With Organic Nitrogen, Phosphorus, Or Chalcogen Compound Patents (Class 508/364)
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Patent number: 11608477Abstract: A lubricating oil composition and method for controlling timing chain stretch, wherein the composition contains greater than 50 wt. % of base oil, zinc dialkyl dithiophosphate(s) to provide 350-2200 ppm zinc, molybdenum-containing compound(s) to provide >1-3000 ppm molybdenum, and magnesium-containing detergent(s) to provide <2050 ppm magnesium, all based on the total weight of the composition. The composition has a total TBN of less than 7.5 mg KOH/g, measured by ASTM D-2896 and a weight ratio of ppm of zinc from zinc dialkyl dithiophosphate(s) to ppm of molybdenum from molybdenum-containing compound(s) of <10. The method employs the lubricating oil composition to control timing chain stretch to a level of 0.1% or less.Type: GrantFiled: July 31, 2021Date of Patent: March 21, 2023Assignee: AFTON Chemical CorporationInventors: Ken Garelick, Leslie Schmid, Kristi Engelman
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Patent number: 11566199Abstract: The present invention relates to lubricating compositions and particularly gear oil compositions that include a specific class of substituted triazoles, where the substituted triazole includes at least one hydrocarbyl group linked to one of the nitrogen atoms in the triazole ring. Such compositions provide surprisingly good seal compatibility compared to compositions with other triazoles and/or alternative additives.Type: GrantFiled: December 22, 2020Date of Patent: January 31, 2023Assignee: The Lubrizol CorporationInventor: James N. Vinci
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Patent number: 10913917Abstract: An internal combustion engine lubricating oil composition containing a base oil that is a hydrocarbon oil containing less than 1% by mass of aromatic components and having a sulphur content of less than 20 ppm by mass; a specific organic molybdenum compound as a component (A) at 300 to 1500 ppm by mass as molybdenum atoms; and a borate ester compound as a component (B) at 100 to 1000 ppm by mass as boron atoms.Type: GrantFiled: June 27, 2017Date of Patent: February 9, 2021Assignee: ADEKA CORPORATIONInventors: Taro Sumi, Shinji Iino
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Patent number: 10889778Abstract: A manufacturing method of a lubricant composition includes mixing a composite ester A that contains polyester obtained by condensing trihydric or more polyhydric alcohol a1, a divalent or more polyvalent carboxylic acid a2, and at least one selected from monohydric alcohol a3 or a monovalent carboxylic acid a4, with a compound B having a hydroxyl number of greater than 50 mgKOH/g. A lubricant composition contains the composite ester A and the compound B.Type: GrantFiled: February 21, 2019Date of Patent: January 12, 2021Assignee: FUJIFILM CornorationInventors: Kunihiko Kodama, Yuta Shigenoi
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Patent number: 10000719Abstract: An automotive lubricating oil composition for an internal combustion engine comprises (A) an oil of lubricating viscosity in a major amount; and (B) an oil-soluble zinc dithiocarbamate as an additive component in a minor amount in which each of the two amino groups is substituted with an aryl group and with either another aryl group, an aliphatic group or a hydrogen atom, the composition having not greater than 1600 ppm by mass of phosphorus, expressed as phosphorous atom.Type: GrantFiled: August 17, 2012Date of Patent: June 19, 2018Assignee: INFINEUM INTERNATIONAL LIMITEDInventors: Joseph P. Hartley, Jonathan P. Flemming
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Patent number: 9982211Abstract: A composition comprises the reaction product of a dithiophosphate derivative and an amine. The reaction product is present in the composition in an amount of at least about 25 wt. %. The composition may include additional components. A method of forming the composition comprises the step of combining the dithiophosphate derivative and the amine to form the composition. A method of increasing thermal stability of a dithiophosphate derivative comprises the step of combining the dithiophosphate derivative and an amine. The dithiophosphate derivative can decompose to form hydrogen sulfide (H2S). However, the amine substantially prevents thermal decomposition of the dithiophosphate derivative. An example of the dithiophosphate derivative is 3-(di-isobutoxy-thiophosphorylsulfanyl)-2-methyl-propanoic acid. An example of the amine is ditridecyl amine. The composition can be used for a variety of applications.Type: GrantFiled: December 4, 2014Date of Patent: May 29, 2018Assignee: BASF SEInventors: Michael Dennis Hoey, Eugene Scanlon, Frederick Mensah, Douglas S. Brown, Alfred Karl Jung, Shaun Robert Seibel, Patrick Daniel Hasenhuetl, Ralf Lorenz Schmitt
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Patent number: 9399748Abstract: The invention provides a lubricating grease composition with a worked penetration of 400 to 500 for a machine tool equipped with an automatic lubricator, containing a base oil having a kinematic viscosity at 40° C. of 10 to 200 mm2/s and 0.1 to 10 mass % of solid particles insoluble in the base oil. The lubricating grease composition of the invention can be fed using the automatic lubricator attached to the machine tool, and can prevent the stick-slip from occurring on the sliding lubrication portion of the machine tool.Type: GrantFiled: October 26, 2011Date of Patent: July 26, 2016Assignees: LUBE CORPORATION, KYODO YUSHI CO., LTD.Inventors: Takayuki Ariyasu, Daming Dong, Hiroshi Ozeki, Minoru Namiki, Terasu Yoshinari
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Patent number: 9193931Abstract: A lubricating oil composition having a sulfur content of up to about 0.4 wt. % and a sulfated ash content of up to about 0.5 wt. % as determined by ASTM D874 is disclosed which comprises (a) a major amount of an oil of lubricating viscosity; (b) at least one oil-soluble or dispersed oil-stable boron-containing compound having no more than about 600 ppm of boron, based upon the total mass of the composition; and (c) at least one oil-soluble or dispersed oil-stable molybdenum-containing compound having no more than about 800 ppm of molybdenum, based upon the total mass of the composition; wherein the lubricating oil composition has a ratio of sulfur to molybdenum of about 5:1 to about 500:1.Type: GrantFiled: December 20, 2013Date of Patent: November 24, 2015Assignees: Chevron Oronite Company LLC, Chevron U.S.A. Inc.Inventors: Kenneth D. Nelson, Alexander B. Boffa, William M. Kleiser, Stephen D. Stults, James A. McGeehan, Wim Van Dam, Richard E. Cherpeck
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Patent number: 9139793Abstract: The present invention provides a grease composition which contains a small amount (not more than 0.06 wt %) of molybdenum and yet is capable of achieving an excellent low friction property when mechanical parts in which the grease composition has been packed are operated under a severe sliding condition in which they are subjected to a high speed and a high contact pressure. The present invention also provides a bearing, a universal joint, and a linear motion device in which the grease composition of the present invention is packed. A grease composition (7) is packed inside a grease-packed bearing (1) in such a way that the grease composition (7) is applied to at least the circumference of each rolling element (4). The grease composition (7) contains base oil, a thickener, and an additive. The additive includes molybdenum dithiocarbamate and sodium dithiocarbamate.Type: GrantFiled: December 16, 2011Date of Patent: September 22, 2015Assignee: NTN CORPORATIONInventors: Takayuki Kawamura, Mitsunari Asao
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Lubricating oil composition for sliding section comprising aluminum material, and lubricating method
Patent number: 9040470Abstract: Provided are a lubricant composition capable of reducing friction between sliding parts at least one of which contains an aluminum-based material in a lubrication section, and a method for lubricating an aluminum-based member with the composition. The lubricant composition is for use in a lubrication section having sliding parts at least one of which contains an aluminum-based material, and contains a lubricant base oil and at least one of a phosphorus-containing carboxylic compound and a metal salt thereof (component (A)) at 0.001 to 1 mass % of the composition in terms of phosphorus. The composition may suitably be used as lubricant such as drive train lubricant for automatic or manual transmissions, grease, wet brake oil, hydraulic actuation oil, turbine oil, compressor oil, bearing oil, refrigerant oil, and the like used in apparatus having the sliding parts.Type: GrantFiled: July 26, 2011Date of Patent: May 26, 2015Assignee: JX NIPPON OIL & ENERGY CORPORATIONInventor: Kazuhiro Yagishita -
Publication number: 20150133352Abstract: The present invention relates to an engine oil lubricant composition for use in internal combustion engines comprising one or more molybdenum containing compounds that deliver 1-1000 ppm molybdenum to the finished oil, one or more phosphorus containing compounds that deliver 25-650 ppm phosphorus to the finished oil, and one or more poly(meth)acrylate viscosity index improvers (VI improvers) that may or may not be functionalized, for improved fuel economy and turbocharger related deposits. In addition, the composition comprises an antioxidant system which is carefully balanced to provide improved fuel economy, comprising an aminic antioxidant, a phenolic antioxidant and an ashless dithiocarbamate. Additionally, the formulated oil may contain a dispersant poly(meth)acrylate, in addition to the PAMA VI improver, to reduce the amount of traditional succinimide dispersants.Type: ApplicationFiled: June 5, 2013Publication date: May 14, 2015Applicant: VANDERBILT CHEMICALS, LLCInventors: Carl K. Esche, Glenn A. Mazzamaro, Thorsten Bartels, David B. Gray
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Patent number: 9029303Abstract: A lubricant oil composition according to the present invention comprises: a lubricant base oil whose kinematic viscosity at 100° C. is 1 to 20 mm2/s; and a viscosity index improver in which a ratio M1a/M2a of a total area M1a of peaks in a chemical shift between 29-31 ppm to a total area M2a of peaks in a chemical shift between 64-69 ppm based on a total area of all the peaks is not less than 10 in a spectrum obtained by 13C-NMR.Type: GrantFiled: May 31, 2010Date of Patent: May 12, 2015Assignee: JX Nippon Oil & Energy CorporationInventors: Shigeki Matsui, Akira Yaguchi, Reiko Kudo
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Publication number: 20150126419Abstract: The present disclosure relates to lubricant compositions for an engine, including at least one base oil, at least one polymer for improving the viscosity index, at least one organomolybdenum compound, and at least one polyalkylene glycol, obtained by polymerizing or copolymerizing alkylene oxides including from 3 to 8 carbon atoms, at least of which is butylene oxide, the polyalkylene glycol content being from 1 to 28% by weight relative to the total weight of lubricant composition. The use of at least one polyalkylene glycol, obtained by polymerizing or copolymerizing alkylene oxides including 3 to 8 carbon atoms, at least one of which is butylene oxide, in a base oil enables a reduction in the wear of the connecting-rod bearings of the thermal internal combustion engines of vehicles with hybrid and/or micro-hybrid engines.Type: ApplicationFiled: May 3, 2013Publication date: May 7, 2015Applicants: TOTAL MARKETING SERVICES, DOW GLOBAL TECHNOLOGIES LLCInventors: Olivier Lerasle, Jérôme Valade, Nadjet Khelidj
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Patent number: 8999904Abstract: The lubricating oil composition of the invention comprises a lubricating base oil with a kinematic viscosity at 100° C. of 1-20 mm2/s, and a viscosity index improver having a ratio M1/M2 of 0.20 or greater, between the total area of the peaks between chemical shifts of 36-38 ppm M1 and the total area of the peaks between chemical shifts of 64-66 ppm M2, with respect to the total area of all of the peaks, in the spectrum obtained by 13C-NMR. The lubricating oil composition of the invention has excellent effects, with a sufficiently high HTHS viscosity at 150° C., and a sufficiently low kinematic viscosity at 40° C., a sufficiently low kinematic viscosity at 100° C. and a sufficiently low HTHS viscosity at 100° C.Type: GrantFiled: January 25, 2010Date of Patent: April 7, 2015Assignee: JX Nippon Oil & Energy CorporationInventors: Shigeki Matsui, Akira Yaguchi, Reiko Kudo, Hiroya Miyamoto, Teppei Tsujimoto
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Publication number: 20150045271Abstract: A lubricating oil composition for an internal combustion engine containing a mixed base oil (AB) including a mixture of a base oil (A) being a mineral oil and/or a synthetic oil with a kinematic viscosity at 100° C. of not more than 3.5 mm2/s and a base oil (B) being a mineral oil and/or a synthetic oil with a kinematic viscosity at 100° C. of more than 3.5 mm2/s, wherein the ratio of the base oil (A) to the entire base oil is not more than 40 mass %, a calcium salicylate-based detergent (C) in 0.05 mass % to 0.5 mass % as a calcium amount based on the total amount of the composition, and a calcium sulfonate-based detergent (D) in 0.002 mass % to 0.2 mass % as a calcium amount based on the total amount of the composition.Type: ApplicationFiled: October 5, 2012Publication date: February 12, 2015Inventor: Satoru Yoshida
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Publication number: 20150045270Abstract: A lubricant composition comprising: a fully formulated commercial lubricating oil which comprises from 0.01 to 2.0 percent by weight of an oil soluble organo-molybdenum friction modifier and at least 0.1 percent by weight active sulfur of a surface active sulfur donor component is effective in preventing the removal of DLC coatings while at the same time allowing the beneficial friction-reducing effects from the molybdenum friction modifier to occur.Type: ApplicationFiled: April 5, 2012Publication date: February 12, 2015Inventors: Paul Francis Bastien, Cheng Chen, Brian Lee Papke
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Publication number: 20140342958Abstract: A lubricating oil composition comprising (A) a lubricating oil base oil the kinematic viscosity of which at 100° C. is in the range of from 1.4 to 6 mm2/s, (B) from 250 to 2000 ppm in terms of molybdenum of a molybdenum dialkyldithiocarbamate, (C) from 20 to 500 ppm in terms of sulphur of tetrabenzyl thiuram disulphide and (D) from 0.05 to 3.0 mass % of an amine. The lubricating oil composition of the present invention has a superior friction reducing effect and which has a superior fuel economy effect.Type: ApplicationFiled: December 7, 2012Publication date: November 20, 2014Inventors: Kouichi Kubo, Kiyoshi Hunyuda
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Patent number: 8846590Abstract: A method of lubricating a surface coated with a diamond-like carbon film or coating which comprises supplying to said surface a lubricating oil composition comprising an oil of lubricating viscosity and an effective friction reducing amount of an oil soluble organo-molybdenum compound.Type: GrantFiled: March 26, 2004Date of Patent: September 30, 2014Assignee: Infineum International LimitedInventor: Rebecca Castle
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Publication number: 20140179572Abstract: A lubricating oil comprising a major amount of base oil and a minor amount of an additive package, wherein the additive package comprises: (A) a friction modifier component selected from: (a) one or more a reaction products of an alcohol with a compound of the formula IV: and (b) one or more compounds of the Formulae II-III: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms, R2 and R3 are independently selected from hydrogen C1-C18 hydrocarbyl groups, and C1-C18 hydrocarbyl groups containing one or more heteroatoms; X is an alkali metal, alkaline earth metal or ammonium cation and n is the valence of cation X, and reaction products of amines, amino alcohols, alkali or alkaline earth metal hydroxides, alkali or alkaline earth metal oxides and mixtures thereof with compounds of the Formula IV: wherein R is as defined above; and (B) at least one friction modifier that is different from the one or mType: ApplicationFiled: December 21, 2012Publication date: June 26, 2014Applicant: AFTON CHEMICAL CORPORATIONInventors: John T. Loper, Jeremy P. Styer
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Publication number: 20140148370Abstract: A lubricant composition, comprising an oil of lubricating viscosity, a dispersant comprising the condensation product of a carboxylic-functionalized polymer with an aromatic moiety through an amide, imide, or ester linkage, and an oil-soluble titanium compound, exhibits good oxidative stability.Type: ApplicationFiled: August 22, 2011Publication date: May 29, 2014Applicant: THE LUBRIZOL CORPORATIONInventors: Mary Galic Raguz, Virginia A. Carrick, John K. Pudelski
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Patent number: 8722597Abstract: Provided is a lubricating oil composition for an internal combustion engine, including as essential components the following component (A), component (B), and component (C), in which a phosphorus content of the composition is 50 ppm by mass to 1,000 ppm by mass: Component (A): a base oil; Component (B): a compound represented by the following general formula (1); and Component (C): a metal-containing antioxidant: where R1 to R8 each independently represent a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, Z represents a hydrocarbon group having 2 to 20 carbon atoms, and n represents a number of 1 to 10.Type: GrantFiled: May 18, 2011Date of Patent: May 13, 2014Assignee: Adeka CorporationInventors: Yukio Tatsumi, Kenji Yamamoto
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Publication number: 20140100148Abstract: The present invention provides a lubricating oil composition exhibit excellent friction reduction properties with a small amount of molybdenum. The lubricating oil composition comprises a lubricating base oil, (A) a phosphoric acid ester metal salt represented by formula (1) and (B) an organic molybdenum compound with a ratio of molybdenum to sulfur of 1:3.5 or greater. (In formula 1, R1 to R4 are each a hydrocarbon group having 1 to 30 carbon atoms, an alkyl or alkenyl group having 1 to 30 carbon atoms, or an alkylthioethyl comprising an alkyl group having 1 to 30 carbon atoms and may be the same or different from each other; X1, X2, X3 and X4 are each sulfur or oxygen, either X1 or X2 is oxygen or both are oxygen, and either X3 or X4 is oxygen or both are oxygen; and Y is a metal element.Type: ApplicationFiled: January 20, 2012Publication date: April 10, 2014Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventor: Kazuhiro Yagishita
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Publication number: 20140045733Abstract: The grease composition for a clean environment includes, a base oil, a thickener and a extreme-pressure agent, in which a kinetic viscosity of the base oil at 40° C. is 100˜300 mm2/s, the thickener comprising a lithium complex soap, a content of the thickener is 10˜40 mass % with respect to the total amount of the grease composition.Type: ApplicationFiled: April 11, 2012Publication date: February 13, 2014Applicants: IDEMITSU KOSAN CO., LTD., THK CO., LTD.Inventors: Akira Nogami, Terumoto Hayami, Hiroshi Sampei, Yukitoshi Fujinami, Kouji Takane
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Publication number: 20130276563Abstract: The present invention provides a grease composition which contains a small amount (not more than 0.06 wt %) of molybdenum and yet is capable of achieving an excellent low friction property when mechanical parts in which the grease composition has been packed are operated under a severe sliding condition in which they are subjected to a high speed and a high contact pressure. The present invention also provides a bearing, a universal joint, and a linear motion device in which the grease composition of the present invention is packed. A grease composition (7) is packed inside a grease-packed bearing (1) in such a way that the grease composition (7) is applied to at least the circumference of each rolling element (4). The grease composition (7) contains base oil, a thickener, and an additive. The additive includes molybdenum dithiocarbamate and sodium dithiocarbamate. The content of the molybdenum for the whole weight of the grease composition (7) is set to not more than 0.06 wt %.Type: ApplicationFiled: December 16, 2011Publication date: October 24, 2013Applicant: NTN CORPORATIONInventors: Takayuki Kawamura, Mitsunari Asao
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Publication number: 20130274158Abstract: An internal combustion engine crankcase lubricating oil composition having a sulphated ash content of no greater than 1.2 mass %, based on the mass of the lubricating oil composition, and a phosphorous content of no greater than 0.1 mass %, based on the mass of the lubricating oil composition, which lubricating oil composition comprises or is made by admixing: (A) a crankcase base oil of lubricating viscosity, in a major amount; and (B) the following additives, in respective minor amounts: (B1) a polymeric friction modifier being the reaction product of (a) a functionalised polyolefin, (b) a polyether, (c) a polyol, and (d) a monocarboxylic acid chain terminating group; and (B2) at least one oil-soluble molybdenum compound.Type: ApplicationFiled: April 12, 2012Publication date: October 17, 2013Inventors: Philip J. Woodward, Wangkan Lin, Erika M. Vela, Anthony J. Strong
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Publication number: 20130244915Abstract: Combining a metal based friction modifier, such as a molybdenum dialkyldithiocarbamate, and certain esters of hydroxy carboxylic acids, such as short chain alkyl esters of citric or tartaric acid, e.g., tributyl citrate, has a synergistic effect on lowering the friction coefficient of lubricating oils allowing one to reduce the amount of metal based friction modifier needed to adequately formulate a lubricant with low friction characteristics.Type: ApplicationFiled: February 28, 2013Publication date: September 19, 2013Applicant: Chemtura CorporationInventors: Frank J. DeBlase, Venkatramanan K. Madabusi, Susan Ferrarotti, Faith Gaenzler, Cyril A. Migdal, Gerard Mulqueen
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LUBRICATING OIL COMPOSITION FOR SLIDING SECTION COMPRISING ALUMINUM MATERIAL, AND LUBRICATING METHOD
Publication number: 20130237463Abstract: Provided are a lubricant composition capable of reducing friction between sliding parts at least one of which contains an aluminum-based material in a lubrication section, and a method for lubricating an aluminum-based member with the composition. The lubricant composition is for use in a lubrication section having sliding parts at least one of which contains an aluminum-based material, and contains a lubricant base oil and at least one of a phosphorus-containing carboxylic compound and a metal salt thereof (component (A)) at 0.001 to 1 mass % of the composition in terms of phosphorus. The composition may suitably be used as lubricant such as drive train lubricant for automatic or manual transmissions, grease, wet brake oil, hydraulic actuation oil, turbine oil, compressor oil, bearing oil, refrigerant oil, and the like used in apparatus having the sliding parts.Type: ApplicationFiled: July 26, 2011Publication date: September 12, 2013Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventor: Kazuhiro Yagishita -
Publication number: 20130206097Abstract: An automotive lubricating oil composition for an internal combustion engine comprises (A) an oil of lubricating viscosity in a major amount; and (B) an oil-soluble zinc dithiocarbamate as an additive component in a minor amount in which each of the two amino groups is substituted with an aryl group and with either another aryl group, an aliphatic group or a hydrogen atom, the composition having not greater than 1600 ppm by mass of phosphorus, expressed as phosphorous atom.Type: ApplicationFiled: August 17, 2012Publication date: August 15, 2013Inventors: Joseph P. Hartley, Jonathan P. Flemming
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Publication number: 20130196888Abstract: A lubricant composition includes: (a) one or more base oils, (b) at least one comb polymer formed by a polyalkyl(meth)acrylate main chain, and hydrocarbon side chains including at least 50 carbon atoms, (c) at least one nitrogen-containing organic friction modifier chosen from the optionally alkoxylated fatty amines, fatty amides or imides obtained by the condensation of fatty amines and carboxylic acids, alone or in a mixture, (d) optionally, one or more organometallic organomolybdenum-type friction modifiers. This is used for the lubrication of 4-stroke gasoline or diesel engines of light vehicles, preferentially of hybrid vehicles.Type: ApplicationFiled: August 25, 2011Publication date: August 1, 2013Inventor: Nguyen Truong-Dinh
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Patent number: 8367591Abstract: Provided is a lubricating oil composition of an environmental regulation compliant type, comprising (A) a base oil for a lubricating oil, (B) sulfated oxymolybdenum dithiocarbamate, (C) an acid amide compound, (D) (d1) a fatty acid partial ester compound and/or (d2) an aliphatic amine compound and (E) a specific benzotriazole derivative, wherein a content of the component (B) is 0.02 to 0.1% by mass in terms of molybdenum; a content of the component (C) is 0.2 to 1.0 % by mass; a content of the component (D) is 0.2 to 1.0% by mass; and a content of the component (E) is 0.02 to 0.1% by mass each based on the whole amount of the composition, and it has an excellent friction reducing effect in combination with a high corrosion preventing effect to copper and lead.Type: GrantFiled: October 19, 2007Date of Patent: February 5, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventor: Hideki Kamano
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Publication number: 20130012418Abstract: Provided is a lubricating oil composition for an internal combustion engine, including as essential components the following component (A), component (B), and component (C), in which a phosphorus content of the composition is 50 ppm by mass to 1,000 ppm by mass: Component (A): a base oil; Component (B): a compound represented by the following general formula (1); and Component (C): a metal-containing antioxidant: where R1 to R8 each independently represent a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, Z represents a hydrocarbon group having 2 to 20 carbon atoms, and n represents a number of 1 to 10.Type: ApplicationFiled: May 18, 2011Publication date: January 10, 2013Inventors: Yukio Tatsumi, Kenji Yamamoto
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Publication number: 20120184473Abstract: Provided herein are lubricating oil compositions comprising a major amount of a base oil, at least one oil-soluble molybdenum compound and a zinc dialkyldithiophosphate compound, wherein the molybdenum content derived from the molybdenum compound is at least 10 ppm based on the total weight of the lubricating oil composition and the phosphorus content derived from the zinc dialkyldithiophosphate compound is about 200 to 500 ppm based on the total weight of the lubricating oil composition. The lubricating oil composition can further comprise at least one additive. Methods of making and using the lubricating oil compositions are also described.Type: ApplicationFiled: March 23, 2012Publication date: July 19, 2012Inventors: Alexander B. Boffa, Kenji Takeoka
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Patent number: 8211839Abstract: The invention relates to an extreme pressure additive composition with excellent corrosion resistance properties for use in grease, as well as a lubricating grease composition containing the additive. The additive composition is based on (a) approximately equal amounts by mass of antimony diamyldithiocarbamate and zinc diamyldithiocarbamate, and (b) thiadiazole dimer poly(ether)glycol complex; at (a):(b) mass ratio of about 1.6:1 to about 9.6:1.Type: GrantFiled: May 27, 2010Date of Patent: July 3, 2012Assignee: R.T. Vanderbilt Company, Inc.Inventors: Ronald J. Tepper, Gaston A. Aguilar, Robert Heverly
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Publication number: 20120135899Abstract: A lubricant composition suitable for lubricating an internal combustion engine comprises: (a) an oil of lubricating viscosity having a viscosity index of at least 105 and a kinematic viscosity at 100 C of less than 7 mm2s-1; (b) 0.01 to 2 weight percent of a friction modifier represented by the structure [I]; (c) 0.5 to 4 weight percent of a poly(meth)acrylate viscosity modifier polymer; (d) 0 to 500 parts per million by weight of molybdenum in the form of an oil-soluble molybdenum compound; and (e) 0 to 200 parts per million by weight of boron in the form of an oil-soluble boron compound.Type: ApplicationFiled: June 2, 2010Publication date: May 31, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Jody A. Kocsis, Brent R. Dohner, Haihu Qin, Marina Baum
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Publication number: 20120135900Abstract: The lubricating oil composition of the invention comprises a lubricating base oil with a kinematic viscosity at 100° C. of 1-20 mm2/s, and a viscosity index improver having a ratio M1/M2 of 0.20 or greater, between the total area of the peaks between chemical shifts of 36-38 ppm M1 and the total area of the peaks between chemical shifts of 64-66 ppm M2, with respect to the total area of all of the peaks, in the spectrum obtained by 13C-NMR. The lubricating oil composition of the invention has excellent effects, with a sufficiently high HTHS viscosity at 150° C., and a sufficiently low kinematic viscosity at 40° C., a sufficiently low kinematic viscosity at 100° C. and a sufficiently low HTHS viscosity at 100° C.Type: ApplicationFiled: January 25, 2010Publication date: May 31, 2012Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Shigeki Matsui, Akira Yaguchi, Reiko Kudo, Hiroya Miyamoto, Teppei Tsujimoto
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Publication number: 20120071373Abstract: A lubricant oil composition according to the present invention comprises: a lubricant base oil whose kinematic viscosity at 100° C. is 1 to 20 mm2/s; and a viscosity index improver in which a ratio M1a/M2a of a total area M1a of peaks in a chemical shift between 29-31 ppm to a total area M2a of peaks in a chemical shift between 64-69 ppm based on a total area of all the peaks is not less than 10 in a spectrum obtained by 13C-NMR.Type: ApplicationFiled: May 31, 2010Publication date: March 22, 2012Applicant: JX Nippon Oil & Energy CorporationInventors: Shigeki Matsui, Akira Yaguchi, Reiko Kudo
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Publication number: 20120065110Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and a product obtainable from a 1,4-conjugate addition of an aminocarboxylic acid to an activated olefin. The invention further relates to a method of lubricating an internal combustion engine by lubricating the engine with the lubricating composition. The invention further relates to the use of the product disclosed herein as a lead corrosion inhibitor.Type: ApplicationFiled: February 8, 2010Publication date: March 15, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Jody A. Kocsis, Matthew D. Gieseiman, Seth L. Crawley, Douglas M Barr
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Publication number: 20120040874Abstract: A particular gear oil composition is provided that contains (A) a base oil, (B) an ethylene-?-olefin copolymer, (C) a sulfur-containing compound, (D) an organomolybdenum compound and (E) a phosphorus-containing compound, which is excellent in extreme pressure properties, shear stability and wear resistance, and is excellent in fuel saving properties.Type: ApplicationFiled: March 26, 2010Publication date: February 16, 2012Applicant: Idemitsu Kosan Co., Ltd.Inventor: Masatoshi Toda
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Patent number: 8093190Abstract: An antioxidant lubricant composition has at least 50 wt % of a lubricating base oil and an oil-soluble metal compound providing between 1 and 2,000 parts per million of metal to the lubricant composition, the metal compound being chosen from the group consisting of molybdenum, tungsten titanium and boron compounds, and an oil-soluble hindered amine providing between about 0.001 and about 2 wt % of oil-soluble hindered amine to the lubricant composition, and optionally, an oil-soluble diarylamine providing between 0.001 and about 2 wt % of oil-soluble diarylamine to the lubricant composition.Type: GrantFiled: December 10, 2010Date of Patent: January 10, 2012Assignee: R.T. Vanderbilt Company, Inc.Inventors: Kevin J. Chase, John M DeMassa, Brian Stunkel, Glenn A. Mazzamaro, Steven G. Donnelly
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Patent number: 8080500Abstract: This invention relates to lubricating oil additives, and to lubricating oil compositions, their method of preparation, and use. More specifically, this invention relates to several novel lubricating oil additives and compositions which contain a tungsten compound and an antioxidant, namely aminic antioxidants such as a secondary diarylamine or an alkylated phenothiazine. The use of the tungsten compound with the secondary diarylamine and/or the alkylated phenothiazine provides improved oxidation and deposit control to lubricating oil compositions. The lubricating oil compositions of this invention are particularly useful as crankcase and transmission lubricants, gear oils and other high performance lubricant applications.Type: GrantFiled: April 3, 2008Date of Patent: December 20, 2011Assignee: King Industries, Inc.Inventors: Ramanathan Ravichandran, Farouk Abi-Karam, Alena Yermolenka, Michel Hourani, Ingo Roehrs
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Patent number: 8067346Abstract: Disclosed are lubricating oil compositions comprising a major amount of an oil of lubricating viscosity and a tetra-functional hydrolyzable silane compound of the general formula Si—X4 or hydrolysis product thereof, wherein X is independently selected from the group consisting of hydroxyl, alkoxy, aryloxy, acyloxy, amino, monoalkyl amino and dialkyl amino.Type: GrantFiled: August 31, 2006Date of Patent: November 29, 2011Assignee: Chevron Oronite Company LLCInventors: Elaine S. Yamaguchi, Kam-Sik Ng
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Patent number: 8048834Abstract: A method and compositions for lubricating surfaces with lubricating oils exhibiting increased phosphorous retention. The lubricated surface includes a lubricant composition containing a base oil of lubricating viscosity, an amount of a phosphorus-containing compound and an amount of at least one hydrocarbon soluble titanium compound that is effective to provide an aged catalyst temperature that converts at least fifty percent of exhaust gas hydrocarbons, carbon monoxide, and NOx that is lower than an aged catalyst temperature that converts at least fifty percent of exhaust gas hydrocarbons, carbon monoxide, and NOx of the lubricant composition devoid of the hydrocarbon soluble titanium compound.Type: GrantFiled: September 17, 2007Date of Patent: November 1, 2011Assignee: Afton Chemical CorporationInventors: Gregory H. Guinther, John T. Loper
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Patent number: 8030256Abstract: This invention relates to lubricating oil additives, and to lubricating oil compositions, their method of preparation, and use. More specifically, this invention relates to several novel lubricating oil additives and compositions which contain a tungsten compound and an antioxidant, namely aminic antioxidants such as a secondary diarylamine or an alkylated phenothiazine. The use of the tungsten compound with the secondary diarylamine and/or the alkylated phenothiazine provides improved oxidation and deposit control to lubricating oil compositions. The lubricating oil compositions of this invention are particularly useful as crankcase and transmission lubricants, gear oils and other high performance lubricant applications.Type: GrantFiled: April 3, 2008Date of Patent: October 4, 2011Assignee: King Industries, Inc.Inventors: Ramanathan Ravichandran, Farouk Abi-Karam, Alena Yermolenka, Michel Hourani, Ingo Roehrs
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Publication number: 20110237474Abstract: A low-phosphorus lubricating composition has less than 600 ppm phosphorus, comprising at least 85 weight % of a lubricating base blend, and an additive comprising the following, as weight % of the total composition: (1) an organomolybdenum compound at an amount which provides about 0.1-800 ppm Mo; (2) a hindered phenol at about 0.1-2%; and (3) a dithiocarbamate at about 0.1-2%; with a first proviso that where the dithiocarbamate does not comprise a metal dithiocarbamate, the additive additionally comprises: (4) an alkylated diphenylamine at about 0.1-2%, and with a second proviso that where the organomolybdenum compound comprises molybdenum dithiocarbamate, it is considered a metal dithiocarbamate for purposes of the first proviso[G1], but is considered an organomolybdenum compound for the purposes of calculation of the amount present in the total composition.Type: ApplicationFiled: March 25, 2011Publication date: September 29, 2011Applicant: R.T. VANDERBILT COMPANY, INC.Inventors: Glenn A. Mazzamaro, Steven G. Donnelly, Ronald J. Hiza
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Patent number: 8017565Abstract: Intake valve deposits in a direct injection internal combustion engine are reduced by lubricating the engine with a lubricant that is substantially free of ashless organic friction modifiers and whose base oil has a Noack volatility of less than 12 mass %.Type: GrantFiled: February 12, 2007Date of Patent: September 13, 2011Assignee: Infineum International LimitedInventors: Christopher J. Locke, Angela J. Keeney
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Patent number: 7897550Abstract: Urea grease composition for constant velocity joints is provided containing base oil, one or more urea thickener compounds, (A) one or more molybdenum sulphurized dialkyldithiocarbamates represented by general formula (I) wherein R1 and R2 are independently chosen from alkyl groups of from 1 to 24 carbons, m+n=4, m is from 0 to 3 and n is from 4 to 1, (B) triphenylphosphorothionate represented by formula (II) and (C) one or more stearic acid metal salts.Type: GrantFiled: June 17, 2004Date of Patent: March 1, 2011Assignee: Shell Oil CompanyInventors: Yasushi Kawamura, Takumi Matsumoto, Kazuhiro Miyajima, Tetsuo Nimura, Kazushige Ohmura, Noriaki Shinoda, Keiji Tanaka, Takeo Yamamoto
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Publication number: 20110041638Abstract: A grease composition includes: a poly-?-olefin having a kinematic viscosity at 40 degrees C. of 60 to 320 mm2/s, the poly-?-olefin being contained in an amount of 50 mass % or more relative to a whole composition; a thickener that is a lithium salt of a hydroxyl-free fatty acid having 10 to 22 carbon atoms; and an ashless dithiocarbamate and/or zinc dithiocarbamate that are contained in an amount of 0.1 to 1.5 mass % in terms of sulfur relative to a whole composition. In the grease composition, a phosphorous content is 0.05 mass % or less relative to the whole composition, and a worked penetration is in a range from 265 to 310.Type: ApplicationFiled: April 7, 2009Publication date: February 24, 2011Applicant: Idemitsu Kosan Co., Ltd.Inventors: Yukitoshi Fujinami, Shigeo Hara, hiroyuki Kitano, Kensaku Fujinaka, Hironori Youshimura, Yasushi Ohara
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Patent number: 7879777Abstract: A lubricating oil composition contains a major portion of a lubricating base oil and an antioxidant additive at about 0.1-5.0 mass percent, the additive including: a secondary diarylamine, an organo molybdenum compound, and an organoammonium tungstate compound.Type: GrantFiled: May 3, 2007Date of Patent: February 1, 2011Assignee: R.T. Vanderbilt Company, Inc.Inventors: Robert John Tynik, Steven G. Donnelly, Gaston A. Aguilar
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Patent number: 7875579Abstract: An antioxidant lubricant composition has at least 50 wt % of a lubricating base oil and an oil-soluble metal compound providing between 1 and 2,000 parts per million of metal to the lubricant composition, the metal compound being chosen from the group consisting of molybdenum, tungsten titanium and boron compounds, and an oil-soluble hindered amine providing between about 0.001 and about 2 wt % of oil-soluble hindered amine to the lubricant composition, and optionally, an oil-soluble diarylamine providing between 0.001 and about 2 wt % of oil-soluble diarylamine to the lubricant composition.Type: GrantFiled: March 3, 2008Date of Patent: January 25, 2011Assignee: R.T. Vanderbilt Company, Inc.Inventors: Kevin J. Chase, John M. DeMassa, Brian W. Stunkel, Glenn A. Mazzamaro, Steven G. Donnelly
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Patent number: 7820602Abstract: This invention relates to lubricating oil additives, and to lubricating oil compositions, their method of preparation, and use. More specifically, this invention relates to several novel lubricating oil additives and compositions which contain a tungsten compound and an antioxidant, namely aminic antioxidants such as a secondary diarylamine or an alkylated phenothiazine. The use of the tungsten compound with the secondary diarylamine and/or the alkylated phenothiazine provides improved oxidation and deposit control to lubricating oil compositions. The lubricating oil compositions of this invention are particularly useful as crankcase and transmission lubricants, gear oils and other high performance lubricant applications.Type: GrantFiled: July 12, 2006Date of Patent: October 26, 2010Assignee: King Industries, Inc.Inventors: Ramanathan Ravichandran, Farouk Abi-Karam, Alena Yermolenka, Michel Hourani, Ingo Roehrs