Superconductor Next To Layer Containing Nonsuperconducting Ceramic Composition Or Inorganic Compound (e.g., Metal Oxide, Metal Nitride, Etc.) Patents (Class 505/238)
  • Patent number: 5972847
    Abstract: A method is disclosed for fabricating YBa.sub.2 Cu.sub.3 O.sub.7 superconductor layers with the capability of carrying large superconducting currents on a metallic tape (substrate) supplied with a biaxially textured oxide buffer layer. The method represents a simplification of previously established techniques and provides processing requirements compatible with scale-up to long wire (tape) lengths and high processing speeds. This simplification has been realized by employing the BaF.sub.2 method to grow a YBa.sub.2 Cu.sub.3 O.sub.7 film on a metallic substrate having a biaxially textured oxide buffer layer.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: October 26, 1999
    Assignee: Lockheed Martin Energy
    Inventors: Roeland Feenstra, David Christen, Mariappan Paranthaman
  • Patent number: 5974336
    Abstract: An oxide superconductor comprises a base material consisting of a single crystalline oxide, an oxide superconductor film consisting of a Y123 compound and formed on the single crystalline oxide base material, and a coating film consisting essentially of a Ba--Cu--O oxide and covering the surface of the oxide superconductor film, the coating film having a thermal expansion coefficient higher than that of the oxide superconductor film.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: October 26, 1999
    Assignees: Kabushiki Kaisha Toshiba, International Superconductivity Technology Center
    Inventors: Yasuji Yamada, Tamaki Masegi, Junichi Kawashima, Yusuke Niiori, Izumi Hirabayashi
  • Patent number: 5962866
    Abstract: A superconductor device has a substrate with an inclined surface that divides the substrate surface into a lower planar substrate surface and an upper planar substrate surface. A lower layer of an anisotropic superconductor material is epitaxially deposited on the lower planar substrate surface so that an a-axis of the anisotropic superconductor material of the lower layer is exposed at a top edge of the lower layer. An upper layer of an anisotropic superconductor material is epitaxially deposited on the upper planar substrate surface so that an a-axis of the anisotropic superconductor material of the upper layer is exposed at a top edge of the upper layer. A layer of a non-superconductor material overlies the inclined surface and the layers of anisotropic superconductor material.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: October 5, 1999
    Assignee: Biomagnetic Technologies, Inc.
    Inventors: Mark S. DiIorio, Shozo Yoshizumi, Kai-Yueh Yang
  • Patent number: 5922650
    Abstract: Microstrip/stripline transmission lines have a plurality of strips on a substrate where strips are separated by a gap. This arrangement results in a reduced maximum current density compared to previous transmission lines with the same power handling capability. The strips can have the same width or different widths. The gaps can have the same width or different widths. The transmission lines can be used in filters and resonators and can be made of high temperature superconductive materials.
    Type: Grant
    Filed: February 6, 1996
    Date of Patent: July 13, 1999
    Assignee: Com Dev Ltd.
    Inventor: Shen Ye
  • Patent number: 5914297
    Abstract: An oxide superconductor composite having improved texture and durability. The oxide superconductor composite includes an oxide superconductor phase substantially surrounded with/by a noble metal matrix, the noble metal matrix comprising a metal oxide in an amount effective to form metal oxide domains that increase hardness of the composite. The composite is characterized by a degree of texture at least 10% greater than a comparable oxide superconductor composite lacking metal oxide domains. An oxide superconducting composite may be prepared by oxidizing the precursor composite under conditions effective to form solute metal oxide domains within the silver matrix and to form a precursor oxide in the precursor alloy phase; subjecting the oxidized composite to a softening anneal under conditions effective to relieve stress within the noble metal phase; and converting the oxide precursor into an oxide superconductor.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: June 22, 1999
    Assignee: American Superconductor Corp
    Inventor: Eric R. Podtburg
  • Patent number: 5912211
    Abstract: A superconducting ceramic film is deposited on a substrate sputtering. In virtue of the low thermal conductivity of ceramic, a laser beam is radiated to the ceramic film in order to remove the irradiated portion by sublimation and produce a pattern on the ceramic film.
    Type: Grant
    Filed: June 15, 1990
    Date of Patent: June 15, 1999
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventor: Shunpei Yamazaki
  • Patent number: 5908812
    Abstract: A superconducting oxide composite structure including a superconducting oxide member, a metal layer surrounding the superconducting oxide member, and an insulating layer of a complex oxide formed in situ adjacent to the superconducting oxide member and the metal layer is provided together with a method of forming such a superconducting oxide composite structure including encapsulating a superconducting oxide member or precursor within a metal matrix layer from the group of: (i) a reactive metal sheath adjacent to the superconducting oxide member or precursor, the reactive metal sheath surrounded by a second metal layer or (ii) an alloy containing a reactive metal; to form an intermediate product, and, heating the intermediate product at temperatures and for time sufficient to form an insulating layer of a complex oxide in situ, the insulating layer to the superconducting oxide member or precursor and the metal matrix layer.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: June 1, 1999
    Assignee: The Regents of the University of California
    Inventors: James D. Cotton, Gilbert Neal Riley, Jr.
  • Patent number: 5906965
    Abstract: A high temperature superconductor (HTS) tri-layer structure and a method for providing the same are described. Preferable two dimensional growth for all layers is provided resulting in smooth surfaces and highly crystalline layers. Full oxygenation of HTS under-layer(s) is provided despite having thick intervening dielectric mid-layer. HTS over- and under-layers are preferably structurally and electrically similar and have high crystallinity, the HTS layers have high T.sub.c (e.g. >90K) comparable to T.sub.c of single layer superconductor layers and a high J.sub.c (e.g. >10.sup.6 A/cm.sup.2), the tri-layer properties do not significantly degrade as the thickness of the layers is increased, and the dielectric mid-layer has high resistivity and is substantially pin-hole free.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: May 25, 1999
    Assignee: Superconductor Technologies, Inc.
    Inventor: Muralidhar R. Rao
  • Patent number: 5906963
    Abstract: A lanthanum aluminate (LaAlO.sub.3) substrate on which thin films of layered perovskite copper oxide superconductors are formed. Lanthanum aluminate, with a pseudo-cubic perovskite crystal structure, has a crystal structure and lattice constant that closely match the crystal structures and lattice constants of the layered perovskite superconductors. Therefore, it promotes epitaxial film growth of the superconductors, with the crystals being oriented in the proper direction for good superconductive electrical properties, such as a high critical current density. In addition, LaAlO.sub.3 has good high frequency properties, such as a low loss tangent and low dielectric constant at superconductive temperatures. Finally, lanthanum aluminate does not significantly interact with the superconductors. Lanthanum aluminate can also used to form thin insulating films between the superconductor layers, which allows for the fabrication of a wide variety of superconductor circuit elements.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: May 25, 1999
    Assignee: TRW Inc.
    Inventors: Randy Wayne Simon, Christine Elizabeth Platt, Alfred Euinam Lee, Gregory Steven Lee
  • Patent number: 5898020
    Abstract: A biaxially textured article includes a rolled and annealed, biaxially textured substrate of a metal having a face-centered cubic, body-centered cubic, or hexagonal close-packed crystalline structure; and an epitaxial superconductor or other device epitaxially deposited thereon.
    Type: Grant
    Filed: May 22, 1996
    Date of Patent: April 27, 1999
    Inventors: Amit Goyal, John D. Budai, Donald M. Kroeger, David P. Norton, Eliot D. Specht, David K. Christen
  • Patent number: 5897945
    Abstract: Metal oxide nanorods and composite materials containing such nanorods. The metal oxide nanorods have diameters between 1 and 200 nm and aspect ratios between 5 and 2000.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: April 27, 1999
    Assignee: President and Fellows of Harvard College
    Inventors: Charles M. Lieber, Peidong Yang
  • Patent number: 5883051
    Abstract: A superconducting Josephson junction element including a first, a-axis oriented, superconductive metal oxide crystal grain having a first area of a {001} plane, and a second, c-axis oriented, superconductive metal oxide crystal grain having a second area of a {110} plane, wherein the first and second crystal grains are in contact with each other at the first and second areas to form a grain boundary therebetween.
    Type: Grant
    Filed: October 22, 1996
    Date of Patent: March 16, 1999
    Assignee: International Superconductivity Technology Center
    Inventors: Yoshihiro Ishimaru, Jian-Guo Wen, Kunihiko Hayashi, Youichi Enomoto, Naoki Koshizuka, Shoji Tanaka
  • Patent number: 5877124
    Abstract: A superconducting oxide ceramic pattern is described. The pattern is comprised of a high Tc superconducting region and a low Tc superconducting region which exhibits a resistivity at the liquid nitrogen temperature while the high Tc region is superconducitive at that temperature. The low Tc region is doped with impurity such as Si and then subjected to thermal treatment to oxidizing the impurity.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: March 2, 1999
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventor: Shumpei Yamazaki
  • Patent number: 5872080
    Abstract: A superconducting article including a flexible polycrystalline metal substrate, a layer of an adhesion layer material upon the surface of the flexible polycrystalline metal substrate, a layer of a cubic oxide material upon the adhesion layer material, the first layer of cubic oxide material deposited by ion beam assisted deposition, a layer of a buffer material upon the ion beam assisted deposited cubic oxide material layer, and, a layer of YBCO upon the buffer material layer is provided and has demonstrated J.sub.c 's of 1.3.times.10.sup.6 A/cm.sup.2, and I.sub.c 's of 120 Amperes across a sample 1 cm wide.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: February 16, 1999
    Assignee: The Regents of the University of California
    Inventors: Paul N. Arendt, Xin Di Wu, Steve R. Foltyn
  • Patent number: 5866252
    Abstract: This invention permits superconducting ceramics, as well as other ceramic materials, to be spray deposited onto indefinitely large sheets of metallic substrate from a carboxylic acid salt solution. Elemental metal precursors of the superconductor are introduced into the solution as carboxylic acid salts. The deposit formed on the malleable metallic substrate is then thermomechanically calcined to form c-axis textured metal-superconductor composite sheet structures. These composite sheet structures can be formed by pressing together two ceramic-substrate structures, ceramic face-to-face, to form a metal-ceramic-metal sheet structure, or by overlaying a metal sheet over the deposited structure. Once the structure has been thermomechanically calcined, the c-axis of the superconductor is oriented parallel to the vector defining the plane of the metal sheet, i.e., perpendicular to the surface of the plane.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: February 2, 1999
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: L. Pierre de Rochemont, Michael J. Suscavage, Daniel F. Ryder, Jr., Mikhail Klugerman
  • Patent number: 5863868
    Abstract: A SQUID 10 was multiple junctions, each junction allowing a critical current to flow therethrough. The SQUID 10 comprises a laminar structure including: (a) a substantially planar substrate 12; (b) a first high temperature superconductive layer 14 of substantially uniform thickness deposited on the substrates; (c) a dielectric layer 16 deposited on the first superconductive layer 14, the dielectric layer 16 comprising a planar level segment 18 having two ramp segments defining SQUID junctions at opposing ends 20 and defining SQUID hole; and (d) a second high temperature superconductive layer 24 of substantially uniform thickness deposited on the dielectric layer 16, the second high temperature superconductive layer 24 covering all three segments of the dielectric layer 16.
    Type: Grant
    Filed: September 25, 1997
    Date of Patent: January 26, 1999
    Assignee: TRW Inc.
    Inventors: Hugo Wai-Kung Chan, Kenneth P. Daly, James M. Murduck
  • Patent number: 5861361
    Abstract: A FET type superconducting device comprises a thin superconducting channel, a superconducting source region and a superconducting drain region formed of an oxide superconductor over a principal surface of the substrate, and a gate electrode on a gate insulator disposed on the superconducting channel for controlling the superconducting current flowing through the superconducting channel by a signal voltage applied to the gate electrode. The superconducting channel is formed of(Pr.sub.w Y.sub.1-w)Ba.sub.2 Cu.sub.3 O.sub.7-z (0<w<1, 0<z<1) oxide superconductororY.sub.1 Ba.sub.2 Cu.sub.3-v CO.sub.V O.sub.7-u (0<v<3, 0<u<1) oxide superconductor.These oxide superconductors have smaller carrier densities than the conventional oxide superconductor so that the superconducting channel has a larger thickness than the one funned of the conventional oxide superconductor.
    Type: Grant
    Filed: April 17, 1996
    Date of Patent: January 19, 1999
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Takao Nakamura, Michitomo Iiyama
  • Patent number: 5856276
    Abstract: A novel ceramic substrate useful for the preparation of superconducting films, said substrate having the formula REBa.sub.2 MO.sub.6 where RE represents rare earth metals--Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and M represents metals Nb, Sb, Sn, Hf, Zr; and a process for the preparation of superconducting YBa.sub.2 Cu.sub.3 O.sub.7-.delta. thick films on new ceramic substrate.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: January 5, 1999
    Assignee: Council of Scientific & Industrial Research
    Inventors: Jacob Koshy, Jijimon Kumpukkattu Thomas, Jose Kurian, Yogendra Prasad Yadava, Alathoor Damodaran Damodaran
  • Patent number: 5849669
    Abstract: A high critical temperature superconducting Josephson device includes a bicrystal substrate formed of a first single crystal substrate and a second single crystal substrate, with end faces of the first and second single crystal substrates having different crystal orientations and being joined to each other. A first superconducting electrode formed of a first film of a high critical temperature superconductor material is located on the first single crystal substrate, whereas a second superconducting electrode formed of a second film of a high critical temperature superconductor material is located on the second single crystal substrate. A bridge is formed of a third film of a high critical temperature superconductor material and located on the bicrystal substrate across a joint between said first and said second single crystal substrates.
    Type: Grant
    Filed: May 30, 1996
    Date of Patent: December 15, 1998
    Assignee: Oki Electric Industry Co., Ltd.
    Inventor: Zhongmin Wen
  • Patent number: 5834405
    Abstract: A superconducting multilayer ceramic substrate is disclosed, prepared by firing a laminate of at least two polymer bonded cast sheets of a ceramic dielectric oxide powder, at least one sheet of which has a metallization pattern provided thereon, to thereby form a superconducting oxide reaction layer at the interface between the sintered ceramic material and the embedded metallic conductor lines of the metallization pattern.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: November 10, 1998
    Assignee: International Business Machines Corporation
    Inventors: Byung Tae Ahn, Robert Bruce Beyers, Emanuel Israel Cooper, Edward August Giess, Eugene John O'Sullivan, Judith Marie Roldan, Lubomyr Taras Romankiw
  • Patent number: 5821199
    Abstract: A process and structure wherein a film comprised of a perovskite or a spinel is built epitaxially upon a surface, such as an alkaline earth oxide surface, involves the epitaxial build up of alternating constituent metal oxide planes of the perovskite or spinel. The first layer of metal oxide built upon the surface includes a metal element which provides a small cation in the crystalline structure of the perovskite or spinel, and the second layer of metal oxide built upon the surface includes a metal element which provides a large cation in the crystalline structure of the perovskite or spinel. The layering sequence involved in the film build up reduces problems which would otherwise result from the interfacial electrostatics at the first atomic layers, and these oxides can be stabilized as commensurate thin films at a unit cell thickness or grown with high crystal quality to thicknesses of 0.5-0.7 .mu.m for optical device applications.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: October 13, 1998
    Assignee: Lockheed Martin Energy Systems, Inc.
    Inventors: Rodney Allen McKee, Frederick Joseph Walker
  • Patent number: 5821556
    Abstract: A superconductive junction (10) comprises a first track (22) of YBa.sub.2 Cu.sub.3 O.sub.7 surmounted by a second track (28) also of YBa.sub.2 Cu.sub.3 O.sub.7. An interconnect (26) in the form of a superconductive mesa electrically connects the first track to the second track and acts as a microbridge. When cooled below a critical temperature, the junction (10) shows Josephson-like behaviour. A non-superconductive layer (24) of PrBa.sub.2 Cu.sub.3 O.sub.7 separates the first track and the second track, with the interconnect extending through the PrBa.sub.2 Cu.sub.3 O.sub.7 layer in the form of an island. The junction (10) is fabricated by electron beam evaporation, optical lithography, and ion beam milling.
    Type: Grant
    Filed: September 23, 1996
    Date of Patent: October 13, 1998
    Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Nigel Gordon Chew, Simon Wray Goodyear, Richard George Humphreys, Julian Simon Satchell
  • Patent number: 5814584
    Abstract: Compounds of the general formula A.sub.2 MeSbO.sub.6 wherein A is either barium (Ba) or strontium (Sr) and Me is a non-magnetic ion selected from the group consisting of scandium (Sc), indium (In) and gallium (Ga) have been prepared and included in high critical temperature thin film superconductor structures.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: September 29, 1998
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Arthur Tauber, William D. Wilber, Steven C. Tidrow, Robert D. Finnegan, Donald W. Eckart
  • Patent number: 5814583
    Abstract: A high-temperature superconducting thin film of compound oxide selected from the group consisting of:Y.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Ho.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Lu.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x,Sm.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Nd.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Gd.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x,Eu.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Er.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Dy.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x,Tm.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Yb.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, La.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x,(La, Sr).sub.2 CuO.sub.4-x,which is deposited on a substrate of MgO or SrTiO.sub.3, with the outer surface of the high-temperature superconducting thin film being covered with a protective crystalline film of SrTiO.sub.3.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: September 29, 1998
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Hideo Itozaki, Saburo Tanaka, Nobuhiko Fujita, Shuji Yazu, Tetsuji Jodai
  • Patent number: 5795848
    Abstract: Superconductivity is inhibited in selected portions of a high temperature superconductor ("HTS") material by patterning the selected portions with a resist. The patterned material is ion-bombarded to implant impurity ions in non-resist-bearing portions of the material. After low temperature annealing, the non-resist-bearing portions of the material lose their superconducting characteristics, but such characteristics are preserved in the material's resist-bearing portions. The material's crystalline structure is preserved, so additional layers can be epitaxially grown atop the inhibited material. Superconductivity is inhibited at a selected depth in a HTS material by subjecting the material to impurity ion bombardment at an energy level controlled to implant ions in the material at the selected depth. After low temperature annealing, the material loses its superconducting characteristics at the selected depth, but such characteristics are preserved at other depths (i.e.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: August 18, 1998
    Assignee: The University of British Columbia
    Inventor: Qi Yuan Ma
  • Patent number: 5795849
    Abstract: A method for producing a superconductor assembly includes preparing a first bulk ceramic superconductor having a first essentially random pattern of superconductor domains of a copper-oxide ceramic superconductor and non-superconductor domains at a critical temperature, and preparing a second bulk ceramic superconductor having a second essentially random pattern of superconductor domains of a copper-oxide ceramic superconductor and non-superconductor domains at the critical temperature. The method further includes juxtaposing a first surface of the first bulk ceramic superconductor proximate with a first surface of the second bulk ceramic superconductor to form a superconductor assembly where superconductor domains of the first bulk ceramic superconductor and superconductor domains of the second bulk ceramic superconductor are only randomly aligned due to the different first essentially random pattern and second essentially random pattern.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 18, 1998
    Inventor: Paul L. Hickman
  • Patent number: 5776863
    Abstract: A method of in-situ fabrication of a Josephson junction having a laminar structure, the method comprising the steps of: (1) etching a planar substrate to yield a first planar segment, a second planar segment and a ramp segment, the ramp segment connecting the two planar segments at an angle thereto and the substrate having a constantly-decreasing thickness in the ramp segment; (2) depositing a first superconductive layer on the substrate; (3) depositing a non-superconductive layer on the first superconductive layer; and (4) depositing a second superconductive layer on the non-superconductive layer, wherein both the first and second superconductive layers, and the non-superconductive layer are epitaxial with a c-axis in a direction substantially normal to the plane of the first and second planar segments, and the layers are of substantially uniform thickness in the three segments.
    Type: Grant
    Filed: July 8, 1996
    Date of Patent: July 7, 1998
    Assignee: TRW Inc.
    Inventor: Arnold H. Silver
  • Patent number: 5767029
    Abstract: Metal-ceramic composite materials which combine advantageous properties of ceramic and metal and have the composition (Mg.sub.1-x Cu.sub.x)O+Ag.sub.y, where 0.03.ltoreq.x.ltoreq.0.25 and 0.001.ltoreq.y.ltoreq.0.5, can be produced in a one-stage process. In this process, sintering is carried out in air at a sintering temperature in the temperature range of 980.degree. C.-1100.degree. C. for a sintering time in the range of 1.5-2.5 hours. The rate of temperature rise from room temperature to the sintering temperature is in the range of 8-50 K/min. When 0.01.ltoreq.y.ltoreq.0.1, such composite materials are suitable as materials having high toughness for low-friction, self-lubricating sliding bearings, in particular of ceramic. When 0.1.ltoreq.y.ltoreq.0.2, they are suitable as electrical contact materials in fuel cells and for abrasion-resistant sliding contacts. When 0.15.ltoreq.y.ltoreq.0.5, the composite materials have a high conductivity.
    Type: Grant
    Filed: November 8, 1996
    Date of Patent: June 16, 1998
    Assignee: ABB Research Ltd.
    Inventor: Claus Schuler
  • Patent number: 5750474
    Abstract: A superconductor-insulator-superconductor Josephson tunnel junction, comprising: a single crystalline substrate having a perovskite crystal structure; a template layer formed of a b-axis oriented PBCO thin film on the substrate; and a trilayer structure consisting of a lower electrode, a barrier layer and an upper electrode, which serve as a superconductor, an insulator and a superconductor, respectively, the lower electrode and the upper electrode each being formed of an a-axis oriented YBCO superconducting thin film and having an oblique junction edge at an angle of 30.degree. to 70.degree., the barrier layer being formed of an insulating thin film between the two superconducting electrodes, can be operated at a low power with an exceptional speed in calculation and data processing.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: May 12, 1998
    Assignee: Electronics and Telecommunications Research Institute
    Inventors: Gun-Yong Sung, Jeong-Dae Suh
  • Patent number: 5747873
    Abstract: A system for incorporating superconductor circuits and semiconductor circuits in multilayered structures. A carrier material is chosen that is a good thermal match with the preferred superconductor substrates. The preferred superconductor substrate materials are lanthanum aluminate, magnesium oxide and neodymium gallate. The substrate carrier material should provide adequate thermal match through the range of operating temperatures which are preferably from room temperature to 77K. The preferred carrier material is a low temperature cofired ceramic (LTCC) which allows for multilayered structures to be developed which incorporate the superconductor circuitry and the semiconductor elements. The LTCC is composed of crystalline quartz particles in a borosilicate glass matrix. The percentage of quartz may be adjusted to adjust the thermal expansion characteristics of the LTCC.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 5, 1998
    Assignee: Northrop Grumman Corporation
    Inventors: Salvador H. Talisa, Michael A. Janocko, Deborah P. Partlow, Andrew J. Piloto
  • Patent number: 5736488
    Abstract: This invention relates to multilayered superconductive composites, particularly to composites based on thallium-containing superconducting oxides, and their process of manufacture.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: April 7, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Dean Willett Face, Kirsten Elizabeth Myers
  • Patent number: 5736489
    Abstract: A method is provided for producing polycrystalline superconductor materials which utilizes a zdense and non-polluting 211 substrate which has been pre-sintered prior to melt processing with a 123 superconducting material. The resulting melt-processed material may be fabricated into a 123 superconductor having a single crystal size of up to 60 mm long which can carry very high current of up to about 1,500 A at 1 .mu.V/cm criterion.
    Type: Grant
    Filed: February 7, 1997
    Date of Patent: April 7, 1998
    Assignee: Wright State University
    Inventor: Gregory Kozlowski
  • Patent number: 5728481
    Abstract: A magnetic detecting device is constructed of a substrate, a first magnetic layer formed on the substrate, a first magnetic layer formed on the substrate, an intermediate layer containing an atom indicative of weak spincoupling and formed on the first magnetic film, and a second magnetic layer formed on the intermediate layer. The magnetic detecting device further comprises a unit or supplying a current through the first and second magnetic layers, and a unit for detecting a voltage generated between the first magnetic layer and the second magnetic layer while the current is supplied thereto.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 17, 1998
    Assignee: Hitachi, Ltd.
    Inventors: Masahiro Kasai, Yuzo Kozono, Yoko Kanke, Toshiyuki Ohno, Masanobu Hanazono
  • Patent number: 5721196
    Abstract: A Josephson junction device comprises a single crystalline substrate including a principal surface, an oxide layer formed on the principal surface of the substrate having a step on its surface and an oxide superconductor thin film formed on the surface of the oxide layer. The oxide superconductor thin film includes a first and a second portions respectively positioned above and below the step of the oxide layer, which are constituted of single crystals of the oxide superconductor, and a step-edge junction made up of a grain boundary on the step of the oxide layer, which constitutes a weak link of the Josephson junction.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: February 24, 1998
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Takao Nakamura, Michitomo Iiyama
  • Patent number: 5721197
    Abstract: A microelectronic thin-film device having a thin superconducting layer in contact with a thin quasi-insulating conversion layer. The critical current of the superconducting layer is controlled by application of a voltage to the conversion layer by means of a gate electrode, causing the conversion layer to undergo an insulator-metal transition.
    Type: Grant
    Filed: October 6, 1995
    Date of Patent: February 24, 1998
    Assignee: Dornier GmbH
    Inventors: Hartmut Downar, Werner Scherber, Thomas Peterreins, Paul Ziemann
  • Patent number: 5712227
    Abstract: A substrate having a superconducting thin film of compound oxide thereon. An intermediate layer consists of at least one layer of copper-containing oxide is interposed between the substrate and the superconducting thin film.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: January 27, 1998
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Kenjiro Higaki, Keizo Harada, Takashi Matsuura, Hitoshi Oyama, Hideo Itozaki, Shuji Yazu
  • Patent number: 5696392
    Abstract: A conductor suitable for use in oxide-based electronic devices and circuits is disclosed. Metallic oxides having the general composition AMO.sub.3, where A is a rare or alkaline earth or an alloy of rare or alkaline earth elements, and M is a transition metal, exhibit metallic behavior and are compatible with high temperature ceramic processing. Other useful metallic oxides have compositions (A.sub.1-x A'.sub.x)A".sub.2 (M.sub.1-y M'.sub.y).sub.3 O.sub.7-.delta. or (A.sub.1-x A'.sub.x).sub.m (M.sub.1-y M'.sub.y).sub.n O.sub.2m+n, where 0.ltoreq.x, y.ltoreq.1 and 0.5.ltoreq.m, n.ltoreq.3, A and A' are rare or alkaline earths, or alloys of rare or alkaline earths, A' and A" are alkaline earth elements, alloys of alkaline earth elements, rare earth elements, alloys of rare earth elements, or alloys of alkaline earth and rare earth elements, and M and M' are transition metal elements or alloys of transition metal elements.
    Type: Grant
    Filed: November 28, 1994
    Date of Patent: December 9, 1997
    Assignee: Conductus, Inc.
    Inventors: Kookrin Char, Theodore H. Geballe, Brian H. Moeckly
  • Patent number: 5691279
    Abstract: c-axis oriented high temperature superconductors are deposited onto new compositions of garnets using pulsed laser deposition (PLD) with conditions of 85 mTorr of oxygen partial pressure; a block temperature of 730.degree. C., a substrate surface temperature of 790.degree. C. and a laser fluence of 1 to 2 Joules/cm.sup.2 at the target, a laser repetition rate of 10 Hz and a target to substrate distance of 7 cm and in which the a and b lattice parameters of the new compositions of garnets exhibit a mismatch of less than 7 percent with the a and b lattice parameters of the HTSC.
    Type: Grant
    Filed: April 18, 1995
    Date of Patent: November 25, 1997
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Arthur Tauber, Steven C. Tidrow
  • Patent number: 5677264
    Abstract: The present invention discloses a process for forming an a-axis superconducting junction by adjusting the deposition temperature of an oxide normal conductor layer/and oxide superconductor layer/an oxide insulating layer/an oxide normal conductor layer/and an oxide superconductor layer, which are sequentially multilayered on an oxide single crystalline substrate. According to the present invention, the oxide superconductor layer and the oxide insulating layer have an a-axis oriented perpendicularly, and the oxide normal conductor layer have a b-axis oriented perpendicularly, so that a superconductor Josephson junction may be obtained.
    Type: Grant
    Filed: August 13, 1996
    Date of Patent: October 14, 1997
    Assignee: Electronics & Telecommunications Research Institute
    Inventors: Jeong-Dae Suh, Gun-Yong Sung
  • Patent number: 5654259
    Abstract: The substance has a composition of a general chemical formula ofBi.sub.2 -(Sr.sub.2 Ca.sub.1).sub.1-x (La.sub.2 Y.sub.1).sub.x -Cu.sub.y -O.sub.z,where 0.4.ltoreq.x.ltoreq.1, y=2 and z=9-10.5, wherein the substance is an insulator or a semiconductor in the dark, and has a photoconductivity Q(.lambda.,T) in conjugate with superconductivity of a superconductor of an adjacent component of the Bi-SrCa-LaY-Cu-O system at and below a critical temperature (T) of less than 105.degree.-115.degree. K. and below 65.degree.-85.degree. K. at photoexcitation in an optical wavelength range (.lambda.) of 420-670 nm. The present invention relates to a method for producing the same and a superconductive optoelectronic device by using the same. The present invention also relates to an organized integration of the element or device into an apparatus to further develop a new field of "Superconductive Optoelectronics.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 5, 1997
    Assignee: The University of Tokyo
    Inventor: Taizo Masumi
  • Patent number: 5650378
    Abstract: The present invention relates to a polycrystalline thin film deposit acting as a substrate material composed of grains of a cubic structure in which the intergranular misorientation, defined as the orientation difference between the a-axes (or b-axes) of the neighboring grains, is less than 30 degrees. Such a substrate base is produced by depositing a target material on a base material by sputtering while irradiating the substrate base with ion beams at an oblique angle to the base. The preferred range of the oblique angle is between 40 to 60 degrees. Examples are presented of application of such textured polycrystalline substrate base for the production of superconducting oxide thin layer of outstanding superconducting properties.
    Type: Grant
    Filed: August 3, 1995
    Date of Patent: July 22, 1997
    Assignee: Fujikura Ltd.
    Inventors: Yasuhiro Iijima, Nobuo Tanabe
  • Patent number: 5650377
    Abstract: Fine epitaxial patterns of yttrium barium copper oxide on a strontium titanate substrate are provided by using a silicon nitride mask to define the pattern to be formed. A thin film of yttrium barium copper oxide is placed on the silicon nitride mask and exposed portions of strontium titanate substrate. Where the yttrium barium copper oxide is in contact with the silicon nitride mask, it is nonepitaxial in crystal structure. Where the yttrium barium copper oxide contacts the strontium titanate substrate in the openings, it is epitaxial in structure forming fine patterns that become superconducting below the critical transition temperature. A channel can be formed in the strontium titanate substrate. The epitaxial yttrium barium copper oxide pattern is formed in this channel to minimize possible exposure to the silicon nitride mask.
    Type: Grant
    Filed: October 5, 1993
    Date of Patent: July 22, 1997
    Assignee: International Business Machines Corporation
    Inventors: Dieter Paul Kern, Robert Benjamin Laibowitz, Kim Yang Lee, Mark I. Lutwyche
  • Patent number: 5650376
    Abstract: A superconducting film is disclosed which has the following composition:(Nd, Ba).sub.3 Cu.sub.3 O.sub.7-dwhere d is a number greater than 0 but smaller than 0.5. The superconducting film has the same crystal structure as that of YBa.sub.2 Cu.sub.3 O.sub.7 except that part of the Nd sites and/or part of the Ba sites are occupied by Ba and Nd atoms, respectively.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: July 22, 1997
    Assignee: International Superconductivity Technology Center
    Inventors: Massoud Badaye, Tadataka Morishita, Youichi Enomoto, Shoji Tanaka
  • Patent number: 5635730
    Abstract: A superconducting oxide thin film device is composed of a LaAlO.sub.3 substrate and a YBCO thin film with a BaCeO.sub.3 buffer layer disposed between the two. The adhesion between the film and the substrate is increased by the presence of the buffer layer. The buffer layer also inhibits peeling of the film from the substrate and diffusion of Ba from the film into the substrate.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: June 3, 1997
    Assignee: Advanced Mobile Telecommunication Technology Inc.
    Inventor: Nobuyoshi Sakakibara
  • Patent number: 5629267
    Abstract: A superconducting element is disclosed which comprises a lower superconducting layer, an upper superconducting layer, and an intermediate layer interposed between the lower and upper superconducting layers. The lower and upper superconducting layers are both form of a superconducting cuprate. The intermediate layer is formed of a layered cuprate containing in the crystal structure thereof multiple fluorite blocks represented by the formula:[B]AE.sub.2 (RE1.sub.1-y RE2.sub.y).sub.m+1 Cu.sub.2 O.sub.z(wherein [B] stands for a block layer, AE for an alkaline earth element, RE1 for at least one element selected from the group consisting of lanthanide elements and actinoid elements which form ions of valency of larger than 3, RE2 for at least one element selected from the group consisting of lanthanide elements which form ions of valency of 3 and yttrium, m for a number satisfying the expression m.gtoreq.2, y for a number satisfying the expression 0.ltoreq.y<1, and z for the oxygen content).
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: May 13, 1997
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Sumio Ikegawa, Tadao Miura
  • Patent number: 5629268
    Abstract: A process for depositing successively a plurality of thin films on a bottom superconductor layer made of oxide superconductor deposited on a substrate in a single chamber under a condition, the bottom superconductor layer is heated in ultra-high vacuum at a temperature which is lower than the oxygen-trap temperature (T.sub.trap) at which oxygen enter into the oxide superconductor but higher than a temperature which is lower by 100.degree. C. than the oxygen-trap temperature (T.sub.trap -100.degree. C.) and then the first thin film is deposited thereon.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: May 13, 1997
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: So Tanaka, Takao Nakamura, Michitomo Iiyama
  • Patent number: 5627139
    Abstract: A HTSC Josephson device wherein the barrier layer is a cubic, conductive material.
    Type: Grant
    Filed: March 17, 1995
    Date of Patent: May 6, 1997
    Assignee: The Regents of the University of California
    Inventors: David K. Chin, Theodore Van Duzer
  • Patent number: 5595960
    Abstract: A method of preparing a substrate with a view to depositing a thin layer of a superconductive material thereon, wherein an operation is performed of depositing on the substrate an intermediate material having the property of having a crystal lattice constant that is a function of the percentage of a doping element, the depositing operation being initiated with a concentration of the doping element such that the lattice constant of the intermediate material is equal to or as close as possible to the lattice constant of the substrate, the proportion of the doping element being continuously varied during the depositing operation to a proportion of the doping element such that the lattice constant of the intermediate material is equal to or as close as possible to the lattice constant of the superconductive material.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: January 21, 1997
    Assignee: Alcatel Alsthom Compagnie Generale d'Electricite
    Inventors: Christian Belouet, Didier Chambonnet
  • Patent number: 5593951
    Abstract: An epitaxial structure comprising a silicon containing substrate and a high T.sub.c copper-oxide-based superconducting layer, which may include an intermediate layer between the silicon substrate and the superconductor layer. Epitaxial deposition is accomplished by depositing a superconductor on a (001) surface of silicon in a manner in which the unit cell of the superconductor layer has two out of three of its crystallographic axes rotated 45 degrees with respect to the corresponding axes of the silicon unit cell, the remaining axis of the superconductor unit cell being normal to the Si (001) surface.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: January 14, 1997
    Assignee: International Business Machines Corporation
    Inventor: Franz J. Himpsel
  • Patent number: 5593950
    Abstract: A lattice matching device includes a substrate having thereon monocrystal regions having different lattice mismatches with respect to a LnBa.sub.2 Cu.sub.3 O.sub.x superconductor. A superconducting thin film is formed on the substrate, which film consists essentially of a superconductor of LnBa.sub.2 Cu.sub.3 O.sub.x wherein Ln represents yttrium or a lanthanide, and 6<x<7. The first and second superconducting thin film portions have different axes of orientation perpendicular to a main surface of the substrate, and arranged in contact with each other or at a distance which allows transmission of electron pairs from one to another.
    Type: Grant
    Filed: July 27, 1993
    Date of Patent: January 14, 1997
    Assignee: Nippon Telegraph & Telephone Corporation
    Inventors: Masashi Mukaida, Shintaro Miyazawa, Junya Kobayashi