Nitrogen Of The Quaternary Ammonium Group Is A Member Of A Hetero Ring Patents (Class 507/223)
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Publication number: 20150047848Abstract: A well treatment composite is characterized by particulates wherein at least a portion of the substrate of the particulates is coated with a polycationic polymer. The presence of the polycationic polymer on the surface of the well treatment particulates reduces the generation of dust and fines during a well treatment operation. The polycationic polymer further reduces the amount of dust or fines generated during transport of the well treatment particulates to a remote location as well during the manufacture or processing of well treatment particulates.Type: ApplicationFiled: October 28, 2014Publication date: February 19, 2015Inventors: Naima Bestaoui-Spurr, Mark Alan Vorderbruggen, D.V. Satyanarayana Gupta, Harold Gene Hudson
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Patent number: 8796187Abstract: Composition comprising a plurality of particulates wherein at least some particulates are at least partially covered with a coating that impedes the intrusion of water into the particulates; and, a silica scale control additive, wherein the silica scale control additive is capable of suppressing silica scale build-up proximate the plurality of particulates. Some compositions further include a treatment fluid wherein and the silica scale control additive are present in the treatment fluid.Type: GrantFiled: March 16, 2012Date of Patent: August 5, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Enrique A. Reyes, Jimmie D. Weaver, Matt E. Blauch, Corine L. McMechan
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Patent number: 8697613Abstract: Methods comprising: providing an aqueous treatment fluid comprising an aqueous fluid, a friction reducing polymer, and an antiflocculation additive; and introducing the treatment fluid into a subterranean formation. Methods of fracturing a subterranean formation comprising: providing an aqueous treatment fluid comprising an aqueous fluid, a friction reducing polymer, and an antiflocculation additive; and introducing the treatment fluid into a well bore penetrating the subterranean formation at rate in the range of from about 30 barrels to about 250 barrels per minute so as to create or enhance one or more fractures in the subterranean formation. Aqueous treatment fluids comprising: an aqueous fluid, a friction reducing polymer in an amount sufficient to reduce friction without forming a gel, and an antiflocculation additive.Type: GrantFiled: March 3, 2006Date of Patent: April 15, 2014Assignee: Halliburton Energy Services, Inc.Inventors: David E. McMechan, Jimmie D. Weaver, Thomas D. Welton, Robert E. Hanes, Jr., Karen L. King, Gary P. Funkhouser
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Patent number: 8691736Abstract: The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or a suitable pH in the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to negative sites of the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.Type: GrantFiled: June 14, 2010Date of Patent: April 8, 2014Assignees: ConocoPhillips Company, University of KansasInventors: Ahmad Moradi-Araghi, James H. Hedges, David R. Zornes, Riley B. Needham, Huili Guan, Jenn-Tai Liang, Cory Berkland, James P. Johnson, Min Cheng, Faye L. Scully
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Patent number: 8680028Abstract: A method for the treatment of rock formations which may or may not be underground and, more particularly, of oil or gas production wells, water-injection wells intended to flood hydrocarbon (oil or gas) reservoirs or gas mines or gas storage wells includes a step of injecting, into the rock formation or well, a microgel obtained by dilution in water of a self-invertible inverse latex or of a self-invertible inverse microlatex of a crosslinked polyelectrolyte, obtained by copolymerization, in the presence of a crosslinking agent of partially- or totally-salified free 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid, with at least one cationic monomer chosen from: 2,N,N,N-tetramethyl-2-[(1-oxo-2-propenyl)amino]propanammonium chloride; N,N,N-trimethyl-3-[(1-oxo-2-propenyl)amino]propanammonium chloride; diallyldimethylammonium chloride; N,N,N-trimethyl-2-[(1-oxo-2-propenyl)]ethanammonium chloride; N,N,N-trimethyl-2-[(1-oxo-2-methyl-2-propenyl)]ethanammonium chloride; or N,N,N-trimethyl-3-[(1-oxo-2-methType: GrantFiled: June 2, 2009Date of Patent: March 25, 2014Assignees: Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC, PoweltecInventors: Olivier Braun, Paul Mallo, Alain Zaitoun
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Publication number: 20130233545Abstract: The present invention provides modified proppants, and methods for their manufacture. In embodiments, the modified proppant comprises a proppant particle and a hydrogel coating, wherein the hydrogel coating is applied to a surface of the proppant particle and localizes on the surface to produce the modified proppant. In embodiments, formulations are disclosed comprising the modified particles, and methods are disclosed for using the formulations.Type: ApplicationFiled: August 30, 2012Publication date: September 12, 2013Inventors: Robert P. Mahoney, David S. Soane, Marie K. Herring, Kevin P. Kincaid
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Patent number: 8455404Abstract: Additives and treatment fluids with improved shale inhibition, and associated methods of use in subterranean operations, are provided. The additives and treatment fluids used generally comprise a shale-inhibiting component and one or more silicates.Type: GrantFiled: July 15, 2005Date of Patent: June 4, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Elaine Harrower, Arthur Youngson, Colin Temple
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Patent number: 8420577Abstract: Polyboronic compounds and methods of making them are provided. The polyboronic compounds are useful as crosslinking agents. The polyboronic compounds are produced by contacting a polymeric amine with a trialkylborate in the presence of a solvent so that the resulting molecule has more than one B—N bond.Type: GrantFiled: October 16, 2009Date of Patent: April 16, 2013Assignee: Baker Hughes IncorporatedInventors: Hong Sun, Frances De Benedictis, Qi Qu
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Patent number: 8372789Abstract: Methods that comprise selecting proppant for use in a fracturing fluid based on one or more factors, wherein the one or more factors comprise an interaction between the proppant and the fracturing fluid. Methods that comprise designing a treatment fluid that comprises a gelled base fluid and a particulate based on one or more factors, wherein the one or more factors comprise an interaction between the particulate and the gelled base fluid.Type: GrantFiled: January 16, 2009Date of Patent: February 12, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Phillip C. Harris, Stanley J. Heath, Harold G. Walters
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Patent number: 8343896Abstract: Methods are provided comprising providing a sealant composition comprising an aqueous fluid, a diutan composition, at least one gel system, and a leak off prevention material; introducing the sealant composition into a well bore penetrating the subterranean formation; and allowing the sealant composition to form a seal.Type: GrantFiled: September 30, 2009Date of Patent: January 1, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, Richard W. Pauls
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Publication number: 20120329684Abstract: Coacervate gels having excellent shear viscosities and other properties are made with anionic or cationic polymers, a smaller amount of a surfactant having a charge opposite that of the polymer, and a hydrophobic alcohol and an effective amount of a phosphorus-containing compound sufficient to increase the viscosity of coacervate gels up to 3 times as compared to the gels in the absence of the phosphorus-containing compound. The Zeta Potential of the gel is maintained at an absolute value of at least 20. Optional gel promoting additives include betaines and amine oxides. A preferred gel comprises poly diallyl dimethyl ammonium chloride, a lesser amount of sodium lauryl sulfonate, and lauryl alcohol. The gels are particularly useful in well drilling fluids and well fracturing fluids.Type: ApplicationFiled: September 7, 2012Publication date: December 27, 2012Inventor: Kevin M. Schwartz
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Patent number: 8193124Abstract: A wellbore fluid that includes an oleaginous base fluid; and a silanated weighting agent is disclosed. In particular, the silanated weighting agents may be produced by reaction between an alkyl alkoxy silane and a weighting agent Methods of formulating such fluids and methods of drilling using such fluids are also disclosed.Type: GrantFiled: January 22, 2009Date of Patent: June 5, 2012Assignee: M-I L.L.C.Inventors: Sashikumar Mettath, Steven Young
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Publication number: 20120103615Abstract: A wellbore fluid contains a viscosifying polymer in which portions of the polymer are connected through formation of an inclusion complex involving cucurbituril 8 (i.e. CB[8]) as host molecule. The fluid contains guest molecules with first and second guest groups covalently attached wherein at least one of the guest molecules comprises a polymer chain. The CB [8] host and the guest molecules attach together through reception of first and second guest groups within CB[8] host cavities, thereby connecting polymer chains together as a larger, supramolecular polymer and enhancing viscosity of the fluid. Polymer molecules may be synthetic polymers and guest groups may be attached to monomers before polymerization. Alternatively guest groups may be attached to existing polymers which may be polysaccharide.Type: ApplicationFiled: August 30, 2011Publication date: May 3, 2012Applicant: Schlumberger Technology CorporationInventors: Oren A. Scherman, Eric Appel, Trevor Hughes
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Patent number: 7833945Abstract: Additives and treatment fluids with improved shale inhibition, and associated methods of use in subterranean operations, are provided. The additives and treatment fluids used generally comprise a shale-inhibiting component and one or more silicates.Type: GrantFiled: July 15, 2005Date of Patent: November 16, 2010Assignee: Halliburton Energy Services Inc.Inventors: Elaine Harrower, Arthur Youngson, Colin Temple
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Publication number: 20100230106Abstract: A fluid comprising a viscous hyposaline aqueous solution of first and second cationic polymers comprising quaternized ammonium groups, wherein the first cationic polymer comprises a hydrophilic base polymer structure and the second cationic polymer comprises a lipophilic base polymer structure, and a method comprising introducing the viscous fluid into an initial first interval of a subterranean formation, and diverting with the viscous fluid a treating fluid from the initial first interval to an initial second interval. The fluid and method are useful to modify a hydrocarbon reservoir formation for improved relative permeability of oil with respect to water to enhance hydrocarbon production from the reservoir.Type: ApplicationFiled: February 23, 2010Publication date: September 16, 2010Inventors: Arthur Milne, Eric Gin Wai Lian, Sandra Janette Montoya Padilla, Mario Ulloa, Frederic Vincent Martin, Mathew M. Samuel
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Patent number: 7651981Abstract: A process for recovering materials from a subterranean formation, for example in enhanced oil recovery, comprises: (A) (a) (i) selecting a first polymeric material having a repeat unit of formula (A) wherein A and B are the same or different, are selected from optionally-substituted aromatic and heteroaromatic groups and at least one comprises a relatively polar atom or group and R1 and R2 independently comprise relatively non-polar atoms or groups; or (ii) selecting a first polymeric material prepared or preparable by providing a compound of general formula (B) wherein A, B, R1 and R2 are as described above, in an aqueous solvent and causing the groups C?C in said compound to react with one another to form said first polymeric material; (b) selecting a second polymeric material which includes a functional group which is able to react in the presence of said first polymeric material to form a third polymeric material; (c) causing the formation of said third polymeric material by a reaction involving said firsType: GrantFiled: March 28, 2003Date of Patent: January 26, 2010Assignees: Advanced Gel Technology Limited, Aubin LimitedInventors: Donald Eagland, Nicholas John Crowther, James Murray, Austin Tobin
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Patent number: 6803348Abstract: The use of a hydrophobically modified water soluble polymer is described capable of being chemically cross-linked so as to produce a stable gel for blocking a water-bearing formation from a hydrocarbon-producing well. The polymer is essentially linear having hydrophilic side groups located at random positions along its backbone.Type: GrantFiled: November 16, 2000Date of Patent: October 12, 2004Assignee: Schlumberger Technology CorporationInventors: Timothy G. J. Jones, Gary J. Tustin