Polymer Derived From Monomer Having Quaternary Ammonium Group Patents (Class 507/222)
  • Patent number: 11401458
    Abstract: Methods and systems for reducing friction in fracturing fluids are disclosed. An exemplary friction reducing composition includes a synthetic water-soluble polymer and a nanocellulose. This friction reducing composition is added to aqueous saline fluid for hydraulic fracturing treatment of hydrocarbon wells.
    Type: Grant
    Filed: August 31, 2020
    Date of Patent: August 2, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Wenwen Li, Rajesh Kumar Saini
  • Patent number: 11396624
    Abstract: The instant application relates to nanogels or compositions that hold multivalent metal ions until some level of nanogel degradation has occurred, then slowly release the multivalent metal ions for gelation with carboxylate containing polymers. Compositions comprising such nanogels, together with polymers that can be crosslinked with multivalent metal ions, allow the deployment of such mixtures in various applications, and greatly increased gelation times.
    Type: Grant
    Filed: July 24, 2020
    Date of Patent: July 26, 2022
    Assignees: CONOCOPHILIPS COMPANY, UNIVERSITY OF KANSAS
    Inventors: Huili Guan, Cory Berkland, Ahmad Moradi-Araghi, Jenn-Tai Liang, Terry M. Christian, Riley B. Needham, Min Cheng, Faye Lynn Scully, James H. Hedges
  • Patent number: 11136493
    Abstract: The present invention generally relates to methods and friction-reducers for decreasing the friction of a fluid. More specifically, the method comprises contacting a friction-reducer to reduce the friction of a fluid flowing in a conduit. The friction-reducer comprises an emulsion polymer, comprising polyanion, polycation, and polynonionic monomers, and a highly concentrated salt solution.
    Type: Grant
    Filed: November 4, 2016
    Date of Patent: October 5, 2021
    Assignee: ChampionX USA Inc.
    Inventors: Analette I. Lopez, Kin-Tai Chang, Pious Kurian
  • Patent number: 10858571
    Abstract: The present disclosure relates to a high-temperature retarder suitable for oil and gas well cementation, a preparation method thereof and a cementing slurry.
    Type: Grant
    Filed: January 27, 2020
    Date of Patent: December 8, 2020
    Assignees: CHINA UNIVERSITY OF PETROLEUM (EAST CHINA), CHENGDU OMAX PETROLEUM TECHNOLOGY CO., LTD
    Inventors: Chengwen Wang, Yucheng Xue, Wei Zhou, Ruihe Wang, Jinsheng Sun, Yong Li, Changqiang Tang
  • Patent number: 10774257
    Abstract: A random copolymer, a preparation method of the random copolymer, a drilling fluid containing the random copolymer. The random copolymer contains structural unit (A) represented by formula (1), structural unit (B) represented by formula (2), structural unit (C) represented by formula (3), and structural unit (D) represented by formula (4) or (5): wherein X is halogen. When the random copolymer is used as a filter loss reducer in a high-calcium drilling fluid, the filter loss of the high-calcium drilling fluid can be reduced.
    Type: Grant
    Filed: September 12, 2018
    Date of Patent: September 15, 2020
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SINOPEC RESEARCH INSTITUTE OF PETROLEUM ENGINEERING
    Inventors: Yongxue Lin, Xiaohua Yang, Lin Wang, Jian He, Junbin Jin, Fan Yang, Haibo Wang
  • Patent number: 10752822
    Abstract: A crosslinked polymer comprising reactants of a first repeating unit, a second repeating unit, and a crosslinker that react to form the crosslinked polymer, wherein the first repeating unit is a sulfonic acid-containing monomer present from 1% to 45% by weight of the reactants, wherein the second repeating unit is selected from the group consisting of an N-vinyl amide-containing monomer, a terminal double bond-containing monomer, and any combination thereof, and is present from 55% to 99% by weight of the reactants, and wherein the crosslinker comprises at least two olefinic bonds.
    Type: Grant
    Filed: February 23, 2015
    Date of Patent: August 25, 2020
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Hui Zhou, Weibin Zha
  • Patent number: 10040987
    Abstract: The present invention refers to the use of anionic water-soluble polymers being partially or totally neutralized with an organic counter-ion for oil filed application, especially tertiary oil recovery steps.
    Type: Grant
    Filed: April 7, 2014
    Date of Patent: August 7, 2018
    Assignee: S.P.C.M. SA
    Inventors: Cédrick Favero, Nicolas Gaillard, Bruno Giovannetti
  • Patent number: 9702239
    Abstract: Introducing a treatment fluid comprising proppant particulates into a subterranean formation, the treatment fluid comprising a high salt concentration base fluid, a charged polymeric gelling agent, and proppant particulates suspended therein, wherein the high salt concentration base fluid comprises a concentration of salt in the range of from about 0.5% to saturation, and wherein the treatment fluid has a bulk viscosity of from about 30 cP to about 150 cP at a shear rate of about 40 sec?1.
    Type: Grant
    Filed: June 27, 2013
    Date of Patent: July 11, 2017
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Aaron Gene Russell, Dipti Singh, HsinChen Chung, Xiangnan Ye
  • Patent number: 9102865
    Abstract: A method comprising placing a wellbore servicing fluid comprising a cationic polymer into wellbore wherein the cationic polymer has a molecular weight of from about 300,000 Daltons to about 10,000,000 Daltons. A composition comprising a wellbore servicing fluid, a cationic polymer, and a brine.
    Type: Grant
    Filed: February 16, 2009
    Date of Patent: August 11, 2015
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: Kelly B. Fox
  • Patent number: 8969261
    Abstract: A composition for enhancing fluid viscosity including a mixture of at least one cationic or cationizable polymer and at least one anionic or anionizable (hydrolysable) polymer. The composition has a zeta potential at 25° C. in the range of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV, or is a precursor convertible at a temperature of 100 to 250° C. to the composition having a zeta potential at 25° C. of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV. Typically the compositions exhibit salt tolerance and interaction of both polymers at very high temperatures (>300° F.) such that the system exhibits an increase of viscosity at extreme temperatures. The compositions are useful for hydraulic fracturing, enhanced oil recovery, subterranean acidization, personal care as well as home and industrial cleaners.
    Type: Grant
    Filed: February 14, 2011
    Date of Patent: March 3, 2015
    Assignee: Rhodia Operations
    Inventors: Ruela Talingting Pabalan, Nemesio Martinez-Castro, Subramanian Kesavan, Marie Pierre Labeau, Bruno Langlois
  • Publication number: 20150047848
    Abstract: A well treatment composite is characterized by particulates wherein at least a portion of the substrate of the particulates is coated with a polycationic polymer. The presence of the polycationic polymer on the surface of the well treatment particulates reduces the generation of dust and fines during a well treatment operation. The polycationic polymer further reduces the amount of dust or fines generated during transport of the well treatment particulates to a remote location as well during the manufacture or processing of well treatment particulates.
    Type: Application
    Filed: October 28, 2014
    Publication date: February 19, 2015
    Inventors: Naima Bestaoui-Spurr, Mark Alan Vorderbruggen, D.V. Satyanarayana Gupta, Harold Gene Hudson
  • Publication number: 20140367108
    Abstract: Various embodiments disclosed relate to acidizing compositions including an ampholyte polymer. Various embodiments provide a method of treating a subterranean formation. The method can include placing in a subterranean formation an ampholyte polymer including an ethylene repeating unit including a —C(O)NH2 group, an ethylene repeating unit including an —S(O)2OR1 group, and an ethylene repeating unit including an —N+R23X? group. At each occurrence, R1 can be independently selected from the group consisting of —H and a counterion. At each occurrence, R2 can be independently substituted or unsubstituted (C1-C20)hydrocarbyl. At each occurrence, X? can be independently a counterion.
    Type: Application
    Filed: August 28, 2014
    Publication date: December 18, 2014
    Inventors: HsinChen Chung, Jason Eric Maxey
  • Publication number: 20140352960
    Abstract: Ampholyte polymeric compound that comprises at least one nonionic monomer, at least one sulfonic acid-containing monomer, and at least one cationic monomer may be useful in viscosifying treatment fluids for use in subterranean operations at a concentration of about 0.5 v/v % to about 30 v/v % of the treatment fluid. Such operations may involve introducing the treatment fluid into a wellbore penetrating a subterranean formation optionally at a pressure sufficient to create or extend at least one fracture in the subterranean formation.
    Type: Application
    Filed: June 28, 2013
    Publication date: December 4, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: HsinChen Chung, Yuntao Thomas Hu, Xiangnan Ye, Narongsak Tonmukayakul, Michael A. McCabe, Kevin Walter Frederick, Shih-Ruey Tom Chen, Randy Jack Loeffler
  • Patent number: 8889602
    Abstract: Embodiments disclosed herein relate to methods for stabilizing shales while drilling a wellbore into an earthen formation comprising circulating an aqueous based wellbore fluid in the wellbore while drilling through shales; wherein the aqueous-based wellbore fluid comprises a copolymer of acrylamide-type comonomers and at least one cationic comonomer.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: November 18, 2014
    Assignee: M-l Drilling Fluids U.K. Limited
    Inventor: Stephen Cliffe
  • Publication number: 20140323366
    Abstract: A method of preparing and using a drag-reducing composition in a well treatment operation includes the step of preparing the drag-reducing composition by mixing a polymer emulsion that includes a first surfactant and a first solvent, with a second surfactant and a second solvent. The method continues with the step of combining the drag-reducing composition with an aqueous treatment fluid. The method further includes the step of injecting the drag-reducing composition and aqueous treatment fluid into a subterranean formation, a pipeline or a gathering line.
    Type: Application
    Filed: July 3, 2014
    Publication date: October 30, 2014
    Inventors: Earl Parnell, Todd Sanner, Marlin Holtmyer, David Philpot, Andrei Zelenev, Gydeon Gilzow, Thomas Sifferman, Lakia Champagne
  • Patent number: 8871692
    Abstract: The present invention refers to the use of anionic water-soluble polymers being partially or totally neutralized with an organic counter-ion for oil filed application, especially tertiary oil recovery steps.
    Type: Grant
    Filed: January 26, 2011
    Date of Patent: October 28, 2014
    Assignee: S.P.C.M. S.A.
    Inventors: Cédrick Favero, Nicolas Gaillard, Dennis Marroni
  • Patent number: 8783356
    Abstract: Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.
    Type: Grant
    Filed: November 19, 2012
    Date of Patent: July 22, 2014
    Assignee: BASF SE
    Inventors: Roland Reichenbach-Klinke, Thomas Pfeuffer, Kati Schmidt, Thomas Ostrowski, Reinhold J. Leyrer, Yulia Fogel, Stefan Friedrich, Peter Gaeberlein, Andrea Orleans, Manfred Schuhbeck, Marcus Guzmann, Marcus Rösch, Bjorn Langlotz
  • Publication number: 20140162912
    Abstract: The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or a suitable pH in the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to negative sites of the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.
    Type: Application
    Filed: February 18, 2014
    Publication date: June 12, 2014
    Applicants: University of Kansas, ConocoPhillips Company
    Inventors: Ahmad MORADI-ARAGHI, James H. HEDGES, David R. ZORNES, Riley B. NEEDHAM, Huili GUAN, Jenn-Tai LIANG, Cory BERKLAND, James P. JOHNSON, Min CHENG, Faye Lynn SCULLY
  • Patent number: 8709982
    Abstract: The invention relates to the use of quaternary polyamines having formula (I) for the recovery of oil from reservoirs formula (I), wherein n>=1 R1 represents H, CH3, CH2CH3, CnH2n+1 R2 represents H2CHOHCH2, CH2, CH2CH?CH2 R3 represents CH3, CH2CH3, CnH2n+1 R4 represents CH2, CH2CH?CH2 when R2 and R4 are allyl group, they can jointly form aliphatic cyclic structures, the ratio between the carbon atoms and nitrogen atoms (C/N) ranges from 2 to 30.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: April 29, 2014
    Assignee: ENI S.p.A.
    Inventors: Lucilla Del Gaudio, Thomas Paul Lockhart, Emanuele Vignati
  • Patent number: 8703659
    Abstract: A sealant composition for servicing a wellbore comprising at least one gel system, a leak off prevention material and water.
    Type: Grant
    Filed: January 19, 2006
    Date of Patent: April 22, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Eldon D. Dalrymple, Larry S. Eoff, Diederik W. van Batenburg, Jip van Eijden
  • Patent number: 8697613
    Abstract: Methods comprising: providing an aqueous treatment fluid comprising an aqueous fluid, a friction reducing polymer, and an antiflocculation additive; and introducing the treatment fluid into a subterranean formation. Methods of fracturing a subterranean formation comprising: providing an aqueous treatment fluid comprising an aqueous fluid, a friction reducing polymer, and an antiflocculation additive; and introducing the treatment fluid into a well bore penetrating the subterranean formation at rate in the range of from about 30 barrels to about 250 barrels per minute so as to create or enhance one or more fractures in the subterranean formation. Aqueous treatment fluids comprising: an aqueous fluid, a friction reducing polymer in an amount sufficient to reduce friction without forming a gel, and an antiflocculation additive.
    Type: Grant
    Filed: March 3, 2006
    Date of Patent: April 15, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: David E. McMechan, Jimmie D. Weaver, Thomas D. Welton, Robert E. Hanes, Jr., Karen L. King, Gary P. Funkhouser
  • Patent number: 8691736
    Abstract: The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or a suitable pH in the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to negative sites of the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.
    Type: Grant
    Filed: June 14, 2010
    Date of Patent: April 8, 2014
    Assignees: ConocoPhillips Company, University of Kansas
    Inventors: Ahmad Moradi-Araghi, James H. Hedges, David R. Zornes, Riley B. Needham, Huili Guan, Jenn-Tai Liang, Cory Berkland, James P. Johnson, Min Cheng, Faye L. Scully
  • Patent number: 8680028
    Abstract: A method for the treatment of rock formations which may or may not be underground and, more particularly, of oil or gas production wells, water-injection wells intended to flood hydrocarbon (oil or gas) reservoirs or gas mines or gas storage wells includes a step of injecting, into the rock formation or well, a microgel obtained by dilution in water of a self-invertible inverse latex or of a self-invertible inverse microlatex of a crosslinked polyelectrolyte, obtained by copolymerization, in the presence of a crosslinking agent of partially- or totally-salified free 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid, with at least one cationic monomer chosen from: 2,N,N,N-tetramethyl-2-[(1-oxo-2-propenyl)amino]propanammonium chloride; N,N,N-trimethyl-3-[(1-oxo-2-propenyl)amino]propanammonium chloride; diallyldimethylammonium chloride; N,N,N-trimethyl-2-[(1-oxo-2-propenyl)]ethanammonium chloride; N,N,N-trimethyl-2-[(1-oxo-2-methyl-2-propenyl)]ethanammonium chloride; or N,N,N-trimethyl-3-[(1-oxo-2-meth
    Type: Grant
    Filed: June 2, 2009
    Date of Patent: March 25, 2014
    Assignees: Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC, Poweltec
    Inventors: Olivier Braun, Paul Mallo, Alain Zaitoun
  • Patent number: 8592353
    Abstract: Method of diverting fluids in a subterranean formation including the steps of providing a first fluid comprising an aqueous fluid and a hydrophobically modified water-soluble relative permeability modifier; introducing the first fluid into a well bore such that the first treatment fluid penetrates into a portion of the subterranean formation in a sufficient amount so as to substantially divert a second treatment fluid to another portion of the subterranean formation. Then, a second aqueous fluid is introduced into the well bore and substantially diverted from the portion of the subterranean formation penetrated with the first treatment fluid. In some cases, a well treatment operation, such as acid stimulation operation, a clay stabilization operation, or a scale inhibition operation, is performed using the second fluid.
    Type: Grant
    Filed: March 16, 2012
    Date of Patent: November 26, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Eldon D. Dalrymple, Larry S. Eoff, B. Raghava Reddy
  • Publication number: 20130310285
    Abstract: A treatment fluid made of mineral acid, viscoelastic surfactant, at least one of a fluoride source and a chelant, and optionally a corrosion inhibitor. A method of combining a mineral acid, viscoelastic surfactant, at least one of a fluoride source and a chelant, and optionally a corrosion inhibitor, in a fluid mixture. A method of contacting a low-temperature formation with a fluid mixture of mineral acid, viscoelastic surfactant, at least one of a fluoride source and a chelant, and optionally a corrosion inhibitor.
    Type: Application
    Filed: May 18, 2012
    Publication date: November 21, 2013
    Inventors: Andrey Fedorov, Bernhard Lungwitz, Olesya Levanyuk, Philippe Enkababian
  • Patent number: 8586510
    Abstract: A method comprising: providing at least one encaged treatment chemical that comprises a treatment chemical and a polymer carrier; placing the encaged treatment chemical into a portion of a subterranean formation; and allowing the treatment chemical to diffuse out of the encaged treatment chemical and into a portion of the subterranean formation or an area adjacent thereto.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: November 19, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Michael A. McCabe, Jim D. Weaver, Robert E. Hanes, Billy F. Slabaugh
  • Patent number: 8586511
    Abstract: This invention provides a method for inhibiting scale formation within a hydrocarbon producing system, said method comprising contacting said system with a copolymer formed from a diallyl ammonium salt and at least one other monomer.
    Type: Grant
    Filed: August 2, 2006
    Date of Patent: November 19, 2013
    Assignee: Champion Technologies Ltd.
    Inventors: Ping Chen, Xing Yan, Thomas Hagen, Harry Montgomerie
  • Publication number: 20130255954
    Abstract: Fracturing fluid comprising, in solution in water, a proppant and an associative amphoteric polymer, the said polymer having a molecular weight of at least 1 000 000 g/mol and comprising: 0.01 to 10 mol % of at least one cationic monomer derived from acrylamide, from 0.09 to 89.99 mol % of at least one anionic monomer, and from 10 to 99 mol % of at least one nonionic water-soluble monomer. Fracturing process using the fluid.
    Type: Application
    Filed: March 15, 2013
    Publication date: October 3, 2013
    Applicant: S.P.C.M. SA
    Inventors: Cédrick FAVERO, Nicolas GAILLARD
  • Patent number: 8507413
    Abstract: Clay is stabilized in methods for drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid including a choline compound together with an formation control additive.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: August 13, 2013
    Assignee: Clearwater International, LLC
    Inventor: Thomas P. Wilson, Jr.
  • Patent number: 8492317
    Abstract: Methods and compositions are provided that relate to cementing operations. Methods and compositions that include a latex strength enhancer for enhancing the compressive strength of slag compositions.
    Type: Grant
    Filed: March 15, 2012
    Date of Patent: July 23, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jiten Chatterji, Chad Brenneis, Callie R. Jarratt
  • Patent number: 8470746
    Abstract: The present invention relates to methods and compositions for treating a water- and hydrocarbon-producing subterranean formation with a relative permeability modifier, and more specifically, to improved treatment fluids, methods for preparing treatment fluids, and methods for use thereof in a subterranean formation. Methods of the present invention comprise providing a treatment fluid comprising a relative permeability modifier, at least one surfactant, and an aqueous phase base fluid; and placing the treatment fluid in a subterranean formation. The relative permeability modifier comprises a hydrophobically modified hydrophilic polymer. The at least one surfactant is operable to maintain the relative permeability modifier in a dissolved state in the treatment fluid above a pH of about 8.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: June 25, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Larry S. Eoff
  • Publication number: 20130105154
    Abstract: Well treatment agents containing a particulate substrate are coated with a polyelectrolyte bilayer to provide a well treatment composite for use in well treatment operations. Each layer of the polyelectrolyte bilayer is composed of oppositely charged polyionic material. The well treatment composite may further contain a succession of polyelectrolyte bilayers, each polyelectrolyte bilayer containing layers of oppositely charged polyionic materials.
    Type: Application
    Filed: October 27, 2011
    Publication date: May 2, 2013
    Inventors: Mark Alan Vorderbruggen, Hong Sun, Qi Qu
  • Publication number: 20130105165
    Abstract: Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.
    Type: Application
    Filed: November 19, 2012
    Publication date: May 2, 2013
    Applicant: BASF SE
    Inventor: BASF SE
  • Patent number: 8343897
    Abstract: Provided is a method for inhibiting scale formation within a hydrocarbon producing system, said method comprising contacting said system with a polymer formed from a diallyl ammonium salt, a monomer comprising one carboxylate group and a monomer comprising at least two carboxylate groups or an anhydride group. Also provided are hydrocarbon well treatment compositions and polymers for use in connection with the provided methods. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Grant
    Filed: January 15, 2007
    Date of Patent: January 1, 2013
    Assignees: Sichuan Sanyuan Chem Limited, Corporation, Champion Technologies Limited
    Inventors: Harry Montgomerie, Ping Chen, Thomas Hagen, Liehua Zheng
  • Patent number: 8343896
    Abstract: Methods are provided comprising providing a sealant composition comprising an aqueous fluid, a diutan composition, at least one gel system, and a leak off prevention material; introducing the sealant composition into a well bore penetrating the subterranean formation; and allowing the sealant composition to form a seal.
    Type: Grant
    Filed: September 30, 2009
    Date of Patent: January 1, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Larry S. Eoff, Richard W. Pauls
  • Publication number: 20120258894
    Abstract: Methods and compositions are described for treating water- and hydrocarbon-producing subterranean formations with a relative permeability modifier at concentrations below those conventionally used in the art, while not substantially impacting the treatment fluid's performance. Treatment fluids described herein comprise a base fluid, a relative permeability modifier comprising a hydrophobically modified hydrophilic polymer, and a companion polymer interacting synergistically with the relative permeability modifier such that the treatment fluid is operable to reduce the water permeability or to increase an aqueous fluid injection pressure of at least a portion of a subterranean formation by more than the relative permeability modifier or the companion polymer acting alone at like concentration. The water permeability reduction and/or the aqueous fluid injection pressure increase can be more than additive.
    Type: Application
    Filed: April 7, 2011
    Publication date: October 11, 2012
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Larry S. Eoff, Jeff W. Loucks, B. Raghava Reddy
  • Patent number: 8278250
    Abstract: Methods of using relative permeability modifiers for the diversion of aqueous fluids during subterranean operations are provided. An embodiment of the present invention provides a method of diverting fluids in a subterranean formation that may comprise providing a treatment fluid comprising an aqueous fluid and a relative permeability modifier that comprises water-soluble polymer with hydrophobic or hydrophilic modification; introducing the treatment fluid into a well bore that penetrates the subterranean formation; and at least a first portion of the treatment fluid to penetrate into a portion of the subterranean formation so as to substantially divert a second portion of the treatment fluid or another aqueous treatment fluid to another portion of the subterranean.
    Type: Grant
    Filed: May 5, 2005
    Date of Patent: October 2, 2012
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Eldon D. Dalrymple, Larry S. Eoff, B. Raghava Reddy
  • Publication number: 20120214714
    Abstract: A process for achieving enhanced levels of friction reduction in high salinity conditions, particularly suited to slick-water hydraulic fracturing and coiled tubing applications, uses low charge and preferably uncharged water soluble high molecular weight polymers. A fracturing fluid is injected into a conduit. The fracturing fluid is an aqueous solution comprising at least one water soluble (co)polymer comprising less than 10 mol % ionic monomer(s), and the aqueous solution comprises total dissolved salts concentration ranging from 100,000 mg/L to up to the salt concentration at which the aqueous solution becomes saturated in salts.
    Type: Application
    Filed: February 28, 2011
    Publication date: August 23, 2012
    Applicant: SNF HOLDING COMPANY
    Inventors: Paul WHITWELL, Russell THORPE
  • Publication number: 20120196776
    Abstract: A method of servicing a well is disclosed. The method comprises mixing ingredients to form a well servicing fluid. The ingredients comprise (i) at least one surfactant chosen from alcohol ethoxylates, C4 to C12 primary alcohols and ethoxylated propoxylated alcohols, (ii) a zwitterionic polymer prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba, and (iii) a saline based aqueous solution. The well servicing fluid is introduced into a hydrocarbon well.
    Type: Application
    Filed: February 2, 2011
    Publication date: August 2, 2012
    Inventors: D.V. Satyanarayana Gupta, Madhukar Chetty, Paul Carman
  • Publication number: 20120172263
    Abstract: Composition comprising a plurality of particulates wherein at least some particulates are at least partially covered with a coating that impedes the intrusion of water into the particulates; and, a silica scale control additive, wherein the silica scale control additive is capable of suppressing silica scale build-up proximate the plurality of particulates. Some compositions further include a treatment fluid wherein and the silica scale control additive are present in the treatment fluid.
    Type: Application
    Filed: March 16, 2012
    Publication date: July 5, 2012
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Jimmie D. Weaver, Matt E. Blauch, Corine L. McMechan
  • Publication number: 20120135895
    Abstract: The present invention relates to methods and compositions for treating a water- and hydrocarbon-producing subterranean formation with a relative permeability modifier, and more specifically, to improved treatment fluids, methods for preparing treatment fluids, and methods for use thereof in a subterranean formation. Methods of the present invention comprise providing a treatment fluid comprising a relative permeability modifier, at least one surfactant, and an aqueous phase base fluid; and placing the treatment fluid in a subterranean formation. The relative permeability modifier comprises a hydrophobically modified hydrophilic polymer. The at least one surfactant is operable to maintain the relative permeability modifier in a dissolved state in the treatment fluid above a pH of about 8.
    Type: Application
    Filed: November 30, 2010
    Publication date: May 31, 2012
    Applicant: Halliburton Energy Services, Inc.
    Inventor: Larry S. Eoff
  • Publication number: 20120129738
    Abstract: The present disclosure is directed to a method comprising: mixing (i) a zwitterionic polymer prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba, (ii) a surfactant and (iii) produced water to form a well servicing fluid. The resulting well servicing fluid is introduced into a hydrocarbon well.
    Type: Application
    Filed: November 19, 2010
    Publication date: May 24, 2012
    Inventors: D.V. Satyanarayana GUPTA, Madhukar Chetty, Paul Scott Carman
  • Publication number: 20120129734
    Abstract: What is proposed is the use of a water-soluble hydrophobically associating copolymer as an additive in the development, exploitation and completion of underground mineral oil and natural gas deposits and in deep drillings, wherein the copolymer comprises (a) at least one monoethylenically unsaturated monomer (a) selected from H2C?C(R1)—R4—O—(—CH2—CH2—O—)k—(—CH2—CH(R3)—O—)l—R5 ??(I), and/or H2C?C(R1)—O—(—CH2—CH2—O—)k—R2 ??(II), and (b) at least one monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a), wherein the copolymer is obtainable through copolymerization of the monomers (a) and (b) in the presence of at least one surfactant (c).
    Type: Application
    Filed: November 9, 2011
    Publication date: May 24, 2012
    Inventors: Roland REICHENBACH-KLINKE, Oscar Lafuente Cerda, Andrea Assmann, Björn Langlotz
  • Patent number: 8183181
    Abstract: The present disclosure is directed to a method comprising: mixing (i) a zwitterionic polymer prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba, (ii) a surfactant and (iii) produced water to form a well servicing fluid. The resulting well servicing fluid is introduced into a hydrocarbon well.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: May 22, 2012
    Assignee: Baker Hughes Incorporated
    Inventors: D. V. Satyanarayana Gupta, Madhukar Chetty, Paul Scott Carman
  • Patent number: 8143197
    Abstract: The invention concerns an aqueous viscoelastic fracturing fluid for use in the recovery of hydrocarbons. According to the invention, the fluid comprises a cleavable viscoelastic surfactant and a hydrophobically-modified polymer, wherein the cleavable surfactant comprises a head group and a hydrophobic tail of at least 18 carbon atoms connected through a degradable acetal, amide, ether or ester bond and wherein the concentration of the hydrophobically-modified polymer is comprised between its overlap concentration c* and its entanglement concentration ce.
    Type: Grant
    Filed: July 18, 2008
    Date of Patent: March 27, 2012
    Assignee: Schlumberger Technology Corporation
    Inventors: Isabelle Couillet, Trevor Hughes
  • Patent number: 8101554
    Abstract: The present invention provides a method for increasing the retention of a scale inhibitor within a hydrocarbon producing system (e.g. a subterranean formation), said method comprising contacting said system with a polymer formed from a diallyl ammonium salt and with said scale inhibitor, wherein said polymer formed from a diallyl ammonium salt has a molecular weight of greater than 50,000 (e.g. a molecular weight of 55,000 to 2,000,000).
    Type: Grant
    Filed: August 16, 2007
    Date of Patent: January 24, 2012
    Assignees: Champion Technologies Ltd., Statoilhydro ASA.
    Inventors: Harry Montgomerie, Ping Chen, Thomas Hagen, Rex Wat, Olav Martin Selle
  • Patent number: 8097567
    Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid including a choline compound together with an formation control additive.
    Type: Grant
    Filed: January 9, 2006
    Date of Patent: January 17, 2012
    Assignee: Clearwater International, LLC
    Inventor: Thomas P Wilson, Jr.
  • Patent number: 8076271
    Abstract: The present invention relates to aqueous tackifiers and methods of controlling particulates in subterranean formations using aqueous tackifiers. Some embodiments of the present invention provide methods of controlling particulates, comprising placing an aqueous tackifier compound into a portion of a subterranean formation comprising unconsolidated particulates; and, activating the aqueous tackifier compound. Other embodiments of the present invention provide methods of coating a portion of a surface in a subterranean formation comprising substantially coating an aqueous tackifier compound onto a portion of a subterranean formation; and, activating the aqueous tackifier compound. Other embodiments of the present invention provide treatment fluids for controlling fine particulates, comprising a servicing fluid and an aqueous tackifier compound.
    Type: Grant
    Filed: June 9, 2004
    Date of Patent: December 13, 2011
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Matthew E. Blauch, Thomas D. Welton, Philip D. Nguyen
  • Patent number: 7956012
    Abstract: The present disclosure is directed to a method comprising introducing into a well bore a fluid comprising a zwitterionic polymer. The polymer is prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba. The well bore is chosen from a natural gas well bore and an oil well bore.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: June 7, 2011
    Assignee: BJ Services Company LLC
    Inventors: D. V. Satyanarayana Gupta, Madhukar Chetty, Paul Carman
  • Patent number: 7884056
    Abstract: The invention relates to a composition that can form a gel comprising a copolymer. Said composition is an aqueous composition, and the copolymer is a star copolymer. The invention also relates to useful copolymers, especially for the inventive compositions.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: February 8, 2011
    Assignee: Rhodia Chimie
    Inventors: Denis Bendejacq, Claire Pitois, Katerina Karagianni