Additional Oxygen Attached Directly Or Indirectly To The Hetero Ring By Nonionic Bonding Patents (Class 508/290)
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Patent number: 10494583Abstract: Lubricant compositions including an additive composition and methods for its use in engines that produce soot. The lubricant composition contains a base oil and an additive composition having (a) at least 0.05 percent by weight of a first dispersant that is a reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, and B) at least one polyamine; and (b) at least 0.05 percent by weight, both based on a total weight of the lubricant composition, of a second dispersant that is a reaction product of A?) a hydrocarbyl-dicarboxylic acid or anhydride, and B?) at least one polyamine, wherein the reaction product is post-treated with C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride wherein all carboxylic acid or anhydride groups are attached directly to an aromatic ring, and/or D) a non-aromatic dicarboxylic acid or anhydride having a number average molecular weight of less than about 500.Type: GrantFiled: December 11, 2018Date of Patent: December 3, 2019Assignee: AFTON CHEMICAL CORPORATIONInventors: Diane Campbell, Jason Lagona
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Patent number: 10494362Abstract: Compounds (citric acid derivatives) represented by formulas (1) and (2) below are novel compounds having an inhibitory effect against liver disorder and can be used as liver disorder inhibitors and food additives (wherein R1 represents a C1 to C3 alkyl group optionally having a carboxyl group or a hydroxyl group, and R2 represents a hydrogen atom, or R1 and R2 optionally form a cyclic structure together to represent a C2 to C3 alkylene chain).Type: GrantFiled: November 1, 2016Date of Patent: December 3, 2019Assignees: ADABIO CO., LTD., OTSUKA PHARMACEUTICAL FACTORY, INC.Inventors: Katsuya Hiraishi, Fumie Jimma, Hiroyuki Soma, Taro Adachi, Masakazu Adachi, Ippei Yamaoka, Tomohiro Kagawa
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Patent number: 9677023Abstract: This disclosure is directed to an additive package for a lubricant composition that provides improved fluoropolymer compatibility. The additive package comprises an amine compound and a seal compatibility additive. The disclosure is also directed to a lubricant composition comprising a base oil, an amine compound, and a seal compatibility additive. The seal compatibility additive improves the fluoropolymer seal compatibility of the resultant lubricant composition.Type: GrantFiled: April 7, 2015Date of Patent: June 13, 2017Assignee: BASF SEInventors: Kevin J. DeSantis, Roger L. Kuhlman
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Patent number: 9493724Abstract: In accordance with the present invention, it has been discovered that an additive which is substantially insoluble in, has low solubility in and/or is otherwise incompatible with a functional fluid, may be supplied to the functional fluid by use of a gel composition and/or a solid additive composition containing the additive, such that the functional fluid can receive the benefit of the supplied additive and/or contain levels of the additive not otherwise achievable by conventional delivery method due to the incompatibility of the additive with the functional fluid.Type: GrantFiled: September 23, 2009Date of Patent: November 15, 2016Assignee: The Lubrizol CorporationInventors: Calvin W. Schroeck, Michael R. Sutton, James D. Burrington, John K. Pudelski, Ewan E. Delbridge, Jody A. Kocsis, Deborah A. Langer, Matthew D. Gieselman
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Patent number: 9062274Abstract: The low friction sliding member includes a substrate and an amorphous hard carbon film formed on the surface of the substrate and makes sliding contact with a mating member under a wet oiling condition. The lubricant oil includes at least one of sulfur (S) and phosphorus (P) and at least one of zinc (Zn), calcium (Ca), magnesium (Mg), sodium (Na), barium (Ba) and copper (Cu). The amorphous hard carbon film comprises carbon (C) as a major component, and hydrogen (H) in the range from 5 to 25 atomic % and a predetermined amount of boron (B), aluminum (Al), manganese (Mn) or molybdenum (Mo) assuming that the total atomic % of the amorphous carbon film is 100.Type: GrantFiled: July 2, 2010Date of Patent: June 23, 2015Assignees: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO, TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Hiroyuki Mori, Munehisa Matsui, Toshihide Ohmori, Takatoshi Shinyoshi, Yoshio Fuwa, Keiji Hayashi
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Publication number: 20150045267Abstract: The invention provides a composition containing an oil of lubricating viscosity and an N-substituted malimide. The invention further relates to the use of the lubricating composition in an internal combustion engine.Type: ApplicationFiled: October 27, 2014Publication date: February 12, 2015Inventors: Seth L. Crawley, Jody A. Kocsis, Suzanne M. Patterson
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Patent number: 8940671Abstract: The invention relates to a lubricating composition containing (a) an N-substituted malimide, and (b) an oil of lubricating viscosity. The invention further provides for the use of the lubricating composition for lubricating a limited slip differential.Type: GrantFiled: May 10, 2010Date of Patent: January 27, 2015Assignee: The Lubrizol CorporationInventor: Shubhamita Basu
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Patent number: 8901051Abstract: The invention provides a composition containing an oil of lubricating viscosity and an N-substituted malimide. The invention further relates to the use of the lubricating composition in an internal combustion engine.Type: GrantFiled: May 4, 2010Date of Patent: December 2, 2014Assignee: The Lubrizol CorporationInventors: Seth L. Crawley, Jody A. Kocsis, Suzanne M. Patterson
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Publication number: 20140187455Abstract: Disclosed is an ultra-low SAPS lubricating oil composition comprising: an oil of lubricating viscosity; an aromatic dicarboxylic acid treated dispersant supplying at least 0.30 wt % of the aromatic dicarboxylic acid to said lubricating oil composition; an ashless peroxide decomposer present at a treat rate of from about 0.4 to 5.0 wt %; a metal deactivator wherein the metal deactivator is present at a treat rate of greater than 0.08 wt %; wherein said lubricating oil composition contains less than 1000 ppm sulfur, less than 300 ppm phosphorus and less than 0.25 wt % sulfated ash.Type: ApplicationFiled: December 28, 2012Publication date: July 3, 2014Applicant: Chevron Oronite LLCInventors: Katsumi Umehara, Willem Van Dam
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Publication number: 20140073543Abstract: The present invention relates to functional fluid compositions containing friction modifiers, and specifically stable compositions containing friction modifiers with limited solubility in and/or limited compatibility with the functional fluids with which they are used. In particular the present invention deals with functional fluids used in internal combustion engines, such as engine oils, and friction modifiers derived from hydroxy-carboxylic acids, where the friction modifier is present in the functional fluid composition at levels that would otherwise cause the composition to be unstable and/or hazy.Type: ApplicationFiled: May 21, 2012Publication date: March 13, 2014Applicant: THE LUBRIZOL CORPORATIONInventors: Stuart L. Bartley, Patrick E. Mosier, James D. Burrington, David C. Arters
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Publication number: 20140038867Abstract: A method of improving air release in lubricant base stocks and lubricating oils is provided. The method includes providing a Group I base stock, a Group II base stock or a combination thereof and adding to the base stock an effective amount of C7 to C80 paraffin, wherein the lubricant base stock provides air release according to the ASTM D3427 test at least 20% lower than the same lubricant base stock not including the C7 to C80 paraffin. Also provided are lube base stocks and lubricating oils with improved air release and methods of making such base stocks and oils.Type: ApplicationFiled: July 22, 2013Publication date: February 6, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Charles Lambert Baker, JR., Beatrice Marie Gooding, Paul Carl Naegely
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Publication number: 20130210690Abstract: The present invention provides high-HTHS value lubricating compositions that have improved fuel economy performance. The present invention also provides methods of operating an internal combustion engine utilizing such compositions. The lubricating compositions of the invention utilize butane dioic imide compounds, such as tartrimides, and may also be low sulfur, low ash and low phosphorus, providing lower wear and friction and improved fuel economy.Type: ApplicationFiled: May 6, 2011Publication date: August 15, 2013Applicant: THE LUBRIZOL CORPORATIONInventor: Mark C. Davies
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Publication number: 20120264662Abstract: This invention relates to functionalized monomers. The functionalized monomer may be reacted with an enophilic reagent (e.g., maleic anhydride) to form an enophilic reagent modified functionalized monomer. The invention relates to lubricants, functional fluids, fuels, dispersants, detergents, functional compositions (e.g., food products, cleaners, etc.), and the like.Type: ApplicationFiled: March 23, 2012Publication date: October 18, 2012Inventors: Stephen A. DiBiase, Syed Q.A. Rizvi, Georgeta Hategan
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Publication number: 20120172265Abstract: The invention relates to a lubricating composition comprising (a) a compound derived from a hydroxy-carboxylic acid, and (b) an oil of lubricating viscosity. The invention further provides for the use of the lubricating composition for lubricating a limited slip differential.Type: ApplicationFiled: December 8, 2009Publication date: July 5, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Stuart L. Bartley, Mark R. Baker, Shubhamita Basu
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Publication number: 20120135899Abstract: A lubricant composition suitable for lubricating an internal combustion engine comprises: (a) an oil of lubricating viscosity having a viscosity index of at least 105 and a kinematic viscosity at 100 C of less than 7 mm2s-1; (b) 0.01 to 2 weight percent of a friction modifier represented by the structure [I]; (c) 0.5 to 4 weight percent of a poly(meth)acrylate viscosity modifier polymer; (d) 0 to 500 parts per million by weight of molybdenum in the form of an oil-soluble molybdenum compound; and (e) 0 to 200 parts per million by weight of boron in the form of an oil-soluble boron compound.Type: ApplicationFiled: June 2, 2010Publication date: May 31, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Jody A. Kocsis, Brent R. Dohner, Haihu Qin, Marina Baum
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Publication number: 20120111300Abstract: The invention provides a composition containing an oil of lubricating viscosity and an N-substituted malimide. The invention further relates to the use of the lubricating composition in an internal combustion engine.Type: ApplicationFiled: May 4, 2010Publication date: May 10, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Seth L. Crawley, Jody A. Kocsis, Suzanne M. Patterson
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Publication number: 20120115761Abstract: The invention relates to a lubricating composition containing (a) an N-substituted malimide, and (b) an oil of lubricating viscosity. The invention further provides for the use of the lubricating composition for lubricating a limited slip differential.Type: ApplicationFiled: May 10, 2010Publication date: May 10, 2012Applicant: THE LUBRIZOL CORPORATIONInventor: Shubhamita Basu
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Publication number: 20120053101Abstract: Maleated fatty acids that are functionalized with materials such as polyols, alkanolamines and/or alkylene oxides have been discovered to improve the properties of various fluids. In a non-limiting example, functionalized maleated fatty acids having acid numbers less than 10 may improve the lubricity of fuels and lubricants, such as hydrocarbon fuels and lubricants, when added thereto.Type: ApplicationFiled: September 1, 2010Publication date: March 1, 2012Applicant: Baker Hughes IncorporatedInventors: Jianzhong Yang, Paul J. Biggerstaff, Jerry J. Weers
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Patent number: 8071801Abstract: Provided is a phosphorus molybdenum amine compound, represented by the following general formula (I). where R1 to R6 each independently represent a hydrogen atom or a hydrocarbon group and p represents a number of 1 to 5, provided that all of R1 to R6 are can not all be hydrogen atoms at the same time and the phosphorus molybdenum compound is obtained by reducing a hexavalent molybdenum compound with a reducing agent, and then reacting the resulting with an acidic phosphate after neutralization with a mineral acid.Type: GrantFiled: July 3, 2007Date of Patent: December 6, 2011Assignee: Adeka CorporationInventors: Yukio Tatsumi, Kazuhiro Umehara, Kenji Yamamoto
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Patent number: 8022023Abstract: A molybdated succinimide complex is disclosed which is prepared by a process comprising (a) reacting a succinimide of a polyamine of formula I: wherein R is a hydrocarbon radical having a number average molecular weight of about 500 to about 5,000, a and b are independently 2 or 3, and x is 0 to 10, with an ethylenically unsaturated carboxylic acid or anhydride thereof, in a charge mole ratio of the ethylenically unsaturated carboxylic acid or anhydride thereof to the succinimide of formula I of about 0.9:1 to about 1.05:1; and (b) reacting the succinimide product of step (a) with an acidic molybdenum compound. Also disclosed is a lubricating oil composition containing at least (a) a major amount of a base oil of lubricating viscosity and (b) a minor amount of the molybdated succinimide complex.Type: GrantFiled: June 30, 2008Date of Patent: September 20, 2011Assignee: Chevron Oronite Company LLCInventors: Kenneth D. Nelson, Edward A. Chiverton
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Patent number: 8022022Abstract: A molybdated succinimide complex is disclosed which is prepared by a process comprising (a) reacting an alkyl or alkenyl succinimide of a polyamine of formula I wherein R is an about C12 to about C30 alkyl or alkenyl group; a and b are independently 2 or 3, and x is 0 to 10, with an ethylenically unsaturated carboxylic acid or anhydride thereof; and (b) reacting the product of step (a) with an acidic molybdenum compound. Also disclosed is a lubricating oil composition containing at least (a) a major amount of a base oil of lubricating viscosity and (b) a minor amount of the molybdated succinimide complex.Type: GrantFiled: June 30, 2008Date of Patent: September 20, 2011Assignee: Chevron Oronite Company LLCInventors: Kenneth D. Nelson, Edward A. Chiverton
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Patent number: 7951758Abstract: The hydrolytic stability of magnesium overbased products is significantly improved by the addition or inclusion of a mixture or reaction product of an alkylphenol resin with a mixture of an alkenyl succinic anhydride and the acid thereof, and an alkyl amine. These magnesium overbased products are useful additives to fuel oils to improve their corrosion-causing tendencies. In one non-limiting embodiment, the alkylphenol resin is nonylphenol resin and the succinic anhydride is a partially hydrolyzed succinic anhydride having from 14 to 26 carbon atoms, along with the acid thereof. The mixtures and reaction products also serve as asphaltene inhibitors in the fuel oils.Type: GrantFiled: June 17, 2008Date of Patent: May 31, 2011Assignee: Baker Hughes IncorporatedInventors: Corina L. Sandu, Lawrence N. Kremer, Christine Ann Blundell, Lee Michael Howard, Joseph L. Stark
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Publication number: 20100160194Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting (A) reacting a copolymer of an (i) an unsaturated acidic reagent; and (ii) a mono-olefin, with at least one linking hydrocarbyl di-primary amine, thereby producing a hybrid succinic anhydride copolymer having from about 10% to about 90% unreacted anhydride groups; and subsequently (B) reacting the hybrid succinic anhydride copolymer with a second amine compound, thereby producing the succinimide; and (C) reacting the succinimide with at least one post-treating agent selected from a cyclic carbonate, a linear mono-carbonate, a linear poly-carbonate, an aromatic polycarboxylic acid, an aromatic polycarboxylic anhydride, an aromatic polycarboxylic acid ester, or mixtures thereof.Type: ApplicationFiled: December 22, 2008Publication date: June 24, 2010Inventors: James J. Harrison, Mitra Hosseini
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Publication number: 20100099588Abstract: A lubricant composition of an oil, a dispersant viscosity modifier of a poly(meth)acrylate copolymer having a nitrogen-containing monomer in an amount to provide at least about 0.4 percent by weight nitrogen to the copolymer, and a succinimide dispersant prepared in the substantial absence of chlorine gives good performance as a transmission fluid.Type: ApplicationFiled: January 22, 2008Publication date: April 22, 2010Inventors: Calvin A. James, Craig D. Tipton, William D. Abraham, Edward J. Konzman
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Publication number: 20090192062Abstract: Provided is a phosphorus molybdenum amine compound, represented by the following general formula (1). where R1 to R6 each independently represent a hydrogen atom or a hydrocarbon group and p represents a number of 1 to 5, provided that all of R1 to R6 are can not all be hydrogen atoms at the same time and the phosphorus molybdenum compound is obtained by reducing a hexavalent molybdenum compound with a reducing agent, and then reacting the resulting with an acidic phosphate after neutralization with a mineral acid.Type: ApplicationFiled: July 3, 2007Publication date: July 30, 2009Inventors: Yukio Tatsumi, Kazuhiro Umehara, Kenji Yamamoto
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Publication number: 20090156445Abstract: A lubricant composition suitable for use in engines fueled by gasoline or biorenewable fuels or both, comprising an oil of lubricating viscosity and a dispersant system is disclosed herein. Also disclosed is an emulsion composition comprising a biorenewable fuel, an oil of lubricant viscosity, and a dispersant system. A method of reducing aqueous separation in an emulsion composition is also disclosed.Type: ApplicationFiled: December 13, 2007Publication date: June 18, 2009Inventor: William Y. LAM
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Publication number: 20080318815Abstract: Disclosed is a lubricating oil composition containing an oil of lubricating viscosity and a particularly effective mixture of a nitro-substituted diphenylamine and a diarylamine which together provide superior oxidation inhibition.Type: ApplicationFiled: June 20, 2007Publication date: December 25, 2008Inventors: Richard E. Cherpeck, Carrie Y. Chan
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Publication number: 20080076686Abstract: A low sulfated ash, tow sulfur, low phosphorus, low zinc lubricating, oil composition preferably employable for internal combustion engines using a low sulfur hydrocarbon fuel comprises a base oil having a saturated component of 85 wt. % or more, a viscosity index of 110 or more, and a sulfur content of 0.01 wt. % or less; an alkaline earth metal-containing detergent; a nitrogen-containing ashless dispersant of a weight average molecular weight of 4,500 or more; a phenolic or amine oxidation inhibitor; and a basic nitrogen-containing compound-oxymolybdenum complex.Type: ApplicationFiled: September 12, 2007Publication date: March 27, 2008Inventors: Morikuni Nakazato, Yoshitaka Takeuchi, Takahiro Muramatsu
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Patent number: 6780209Abstract: The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second intermeType: GrantFiled: January 24, 2000Date of Patent: August 24, 2004Assignee: The Lubrizol CorporationInventors: Brian B. Filippini, Richard M. Lange, Bryan A. Grisso, Bryn Hird
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Patent number: 6548458Abstract: Succinimide-acid compounds prepared by reaction of hydrocarbyl-substituted succinic acylating agents with alpha-omega amino acids are disclosed, as well as derivatives thereof useful as lubricity additives, lubricant dispersants, friction modifiers, liquid hydrocarbonaceous fuel detergents, antioxidants and alkali and/or alkaline-earth metal detergents.Type: GrantFiled: November 8, 2001Date of Patent: April 15, 2003Assignee: Ethyl CorporationInventor: John T. Loper
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Publication number: 20020091068Abstract: Succinimide-acid compounds prepared by reaction of hydrocarbyl-substituted succinic acylating agents with alpha-omega amino acids are disclosed, as well as derivatives thereof useful as lubricity additives, lubricant dispersants, friction modifiers, liquid hydrocarbonaceous fuel detergents, antioxidants and alkali and/or alkaline-earth metal detergents.Type: ApplicationFiled: November 8, 2001Publication date: July 11, 2002Inventor: John T. Loper
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Patent number: 6326336Abstract: A turbine lubricant consisting of (A) alkylated diphenylamine and/or phenylnaphthylamines, and (B) sulfurized olefins and/or sulfurized fatty acids and/or ashless dithiocarbamates and/or tetraalkylthiuram disulfides, with the balance containing (C) base oils characterized by very low sulfur contents (<0.03 wt %) and a high level of saturates (>90 volume %), and optionally (D) neutral rust inhibitors, show superior oxidative stability and provide adequate corrosion protection and sludge control for turbine oil and R&O oil applications.Type: GrantFiled: October 16, 1998Date of Patent: December 4, 2001Assignee: Ethyl CorporationInventors: Vincent James Gatto, Helen Ryan, Ramnath Narayan Iyer
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Patent number: 6207624Abstract: Disclosed is a lubricating composition having a major amount of an oil of lubrication viscosity and a minor amount of (A) a nitrogen containing dispersant with a total base number of from 20 to 160 on an oil-free basis wherein the improvement comprises adding to said dispersant; (B) a sludge preventing/seal protecting additive of at least one aldehyde or epoxide or mixtures thereof.Type: GrantFiled: July 13, 2000Date of Patent: March 27, 2001Assignee: The Lubrizol CorporationInventors: Carl F. Stachew, William D. Abraham, James A. Supp, James R. Shanklin, Gordon David Lamb
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Patent number: 6117825Abstract: A lubricating oil composition comprising:(a) a major amount of an oil of lubricating viscosity; and(b) a minor dispersant amount of a synergistic combination of an antioxidant-dispersant additive and a dispersant additive, said combination comprising:(i) a polyisobutylene succinimide; and(ii) an ethylene-propylene succinimide.Type: GrantFiled: May 7, 1992Date of Patent: September 12, 2000Assignee: Ethyl CorporationInventors: Christopher Soundang Liu, Cyril Andrew Migdal, Norris Roland Crawford, Roy Isamu Yamamota
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Patent number: 5792729Abstract: A terpolymer having an average M.sub.n of from 600 to 100,000 is obtained by the terpolymerization of a 1-olefin having from 10 to 30 carbon atoms, maleic anhydride, and a 1,1 -disubstituted polyisobutylene having an average M.sub.n of from 500 to 5,000.Type: GrantFiled: August 20, 1996Date of Patent: August 11, 1998Assignee: Chevron Chemical CorporationInventors: James J. Harrison, William R. Ruhe, Jr.
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Patent number: 5753597Abstract: A polysuccinimide composition is prepared by reacting a mixture of a copolymer of a first unsaturated acidic reagent and a 1,1-disubstituted olefin; a copolymer of a second unsaturated acidic reagent and a 1-olefin, and a polyamine under reactive conditions; then treating the reaction product with either a cyclic carbonate or a linear mono- or polycarbonate or boron compound under reactive conditions. The two unsaturated acidic reagents can be the same or different. The mixture contains from 0.1 to 1.5 equivalents of polyamine per equivalent of acidic groups of the first and second copolymers.Type: GrantFiled: August 20, 1996Date of Patent: May 19, 1998Assignee: Chevron Chemical CompanyInventors: James J. Harrison, William R. Ruhe, Jr.
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Patent number: 5719108Abstract: Dispersant/VI improvers for lubricating oil compositions are disclosed which comprise the reaction product of (a) a copolymer of octadecene-1 and maleic anhydride, the copolymer having a number average molecular weight from greater than 6300 to less than 12000; and (b) a succinimide prepared from a polyamine and an acyclic hydrocarbyl-substituted succinic acylating agent of the formula: ##STR1## wherein X and X.sup.1 are the same or different; provided that at least one of X and X.sup.1 is such that the copolymer can function as a carboxylic acylating agent, and optionally (c) a primary or a secondary hydrocarbyl monoamine or a mixture thereof, preferably an amine of the formula: ##STR2## wherein R.sup.1 is either a saturated or an unsaturated aliphatic hydrocarbyl group, and R.sup.2 is either R.sup.1 or hydrogen, and the total number of carbon atoms in the groups R.sup.1 and R.sup.Type: GrantFiled: November 18, 1996Date of Patent: February 17, 1998Assignee: BP Chemicals (Additives) LimitedInventors: Robert Ian Wilby, Pauline Bowden Jackson
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Patent number: 5670462Abstract: A process is disclosed which comprises reacting at elevated temperature(a) a copolymer of an olefin and a monomer having the structure ##STR1## wherein X and X.sup.1 are the same or different provided that at least one of X and X.sup.1 is such that the copolymer can function as a carboxylic acylating agent and(b) a succinimide prepared from an acyclic hydrocarbyl substituted succinic acylating agent and a polyamine wherein the hydrocarbyl substituted succinic acylating agent is prepared by reacting a polyolefin and an acylating agent of formula I under conditions such that at least 75 mole % of the starting polyolefin is converted to the hydrocarbyl-substituted succinic acylating agent. Hydrocarbyl substituted succinic acylating agents derived from high reactivity PIB's are preferred.Type: GrantFiled: May 11, 1995Date of Patent: September 23, 1997Assignee: BP Chemicals (Additives) LimitedInventors: Douglas McP. Barr, David J. Moreton, Alexander F. Psaila
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Patent number: 5639716Abstract: Oil-soluble dispersant additives are disclosed. The additives comprise the reaction product of a functionalized 1-butene copolymer and at least one nucleophilic reactant selected from amines, amino alcohols, alcohols, and reactive metal compounds. The functionalized copolymer has within its structure at least one acyl functional group selected from the group consisting of C.sub.4 to C.sub.10 dicarboxylic acids and derivatives thereof and C.sub.3 to C.sub.10 monocarboxylic acids and derivatives thereof. The 1-butene copolymer is derived from 1-butene and at least one other .alpha.-olefin of formula CH.sub.2 .dbd.CHR', wherein R' is methyl or a C.sub.3 to C.sub.12 linear or branched alkyl group. The copolymer has a number average molecular weight of at least about 700, a molecular weight distribution of less than 5, and ethenylidene groups terminating at least about 30% of all polymer chains.Type: GrantFiled: June 9, 1994Date of Patent: June 17, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Albert Rossi, Jacob I. Emert, Warren A. Thaler