsorption process, or a membrane separations process to separate hydrogen from hydrocarbons present in hydrogen production streams or petrochemical/petroleum refining product streams and intermediate streams.

Abstract: A pressed sorbent form includes a sorbent and a binder. The sorbent is chosen from the group including silica gel, molecular sieve, activated carbon, and clay. The binder is powdered ethyl vinyl acetate.

Abstract: A gas adsorbent which has sufficient gas adsorptivity for noxious gas components in a cigarette when brought into contact with a gas stream having a high flow rate as that when it passes through a cigarette filter, and which releases a small amount of bad odor components such as amine impurities and free noxious components which adversely affect health such as aromatic compounds derived from the gas adsorbent itself, the gas adsorbent satisfying conditions (I), (II), (IV) and (V) or conditions (I), (III), (IV) and (V), as described in the specification.

Abstract: The present invention relates to a structure having a core-shell configuration. The core comprises a predetermined adsorber solid material, and the shell at least partially surrounding the core comprises a predetermined humidity controlling material, thereby enabling using said adsorber solid material for interacting with and thus storing therein a predetermined adsorbable gas under desired environmental conditions. The invention also discloses a pressure vessel for use in storing at least one gas.

Abstract: A technique of fabricating a medium-high temperature CO2 sorbent of layered nano-carbonate is provided. A CO2 sorbent is fabricated. The sorbent captures CO2 at a medium-high temperature above 600° C. Calcium acetate is introduced for making a nano-scale layered double hydroxide (LDH). The layered structure is used for templated synthesis. The sorbent has an initial conversion rate above 90%; and the conversion rate remains the same even after 100 times of carbonation/de-carbonation cycles.

Abstract: Disclosed herein is a fungicide, including: a porous carbon material; and a silver member adhered to the porous carbon material, wherein a value of a specific surface area based on a nitrogen BET, namely Brunauer, Emmett, and Teller method is equal to or larger than 10 m2/g, and a volume of a fine pore based on a BJH, namely Barrett, Joyner, and Halenda method and an MP, namely Micro Pore method is equal to or larger than 0.1 cm3/g.

Abstract: The present application provides a protected solid adsorbent that includes a solid adsorbent substrate and a surface layer at least partially coating the solid adsorbent substrate, the surface layer being generally permeable to an active agent. Additionally, a process for protecting a solid adsorbent and an adsorption system that includes a vessel containing the protected solid adsorbent is provided.

Abstract: Disclosed are a novel hydrogen storage material with enhanced hydrogen storage capacity prepared by doping an organic framework material with light metal cations, and a method of using the same for hydrogen storage. The present inventive material has at least one phenyl group at each face of a triangular building unit, which is doped with metal cations such as alkali metal cations, alkali-earth metal cations, etc., so that the material exhibits greatly improved capacity of hydrogen absorption and desorption at room temperature and can provide hydrogen storage materials practically adapted for fuel batteries useable even at room temperature.

Abstract: The use of a sulfur-impregnated organoclay provides a mercury or arsenic removal media having increased reactivity, stability, and mercury removal ability. The Hg/As removal media described herein is prepared by impregnating an organophilic clay with elemental (free state) sulfur. Alternatively, the clay can be made organophilic by onium ion reaction prior to or simultaneously with impregnating the organoclay with sulfur.

Abstract: An adsorbent suitable for heavy metal adsorption is described, comprising a thiol functionalised support wherein the adsorbent has a BET surface area in the range 200-500 m2/g, a pore diameter in the range 70-150 Angstroms and a pore volume?0.25 cm3/g. The adsorbent may be used to remove heavy metals e.g. mercury and/or arsenic, from wastewater streams such as produced water or flue gas scrubber waters.

Abstract: The present disclosure provides low pH fibers that are treated with additives, preferably after regenerating the cellulosic fiber, to control the pH and oxidation-reduction potential (ORP) in an aqueous environment where the fiber is placed. The low pH fibers can be formed into fibrous articles such as tampons or wipes. The low pH fibers with the additives provide health benefits to the user in that they hinder the ability of harmful bacteria to flourish.

Abstract: A process for preparing water-absorbing polymer beads by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, the initiator being added to the monomer solution from 0.5 to 60 seconds before the droplets are generated.

Abstract: A dry product that permanently removes oil and oil stains from liquid or dry surfaces and is environmentally safe. The dry product is formed by mixing efficacious proportions of untreated amorphous silica with a dry, inert organic, inorganic or synthetic carrier, or combinations of said carriers. Suitable inert carriers include, but are not limited to, (a) inert inorganic carriers including, but not limited to, clays, perlite, vermiculite, crushed glass, volcanic ash and sand; (b) inert organic carriers, including, but not limited to, peat moss, straw, hay, sawdust, ground corncobs, flours, and coconut coir, and (c) inert synthetic carriers, including, but not limited to, polyurethane, polyethylene and polypropylene. The dry product can be applied directly to oil stains either on a hard surface, such as concrete or asphalt, or to oil spills on water.

Abstract: Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

Abstract: The present invention relates to novel chromatography stationary phases comprising non-polysaccharide carbohydrate polyethers and methods for their preparation. Particularly, the invention relates to chromatography stationary phases comprising said carbohydrate polyethers and more particularly to chiral stationary phases. Also, since the carbohydrate polyethers of the present invention can be conveniently prepared with controlled functionality, molecular weights and polydispersity indices as well as controlled microstructure, tertiary structure stationary phases prepared from these polymers can be conveniently modified or custom synthesized to accommodate specific separation requirements.

Abstract: The present invention relates to a method for generating at least one polydentate metal chelating affinity ligand, which method comprises the steps of (a) providing at least one scaffold defined by the general formula (I): H2N—(X1)n—S—S—(X2)m—CH2—NH2 wherein X1 and X2 irrespective of each other are carbon atoms or heteroatoms, and n and m irrespective of each other are integers of 1 to 5; (b) providing at least one polydentate metal chelating affinity ligand arm, optionally in a form wherein the metal chelating functionalities of at least one arm are protected, on each scaffold by derivatisation of the nucleophilic NH2 groups of the scaffold; (c) reducing the disulfide bond of the derivatised scaffold; and, if required (d) deprotecting the functionalities of the ligand arm(s) provided in step (b). In the most preferred embodiment, the reduction of the disulfide bond and the deprotection step is performed essentially simultaneously.

Abstract: Reserve pit remediation utilizing an organic absorbent product made from beetle-killed lodgepole pine. The reserve pit remediation may take place in-situ, ex-situ, or a combination of both in-situ and ex-situ. In one embodiment of an in-situ reserve pit remediation process, one or more of a volume of water within the pit, a volume of fluids other than water within the pit, and a volume of solids within the pit are estimated, a quantity of absorbent product to be distributed within the pit is determined based on one or more of the estimated volumes, the quantity of absorbent product is distributed over the surface of the reserve pit, a period of time for the absorbent product to absorb at least a portion of the fluids other than water is allowed, and the absorbent product is mixed with the solids within the reserve pit.

Abstract: An object of the present invention is to provide an aqueous-liquid-absorbing agent which comprises water-absorbent resin particles as essential components and is suitable for uses in sanitary materials. As a means of achieving this object, an aqueous-liquid-absorbing agent according to the present invention is an aqueous-liquid-absorbing agent comprising water-absorbent resin particles as essential components, wherein the water-absorbent resin particles are obtained by a process including the step of polymerizing a water-soluble ethylenically unsaturated monomer and have a crosslinked structure in their inside; with the aqueous-liquid-absorbing agent exhibiting an absorption rate (FSR) of not less than 0.2 g/g/s, a water absorption capacity (CRC) of 5 to 25 g/g, a saline flow conductivity (SFC) of not less than 400×10?7 cm3·s/g, and a wet porosity of not less than 20%.

Abstract: Compositions, and processes utilizing such compositions, are provided for reducing mercury emissions from combustion gases. Such compositions comprise a sorbent and a brominated organic compound.

Abstract: A separation membrane complex where a carbon membrane is formed directly on a porous body (surface layer) and an intermediate layer has a thickness of 10 to 100 ?m can be used as a filter having improved flux and selectivity in comparison with a conventional one.