Abstract: Drill-in fluids disclosed herein comprise an aqueous base fluid, a viscosifier, a fluid loss control additive, and a degradable bridging agent comprising a degradable high strength polymetaphosphate material capable of undergoing an irreversible degradation downhole. The present disclosure further relates to a method for controlling fluid loss through a subterranean surface by using the drill-in fluid for form a filter cake on the subterranean surface. Also provided is a method of degrading a filter cake with an aqueous fluid or aqueous acidic fluid, wherein the filter cake is produced from the drill-in fluid. Further provided is a specific order of addition of constituents of the drill-in fluid, which results in improved filter cake performance and/or filter cake removal.

Abstract: An aqueous modified acid composition for use in oil industry activities, said composition comprising: an amino acid, an alkanolamine and strong acid wherein the mineral acid: alkanolamine/amino acid are present in a molar ratio of not more than 15:1, preferably not more than 10:1; it can also further comprise a metal iodide or iodate. Said composition demonstrates advantages over known conventional acids and modified acids.

Abstract: Proppant embedment can sometimes be problematic during fracturing operations. A partially oxidized, amine-functionalized polysaccharide comprising a plurality of oxidatively opened monosaccharide units and bearing an amine moiety at one or more sites of oxidative opening may lessen the amount of proppant embedment that occurs. Fracturing methods may comprise providing a fracturing fluid comprising such a partially oxidized, amine-functionalized polysaccharide and a plurality of proppant particulates, introducing the fracturing fluid into a subterranean formation at a hydraulic pressure sufficient to create or extend one or more fractures therein, such that at least a portion of the plurality of proppant particulates become localized in the one or more fractures, and releasing the hydraulic pressure. Upon releasing the hydraulic pressure, embedment of the proppant particulates in a face of the one or more fractures is about 10% to about 40% of a grain size of the proppant particulates.

Abstract: An aqueous cross-linking suspension composition having brine, water-soluble suspending agent and borate cross-linker in a single package and methods for using the package composition for increasing the efficiency of fracturing subterranean formations and effectively delivering borate cross-linkers.

Abstract: Corrosion inhibitor compositions and methods for inhibiting corrosion on a metal surface exposed to a hydrocarbon fluid are provided. The corrosion inhibition composition can comprise tetrafluoroterephthalic acid, dimethyl sulfoxide, and heavy aromatic naphtha. The corrosion inhibitor composition can be phosphate-free and can inhibit naphthenic acid corrosion. In the methods, the corrosion inhibitor composition is added to the hydrocarbon fluid exposed to the metal surface to prevent or inhibit corrosion on the metal surface, including naphthenic acid corrosion.

Abstract: The present invention relates to the use of a sequenced polymer as an agent for monitoring the filtrate in a fluid injected under pressure into an oil rock, wherein the fluid comprises solid particles and/or is brought into contact with solid particles within the oil rock after being injected, the polymer comprising at least three blocks, including: at least one first block which is adsorbed, preferably irreversibly, onto at least some of the particles (p); a second block (B) having a composition other than that of the first and a mean molecular weight of more than 10,000 g/mol, and which is soluble in the fluid (F); and at least one third block of type (A) or type (B).

Abstract: Lost circulation material (LCM) and method including LCM objects each having a centrally-disposed solid core and tentacles extending from the solid core to entangle with tentacles of neighboring LCM objects to treat loss circulation in a wellbore in a subterranean formation. The LCM as solid cores and entangled tentacles at the loss circulation zone collects solids from wellbore fluid to form a barrier to treat the loss circulation.

Abstract: A method of servicing a wellbore penetrating a subterranean formation, comprising placing into the wellbore a wellbore servicing fluid comprising a superabsorbent starch hydrogel (SSH) and an aqueous fluid, wherein the SSH is formed from an SSH reaction mixture comprising a starch, a crosslinker, a base, and water.

Abstract: An aqueous modified acid composition for use in oil industry activities, said composition comprising: an amino acid, an alkanolamine and strong acid wherein the mineral acid:alkanolamine/amino acid are present in a molar ratio of not more than 15:1, preferably not more than 10:1; it can also further comprise a metal iodide or iodate. Said composition demonstrates advantages over known conventional acids and modified acids.

Abstract: Technologies relating to increasing hydraulic fracturing efficiencies in subterranean zones by degrading organic matter, such as kerogen, are described. A method for treating kerogen in a subterranean zone includes placing a composition in the subterranean zone, and the composition includes an oxidizer including sodium bromate and an additive including a tetrasubstituted ammonium salt.

Abstract: A process for making and using a ground product that includes the steps of: reacting a guar split with propylene oxide at a reaction temperature in a range of 120° F. to 180° F. to form a guar derivative; and treating the guar derivative with at least one of washing and drying to form a resultant treated derivative. The process includes transferring the resultant treated derivative to a co-grinder operably associated with a heated vacuum system; and co-grinding the resultant treated derivative with a powdered carboxylic acid to form a ground product.

Abstract: The present application provides an aqueous fluid containing a gas-generating compound such as an azo compound, a hydrazide compound, or a semicarbazide compound. The aqueous fluid may also contain an amine compound, an oxidizer, or viscosifier, and a foaming surfactant. The aqueous composition may be storable at pH of less than about 5 without any appreciable gas generation, and may be activated to produce gas when mixed with a wellbore fluid for use in downhole applications.

Abstract: A method of making a solution including poly(ethylene terephthalate). The method includes dissolving poly(ethylene terephthalate) in a solvent mixture to form a solution, the solvent mixture including two solvent components. A Hansen Solubility Parameter Distance between the solvent mixture and HSP coordinates having a dispersion HSP of 18.02 MPa0.5, a polar HSP of 5.56 MPa0.5, and a hydrogen bonding HSP of 14.27 MPa0.5 is less than about 2 MPa0.5.

Abstract: The invention provides a synergistic surfactant composition comprising: (a) from 5 to 95 wt % of a first surfactant which is selected from derivatives of alkyl polyglucosides and mixtures thereof; and (b) from 5 to 95 wt % of a second surfactant which is selected from: amphoteric surfactants, cationic surfactants, anionic surfactants, non-ionic surfactants, and mixtures thereof. This surfactant composition may be used to generate foam that is used for unloading a liquid from a hydrocarbon reservoir. It may be that the liquid unloading of foam generated using the surfactant composition is greater than that of foam generated from the first and second surfactants when they are foamed individually.

Abstract: The addition of at least one promoter selected from the group consisting of thiosulfate salts, sulfite salts, bisulfite salts, erythorbate salts, isoascorbate salts, and combinations thereof to an aqueous treatment fluid containing a viscosifying polymer and a peroxide helps to promote the activity of the peroxide as a breaker, thus facilitating a reduction in viscosity of the aqueous treatment fluid at lower temperatures than are possible in the absence of the promoter. The promoted aqueous treatment fluid is useful as a fracture fluid to fracture subterranean formations in oil and gas recovery.

Abstract: Methods including preparing a silanization composition comprising an aqueous base fluid and an alkyltrialkoxysilane; coating the silanization composition at least partially onto proppant particulates, thereby forming coated proppant particulates, wherein the silanization composition imparts hydrophobicity to the proppant particulates; and introducing the coated proppant particulates into a subterranean formation. The alkyltrialkoxysilane in the silanization composition may have the formula R1(OR2)3Si, where R1 is a C8 to C22 alkyl chain and R2 is an alkyl group selected from the group consisting of methyl, ethyl, butyl, tert-butyl, isopropyl, and any combination thereof.

Abstract: A method of using a swellable polymer downhole may include introducing a first treatment fluid comprising a first aqueous fluid, a salt with a multivalent cation, and the swellable polymer into a wellbore penetrating a subterranean formation; placing the swellable polymer in a portion of the subterranean formation; contacting the swellable polymer in the portion of the subterranean formation with a second treatment fluid comprising a second aqueous fluid and at least one selected from the group consisting of a precipitating agent, a chelating agent, and a combination thereof; and swelling the swellable polymer in the portion of the subterranean formation, thereby reducing fluid flow through the portion of the subterranean formation.

Abstract: Treatment fluids employing stabilized heteropolysaccharide-based gels in brines are used as part of gravel packing and combined gravel packing-fracturing operations; a method includes providing a treatment fluid which includes an aqueous brine base, a heteropolysaccharide including one selected from the group consisting of diutan, scleroglucan, and succinoglycan, and a protein present in an amount sufficient to stabilize the heteropolysaccharide and hence minimizing the salting out phenomenon, the method including placing the treatment fluid in a subterranean formation.

Abstract: A system for blocking fast flow paths in geological formations includes preparing a solution of colloidal silica having a nonviscous phase and a solid gel phase. The solution of colloidal silica is injected into the geological formations while the solution of colloidal silica is in the nonviscous phase. The solution of colloidal silica is directed into the fast flow paths and reaches the solid gel phase in the fast flow paths thereby blocking flow of fluid in the fast paths.

Abstract: A fluid including: (i) a continuous aqueous phase, wherein the continuous aqueous phase has total dissolved solids in a concentration of at least 30,000 mg/l; (ii) an alkyl amido quaternary amine; (iii) a polymer, wherein the polymer is water-soluble or water-hydratable; and (iv) a crosslinker for the polymer. The continuous aqueous phase of the fluid can include a water source selected from the group consisting of flowback water, produced water, and any combination thereof. Methods include: (A) forming a fluid according to any of the various embodiments of the disclosure, and (B) introducing the fluid into a well. For example, the fluid can be used as a fracturing fluid for fracturing a treatment zone of a well.

Abstract: A hydraulic fracturing fluid for use in oilfield applications, the hydraulic fracturing fluid includes a spherical bead-forming liquid composition, the spherical bead-forming liquid composition comprised of a primary liquid precursor and a secondary liquid precursor, the primary liquid precursor comprises a micellar forming surfactant, a bead-forming compound, and a non-solids bearing liquid solvent; and the secondary liquid precursor comprises one or more curing agents, and one or more co-curing agents.

Abstract: A hydraulic fracturing fluid for use in oilfield applications, where the hydraulic fracturing fluid includes a spherical bead-forming liquid composition, the spherical bead-forming liquid composition comprising a micellar forming surfactant, a bead-forming compound, a non-solids bearing liquid solvent, a pH control agent, and a curing agent.

Abstract: Technical grade acrylic acid derived from renewable resources utilizing a base catalyst system by a process including reacting lactide (or lactic acid oligomers) with methyl acetate to form methyl 2-acetoxypropionate in the presence of a base catalyst such as sodium methoxide, pyrolyzing the methyl 2-acetoxypropionate, with or without a catalyst, to methyl acrylate and acetic acid, transesterifying the mixture to acrylic acid and methyl acetate, separating and purifying the acrylic acid by distillation late in the presence of polymerization inhibitor(s). The disclosed process will produce a “green” (i.e. renewable resources derived) acrylic acid and/or methyl acrylate ester.

Abstract: A method of increasing a stimulated reservoir volume in a wellbore in a gas-containing formation includes the steps of mixing an exothermic reaction component to achieve a pre-selected solution pH, the exothermic reaction component is operable to react at a wellbore temperature to generate a pressure pulse, mixing the exothermic reaction component with a viscous fluid component operable to fracture the gas-containing formation to create fractures, and a proppant component, the proppant component carried to the fractures by the viscous fluid, the proppant component comprises a proppant operable to hold open the fractures, to form a fracturing fluid, injecting the fracturing fluid into the wellbore in the gas-containing formation to create fractures, and generating the pressure pulse when the exothermic reaction component reaches the wellbore temperature, the pressure pulse operable to create auxiliary fractures, wherein the auxiliary fractures create a fracture network, the fracture network increases the stimu

Abstract: A method includes forming a well treatment fluid by combining an aqueous fluid, a viscosifying agent, a crosslinker, and a rheology modifier containing an aldehyde. The viscosifying agent is crosslinked, increasing viscosity of the fluid. The method includes treating a well with the fluid exhibiting the increased viscosity, chemically changing the aldehyde after the crosslinking and thereby forming an acid, and decreasing viscosity of the crosslinked fluid as a result of forming the acid. The aldehyde may be glyoxal which forms oxalic acid, breaking a crosslink. A well treatment fluid is formulated with ingredients including an aqueous fluid and a viscosifying agent and a crosslinker configured to crosslink the viscosifying agent. The fluid includes a rheology modifier containing an aldehyde. The fluid may lack an aldehyde crosslinking delay additive.

Abstract: A carbohydrate-based compound is used as a setting accelerator in a pumpable geopolymeric suspension for oil and/or gas industry applications. The suspension further comprises an aluminosilicate source, a carrier fluid, and an activator. The suspensions may be placed in a subterranean well and used for well primary cementing operations and/or remedial applications.

Abstract: An oxygen scavenger for completion brines effective and stable in high temperature subterranean formations. In one embodiment, the scavenger contains erythorbate and alkylhydroxlyamine.

Abstract: The invention provides an oilfield suspending friction reducer treatment composition fluid comprising from about 0.001 weight percent to about 0.5 weight percent of a drag reducing surfactant; at least one drag reducing enhancer selected from the group consisting of polymeric drag reduction enhancers, monomeric drag reduction enhancers, and mixtures thereof.

Abstract: A method of plugging an opening in a subterranean formation such as a fracture system is provided. A gel composition can be provided which includes an aqueous fluid, a cross-linkable polymer soluble in the aqueous fluid and a cross-linking agent. Inorganic fibers can be added to the gel composition. The gel composition can be injected into the opening in the subterranean formation. The gel composition can be cross-linked, and the opening can be plugged with the gel composition. In certain illustrative embodiments, the inorganic fibers can be mineral wool fibers.

Abstract: Aqueous and substantially anhydrous fluids having particularly low thermal conductivities and variable densities are disclosed. The fluids include: one or more organic and/or inorganic salts and at least one aprotic polar organic solvent, a mixture of aprotic and protic polar organic solvents, and/or a polar organic solvent having both protic and aprotic polar functional group linkages. The fluids optionally include one or more viscosifying agents and are free of cross-linking agents. Methods for formulating and using the fluids are also disclosed.

Abstract: Methods of stimulating a well comprising providing a stimulation fluid comprising at least one surfactant and submicron particles, the submicron particles having a particle size between about 200 nm and about 800 nm and a specific surface area greater than about 5 square meters per gram; and introducing the stimulation fluid into a wellbore. Additional methods to enhance oil recovery from subterranean reservoirs accessible via a well are described.

Abstract: A method of servicing a wellbore in a subterranean formation comprising preparing a wellbore servicing fluid comprising (i) a breaking agent, a breaking agent precursor, or combinations thereof, wherein the breaking agent comprises a sugar acid and (ii) an aqueous base fluid, and contacting the wellbore servicing fluid with a filter cake in the wellbore and/or subterranean formation.

Abstract: The present invention is directed to fracturing fluids having temperature-sensitive viscosities. The fracturing fluids may include a mixture of a hydrophobically associative polymer (HAP) and a surfactant in an aqueous medium, wherein the surfactant imparts a critical solution temperature (CST) to the fluid. The fluid is more viscous at temperatures lower than the CST as compared to temperatures above the CST.

Abstract: A composition and method for hydraulically fracturing an oil or gas well to improve the production rates and ultimate recovery using a porous ceramic proppant infused with a chemical treatment agent is provided. The chemical treatment agent may be a tracer material that provides diagnostic information about the production performance of a hydraulic fracture stimulation by the use of distinguishable both water soluble and hydrocarbon soluble tracers. The tracer can be a biological marker, such as DNA. The porous ceramic proppant can be coated with a polymer which provides for controlled release of the chemical treatment agent into a fracture or well bore area over a period of time.

Abstract: Drilling, drill-in and completion fluids containing nanoparticles for use in hydrocarbon drilling and recovery processes and methods related thereto are provided. The fluids also include a dual acting shield agent that shields the nanoparticles and also acts as a viscosifier. The fluids can be used in various types of hydrocarbon drilling and recovery processes, such as drilling, drill in, completion, and the like.

Abstract: A treatment fluid comprises: water; a carboxylate; and a corrosion inhibitor, wherein the corrosion inhibitor is environmentally-friendly, biodegradable, and is a polymer, wherein the polymer comprises a carbohydrate backbone and a quaternary amine functional group; wherein a test fluid consisting essentially of the water, the carboxylate, and the corrosion inhibitor, and in the same proportions as in the treatment fluid, is capable of providing a corrosion weight loss to a metal plate of less than 0.05 pounds per square feet (lb/ft2) under testing conditions of 200° F. (93.3° C.), a pressure of 500 psi (3.4 MPa), and a time of 24 hours whereas a substantially identical test fluid without the corrosion inhibitor provides a corrosion weight loss of greater than 0.05 lb/ft2 under the testing conditions. A method of treating a portion of a well comprises: forming the treatment fluid; and introducing the treatment fluid into the well.

Abstract: A method of treating a subterranean formation. The method may include providing a fluid loss control pill that comprises an aqueous base fluid, a gelling agent, and an internal breaker that is selected from the group consisting of inorganic delayed acids or inorganic salts. The method can include introducing the fluid loss control pill into a subterranean formation, allowing the internal breaker to reduce the viscosity of the pill after a delay period, and allowing the fluid loss control pill to break.

Abstract: Method and agent for reducing water production from oil and gas wells. The agent comprises polymer, cross-linked particles which are stable in water-free solvents. The particles are manufactured in an oil-in-oil emulsion and are cross-linked with at least one water-stable cross-linker and at least one water-labile cross-linker. The water-labile cross-linker is chosen so that when it is opened or broken in a reaction with water a hydrophilic seat is formed which increases the particle's ability to swell in water. The particles furthermore comprise a controlled amount of an immobilized chemical compound which by means of the reaction between water and reactive groups in the polymer skeleton, become able to form chemical bonds to another particle, to another reactive seat in the same particle or to another compounds thereby increasing the agent's stability in the formation.

Abstract: The present invention relates to the discovery that melanoidins, and higher molecular weight fractions of products containing melanoidins, provide significant corrosive inhibition, which render these melanoidins suitable for use as anticorrosive agents in corrosive environments. In addition to being highly anticorrosive, the melanoidins of the present invention are environmentally friendly and non-toxic, and can be found in animal food and in human foodstuffs.

Abstract: A method for treating a well penetrating subterranean formations comprising injecting into the well a composition comprising a high temperature stabilizer composition which comprises at least one mineral-reactive compound; wherein at least a part of the well is at a temperature of at least 120° C. is provided. Also provided is a composition for treating a well comprising a mineral-reactive compound.

Abstract: A method of gravel packing a hole in a subterranean formation having a filter cake coated on the surface thereof is disclosed. The method may include: injecting into the hole a gravel pack composition comprising gravel and a carrier fluid comprising a base fluid and at least one alkyl glycoside. Also disclosed is a solution including an aqueous fluid, at least one alkyl glycoside, and gravel which may be used as a composition for a gravel pack operation, for example.

Abstract: The present invention is a cryogenic subterranean fracturing fluid, comprising a liquefied industrial gas and a viscosity increasing additive. The liquefied industrial gas may be liquefied carbon dioxide, liquefied nitrogen, or a blend of the two. The liquefied industrial gas mixture should be substantially free of water. In this context, substantially free of water means less than 10% water by volume, or preferably less than 5% water by volume. In addition to the viscosity increasing additive, a proppant may be added to the fracturing fluid. In addition to the viscosity increasing additive and/or proppant additional additives may be added to the liquefied industrial gas as required.

Abstract: An enhanced oil recovery formulation composition containing a sacrificial agent and a surfactant dispersed in a fluid is provided. The sacrificial agent reduces the amount of surfactant required to enhance oil recovery from a petroleum-bearing formation. The sacrificial agent is selected from the group consisting of a compound comprising a single carboxylic acid, a single carboxylic acid derivative, or a single carboxylate salt, or a compound lacking a carboxylic acid group, a carboxylate group, a sulfonic acid group, or a sulfonate group that is a pheol, a sulphonamide, or a thiol, or a compound having a molecular weight of 1000 or less that comprises one or more hydroxyl groups.

Abstract: A method of servicing a wellbore comprising placing a wellbore servicing fluid comprising a modified friction reducer into the wellbore. A modified friction reducer comprising a degradable polymer having functional degradable moieties, a polymer having a molecular weight of from about 5M to about 30M, a polymer having a PDI of from about 1.0 to about 2.5, a weakly crosslinked polymer, or combinations thereof.

Abstract: A method of gravel packing a hole in a subterranean formation having a filter cake coated on the surface thereof is disclosed. The method may include: injecting into the hole a gravel pack composition comprising gravel and a carrier fluid comprising a base fluid and at least one alkyl glycoside. Also disclosed is a solution including an aqueous fluid, at least one alkyl glycoside, and gravel which may be used as a composition for a gravel pack operation, for example.

Abstract: A composition comprising a carboxylated, sulfonated polysaccharide and a wellbore servicing fluid. A wellbore servicing composition comprising a hydraulic cement and a carboxylated, sulfonated polysaccharide. A wellbore servicing composition comprising a polysaccharide having carboxylate and sulfonate groups.

Abstract: A method of servicing a wellbore comprising introducing to the wellbore a wellbore servicing fluid comprising an additive composition comprising a polysaccharide having carboxylate and sulfonate groups. A method of servicing a wellbore comprising preparing at the well site an additive composition comprising a polysaccharide having carboxylate and sulfonate groups, introducing the additive composition into a wellbore servicing fluid, and placing the wellbore servicing fluid into a subterranean formation. A method of preparing a wellbore servicing fluid comprising contacting a polysaccharide composition with an oxidizing agent to form an oxidized polysaccharide, and contacting the oxidized polysaccharide with a sulfonating agent to form a carboxylated sulfonated polysaccharide, and contacting the carboxylated sulfonated polysaccharide with a wellbore servicing fluid.

Abstract: A fluid may contain nanoparticles and a base fluid where the base fluid may be a non-aqueous fluid. The base fluid may be, but is not limited to a drilling fluid, a completion fluid, a production fluid, and/or a stimulation fluid. The fluid may have at least one property, such as but not limited to a dielectric constant ranging from about 5 to about 10,000, an electrical conductivity ranging from about 1×10?6 S/m to about 1 S/m, and combinations thereof. The non-aqueous fluid may be a brine-in-oil emulsion, or a water-in-oil emulsion, and combinations thereof. The addition of nanoparticles to the base fluid may modify the electrical properties of the fluid.

Abstract: The present invention relates to processes employing industrial streams, including glycerol-containing by-products of triglyceride processing as well as waste glycol streams recovered from several sources, to produce oil well drilling, completion and hydrofracturing fluids.

Abstract: A method for unloading fluids from an oil and gas well, pipeline or flowline includes using a synergistic combination of an alkyl glucoside and an amphoteric surfactant as a foaming composition. Use of the combination foaming composition improves unloading of formation fluids, particularly production fluids having natural gas condensate and water and therefore increases the rate of production from the oil and gas well.