And Group Viii (iron Group Or Platinum Group) Metal Containing Patents (Class 502/66)
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Patent number: 7629283Abstract: One exemplary embodiment can be an extruded C8 alkylaromatic isomerization catalyst. The extruded catalyst can include: about 2-about 20%, by weight, of an MTW zeolite; about 80-about 98%, by weight, of a binder including an alumina; about 0.01-about 2.00%, by weight, of a noble group metal calculated on an elemental basis; and about 100 ppm-less than about 1000 ppm, by weight, of at least one alkali metal calculated on an elemental basis. Generally, the weight percents of the MTW zeolite, the binder, the noble group metal, and the at least one alkali metal are based on a weight of the extruded catalyst.Type: GrantFiled: December 28, 2007Date of Patent: December 8, 2009Assignee: UOP LLCInventors: Patrick C. Whitchurch, Paula L. Bogdan, John E. Bauer
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Publication number: 20090299115Abstract: A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite selected from IM-5 zeolite and zeolites with structure type MFI, MOR, BEA and MTW, at least one group VIII metal, at least one group IIIA metal and at least one porous mineral matrix. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.Type: ApplicationFiled: November 3, 2006Publication date: December 3, 2009Applicant: GEMPLUSInventors: Emmanuelle Guillon, Eric Sanchez, Sylvie Lacombe
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Patent number: 7625478Abstract: Blends of ZSM-48 catalysts are used for hydroprocessing of hydrocarbon feedstocks. The blend of ZSM-48 catalysts includes at least a portion of ZSM-48 crystals having a SiO2:Al2O3 ratio of 110 or less that are free of non-ZSM-48 seed crystals and have a desirable morphology.Type: GrantFiled: December 12, 2006Date of Patent: December 1, 2009Assignee: ExxonMobil Research and Engineering CompanyInventors: Wenyih F. Lai, Terry E. Helton, Dominick N. Mazzone
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Patent number: 7625832Abstract: A catalyst for the hydroprocessing of organic compounds, composed of an interstitial metal hydride having a reaction surface at which monatomic hydrogen is available. The activity of the catalyst is maximized by avoiding surface oxide formation. Transition metals and lanthanide metals compose the compound from which the interstitial metal hydride is formed. The catalyst's capabilities can be further enhanced using radio frequency (RF) or microwave energy.Type: GrantFiled: December 5, 2006Date of Patent: December 1, 2009Assignee: Carnegie Mellon UniversityInventors: David A. Purta, Marc A. Portnoff, Faiz Pourarian, Margaret A. Nasta, Jingfeng Zhang
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Publication number: 20090292154Abstract: The invention relates to a modified zeolite catalyst, useful for the conversion of paraffins, olefins and aromatics in a mixed feedstock such as FCC gasoline that contain high content of olefin, aromatic and n-paraffin into isoparaffins. The invention further relates to the use of such a catalyst, for example but not limited to, in a process for the conversion of paraffins, olefins and aromatics in a mixed feedstock into the product having high amount of branched paraffins with decreased aromatics and olefins, a useful gasoline blend, with negligible production of lighter gases.Type: ApplicationFiled: March 6, 2009Publication date: November 26, 2009Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCHInventors: Viswanadham Nagabhatla, Raviraj Kamble, Amit Sharma, Jagdish Kumar, Bhagwan Singh Negi, Murali Dhar Gudimella, Madhukar Onkarnath Garg
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Publication number: 20090291835Abstract: A honeycomb structure includes a honeycomb unit having inorganic particles, an inorganic binder and inorganic fibers. A value of (D90-D10)/D50, which indicates a length distribution of the inorganic fibers, is about two or less, where, when the fiber length is taken in a horizontal axis and a volume frequency is taken in a vertical axis, D10 is a fiber length at 10% by volume, D50 is a fiber length at 50% by volume, and D90 is a fiber length at 90% by volume, where D10<D50<D90.Type: ApplicationFiled: February 19, 2009Publication date: November 26, 2009Applicant: IBIDEN CO., LTD.Inventors: Kazushige OHNO, Masafumi Kunieda, Takahiko Ido
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Publication number: 20090291833Abstract: A honeycomb structure includes center and peripheral regions. The center region has a smaller similarity shape in relation to a peripheral shape of the honeycomb structure in a cross section perpendicular to the longitudinal direction. The peripheral region is located outside the smaller similarity shape. Zeolite ion-exchanged with at least one of Cu, Mn, Ag, and V is present at a first weight ratio and a second weight ratio in the center region and the peripheral region, respectively, relative to a total weight of the zeolite. The second weight ratio is larger than the first weight ratio. Zeolite ion-exchanged with at least one of Fe, Ti, and Co is present at a third weight ratio and a fourth weight ratio in the center region and the peripheral region, respectively, relative to a total weight of the zeolite. The third weight ratio is larger than the fourth weight ratio.Type: ApplicationFiled: June 30, 2009Publication date: November 26, 2009Applicant: IBIDEN CO., LTD.Inventors: Kazushige OHNO, Masafumi KUNIEDA, Takahiko IDO
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Publication number: 20090291831Abstract: A honeycomb structure includes at least one honeycomb unit. The honeycomb unit includes plural cell walls to define plural cells, about 61 to about 70 mass % of zeolite, about 15 to about 25 mass % of an inorganic fiber, and about 10 to about 20 mass % of alumina other than alumina included in the zeolite and the inorganic fiber. The honeycomb unit has an opening ratio (%) of about 57% or more. The opening ratio is equal to or less than y shown in a formula of y=0.55x+30 when a content x (mass %) of the zeolite included in the honeycomb unit is less than about 66 mass %. The opening ratio is equal to or less than y shown in a formula of y 32 ?0.25x+82.8 when the content x (mass %) is about 66 mass % or more.Type: ApplicationFiled: January 26, 2009Publication date: November 26, 2009Applicant: IBIDEN CO., LTD.Inventors: Kazushige OHNO, Masafumi Kunieda, Takahiko Ido
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Publication number: 20090291834Abstract: A honeycomb structure includes a honeycomb unit and a coating layer. The honeycomb unit includes inorganic particles, an inorganic binder, and partition walls. The partition walls extend along a longitudinal direction of the honeycomb unit to define plural through holes. The coating layer defines a periphery of the honeycomb structure. A ratio of a specific heat capacity of the coating layer to a specific heat capacity of the honeycomb unit is about 1.0 or less.Type: ApplicationFiled: January 19, 2009Publication date: November 26, 2009Applicant: IBIDEN CO., LTD.Inventors: Kazushige OHNO, Masafumi Kunieda, Takahiko Ido
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Publication number: 20090291832Abstract: A honeycomb structure includes a first end face, a second end face, and at least one honeycomb unit. The second end face is disposed opposite the first end face along a longitudinal direction of the honeycomb structure. The at least one honeycomb unit has plural cell walls extending along the longitudinal direction from the first end face toward the second end face to define plural cells. The at least one honeycomb unit includes about 50 mass % to about 60 mass % of zeolite, about 15 mass % to about 25 mass % of inorganic fibers, about 20 mass % to about 32 mass % of alumina that is not contained in the zeolite or the inorganic fibers, and an opening ratio Y(%). The opening ratio Y(%) satisfies an expression about 57?Y?0.7X+25, where X (mass %) is a zeolite content of the at least one honeycomb unit.Type: ApplicationFiled: February 11, 2009Publication date: November 26, 2009Applicant: IBIDEN CO., LTD.Inventors: Kazushige OHNO, Masafumi Kunieda, Takahiko Ido
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Publication number: 20090272675Abstract: A method for producing a substantially desulfurized a hydrocarbon fuel stream at temperatures less than 100° C. The method includes providing a nondesulfurized fuel cell hydrocarbon fuel stream that may include water and passing the fuel stream sequentially through a zeolite Y adsorbent and a selective sulfur adsorbent. The zeolite Y adsorbent may be exchanged with copper ions. The method produces a substantially desulfurized hydrocarbon fuel stream containing less than 50 ppb sulfur.Type: ApplicationFiled: June 5, 2009Publication date: November 5, 2009Applicant: SUD-CHEMIE INC.Inventors: Chandra C Ratnasamy, Jon P. Wagner, R. Steve Spivey, Hans-Georg Anfang
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Patent number: 7611689Abstract: The invention provides a zeolite of the faujasite structure which has a unit cell size in the range of from 24.40 to 24.50 ?; a bulk silica to alumina ratio (SAR) in the range of from 5 to 10; and an alkali metal content of less than 0.15 wt %. Such zeolites have been found to have a very useful naphtha selectivity in hydrocracking, particularly a selectivity to heavy naphtha. A preparation process for the zeolite, hydrocracking catalyst composition comprising the zeolite and its use in hydrocracking are also provided.Type: GrantFiled: September 21, 2005Date of Patent: November 3, 2009Assignee: Shell Oil CompanyInventors: Edward Julius Creyghton, Laurent Georges Huve, Aan Hendrik Klazinga
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Publication number: 20090264280Abstract: The invention relates to sorption materials for removing of heavy metal ions from ground water and surface aquifer systems, and can be used by enterprises in chemical and metallurgical industry which utilize etching and galvanic technologies. The sorbent for removing of heavy metal ions from water is composed of ground zeolite and nanophase material, where the nanophase material consists of nanophase iron hydroxide and nanophase boehmite in the following ratio, mass %: Nanophase iron hydroxide 12-18 Nanophase boehmite ?5-13 Ground zeolite the rest. Technical result is the enhanced purification effectiveness of the sorbent due to a wider range of heavy metals it can absorb when purifying highly contaminated water.Type: ApplicationFiled: June 30, 2009Publication date: October 22, 2009Inventors: Vladimir N. LISETSKIY, Tatyana A. LISETSKAYA, Lidija N. MERKUSCHEVA
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Patent number: 7605110Abstract: A ceramic body, a ceramic catalyst body, a ceramic catalyst body and related manufacturing methods are disclosed wherein a cordierite porous base material has a surface, formed with acicular particles made of a component different from that of cordierite porous base material, which has an increased specific surface area with high resistance to a sintering effect. The ceramic body is manufactured by preparing a slurry containing an acicular particle source material, preparing a porous base material, applying the slurry onto a surface of the porous base material and firing the porous base material, whose surface is coated with the slurry, to cause acicular particles to develop on the surface of the porous base material. A part of or a whole of surfaces of the acicular particles is coated with a constituent element different from that of the acicular particles.Type: GrantFiled: April 5, 2007Date of Patent: October 20, 2009Assignees: Denso Corporation, Nippon Soken, Inc.Inventors: Keiichi Yamada, Kazuhiko Koike, Katsumi Yoshida, Hideki Kita, Naoki Kondo, Hideki Hyuga
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Publication number: 20090240008Abstract: A process for the preparation of a catalyst that contains at least one modified zeolite, whereby said zeolite—before being modified—has a maximum pore opening diameter that is less than or equal to 7 ?, and whereby said process comprises at least: a) One stage for introducing at least one metal that is selected from among the metals of groups VIB and VIII of the periodic table on a substrate that is based on at least one protonated zeolite, b) One stage for treating said zeolite in the presence of at least one molecular compound that contains at least one silicon atom, and said compound that has a diameter that is greater than the maximum opening diameter of the pores of said zeolite, c) At least one heat treatment stage, is described.Type: ApplicationFiled: November 3, 2006Publication date: September 24, 2009Inventor: Laurent Simon
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Publication number: 20090230023Abstract: The present invention 1, 2 or 3 provides a desulfurization function-added FCC catalyst which can efficiently reduce the sulfur content of FCC gasoline while maintaining the yield of FCC gasoline in a process of producing FCC gasoline by cracking of heavy oil.Type: ApplicationFiled: June 25, 2007Publication date: September 17, 2009Applicants: IDEMITSU KOSAN CO., LTD., PETROLEUM ENERGY CENTER, A JURIDICAL INC. FOUND.Inventors: Akira Iino, Toshio Itoh, Shinji Akashi
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Patent number: 7585812Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.Type: GrantFiled: June 20, 2008Date of Patent: September 8, 2009Assignee: Sud-Chemie Inc.Inventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
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Patent number: 7582202Abstract: A Composition comprising one or more metal hydroxy salts and a matrix, binder or carrier material, wherein the metal hydroxy salt is a compound comprising (a) as metal either (i) one or more divalent metals, at least one of them being selected from the group consisting of Ni, Co, Ca, Zn, Mg, Fe, and Mn, or (ii) one or more trivalent metal(s), (b) framework hydroxide, and (c) a replaceable anion. This composition has various catalytic applications.Type: GrantFiled: February 10, 2004Date of Patent: September 1, 2009Assignees: Akzo Nobel N.V., Albemarle Netherlands B.V.Inventors: William Jones, Paul O'Connor, Dennis Stamires
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Publication number: 20090216058Abstract: A process for producing a catalyst additive for an FCC catalytic cracking process, the process comprising the steps of providing an MFI or MEL aluminosilicate having a silicon/aluminium atomic ratio of from 10 to 250; de-aluminating the MFI or MEL aluminosilicate by extracting from 20 to 40 wt % of the alumina therefrom; combining the de-aluminated MFI or MEL aluminosilicate with a binder; and calcining the combination of the de-aluminated MFI or MEL aluminosilicate and the binder at elevated temperature to produce the catalyst additive.Type: ApplicationFiled: December 14, 2006Publication date: August 27, 2009Applicant: Total Petrochemicals Research FeluyInventors: Jean-Pierre Dath, Walter Vermeiren, Andre Noiret
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Publication number: 20090209407Abstract: A selective hydrogenation process and a layered catalyst composition for use in the selective hydrogenation process are disclosed. The process is useful for the selective hydrogenation of diolefins having from about 8 to about 19 carbon atoms per molecule to monoolefins.Type: ApplicationFiled: April 9, 2009Publication date: August 20, 2009Inventor: Gregory J. Gajda
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Publication number: 20090197761Abstract: An adsorbent for exhaust gas in accordance with the present invention is produced by mixing a base material with an additive, in which the base material containing Fe-ZSM-5 is obtained by Fe ion exchange of ZSM-5 having an Si/Al2O3 molar ratio of 28 (the number of moles of Si:the number of moles of Al2O3=28:1), and in which the additive contains at least one selected from Y-zeolite having an Si/Al2O3 molar ratio of 250, mordenite having an Si/Al2O3 molar ratio of 200, and ?-zeolite having an Si/Al2O3 molar ratio of 400. The adsorbent can adsorb both hydrocarbons and nitrogen oxides simultaneously effectively.Type: ApplicationFiled: May 30, 2007Publication date: August 6, 2009Inventor: Takaaki Kanazawa
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Publication number: 20090196811Abstract: A NOx reduction catalyst is provided which reduces NOx in processing gas. The NOx reduction catalyst includes a catalyst substrate containing an oxide, a NOx absorption component, and a NOx purification component.Type: ApplicationFiled: May 17, 2007Publication date: August 6, 2009Applicant: CATALER CORPORATIONInventors: Yoshinori Yamashita, Norihiko Aono, Toshimi Murai
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Patent number: 7569511Abstract: An alcohol steam reforming catalyst for generating hydrogen contains palladium, yttrium, and at least one of cerium and a metal oxide. The catalyst displays both an improved alcohol conversion rate and improved carbon dioxide selectivity. Methods of making and using the alcohol steam reforming catalyst are described.Type: GrantFiled: May 5, 2006Date of Patent: August 4, 2009Assignee: BASF Catalysts LLCInventors: Christopher R. Castellano, Ye Liu, Ahmad Moini, Gerald Stephen Koermer, Robert Joseph Farrauto
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Patent number: 7563744Abstract: The present invention relates to a catalyst for the purification of exhaust gases from an internal combustion engine, which comprises a catalytically active coating on an inert ceramic or metal honeycomb body, said coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium and iridium on a fine, oxidic support material. As an oxidic support material, the catalyst comprises a low-porosity material on the basis of silicon dioxide that comprises aggregates of essentially spherical primary particles having an average particle diameter of between 7 and 60 nm.Type: GrantFiled: August 8, 2002Date of Patent: July 21, 2009Assignee: Umicore AG & Co. KGInventors: Harald Klein, Ulrich Neuhausen, Egbert Lox, Jürgen Gieshoff, Thomas Kreuzer
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Publication number: 20090176643Abstract: Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.Type: ApplicationFiled: December 18, 2008Publication date: July 9, 2009Inventors: Christine N. Elia, Mohan Kalyanaraman, Michel A. Daage, Stephen H. Brown, Lei Zhang, Robert A. Crane, Valery Sokolovskii, David M. Lowe, Jun Han, Nicholas Ohler, Daniel M. Giaquinta, Anthony F. Volpe, JR.
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Patent number: 7553791Abstract: A catalyst composition, a process for producing the composition and a process for the conversion of a feedstock containing C9+ aromatic hydrocarbons to produce a resulting product containing lighter aromatic products and less than about 0.5 wt % of ethylbenzene based on the weight of C8 aromatics fraction of the resulting product. The C9+ aromatic hydrocarbons are converted under the transalkylation reaction conditions to a reaction product containing xylene. The catalyst composition comprises (i) an acidity component having an alpha value of at least 300; and (ii) a hydrogenation component having hydrogenation activity of at least 300. The composition can be produced by to incorporating at least one hydrogenation component into an acidity component having an alpha value of at least 300.Type: GrantFiled: November 5, 2004Date of Patent: June 30, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Timothy Edward McMinn, David Anthony Stachelczyk
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Publication number: 20090163353Abstract: The invention is directed to an isomerization catalyst containing an intermediate pore size molecular sieve, a metal or metals selected from the group consisting of Ca, Cr, Mg, La, Ba, Pr, Sr, K and Nd which are effective in raising the isomerization selectivity, and additionally loaded with a Group VIII metal or metals for hydrogenation purposes.Type: ApplicationFiled: February 25, 2009Publication date: June 25, 2009Inventors: Joseph A. Biscardi, Darren P. Fong, Paul Marcantonio
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Publication number: 20090163354Abstract: The invention relates to a structure for the purification of a contaminated gas, for example the exhaust gas from a diesel or petrol engine, the structure incorporating an electrochemical system for treating said gas, composed of an NOx reduction catalyst A, a hydrocarbon oxidation catalyst B, an electron-conducting compound C and an ion-conducting compound D, said structure being characterized in that it is made of or covered with at least one porous, inorganic, electron-conducting and/or ion-conducting material in such a way that the catalysts A and B are disposed in the porosity of the inorganic material and that the ion-conducting, electron-conducting or ion-conducting and electron-conducting inorganic material makes up, respectively, the element C, the element D, or the sum of the elements C and D of said electrochemical system.Type: ApplicationFiled: April 6, 2007Publication date: June 25, 2009Applicant: SAINT-GOBAIN CENTRE RECHERCHES ET D'ET EUROPEENInventors: Patricia Andy, Daniel Urffer, William Mustel
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Patent number: 7550405Abstract: A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.Type: GrantFiled: June 2, 2006Date of Patent: June 23, 2009Assignee: Lummus Technology Inc.Inventors: Zhiping Shan, Peter Wilhelm Gerhard Waller, Bowden George Maingay, Philip J. Angevine, Jacobus Cornelis Jansen, Chuen Y. Yeh, Thomas Maschmeyer, Frits M. Dautzenberg, Leonardo Marchese, Heloise de Oliveira Pastore
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Publication number: 20090139898Abstract: The present invention provides a hydrogenation catalyst, containing a carrier, metal components of nickel, molybdenum and tungsten supported thereon, and an adjuvant component selected from the group consisting of fluorine and phosphor and combination thereof. In another embodiment, the present invention provides a hydrogenation catalyst, containing a carrier and metal components of nickel, molybdenum and tungsten supported thereon, wherein said carrier contains a molecular sieve. The present invention provides further use of said catalyst in the process for hydrogenating hydrocarbon oil. In comparison with a hydrogenation catalyst according to the prior art, the catalyst according to the present invention has a much higher activity.Type: ApplicationFiled: April 20, 2006Publication date: June 4, 2009Inventors: Xiangyun Long, Xuefen Liu, Hong Nie, Kui Wang, Jing Xin, Qinghe Liu, Xiaodong Gao, Zhihai Hu, Yahua Shi, Dadong Li
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Publication number: 20090143220Abstract: Process for the production of hybrid catalysts formed by mixing two catalysts; one active in Fischer-Tropsch synthesis, the other being bifunctional. Such hybrid catalyst thus formed is active both in hydrocracking and in hydroisomerisation reactions. The present invention in addition provides obtainment of a hybrid catalyst and application thereof conjointly with FT catalysts in Fischer-Tropsch synthesis reactions. The hybrid catalyst of the present invention is capable of producing in conditions typically such as those utilised in Fischer-Tropsch synthesis branched hydrocarbons in diverse bands relating to the products thereof (for example naphtha and diesel), reducing or even eliminating necessity for a subsequent hydrotreatment stage in such synthesis reactions.Type: ApplicationFiled: October 30, 2008Publication date: June 4, 2009Inventors: Joberto Ferreira DIAS JUNIOR, Agustin Martines Feliu, Joan Rollan Martinez, Alexandre de Figueiredo Costa, Henrique Soares Cerqueira, Eduardo Falabella Sousa Aguiar
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Publication number: 20090134065Abstract: The catalyst of this invention is capable of enhancing light olefin, e.g., propylene, yields in fluidizable catalytic cracking (FCC) processes. The catalyst comprises (a) pentasil zeolite, (b) at least 5% by weight phosphorus (P2O5) based on particles containing the pentasil, and at least about 1% by weight iron oxide, as measured by Fe2O3, outside of the pentasil zeolite's framework. The catalyst is fluidizable and has an average particle size in the range of about 20 to about 200 microns. The catalyst composition can further comprise additional zeolite suitable for cracking hydrocarbons in a FCC process. The catalyst has been shown to be highly active compared to other catalysts and shows a high selectivity for propylene produced in an FCC process.Type: ApplicationFiled: March 23, 2006Publication date: May 28, 2009Inventors: Wu-Cheng Cheng, Ranjit Kumar, Meenakshi Sundaram Krishnamoorthy, Michael Scott Ziebarth, Philip S. Deitz
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Patent number: 7538065Abstract: An improved noble metal-containing catalyst containing a specific ratio of silica to aluminum in the framework suitable for use in the hydroprocessing of hydrocarbonaceous feeds, which is directed at a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof on a mesoporous support having aluminum incorporated into its framework and an average pore diameter of about 15 to less than about 40 ?.Type: GrantFiled: August 17, 2005Date of Patent: May 26, 2009Assignee: International Business Machines CorporationInventors: Stephen J. McCarthy, Wenyih F. Lai, Sylvain S. Hantzer, Ian A. Cody
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Patent number: 7534738Abstract: An emission control catalyst that exhibits improved CO and HC reduction performance includes a supported platinum-based catalyst, and a supported palladium-gold catalyst. The two catalysts are coated onto different layers, zones, or monoliths of the substrate for the emission control catalyst such that the platinum-based catalyst encounters the exhaust stream before the palladium-gold catalyst. Zeolite may be added to the emission control catalyst as a hydrocarbon absorbing component to boost the oxidation activity of the palladium-gold catalyst.Type: GrantFiled: November 20, 2007Date of Patent: May 19, 2009Assignee: Nanostellar, Inc.Inventors: Kyle L. Fujdala, Timothy J. Truex
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Publication number: 20090124712Abstract: Process for the production of hybrid catalysts formed by mixing two catalysts; one active in Fischer-Tropsch synthesis, the other being bifunctional. Such hybrid catalyst thus formed is active both in hydrocracking and in hydroisomerisation reactions. The present invention in addition provides obtainment of a hybrid catalyst and application thereof conjointly with FT catalysts in Fischer-Tropsch synthesis reactions. The hybrid catalyst of the present invention is capable of producing in conditions typically such as those utilised in Fischer-Tropsch synthesis branched hydrocarbons in diverse bands relating to the products thereof (for example naphtha and diesel), reducing or even eliminating necessity for a subsequent hydrotreatment stage in such synthesis reactions.Type: ApplicationFiled: October 29, 2008Publication date: May 14, 2009Applicant: PETROLEO BRASILEIRO S.A.- PETROBRASInventors: Alexandre DE FIGUEIREDO COSTA, Agustin Martines Feliu, Joan Rollan Martinez, Henrique Soares Cerqueira, Joberto Ferreira Dias Junior, Eduardo Falabella Sousa Aguiar
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Publication number: 20090118556Abstract: The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10?10 m to 24.15×10?10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).Type: ApplicationFiled: December 13, 2005Publication date: May 7, 2009Inventors: Patrick Euzen, Patrick Bourges, Christophe Gueret, Carole Bobin, Alexandra Chaumonnot, Hugues Dulot
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Publication number: 20090112006Abstract: Catalysts useful for the direct epoxidation of olefins are disclosed. The catalysts comprise a noble metal, lead, bismuth, and a titanium or vanadium zeolite. The noble metal, lead, and bismuth may be supported on the titanium or vanadium zeolite. The catalyst may also be a mixture comprising the titanium or vanadium zeolite and a supported catalyst comprising the noble metal, lead, bismuth, and a carrier. The invention includes a process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of the catalyst. The process results in significantly reduced alkane byproduct formed by the hydrogenation of olefin.Type: ApplicationFiled: October 24, 2007Publication date: April 30, 2009Inventor: Roger A. Grey
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Publication number: 20090112034Abstract: This disclosure relates to a catalyst system adapted for transalkylation a C9+ aromatic feedstock with a C6-C7 aromatic feedstock, comprising: (a) a first catalyst comprising a first molecular sieve having a Constraint Index in the range of 3-12 and 0.01 to 5 wt. % of at least one source of a first metal element of Groups 6-10; and (b) a second catalyst comprising a second molecular sieve having a Constraint Index less than 3 and 0 to 5 wt. % of at least one source of a second metal element of Groups 6-10, wherein the weight ratio of the first catalyst over the second catalyst is in the range of 5:95 to 75:25 and wherein the first catalyst is located in front of the second catalyst when they are brought into contacting with the C9+ aromatic feedstock and the C6-C7 aromatic feedstock in the present of hydrogen.Type: ApplicationFiled: October 10, 2008Publication date: April 30, 2009Inventor: Doron Levin
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Patent number: 7524788Abstract: Process for preparing alkylated aromatic compounds which comprises reacting an aromatic compound with a ketone and hydrogen in the presence of a catalytic composition comprising a solid acid material and copper. A preferred aspect is to use a catalytic composition also containing one or more elements selected from elements of groups IIIA, IVA, IIIB, IVB, VB, VIB, VIIB, group VIII limited to Fe, Ru and Os, and of the series of lanthanides. A particularly preferred aspect is to use a catalytic composition containing one or more elements selected from elements of groups IIIA and VIB.Type: GrantFiled: December 18, 2002Date of Patent: April 28, 2009Assignee: Polimeri Europa S.p.A.Inventors: Gianni Girotti, Franco Rivetti, Stefano Ramello
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Publication number: 20090099007Abstract: A prolongated silica bound zeolite support comprising from about 85 wt % to about 95 wt % zeolite. A catalyst composition comprising a prolongated silica bound zeolite supporting at least one Group VIII metal and at least one halide. A process of making a prolongated silica bound zeolite support comprising mixing a zeolite, a prolongated silica, and water to form a mixture, and shaping the mixture into the prolongated silica bound zeolite support. A process of making a prolongated silica bound zeolite catalyst comprising mixing a zeolite, a prolongated silica, and water to form a mixture, shaping the mixture into a prolongated silica bound zeolite support, and adding one or more catalytic compounds to the prolongated silica bound zeolite support to form the prolongated silica bound zeolite catalyst.Type: ApplicationFiled: October 11, 2007Publication date: April 16, 2009Inventor: Gyanesh P. Khare
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Patent number: 7517826Abstract: A multi-layer emission control catalyst exhibits improved CO and HC reduction performance. The bottom layer includes a supported catalyst comprising platinum and palladium particles or palladium and gold particles. The middle layer includes zeolites. The top layer includes a supported catalyst comprising platinum and palladium particles. The use of zeolite mixture in the middle layer further improves CO and HC reduction performance in comparison with using zeolite of a single type. The use of a supported catalyst comprising palladium and gold particles in the bottom layer further improves CO and HC reduction performance in comparison with using a supported catalyst comprising platinum and palladium particles.Type: GrantFiled: November 20, 2007Date of Patent: April 14, 2009Assignee: Nanostellar, Inc.Inventors: Kyle L. Fujdala, Timothy J. Truex
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Publication number: 20090093661Abstract: A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite having channels the opening to which is defined by a ring of 10 oxygen atoms (10 MR), at least one zeolite having channels the opening to which is defined by a ring of 12 oxygen atoms (12 MR) and at least one porous mineral matrix. Said catalyst optionally also contains at least one group VIII metal. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.Type: ApplicationFiled: December 1, 2006Publication date: April 9, 2009Inventors: Emmanuelle Guillon, Eric Sanchez, Sylvie Lacombe
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Publication number: 20090093662Abstract: One exemplary embodiment can be a catalyst for a C8 aromatic isomerization process. The catalyst can include: about 1-about 90%, by weight, of a zeolite including an MTW zeolite; about 10-about 99%, by weight, of a binder including a gamma-alumina, the gamma-alumina being derived from a Boehmite alumina; about 0.1-about 2%, by weight, of a noble metal, calculated on an elemental basis; and at least one alkali metal wherein a total alkali metal content of the catalyst is at least about 100 ppm, by weight, calculated on an elemental basis. Generally, the catalyst has a pore volume distribution and at least about 70% of a pore volume of the catalyst is defined by pores having a diameter greater than about 100 ?.Type: ApplicationFiled: October 8, 2007Publication date: April 9, 2009Inventors: Patrick C. Whitchurch, Paula L. Bogdan, John E. Bauer
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Publication number: 20090093660Abstract: One exemplary embodiment can be an extruded C8 alkylaromatic isomerization catalyst. The extruded catalyst can include: about 2-about 20%, by weight, of an MTW zeolite; about 80-about 98%, by weight, of a binder including an alumina; about 0.01-about 2.00%, by weight, of a noble group metal calculated on an elemental basis; and about 100 ppm-less than about 1000 ppm, by weight, of at least one alkali metal calculated on an elemental basis. Generally, the weight percents of the MTW zeolite, the binder, the noble group metal, and the at least one alkali metal are based on a weight of the extruded catalyst.Type: ApplicationFiled: December 28, 2007Publication date: April 9, 2009Inventors: Patrick C. Whitchurch, Paula L. Bogdan, John E. Bauer
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Patent number: 7510645Abstract: Increased yields of naphtha and increased catalyst activity are obtained in a hydrocracking process by the use of a catalyst containing a beta zeolite and a Y zeolite having a unit cell size from 24.38 to 24.50 angstrom. The catalyst has a relatively high amount of Y zeolite relative to beta zeolite.Type: GrantFiled: November 4, 2005Date of Patent: March 31, 2009Assignee: UOP LLCInventor: Li Wang
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Patent number: 7507684Abstract: The invention relates to an extruded solid catalyst body for breaking down nitrogen oxides in the presence of a reducing agent as well as to a process for manufacture of said body. The solid catalyst body has an active material that contains 60 to 87% by weight of an ion-exchanged zeolite containing at least one metal from the group containing Cu, Hf, La, Au, In, V, lanthanoids and transition metals of group VIII of the periodic system, more than 10 to 37% by weight of aluminum oxide and 2 to 10% by weight of inorganic fibers. The solid catalyst body, the active material of which contains a zeolite can be manufactured by extrusion and has a high degree of mechanical stability at a high catalytic activity.Type: GrantFiled: December 29, 2006Date of Patent: March 24, 2009Assignee: Argillon GmbHInventors: Lothar Hofmann, Jörg Münch, Ralf Dotzel
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Publication number: 20090050527Abstract: A NOx reduction composition and process of using the composition to reduce the content of NOx emissions and gas phase reduced nitrogen species released from the regeneration zone during fluid catalytic cracking of a hydrocarbon feedstock into lower molecular weight components is disclosed. The process comprises contacting a hydrocarbon feedstock during a fluid catalytic cracking (FCC) process wherein a regeneration zone of an fluid catalytic cracking unit (FCCU) is operated in a partial or incomplete combustion mode under FCC conditions, with a circulating inventory of an FCC cracking catalyst and a particulate NOx reduction composition. The NOx reduction composition has a mean particle size of greater than 45 ?m and comprises (1) a zeolite component having (i) a pore size of form 2-7 A Angstroms and (ii) a SiO2 to Al2O3 molar ratio of less than 500, and (2) at least one noble metal selected from the group consisting of platinum, palladium, rhodium, iridium, osmium, ruthenium, rhenium and mixtures thereof.Type: ApplicationFiled: March 24, 2006Publication date: February 26, 2009Inventors: M. Sundaram Krishnamoorthy, Michael Scott Ziebarth, George Yaluris, Roger Jean Lussier, John Allen Rudesill
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Publication number: 20090048477Abstract: A hydrocracking catalyst that solves the above-described problem comprises a carrier containing ultra-stable Y-type zeolite obtained by the ultrastabilization of NaY-type zeolite and a metal from group VIII of the Periodic Table supported on this carrier, and is characterized in that the NaY-type zeolite has a peak in its X-ray diffraction pattern in the range of 2?=28.0° to 28.5° and 2?=15.0° to 16.0°, and the intensity ratio I1/I2 is no greater than 0.05, letting I1 be the peak intensity observed in the range of 2?=28.0° to 28.5° and I2 be the peak intensity observed in the range of 2?=15.0° to 16.0°.Type: ApplicationFiled: March 14, 2007Publication date: February 19, 2009Inventors: Hiroyuki Seki, Masahiro Higashi, Sumio Saito, Ryuzo Kuroda, Takashi Kameoka
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Publication number: 20090042717Abstract: A catalyst for producing a liquefied petroleum gas according to the present invention comprises a Pd-based methanol synthesis catalyst component and a ?-zeolite catalyst component. It can be used in a reaction of carbon monoxide and hydrogen to give a hydrocarbon containing propane or butane as a main component, i.e., a liquefied petroleum gas, with high activity, high selectivity and high yield. Furthermore, the catalyst has a longer catalyst life with less deterioration.Type: ApplicationFiled: October 11, 2007Publication date: February 12, 2009Applicant: Japan Gas Synthesize, Ltd.Inventors: Kaoru Fujimoto, Kenji Asami, Sachio Asaoka, Xiaohong Li, Qianwen Zhang
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Patent number: 7485595Abstract: A molecular sieve-containing catalyst for cracking hydrocarbons, comprising molecular sieve, refractory inorganic oxide, clay and a metal component, wherein the amount of said molecular sieve is from 1 to 90% by weight, the refractory inorganic oxide is from 2 to 80% by weight, the clay is from 2 to 80% by weight, and the metal component is from 0.1 to 30% by weight, calculated as the oxide of said metal having its maximum valence state, based on the total amount of the catalyst, wherein said metal component exists essentially in a reduction state and is one or more metals selected from the group consisting of metals of Group IIIA (other than aluminum), and metals of Group IVA, VA, IB, IIB, VB, VIB and VIIB, and non-noble metals of Group VIII of the periodic table. The catalyst has higher cracking activity and higher sulfur reduction activity.Type: GrantFiled: May 28, 2004Date of Patent: February 3, 2009Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Jun Long, Yuxia Zhu, Huiping Tian, Yujian Liu, Zhenyu Chen, Yaoqing Guo, Zhijian Da, Jiushun Zhang, Mingyuan He