Mordenite Type Patents (Class 502/78)
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Patent number: 8353155Abstract: A catalyst system comprising a first catalytic composition comprising a first catalytic material disposed on a metal inorganic support; wherein the metal inorganic support has pores; and at least one promoting metal. The catalyst system further comprises a second catalytic composition comprising, (i) a zeolite, or (ii) a first catalytic material disposed on a first substrate, the first catalytic material comprising an element selected from the group consisting of tungsten, titanium, and vanadium. The catalyst system may further comprise a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. A catalyst system comprising a first catalytic composition, the second catalytic composition, and the third catalytic composition is also provided. An exhaust system comprising the catalyst systems described herein is also provided.Type: GrantFiled: August 31, 2009Date of Patent: January 15, 2013Assignee: General Electric CompanyInventors: Larry Neil Lewis, Benjamin Hale Winkler, Dan Hancu, Daniel George Norton, Ashish Balkrishna Mhadeshwar
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Patent number: 8349754Abstract: The invention relates to a modified zeolite catalyst, useful for the conversion of paraffins, olefins and aromatics in a mixed feedstock such as FCC gasoline that contain high content of olefin, aromatic and n-paraffin into isoparaffins. The invention further relates to the use of such a catalyst, for example but not limited to, in a process for the conversion of paraffins, olefins and aromatics in a mixed feedstock into the product having high amount of branched paraffins with decreased aromatics and olefins, a useful gasoline blend, with negligible production of lighter gases.Type: GrantFiled: March 6, 2009Date of Patent: January 8, 2013Assignee: Council of Scientific & Industrial ResearchInventors: Viswanadham Nagabhatla, Raviraj Kamble, Amit Sharma, Jagdish Kumar, Bhagwan Singh Negi, Murali Dhar Gudimella, Madhukar Onkarnath Garg
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Publication number: 20130005564Abstract: Composites of a crystalline or long-ranged ordered material (CLROM), for example zeolites and non-zeolitic molecular sieves, are disclosed. The composites have both a macroscopic particle size (e.g., an average particle size of greater than about 0.1 mm), as desired in commercial applications, as well as improved functionality. Such composites result from the conversion of a conventional amorphous material, for example a solid amorphous silica alumina of this particle size, into the CLROM. According to particular embodiments, all or substantially all (e.g., at least about 99%) of the amorphous material is converted to the CLROM, such that essentially the entire macroscopic material may have the desired functionality of the CLROM as a catalyst or adsorbent.Type: ApplicationFiled: June 30, 2011Publication date: January 3, 2013Applicant: UOP LLCInventors: RICHARD R. WILLIS, ANNABELLE BENIN, HUI WANG, STEPHEN WILSON
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Patent number: 8334230Abstract: A honeycomb structure includes at least one honeycomb unit which includes walls. The walls have a thickness of from about 0.10 mm to about 0.50 mm and extend along a longitudinal direction of the honeycomb structure to define through-holes. The honeycomb structure has a center area inside a boundary line passing through positions located at substantially a half of a length from a center of the honeycomb structure to a periphery of the honeycomb structure in a cross section perpendicular to the longitudinal direction. The honeycomb structure has a peripheral area outside the boundary line. A thickness of the walls located in the peripheral area is larger than a thickness of the walls located in the center area. A first opening ratio in the center area in the cross section is larger than a second opening ratio in the peripheral area in the cross section.Type: GrantFiled: July 22, 2009Date of Patent: December 18, 2012Assignee: Ibiden Co., Ltd.Inventors: Kazushige Ohno, Masafumi Kunieda, Takahiko Ido
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Patent number: 8283273Abstract: A metal-modified alkylation catalyst including a metal/zeolite is provided where the metal is one or two selected from the group consisting of yttrium and a rare earth of the lanthanide series other than cerium. Where two metals are used, one may be Ce or La. The metal-promoted zeolite is useful as a molecular sieve aromatic alkylation catalyst for the production of ethylbenzene by the ethylation of benzene in the liquid phase or critical phase. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 10-60 wt % of the ethylbenzene.Type: GrantFiled: March 31, 2010Date of Patent: October 9, 2012Assignee: Fina Technology, Inc.Inventors: Kevin Kelly, James Butler
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Publication number: 20120252658Abstract: A honeycomb structure includes a honeycomb unit containing zeolite and an inorganic binder and having a plurality of cell walls to define a plurality of cells extending from a first end face to a second end face of the honeycomb unit along a longitudinal direction of the honeycomb unit. The honeycomb unit is manufactured by molding and firing raw material paste containing zeolite particles and the inorganic binder. The zeolite particles have a D50 of approximately 3.6 ?m or more. An average pore size of the cell walls is more than or equal to approximately 0.10 ?m and less than or equal to approximately 0.50 ?m. An average particle size of the cell walls is more than or equal to approximately 3.6 ?m and less than or equal to approximately 7.0 ?m.Type: ApplicationFiled: November 24, 2011Publication date: October 4, 2012Applicant: IBIDEN CO., LTD.Inventors: Masafumi KUNIEDA, Yosuke Matsukawa
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Patent number: 8262902Abstract: Methods and apparatus relate to processing of petroleum with a bed having a sorbent based diluent that the petroleum contacts upon passing through the bed. Magnetic properties of the sorbent and any other material, such as zeolite, used in the bed enable separation of such bed constituents based on a sulfided form of the sorbent being magnetic in contrast to a non-sulfided form of the sorbent being non-magnetic. Dividing the bed constituents into first and second portions by magnetic separation facilitates in selective replacing and/or regenerating the first portion independent of the second portion.Type: GrantFiled: February 17, 2010Date of Patent: September 11, 2012Assignee: Phillips 66 CompanyInventors: Sundararajan Uppili, Donald R. Engelbert
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Publication number: 20120222555Abstract: A gas separation process uses a structured particulate bed of adsorbent coated shapes/particles laid down in the bed in an ordered manner to simulate a monolith by providing longitudinally extensive gas passages by which the gas mixture to be separated can access the adsorbent material along the length of the particles. The particles can be laid down either directly in the bed or in locally structured packages/bundles which themselves are similarly oriented such that the bed particles behave similarly to a monolith but without at least some disadvantages. The adsorbent particles can be formed with a solid, non-porous core with the adsorbent formed as a thin, adherent coating on the exposed exterior surface. Particles may be formed as cylinders/hollow shapes to provide ready access to the adsorbent. The separation may be operated as a kinetic or equilibrium controlled process.Type: ApplicationFiled: February 27, 2012Publication date: September 6, 2012Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Ramesh Gupta, Harry W. Deckman, Daniel P. Leta
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Patent number: 8252709Abstract: An object of the present invention is to provide a catalyst for hydrodesulfurization/dewaxing of a hydrocarbon oil, with which sulfur compounds in the hydrocarbon oil can be desulfurized to a high degree and which simultaneously is extremely effective in reducing the wax deposit content; a process for producing the catalyst; and a method of hydrotreatment with the catalyst. The invention relates to a catalyst for hydrodesulfurization/dewaxing of a hydrocarbon oil, comprising a support comprising an inorganic oxide containing at least one crystalline aluminosilicate having a one- or two-dimensional pore path system and, having provided thereon, 10 to 35% by mass of a metal in Group 6 of the Periodic Table, 1 to 10% by mass of a metal in Group 8 of the Periodic Table, and 1.Type: GrantFiled: September 10, 2007Date of Patent: August 28, 2012Assignee: Cosmo Oil Co., Ltd.Inventors: Yoshinori Kato, Hiroshi Kimura, Kazuyuki Kiriyama, Takashi Fujikawa
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Publication number: 20120215043Abstract: The presently disclosed and claimed inventive concept(s) generally relates to a solid catalyst component comprising a zeolite with a modifier and at least one Group VIII meal alloyed with at least one transition metal. The presently disclosed and claimed inventive concept(s) further relates to a method of making the solid catalyst component and a process of converting mixed waste plastics into low molecular weight organic compounds using the solid catalyst component.Type: ApplicationFiled: February 14, 2012Publication date: August 23, 2012Inventor: Anne Mae Gaffney
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Publication number: 20120165182Abstract: This invention provides for a method of making a spray-dried catalyst composition for use in any hydrocarbon conversion process. The particle size of the components is adjusted to improve the functionality of the catalyst for specific reactions. This invention also provides for a composite catalyst composition for use in any hydrocarbon conversion process that is dependent on the particle size.Type: ApplicationFiled: March 25, 2011Publication date: June 28, 2012Inventor: Augusto Rodolfo Quinones
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Patent number: 8183172Abstract: A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite selected from IM-5 zeolite and zeolites with structure type MFI, MOR, BEA and MTW, at least one group VIII metal, at least one group IIIA metal and at least one porous mineral matrix. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.Type: GrantFiled: November 3, 2006Date of Patent: May 22, 2012Assignee: IFP Energies NouvellesInventors: Emmanuelle Guillon, Eric Sanchez, Sylvie Lacombe
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Publication number: 20120071317Abstract: A molecular sieve catalyst useful in the conversion of hydrocarbons containing niobium is disclosed, along with a process for the disproportionation of toluene to benzene and xylene using such catalyst.Type: ApplicationFiled: October 13, 2011Publication date: March 22, 2012Applicant: Fina Technology, Inc.Inventors: James R. Butler, Rosa Hall, Xin Xiao
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Publication number: 20120058034Abstract: Extruded honeycomb catalyst bodies and methods of manufacturing same. The catalyst body includes a first oxide selected from the group consisting of tungsten oxides, vanadium oxides, and combinations thereof, a second oxide selected from the group consisting of cerium oxides, lanthanum oxides, zirconium oxides, and combinations thereof, and a zeolite.Type: ApplicationFiled: February 26, 2010Publication date: March 8, 2012Inventors: Steven Bolaji Ogunwumi, Mallanagouda Dyamanagouda Patil, Yuming Xie, Hao Cheng, Shudong Wang
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Publication number: 20120024776Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.Type: ApplicationFiled: August 8, 2011Publication date: February 2, 2012Applicant: MASSACHUSETTS INSTITUTE OF TECHNOLOGYInventor: Javier Garcia-Martinez
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Publication number: 20110305617Abstract: The present invention relates to a catalyst including a ceramic structure containing porous ceramic paper and a catalyst component supported on the ceramic structure, and to a method for removing formaldehyde using the catalyst. The present invention provides a catalyst in which a structure made of ceramic paper having excellent characteristics in terms of porosity, specific surface area, and the like is used as a support for the catalyst component to maximize an effective area for reacting the supported catalyst component with a substance to be treated, thereby improving catalyst performance. The present invention also provides a method of using the catalyst.Type: ApplicationFiled: February 24, 2010Publication date: December 15, 2011Applicant: LG Hausys, LTD.Inventors: Ju-Hyung Lee, In-Sik Nam, Seong-Moon Jung, Jong-Sik Choi, Sun-Joo Kim, Ho-Yeon Lim, Joo-Hwan Seo
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Publication number: 20110294655Abstract: A method of manufacturing a catalyst body which includes: soaking at least part of a fired zeolite-based body in a transition metal oxide solution; removing the body from the transition metal oxide solution; exposing the body to a humidified atmosphere at one or more temperatures above 20° C.; then drying the body; and calcining the body.Type: ApplicationFiled: May 26, 2011Publication date: December 1, 2011Inventors: Steven Bruce Dawes, Steven Bolaji Ogunwumi
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Publication number: 20110274607Abstract: The catalytic behaviour of vanadia-supported zeolite catalysts with different SiO2/Al2O3 ratios was tested for the SCR of NO with ammonia. The SCR activity was found to be directly correlated to the total acidity of the catalysts. On the surface of these zeolites the V2O5 was highly dispersed and amorphous in nature. After the impregnation with vanadium and subsequent poisoning with potassium oxide not much change in micro-pore structure of HZSM5 was observed by N2 adsorption studies. Interestingly, potassium-doped HZSM5 and HMORDENITE catalysts showed high resistance to deactivation because of the unique nature of the material exhibiting higher surface area and acidity than the conventional V2O5—WOx/ZrO2 or TiO2 catalysts. Consequently, a possible application of these alkali-tolerant SCR catalysts in biomass fired power plants can be envisaged.Type: ApplicationFiled: April 1, 2011Publication date: November 10, 2011Applicant: TECHNICAL UNIVERSITY OF DENMARKInventors: Putluru Siva Sankar Reddy, Anders Riisager, Rasmus Fehrmann
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Publication number: 20110236271Abstract: The zeolite structure includes a zeolite material containing a plurality of zeolite particles and an inorganic binding material which binds the zeolite particles to one another, the plurality of zeolite particles include fine zeolite particles having a small average particle diameter and coarse zeolite particles which have an average particle diameter of three or more times the average particle diameter of the fine zeolite particles and which are not an agglomerated material of primary particles, a ratio of volumes of the coarse zeolite particles with respect to the whole volume of the plurality of zeolite particles is from 40 to 90 vol %, in the zeolite material, a ratio of a volume of the inorganic binding material is from 5 to 50 vol %, and a zeolite raw material containing the plurality of zeolite particles and the inorganic binding material is extruded to form a zeolite structure.Type: ApplicationFiled: March 17, 2011Publication date: September 29, 2011Applicant: NGK Insulators, Ltd.Inventors: Yoshio KIKUCHI, Haruo OTSUKA
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Patent number: 8008223Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.Type: GrantFiled: April 25, 2005Date of Patent: August 30, 2011Assignee: Massachusetts Institute of TechnologyInventor: Javier Garcia-Martinez
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Patent number: 7982083Abstract: A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite having channels the opening to which is defined by a ring of 10 oxygen atoms (10 MR), at least one zeolite having channels the opening to which is defined by a ring of 12 oxygen atoms (12 MR) and at least one porous mineral matrix. Said catalyst optionally also contains at least one group VIII metal. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.Type: GrantFiled: December 1, 2006Date of Patent: July 19, 2011Assignee: IFP Energies NouvellesInventors: Emmanuelle Guillon, Eric Sanchez, Sylvie Lacombe
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Publication number: 20110172482Abstract: A catalyst that comprises at least one binder and at least one crystallized material with hierarchized and organized porosity in the fields of microporosity and mesoporosity is described, whereby said crystallized material consists of at least two elementary spherical particles, each of said particles comprising a mesostructured silicon-oxide-based matrix that has a mesopore diameter of between 1.5 and 30 nm and that has microporous and crystallized walls with a thickness of between 1 and 60 nm, whereby said elementary spherical particles have a maximum diameter of 200 microns. Said catalyst is used in a process for oligomerization of an olefinic feedstock that contains hydrocarbon molecules that have 2 to 12 carbon atoms per molecule.Type: ApplicationFiled: April 28, 2009Publication date: July 14, 2011Applicant: IFP ENERGIES NOUVELLESInventors: Amandine Cabiac, Alexandra Chaumonnot, Laurent Simon
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Publication number: 20110155641Abstract: The present invention concerns a catalyst comprising at least one crystalline material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said crystalline material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having microporous and crystalline walls with a thickness in the range 1.5 to 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.Type: ApplicationFiled: May 13, 2009Publication date: June 30, 2011Applicant: IFP ENERGIES NOUVELLESInventors: Audrey Bonduelle, Alexandra Chaumonnot
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Publication number: 20110130579Abstract: A process for the preparation of a catalyst for the use in a hydrocarbon conversion reaction, said catalyst containing a titanium zeolite and carbonaceous material, the catalyst containing said carbonaceous material in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst, the process comprising (i) preparing a catalyst containing the titanium zeolite and (ii) depositing carbonaceous material on the catalyst according to (i) in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst by contacting said catalyst, prior to using the catalyst in said hydrocarbon conversion reaction, with a fluid containing at least one hydrocarbon in an inert atmosphere, to obtain the carbonaceous material containing catalyst, wherein in (ii), the catalyst is not contacted with an oxygen containing gas.Type: ApplicationFiled: November 26, 2010Publication date: June 2, 2011Applicants: BASF SE, The Dow Chemical CompanyInventors: Ulrich MÜLLER, Peter Rudolf, Georg Krug, Rainer Senk
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Publication number: 20110120100Abstract: A catalyst system comprising a first catalytic composition comprising a homogeneous solid mixture containing at least one catalytic metal and at least one metal inorganic support. The pores of the solid mixture have an average diameter in a range of about 1 nanometer to about 15 nanometers. The catalytic metal comprises nanocrystals.Type: ApplicationFiled: November 24, 2009Publication date: May 26, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Ming Yin, Larry Neil Lewis, Oltea Puica Siclovan, Dan Hancu, Benjamin Hale Winkler, Daniel George Norton, Ashish Balkrishna Mhadeshwar
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Patent number: 7939701Abstract: One exemplary embodiment can be an ion-exchanged xylene isomerization catalyst. The ion-exchanged xylene isomerization catalyst can include: about 1-about 99%, by weight, of at least one of MFI, MEL, EUO, FER, MFS, MTT, MTW, TON, MOR, and FAU zeolite; about 1-about 99%, by weight, of a binder having an aluminum phosphate; and no more than about 350 ppm, by weight, of a noble metal based on the weight of the catalyst. Generally, the catalyst has a quotient of (CO area)/(weight % of the noble metal) of no more than about 0.10.Type: GrantFiled: December 12, 2007Date of Patent: May 10, 2011Assignee: UOP LLCInventors: Patrick C. Whitchurch, Paula L. Bogdan, Terrence E. Deak, Dimitri A. Trufanov
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Publication number: 20110092356Abstract: Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures.Type: ApplicationFiled: December 16, 2010Publication date: April 21, 2011Applicant: BATTELLE ENERGY ALLIANCE, LLCInventors: Harry W. Rollins, Lucia Petkovic, Daniel M. Ginosar
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Publication number: 20110085940Abstract: A honeycomb filter includes a honeycomb structure and a zeolite. The honeycomb structure has cell walls to define cells between the cell walls. The zeolite is supported on the cell walls. An amount of the zeolite is from about 80 g/L to about 150 g/L. The cells include a large volume cell and a small volume cell. A porosity of the cell walls is from about 55% to about 65%. A proportion of a sum of a pore volume A and a pore volume B relative to a total pore volume C is about 20% or less. The pore volume A indicates a pore volume of pores having a pore diameter of one half or less of the average pore diameter. The pore volume B indicates a pore volume of pores having a pore diameter of twice or more the average pore diameter.Type: ApplicationFiled: April 9, 2010Publication date: April 14, 2011Applicant: IBIDEN CO., LTD.Inventors: Kazutake Ogyu, Toyoki Ogasawara
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Publication number: 20110077441Abstract: A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises particles of a porous refractory material, crystals of a zeolite material grown within the pores of the refractory material, and at least one catalytically active metal or metal compound associated with the zeolite crystals.Type: ApplicationFiled: September 22, 2010Publication date: March 31, 2011Inventor: Larry L. Iaccino
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Publication number: 20110071264Abstract: The invention covers a process for obtaining an alkaline earth or rare earth metal-P-modified molecular sieve (M-P-modified molecular sieve) comprising the following steps: a). selecting at least one molecular sieve selected from one of: a P-modified molecular sieve which contains at least 0.3 wt % of P obtained by dealuminating a molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P a molecular sieve which is modified with P during step b) by dealuminating the molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P thereby introducing at least 0.3 wt % of P b). contacting said molecular sieve with an alkaline earth or rare earth metal-containing compound (M-containing compound) to introduce at least 0.05 wt % of the alkaline earth or rare earth metal to the molecular sieve. The invention also covers a catalyst composite comprising: a).Type: ApplicationFiled: January 23, 2009Publication date: March 24, 2011Applicant: TOTAL PETROCHEMICALS RESEARCH FELUYInventors: Nikolai Nesterenko, Walter Vermeiren, Sander Van Donk, Delphine Minoux
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Publication number: 20110047988Abstract: A catalyst system comprising a first catalytic composition comprising a first catalytic material disposed on a metal inorganic support; wherein the metal inorganic support has pores; and at least one promoting metal. The catalyst system further comprises a second catalytic composition comprising, (i) a zeolite, or (ii) a first catalytic material disposed on a first substrate, the first catalytic material comprising an element selected from the group consisting of tungsten, titanium, and vanadium. The catalyst system may further comprise a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. A catalyst system comprising a first catalytic composition, the second catalytic composition, and the third catalytic composition is also provided. An exhaust system comprising the catalyst systems described herein is also provided.Type: ApplicationFiled: August 31, 2009Publication date: March 3, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Larry Neil Lewis, Benjamin Hale Winkler, Dan Hancu, Daniel George Norton, Ashish Balkrishna Mhadeshwar
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Publication number: 20110047995Abstract: A catalyst system comprising a first catalytic composition comprising, (i) a first component comprising a zeolite, and (ii) a second component comprising a homogeneous solid mixture containing at least one catalytic metal and at least one metal inorganic network; wherein the pores of the solid mixture have an average diameter in a range of about 1 nanometer to about 15 nanometers; wherein the first component and the second component form an intimate mixture. The catalyst system may further comprise a second catalytic composition and a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. An exhaust system comprising the catalyst systems described herein is also provided.Type: ApplicationFiled: August 31, 2009Publication date: March 3, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Larry Neil Lewis, Donald Wayne Whisenhunt, Jr., Dan Hancu, Ashish Balkrishna Mhadeshwar, Benjamin Hale Winkler, Daniel George Norton, Oltea Puica Siclovan
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Patent number: 7879749Abstract: Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures.Type: GrantFiled: August 15, 2006Date of Patent: February 1, 2011Assignee: Battelle Energy Alliance, LLCInventors: Harry W. Rollins, Lucia M. Petkovic, Daniel M. Ginosar
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Publication number: 20100319332Abstract: To equip a diesel particle filter with a zeolite-containing coating uniformly over the entire length of the particle filter and with a further zeolite-free coating which is applied, from the entry side of the filter, solely up to a specific length of the filter, it is proposed, first, to apply the zeolite-free coating from the entry side of the filter and only thereafter to apply the zeolite-containing coating over the entire length of the filter from the exit side of the filter. As a result of this sequence of coatings, a better adhesive strength of the coatings than when both coatings are applied from the entry side is ensured.Type: ApplicationFiled: February 17, 2009Publication date: December 23, 2010Inventors: Gerald Jeske, Marcus Pfeifer, Wolfgang Schneider, Franz Dornhaus, Ralf Mueller, Michael Schiffer
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Publication number: 20100316547Abstract: Embodiments of the present disclosure include a catalyst for the conversion of CO and/or hydrocarbons in an exhaust stream including a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof. In those embodiments, the binary composition may include Sn(X)Ti(y)O2, wherein x+y=1, 0.85>y>0. In other embodiments of the present disclosure, the Sn compound includes a ternary composition including Sn(a)Ti(b)Zr(c)O2, wherein a is 0.25, b is 0.25 and c is 0.5. Certain embodiments of this disclosure include a method for the conversion of CO in an exhaust stream, including contacting an exhaust stream containing CO with the catalyst described above containing a Sn compound. In other embodiments, the exhaust stream includes hydrocarbons.Type: ApplicationFiled: May 20, 2010Publication date: December 16, 2010Inventors: Rachelle Justice, Rajashekharam V. Malyala, Svetlana Iretskaya, Dylan Trandal, Dien To, Jason Pless, Stephen Golden, Jiho Yoo
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Publication number: 20100304957Abstract: Zeolite-based honeycomb bodies and methods of manufacturing same. Zeolite-based honeycomb bodies especially suited for engine exhaust treatment applications include a primary phase comprising a zeolite having a SiO2 to Al2O3 molar ratio in the range from 5 to 300. The zeolite-based composites are porous with an open porosity of at least 25% and a median pore diameter of at least 1 micron. The zeolite-based honeycomb bodies can be manufactured by an extrusion method.Type: ApplicationFiled: June 3, 2010Publication date: December 2, 2010Inventors: Steven Bolaji Ogunwumi, Patrick David Tepesch, Raja Rao Wusirika
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Publication number: 20100296992Abstract: Honeycomb catalyst structures and methods of using them, where the structures have honeycomb channel walls of selective catalytic reduction catalyst, the channel walls occupy at least 20% of the volume of the structure, the structure exhibits a pressure drop for flowing air not exceeding about 110 Pa at a space velocity of 20,000 hr?1, and the channel walls are of a thickness insuring high degree of catalyst utilization and NOx conversion efficiency.Type: ApplicationFiled: May 22, 2009Publication date: November 25, 2010Inventors: Yi Jiang, Ameya Joshi, Steven Bolaji Ogunwumi, Jianhua Weng
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Patent number: 7807132Abstract: A quantity of solution sufficient to dissolve a pH controlling substance and/or substantially dissolve a surfactant without substantial excess solution is controlled under a set of time and temperature conditions to transform an inorganic material having long-range crystallinity to a mesostructure having long-range crystallinity. The method employs concentrated conditions that have a consistency similar to a thick slurry. The economic viability of scaling up such thick slurry methods is improved relative to prior more dilute methods of transforming an inorganic material to a mesostructure.Type: GrantFiled: March 13, 2007Date of Patent: October 5, 2010Assignee: Rive Technology, Inc.Inventor: Javier Garcia-Martinez
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Publication number: 20100222205Abstract: A method of manufacturing a catalyst body which includes: combining one or more inorganic components with an inorganic binder, and optionally with an organic binder, to form a mixture, the one or more inorganic components comprising a primary phase material being zeolite, or CeO2—ZrO2, or a combination; forming the mixture into a shaped body; firing the shaped body to allow the inorganic binder to bind the one or more inorganic components; impregnating the shaped body with a source of a reducing or oxidizing element; and heating the impregnated shaped body to form a redox oxide from the source, the redox oxide being supported by the shaped body.Type: ApplicationFiled: February 27, 2009Publication date: September 2, 2010Inventors: Steven Bolaji Ogunwumi, Mallanagouda Dyamanagouda Patil
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Publication number: 20100221165Abstract: The present invention relates to a process for reactivating a catalyst which comprises a zeolite doped with an iron species, which comprises the step of treating the catalyst with hydrogen chloride-containing gas. The invention further relates to a reactivated catalyst which is obtained with the aid of the process according to the invention and to the use thereof for treatment of off-gases from incineration processes, especially for the treatment of off-gases from refuse incineration plants, very particularly for the reduction of nitrogen oxides.Type: ApplicationFiled: July 2, 2008Publication date: September 2, 2010Applicant: Sud-Chemie AGInventors: Ingo Hanke, Arno Tissler
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Publication number: 20100185035Abstract: A niobium-modified mordenite catalyst can be made from water soluble niobium precursors such as niobium oxalate and ammonium niobate(V) oxalate and can be used in toluene disproportionation reactions. Embodiments can provide a toluene conversion of at least 30 wt % of the toluene feed with selectivity to benzene above 40 wt % of the reaction product composition and to xylenes above 40 wt % of the reaction product composition and non-aromatics selectivity of less than 1.0 wt % of the reaction product composition.Type: ApplicationFiled: March 29, 2010Publication date: July 22, 2010Applicant: Fin Technology Inc.Inventors: James Butler, Olga Khabashesku, Darek Wachowicz, Callum Bailey
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Publication number: 20100160667Abstract: Processes comprising: (a) providing a shaped body having a surface and comprising a metal oxide, and impregnating the shaped body with a liquid comprising an unsaturated compound; (b) subjecting the impregnated shaped body to thermolysis under an inert gas atmosphere at a temperature of 250 to 400° C., such that at least 10% by weight of the unsaturated compound is thermalized to form a layer of a high molecular weight polyaromatic on at least a portion of the surface of the shaped body; and (c) reacting the shaped body with a reagent to functionalize the polyaromatic layer, wherein the shaped body has a smallest dimension in any spatial direction of at least 1 mm to provide a shaped catalyst body having ion- exchange properties; shaped catalyst bodies prepared thereby and uses therefor as catalysts.Type: ApplicationFiled: August 7, 2007Publication date: June 24, 2010Applicant: BASF SEInventors: Marco Bosch, Nawid Kashani-Shirazi, Christian Kuhrs
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Publication number: 20100143227Abstract: Disclosed herein is a catalyst comprising a binder; and a catalytic composition, the catalytic composition comprising a first catalyst composition that comprises a zeolite; and a second catalyst composition that comprises a catalytic metal disposed upon a porous inorganic material, wherein the porous inorganic material is a metal oxide, an inorganic oxide, an inorganic carbide, an inorganic nitride, an inorganic hydroxide, an inorganic oxide having a hydroxide coating, an inorganic carbonitride, an inorganic oxynitride, an inorganic boride, an inorganic borocarbide, or a combination comprising at least one of the foregoing inorganic materials; wherein the catalyst is in the form of an extrudate or foam.Type: ApplicationFiled: December 5, 2008Publication date: June 10, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Hrishikesh Keshavan, Benjamin Hale Winkler, Dan Hancu
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Publication number: 20100135864Abstract: Provided are a photocatalytic material that improves a decomposition performance and a decomposition rate, as well as a photocatalytic member and a purification device in which the photocatalytic material is used. The photocatalytic member is a photocatalytic member (1) that includes a substrate (10) and a photocatalyst layer (11) formed on a surface of the substrate (10), wherein the photocatalyst layer (11) contains a titanium oxide photocatalyst and zeolite, the titanium oxide photocatalyst containing at least an anatase-type titanium oxide and fluorine, in which a content of the fluorine in the titanium oxide photocatalyst is 2.5 wt % to 3.5 wt %, and 90 wt % or more of the fluorine is chemically bonded to the anatase-type titanium oxide.Type: ApplicationFiled: April 18, 2008Publication date: June 3, 2010Applicant: PANASONIC CORPORATIONInventors: Noboru Taniguchi, Tomohiro Kuroha, Shuzo Tokumitsu, Kenichi Tokuhiro
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Patent number: 7723252Abstract: There is disclosed in embodiments catalysts produced by a two-stage loading of a zeolite carrier with an aqueous solution of a cobalt compound, with drying in an air current after each loading. Methods using the catalysts to produce synfuel are disclosed.Type: GrantFiled: April 11, 2007Date of Patent: May 25, 2010Assignee: WescoInventors: Lapidus Albert Lvovich, Budtsov Vladimir Sergeevich
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Patent number: 7718840Abstract: Disclosed is a process for producing light olefins from hydrocarbon feedstock. The process is characterized in that a porous molecular sieve catalyst consisting of a product obtained by evaporating water from a raw material mixture comprising a molecular sieve with a framework of Si—OH—Al— groups, a water-insoluble metal salt, and a phosphate compound, is used to produce light olefins, particularly ethylene and propylene, from hydrocarbon, while maintaining excellent selectivity to light olefins. According to the process, by the use of a specific catalyst with hydrothermal stability, light olefins can be selectively produced in high yield with high selectivity from hydrocarbon feedstock, particularly full-range naphtha. In particular, the process can maintain higher cracking activity than the reaction temperature required in the prior thermal cracking process for the production of light olefins, and thus, can produce light olefins with high selectivity and conversion from hydrocarbon feedstock.Type: GrantFiled: June 27, 2006Date of Patent: May 18, 2010Assignees: SK Energy Co., Ltd., Korea Research Institute of Chemical TechnologyInventors: Sun Choi, Yong Seung Kim, Deuk Soo Park, Suk Joon Kim, Il Mo Yang, Hee Young Kim, Yong Ki Park, Chul Wee Lee, Won Choon Choi, Kwang An Ko, Na Young Kang
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Publication number: 20100111796Abstract: Catalysts, methods of preparing catalyst, and methods for treating exhaust gas streams are described. In one or more embodiments, a catalyst system includes an upstream zone effective to catalyze the conversion of a mixture of NOx and NH3 to N2, and a downstream zone effective for the conversion of ammonia to N2 in the presence or absence of NOx. In an embodiment, a method for preparing a catalyst system includes: first coating one end of a substrate along at least 5% of its length with an undercoat washcoat layer containing a material composition effective to catalyze the removal of ammonia; second coating with an overcoat layer containing a material composition effective to catalyze the conversion of a mixture of NOx and NH3 to N2.Type: ApplicationFiled: November 3, 2008Publication date: May 6, 2010Applicant: BASF Catalysts LLCInventors: Matthew Tyler Caudle, Martin Dieterle, Scott E. Buzby
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Patent number: 7700816Abstract: An oxygenate conversion catalyst useful in the conversion of oxygenates such as methanol to olefinic products may be improved by the use of a catalyst combination based on a molecular sieve in combination with a co-catalyst comprising a mixed metal oxide composition which has oxidation/reduction functionality under the conditions of the conversion. This metal oxide co-catalyst component will comprise a mixed oxide of one or more, preferably at least two, transition metals, usually of Series 4, 5 or 6 of the Periodic Table, with the metals of Series 4 being preferred, as an essential component of the mixed oxide composition. The preferred transition metals are those of Groups 5, especially titanium and vanadium, Group 6, especially chromium or molybdenum, Group 7, especially manganese and Group 8, especially cobalt or nickel. Other metal oxides may also be present.Type: GrantFiled: July 11, 2006Date of Patent: April 20, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Teng Xu, Tan-Jen Chen, Neeraj Sangar, John Di Yi Ou
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Patent number: 7687423Abstract: The subject invention comprises a novel UZM-14 catalytic material comprising globular aggregates of crystallites having a MOR framework type with a mean crystallite length parallel to the direction of 12-ring channels of about 60 nm or less and a mesopore volume of at least about 0.10 cc/gram. Catalysts formed from the novel material are particularly effective for the transalkylation of aromatics.Type: GrantFiled: June 26, 2008Date of Patent: March 30, 2010Assignee: UOP LLCInventors: Jaime G. Moscoso, Edwin P. Boldingh, Michael G. Gatter, Susan C. Koster
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Publication number: 20100075834Abstract: The present invention provides a process for the preparation of metal-doped zeolites comprising the steps of i) provision of a dry mixture of a) a zeolite, b) a compound of a catalytically active metal, ii) intimate grinding of the mixture, iii) heating of the mixture in a reactor, iv) cooling to room temperature and obtaining the metal-doped zeolite, wherein the internal pressure in the reactor during the heating is kept in a pressure range from 0 to ?200 millibar. The invention further relates to the use of a metal-doped zeolite prepared by means of the process according to the invention for the conversion of NOx and N2O into harmless products.Type: ApplicationFiled: July 19, 2007Publication date: March 25, 2010Inventors: Soovi Hurgobin, Arno Tissler, Ashveer Raghunandan, Attila Jambor, Rainer Rakoczy, Roderik Althoff