Abstract: For lost circulation treatment, a lost circulation additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, and a reinforcing material of fibers and/or comminuted plant materials. The method of forming a lost circulation fluid includes contacting the additive with water or an aqueous solution, with a method of conforming the formation further including the step of injecting the fluid into the wellbore.
Abstract: For well kill treatment to prevent the intrusion of formation fluids into the wellbore while the well is open, a well kill additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, and a reinforcing material of fibers and/or comminuted plant materials. The method of forming a well kill fluid includes contacting the additive with water or an aqueous solution, with a method of conforming the formation further including the step of injecting the fluid into the wellbore.
Abstract: The disclosed invention provides a method for recovering hydrocarbons from a subterranean formation by injecting an emulsion, comprising oil and water, into the formation. More specifically, the emulsion is stabilized using undissolved solid particles, which are preferably at least partially oleophilic. The solids-stabilized emulsion may be used either as a drive fluid for displacing hydrocarbons from the formation or to produce a barrier for diverting flow of fluids in the formation. Such solid particles may be either formation solid particles (i.e., indigenous to the formation) or nonformation solid particles (i.e., obtained from outside the formation). Nonformation solid particles may either be naturally occurring or synthetic. Some preferred solids include clays, quartz, feldspar, gypsum, coal dust, asphaltenes, and polymers.
Abstract: A drilling fluid additive for use during drilling and excavating applications, the additive comprises a mixture of an oil, an ester alcohol, nonionic surfactant and polypropylene glycol; and a method for manufacturing a drilling fluid additive comprising the step of admixing an oil, an ester alcohol, a nonionic surfactant, and a polypropylene glycol.
Abstract: The disclosed invention provides a method for recovering hydrocarbons from a subterranean formation by injecting an emulsion, comprising oil and water, into the formation. More specifically, the emulsion is stabilized using undissolved solid particles, which are preferably at least partially oleophilic. The solids-stabilized emulsion may be used either as a drive fluid for displacing hydrocarbons from the formation or to produce a barrier for diverting flow of fluids in the formation. Such solid particles may be either formation solid particles (i.e., indigenous to the formation) or nonformation solid particles (i.e., obtained from outside the formation). Nonformation solid particles may either be naturally occurring or synthetic. Some preferred solids include clays, quartz, feldspar, gypsum, coal dust, asphaltenes, and polymers. Carbon dioxide or another gas may be added to the emulsion to adjust the emulsion's viscosity to the desired level.
Abstract: An oil base environmentally benign drilling fluid composition having a stable high viscosity and high gel strength at use temperatures of up to at least 450.degree. F. The drilling fluid includes a low toxicity biodegradable oil vehicle, and as a viscosifying agent an organoclay which is the reaction product of a mineral clay mixture and an alkyl quaternary ammonium salt. The mineral clay mixture comprises at least 50% by weight of a mineral clay selected from the group consisting of sepiolite, palygorskite and mixtures of sepiolite and palygorskite; and substantially the balance of the mixture is a smectite. Conventional additives such as emulsifiers and fillers may also be present in the drilling fluid.
Type:
Grant
Filed:
May 6, 1997
Date of Patent:
November 17, 1998
Assignee:
Southern Clay Products, Inc.
Inventors:
Paul W. Carroll, David Hugh Durham, Thomas C. Farrow
Abstract: The present invention provides borate cross-linked well treating fluids and methods of preparing and using the fluids in treating wells such as fracturing subterranean zones therein. The improved cross-linked treating fluids are basically comprised of water, a hydrated galactomannan gelling agent and a borate composition for buffering the treating fluid and cross-linking the hydrated galactomannan gelling agent comprised of water, a soluble boron source and an alkanolamine or alkylamine.
Type:
Grant
Filed:
April 4, 1997
Date of Patent:
October 27, 1998
Inventors:
Phillip C. Harris, Michael A. McCabe, Lewis R. Norman, Ronald J. Powell, Chris E. Shuchart, Billy F. Slabaugh, John M. Terracina, Joseph G. Yaritz
Abstract: A method of treating a subterranean formation penetrated by a wellbore utilizing a preformed high solids content slurry is prepared and transported to the wellsite. A portion of the slurry is admixed with a treatment fluid whereby the resultant solids content of the fluid is reduced and the fluid is introduced into a wellbore penetrating the subterranean formation. The high solids content slurry is substantially stable and the particulate does not substantially settle within the fluid prior to admixing with the treatment fluid thereby permitting large quantities of particulate to be rapidly admixed with a treatment fluid.
Type:
Grant
Filed:
July 18, 1996
Date of Patent:
September 1, 1998
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Lewis R. Norman, Billy F. Slabaugh, Michael A. McCabe, Ronnie G. Morgan
Abstract: An drilling fluid additive to reduce loss circulation includes comminuted rice fraction and corn cobs, and includes ground at least one of ground wood fiber, ground nut shells, ground paper and shredded cellophane. A method of treating a drilling fluid includes contacting such drilling fluid additive with the base drilling fluid to form well fluid. A method of operating a well includes circulation of such a well fluid into and out of a borehole.
Abstract: Elastic solids having reversible stress-induced fluidity are prepared, e.g., by combining liquid formulations with a crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH).sub.(m+2d+3+n.multidot.a) (A.sup.n).sub.a .multidot.xH.sub.2 Owhere m is amount of Li, d is amount of divalent metal D, T is a trivalent metal, A represents at least one anion or negative-valence radical of valence n and a is the amount of A, and xH.sub.2 O represents excess waters of hydration, if any. These make useful coatings.The instantly reversible fluidization of these unique elastic solids may be expressed as:.sigma.=k.sub..alpha. .epsilon. when .epsilon.<F, for the solid phase; and.sigma.=f(d.epsilon.'/dt) when .epsilon.'>F, (this equation represents a generalized form for the usual theological equations); for a cycle of .epsilon., -xF <.epsilon.<xF, and when .epsilon.' equals 0 the liquid phase changes back to the solid phase, andwhere the symbol .sigma. represents stress; k.
Type:
Grant
Filed:
August 18, 1995
Date of Patent:
February 24, 1998
Assignee:
The Dow Chemical Company
Inventors:
John L. Burba, III, Christopher P. Christenson
Abstract: A thixotropic thermal insulating fluid includes a heavy hydrocarbon, water and oleophilic clay, wherein said heavy hydrocarbon is present in an amount of between about 75% to about 92% by volume of the fluid, said water is present in an amount of between about 5% to about 15% by volume of the fluid, and said oleophilic clay is present in an amount of between about 3% to about 10% by volume of the fluid. The fluid may be prepared by mixing water in an amount of between about 5% to about 15% by total volume of the fluid with oleophilic clay in an amount of between about 3% to about 10% by total volume of the fluid so as to provide a substantially homogeneous first gel product; and mixing said first gel product with a heavy hydrocarbon in an amount of between about 75% to about 92% by total volume of the fluid under agitation for a time sufficient to provide a second thixotropic gel product.
Type:
Grant
Filed:
November 16, 1995
Date of Patent:
October 14, 1997
Assignee:
Intevep, S.A.
Inventors:
Simon Suarez, Carlos Rios, Ignacio Layrisse, Jose Gregorio Tovar
Abstract: An additive to reduce fluid loss from drilling fluids is comprised of comminuted products from the rice plant or blends of other comminuted plant materials with the rice products. Polymers to reduce fluid loss even lower and friction-reducing materials may be added to the plant materials.
Abstract: A method of making a well fluid for use in a well which includes the steps of determining uphole and downhole operating temperatures in the well, and then contacting a well lubricant with a lubricating additive, wherein the lubricating additive has a cloud point temperature greater than the uphole operating temperature and less than the downhole operating temperature. A method of lubricating drilling equipment during opeation of a subterranean well, includes the steps of determining uphole and downhole operating temperatures in the well, and then contacting the drilling equipment with a treating fluid comprising a well lubricant and a lubricating additive, with the lubricating additive having a cloud point temperature greater than the uphole operating temperature and less than the downhole operating temperature.