Process Of Making Fluids Or Additives Therefor Patents (Class 507/904)
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Patent number: 7629296Abstract: A process of preparing a well servicing fluid comprising viscosifying a heavy brine by contacting with a cationic polysaccharide and a composition thereof.Type: GrantFiled: November 16, 2005Date of Patent: December 8, 2009Assignee: Rhodia Inc.Inventors: Manilal S. Dahanayake, Subramanian Kesavan, Allwyn Colaco
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Patent number: 7562711Abstract: A method of servicing a wellbore comprising transporting at least two portable tanks to a well site to be serviced, and hydraulically injecting biocide into a first of the two tanks, wherein a second of the two tanks serves as a fluid source for conveying the biocide into the first tank.Type: GrantFiled: January 8, 2007Date of Patent: July 21, 2009Assignee: Halliburton Energy Services, Inc.Inventors: Edward Flemma, Jr., Mitch Mitchum
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Patent number: 7546874Abstract: A cavitation device is used to heat, concentrate and recycle or otherwise reuse dilute and other oil well fluids, brines and muds, and solution mining fluids, all of which commonly contain ingredients worthy of conservation. The cavitation device can be powered by a Diesel engine whose exhaust may be used to heat the incoming fluid, and the product of the cavitation device is directed to a flash tank.Type: GrantFiled: January 22, 2007Date of Patent: June 16, 2009Assignee: Total Separation Solutions, LLCInventors: Kevin W. Smith, Robert L. Sloan, Harry D. Smith, Jr.
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Patent number: 7538074Abstract: A wellbore fluid having an oleaginous phase and an additive for increasing the density of the wellbore fluid. The additive comprises solid colloidal particles coated with a dispersant coated onto the colloidal particle during the comminution process of forming the particles. Exemplary starting materials for the colloidal particles include commonly known weighting agents including barite, calcium carbonate, dolomite, ilmenite, hematite or other iron ores, olivine, siderite, and strontium sulfate as well as mixture and combinations of these and other similar weighting materials. The dispersant in one illustrative embodiment, is selected from carboxylic acids of molecular weight of at least 150 Daltons.Type: GrantFiled: April 19, 2007Date of Patent: May 26, 2009Assignee: M-I L.L.C.Inventors: Andrew J. Bradbury, Jarrod Massam, Christopher A. Sawdon
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Patent number: 7513307Abstract: A system and method to inject a combined aqueous or hydrocarbon-based liquid stream and a liquid carbon dioxide stream into a subterranean formation via a well using a single high-pressure pump.Type: GrantFiled: August 9, 2006Date of Patent: April 7, 2009Assignee: Team CO2 Holdings LLCInventor: Randal L. Decker
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Patent number: 7461697Abstract: Methods comprising: providing a treatment fluid that comprises a base fluid and a least a plurality of coated particulates, the coated particulates having been treated with a surface modification agent and coated with a hydrolysable coating; placing the treatment fluid into a subterranean formation via a well bore. Also provided are methods comprising: treating a particulate with a surface modification agent; coating the particulate with a hydrolysable coating that has an initial degradation rate to produce a coated particulate; placing the particulate in a subterranean formation; and allowing the hydrolysable coating to degrade at a second degradation rate that is slower than its initial degradation rate.Type: GrantFiled: November 21, 2005Date of Patent: December 9, 2008Assignee: Halliburton Energy Services, Inc.Inventors: Bradley L. Todd, Keith A. Frost, Jimmie D. Weaver, Bessie Q. Citrowske
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Patent number: 7350571Abstract: The present invention involves methods of preparing coated particulates and using such coated particulates in subterranean applications such as production enhancement and sand control. One embodiment of the present invention provides a method of preparing coated particulates comprising the steps of coating particulates with a resin or a tackifying agent to create pre-coated particulates; and, covering the pre-coated particulates with a partitioning agent to create coated particulates.Type: GrantFiled: March 7, 2006Date of Patent: April 1, 2008Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Jimmie D. Weaver
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Patent number: 7341104Abstract: Fracturing fluids comprising a base fluid and substantially hydrated cement particulates. Methods of fracturing a subterranean formation comprising fracturing the subterranean formation so as to create or enhance one or more fractures in the subterranean formation; introducing a fracturing fluid comprising a base fluid and substantially hydrated cement particulates into the one or more fractures; and depositing at least a portion of the substantially hydrated cement particulates in the one or more fractures in the subterranean formation. Methods of gravel packing comprising providing a gravel packing fluid comprising a base fluid and substantially hydrated cement particulates, introducing the gravel packing fluid into a subterranean formation, and depositing at least a portion of the substantially hydrated cement particulates in the subterranean formation so as to form a gravel pack. Gravel packing fluids that comprise a base fluid, and gravel comprising substantially hydrated cement particulates.Type: GrantFiled: March 24, 2006Date of Patent: March 11, 2008Assignee: Halliburton Energy Services, Inc.Inventor: Craig W. Roddy
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Patent number: 7308939Abstract: Methods are provided including a method comprising: providing a treatment fluid comprising particulates at least partially coated with a polymer, wherein the polymer is deposited on the particulates by at least partially coating the particulates with a polymer solution comprising the polymer and a solvent and then exposing the particulates to an aqueous medium such that the solvent substantially dissociates from the polymer solution and such that the polymer substantially remains on the particulates; introducing the treatment fluid into a portion of a subterranean formation; and, depositing at least a portion of the particulates in the portion of the subterranean formation.Type: GrantFiled: March 9, 2005Date of Patent: December 18, 2007Assignee: Halliburton Energy Services, Inc.Inventors: Thomas D. Welton, Philip D. Nguyen
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Patent number: 7267291Abstract: A wellbore fluid having an oleaginous phase and an additive for increasing the density of the wellbore fluid. The additive comprises solid colloidal particles coated with a dispersant during the comminution process of forming the particles. Exemplary starting materials for the colloidal particles include commonly known weighting agents as well as mixture and combinations thereof. The dispersant in one embodiment, is selected from carboxylic acids of molecular weight of at least 150 Daltons. Alternatively, the dispersant coating may be made of compounds including oleic acid, polybasic fatty acids, alkylbenzene sulfonic acids, alkane sulfonic acids, linear alpha-olefin sulfonic acid or the alkaline earth metal salts of any of the above acids, and phospholipids as well as mixtures and combinations of these compounds. In another embodiment the dispersant is a polyacrylate ester having an average molecular weight from about 10,000 Daltons to about 200,000 Daltons.Type: GrantFiled: June 30, 2003Date of Patent: September 11, 2007Assignee: M-I LLCInventors: Andrew J. Bradbury, Jarrod Massam, Christopher A. Sawdon
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Patent number: 7261157Abstract: Methods for controlling particulate segregation comprising providing a mixture of an aqueous tackifying composition with a treatment fluid; slurrying the mixture with a first type of solid particulates and a second type of solid particulates and wherein the first type of solid particulates have a tendency to segregate from the second type of solid particulates when slurried into a liquid; and, placing the slurry into a portion of a subterranean formation. Methods for controlling particulate segregation comprising providing a treatment fluid; at least partially coating with an aqueous tackifying composition: a first type of solid particulates and a second type of solid particulates and wherein the first type of solid particulates have a tendency to segregate from the second type of solid particulates when slurried into a liquid; slurrying the two types of particulates into the treatment fluid; and, placing the slurry into a portion of a subterranean formation.Type: GrantFiled: December 8, 2004Date of Patent: August 28, 2007Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Matthew E. Blauch, Thomas D. Welton
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Patent number: 7256159Abstract: The present invention concerns a water-based drilling mud for utilization in the drilling of oil wells comprising an aqueous phase wherein the aqueous phase contains an oil soluble polymer in the form of a gel as a fluid loss reducer. The subject invention further reveals a method of lubricating a drilling bit during the drilling of a well which comprises circulating a water-based drilling mud in the vicinity of the drilling bit wherein the water-based drilling mud is comprised of an aqueous phase, and wherein the aqueous phase contains an oil soluble polymer in the form of a gel as a fluid loss reducer.Type: GrantFiled: August 23, 2006Date of Patent: August 14, 2007Assignee: Eliokem S.A.S.Inventors: Bertrand Guichard, Barry Wood, Patrick Vongphouthone
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Patent number: 7204310Abstract: Settable drilling fluids comprising an aqueous-based drilling fluid and cement kiln dust. Methods of cementing in a subterranean formation comprising: providing a settable drilling fluid comprising an aqueous-based drilling fluid and cement kiln dust, introducing the settable drilling fluid into a subterranean formation, and allowing the settable drilling fluid to set in the subterranean formation. Methods of converting an aqueous-based drilling fluid to a settable drilling fluid comprising: providing the aqueous-based drilling fluid, and adding cement kiln dust to the aqueous-based drilling fluid to form the settable drilling fluid. Methods of drilling a well bore and cementing a well bore comprising: drilling a well bore, circulating an aqueous-based drilling fluid in the well bore during the step of drilling the well bore, adding cement kiln dust to the aqueous-based drilling fluid to form a settable drilling fluid, and allowing the settable drilling fluid to set in the well bore.Type: GrantFiled: April 11, 2006Date of Patent: April 17, 2007Assignee: Halliburton Energy Services, Inc.Inventors: Craig W. Roddy, Jiten Chatterji, D. Chad Brenneis, Bobby J. King
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Patent number: 7128149Abstract: Apparatus and methods for determining suitable displacement fluids for use in subterranean cementing operations, and methods of cementing that use such displacement fluids, are provided. Examples of methods include methods of water-wetting an annulus in a subterranean formation having an oleaginous-external/aqueous-internal fluid disposed on at least a portion of one or more surfaces of the annulus. Another example of a method is a method of using an inverter fluid in a subterranean formation that includes a tubular string disposed therein having an annular region adjacent the outer surface of the tubular string, at least part of the annular region having an oleaginous-external/aqueous-internal fluid on a surface thereof. Another example of a method of the present invention is a method of identifying an inverter fluid to use for inverting an oleaginous-external/aqueous-internal fluid in a subterranean formation.Type: GrantFiled: August 24, 2005Date of Patent: October 31, 2006Assignee: Halliburton Energy Services, Inc.Inventors: James F. Heathman, Sears T. Dealy, James H. Cantrell, Dennis W. Gray
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Patent number: 7121339Abstract: A solids-stabilized oil-in-water emulsion and a method for preparing the solids-stabilized oil-in-water emulsion. The oil-in-water emulsion is formed by combining oil, water, solid particles and a pH enhancing agent and mixing until the solid-stabilized oil-in-water emulsion is formed. The low viscosity oil-in-water emulsion can be used to enhance production of oil from subterranean reservoirs. The low viscosity oil-in-water emulsion can also be used to enhance the transportation of oil through a pipeline.Type: GrantFiled: November 8, 2005Date of Patent: October 17, 2006Assignee: ExxonMobil Upstream Research CompanyInventors: James R. Bragg, Ramesh Varadaraj
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Patent number: 7104328Abstract: The present invention relates to a method and system for hydrating a gel for treating a wellbore penetrating a subterranean formation. The method includes directing a base fluid through an inlet into a mixer having an inner chamber housing a plurality of impellors extending radially from and rotating about a hub, causing a centrifugal motion of the base fluid, feeding a quantity of gel into the mixer, mixing the gel with the base fluid and discharging the now-hydrated gel from the inner chamber through an outlet of the mixer. A prewetting device may also be used. Thereafter, a variety of additives may be added to the gel fluid mix to form a fluid treatment to be introduced into a subterranean formation.Type: GrantFiled: October 5, 2005Date of Patent: September 12, 2006Assignee: Halliburton Energy Services, Inc.Inventors: Max L. Phillippi, Billy Slabaugh
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Patent number: 7101829Abstract: The present invention concerns a water-based drilling mud for utilization in the drilling of oil wells comprising an aqueous phase wherein the aqueous phase contains an oil soluble polymer in the form of a gel as fluid loss reducer. The subject invention further reveals a process for preparing an oil soluble polymer fluid loss control agent comprising the steps of dissolving at least one polymer in a hydrocarbon oil to form a clear solution or a gel, adding an emulsifier to the solution or the gel, and keeping the mixture under conditions of agitation until a clear creamy mixture is obtained.Type: GrantFiled: December 17, 2003Date of Patent: September 5, 2006Assignee: Eliokem S.A.S.Inventors: Bertrand Guichard, Barry Wood, Patrick Vongphouthone
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Patent number: 7086466Abstract: The present invention relates to substantially hydrated cement particulates. More particularly, the present invention relates to compositions comprising substantially hydrated cement particulates and associated methods of use in drilling and subterranean applications. These substantially hydrated cement particulates may be included in drilling and subterranean treatment fluids, inter alia, as carrier particles for admixtures, lost circulation materials, density-varying additives, proppants, and the like.Type: GrantFiled: February 10, 2004Date of Patent: August 8, 2006Assignee: Halliburton Energy Services, Inc.Inventor: Craig W. Roddy
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Patent number: 7077219Abstract: Methods in which temperature is used to control the foaming and/or defoaming of foamed treatment fluids comprising an aqueous liquid, an ionic foaming surfactant, and a gas are provided. A method of treating at least a portion of a subterranean formation is provided, the method comprising: providing a treatment fluid having a foam transition temperature, the treatment fluid comprising an aqueous liquid, and an ionic foaming surfactant; foaming the treatment fluid to form a foamed treatment fluid; circulating the foamed treatment fluid in a well bore penetrating the subterranean formation; and defoaming at least a substantial portion of the foamed treatment fluid, the defoaming comprising lowering the temperature of the foamed treatment fluid to about at or below the foam transition temperature.Type: GrantFiled: February 18, 2005Date of Patent: July 18, 2006Assignee: Halliburton Energy Services, Inc.Inventors: Jiten Chatterji, Gary P. Funkhouser, Bobby J. King
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Patent number: 7040419Abstract: The current invention provides improved methods and compositions for completing a well bore. In one aspect, the current invention provides a process for preparing a foamed well composition. The process utilizes air to foam the composition after the air has been treated to lower the oxygen content below that concentration necessary to support combustion. Additionally, the current invention provides a process for completing and/or treating a well bore using a foamed composition wherein the foam is generated with reduced oxygen content air. Finally, a preferred embodiment of the invention provides a foamed cement composition wherein the gaseous portion of the composition is air having a reduced oxygen content.Type: GrantFiled: July 9, 2003Date of Patent: May 9, 2006Assignee: Halliburton Energy Services, Inc.Inventors: Jiten Chatterji, Richard L. Middaugh, James E. Griffith
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Patent number: 7021378Abstract: A method for retaining a treatment chemical in a subterranean formation containing hydrocarbons is disclosed. The method includes first preparing an emulsion. The emulsion contains an oil continuous phase and first and second aqueous phases. The first aqueous phase includes a treatment chemical, such as a scale inhibitor. The second aqueous phase comprises a retention enhancing chemical which is to be reacted with the treatment chemical in the subterranean formation. Preferably, the first and second aqueous phases remain generally separately dispersed and stable within the oil continuous phase prior to being introduced into the subterranean formation. The emulsion is then placed down a well bore and into the subterranean formation.Type: GrantFiled: December 31, 2003Date of Patent: April 4, 2006Assignee: Chevron U.S.A.Inventor: Gabriel Prukop
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Patent number: 6959773Abstract: In a method for drilling, completing and fracturing a subterranean formation, an electrical potential is applied to oil or synthetic based drilling fluid to increase the viscosity of the fluid and enable the fluid to entrain drill cuttings and proppant. The same base fluid may be used for drilling, completion and fracturing by adjusting the electrical potential and consequently the viscosity of the fluid for the particular application. In fracturing, little or no potential is applied until the fluid enters the zone of the formation to be fractured. High potential is then applied at the fracture point of the formation to effect fracturing and to enable the fluid to transport proppant into the fracture.Type: GrantFiled: November 10, 2003Date of Patent: November 1, 2005Assignee: Halliburton Energy Services, Inc.Inventors: Ali Mese, Mohamed Soliman
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Patent number: 6867170Abstract: For tubing/casing annulus plug treatment to plug a well, a tubing/casing annulus plug additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, and a reinforcing material of fibers and/or comminuted plant materials. The method of forming a tubing/casing annulus plug fluid includes contacting the additive with water or an aqueous solution, with a method of plugging the tubing/casing annulus of a well further including the step of injecting the fluid into the annulus.Type: GrantFiled: November 17, 2000Date of Patent: March 15, 2005Inventor: Boyce D. Burts, Jr.
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Publication number: 20040256106Abstract: The present invention relates to a method and system for hydrating a gel for treating a wellbore penetrating a subterranean formation. The method includes directing a base fluid through an inlet into a mixer having an inner chamber housing a plurality of impellors extending radially from and rotating about a hub, causing a centrifugal motion of the base fluid, feeding a quantity of gel into the mixer, mixing the gel with the base fluid and discharging the now-hydrated gel from the inner chamber through an outlet of the mixer. A prewetting device may also be used. Thereafter, a variety of additives may be added to the gel fluid mix to form a fluid treatment to be introduced into a subterranean formation.Type: ApplicationFiled: June 19, 2003Publication date: December 23, 2004Inventors: Max L. Phillippi, Billy Slabaugh
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Publication number: 20040206498Abstract: The present invention provides xanthan gels hydratable in brine, methods of making these xanthan gels, and methods of using these compositions in subterranean formation applications, such as gravel packing.Type: ApplicationFiled: April 11, 2003Publication date: October 21, 2004Inventors: Max L. Phillippi, Richard Pauls
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Publication number: 20040188092Abstract: Zeolite compositions having enhanced compressive strength and methods therefor are provided. In particular, methods and compositions for wellbore treating fluids, especially settable spotting fluids having enhanced compressive strength are provided.Type: ApplicationFiled: April 12, 2004Publication date: September 30, 2004Inventors: Ashok K. Santra, Karen Luke
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Patent number: 6793025Abstract: A method of electrically logging subterranean wells using a conductive double emulsion fluid includes a miscible combination of an oleaginous fluid, an emulsifier capable of forming a microemulsion, an emulsifier capable of forming an invert emulsion, and an electrolytic salt. A microemulsion is the continuous phase of an invert emulsion. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The fluid may additionally contain a polar organic solvent and a carbon dioxide buffer. The polar organic solvent may be an oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like.Type: GrantFiled: June 17, 2002Date of Patent: September 21, 2004Assignee: M-I L. L. C.Inventors: Arvind D. Patel, Reginald J. Bell, Steve Young, Ahmadi Tehrani
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Patent number: 6750179Abstract: For well plug treatment to plug an abandoned well, a well plug additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, and a reinforcing material of fibers and/or comminuted plant materials. The method of forming a well plug fluid includes contacting the additive with water or an aqueous solution, with a method of plugging the well further including the step of injecting the fluid into the wellbore.Type: GrantFiled: May 7, 1999Date of Patent: June 15, 2004Inventor: Boyce D. Burts, Jr.
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Patent number: 6734144Abstract: A method for enhancing the stability of a solids-stabilized water-in-oil emulsion by pretreating the oil prior to emulsification. The pretreatment step can be accomplished by adding dilute acid to the oil, adding a lignosulfonate additive to the oil, sulfonating the oil, thermally oxidizing the oil, thermally treating the oil in an inert environment, and combinations thereof. The emulsion can be used in enhanced oil recovery methods, including using the emulsion as a drive fluid to displace hydrocarbons in a subterranean formation, and using the emulsion as a barrier fluid for diverting flow of fluids in the formation.Type: GrantFiled: March 28, 2001Date of Patent: May 11, 2004Assignee: ExxonMobil Upstream Research CompanyInventors: Ramesh Varadaraj, James R. Bragg, Monte K. Dobson, Dennis G. Peiffer, John S. Huang, Donald B. Siano, Cornelius H. Brons, Chester W. Elspass
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Patent number: 6716798Abstract: For conformance treatment to plug an opening in subterranean hydrocarbon bearing formation, a conformance additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, and a reinforcing material of fibers and/or comminuted plant materials. The method of forming a conformance fluid includes contacting the additive with water or an aqueous solution, with a method of conforming the formation further including the step of injecting the fluid into the formation to plug the opening.Type: GrantFiled: April 22, 1999Date of Patent: April 6, 2004Inventor: Boyce D. Burts, Jr.
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Patent number: 6664215Abstract: The disclosure is directed to a composition for controlling wellbore fluid and gas invasion including methods for using said composition. The composition of the invention is a flowable slurry preferably comprising about 70 to 30% by weight of magnesium oxychloride and about 70 to 30% by weight of water. The composition is a flowable slurry at composition temperatures below about 60° C. and sets to form a substantially solid mass upon reaching a composition temperature of about 60-68° C. The phase transition is rapid, thereby limiting or avoiding formation of gel states which contribute to incomplete wellbore seals. The rapid set of the slurry further avoids invasive contamination of earthen formations surrounding the wellbore. The composition has a near-linear relationship between the time required for the phase transition to occur and the composition temperature at which the phase transition occurs.Type: GrantFiled: June 6, 2000Date of Patent: December 16, 2003Inventor: Brian H. Tomlinson
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Publication number: 20030196809Abstract: The present invention related to a method for fracturing subterranean formations including the steps of (a) providing a water source; (b) adding a crosslinking agent to said water source; (c) adding a polymeric component to said water to create a fracturing fluid; (d) pumping said fracturing fluid into said formation. The fluid may contain an acrylamide-acrylate copolymer and any suitable number of additives. The additives are preferably combined with the water source to form an additive stream, to which the polymer is later added.Type: ApplicationFiled: July 10, 2002Publication date: October 23, 2003Inventors: Dean Willberg, Michaela Nagl
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Patent number: 6562763Abstract: A drilling fluid homogenizer and method of homogenizing drilling fluid which produce a non-clogging homogenized drilling fluid at a high throughput, in an open-loop process. The non-clogging homogenized drilling fluid is capable of being created at high rate so that the non-clogging homogenized drilling fluid is available on demand to eliminate halting of drilling operations. The drilling fluid homogenizer is coupled in series with the closed-loop designed drilling fluid system and is adapted to homogenize water-based drilling fluid and other drilling fluid types, such as, synthetic drilling fluid during drilling operations on demand.Type: GrantFiled: May 8, 2001Date of Patent: May 13, 2003Assignee: Diamond Tank Rentals, Inc.Inventors: Ben A. Adams, Chris G. Cooper
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Patent number: 6550552Abstract: Oil drill cuttings, containing an oil-based mud, may be treated by mixing the cuttings with an organic solvent. The oil drill cuttings are then separated from the organic solvent and extracted oil. The organic solvent is then separated from the oil, and mixed with the extracted oil drill cuttings to extract additional oil therefrom. The oil drill cuttings are again separated from the organic solvent and oil, the oil separated from the solvent, and recombined with the oil from the first extraction step. The oil base and other mud components are recycled, depending on the treatment procedure, for subsequent use in drilling.Type: GrantFiled: September 7, 2000Date of Patent: April 22, 2003Assignee: EniTechnologie S.p.A.Inventors: Rosario Pappa, Umberto Cova, Raffaello Sisto, Armando Marcotullio, Antonella Carpentieri
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Patent number: 6514916Abstract: Sulfonated uintaite is prepared by sulfonating a naturally occurring uintaite charge with a sulfonating agent such as sulfur trioxide, fuming sulfuric acid, chlorosulfonic acid, oleum, or concentrated sulfuric acid to produce sulfonic acids of uintaite. The resulting sulfonic acids are neutralized with a caustic neutralizing agent and sulfonated uintaite is the product. The sulfonated uintaite product is dried and packaged. The produced sulfonated uintaite is useful in oil and gas well working fluids (drilling muds). Neutralization of the resulting sulfonic acids with sodium hydroxide or ammonium hydroxide as the caustic neutralizing agent yields water and oil-soluble or dispersible salts of the sulfonated uintaite. Neutralization with Ca(OH)2 (calcium hydroxide) as the caustic neutralizing agent yields a product which is preferable in oil-based muds.Type: GrantFiled: September 12, 2000Date of Patent: February 4, 2003Assignee: R. L. Clampitt & Associates, Inc.Inventors: Richard L. Clampitt, Billy L. Swanson
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Patent number: 6491099Abstract: A viscous fluid is shown which is useful in treating subterranean formations. The fluid is formulated from an aqueous base, an alkyl sarcosinate surfactant and a buffer suitable for adjusting the pH of the blended fluid to a range in which the fluid is suitably viscosified. The fluid can also include an additional source of anions, such as chloride or fluoride ions, in order to increase the temperature stability of the fluid. The fluids have application for conventional well fracturing, coiled tubing fracturing, gravel packing and frac packing, as well as for use as selective water control additives and other applications.Type: GrantFiled: February 14, 2001Date of Patent: December 10, 2002Assignee: BJ Services CompanyInventors: Gino F. Di Lullo Arias, Philip Rae, Atikah J. K. Ahmad
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Patent number: 6488091Abstract: Subterranean formation treating fluid concentrates, treating fluids and methods are provided by the present invention. The treating fluid concentrates are basically comprised of water and a substantially fully hydrated depolymerized polymer. The treating fluids which are formed by adding water to the treating fluid concentrates are basically comprised of water, a substantially fully hydrated depolymerized polymer and a crosslinking agent for crosslinking the hydrated depolymerized polymer.Type: GrantFiled: June 11, 2001Date of Patent: December 3, 2002Assignee: Halliburton Energy Services, Inc.Inventors: Jim D. Weaver, Steve F. Wilson, Bobby K. Bowles, Billy F. Slabaugh, Mark A. Parker, David M. Barrick, Stanley J. Heath, Harold G. Walters, R. Clay Cole
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Patent number: 6475959Abstract: A method for the rheology control of fluid phases, in which adducts which contain layered mixed metal hydroxides (MMH) and hectorite are used, and corresponding compositions for this purpose are claimed. Preferably used MMH are those which were produced by hydration of mixed metal oxides or oxyhydroxides, which in turn may be thermally activated. The use of coprecipitated MMH or of MMH produced in situ is also possible. The ratio of MMH to the hectorite component should preferably be from 0.05 to 0.2:1, it also being possible to use adducts whose clay fraction contains up to 80%. by weight of clays differing from hectorite, in particular bentonite. The method is preferably carried out using drilling fluids in the high-temperature range >300° F. (>149° C.).Type: GrantFiled: July 14, 2000Date of Patent: November 5, 2002Assignee: SKW Polymers GmbHInventors: Peter Lange, Gregor Keilhofer, Johann Plank
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Patent number: 6464009Abstract: Pumpable multiple phase compositions for carrying agents and components downhole and controllably releasing them by breaking the suspensions are described. The multiple phase composition may have an external or third phase, which in turn has a first pumpable emulsion internally. The first pumpable emulsion has a second phase containing a first phase which bears the agent to be controllably released. The entire pumpable multiple phase composition may thus be an oil phase-in-aqueous phase-in-oil phase emulsion, or an aqueous phase-in-oil phase-in-aqueous phase emulsion. The agent may be released by one or more of a variety of mechanisms. For example, a water-soluble shale stabilizer could be delivered downhole in an aqueous phase-in-oil phase-in-aqueous phase multiple phase emulsion by injecting the multiple phase composition into a water-based drilling fluid, and then the suspension broken by rotary bit nozzles under high shear stress to release the shale stabilizer at the drilling zone.Type: GrantFiled: July 6, 2001Date of Patent: October 15, 2002Assignee: Baker Hughes IncorporatedInventors: Ronald G. Bland, Lirio Quintero
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Patent number: 6410488Abstract: A fluid suitable for use as the continuous phase in a drilling fluid is disclosed. The fluid is prepared by the sequential hydrotreating, hydroisomerization and hydrogenation of a crude oil feedstock. The fluid has good low temperature properties, including pour point and accordingly is useable in cold environments. A method of producing the fluid is also disclosed. The fluid may also be used as an additive to a drilling fluid having a continuous aqueous phase wherein it may act as, for example, a rate of penetration enhancer or a spotting fluid. The fluid may also be used as an additive to known drilling fluids such as internal olefins.Type: GrantFiled: March 10, 2000Date of Patent: June 25, 2002Assignee: Petro-CanadaInventors: Michael Fefer, Lorne Pierson
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Patent number: 6337308Abstract: A drilling fluid homogenizer and method of homogenizing drilling fluid which produce a non-clogging homogenized drilling fluid at a high throughput, in an open-loop process. The non-clogging homogenized drilling fluid is capable of being created at high rate so that the non-clogging homogenized drilling fluid is available on demand to eliminate halting of drilling operations. The drilling fluid homogenizer is coupled in series with the closed-loop designed drilling fluid system and is adapted to homogenize water-based drilling fluid and other drilling fluid types, such as, synthetic drilling fluid during drilling operations on demand.Type: GrantFiled: June 8, 1999Date of Patent: January 8, 2002Assignee: Diamond Tank Rentals, Inc.Inventors: Ben A. Adams, Chris G. Cooper
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Patent number: 6269881Abstract: An oil recovery process is disclosed which uses a particular class of alkylaryl sulfonate surfactants. The surfactants are derived from an alpha-olefin stream having a broad distribution of even carbon numbers ranging from 12 to 58. The olefin stream is reacted with aromatic feedstock, such as benzene, toluene, xylene, or a mixture thereof to form alkylates, and then reacted with SO3 to form sulfonic acids. The resulting surfactant has high solubilization and ultra-low interfacial tension with crude oils, especially waxy crude oil, having a broad distribution of carbon numbers.Type: GrantFiled: December 17, 1999Date of Patent: August 7, 2001Assignees: Chevron U.S.A. Inc, Chevron Chemical Company LLCInventors: Shang Chou, Curtis B. Campbell
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Patent number: 6230814Abstract: A method for producing hydrocarbons from a subterranean formation comprises injecting steam and an additive into the formation. The additive has at least one nonaqueous fluid, which is selected so that the evaporation temperature of the additive is within about ±150° C. of the steam temperature at the operating pressure. Suitable additives include C1 to C25 hydrocarbons, and combinations thereof. At least a portion of the additive condenses in the formation. The mobility of the hydrocarbons is greater than that obtained using steam alone under substantially similar formation conditions.Type: GrantFiled: October 14, 1999Date of Patent: May 15, 2001Assignee: Alberta Oil Sands Technology and Research AuthorityInventors: Tawfik Noaman Nasr, Ezra Eddy Isaacs
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Patent number: 6213214Abstract: Solid, slowly dispersible well treatment composites are provided which have a sufficiently high melting point to prevent melting of the composite in hot weather. The composites have a low solubility and high specific gravity compared to prior art treatment agents; thus the composites readily sink in well and pipeline fluids and slowly release treatment ingredients over time, depending on the downhole and pipeline conditions. The composites include a nonylphenol ethoxylate having at least about 50 moles of ethylene oxide per mole of nonylphenol and a fatty acid amide having from 14-20 carbon atoms. Preferably, the composites further include a weighting agent and active ingredients selected from the group consisting of corrosion inhibitors, scale inhibitors, bactericides, scale converters, foaming agents, and mixtures thereof. In one embodiment, the composites are spherical in shape and are passed through pipelines for maintenance and treatment of the pipelines.Type: GrantFiled: February 19, 1999Date of Patent: April 10, 2001Assignee: Jacam Chemicals L.L.C.Inventors: Gene H. Zaid, Beth Ann Wolf
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Patent number: 6206103Abstract: Solid, slowly dispersible well treatment composites are provided which have a sufficiently high melting point to prevent melting of the composite in hot weather. The composites have a low solubility and high specific gravity compared to prior art treatment agents; thus the composites readily sink in well and pipeline fluids and slowly release treatment ingredients over time, depending on the downhole and pipeline conditions. The composites include a compound selected from the group consisting of nonylphenol ethoxylates having at least about 50 moles of ethylene oxide per mole of nonylphenol, fatty acid amides having from 14-20 carbon atoms, and mixtures thereof. Preferably, the composites further include a weighting agent and active ingredients selected from the group consisting of corrosion inhibitors, scale inhibitors, bactericides, scale converters, foaming agents, and mixtures thereof.Type: GrantFiled: July 29, 1999Date of Patent: March 27, 2001Assignee: JACAM Chemicals L.L.C.Inventors: Gene H. Zaid, Beth Ann Wolf
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Patent number: 6135207Abstract: Solid, slowly dispersible well treatment composites are provided which have a sufficiently high melting point to prevent melting of the composite in hot weather. The composites have a low solubility and high specific gravity compared to prior art treatment agents; thus the composites readily sink in well fluids and slowly release treatment ingredients over time, depending on the downhole conditions. The composites include a nonylphenol ethoxylate having at least about 50 moles of ethylene oxide per mole of nonylphenol and a fatty acid amide having from 16-20 carbon atoms. Preferably, the composites further include a weighting agent and active ingredients selected from the group consisting of corrosion inhibitors, scale inhibitors, bactericides, scale converters, foaming agents, and mixtures thereof.Type: GrantFiled: August 27, 1998Date of Patent: October 24, 2000Assignee: Jacam Chemicals, L.L.C.Inventors: Gene H. Zaid, Beth Ann Wolf
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Patent number: 6102121Abstract: For conformance treatment to plug an opening in subterranean hydrocarbon bearing formation, a conformance additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, and a reinforcing material of fibers and/or comminuted plant materials. The method of forming a conformance fluid includes contacting the additive with water or an aqueous solution, with a method of conforming the formation further including the step of injecting the fluid into the formation to plug the opening.Type: GrantFiled: October 31, 1997Date of Patent: August 15, 2000Assignee: BottomLine Industries, Inc.Inventor: Boyce D. Burts, Jr.
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Patent number: 6068054Abstract: The disclosed invention provides a method for recovering hydrocarbons from a subterranean formation by injecting an emulsion, comprising oil and water, into the formation. More specifically, the emulsion is stabilized using undissolved solid particles, which are preferably at least partially oleophilic. The solids-stabilized emulsion may be used either as a drive fluid for displacing hydrocarbons from the formation or to produce a barrier for diverting flow of fluids in the formation. Such solid particles may be either formation solid particles (i.e., indigenous to the formation) or nonformation solid particles (i.e., obtained from outside the formation). Nonformation solid particles may either be naturally occurring or synthetic. Some preferred solids include clays, quartz, feldspar, gypsum, coal dust, asphaltenes, and polymers.Type: GrantFiled: April 12, 1999Date of Patent: May 30, 2000Assignee: Exxon Production Research CompanyInventor: James R. Bragg
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Patent number: 6025303Abstract: A solids composition based on clay minerals and consisting of a) 40-99.8 wt. % of a clay mineral with a reduced moisture content of .ltoreq.7 wt. %, b) 0.01-30 wt. % of a mixed metal hydroxide and c) 0.01-30 wt. % of a solid base, and if necessary other additives, is described. The solids composition of the invention is an easy-to-use thickening agent for water-based drilling fluids, and has a long-term stability of at least three months.Type: GrantFiled: June 25, 1998Date of Patent: February 15, 2000Assignee: SKW Trostberg AktiengesellschaftInventors: Gregor Keilhofer, Johann Plank
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Patent number: 6016871Abstract: For hydraulic fracturing treatment to increase productivity of subterranean hydrocarbon bearing formation, a hydraulic fracturing additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, and a reinforcing material of fibers and/or comminuted plant materials. The method of forming a hydraulic fracturing fluid includes contacting the additive with water or an aqueous solution, with a method of hydraulically fracturing the formation further including the step of injecting the fluid into the wellbore.Type: GrantFiled: October 31, 1997Date of Patent: January 25, 2000Inventor: Boyce D. Burts, Jr.