Ester Is Higher Fatty Or Carboxylic Acid Ester (e.g., Sorbitan Oleate, Etc.) Patents (Class 507/218)
  • Patent number: 9222344
    Abstract: Methods treating a subterranean formation including providing a one-step acidizing treatment fluid comprising a first aqueous base fluid, a formation stimulation agent, and a stabilizing emulsion, wherein the stabilizing emulsion is an aqueous external emulsion comprising a second aqueous base fluid, a surfactant, and an aqueous-based surface modification agent; introducing the one-step acidizing treatment fluid into the subterranean formation; contacting the formation stimulation agent with the subterranean formation so as to acidize the subterranean formation and create conductive channels therethrough; and contacting the stabilizing emulsion with the subterranean formation so as to release the aqueous-based surface modification agent and stabilize unconsolidated formation particulates therein.
    Type: Grant
    Filed: May 21, 2013
    Date of Patent: December 29, 2015
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Loan K. Vo, Philip D. Nguyen, Christopher R. Parton
  • Publication number: 20140303047
    Abstract: A method of servicing a wellbore in a subterranean formation comprising preparing a wellbore servicing fluid comprising (i) a breaking agent, a breaking agent precursor, or combinations thereof, wherein the breaking agent comprises a sugar acid and (ii) an aqueous base fluid, and contacting the wellbore servicing fluid with a filter cake in the wellbore and/or subterranean formation.
    Type: Application
    Filed: April 5, 2013
    Publication date: October 9, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Cato Russell MCDANIEL, Eric DAVIDSON
  • Publication number: 20140096969
    Abstract: A method is described for treating a formation adjacent a subterranean well with a treatment fluid composition imparted with emulsion formation prevention properties. A microemulsion additive is mixed into a treatment fluid component to form a volume of a treatment fluid composition having emulsion formation prevention properties. The microemulsion additive is composed of a mixture solvent, a co-solvent, a mutual solvent, a non-emulsifier, a non-ionic surfactant, a non-ionic co-surfactant, alcohol, an emulsifying surfactant, and an aqueous fluid. The volume of the fluid composition is then injected into the subterranean well and contacts the formation, whereby the microemulsion additive in the treatment fluid volume acts to prevent emulsion formation in the formation.
    Type: Application
    Filed: October 4, 2012
    Publication date: April 10, 2014
    Inventors: Syed Afaq Ali, Yenny Christanti
  • Publication number: 20140073537
    Abstract: Of the many methods and compositions provided herein, one method includes a method comprising introducing a sealant composition into a well bore that penetrates a subterranean formation, wherein the sealant composition comprises a base fluid, a binder material, and a filler material; and allowing the sealant composition to form a cohesive sealant. One composition provided herein includes a sealant composition comprising a base fluid, a binder material, and a filler material, wherein the sealant composition will form a cohesive sealant.
    Type: Application
    Filed: November 12, 2013
    Publication date: March 13, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Krishna M. Ravi, Gunnar Lende
  • Publication number: 20130137610
    Abstract: Incorporating water-based polymer breakers, such as oxidizers, enzymes and/or acids, into a mixture of an oil and oil-soluble surfactants creates an emulsion that can then perform as a dual-functional breaker for reducing the viscosity of hybrid fluids gelled with both a viscoelastic surfactant (VES) and a polymer. The outer phase of the dual-functional breaker emulsion is oil, e.g. a mineral oil, containing an oil-soluble surfactant that will, over time and with heat, break the VES portion of the gel. As it does so, the polymer breaker in the internal aqueous phase will be released to then break the polymer portion of the gel. The polymer breaker will not start to break the polymer gel before the oil-soluble surfactant starts to break the VES gel. The overall breaking using the emulsion is slower as compared to introducing the polymer breaker and the oil-soluble surfactant in a non-emulsified form.
    Type: Application
    Filed: January 24, 2013
    Publication date: May 30, 2013
    Applicant: Baker Hughes Incorporated
    Inventors: Tianping Huang, James B. Crews
  • Publication number: 20130109598
    Abstract: A composition for use in extracting oil, the composition comprising: (a) a mixture comprising, by weight, 50-55% of an aromatic alkyl, 15-19% d-limonene, 6.5-7% polyethylsorbitan monoleate, 15-15.5% PEG sorbitan monostearate, 3.4-9.9% tall fatty acid, and EDTA in an amount up to 1%; and (b) water in an amount such that the mixture is diluted to 1%-2% by weight of the composition.
    Type: Application
    Filed: September 14, 2012
    Publication date: May 2, 2013
    Inventor: Sabatino Nacson
  • Publication number: 20120073817
    Abstract: Of the methods provided in this invention, one method includes: providing a treatment fluid comprising: an aqueous fluid, a microemulsion surfactant, and an amphiphilic polymer, wherein the amphiphilic polymer comprises a hydrophobic component, and a hydrophilic component; and introducing the treatment fluid into a subterranean formation, wherein the microemulsion surfactant forms a microemulsion that comprises the amphiphilic polymer within the subterranean formation.
    Type: Application
    Filed: September 23, 2010
    Publication date: March 29, 2012
    Inventor: Ryan van Zanten
  • Publication number: 20100273685
    Abstract: Methods comprising: providing a degradable polymer within a portion of a subterranean formation; introducing a base solution into the portion of the subterranean formation, wherein the base solution comprises at least one base selected from the group consisting of: ammonium hydroxide, an alcoholic alkaline solution, and an alkaline amine solution, and derivatives thereof; and allowing the base solution to degrade the degradable polymer.
    Type: Application
    Filed: April 22, 2009
    Publication date: October 28, 2010
    Inventors: Rajesh K. Saini, Bradley L. Todd
  • Publication number: 20100147515
    Abstract: A method and apparatus for treating a subterranean formation with a fluid, including forming a fluid including a organosilane and a particulate and introducing the fluid into a subterranean formation with exposed surfaces, wherein the organosilane modifies the particulate or surfaces or both. Also, a method and apparatus for treating a subterranean formation with a fluid, including forming a fluid including an organosilane and introducing the fluid into a subterranean formation with exposed surfaces, wherein the organosilane modifies the surfaces with a first functional group.
    Type: Application
    Filed: December 15, 2009
    Publication date: June 17, 2010
    Inventors: Trevor Lloyd Hughes, Michael J. Fuller, Jill F. Geddes
  • Patent number: 7727938
    Abstract: A method of treating an earth formation that includes injecting at least one lipophilic monomer into the earthen formation; wherein the at least one lipophilic monomer is selected from epoxide-functionalized derivative of soybean oil, linseed oil, rapeseed oil, cashew nut shell oil; perilla oil, tung oil, oiticia oil, safflower oil, poppy oil, hemp oil, cottonseed oil, sunflower oil, high-oleic triglycerides, triglycerides of euphorbia plants, peanut oil, olive oil, olive kernel oil, almond oil, kapok oil, hazelnut oil, apricot kernel oil, beechnut oil, lupine oil, maize oil, sesame oil, grapeseed oil, lallemantia oil, castor oil, herring oil, sardine oil, menhaden oil, whale oil, and tall oil, injecting at least one crosslinking agent into the earthen formation; wherein the at least one crosslinking agent comprises at least one primary amine; and allowing the lipophilic monomer and the crosslinking agent to react in the earth formation is disclosed.
    Type: Grant
    Filed: June 8, 2007
    Date of Patent: June 1, 2010
    Assignee: M-I L.L.C.
    Inventor: David Antony Ballard
  • Patent number: 7622427
    Abstract: A completion and workover fluid composition comprising, water and at least one rheology modifier and/or fluid loss control agent, and at least one other ingredient selected from the group consisting of inorganic salts, shale inhibitors, corrosion inhibitor, biocide, defoamers and finely divided solids particles (e.g., bentonite, attapulgite, sepiolite, calcium carbonate, etc.), depending upon the desired attributes, wherein the rheology modifier and/or the fluid loss control agent is an ethoxylated raw cotton linters or a modified ethoxylated raw cotton linters. The ethoxylated raw cotton linters provides comparable or better rheology and viscosity properties compared to high molecular weight commercial HECs made from purified cotton linters. These ethoxylated raw cotton linters derivatives are suitable for applications in oil-well servicing fluids, particularly to enhance functional properties of completion and workover fluids used during oil-well drilling operations.
    Type: Grant
    Filed: February 21, 2007
    Date of Patent: November 24, 2009
    Assignee: Hercules Incorporated
    Inventors: Arjun C. Sau, Mohand Melbouci
  • Publication number: 20090163389
    Abstract: An aqueous composition for treating hydrocarbon wells contains (a) a scale inhibitor and (b) a viscoelastic surfactant, and further contains from 0 to less than 1% by weight of acid selected from the group consisting of hydrochloric acid, sulfuric acid, phosphoric acid, formic acid, acetic acid, citric acid, maleic acid, hydrofluoric acid, and mixtures thereof.
    Type: Application
    Filed: November 30, 2007
    Publication date: June 25, 2009
    Inventors: Floryan De Campo, Allwyn Colaco, Bruno Langlois, Chris Jones, Gary Woodward
  • Publication number: 20090143256
    Abstract: Methods for creating a fluid diverting barrier in a zone of a subterranean formation are provided. Certain methods comprise providing a treatment fluid that comprises an aqueous base fluid, a viscoelastic surfactant, and a soap component; placing the treatment fluid in a subterranean formation penetrated by a well bore; and allowing the soap component of the treatment fluid to interact with a metal ion present in the subterranean formation to form a precipitate.
    Type: Application
    Filed: January 28, 2009
    Publication date: June 4, 2009
    Inventors: Thomas D. Welton, Bobby J. Burns
  • Publication number: 20090082228
    Abstract: A well treatment fluid and method uses an organic peroxide. An activator embodiment can lower an effective concentration of the peroxide to break the fluid. A weight ratio of activator:organic peroxide can be at least about 1:20 in one well treatment fluid embodiment. A peroxyester breaker embodiment can be used in a well treatment fluid and method. A breaker delay agent embodiment can control the polymer break window in a well treatment fluid and method using an organic peroxide. A breaker package embodiment used in a well treatment fluid and method can include an organic peroxide and an amine breaker delay agent having the formula RR1NR2 wherein R, R1 and R2 are independently selected from hydrogen, alkyl, hydroxyalkyl, and combinations thereof.
    Type: Application
    Filed: September 17, 2008
    Publication date: March 26, 2009
    Inventors: Michael D. Parris, Andrey Mirakyan, Yiyan Chen, Carlos Abad
  • Publication number: 20080287324
    Abstract: Disclosed is a method for treating an oil or gas well having a wellbore that includes the steps of forming a solvent-surfactant blend by combining a solvent and a surfactant, adding a diluent to the solvent-surfactant blend to form an emulsified solvent-surfactant blend; combining the emulsified solvent-surfactant blend with a water-based carrier fluid to form a well treatment microemulsion, and injecting the well treatment microemulsion into the oil or gas well. In a preferred embodiment, the step of forming a solvent-surfactant blend includes combining a surfactant with a solvent selected from the group consisting of terpenes and alkyl or aryl esters of short chain alcohols.
    Type: Application
    Filed: May 30, 2008
    Publication date: November 20, 2008
    Applicant: CESI Chemical, Inc., A Flotek Company
    Inventors: John Thomas Pursley, David L. Holcomb, Glenn S. Penny
  • Publication number: 20080182763
    Abstract: Pumpable multiple phase vesicle compositions carry agents and components downhole or through a conduit, and controllably releasing them at a different place and time by breaking the compositions. In one non-limiting embodiment the pumpable multiple phase vesicles have a third phase containing a first phase which bears the agent to be controllably released. The first and third phases of the vesicles are separated by a surface active material bilayer that forms the second phase. The pumpable multiple phase vesicles may have internal and external phases that are both oil miscible, both aqueous miscible, or both alcohol miscible. The surface active material bilayer may be composed of compounds such as phospholipids, alkyl polyglycosides, gemini surfactants, sorbitan monooleate, sorbitan trioleate, and many others. The agent may be released by one or more of a variety of mechanisms.
    Type: Application
    Filed: April 3, 2008
    Publication date: July 31, 2008
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Ronald G. BLAND, Lirio QUINTERO
  • Publication number: 20080171671
    Abstract: The invention relates to the use of ethoxylated derivatives of amidoamines corresponding to general formula (I): R1—OC—NR2—[(CH2)n—NR3]m—CO—R4 ??(I) In which R1, R2, R3 and R4 independently of one another represent a hydrogen atom, a branched or unbranched alkyl or alkenyl group containing 5 to 23 carbon atoms or a CO—CH=CH—COOH group and n is a number of 1 to 6 and m is a number of 1 to 8, as an emulsifier in drilling fluids which contain at least one continuous oil phase, an aqueous phase and typical additives.
    Type: Application
    Filed: October 14, 2005
    Publication date: July 17, 2008
    Inventors: Heinz Mueller, Jens Hartmann, Stephan Von Tapavicza, Diana Maeker
  • Publication number: 20080161210
    Abstract: Among many things, in some embodiments, improved viscoelastic surfactant gels that comprise non-aqueous tackifying agents, and their associated methods of use, are provided. In one embodiment, the methods comprise: providing a treatment fluid that comprises an aqueous base fluid, a non-aqueous tackifying agent, and a viscoelastic surfactant; and introducing the treatment fluid into a subterranean formation.
    Type: Application
    Filed: December 29, 2006
    Publication date: July 3, 2008
    Inventors: Thomas D. Welton, Jason E. Bryant
  • Patent number: 7354886
    Abstract: Pumpable multiple phase vesicle compositions carry agents and components downhole or through a conduit, and controllably releasing them at a different place and time by breaking the compositions. In one non-limiting embodiment the pumpable multiple phase vesicles have a third phase containing a first phase which bears the agent to be controllably released. The first and third phases of the vesicles are separated by a surface active material bilayer that forms the second phase. The pumpable multiple phase vesicles may have internal and external phases that are both oil miscible, both aqueous miscible, or both alcohol miscible. The surface active material bilayer may be composed of compounds such as phospholipids, alkyl polyglycosides, gemini surfactants, sorbitan monooleate, sorbitan trioleate, and many others. The agent may be released by one or more of a variety of mechanisms.
    Type: Grant
    Filed: October 13, 2004
    Date of Patent: April 8, 2008
    Assignee: Baker Hughes Incorporated
    Inventors: Ronald G. Bland, Lirio Quintero
  • Publication number: 20070287636
    Abstract: A drilling fluid compound, for use as an additive in a water-based drilling mud system, comprises a neat (B100) biodiesel liquid at a concentration of at least 5% by volume, and is useful in downhole applications such as lubrication, spotting, shale inhibition, fluid loss control, and rate of penetration enhancement. A base fluid for a synthetic-based drilling mud system comprises a B100 biodiesel liquid at a concentration of at least 5% by volume. A polyalphaolefin, another isomerized olefin, a petrodiesel, a mineral oil, a mineral oil derivative, or combinations thereof, may also be included in the drilling fluid compound or in the base fluid, within suitable ranges. The compositions of matter satisfy the current environmental standards defined by the U.S. Environmental Protection Agency for drilling fluids.
    Type: Application
    Filed: June 7, 2007
    Publication date: December 13, 2007
    Applicant: Sun Drilling Products Corporation
    Inventors: Douglas P. Heller, Jozef Bicerano, Jimmy Earl Priest
  • Patent number: 7229950
    Abstract: A method of treating a hydrocarbon containing formation is described. The method may include providing a hydrocarbon recovery composition to the hydrocarbon containing formation. Hydrocarbons in the hydrocarbon containing formation may interact with the hydrocarbon recovery composition. The hydrocarbon recovery composition may include an aliphatic anionic surfactant and an aliphatic nonionic additive. In some embodiments, an aliphatic anionic surfactant may be branched. In other embodiments, an aliphatic nonionic additive may be branched.
    Type: Grant
    Filed: April 20, 2006
    Date of Patent: June 12, 2007
    Assignee: Shell Oil Company
    Inventors: Paul Gregory Shpakoff, Kirk Herbert Raney
  • Patent number: 7094736
    Abstract: A method of separating from a mixture of oil-based drilling fluid and sample of formation hydrocarbon, the liquid component of the drilling fluid, which method comprises treating, e.g. chemically, the mixture in a way that selectively substantially affects the liquid component of the drilling fluid, producing one or more treatment products, while leaving the formation hydrocarbon substantially unaffected; and separating the treatment products from the formation hydrocarbon, by solvent extraction. The liquid component of the drilling fluid conveniently comprises one or more esters (which do not occur in significant quantities in naturally occuring formation hydrocarbons) and which can be hydrolysed to give water-soluble products readily removable from the formation hydrocarbon. The invention is applicable to sampling of formation hydrocarbon using wireline formation testers or sampling tools.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: August 22, 2006
    Assignee: Schlumberger Technology Corporation
    Inventors: Timothy Gareth John Jones, Gary John Tustin
  • Publication number: 20040224854
    Abstract: A method and composition are described for improving recovery of oil from an oil reservoir. The method includes adding an effective amount of a fatty acid alkyl ester oil recovery composition to an oil reservoir and recovering oil from the reservoir. The composition may include in predominant proportion a fatty acid alkyl ester as well as effective concentrations of a surfactant, a colloid, and an acid. One exemplary composition includes 96% soy methyl ester, 3% surfactant, and 1% vinegar.
    Type: Application
    Filed: June 9, 2004
    Publication date: November 11, 2004
    Inventor: Edward L. Boudreau
  • Patent number: 6555506
    Abstract: A method of preventing corrosion in pipelines comprising draining pipeline of all residual compounds, blowing through with nitrogen and rinsing with a corrosion inhibiting rinsing agent.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: April 29, 2003
    Assignee: Illinois Tool Works Inc.
    Inventors: William Hopkins, Christopher Nettleship
  • Patent number: 6180572
    Abstract: The invention relates to the use of oil-soluble oleophilic organic liquid phases—flowable at temperatures of 0 to 10° C.—from the classes of corresponding monocarboxylic and/or polycarboxylic acid esters, carbonic acid esters, fatty alcohols and their oligoalkoxides and/or ethers as the at least predominant part of the liquid phase in storage-stable homogeneous mixtures with guar and/or water-soluble guar derivatives for their use in water-based borehole servicing fluids.
    Type: Grant
    Filed: December 28, 1998
    Date of Patent: January 30, 2001
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz Mueller, Claus-Peter Herold, Stephan von Tapavicza
  • Patent number: 5756004
    Abstract: The present invention provides improved quaternary ammonium compounds useful as metal corrosion inhibitors in aqueous acid solutions, methods of preparing the compounds, metal corrosion inhibited aqueous acid solutions containing the compounds and methods of protecting metal surfaces from acid corrosion using the compounds. The compounds are prepared by contacting the still bottoms residue produced in the distillation of quinoline from coal tar with oxygen to oligomerize aromatic amines contained therein and then reacting the oligomerized amines with a benzylhalide.
    Type: Grant
    Filed: May 13, 1997
    Date of Patent: May 26, 1998
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Michael M. Brezinski
  • Patent number: 5723423
    Abstract: Compositions comprising (a) a surfactant and (b) a diluent oil are employed in oil-based drilling fluids and processes for cleaning oil-contaminated substrates (e.g., oil-contaminated animals, drill cuttings) as well as in processes for cementing well casings, enhanced oil recovery, and lifting oil from wellbores.
    Type: Grant
    Filed: March 12, 1996
    Date of Patent: March 3, 1998
    Assignee: Union Oil Company of California, dba UNOCAL
    Inventor: Donald C. Van Slyke
  • Patent number: 5710108
    Abstract: The invention involves biopolymer/oil suspension compositions for the oil service industry, most particularly drilling and completion fluids, which provide such fluids a variety of desirable properties. Biopolymers include water soluble polymers and water swellable polymers. Such biopolymer/oil suspension compositions are essentially mixtures of biopolymers such as cellulosics in an oil medium with a specific anti-settling additive. The invention is particularly directed to providing enhanced anti-settling properties to such biopolymer/oil compositions; that is, the ability of the biopolymer/oil composition to retain the biopolymers in suspension prior to the composition being introduced into drilling and completion fluids. The invention in one embodiment is described as a liquid biopolymer-in-oil additive compositions for use in aqueous-based completion fluids, containing an agent comprising: a) one or more polyamides, and b) hydrogenated caster oils including castorwax.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: January 20, 1998
    Assignee: Rheox, Inc.
    Inventors: Keith McNally, James Gambino, Charles Cody, Wilbur Mardis
  • Patent number: 5618780
    Abstract: The present invention relates to an optimized lubricating composition including, in useful amount, an ester and a fatty acid, and optionally, the invention also relates to a well fluid including the lubricating composition according to the invention and the use of the composition for controlling the lubricity of a water-base fluid.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: April 8, 1997
    Assignee: Institut Francais Du Petrole
    Inventors: Jean-Fran.cedilla.ois Argillier, Annie Audibert, Pierre Marchand, Andr e Demoulin, Michel Janssen