Sulfur Or Sulfur Compound Removal Patents (Class 502/517)
  • Patent number: 4507397
    Abstract: The process of oxidatively regenerating in situ a fixed bed hydrocarbon catalyst which is sensitive to reactive sulfur compounds in a conversion system having sulfur-contaminated vessels and/or conduits in the flow path upstream from said catalyst is improved by passing regenerating oxygen-containing gas first through the sulfur-contaminated vessels and/or conduits and then through the fixed catalyst bed while limiting the water content of the regenerating gas to a concentration of not more than 0.1 mol percent throughout the flow path and at a temperature in the range of 750.degree.-1100.degree. F. to oxidize the sulfur contaminants in the vessels and/or conduits upstream from the catalyst. Thereby the evolved sulfur oxides flow through the fixed bed catalyst in the absence of sufficient water which would promote reaction of sulfur oxides with the catalyst.
    Type: Grant
    Filed: July 28, 1983
    Date of Patent: March 26, 1985
    Assignee: Chevron Research Company
    Inventor: Waldeen C. Buss
  • Patent number: 4489047
    Abstract: An acceptor of MnO.sub.x or iron oxide, wherein x has a value of from 1 to 1.5, supported on a (.gamma.)-alumina carrier which may contain silica, is used to remove hydrogen sulfide from process gases. The acceptor is regenerated with steam in a reducing atmosphere at a temperature of from 300.degree. C. to 700.degree. C.
    Type: Grant
    Filed: October 29, 1982
    Date of Patent: December 18, 1984
    Assignee: Nederlandse Centrale Organisatie voor Toegepast-Natuurwetenschappelijk Onderzoek
    Inventors: Willem A. de Jong, Berend J. van der Linde
  • Patent number: 4485183
    Abstract: Deactivated hydrorefining catalysts are regenerated by incorporation of as phosphorus component followed by combustive coke-removal from the catalyst. The regenerated catalyst is useful for promoting hydrodesulfurization reactions, particularly those involving demetallation of hydrocarbons.
    Type: Grant
    Filed: April 12, 1982
    Date of Patent: November 27, 1984
    Assignee: Union Oil Company of California
    Inventors: Richard B. Miller, Ryden L. Richardson
  • Patent number: 4482637
    Abstract: A method is disclosed for regenerating reforming catalysts containing a platinum group component and/or rhenium component in association with a halogen component on a porous inorganic oxide, such as one containing alumina without significant displacement of the rhenium components by sulfur oxides generated during the regeneration process. The method is particularly characterized in that carbon is removed from the catalyst by in situ oxidation at temperatures not in excess of about 750.degree. F. and without modification of the catalytic reforming process flow circuit, as by disconnecting or isolating the heat exchangers and furnace tubes.Sulfide scale is converted in a separate oxidation step to sulfur dioxide, SO.sub.2, without substantial oxidation to sulfur trioxide, SO.sub.3, by maintaining the inner walls of the heat exchangers and furnace tubes, where such iron sulfides are present, at a temperature not in excess of about 900.degree. F. and not less than about 750.degree. F.
    Type: Grant
    Filed: August 4, 1982
    Date of Patent: November 13, 1984
    Assignee: Chevron Research Company
    Inventors: Waldeen C. Buss, Thomas R. Hughes
  • Patent number: 4469803
    Abstract: Poisoned catalyst is regenerated by first subjecting it to an oxidative burn-off and then soaking it in a base, preferably NaOH. The dried product is comparable in Claus activity to fresh catalyst.
    Type: Grant
    Filed: March 1, 1983
    Date of Patent: September 4, 1984
    Assignee: Alberta Research Council
    Inventor: Zacheria M. George
  • Patent number: 4444741
    Abstract: Catalysts comprising bismuth and vanadium components are highly active and stable, especially in the presence of water vapor, for oxidizing hydrogen sulfide to sulfur or SO.sub.2. Such catalysts have been found to be especially active for the conversion of hydrogen sulfide to sulfur by reaction with oxygen or SO.sub.2.
    Type: Grant
    Filed: December 30, 1981
    Date of Patent: April 24, 1984
    Assignee: Union Oil Company of California
    Inventors: Robert H. Hass, John W. Ward
  • Patent number: 4444908
    Abstract: Catalysts comprising bismuth and vanadium components are highly active and stable, especially in the presence of water vapor, for oxidizing hydrogen sulfide to sulfur or SO.sub.2. Such catalysts have been found to be especially active for the conversion of hydrogen sulfide to sulfur by reaction with oxygen or SO.sub.2.
    Type: Grant
    Filed: April 1, 1982
    Date of Patent: April 24, 1984
    Assignee: Union Oil Company of California
    Inventors: Robert H. Hass, John W. Ward
  • Patent number: 4444742
    Abstract: Catalysts comprising bismuth and vanadium components are highly active and stable, especially in the presence of water vapor, for oxidizing hydrogen sulfide to sulfur or SO.sub.2. Such catalysts have been found to be especially active for the conversion of hydrogen sulfide to sulfur by reaction with oxygen or SO.sub.2.
    Type: Grant
    Filed: April 1, 1982
    Date of Patent: April 24, 1984
    Assignee: Union Oil Company of California
    Inventors: Robert H. Hass, John W. Ward
  • Patent number: 4442221
    Abstract: A process for regenerating a spent copper-porous refractory metal oxide carrier composite sorbent for removing sulfur-containing compounds from naphthas in which the spent sorbent is optionally stripped of absorbed naphtha, oxidized to convert absorbed sulfur to sulfates or sulfur dioxide, optionally reduced to further convert absorbed sulfur to sulfur dioxide, and, finally, impregnated with fresh copper via contact with an aqueous solution of a copper salt followed by drying and calcining to convert the salt to copper oxide or copper metal whereby a substantial portion of the sulfur sorbent activity and lifetime of the sorbent is restored.
    Type: Grant
    Filed: April 9, 1982
    Date of Patent: April 10, 1984
    Assignee: Chevron Research Company
    Inventors: Keith C. Bishop, III, David E. Earls, Richard C. Robinson, Donald W. Blakely, deceased, by Robert L. Jacobson, administrator
  • Patent number: 4432961
    Abstract: Catalysts comprising bismuth and vanadium components are highly active and stable, especially in the presence of water vapor, for oxidizing hydrogen sulfide to sulfur or SO.sub.2. Such catalysts have been found to be especially active for the conversion of hydrogen sulfide to sulfur by reaction with oxygen or SO.sub.2.
    Type: Grant
    Filed: December 30, 1981
    Date of Patent: February 21, 1984
    Assignee: Union Oil Company of California
    Inventors: Robert H. Hass, John W. Ward