The Nitrogen Is Bonded Directly To The Carbon Of A -c(=x)x- Group, Wherein The Xs May Be The Same Or Diverse Chalcogens (e.g., Dithiocarbamates, Etc.) Patents (Class 508/363)
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Patent number: 12037561Abstract: A grease composition including: a base oil; a thickener; a zinc sulfonate; a polysulfide; an overbased calcium sulfonate; and triphenyl phosphite, in which a proportion of the zinc sulfonate with respect to a total mass of the base oil and the thickener is 0.030 mass % to 0.045 mass % in terms of a zinc content, a proportion of the polysulfide with respect to the total mass of the base oil and the thickener is 0.16 mass % to 0.24 mass % in terms of a sulfur content, a proportion of the overbased calcium sulfonate with respect to the total mass of the base oil and the thickener is 0.010 mass % to 0.015 mass % in terms of a calcium content, and a proportion of the triphenyl phosphite with respect to the total mass of the base oil and the thickener is 0.24 mass % to 0.36 mass %.Type: GrantFiled: August 10, 2021Date of Patent: July 16, 2024Assignees: JTEKT CORPORATION, ENEOS CORPORATIONInventors: Takeshi Tsuda, Yurie Hagino, Kazumi Sakai, Yusuke Ayame, Go Tatsumi, Kiyomi Sakamoto
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Patent number: 11466227Abstract: An improved organic and molybdenum friction modifier combination is disclosed, the combination resulting in a synergistic result of both initial friction reduction performance and a further retention and durability of continued friction reduction performance. These results will produce added benefit from, e.g., formulated passenger car motor oils targeting lower viscosity formulations to help improve fuel economy.Type: GrantFiled: October 15, 2018Date of Patent: October 11, 2022Assignee: LANXESS CorporationInventor: Frank J. DeBlase
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Patent number: 11401482Abstract: Disclosed is a method for preventing or reducing low speed pre-ignition in an engine lubricated with a formulated oil. The formulated oil has a composition comprising at least one oil soluble or oil dispersible cobalt-containing compound.Type: GrantFiled: September 13, 2018Date of Patent: August 2, 2022Assignees: CHEVRON ORONITE COMPANY LLC, CHEVRON U.S.A. INC.Inventors: Ian G. Elliott, Richard E. Cherpeck, Amir Gamal Maria, Theresa Liang Gunawan
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Patent number: 11261517Abstract: A sliding member includes a carbon transfer layer and can superiorly effectively decrease friction and reduce wear. A method produces the sliding member. The sliding member includes a substrate and a carbon transfer layer. The carbon transfer layer is disposed on the surface of the substrate and includes both sp2 bonded carbon and sp3 bonded carbon. The carbon transfer layer preferably has a ratio sp3/(sp2+sp3) of the sp3 bonded carbon to the totality of the sp2 bonded carbon and the sp3 bonded carbon of 0.1 or more.Type: GrantFiled: October 28, 2019Date of Patent: March 1, 2022Assignees: DAICEL CORPORATION, TOHOKU UNIVERSITYInventors: Norihiro Kimoto, Tomohiro Goto, Koshi Adachi, Tsubasa Takahashi
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Patent number: 11118128Abstract: A fuel-saving-type engine oil composition is provided that exhibits a satisfactory friction-reducing effect in a low-viscosity engine oil without being constrained by, for example, high temperatures, low temperatures, low loads, or high loads. The engine oil composition includes: an engine oil having a low-temperature viscosity of from 0 to 10 in SAE viscosity grades and a high-temperature viscosity of from 4 to 20 in the SAE viscosity grades; and a molybdenum compound (A) represented by the following general formula (1): where R1 to R4 each independently represent a hydrocarbon group having 4 to 18 carbon atoms, and not all of R1 to R4 represent the same group, and when R1 and R2 represent the same group, R3 and R4 do not represent the same group, and X1 to X4 each independently represent a sulfur atom or an oxygen atom.Type: GrantFiled: January 22, 2018Date of Patent: September 14, 2021Assignee: ADEKA CORPORATIONInventors: Taro Sumi, Shinji Iino
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Patent number: 10920167Abstract: A lubricant composition including a binuclear molybdenum compound (A) and a trinuclear molybdenum compound (B), wherein these compounds are included in a range represented by (molybdenum of the binuclear molybdenum compound (A)):(molybdenum of the trinuclear molybdenum compound (B))=99.98:0.02 to 95:5 as a mass ratio.Type: GrantFiled: June 26, 2017Date of Patent: February 16, 2021Assignee: ADEKA CORPORATIONInventors: Eiji Katsuno, Taro Sumi
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Patent number: 10800993Abstract: The present invention relates to a lubricated system comprising: a) a component comprising a first surface which is a diamond-like carbon (DLC) surface; b) a component comprising a second surface; and c) a lubricant formulation interposed between the first surface and second surface. The lubricant formulation comprises: i) a base stock; ii) a molybdenum compound; iii) an organic polymer comprising a hydrophobic polymeric sub unit selected from polyesters and functionalised polyolefins and a hydrophilic polymeric sub unit selected from polyethers; and iv) optionally, other additives. The combination of the molybdenum compound and the organic polymer in the lubricant formulation reduces the wear on one or more of the surfaces in the lubricated system when compared with using the molybdenum containing friction modifier alone.Type: GrantFiled: March 14, 2017Date of Patent: October 13, 2020Assignee: Croda International PLCInventors: Gareth Moody, John Eastwood, Aitziber Viadas Cienfuegos
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Patent number: 10711219Abstract: An automatic transmission fluid comprises a major amount of an oil of lubricating viscosity and minor amounts of (a) one or more oil-soluble or dispersible molybdenum-containing compounds, and (b) a reaction product of an isomerized alkenyl-substituted succinic anhydride and a polyamine characterized by structure (II): In structure (II) x and y are independently zero or integers from 1 to 30, where x+y is from 1 to 30, and z is zero or an integer from 1 to 10.Type: GrantFiled: December 11, 2017Date of Patent: July 14, 2020Assignee: Infineum International LimitedInventors: HahnSoo Kim, Laura Kahsar
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Patent number: 10704010Abstract: A grease of the invention contains a base oil and a thickener, where, when the volumetric-based arithmetic mean particle size of particles contained in the grease measured using laser diffraction/scattering method is A (unit: ?m), a formula A?3 (1) is satisfied.Type: GrantFiled: February 4, 2016Date of Patent: July 7, 2020Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Yoshiyuki Suetsugu, Hiromu Kumagai
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Patent number: 10155915Abstract: A lubricating oil composition that hardly generates precipitation attributable to a molybdenum compound under the low temperature environment and is excellent in a friction-reducing effect under the low temperature environment is provided. The lubricating oil composition is one including (A) a lubricating base oil, (B) a molybdenum-based compound, (C) a metal-based detergent, and (D) an ester compound having one or more hydroxyl groups in a molecule thereof, wherein the metal-based detergent (C) includes (C1) a calcium detergent and (C2) a magnesium detergent, and a content of the ester compound (D) having one or more hydroxyl groups in a molecule thereof is 0.03 to 1.20 mass % on a basis of the total amount of the lubricating oil composition.Type: GrantFiled: March 30, 2016Date of Patent: December 18, 2018Assignee: IDEMITSU KOSAN CO., LTD.Inventor: Kazushi Tamura
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Patent number: 10087392Abstract: The present invention relates to a lubricant composition including a molybdenum dithiocarbamate (A) represented by the general formula (1) and a copolymer (B) that includes, as essential constitutional units, a unit (a) represented by the general formula (2) and a unit (b) represented by the general formula (3), has a weight-average molecular weight of from 5,000 to 150,000, and has a composition ratio of the unit (a) to the unit (b), i.e., (a)/(b), of from 50/50 to 90/10 by mole, and a lubricant oil composition including same.Type: GrantFiled: November 5, 2014Date of Patent: October 2, 2018Assignee: ADEKA CORPORATIONInventors: Yukiya Moriizumi, Kenji Yamamoto
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Patent number: 10030207Abstract: A sliding machine includes: a pair of sliding members having sliding surfaces that oppose each other and are able to move relative to each other; and a lubricating oil which is able to be interposed between the opposed sliding surfaces, in which at least one of the sliding surfaces is covered with a chromium (Cr)-containing amorphous carbon film (chromium-coating DLC), and the lubricating oil contains an oil-soluble molybdenum compound having a chemical structure formed from a trinuclear material of molybdenum (Mo). Specifically, the chromium-coating DLC contains, when the entirety of the film is assumed to be 100 at. %, 1% to 49% of Cr, 0% to 30% of hydrogen (H), carbon (C) as a remainder, and impurities. The lubricating oil contains 5 ppm to 800 ppm of the oil-soluble molybdenum compound in terms of Mo mass ratio with respect to the entirety of the lubricating oil.Type: GrantFiled: July 9, 2015Date of Patent: July 24, 2018Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Hiroyuki Mori, Mamoru Tohyama, Masaru Okuyama, Keiji Hayashi, Naoya Ikeda
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Patent number: 9790447Abstract: [Technical Problem] An object is to provide a sliding system which can drastically reduce the friction coefficient on a sliding portion by means of a novel combination of a chromium nitride film and a lubricant oil. [Solution to Problem] The sliding system according to the present invention includes: a pair of sliding members having sliding surfaces that can relatively move while facing each other; and a lubricant oil that can be interposed between the sliding surfaces facing each other. At least one of the sliding surfaces is formed as a coating surface of a chromium nitride film, and the lubricant oil contains an oil-soluble molybdenum compound that has a chemical structure of a trinuclear of Mo.Type: GrantFiled: July 10, 2015Date of Patent: October 17, 2017Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Hiroyuki Mori, Mamoru Tohyama, Masaru Okuyama, Keiji Hayashi, Naoya Ikeda
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Patent number: 9644166Abstract: A nanolubricant composition is described where the lubricant composition includes a flowable oil or grease with nanoparticles dispersed in the flowable oil or grease. The nanoparticles are configured to polish a surface of a structure slowly over a period of time. The nanoparticles a hardness of at least about 7 Mohs and a diameter that is less than one half the arithmetic average roughness of the surface or a length that is less than one half of the arithmetic average roughness of the surface.Type: GrantFiled: May 25, 2012Date of Patent: May 9, 2017Assignee: Howard UniversityInventor: Mohsen Mosleh
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Patent number: 9567546Abstract: The present invention provides a lubricating oil composition having fuel saving properties and providing gears and bearings with satisfactory durability, which is thus suitably used particularly for a gear system of an automobile. The lubricating oil composition a lubricating base oil comprising a mix base oil of (A) a mineral base oil having a 40° C. kinematic viscosity of 10 mm2/s or higher and 100 mm2/s or lower and (E) a mineral base oil having a 40° C. kinematic viscosity of 200 mm2/s or higher and 600 mm2/s or lower and a sulfur content of 0.3 to 0.9 percent by mass, the content of the base oil belonging to Component (B) is 15 percent by mass or more, and (C) and an organic molybdenum compound in an amount of 100 to 1000 ppm by mass as molybdenum, the lubricating oil composition having a 40° C. kinematic viscosity of 90 mm2/s or lower.Type: GrantFiled: August 27, 2013Date of Patent: February 14, 2017Assignee: JX Nippon Oil & Energy CorporationInventor: Hitoshi Komatsubara
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Patent number: 9564508Abstract: A method of making a semiconductor structure includes forming a trench through a shallow trench isolation (STI) structure and into a substrate, and forming a liner including an electrical insulator material on sidewalls of the trench. The method also includes forming a core including a high thermal conductivity material in the trench and on the liner, and forming a cap in the trench and on the core.Type: GrantFiled: October 30, 2014Date of Patent: February 7, 2017Assignee: GLOBALFOUNDRIES INC.Inventors: Mattias E. Dahlstrom, Dinh Dang, Qizhi Liu, Ramana M. Malladi
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Patent number: 9536836Abstract: An MIS contact structure comprises a layer of semiconductor material, a layer of insulating material having a contact opening formed therein, a layer of contact insulating material having substantially vertically oriented portions and a substantially horizontally oriented portion, the vertically oriented portions of the layer of contact insulating material contacting a portion, but not all, of the sidewalls of the contact opening and the horizontally oriented portion of the layer of contact insulating material contacting the semiconductor layer. A conductive material is positioned on the layer of contact insulating material within the contact opening, the conductive material layer having vertically oriented portions and a horizontally oriented portion and a conductive contact positioned in the contact opening that contacts the uppermost surfaces of the conductive material layer and the layer of contact insulating material.Type: GrantFiled: May 27, 2016Date of Patent: January 3, 2017Assignees: GLOBALFOUNDRIES Inc., International Business Machines CorporationInventors: Ruilong Xie, Xiuyu Cai, Kangguo Cheng, Ali Khakifirooz
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Patent number: 9528073Abstract: The invention provides a lubricant composition capable of favorably preventing the members from causing hydrogen embrittlement-induced flaking when the members are operated under the conditions where the oil film is thin (namely, the metal surfaces considerably come in contact with each other). The lubricant composition used for lubricating the steel mechanical members operated by a rolling motion or rolling-sliding motion is characterized by containing a base oil and additives, the additives including an organic sulfonate rust inhibitor and a load carrying additive.Type: GrantFiled: January 23, 2009Date of Patent: December 27, 2016Assignee: KYODO YUSHI CO., LTD.Inventors: Toshiaki Endo, Junichi Imai, Yutaka Imai
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Patent number: 9228152Abstract: An automotive engine oil and/or fuel comprising a base stock and an organic polymeric friction reducing additive is claimed. A method of reducing friction in an automotive engine oil and/or fuel by the addition of the organic polymeric friction reducing additive to the base stock is also claimed.Type: GrantFiled: March 3, 2011Date of Patent: January 5, 2016Assignee: CRODA INTERNATIONAL PLCInventors: Lee Thompson, Steven James Randles, Stephen Boyde, John Gamwell, Nicola Readman
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Patent number: 9012383Abstract: A novel molybdenum dithiocarbamate composition is produced by preparing a di-tridecylamine (DTDA) intermediate from a butylene feedstock comprising greater than 50% 2-butylene, and preparing a molybdenum dithiocarbamate composition from the DTDA intermediate.Type: GrantFiled: March 21, 2012Date of Patent: April 21, 2015Assignee: Vanderbilt Chemicals, LLCInventors: Steven G. Donnelly, Gaston A. Aguilar, Kevin J. Chase, William T. Wallack
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Patent number: 8980806Abstract: The invention is directed to oil soluble additive compositions, lubricating oil compositions, and additive concentrates comprising the salt of (1) a molybdenum oxide, sulfide, or oxysulfide; (2) an amide reaction product of a carboxylic acid component and a polyamine component wherein the charge mole ratio (CMR) of the carboxylic acid component to the polyamine component is about 2:1 to 1:1; and (3) a post-treating agent.Type: GrantFiled: December 16, 2011Date of Patent: March 17, 2015Assignee: Chevron Oronite Company LLCInventors: Gaurav Bhalla, Man Hon Tsang
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Patent number: 8901049Abstract: The purpose of the present invention is to provide: a sliding member having a lubricating film formed on the sliding surface thereof, and capable of exhibiting friction-reducing performance; and a friction reduction method for the same. To that end, the present invention entails coating the sliding surface with a titanium nitride-based material (for example, titanium carbon nitride, titanium nitride, or titanium aluminum nitride), adding a molybdenum dithiocarbamate with molybdenum in the amount of 600-1000 ppm to diesel engine oil, setting the arithmetic mean roughness of the sliding member to 2-10 nm, and upon converting the Sommerfeld number viscosity to Pa·s, the speed to s?1, and the load to mean Hertzian stress (Pa), then the lubrication conditions for use are within the range of 2.12365×10?19 to 5.94509×10?19.Type: GrantFiled: October 21, 2011Date of Patent: December 2, 2014Assignees: UD Trucks Corporation, Adeka CorporationInventors: Keisuke Yari, Sachiyo Ono, Masaru Iijima, Noriyoshi Tanaka, Kenji Yamamoto, Akihiro Kotaka
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Patent number: 8883696Abstract: The purpose of the present invention is to provide: a sliding mechanism having a lubricating film formed on the sliding surface thereof, and capable of exhibiting friction-reducing performance; and a friction reduction method for the same. To that end, the present invention entails coating the sliding surface with chromium nitride, adding a molybdenum dithiocarbamate with molybdenum in the amount of 600-1000 ppm to diesel engine oil, setting the arithmetic mean roughness of the sliding member to 2-60 nm, and upon converting the Sommerfeld number viscosity to Pa·s, the speed to s?1, and the load to mean Hertzian stress (Pa), then the lubrication conditions for use are within the range of 2.12365×10?20 to 5.94509×10?19.Type: GrantFiled: October 21, 2011Date of Patent: November 11, 2014Assignees: UD Trucks Corporation, Adeka CorporationInventors: Keisuke Yari, Sachiyo Ono, Masaru Iijima, Noriyoshi Tanaka, Kenji Yamamoto, Akihiro Kotaka
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Publication number: 20140303055Abstract: The lubricant composition of this invention comprises a base oil and an additive, which is at least one selected from the group consisting of an organic sulfonate, a carboxylate, a thiocarbamate and a thiophosphoric acid ester salt. The lubricant composition can effectively suppress hydrogen embrittlement-caused flaking of an element, such as a rolling bearing, a sliding bearing, a gear, a ball thread, a linear guide, a linear bearing, a cam and various joints in a high concentration hydrogen environment. The invention provides also a rolling bearing, a sliding bearing, a gear, a ball thread, a linear guide, a linear bearing, a cam and various joints using the lubricant composition.Type: ApplicationFiled: June 23, 2014Publication date: October 9, 2014Inventors: Toshiaki ENDO, Da Ming DONG, Yutaka IMAI
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Patent number: 8846590Abstract: A method of lubricating a surface coated with a diamond-like carbon film or coating which comprises supplying to said surface a lubricating oil composition comprising an oil of lubricating viscosity and an effective friction reducing amount of an oil soluble organo-molybdenum compound.Type: GrantFiled: March 26, 2004Date of Patent: September 30, 2014Assignee: Infineum International LimitedInventor: Rebecca Castle
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Patent number: 8592355Abstract: An engine oil composition obtained by compounding: (A) a base oil mixture including a first base oil and a second base oil, the first base oil having a kinematic viscosity of 2 to 50 mm2/s at 100° C., a viscosity index of 80, and a sulfur content of less than 0.03 mass %, the second base oil having a kinematic viscosity of 2 to 50 mm2/s at 100° C., a viscosity index of 60, and a sulfur content of 0.03 mass % or more; (B) an oil-soluble molybdenum-containing composition; and (C) a molybdenum-based friction modifier; in which, based on the total amount of engine oil composition, the content of the second base oil is 0.1 to 15 mass %, the content of (B) oil-soluble molybdenum-containing composition is 10 to 1000 mass ppm in terms of amount of molybdenum, and the content of (C) molybdenum-based friction modifier is 100 to 1000 mass ppm in terms of amount of molybdenum.Type: GrantFiled: June 5, 2006Date of Patent: November 26, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventor: Koki Ito
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Publication number: 20130310289Abstract: Provided is a lubricating oil composition for an internal combustion engine, including: an organic molybdenum compound as a component (A); a base oil having a kinematic viscosity at 100° C. of 25 mm2/s or more as a component (B); and a base oil having a kinematic viscosity at 100° C. of less than 12.5 mm2/s as a component (C), in which the composition has a kinematic viscosity at 100° C. of 5 mm2/s to 12.5 mm2/s and a phosphorus content of 800 ppm or less.Type: ApplicationFiled: August 19, 2011Publication date: November 21, 2013Inventors: Kazuhiro Umehara, Kenji Yamamoto, Masaki Maruyama, Yasushi Naito, Satoru Yoshida
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Patent number: 8586516Abstract: There is disclosed a Super Tractor Oil Universal lubricating composition comprising an oil of lubricating viscosity formulated with an additive package comprising at least one metal detergent, at least one phosphorus-based wear preventative, and at least one molybdenum compound. Methods for improving the braking performance of a tractor and the anti-wear protection of a tractor engine are also disclosed.Type: GrantFiled: January 19, 2007Date of Patent: November 19, 2013Assignee: Afton Chemical CorporationInventors: Jeffrey L. Milner, Peter L. Leitner, John M. Pietras
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Publication number: 20130206097Abstract: An automotive lubricating oil composition for an internal combustion engine comprises (A) an oil of lubricating viscosity in a major amount; and (B) an oil-soluble zinc dithiocarbamate as an additive component in a minor amount in which each of the two amino groups is substituted with an aryl group and with either another aryl group, an aliphatic group or a hydrogen atom, the composition having not greater than 1600 ppm by mass of phosphorus, expressed as phosphorous atom.Type: ApplicationFiled: August 17, 2012Publication date: August 15, 2013Inventors: Joseph P. Hartley, Jonathan P. Flemming
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Publication number: 20130157913Abstract: The invention is directed to oil soluble additive compositions, lubricating oil compositions, and additive concentrates comprising the salt of (1) a molybdenum oxide, sulfide, or oxysulfide; (2) an amide reaction product of a carboxylic acid component and a polyamine component wherein the charge mole ratio (CMR) of the carboxylic acid component to the polyamine component is about 2:1 to 1:1; and (3) a post-treating agent.Type: ApplicationFiled: December 16, 2011Publication date: June 20, 2013Applicant: Chevron Oronite Company LLCInventors: Gaurav Bhalla, Man Hon Tsang
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Patent number: 8450255Abstract: The disclosed invention relates to a functional fluid comprising: at least one oil of lubricating viscosity; at least one detergent, the detergent contributing an amount of metal to the functional fluid equal to a concentration in the range from about 0.015 to about 1% by weight of the functional fluid, the detergent contributing an amount of basicity to the functional fluid equal to a total base number in the range from about 0.3 to about 2; and at least one friction modifier, the friction modifier comprising at least two hydrocarbyl groups attached to a polar group or atom (eg., a nitrogen atom).Type: GrantFiled: December 13, 2007Date of Patent: May 28, 2013Assignee: The Lubrizol CorporationInventors: Masahiko Ikeda, Susie Hurley, William D. Abraham, James L. Sumiejski, Craig D. Tipton
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Patent number: 8445418Abstract: A lubricating oil composition for an internal combustion engine contains: a base oil having a viscosity index of 120 or more; and a polymer compound that includes a first constituent having a mass average molecular weight of less than 100,000 and a second constituent having a mass average molecular weight of 100,000 or more, the first constituent of 0.01 mass % to 10 mass % being contained relative to a total amount of the lubricating oil composition, preferably 0.1 mass % to 10 mass %, the second constituent of less than 0.5 mass % being contained relative to the total amount of the lubricating oil composition. A viscosity index of the lubricating oil composition is 130 or more.Type: GrantFiled: September 17, 2009Date of Patent: May 21, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventor: Ryo Yamada
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Publication number: 20130029892Abstract: Provided is a lubricant oil composition for an internal combustion engine which is characterized by including a base oil having a viscosity index of 125 or higher and a Noack evaporation amount (250° C.×1 h) of 15% by mass or less, and, based on a total amount of the composition, from 0.1 to 10% by mass of (A) a C2 to C20 olefin polymer having a mass average molecular weight of 500 or more and 10,000 or less and/or (B) a polymeric compound having a mass average molecular weight of 10,000 or more and less than 100,000, wherein a content of (C) a polymeric compound having a mass average molecular weight of 100,000 or more is less than 1.0% by mass. The lubricant oil composition can, despite of its low viscosity, reduce noise during running, prevent fatigue damage such as gear pitting, reduce the consumption of the oil, and provide excellent fuel saving performance.Type: ApplicationFiled: March 18, 2011Publication date: January 31, 2013Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Ryou Yamada
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Patent number: 8304374Abstract: The present invention relates to a lubricating composition containing a dicarboxylic acid ester or a dicarboxylic acid amide as an antiwear agent. The invention further provides a lubricating composition suitable for the mechanical device such as an internal combustion engine.Type: GrantFiled: October 22, 2007Date of Patent: November 6, 2012Assignee: The Lubrizol CorporationInventors: Jason R. Brown, Patrick E. Mosier, Paul E. Adams
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Patent number: 8299005Abstract: A lubricating composition is provided that has good elastomer compatibility and friction-reduced properties which comprises a base oil having a viscosity index (VI) greater than about 80, a kinematic viscosity (Kv) at 100° C. of from about 2 mm2/s to about 50 mm2/s, containing 90 wt % or more saturates, having less than about 5 ppm sulfur, and wherein the base oil is derived from a waxy feed; said composition being free of a tallow diaminepropane dioleate; and containing a minor amount of (a) a polylester of an aliphatic carboxylic acid having 12 to 24 carbon atoms and (b) an oil soluble or oil dispersible molybdenum compound.Type: GrantFiled: May 7, 2007Date of Patent: October 30, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Marc-Andre Poirier, Douglas E. Deckman
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Publication number: 20120264666Abstract: A novel molybdenum dithiocarbamate composition is produced by preparing a di-tridecylamine (DTDA) intermediate from a butylene feedstock comprising greater than 50% 2-butylene, and preparing a molybdenum dithiocarbamate composition from the DTDA intermediate.Type: ApplicationFiled: March 21, 2012Publication date: October 18, 2012Applicant: R.T. VANDERBILT COMPANY, INC.Inventors: Steven G. DONNELLY, Gaston A. Aguilar, Kevin J. Chase, William T. Wallack
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Publication number: 20120258896Abstract: A lubricating oil composition comprising a zinc dithiocarbamate fraction, for use in a gasoline or diesel engine equipped with fluoroelastomer seals, wherein said zinc dithiocarbamate fraction consists essentially of zinc dithiocarbamate molecules per Formula I: having alkyl groups R1, R2, R3, and R4, wherein the weighted total average for carbon chain lengths for all molecules together is 9 or more:Type: ApplicationFiled: April 2, 2012Publication date: October 11, 2012Applicant: R.T. VANDERBILT COMPANY, INC.Inventors: Gaston A. AGUILAR, Francis S. Cheng, Kevin J. Chase
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Patent number: 8278253Abstract: The resistance to oxidation of a lubricating oil is enhanced by the addition to the lubricating oil of an additive amount of an ionic liquid.Type: GrantFiled: February 5, 2010Date of Patent: October 2, 2012Assignee: ExxonMobil Research and Engineering CompanyInventor: Jacob Joseph Habeeb
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Patent number: 8216983Abstract: The present invention provides a grease composition for use in a constant velocity joint, which is excellent in the resistance to flaking. The grease composition comprises the following components (a) to (d): (a) a base oil; (b) a thickener; (c) an organic molybdenum compound; and (d) at least one compound selected from the group consisting of oxides of divalent typical metals having a Mohs hardness lower than that of the steel and compounds of the foregoing divalent typical metals, which can immediately be converted into the corresponding oxides of these metals having a Mohs hardness lower than that of the steel under the boundary lubrication conditions. In particular, the present invention relates to a grease composition for use in a constant velocity joint, wherein the component (d) is zinc oxide or zinc carbonate and wherein the component (c) is molybdenum dithiocarbamate.Type: GrantFiled: August 25, 2006Date of Patent: July 10, 2012Assignee: Kyodo Yushi Co., Ltd.Inventors: Akira Taniguchi, Shinya Kondo
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Product of amines with hydroxy acid as friction modifiers suitable for automatic transmission fluids
Patent number: 8148306Abstract: Compositions comprising an oil of lubricating viscosity; an amide represented by the formula R1R2N—C(O)R3 wherein R1 and R2 are hydrocarbyl groups of at least 6 carbon atoms and R3 is a hydroxyalkyl group of 1 to 6 carbon atoms or a group formed by the condensation of said hydroxyalkyl group, through a hydroxyl group thereof, with an acylating agent; a nitrogen-containing dispersant; and a phosphorus-containing compound are suitable for lubricating a transmission.Type: GrantFiled: October 11, 2006Date of Patent: April 3, 2012Assignee: The Lubrizol CorporationInventors: Stuart L. Bartley, Shreyasi Lahiri, Mark R. Baker, Craig D. Tipton -
Patent number: 8101558Abstract: A composition containing an oil of lubricating viscosity in a concentrate-forming or major amount; and, as an additive component, an oil-soluble or oil dispersible mononuclear molybdenum compound having a molybdenum atom having bonded thereto one or more diazenide ligands and one or more hydrocarbyl group-carrying ligands, other than diazenide ligands, the hydrocarbyl groups conferring oil-solubility or oil-dispersibility on the molybdenum compound.Type: GrantFiled: December 1, 2009Date of Patent: January 24, 2012Assignee: Infineum International LimitedInventors: Benjamin R. Elvidge, Aleka Hinni, Jonathan Dilworth
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Patent number: 8044005Abstract: A rolling bearing, for use in household appliances, having a high degree of quietness, an excellent durability at high temperatures and rotational speeds, a low torque, and excellent fretting property; and a lubricant composition which can be sealed into the rolling bearing. The lubricant composition includes a base oil and a thickening agent. The base oil is a mixed oil having the following characteristics of (a) to (c): (a) The base oil consists essentially of a synthetic hydrocarbon oil and an ester oil; (b) A kinematic viscosity of the mixed oil at 40° C. is 40 to 70 mm2/second; (c) A mixing weight ratio between the ester oil of the mixed oil and the synthetic hydrocarbon oil thereof is 30:70 to 70:30. The thickening agent comprises a diurea compound shown by a formula (1): where R1 and R3 are a straight-chain alkyl groups having 9 to 22 carbon atoms respectively, and R2 is an aromatic hydrocarbon group having 6 to 15 carbon atoms. The lubricant composition is sealed into the rolling bearing.Type: GrantFiled: May 24, 2004Date of Patent: October 25, 2011Assignee: NTN CorporationInventors: Hidenobu Mikami, Seiji Okamura, Hiroki Iwamatsu, Masashi Mitsuoka
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Patent number: 8034753Abstract: A low SAPS lubricating oil composition exhibiting excellent piston cleanliness having up to 0.3 wt. % sulfur, up to 0.08 wt. % phosphorus, and a sulfated ash content up to 0.80 wt. % comprising an overbased alkali metal or alkaline earth metal alkyl salicylate detergent having a low soap content.Type: GrantFiled: September 2, 2005Date of Patent: October 11, 2011Assignee: Infineum International LimitedInventor: Robert W. Shaw
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Patent number: 8026199Abstract: The present invention provide a lubricating oil composition suitable for internal combustion engines, which composition is excellent in thermal/oxidation stability and can inhibit the increases of the viscosity and acid number even in the presence of NOx and can be used for a long period of time or provide a lubricating oil composition particularly suitable for diesel or direct injection engines equipped with an exhaust-gas after-treatment device such as DPF or various catalysts, which composition is excellent in high-temperature detergency and base number retention properties and further can achieve the effect of inhibit wear caused by soot contamination in the oil occurring significantly when the content of phosphorus compounds such as ZnDTP is decreased, at a high level and can inhibit the exhaust-gas after-treatment device from being adversely affected.Type: GrantFiled: November 1, 2007Date of Patent: September 27, 2011Assignee: Nippon Oil CorporationInventors: Shigeki Matsui, Koji Hoshino, Shigeki Takeshima
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Patent number: 8003584Abstract: There is disclosed a lubricating composition comprising a friction modifier and a base oil comprising less than about 3% by weight of tetracycloparaffins. Methods of making and using the composition are also disclosed.Type: GrantFiled: July 14, 2006Date of Patent: August 23, 2011Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Tze-chi Jao, John T. Loper, Helen T. Ryan, Carl K. Esche
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Patent number: 7989407Abstract: The present invention is directed to lubricating oils exhibiting improved resistance to oxidation and deposit/sludge formation comprising a lubricant base oil and an effective amount of a catalytic antioxidant comprising one or more polymetal organometallic compound, to a method for improving the antioxidancy and the resistance to deposit/sludge formation of formulated lubricating oil compositions by the addition thereto of an effective amount of the aforementioned polymetal organometallic compound, and to an additive concentrate containing the aforementioned polymetal organometallic compound.Type: GrantFiled: September 18, 2007Date of Patent: August 2, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Jacob J. Habeeb, Steven P. Rucker, Michael E. Landis, Abhimanyu O. Patil
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Publication number: 20110166053Abstract: A lubricating oil composition for an internal combustion engine contains: a base oil having a viscosity index of 120 or more; and a polymer compound that includes a first constituent having a mass average molecular weight of less than 100,000 and a second constituent having a mass average molecular weight of 100,000 or more, the first constituent of 0.01 mass % to 10 mass % being contained relative to a total amount of the lubricating oil composition, preferably 0.1 mass % to 10 mass %, the second constituent of less than 0.5 mass % being contained relative to the total amount of the lubricating oil composition. A viscosity index of the lubricating oil composition is 130 or more.Type: ApplicationFiled: September 17, 2009Publication date: July 7, 2011Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Ryo Yamada
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Publication number: 20110077180Abstract: The invention is directed to oil soluble additive compositions, lubricating oil compositions derived from a process for preparing a sulfurized oil soluble molybdenum complex having reduced active sulfur comprising: reacting an acidic molybdenum compound with an amide derived from a carboxylic acid component an polyamine component in a ratio from 2:1 to 1:1; there after sulfurizing to provide a sulfurized oil soluble molybdenum which is subsequently treated with at least one compound capable of reacting with the active sulfur of step b).Type: ApplicationFiled: September 30, 2009Publication date: March 31, 2011Inventors: Qunlai Chen, Man Hon Tsang, Gaurav Bhalla, William R. Ruhe, JR.
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Patent number: 7910526Abstract: The present invention provides a grease composition for use in constant velocity joints, which comprises the following components (a) to (g) and a constant velocity joint comprising the grease composition sealed or encapsulated therein: (a) a base oil; (b) a diurea thickener represented by the following general formula: R1NH—CO—NH—C6H4-p-CH2—C6H4-p-NH—CO—NHR2 wherein R1 and R2 each independently represents an alkyl group having 8 to 20 carbon atoms, an aryl group having 6 to 12 carbon atoms or a cycloalkyl group having 6 to 12 carbon atoms; (c) a molybdenum dialkyl dithiocarbamate insoluble in the base oil; (d) a molybdenum dialkyl dithiocarbamate soluble in the base oil; (e) molybdenum disulfide; (f) at least one member selected from the group consisting of calcium phenate and calcium sulfonate; and (g) a sulfur-containing extreme-pressure agent free of phosphorus.Type: GrantFiled: December 21, 2006Date of Patent: March 22, 2011Assignees: Kyodo Yushi Co., Ltd., NTN CorporationInventors: Mitsuhiro Kakizaki, Takashi Okaniwa, Minoru Ishijima, Shinichi Takabe
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Patent number: 7906469Abstract: Lubricating oil compositions having a sulfated ash content of no more than 1.0 mass %, which contain a major amount of oil of lubricating viscosity, a minor amount of calcium salicylate detergent, an amount of a magnesium-based detergent providing the lubricating oil composition with at least 200 ppm of magnesium, an amount of a sulfur-containing molybdenum compound providing the lubricating oil composition with at least 20 ppm of molybdenum, and at least one nitrogen-containing dispersant providing the lubricating oil composition with at least 0.9 mass % nitrogen, which compositions provide improved top ring wear protection in internal combustion engines.Type: GrantFiled: November 29, 2005Date of Patent: March 15, 2011Assignee: Infineum International LimitedInventors: Stephen Arrowsmith, Matthew D. Irving