Polymer Derived From Monomer Having Quaternary Ammonium Group Patents (Class 507/222)
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Patent number: 11401458Abstract: Methods and systems for reducing friction in fracturing fluids are disclosed. An exemplary friction reducing composition includes a synthetic water-soluble polymer and a nanocellulose. This friction reducing composition is added to aqueous saline fluid for hydraulic fracturing treatment of hydrocarbon wells.Type: GrantFiled: August 31, 2020Date of Patent: August 2, 2022Assignee: Saudi Arabian Oil CompanyInventors: Wenwen Li, Rajesh Kumar Saini
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Patent number: 11396624Abstract: The instant application relates to nanogels or compositions that hold multivalent metal ions until some level of nanogel degradation has occurred, then slowly release the multivalent metal ions for gelation with carboxylate containing polymers. Compositions comprising such nanogels, together with polymers that can be crosslinked with multivalent metal ions, allow the deployment of such mixtures in various applications, and greatly increased gelation times.Type: GrantFiled: July 24, 2020Date of Patent: July 26, 2022Assignees: CONOCOPHILIPS COMPANY, UNIVERSITY OF KANSASInventors: Huili Guan, Cory Berkland, Ahmad Moradi-Araghi, Jenn-Tai Liang, Terry M. Christian, Riley B. Needham, Min Cheng, Faye Lynn Scully, James H. Hedges
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Patent number: 11136493Abstract: The present invention generally relates to methods and friction-reducers for decreasing the friction of a fluid. More specifically, the method comprises contacting a friction-reducer to reduce the friction of a fluid flowing in a conduit. The friction-reducer comprises an emulsion polymer, comprising polyanion, polycation, and polynonionic monomers, and a highly concentrated salt solution.Type: GrantFiled: November 4, 2016Date of Patent: October 5, 2021Assignee: ChampionX USA Inc.Inventors: Analette I. Lopez, Kin-Tai Chang, Pious Kurian
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Patent number: 10858571Abstract: The present disclosure relates to a high-temperature retarder suitable for oil and gas well cementation, a preparation method thereof and a cementing slurry.Type: GrantFiled: January 27, 2020Date of Patent: December 8, 2020Assignees: CHINA UNIVERSITY OF PETROLEUM (EAST CHINA), CHENGDU OMAX PETROLEUM TECHNOLOGY CO., LTDInventors: Chengwen Wang, Yucheng Xue, Wei Zhou, Ruihe Wang, Jinsheng Sun, Yong Li, Changqiang Tang
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Patent number: 10774257Abstract: A random copolymer, a preparation method of the random copolymer, a drilling fluid containing the random copolymer. The random copolymer contains structural unit (A) represented by formula (1), structural unit (B) represented by formula (2), structural unit (C) represented by formula (3), and structural unit (D) represented by formula (4) or (5): wherein X is halogen. When the random copolymer is used as a filter loss reducer in a high-calcium drilling fluid, the filter loss of the high-calcium drilling fluid can be reduced.Type: GrantFiled: September 12, 2018Date of Patent: September 15, 2020Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SINOPEC RESEARCH INSTITUTE OF PETROLEUM ENGINEERINGInventors: Yongxue Lin, Xiaohua Yang, Lin Wang, Jian He, Junbin Jin, Fan Yang, Haibo Wang
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Patent number: 10752822Abstract: A crosslinked polymer comprising reactants of a first repeating unit, a second repeating unit, and a crosslinker that react to form the crosslinked polymer, wherein the first repeating unit is a sulfonic acid-containing monomer present from 1% to 45% by weight of the reactants, wherein the second repeating unit is selected from the group consisting of an N-vinyl amide-containing monomer, a terminal double bond-containing monomer, and any combination thereof, and is present from 55% to 99% by weight of the reactants, and wherein the crosslinker comprises at least two olefinic bonds.Type: GrantFiled: February 23, 2015Date of Patent: August 25, 2020Assignee: Halliburton Energy Services, Inc.Inventors: Hui Zhou, Weibin Zha
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Patent number: 10040987Abstract: The present invention refers to the use of anionic water-soluble polymers being partially or totally neutralized with an organic counter-ion for oil filed application, especially tertiary oil recovery steps.Type: GrantFiled: April 7, 2014Date of Patent: August 7, 2018Assignee: S.P.C.M. SAInventors: Cédrick Favero, Nicolas Gaillard, Bruno Giovannetti
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Patent number: 9702239Abstract: Introducing a treatment fluid comprising proppant particulates into a subterranean formation, the treatment fluid comprising a high salt concentration base fluid, a charged polymeric gelling agent, and proppant particulates suspended therein, wherein the high salt concentration base fluid comprises a concentration of salt in the range of from about 0.5% to saturation, and wherein the treatment fluid has a bulk viscosity of from about 30 cP to about 150 cP at a shear rate of about 40 sec?1.Type: GrantFiled: June 27, 2013Date of Patent: July 11, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Aaron Gene Russell, Dipti Singh, HsinChen Chung, Xiangnan Ye
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Patent number: 9102865Abstract: A method comprising placing a wellbore servicing fluid comprising a cationic polymer into wellbore wherein the cationic polymer has a molecular weight of from about 300,000 Daltons to about 10,000,000 Daltons. A composition comprising a wellbore servicing fluid, a cationic polymer, and a brine.Type: GrantFiled: February 16, 2009Date of Patent: August 11, 2015Assignee: Chevron Phillips Chemical Company LPInventor: Kelly B. Fox
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Patent number: 8969261Abstract: A composition for enhancing fluid viscosity including a mixture of at least one cationic or cationizable polymer and at least one anionic or anionizable (hydrolysable) polymer. The composition has a zeta potential at 25° C. in the range of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV, or is a precursor convertible at a temperature of 100 to 250° C. to the composition having a zeta potential at 25° C. of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV. Typically the compositions exhibit salt tolerance and interaction of both polymers at very high temperatures (>300° F.) such that the system exhibits an increase of viscosity at extreme temperatures. The compositions are useful for hydraulic fracturing, enhanced oil recovery, subterranean acidization, personal care as well as home and industrial cleaners.Type: GrantFiled: February 14, 2011Date of Patent: March 3, 2015Assignee: Rhodia OperationsInventors: Ruela Talingting Pabalan, Nemesio Martinez-Castro, Subramanian Kesavan, Marie Pierre Labeau, Bruno Langlois
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Publication number: 20150047848Abstract: A well treatment composite is characterized by particulates wherein at least a portion of the substrate of the particulates is coated with a polycationic polymer. The presence of the polycationic polymer on the surface of the well treatment particulates reduces the generation of dust and fines during a well treatment operation. The polycationic polymer further reduces the amount of dust or fines generated during transport of the well treatment particulates to a remote location as well during the manufacture or processing of well treatment particulates.Type: ApplicationFiled: October 28, 2014Publication date: February 19, 2015Inventors: Naima Bestaoui-Spurr, Mark Alan Vorderbruggen, D.V. Satyanarayana Gupta, Harold Gene Hudson
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Publication number: 20140367108Abstract: Various embodiments disclosed relate to acidizing compositions including an ampholyte polymer. Various embodiments provide a method of treating a subterranean formation. The method can include placing in a subterranean formation an ampholyte polymer including an ethylene repeating unit including a —C(O)NH2 group, an ethylene repeating unit including an —S(O)2OR1 group, and an ethylene repeating unit including an —N+R23X? group. At each occurrence, R1 can be independently selected from the group consisting of —H and a counterion. At each occurrence, R2 can be independently substituted or unsubstituted (C1-C20)hydrocarbyl. At each occurrence, X? can be independently a counterion.Type: ApplicationFiled: August 28, 2014Publication date: December 18, 2014Inventors: HsinChen Chung, Jason Eric Maxey
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Publication number: 20140352960Abstract: Ampholyte polymeric compound that comprises at least one nonionic monomer, at least one sulfonic acid-containing monomer, and at least one cationic monomer may be useful in viscosifying treatment fluids for use in subterranean operations at a concentration of about 0.5 v/v % to about 30 v/v % of the treatment fluid. Such operations may involve introducing the treatment fluid into a wellbore penetrating a subterranean formation optionally at a pressure sufficient to create or extend at least one fracture in the subterranean formation.Type: ApplicationFiled: June 28, 2013Publication date: December 4, 2014Applicant: Halliburton Energy Services, Inc.Inventors: HsinChen Chung, Yuntao Thomas Hu, Xiangnan Ye, Narongsak Tonmukayakul, Michael A. McCabe, Kevin Walter Frederick, Shih-Ruey Tom Chen, Randy Jack Loeffler
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Patent number: 8889602Abstract: Embodiments disclosed herein relate to methods for stabilizing shales while drilling a wellbore into an earthen formation comprising circulating an aqueous based wellbore fluid in the wellbore while drilling through shales; wherein the aqueous-based wellbore fluid comprises a copolymer of acrylamide-type comonomers and at least one cationic comonomer.Type: GrantFiled: June 23, 2009Date of Patent: November 18, 2014Assignee: M-l Drilling Fluids U.K. LimitedInventor: Stephen Cliffe
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Publication number: 20140323366Abstract: A method of preparing and using a drag-reducing composition in a well treatment operation includes the step of preparing the drag-reducing composition by mixing a polymer emulsion that includes a first surfactant and a first solvent, with a second surfactant and a second solvent. The method continues with the step of combining the drag-reducing composition with an aqueous treatment fluid. The method further includes the step of injecting the drag-reducing composition and aqueous treatment fluid into a subterranean formation, a pipeline or a gathering line.Type: ApplicationFiled: July 3, 2014Publication date: October 30, 2014Inventors: Earl Parnell, Todd Sanner, Marlin Holtmyer, David Philpot, Andrei Zelenev, Gydeon Gilzow, Thomas Sifferman, Lakia Champagne
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Patent number: 8871692Abstract: The present invention refers to the use of anionic water-soluble polymers being partially or totally neutralized with an organic counter-ion for oil filed application, especially tertiary oil recovery steps.Type: GrantFiled: January 26, 2011Date of Patent: October 28, 2014Assignee: S.P.C.M. S.A.Inventors: Cédrick Favero, Nicolas Gaillard, Dennis Marroni
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Patent number: 8783356Abstract: Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.Type: GrantFiled: November 19, 2012Date of Patent: July 22, 2014Assignee: BASF SEInventors: Roland Reichenbach-Klinke, Thomas Pfeuffer, Kati Schmidt, Thomas Ostrowski, Reinhold J. Leyrer, Yulia Fogel, Stefan Friedrich, Peter Gaeberlein, Andrea Orleans, Manfred Schuhbeck, Marcus Guzmann, Marcus Rösch, Bjorn Langlotz
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Publication number: 20140162912Abstract: The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or a suitable pH in the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to negative sites of the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.Type: ApplicationFiled: February 18, 2014Publication date: June 12, 2014Applicants: University of Kansas, ConocoPhillips CompanyInventors: Ahmad MORADI-ARAGHI, James H. HEDGES, David R. ZORNES, Riley B. NEEDHAM, Huili GUAN, Jenn-Tai LIANG, Cory BERKLAND, James P. JOHNSON, Min CHENG, Faye Lynn SCULLY
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Patent number: 8709982Abstract: The invention relates to the use of quaternary polyamines having formula (I) for the recovery of oil from reservoirs formula (I), wherein n>=1 R1 represents H, CH3, CH2CH3, CnH2n+1 R2 represents H2CHOHCH2, CH2, CH2CH?CH2 R3 represents CH3, CH2CH3, CnH2n+1 R4 represents CH2, CH2CH?CH2 when R2 and R4 are allyl group, they can jointly form aliphatic cyclic structures, the ratio between the carbon atoms and nitrogen atoms (C/N) ranges from 2 to 30.Type: GrantFiled: April 2, 2008Date of Patent: April 29, 2014Assignee: ENI S.p.A.Inventors: Lucilla Del Gaudio, Thomas Paul Lockhart, Emanuele Vignati
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Patent number: 8703659Abstract: A sealant composition for servicing a wellbore comprising at least one gel system, a leak off prevention material and water.Type: GrantFiled: January 19, 2006Date of Patent: April 22, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Larry S. Eoff, Diederik W. van Batenburg, Jip van Eijden
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Patent number: 8697613Abstract: Methods comprising: providing an aqueous treatment fluid comprising an aqueous fluid, a friction reducing polymer, and an antiflocculation additive; and introducing the treatment fluid into a subterranean formation. Methods of fracturing a subterranean formation comprising: providing an aqueous treatment fluid comprising an aqueous fluid, a friction reducing polymer, and an antiflocculation additive; and introducing the treatment fluid into a well bore penetrating the subterranean formation at rate in the range of from about 30 barrels to about 250 barrels per minute so as to create or enhance one or more fractures in the subterranean formation. Aqueous treatment fluids comprising: an aqueous fluid, a friction reducing polymer in an amount sufficient to reduce friction without forming a gel, and an antiflocculation additive.Type: GrantFiled: March 3, 2006Date of Patent: April 15, 2014Assignee: Halliburton Energy Services, Inc.Inventors: David E. McMechan, Jimmie D. Weaver, Thomas D. Welton, Robert E. Hanes, Jr., Karen L. King, Gary P. Funkhouser
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Patent number: 8691736Abstract: The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or a suitable pH in the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to negative sites of the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.Type: GrantFiled: June 14, 2010Date of Patent: April 8, 2014Assignees: ConocoPhillips Company, University of KansasInventors: Ahmad Moradi-Araghi, James H. Hedges, David R. Zornes, Riley B. Needham, Huili Guan, Jenn-Tai Liang, Cory Berkland, James P. Johnson, Min Cheng, Faye L. Scully
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Patent number: 8680028Abstract: A method for the treatment of rock formations which may or may not be underground and, more particularly, of oil or gas production wells, water-injection wells intended to flood hydrocarbon (oil or gas) reservoirs or gas mines or gas storage wells includes a step of injecting, into the rock formation or well, a microgel obtained by dilution in water of a self-invertible inverse latex or of a self-invertible inverse microlatex of a crosslinked polyelectrolyte, obtained by copolymerization, in the presence of a crosslinking agent of partially- or totally-salified free 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid, with at least one cationic monomer chosen from: 2,N,N,N-tetramethyl-2-[(1-oxo-2-propenyl)amino]propanammonium chloride; N,N,N-trimethyl-3-[(1-oxo-2-propenyl)amino]propanammonium chloride; diallyldimethylammonium chloride; N,N,N-trimethyl-2-[(1-oxo-2-propenyl)]ethanammonium chloride; N,N,N-trimethyl-2-[(1-oxo-2-methyl-2-propenyl)]ethanammonium chloride; or N,N,N-trimethyl-3-[(1-oxo-2-methType: GrantFiled: June 2, 2009Date of Patent: March 25, 2014Assignees: Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC, PoweltecInventors: Olivier Braun, Paul Mallo, Alain Zaitoun
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Patent number: 8592353Abstract: Method of diverting fluids in a subterranean formation including the steps of providing a first fluid comprising an aqueous fluid and a hydrophobically modified water-soluble relative permeability modifier; introducing the first fluid into a well bore such that the first treatment fluid penetrates into a portion of the subterranean formation in a sufficient amount so as to substantially divert a second treatment fluid to another portion of the subterranean formation. Then, a second aqueous fluid is introduced into the well bore and substantially diverted from the portion of the subterranean formation penetrated with the first treatment fluid. In some cases, a well treatment operation, such as acid stimulation operation, a clay stabilization operation, or a scale inhibition operation, is performed using the second fluid.Type: GrantFiled: March 16, 2012Date of Patent: November 26, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Larry S. Eoff, B. Raghava Reddy
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Publication number: 20130310285Abstract: A treatment fluid made of mineral acid, viscoelastic surfactant, at least one of a fluoride source and a chelant, and optionally a corrosion inhibitor. A method of combining a mineral acid, viscoelastic surfactant, at least one of a fluoride source and a chelant, and optionally a corrosion inhibitor, in a fluid mixture. A method of contacting a low-temperature formation with a fluid mixture of mineral acid, viscoelastic surfactant, at least one of a fluoride source and a chelant, and optionally a corrosion inhibitor.Type: ApplicationFiled: May 18, 2012Publication date: November 21, 2013Inventors: Andrey Fedorov, Bernhard Lungwitz, Olesya Levanyuk, Philippe Enkababian
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Patent number: 8586510Abstract: A method comprising: providing at least one encaged treatment chemical that comprises a treatment chemical and a polymer carrier; placing the encaged treatment chemical into a portion of a subterranean formation; and allowing the treatment chemical to diffuse out of the encaged treatment chemical and into a portion of the subterranean formation or an area adjacent thereto.Type: GrantFiled: April 15, 2005Date of Patent: November 19, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Michael A. McCabe, Jim D. Weaver, Robert E. Hanes, Billy F. Slabaugh
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Patent number: 8586511Abstract: This invention provides a method for inhibiting scale formation within a hydrocarbon producing system, said method comprising contacting said system with a copolymer formed from a diallyl ammonium salt and at least one other monomer.Type: GrantFiled: August 2, 2006Date of Patent: November 19, 2013Assignee: Champion Technologies Ltd.Inventors: Ping Chen, Xing Yan, Thomas Hagen, Harry Montgomerie
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Publication number: 20130255954Abstract: Fracturing fluid comprising, in solution in water, a proppant and an associative amphoteric polymer, the said polymer having a molecular weight of at least 1 000 000 g/mol and comprising: 0.01 to 10 mol % of at least one cationic monomer derived from acrylamide, from 0.09 to 89.99 mol % of at least one anionic monomer, and from 10 to 99 mol % of at least one nonionic water-soluble monomer. Fracturing process using the fluid.Type: ApplicationFiled: March 15, 2013Publication date: October 3, 2013Applicant: S.P.C.M. SAInventors: Cédrick FAVERO, Nicolas GAILLARD
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Patent number: 8507413Abstract: Clay is stabilized in methods for drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid including a choline compound together with an formation control additive.Type: GrantFiled: January 17, 2012Date of Patent: August 13, 2013Assignee: Clearwater International, LLCInventor: Thomas P. Wilson, Jr.
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Patent number: 8492317Abstract: Methods and compositions are provided that relate to cementing operations. Methods and compositions that include a latex strength enhancer for enhancing the compressive strength of slag compositions.Type: GrantFiled: March 15, 2012Date of Patent: July 23, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Jiten Chatterji, Chad Brenneis, Callie R. Jarratt
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Patent number: 8470746Abstract: The present invention relates to methods and compositions for treating a water- and hydrocarbon-producing subterranean formation with a relative permeability modifier, and more specifically, to improved treatment fluids, methods for preparing treatment fluids, and methods for use thereof in a subterranean formation. Methods of the present invention comprise providing a treatment fluid comprising a relative permeability modifier, at least one surfactant, and an aqueous phase base fluid; and placing the treatment fluid in a subterranean formation. The relative permeability modifier comprises a hydrophobically modified hydrophilic polymer. The at least one surfactant is operable to maintain the relative permeability modifier in a dissolved state in the treatment fluid above a pH of about 8.Type: GrantFiled: November 30, 2010Date of Patent: June 25, 2013Assignee: Halliburton Energy Services, Inc.Inventor: Larry S. Eoff
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Publication number: 20130105154Abstract: Well treatment agents containing a particulate substrate are coated with a polyelectrolyte bilayer to provide a well treatment composite for use in well treatment operations. Each layer of the polyelectrolyte bilayer is composed of oppositely charged polyionic material. The well treatment composite may further contain a succession of polyelectrolyte bilayers, each polyelectrolyte bilayer containing layers of oppositely charged polyionic materials.Type: ApplicationFiled: October 27, 2011Publication date: May 2, 2013Inventors: Mark Alan Vorderbruggen, Hong Sun, Qi Qu
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Publication number: 20130105165Abstract: Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.Type: ApplicationFiled: November 19, 2012Publication date: May 2, 2013Applicant: BASF SEInventor: BASF SE
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Patent number: 8343896Abstract: Methods are provided comprising providing a sealant composition comprising an aqueous fluid, a diutan composition, at least one gel system, and a leak off prevention material; introducing the sealant composition into a well bore penetrating the subterranean formation; and allowing the sealant composition to form a seal.Type: GrantFiled: September 30, 2009Date of Patent: January 1, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, Richard W. Pauls
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Patent number: 8343897Abstract: Provided is a method for inhibiting scale formation within a hydrocarbon producing system, said method comprising contacting said system with a polymer formed from a diallyl ammonium salt, a monomer comprising one carboxylate group and a monomer comprising at least two carboxylate groups or an anhydride group. Also provided are hydrocarbon well treatment compositions and polymers for use in connection with the provided methods. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: GrantFiled: January 15, 2007Date of Patent: January 1, 2013Assignees: Sichuan Sanyuan Chem Limited, Corporation, Champion Technologies LimitedInventors: Harry Montgomerie, Ping Chen, Thomas Hagen, Liehua Zheng
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Publication number: 20120258894Abstract: Methods and compositions are described for treating water- and hydrocarbon-producing subterranean formations with a relative permeability modifier at concentrations below those conventionally used in the art, while not substantially impacting the treatment fluid's performance. Treatment fluids described herein comprise a base fluid, a relative permeability modifier comprising a hydrophobically modified hydrophilic polymer, and a companion polymer interacting synergistically with the relative permeability modifier such that the treatment fluid is operable to reduce the water permeability or to increase an aqueous fluid injection pressure of at least a portion of a subterranean formation by more than the relative permeability modifier or the companion polymer acting alone at like concentration. The water permeability reduction and/or the aqueous fluid injection pressure increase can be more than additive.Type: ApplicationFiled: April 7, 2011Publication date: October 11, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, Jeff W. Loucks, B. Raghava Reddy
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Patent number: 8278250Abstract: Methods of using relative permeability modifiers for the diversion of aqueous fluids during subterranean operations are provided. An embodiment of the present invention provides a method of diverting fluids in a subterranean formation that may comprise providing a treatment fluid comprising an aqueous fluid and a relative permeability modifier that comprises water-soluble polymer with hydrophobic or hydrophilic modification; introducing the treatment fluid into a well bore that penetrates the subterranean formation; and at least a first portion of the treatment fluid to penetrate into a portion of the subterranean formation so as to substantially divert a second portion of the treatment fluid or another aqueous treatment fluid to another portion of the subterranean.Type: GrantFiled: May 5, 2005Date of Patent: October 2, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Larry S. Eoff, B. Raghava Reddy
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Publication number: 20120214714Abstract: A process for achieving enhanced levels of friction reduction in high salinity conditions, particularly suited to slick-water hydraulic fracturing and coiled tubing applications, uses low charge and preferably uncharged water soluble high molecular weight polymers. A fracturing fluid is injected into a conduit. The fracturing fluid is an aqueous solution comprising at least one water soluble (co)polymer comprising less than 10 mol % ionic monomer(s), and the aqueous solution comprises total dissolved salts concentration ranging from 100,000 mg/L to up to the salt concentration at which the aqueous solution becomes saturated in salts.Type: ApplicationFiled: February 28, 2011Publication date: August 23, 2012Applicant: SNF HOLDING COMPANYInventors: Paul WHITWELL, Russell THORPE
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Publication number: 20120196776Abstract: A method of servicing a well is disclosed. The method comprises mixing ingredients to form a well servicing fluid. The ingredients comprise (i) at least one surfactant chosen from alcohol ethoxylates, C4 to C12 primary alcohols and ethoxylated propoxylated alcohols, (ii) a zwitterionic polymer prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba, and (iii) a saline based aqueous solution. The well servicing fluid is introduced into a hydrocarbon well.Type: ApplicationFiled: February 2, 2011Publication date: August 2, 2012Inventors: D.V. Satyanarayana Gupta, Madhukar Chetty, Paul Carman
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Publication number: 20120172263Abstract: Composition comprising a plurality of particulates wherein at least some particulates are at least partially covered with a coating that impedes the intrusion of water into the particulates; and, a silica scale control additive, wherein the silica scale control additive is capable of suppressing silica scale build-up proximate the plurality of particulates. Some compositions further include a treatment fluid wherein and the silica scale control additive are present in the treatment fluid.Type: ApplicationFiled: March 16, 2012Publication date: July 5, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Enrique A. Reyes, Jimmie D. Weaver, Matt E. Blauch, Corine L. McMechan
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Publication number: 20120135895Abstract: The present invention relates to methods and compositions for treating a water- and hydrocarbon-producing subterranean formation with a relative permeability modifier, and more specifically, to improved treatment fluids, methods for preparing treatment fluids, and methods for use thereof in a subterranean formation. Methods of the present invention comprise providing a treatment fluid comprising a relative permeability modifier, at least one surfactant, and an aqueous phase base fluid; and placing the treatment fluid in a subterranean formation. The relative permeability modifier comprises a hydrophobically modified hydrophilic polymer. The at least one surfactant is operable to maintain the relative permeability modifier in a dissolved state in the treatment fluid above a pH of about 8.Type: ApplicationFiled: November 30, 2010Publication date: May 31, 2012Applicant: Halliburton Energy Services, Inc.Inventor: Larry S. Eoff
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Publication number: 20120129738Abstract: The present disclosure is directed to a method comprising: mixing (i) a zwitterionic polymer prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba, (ii) a surfactant and (iii) produced water to form a well servicing fluid. The resulting well servicing fluid is introduced into a hydrocarbon well.Type: ApplicationFiled: November 19, 2010Publication date: May 24, 2012Inventors: D.V. Satyanarayana GUPTA, Madhukar Chetty, Paul Scott Carman
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Publication number: 20120129734Abstract: What is proposed is the use of a water-soluble hydrophobically associating copolymer as an additive in the development, exploitation and completion of underground mineral oil and natural gas deposits and in deep drillings, wherein the copolymer comprises (a) at least one monoethylenically unsaturated monomer (a) selected from H2C?C(R1)—R4—O—(—CH2—CH2—O—)k—(—CH2—CH(R3)—O—)l—R5 ??(I), and/or H2C?C(R1)—O—(—CH2—CH2—O—)k—R2 ??(II), and (b) at least one monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a), wherein the copolymer is obtainable through copolymerization of the monomers (a) and (b) in the presence of at least one surfactant (c).Type: ApplicationFiled: November 9, 2011Publication date: May 24, 2012Inventors: Roland REICHENBACH-KLINKE, Oscar Lafuente Cerda, Andrea Assmann, Björn Langlotz
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Patent number: 8183181Abstract: The present disclosure is directed to a method comprising: mixing (i) a zwitterionic polymer prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba, (ii) a surfactant and (iii) produced water to form a well servicing fluid. The resulting well servicing fluid is introduced into a hydrocarbon well.Type: GrantFiled: November 19, 2010Date of Patent: May 22, 2012Assignee: Baker Hughes IncorporatedInventors: D. V. Satyanarayana Gupta, Madhukar Chetty, Paul Scott Carman
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Patent number: 8143197Abstract: The invention concerns an aqueous viscoelastic fracturing fluid for use in the recovery of hydrocarbons. According to the invention, the fluid comprises a cleavable viscoelastic surfactant and a hydrophobically-modified polymer, wherein the cleavable surfactant comprises a head group and a hydrophobic tail of at least 18 carbon atoms connected through a degradable acetal, amide, ether or ester bond and wherein the concentration of the hydrophobically-modified polymer is comprised between its overlap concentration c* and its entanglement concentration ce.Type: GrantFiled: July 18, 2008Date of Patent: March 27, 2012Assignee: Schlumberger Technology CorporationInventors: Isabelle Couillet, Trevor Hughes
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Patent number: 8101554Abstract: The present invention provides a method for increasing the retention of a scale inhibitor within a hydrocarbon producing system (e.g. a subterranean formation), said method comprising contacting said system with a polymer formed from a diallyl ammonium salt and with said scale inhibitor, wherein said polymer formed from a diallyl ammonium salt has a molecular weight of greater than 50,000 (e.g. a molecular weight of 55,000 to 2,000,000).Type: GrantFiled: August 16, 2007Date of Patent: January 24, 2012Assignees: Champion Technologies Ltd., Statoilhydro ASA.Inventors: Harry Montgomerie, Ping Chen, Thomas Hagen, Rex Wat, Olav Martin Selle
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Patent number: 8097567Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid including a choline compound together with an formation control additive.Type: GrantFiled: January 9, 2006Date of Patent: January 17, 2012Assignee: Clearwater International, LLCInventor: Thomas P Wilson, Jr.
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Patent number: 8076271Abstract: The present invention relates to aqueous tackifiers and methods of controlling particulates in subterranean formations using aqueous tackifiers. Some embodiments of the present invention provide methods of controlling particulates, comprising placing an aqueous tackifier compound into a portion of a subterranean formation comprising unconsolidated particulates; and, activating the aqueous tackifier compound. Other embodiments of the present invention provide methods of coating a portion of a surface in a subterranean formation comprising substantially coating an aqueous tackifier compound onto a portion of a subterranean formation; and, activating the aqueous tackifier compound. Other embodiments of the present invention provide treatment fluids for controlling fine particulates, comprising a servicing fluid and an aqueous tackifier compound.Type: GrantFiled: June 9, 2004Date of Patent: December 13, 2011Assignee: Halliburton Energy Services, Inc.Inventors: Matthew E. Blauch, Thomas D. Welton, Philip D. Nguyen
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Patent number: 7956012Abstract: The present disclosure is directed to a method comprising introducing into a well bore a fluid comprising a zwitterionic polymer. The polymer is prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba. The well bore is chosen from a natural gas well bore and an oil well bore.Type: GrantFiled: February 4, 2009Date of Patent: June 7, 2011Assignee: BJ Services Company LLCInventors: D. V. Satyanarayana Gupta, Madhukar Chetty, Paul Carman
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Patent number: 7884056Abstract: The invention relates to a composition that can form a gel comprising a copolymer. Said composition is an aqueous composition, and the copolymer is a star copolymer. The invention also relates to useful copolymers, especially for the inventive compositions.Type: GrantFiled: December 20, 2005Date of Patent: February 8, 2011Assignee: Rhodia ChimieInventors: Denis Bendejacq, Claire Pitois, Katerina Karagianni