Zeolite Patents (Class 502/64)
  • Patent number: 10773965
    Abstract: The present invention concerns zeolites with hierarchical porosity having a molar ratio Si/Al of between 1 and 1.4, inclusive, of which the average diameter, as a number, is between 0.1 ?m and 20 ?m, having controlled and optimized crystallinity, and having mesoporosity such that the mesoporous outer surface area is between 40 m2·g?1 and 400 m2·g?1. The present invention also concerns the method for preparing said zeolites with hierarchical porosity.
    Type: Grant
    Filed: August 24, 2018
    Date of Patent: September 15, 2020
    Assignee: Arkema France
    Inventors: Serge Nicolas, Karine Lopez, Cécile Lutz, Ludivine Bouvier
  • Patent number: 10766018
    Abstract: The subject matter of the invention is a method for producing composites comprising aluminum oxide and cerium/zirconium mixed oxides, hereinafter referred to briefly as Al/Ce/Zr oxide composite(s) using boehmite and soluble cerium/zirconium salts. Al/Ce/Zr oxide composites produced in this way have an increased thermal stability.
    Type: Grant
    Filed: March 19, 2018
    Date of Patent: September 8, 2020
    Assignee: Sasol Germany GmbH
    Inventors: Marcos Schoneborn, Reiner Glockler, Anja Paeger
  • Patent number: 10751710
    Abstract: A method of making a multifunctional catalyst for upgrading pyrolysis oil includes contacting a zeolite support with a solution including at least a first metal catalyst precursor and a second metal catalyst precursor, the first metal catalyst precursor, the second metal catalyst precursor, or both, including a heteropolyacid. Contacting the zeolite support with the solution deposits or adsorbs the first metal catalyst precursor and the second catalyst precursor onto outer surfaces and pore surfaces of the zeolite support to produce a multifunctional catalyst precursor. The method further includes removing excess solution from the multifunctional catalyst precursor and calcining the multifunctional catalyst precursor to produce the multifunctional catalyst comprising at least a first metal catalyst and a second metal catalyst deposited on the outer surfaces and pore surfaces of the zeolite support.
    Type: Grant
    Filed: March 3, 2020
    Date of Patent: August 25, 2020
    Assignee: Saudi Arabian Oil Company
    Inventor: Miao Sun
  • Patent number: 10717917
    Abstract: Provided is a method of dispersing asphaltenes to inhibit asphaltene precipitation and/or deposition in a hydrocarbon. The method includes adding to the hydrocarbon an asphaltene dispersing agent which is an ester of a mono-carboxylic fatty acid and a sugar. The sugar has at least 4 hydroxyl groups. In addition, more than one of the hydroxyl groups on the sugar are reacted with the mono-carboxylic fatty acid to form the ester.
    Type: Grant
    Filed: June 20, 2017
    Date of Patent: July 21, 2020
    Assignee: Croda, Inc.
    Inventors: Xin Chen, Min Ma Wang, Craig Michael Sungail, Zhongqi Shen
  • Patent number: 10661260
    Abstract: Embodiments of zeolite composite catalysts and methods of producing the zeolite composite catalysts are provided, where the methods comprise dissolving in an alkaline solution a catalyst precursor comprising at least one mesoporous zeolite while heating, stirring, or both to yield a dissolved zeolite solution, where the mesoporous zeolite has a molar ratio of SiO2/Al2O3 of at least 30, where the mesoporous zeolite comprises zeolite beta, adjusting the pH of the dissolved zeolite solution, aging the pH adjusted dissolved zeolite solution to yield solid zeolite composite from the dissolved zeolite solution, and calcining the solid zeolite composite to produce the zeolite composite catalyst, where the zeolite composite catalyst has a mesostructure comprising at least one disordered mesophase and at least one ordered mesophase, and where the zeolite composite catalyst has a surface area defined by the Brunauer-Emmett-Teller (BET) analysis of at least 600 m2/g.
    Type: Grant
    Filed: June 15, 2017
    Date of Patent: May 26, 2020
    Assignees: King Fahd University of Petroleum and Minerals, Saudi Arabian Oil Company
    Inventors: Balasamy Rabindran Jermy, Syed Ahmed Ali, Raed Hasan Abudawoud, Abdullah Mohammed Aitani, Sulaiman Saleh Al-Khattaf
  • Patent number: 10654720
    Abstract: Recovering bromine from solid waste containing bromine compounds, and applications thereof, such as for recovering bromine in a form suitable for reuse, or for manufacturing bromine salt (for example, calcium bromide). Bromine recovery method and system include: providing and mixing (i) solid waste containing bromine compounds and (ii) solid calcium hydroxide; heating the mixture in a chemical reducing (non-oxidizing) environment, thereby forming heated product consisting essentially of only solid calcium bromide (salt); and processing the heated product, to form bromine. Calcium bromide manufacturing method and system include: providing and mixing (i) solid waste containing bromine compounds and (ii) solid calcium hydroxide; heating the mixture in a chemical reducing (non-oxidizing) environment, thereby forming solid calcium bromide (salt). Applicable to processes of, or involving, manufacturing bromine-based flame (fire) retardant materials.
    Type: Grant
    Filed: February 18, 2016
    Date of Patent: May 19, 2020
    Assignee: Elcon Recycling Center (2003) Ltd.
    Inventors: Zvi Elgat, Abraham Ben Menashe
  • Patent number: 10654773
    Abstract: The present invention is related to an integrated process for enhancing the yields of propylene and other light olefins from Fluid catalytic cracking (FCC) process in combination with Oxidative propane dehydrogenation (OPDH) where in a hydrocarbon stream from Propylene recovery section consisting of propane predominantly, is converted to high value light olefins primarily C3 and C2 olefins by catalytic oxidative dehydrogenation using carbon dioxide from FCC flue gas exiting the regenerator. Several process configurations for the conversion of C3 and C4 alkanes to their respective alkenes separately or simultaneously by integrating with FCC are provided.
    Type: Grant
    Filed: October 30, 2018
    Date of Patent: May 19, 2020
    Assignee: INDIAN OIL CORPORATION LIMITED
    Inventors: Hima Bindu Doosa, Ram Mohan Thakur, Vineeth Venu Nath, Kamlesh Gupta, Debasis Bhattacharyya, Sanjiv Kumar Mazumdar, Sankara Sri Venkata Ramakumar
  • Patent number: 10646856
    Abstract: A hydrothermal method of preparing uniform, monodisperse ceramic lanthanum hydroxyl carbonate (LaCO3OH) having cherry-blossom-like nanogears and/or nanocubes is described. The method produced a hexagonal crystal with a crystal lattice in which at least on lanthanum ion is substituted with calcium ion. The ceramic nanoparticles produced by the method are good catalyst for the reduction of nitrogen oxides with a hydrocarbon. A method of reducing exhaust gases is described.
    Type: Grant
    Filed: April 23, 2019
    Date of Patent: May 12, 2020
    Assignee: King Fahd University of Petroleum and Minerals
    Inventor: Md. Hasan Zahir
  • Patent number: 10646853
    Abstract: The present disclosure relates to methods for making chromium-containing dehydrogenation catalysts using chromium feedstocks that need not include chromium(VI). The disclosure also relates to the catalysts made thereby, as well as to dehydrogenation methods using such catalysts. In one aspect of the disclosure, a method includes providing a formable mixture comprising, on a dry basis, an aluminum hydroxide, present in an amount within the range of about 40 wt. % to about 90 wt. %; an acid (e.g., nitric acid), present in an amount within the range of about 2 wt. % to about 15 wt. %; and a chromium(III) source, present in an amount within the range of about 2 wt. % to about 35 wt. %; forming the formable mixture; and calcining the formed mixture. In certain embodiments, the method further includes impregnating the calcined mixture with an aqueous impregnation solution including a chromium(III) salt; and calcining the impregnated mixture.
    Type: Grant
    Filed: January 9, 2018
    Date of Patent: May 12, 2020
    Assignee: Clariant Corporation
    Inventor: Vladimir Fridman
  • Patent number: 10647925
    Abstract: Fuels and/or fuel blending components can be formed from hydroprocessing of high lift deasphalted oil. The high lift deasphalting can correspond to solvent deasphalting to produce a yield of deasphalted oil of at least 50 wt %, or at least 65 wt %, or at least 75 wt %. The resulting fuels and/or fuel blending components formed by hydroprocessing of the deasphalted oil can have unexpectedly high naphthene content and/or density. Additionally or alternately, deasphalted oil generated from high lift deasphalting represents a disadvantaged feed that can be converted into a fuel and/or fuel blending components with unexpected compositions. Additionally or alternately, the resulting fuels and/or fuel blending components can have unexpectedly beneficial cold flow properties, such as cloud point, pour point, and/or freeze point.
    Type: Grant
    Filed: December 27, 2016
    Date of Patent: May 12, 2020
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Sheryl B. Rubin-Pitel, Kenneth Kar, Kendall S. Fruchey
  • Patent number: 10610855
    Abstract: Process for preparing a hydrocracking catalyst carrier which process comprises subjecting a carrier comprising an amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10 to calcination at a temperature of from 700 to 900° C., hydrocracking catalyst carrier comprising amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10, the infrared spectrum of which catalyst has a peak at 3690 cm?1, substantially reduced peaks at 3630 cm?1 and 3565 cm?1 and no peak at 3600 cm?1, hydrocracking catalyst carrier comprising an amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10, which catalyst has an acidity as measured by exchange with perdeuterated benzene of at most 20 micromole/gram, hydrocracking catalyst derived from such carrier and hydrocracking process with the help of such catalyst.
    Type: Grant
    Filed: November 24, 2015
    Date of Patent: April 7, 2020
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Cornelis Ouwehand
  • Patent number: 10603652
    Abstract: Provided are: a silver-carrying zeolite molded article in which aggregation of silver is inhibited and which has excellent capability of dispersing silver, when compared to conventional silver-carrying zeolite molded articles; and a method for producing the silver-carrying zeolite molded article. In the silver-carrying zeolite molded article, the molar ratio of Si/Al2 is 2.0-3.0, the molar ratio of (alkali metal+Ag)/Al is 0.9-1.1, the total amount of SiO2, Al2O3, Ag2O, and alkali metal oxides is 90 wt % or more, the contained amount of silver ions is 5 wt % or more, and only a single type of zeolite is contained. The molded article can be produced by subjecting a zeolite molded article having zeolite purity of 90% or more to an ion exchange treatment using a silver-containing aqueous solution.
    Type: Grant
    Filed: February 23, 2017
    Date of Patent: March 31, 2020
    Assignee: TOSOH CORPORATION
    Inventors: Keisuke Tokunaga, Shigeru Hirano, Yoju Shimizu, Hajime Funakoshi
  • Patent number: 10537884
    Abstract: Methods for producing lactams from oximes by performing a Beckmann rearrangement using a hierarchical porous aluminophosphate catalyst having interconnected microporous and mesoporous networks are provided. Exemplary catalysts include a plurality of weak Brønsted acid active sites, including silicon-containing aluminophosphates having the IZA framework code AFI, such as SAPO-5, CHA, such as SAPO-34, and FAU, such as SAPO-37.
    Type: Grant
    Filed: October 16, 2018
    Date of Patent: January 21, 2020
    Assignees: AdvanSix Resins & Chemicals LLC, University of Southampton
    Inventors: Alan B. Levy, Robert Raja, Stephanie H. Newland, Scott R. Keenan, Simon R. Bare
  • Patent number: 10526546
    Abstract: According to one or more embodiments, a hydrocarbon feed stream may be cracked by a method comprising contacting the hydrocarbon feed stream with a cracking catalyst in a reactor unit. The hydrocarbon feed stream may have an API gravity of at least 40 degrees. The cracking catalyst may comprise one or more binder materials, one or more matrix materials, and *BEA framework type zeolite.
    Type: Grant
    Filed: February 15, 2018
    Date of Patent: January 7, 2020
    Assignee: Saudi Arabian Oil Company
    Inventors: Aaron Chi Akah, Anas Saleh Aqeeli
  • Patent number: 10518254
    Abstract: Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia.
    Type: Grant
    Filed: January 30, 2019
    Date of Patent: December 31, 2019
    Assignee: BASF Corporation
    Inventors: Joseph A. Patchett, Joseph C. Dettling, Elizabeth A. Przybylski
  • Patent number: 10512900
    Abstract: A hydrothermal method of preparing uniform, monodisperse ceramic lanthanum hydroxyl carbonate (LaCO3OH) having cherry-blossom-like nanogears and/or nanocubes is described. The method produced a hexagonal crystal with a crystal lattice in which at least on lanthanum ion is substituted with calcium ion. The ceramic nanoparticles produced by the method are good catalyst for the reduction of nitrogen oxides with a hydrocarbon. A method of reducing exhaust gases is described.
    Type: Grant
    Filed: April 23, 2019
    Date of Patent: December 24, 2019
    Assignee: King Fahd University of Petroleum and Minerals
    Inventor: Md. Hasan Zahir
  • Patent number: 10322409
    Abstract: A hydrothermal method of preparing uniform, monodisperse ceramic lanthanum hydroxyl carbonate (LaCO3OH) having cherry-blossom-like nanogears and/or nanocubes is described. The method produced a hexagonal crystal with a crystal lattice in which at least on lanthanum ion is substituted with calcium ion. The ceramic nanoparticles produced by the method are good catalyst for the reduction of nitrogen oxides with a hydrocarbon. A method of reducing exhaust gases is described.
    Type: Grant
    Filed: March 5, 2018
    Date of Patent: June 18, 2019
    Assignee: King Fahd University of Petroleum and Minerals
    Inventor: Md. Hasan Zahir
  • Patent number: 10286388
    Abstract: A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-53. This zeolite is represented by the empirical formula: M+mRrAl1-xExSiyOz where M represents sodium, potassium or a combination of sodium and potassium cations, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-53 have utility in various hydrocarbon conversion reactions.
    Type: Grant
    Filed: November 9, 2018
    Date of Patent: May 14, 2019
    Inventors: Christopher P. Nicholas, Mark A. Miller
  • Patent number: 10265686
    Abstract: The invention therefore relates to a method for producing zeolite, zeolite-like or zeotype encapsulated metal nanoparticles, the method comprises the steps of: 1) Adding one or more metal precursors to a silica or alumina source; 2) Reducing the one or more metal precursors to form metal nanoparticles on the surface of the silica or alumina source; 3) Passing a gaseous hydrocarbon, alkyl alcohol or alkyl ether over the silica or alumina supported metal nanoparticles to form a carbon template coated zeolite, zeolite-like or zeotype precursor composition; 4a) Adding a structure directing agent to the carbon template coated zeolite, zeolite-like or zeotype precursor composition thereby creating a zeolite, zeolite-like or zeotype gel composition; 4b) Crystallising the zeolite, zeolite-like or zeotype gel composition by subjecting said composition to a hydrothermal treatment; 5) Removing the carbon template and structure directing agent and isolating the resulting zeolite, zeolite-like or zeotype encapsulated meta
    Type: Grant
    Filed: July 7, 2014
    Date of Patent: April 23, 2019
    Assignee: DANMARKS TEKNISKE UNIVERSITET
    Inventors: Søren Kegnæs, Jacob Oskar Abildstrøm, Jerrik Jørgen Mielby, Agata Gallas-Hulin
  • Patent number: 10266416
    Abstract: The invention relates to a method for producing zeolite, zeolite-like or zeotype particles comprising the steps of: 1) Adding one or more metal precursors to a silica or alumina source; 2) Reducing the one or more metal precursors to form metal nanoparticles on the surface of the silica or alumina source; 3) Passing a gaseous hydrocarbon, alkyl alcohol or alkyl ether over the silica or alumina supported metal nanoparticle to form a carbon template coated zeolite, zeolite-like or zeotype precursor composition; 4a) Adding a structure directing agent to the carbon template coated zeolite, zeolite-like or zeotype precursor composition thereby creating a zeolite, zeolite-like or zeotype gel composition; 4b) Crystallizing the zeolite, zeolite-like or zeotype gel composition by subjecting said composition to a hydrothermal treatment; 5) Removing the carbon template and structure directing agent and isolating the resulting zeolite, zeolite-like or zeotype particles.
    Type: Grant
    Filed: July 7, 2014
    Date of Patent: April 23, 2019
    Assignee: DANMARKS TEKNISKE UNIVERSITET
    Inventors: Søren Kegnæs, Jacob Oskar Abildstrøm, Jerrik Jørgen Mielby
  • Patent number: 10252250
    Abstract: A process of producing a catalyst based on pentasil-type crystalline aluminosilicate is described, including the steps of (a) treating hydrous aluminum oxide with an aqueous, acid-containing medium, (b) mixing the hydrous aluminum oxide treated with aqueous, acid-containing medium from step (a) with an H-zeolite and (c) calcining the mixture obtained in step (b). In addition, a catalyst is disclosed which is obtained by such a process, as well as its use in CMO and OTO processes.
    Type: Grant
    Filed: July 8, 2011
    Date of Patent: April 9, 2019
    Inventors: Gotz Burgfels, Manfred Frauenrath, Sven Pohl, Martin Rothamel, Stephane Haag
  • Patent number: 10213772
    Abstract: A hydrocracking catalyst is provided comprising: a) greater than 10 wt % of a zeolite USY having: i. a total OD acidity of 0.350 to 0.650 mmol/g; ii. an ASDI between 0.05 and 0.15; iii. a BET surface area greater than 600 m2/g; iv. a SAR greater than 10; v. less than 45 vol % of pores greater than 2 nm; b) a support; and c) at least one metal selected from the group consisting of elements from Group 6 and Groups 8 through 10 of the Periodic Table. A process for hydrocracking using a hydrocracking catalyst to produce middle distillates is provided. A method for making a hydrocracking catalyst is also provided.
    Type: Grant
    Filed: April 10, 2015
    Date of Patent: February 26, 2019
    Assignee: Chevron U.S.A. Inc.
    Inventors: Yihua Zhang, Theodorus Ludovicus Michael Maesen, Andrew Rainis, Bao Quoc Le
  • Patent number: 10201806
    Abstract: The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, wherein the catalyst displays a water uptake of 9.0 wt.-% or less, as well as to a process for the production thereof and to its use, in particular in a process for converting oxygenates to olefins.
    Type: Grant
    Filed: December 18, 2014
    Date of Patent: February 12, 2019
    Assignee: BASF SE
    Inventors: Kirsten Braunsmann, Bernd Bastian Schaack, Ekkehard Schwab, Manuela Gaab, Mathias Feyen
  • Patent number: 10183282
    Abstract: A second-stage hydrocracking catalyst is provided comprising: a. from 40 wt % to 70 wt % of a zeolite USY having an ASDI from 0.05 to 0.18; b. an amorphous silica alumina; c. a second alumina; and d. 0.1 to 10 wt % noble metal; wherein the second-stage hydrocracking catalyst has a BET surface area from 450 to 650 m2/g. A second-stage hydrocracking process is provided comprising using the second-stage hydrocracking catalyst to produce middle distillate. A method for making the second-stage hydrocracking catalyst is also provided.
    Type: Grant
    Filed: January 22, 2015
    Date of Patent: January 22, 2019
    Assignee: Chevron U.S.A. Inc.
    Inventors: Jifei Jia, Andrew Rainis, Theodorus Ludovicus Michael Maesen, Richard Coser, Yihua Zhang
  • Patent number: 10115844
    Abstract: An electrode includes a network of compressed interconnected nanostructured carbon particles such as carbon nanotubes. Some nanostructured carbon particles of the network are in electrical contact with adjacent nanostructured carbon particles. Electrodes may be used in various devices, such as capacitors, electric arc furnaces, batteries, etc. A method of producing an electrode includes confining a mass of nanostructured carbon particles and densifying the confined mass of nanostructured carbon particles to form a cohesive body with sufficient contacts between adjacent nanostructured carbon particles to provide an electrical path between at least two remote points of the cohesive body. The electrodes may be sintered to induce covalent bonding between the nanostructured carbon particles at contact points to further enhance the mechanical and electrical properties of the electrodes.
    Type: Grant
    Filed: March 12, 2014
    Date of Patent: October 30, 2018
    Assignee: SEERSTONE LLC
    Inventor: Dallas B. Noyes
  • Patent number: 10105690
    Abstract: A catalyst composition includes a zeolite, a binder, and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition comprising about 50 wt % or less of the binder based on a total weight of the catalyst composition, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10?2 sec?1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: October 23, 2018
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Stephen J. McCarthy, Rohit Vijay, Brett Loveless
  • Patent number: 10099209
    Abstract: A catalyst composition comprising a zeolite, an alumina binder, and a Group 12 transition metal selected from Zn and/or Cd, the zeolite having a Si/Al ratio of at least about 10 and a micropore surface area of at least about 340 m2/g, the catalyst composition comprising about 50 wt % or less of the binder, based on a total weight of the catalyst composition, and having a micropore surface area of at least about 290 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: a mesoporosity of about 20 m2/g to about 120 m2/g; a diffusivity for 2,2-dimethylbutane of greater than about 1×10?2 sec?1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (8 kPa); and a combined micropore surface area and mesoporosity of at least about 380 m2/g.
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: October 16, 2018
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Stephen J. McCarthy, Rohit Vijay, Brett Loveless
  • Patent number: 10040056
    Abstract: To provide a method for preparing a visible light-responsive photocatalyst and a visible light-responsive photocatalyst intermediate, a usage of a visible light-responsive photocatalyst, and the visible light-responsive photocatalyst, the method enabling arbitrary setting of the amount of solvent, thus making it possible to prepare composite fine particles of gold colloids and titanium oxide fine particles in high yield. A method for preparing a visible light-responsive photocatalyst or a visible light-responsive photocatalyst intermediate includes the step of forming a disperse system including an oil liquid containing an organic titanium complex as a dispersant, and an aqueous dispersion containing gold colloids as a dispersoid, and the visible light-responsive photocatalyst or the visible light-responsive photocatalyst intermediate enables the organic titanium complex to undergo hydrolysis to cause clathration of gold colloids, thus forming a clathrate.
    Type: Grant
    Filed: March 7, 2014
    Date of Patent: August 7, 2018
    Assignee: KANAGAWA UNIVERSITY
    Inventors: Kazuo Tajima, Yoko Imai
  • Patent number: 10022710
    Abstract: An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.
    Type: Grant
    Filed: October 28, 2014
    Date of Patent: July 17, 2018
    Assignee: FINA TECHNOLOGY, INC.
    Inventors: Sivadinarayana Chinta, Joseph E. Pelati
  • Patent number: 9975112
    Abstract: New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.
    Type: Grant
    Filed: December 15, 2015
    Date of Patent: May 22, 2018
    Assignee: ENI S.P.A.
    Inventors: Giuseppe Bellussi, Angela Carati, Maria Federica Gagliardi, Stefano Zanardi, Marcello Marella, Roberto Scattolin, Michele Tomaselli
  • Patent number: 9908111
    Abstract: The invention provides a mixed molecular sieve catalyst, comprising 5-30 wt % Y molecular sieve, 5-30 wt % ZSM-5 molecular sieve and the balance of matrix component and binder component. The invention further provides a method of preparing the mixed molecular sieve catalyst, comprising the following steps: mixing the Y molecular sieve, the ZSM-5 molecular sieve with a matrix material, a binder precursor, a pore former, a dispersant and water to formulate an aqueous slurry; spray drying the slurry; and baking. The invention further provides a method of preparing olefins from methanol with the use of the catalyst. By use of the catalyst of the invention, the selectivity to C3 and C4 olefins is improved significantly.
    Type: Grant
    Filed: April 8, 2014
    Date of Patent: March 6, 2018
    Assignee: SHANGHAI BI KE CLEAN ENERGY TECHNOLOGY CO., LTD.
    Inventors: Fan Zhang, Yijun Wang, Guo Rui, Yongsheng Gan, Xiaomang Zhang
  • Patent number: 9896628
    Abstract: A hydrocracking catalyst having a support of a composite of mesoporous materials, molecular sieves and alumina, is used in the last bed of a multi-bed system for treating heavy crude oils and residues and is designed to increase the production of intermediate distillates having boiling points in a temperature range of 204° C. to 538° C., decrease the production of the heavy fraction (>538° C.), and increase the production of gasoline fraction (<204° C.). The feedstock to be processed in the last bed contains low amounts of metals and is lighter than the feedstock that is fed to the first catalytic bed.
    Type: Grant
    Filed: November 6, 2013
    Date of Patent: February 20, 2018
    Assignee: Instituto Mexicano del Petroleo
    Inventors: Patricia Rayo Mayoral, Jorge Ancheyta Juarez, Gustavo Jesus Marroquin Sanchez, Guillermo Centeno Nolasco, Jorge Fernando Ramirez Solis
  • Patent number: 9862897
    Abstract: The method for producing a monocyclic aromatic hydrocarbon includes a cracking and reforming reaction step in which a catalyst for producing a monocyclic aromatic hydrocarbon containing crystalline aluminosilicate which has been subjected to a heat treatment in an atmosphere containing water vapor in advance is loaded into a fixed-bed reactor, and a feedstock oil having a 10 volume % distillate temperature of 140° C. or higher and a 90 volume % distillate temperature of 390° C. or lower is brought into contact with the catalyst to cause a reaction, so as to obtain a product containing a monocyclic aromatic hydrocarbon having 6 to 8 carbon atoms.
    Type: Grant
    Filed: February 21, 2014
    Date of Patent: January 9, 2018
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Yasuyuki Iwasa, Shinichiro Yanagawa, Masahide Kobayashi
  • Patent number: 9844771
    Abstract: To provide a hydrocarbon reforming/trapping material which is capable of adsorbing and reforming a hydrocarbon. A hydrocarbon reforming/trapping material of the present invention has an SiO2/Al2O3 ratio of from 7 to 12, and contains an Fe(II)-substituted beta zeolite which is ion-exchanged by Fe(II) ions. The amount of supported Fe(II) is preferably 0.001-0.5 mmol/g with respect to the Fe(II)-substituted beta zeolite. This Fe(II)-substituted beta zeolite is suitably produced by dispersing and mixing a beta zeolite having an SiO2/Al2O3 ratio of from 7 to 12 in an aqueous solution of a water-soluble compound of divalent iron, and mixing and stirring the solution, so that Fe(II) ions are supported on the beta zeolite.
    Type: Grant
    Filed: March 10, 2014
    Date of Patent: December 19, 2017
    Assignees: UniZeo Co., Ltd., THE UNIVERSITY OF TOKYO
    Inventors: Masaru Ogura, Keiji Itabashi, Tatsuya Okubo, Kiyofumi Monma, Palani Elangovan Shanmugam
  • Patent number: 9744530
    Abstract: The present disclosure relates to a method for treating a catalyst that is useful for producing mono-alkylaromatic compounds, the method comprises the steps of (a) contacting the untreated catalyst with water to produce water-contacted catalyst, and (b) drying the water-contacted catalyst with a drying gas without steam being formed at a temperature of less than 300° C. to produce a treated catalyst. The treatment is effective to improve the activity and catalyst selectivity. A process for producing a mono-alkylaromatic compound comprising such a catalyst treatment is also disclosed.
    Type: Grant
    Filed: April 22, 2014
    Date of Patent: August 29, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Matthew J. Vincent, Terry E. Helton, Dominick A. Zurlo
  • Patent number: 9744519
    Abstract: The present invention relates to spherical agglomerates based on zeolite(s) and clay(s), having controlled size and morphology, in particular a size of less than or equal to 600 ?m, very good sphericity, and a high content of zeolitic material, to the process for the production thereof. These agglomerates are particularly suitable for uses in gas-phase and/or liquid-phase adsorption processes.
    Type: Grant
    Filed: June 2, 2008
    Date of Patent: August 29, 2017
    Assignee: ARKEMA FRANCE
    Inventors: Cecile Lutz, Sylvie Szendrovics, Quitterie Persillon
  • Patent number: 9708548
    Abstract: The invention relates to a method for hydroprocessing hydrocarbon feedstocks, said process comprising contacting a hydrocarbon feedstock under hydroprocessing conditions with a bulk catalyst composition comprising bulk metal particles that comprise at least one Group VIII non-noble metal, at least one Group VIB metal and nanoparticles. The bulk metal catalyst composition comprises bulk metal particles that may be prepared by a manufacturing process comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 ?m upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles.
    Type: Grant
    Filed: December 2, 2008
    Date of Patent: July 18, 2017
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Stuart L. Soled, Sabato Miseo, Sona Eijsbouts-Spickova, Robertus Gerardus Leliveld, Paul Joseph Maria Lebens, Frans Lodewijk Plantenga, Bob Gerardus Oogjen, Henk-Jan Tromp
  • Patent number: 9676982
    Abstract: A particulate material having a body including a first phase having at least about 70 wt % alumina for a total weight of the first phase, and a second phase comprising phosphorus, wherein the body includes at least about 0.1 wt % of the second phase for the total weight of the body, and wherein the second phase has an average grain size of not greater than about 1 micron.
    Type: Grant
    Filed: June 2, 2015
    Date of Patent: June 13, 2017
    Assignee: SAINT-GOBAIN CERAMICS & PLASTICS, INC.
    Inventors: Tracy H. Panzarella, Doruk O. Yener, Michael D. Kavanaugh, Alan J. Brandes
  • Patent number: 9616417
    Abstract: A catalyst for the conversion of oxygenates, such as alcohols or ethers, to olefins consists essentially of a selected SUZ-4 zeolite that has a Si/Al ratio of at least 20, preferably between 20 and 500, especially between 20 and 100. The basic SUZ-4 zeolite is prepared in a manner known per se, whereafter the Si/Al ratio is increased to the desired value. The selected SUZ-4 zeolite catalyst of the invention has a longer life time and a better product selectivity than the conventional/standard SUZ-4 zeolite catalysts.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: April 11, 2017
    Assignee: Haldor Topsoe A/S
    Inventors: Shewangizaw Teketel, Stian Svelle, Pablo Beato
  • Patent number: 9597663
    Abstract: An exhaust cleaning catalyst, with which precious metal sintering is inhibited and which has greater exhaust cleaning abilities, has a substrate and a catalyst coating layer provided on the substrate. The catalyst coating layer has a precious metal that serves as an oxidation and/or reduction catalyst. The precious metal has Rh-containing metal particles in which rhodium (Rh) coexists with a base metal selected among platinum group elements excluding rhodium. The Rh-containing metal particles have an average rhodium content of 0.1% to 5% by mole with the total amount of the base metal and rhodium being 100% by mole.
    Type: Grant
    Filed: December 8, 2014
    Date of Patent: March 21, 2017
    Assignee: CATALER CORPORATION
    Inventors: Satoru Inoda, Akimasa Hirai, Kenichi Taki, Satoshi Matsueda
  • Patent number: 9573124
    Abstract: A new crystalline molecular sieve designated SSZ-95 is disclosed. In general, SSZ-95 is synthesized from a reaction mixture suitable for synthesizing MTT-type molecular sieves and maintaining the mixture under crystallization conditions sufficient to form product. The product molecular sieve is subjected to a pre-calcination step, and ion-exchange to remove extra-framework cations, and a post-calcination step. The molecular sieve has a MTT-type framework and a H-D exchangeable acid site density of 0 to 50% relative to molecular sieve SSZ-32.
    Type: Grant
    Filed: May 21, 2014
    Date of Patent: February 21, 2017
    Assignee: Chevron U.S.A. Inc.
    Inventors: Adeola Florence Ojo, Yihua Zhang, Stacey Ian Zones, Guan-Dao Lei
  • Patent number: 9527064
    Abstract: The present invention provides a method for producing a silica composite by the steps of: preparing a raw material mixture containing silica and zeolite; drying the raw material mixture to obtain a dried product; and calcining the dried product, wherein the method comprising the step of allowing the raw material mixture to contain phosphoric acid and/or phosphate or bringing a solution of phosphoric acid and/or phosphate into contact with the zeolite and/or the dried product, or a combination thereof to thereby adjust a phosphorus content in the silica composite to 0.01 to 1.0% by mass based on the total mass of the silica composite.
    Type: Grant
    Filed: November 24, 2011
    Date of Patent: December 27, 2016
    Assignee: ASAHI KASEI KABUSHIKI KAISHA
    Inventors: Kenji Akagishi, Ryusuke Miyazaki
  • Patent number: 9528420
    Abstract: Catalyst diagnostic limit parts and methods for making catalyst diagnostic limit parts are disclosed. An exemplary catalyst diagnostic limit part includes a substrate and a washcoat coating the substrate. The washcoat includes an active catalyst and an inactive catalyst at a predetermined ratio of active catalyst to inactive catalyst so as to control the performance of the catalyst diagnostic limit part.
    Type: Grant
    Filed: September 23, 2014
    Date of Patent: December 27, 2016
    Assignee: CUMMINS EMISSION SOLUTIONS, INC.
    Inventors: Qiang Liu, Yi Liu, Zheng Liu, Arvind V. Harinath, Huiling Li
  • Patent number: 9505681
    Abstract: A process for isomerizing an aromatic cut containing at least one aromatic compound containing eight carbon atoms per molecule, which includes bringing the aromatic cut into contact with a catalyst containing a zeolite with structure type EUO, which catalyst has been prepared by obtaining a zeolite with structure type EUO having an overall Si/Al atomic ratio in the range 5 to 45, a sodium content in the range 500 to 5000 ppm by weight, with a Na/Al ratio in the range 5% to 20% by mole, and thereafter performing the following: i) preparing a support by shaping the zeolite with a matrix such that the zeolite content is in the range 8% to 15% by weight with respect to the support; ii) depositing at least one metal from group VIII of the periodic classification of the elements onto the support or onto the zeolite; wherein the catalyst contains a final sodium content of 75 to 600 ppm by weight.
    Type: Grant
    Filed: November 12, 2013
    Date of Patent: November 29, 2016
    Assignee: IFP Energies nouvelles
    Inventors: Emmanuelle Guillon, Laure Brandhorst
  • Patent number: 9403155
    Abstract: The present invention concerns a novel additive composition for reducing sulfur content of a catalytically cracked gasoline fraction. This additive composition comprises a support consisting of porous clay into which a first metal from group IVB is incorporated and a second metal from group IIB is impregnated. Preferably, the first incorporated metal is zirconium and the second impregnated metal is zinc. The sulfur reduction additive is used in the form of a separate particle in combination with a conventional cracking catalyst in a fluidized catalytic cracking process to convert hydrocarbon feed stocks into gasoline having comparatively lower sulfur content and other liquid products.
    Type: Grant
    Filed: February 7, 2013
    Date of Patent: August 2, 2016
    Assignees: SAUDI ARABIAN OIL COMPANY, KING FAHD UNIVERSITY OF PETROLEUM AND MINERAL
    Inventors: Christopher F. Dean, Musaed Salem Musaed Al-Ghrami Al-Ghamdi, Khurshid K. Alam, Mohammed Abdul Bari Siddiqui, Shakeel Ahmed
  • Patent number: 9382170
    Abstract: The present invention provides an improved process for producing an alkylated aromatic compound from an at least partially untreated alkylatable aromatic compound having catalyst poisons and an alkylating agent, wherein said alkylatable aromatic compound stream is treated to reduce catalyst poisons with a treatment composition having a surface area/surface volume ratio of greater than or equal to 30 in?1 (12 cm?1) in a treatment zone separate from an alkylation reaction zone under treatment conditions including a temperature of from about 30° C. to about 300° C. to form an effluent comprising said treated alkylatable aromatic compound.
    Type: Grant
    Filed: December 28, 2015
    Date of Patent: July 5, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Matthew J. Vincent, Vijay Nanda, Terry E. Helton
  • Patent number: 9278342
    Abstract: A method of modifying a phosphorus-treated zeolite catalyst is carried out by contacting an unbound and calcined phosphorus-treated pentasil zeolite with water in a water treatment wherein at least a portion of the water is in a liquid phase. The water treatment is sufficient to remove at least 80% by weight or more of phosphorus from the phosphorus-treated zeolite and provide an increase in the pore volume of the zeolite by at least 50% prior to the water treatment to form a modified phosphorus-treated zeolite catalyst. A zeolite catalyst is also provided in the form of a phosphorus-containing pentasil zeolite having a phosphorus content of 7.5% or less by weight of zeolite and a 27Al MAS NMR peak at 50 ppm that is greater than any other 27Al MAS NMR and a pore volume of 0.2 ml/g or more.
    Type: Grant
    Filed: July 2, 2012
    Date of Patent: March 8, 2016
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventor: Ashim Kumar Ghosh
  • Patent number: 9168509
    Abstract: The present disclosure provides a hydrogenation catalyst, the preparation process thereof and the application thereof in the production of 1,4-butanediol by hydrogenating dialkyl maleate and/or dialkyl succinate. The catalyst comprises Cu—Al-A-B—O, wherein A comprises at least one of Zn, Mo and W, B comprises at least one of Ba, Mn, Mg, Ti, Ce and Zr. In the process for preparing said hydrogenation catalyst, a part of Cu and A are precipitated first and the rest of Cu, Al and B are precipitated successively.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: October 27, 2015
    Assignees: China Petroleum & Chemical Corp., Fushun Research Institute of Petroleum
    Inventors: Yanxia Zhang, Shenghua Yuan, Peng Gao, Hao Zhang, Qiuhong Fu, Ri Duan
  • Patent number: 9162899
    Abstract: The present invention provides a method for preparing a BaX type zeolite granules comprising: adding a carbohydrate-based molding promoter to NaX type zeolite powder and thereto subsequently spraying and blending alumina sol and silica sol to form granules of the mixture; heating the formed granules to convert the alumina and silica component to aluminosilica so as to generate pores inside the formed granules; hydrothermally treating the resulted granules in a sodium hydroxide aqueous solution under the conditions for zeolite synthesis, thereby converting a portion of the aluminosilica to zeolite; and carrying out ion-exchanging by Ba ions. The present invention also provides BaX type zeolite granules which have excellent strength and can be suitably used as an adsorbent in simulated moving bed (SMB) application.
    Type: Grant
    Filed: July 3, 2012
    Date of Patent: October 20, 2015
    Assignee: SAMSUNG TOTAL PETROCHEMICALS CO., LTD.
    Inventors: Jeong Kwon Suh, Beom Sik Kim, Yun Ho Jeong, Jin Suk Lee, Won Young Kim, Ho Sik Chang
  • Patent number: 9126181
    Abstract: An aromatic alkylation catalyst is presented. The aromatic alkylation catalyst comprised a zeolite, an inorganic oxide, and silanol functional groups of less than about 0.65 area/mg on the surface of the catalyst.
    Type: Grant
    Filed: August 22, 2013
    Date of Patent: September 8, 2015
    Assignee: UOP LLC
    Inventor: Deng-Yang Jan