Abstract: Fluid refrigeration compositions comprising a hydrocarbon lubricant, an immiscible refrigerant and an additive capable of reducing the interfacial tension between the hydrocarbon lubricant and refrigerant.

Abstract: An improved lubricant is provided by combining ester lubricants with alkylated polyaromatic lubricants. This combination provides a lubricant that exhibits the oxidation/varnish control of alkylated naphthenics, while at the same time providing the high temperature stability of the ester-type lubricants. A wide variety of ester lubricants can be used such as polyol esters, dimeracid esters and the like. Preferably, the alkylated aromatic lubricant has a viscosity greater than 25 up to 220 cSt measured at 40.degree. C. Greases can also be formed using this combination.

Abstract: An oil-soluble polyester having a weight average molecular weight of 10,000 to 1 000,000, which is a polycondensate prepared by polycondensing the following ingredients (A), (B) and (C):(A) a divalent higher carboxylic acid ingredient,(B) a divalent alcohol ingredient comprising a glycol represented by the following formula:HO--CH.sub.2 --CR.sup.1 R.sup.2 --CH.sub.2 --OHwherein R.sup.1 and R.sup.2 represent a alkyl group, and the sum of carbon numbers in R.sup.1 and R.sup.2 is at least three, and(C) 0.1 to 15% by mole, based on the total of ingredients (A) and (B), of at least one multi-valent ingredient selected from a carboxylic acid with a valency of at least three and an alcohol with a valency of at least three. This oil-soluble polyester is useful as an additive for a lubricating oil.

Abstract: A biodegradable lubricant which is prepared from: about 60-99% by weight of at least one biodegradable synthetic ester base stock which comprises the reaction product of: a branched or linear alcohol having the general formula R(OH).sub.n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and mixed acids comprising about 30 to 80 molar % of a linear acid having a carbon number in the range between about C.sub.5 to C.sub.12, and about 20 to 70 molar % of at least one branched acid having a carbon number in the range between about C.sub.5 to C.sub.10 and wherein no more than 10% of the branched acids used to form the biodegradable synthetic ester base stock contains a quaternary carbon; wherein the ester base stock exhibits the following properties: at least 60% biodegradation in 28 days as measured by the Modified Sturm test; a pour point of less than -25.degree. C.; a viscosity of less than 7500 cps at -25.degree. C.

Abstract: A complex alcohol ester which comprises the reaction product of an add mixture of the following: a polyhydroxyl compound represented by the general formula:R(OH).sub.nwherein R is any aliphatic or cyclo-aliphatic hydrocarbyl group and n is at least 2, provided that the hydrocarbyl group contains from about 2 to 20 carbon atoms; a polybasic acid or an anhydride of a polybasic acid, provided that the ratio of equivalents of the polybasic acid to equivalents of alcohol from the polyhydroxyl compound is in the range between about 1.6:1 to 2:1; and a monohydric alcohol, provided that the ratio of equivalents of the monohydric alcohol to equivalents of the polybasic acid is in the range between about 0.84:1 to 1.2:1; wherein the complex alcohol ester exhibits a pour point of less than or equal to -20.degree. C., a viscosity in the range between about 100-700 cSt at 40.degree. C. and having a polybasic acid ester concentration of less than or equal to 70 wt. %, based on the complex alcohol ester.

Abstract: A two step process for preparing a synthetic ester from a vegetable oil by means of lipase enzymes. A lubricant composition comprising a synthetic ester prepare by said process.

Abstract: A synthetic ester composition which exhibits thermal and oxidative stability, lower friction coefficient and lower wear, wherein the ester composition comprises the reaction product of: a branched or linear alcohol having the general formula R(OH).sub.n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and at least one branched mono-carboxylic acid which has a carbon number in the range between about C.sub.5 to C.sub.13 ; wherein the synthetic ester composition has between about 5-35% unconverted hydroxyl groups, based on the total amount of hydroxyl groups in the branched or linear alcohol.

Abstract: A lubricating oil additive contains a partially etherified polyhydric alcohol which has at least two hydroxyl groups and at least one hydrocarbon group having a least one double bond bonded thereto through an ether linkage as an active component. The lubricating additive is added to a lube base oil to form a lubricating oil which imparts excellent wear resistance, scarcely corrodes metallic substances, scarcely swells rubbers or resins and scarcely forms sludge due to thermal oxidation. The lubricating oil is mixed with a refrigerant to give a working fluid suitable for refrigerant compressors of domestic refrigerators, automotive room air conditioners, refrigerators for industrial use and air conditioners.

Abstract: The invention provides alkenyl-substituted dicarboxylic derivatives, having (a) an alkenyl group derived from an atactic propylene oligomer substantially of the formula ##STR1## where n is in the range 15 to 120, having number average molecular weight (M.sub.n) in the range 700 to 5000, and molar ratio dicarboxylic moieties to atactic propylene oligomer in the range 1:1 to 1.5:1; and having (b) an ester group derived from a polyol, which are useful as dispersant additives; a process for making the ester derivatives, additive concentrates containing such ester derivatives, and lubricating oil compositions.

Abstract: Ceramic-containing engines are lubricated by compositions containing synthetic ester base stock. Suitable esters include those prepared from iso- and neo-acids of medium chain length and polyols including inositol.

Abstract: A biodegradable lubricant which is prepared from: about 60-99% by weight of at least one biodegradable synthetic ester base stock which comprises the reaction product of: a branched or linear alcohol having the general formula R(OH).sub.n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and at least one branched oxo acid having a carbon number in the range between about C.sub.5 to C.sub.10, provided that said branched oxo acid does not include 2-ethylhexanoic acid; wherein the ester base stock exhibits the following properties: at least 60% biodegradation in 28 days as measured by the Modified Sturm test; a pour point of less than -25.degree. C.; and a viscosity of less than 7500 cps at -25.degree. C.; about 1 to 20% by weight lubricant additive package; and about 0 to 20% of a solvent.

Abstract: Phosphorus-free and ashless high-temperature aircraft and turbo engine lubricant that contains no halogens or hazardous substances is disclosed. The phosphorus-free lubricating oil may be prepared from pentaerythritol tetraester, methylolpropane triester, or their combinations, ashless dithiocarbamate additives, a dialkydiphenylamine, an alkylphenylnaphthylamine, a triazole derivative, a rest inhibitor or metal deactivator, and an anti-foam. The use of this lubricating oil in addition to its superior wear and friction performance over the standard lubricating oil provides a safe and an environmentally benign gas turbine engine oil for aircraft and turbo engines.

Abstract: A polyol ester-based lubricant comprising a polyol ester (A) and a polyol ester (B);the polyol ester (A) comprising an ester of a neopentyl polyol and an acid residue of carbon number of 6-17, in which alpha-carbon in the acid residue of the polyol ester is tertiarily branched, and when alkyl groups having 4 or more carbon atoms are bonded to the alpha-carbon, the alkyl groups are branched, andthe polyol ester (B) comprising an ester of a neopentyl polyol and an acid residue of carbon number of 6-17, in which alpha-carbon in the acid residue of the polyol ester is secondarily or tertiarily branched and alkyl groups bonded to the alpha-carbon are straight is provided. This polyol ester-based lubricant has high performance, as demonstrated by high compatibility with substitute fluorocarbons in a kinematic viscosity range of 28 to 40 cst at 40.degree. C., excellent hydrolysis resistance, and a low pour point.

Abstract: A grease composition comprising a base oil containing not less than 10% by weight of an ester oil based on the total base oil and having a kinematic viscosity of 50 to 200 mm.sup.2 /sec at 40.degree. C. and 15 to 35% by weight, based on the total grease composition, of a diurea compound represented by formula (I): ##STR1## wherein R.sub.2 represents an aromatic hydrocarbon group having 6 to 15 carbon atoms; and R.sub.1 and R.sub.3, which may be the same or different, each represent an aromatic hydrocarbon group having 6 to 12 carbon atoms or an aliphatic hydrocarbon group having 8 to 20 carbon atoms, the proportion of the aromatic hydrocarbon groups in the total of R.sub.1 and R.sub.3 being 50 to 100 mol %. When applied to outer race rotating bearings, the grease composition is excellent in flaking resistance, leak resistance, and low noise properties and prevents premature seizing under high temperature and high speed conditions.

Abstract: Improved refrigeration lubricants useful in compression refrigeration units are esters, exhibit an excellent balance of performance characteristics, notably in the combination of good miscibility, hydrolytic stablity, wear resistance coupled with a viscosity within the range required in many commercial refrigeration units. These esters are of a hindered dihydric or trihydric alcohol such as trimethylolpentanediol and a fatty acid, where at least 80 number percent of the acyl groups are straight chain groups.

Abstract: A process for the production of a high-performance hybrid polyol ester having excellent compatibility with hydrofluorocarbons which are regarded as the most likely refrigerant and having excellent resistance to hydrolysis which esters are liable to undergo, the polyol ester having a plurality of branched fatty acid residues at least one of which has a different number of carbon atoms from that of the other branched fatty acid residue or those of the other branched fatty acid residues, the process comprising reacting at least two kinds of olefins having different numbers of carbon atoms, carbon monoxide and a polyhydric alcohol in the presence of hydrogen fluoride.

Abstract: A synthetic ester composition which exhibits thermal and oxidative stability, lower friction coefficient and lower wear, wherein the ester composition comprises the reaction product of: a linear or branched alcohol having the general formula R(OH).sub.n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and at least one linear and/or branched acid which has a carbon number in the range between about C.sub.4 to C.sub.20, wherein the synthetic ester composition has a hydroxyl number of between about greater than 5 to 180, preferably between about greater than 5 to 100, and more preferably between about 10 to 80.

Abstract: A lubricating oil composition includes from 0.01 weight per cent to 2 weight per cent of a polymer that includes repeating units derived from a (C.sub.8 -C.sub.15)alkyl (meth)acrylate monomer and 98 weight per cent to 99.99 weight per cent of a vegetable oil or a polyol ester.

Abstract: A biodegradable synthetic ester base stock which comprises a blend of the following base stocks: (A) the reaction product of: (1) a branched or linear alcohol having the general formula R(OH).sub.n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and (2) mixed acids comprising about 30 to 80 molar % of a linear acid having a carbon number in the range between about C.sub.5 to C.sub.12, and about 20 to 70 molar % of at least one branched acid having a carbon number in the range between about C.sub.5 to C.sub.10 and wherein no more than 10% of the branched acids used to form the biodegradable synthetic ester base stock contains a quaternary carbon; wherein the ester base stock exhibits the following properties: at least 60% biodegradation in 28 days as measured by the Modified Sturm test, a pour point of less than -25.degree. C.; and a viscosity of less than 7500 cps at -25.degree. C.

Abstract: A low emissions, high oxidative stability crankcase lubricating oil formulation which is prepared from a base stock which comprises at least one synthetic ester selected from the group consisting of: polyol esters, synthetic esters having between 5-35% unconverted hydroxyl groups, based on the total amount of hydroxyl groups in the polyol, and synthetic esters combined with at least one additional functional group which is capable of increasing the polarity of the functionalized synthetic ester, wherein the base stock has an oxygen, nitrogen or halogen content of at least 15 wt. %, based on the total weight of the base stock; and a lubricant additive package.

Abstract: Lubricant or lubricant concentrate on mineral oil and/or synthetic oil basis having improved lubricating properties, in particular improved load bearing, sliding and corrosion inhibiting properties, which containsa) one or more mineral oils and/or synthetic oils as base oil andb) at least one tetravalent to octavalent alcohol having at least one quaternary carbon atom as well as at least one ester bond in its molecule and having a density d.sub.20 of at least 0,900 and an enthalpy H of at least 350 kcal/kg,c) at least one asymmetric organometallic compound,d) at least one phosphor containing substance,e) at least one sulfur-containing substance andf) further usual additives.

Abstract: A synthetic ester composition exhibiting thermal and oxidative stability which comprises the reaction product of: a branched or linear alcohol having the general formula K(OH).sub.n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and at least one branched mono-carboxylic acid which has a carbon number in the range between about C.sub.5 to C.sub.13 ; wherein the synthetic ester composition has between 5-35% unconverted hydroxyl groups, based on the total amount of hydroxyl groups in the branched or linear alcohol.

Abstract: A biodegradable lubricant which is prepared from: about 60-99% by weight of at least one biodegradable synthetic ester base stock which comprises the reaction product of: a branched or linear alcohol having the general formula R(OH).sub.n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and mixed acids comprising about 30 to 80 molar % of a linear acid having a carbon number in the range between about C.sub.5 to C.sub.12, and about 20 to 70 molar % of at least one branched acid having a carbon number in the range between about C.sub.5 to C.sub.10 and wherein no more than 10% of the branched acids used to form the biodegradable synthetic ester base stock contains a quaternary carbon; wherein the ester base stock has an oxygen to carbon ratio of between about 0.15:1 to 0.3:1 and exhibits the following properties: at least 60% biodegradation in 28 days as measured by the Modified Sturm test; a pour point of less than -25.degree. C.

Abstract: A lubricating fluid composition for dynamic pressure bearings which supports a shaft by dynamic pressure, said lubricating fluid composition comprising fine magnetic particles dispersed in a base oil solvent, to which solvent is added an amine anti-gelling agent.

Abstract: The objective of the present invention resides in providing a lubricant for refrigerators that reacts rapidly with free acids and contains a stabilizer that has good compatibility with a chlorine-free Flon-thpe coolant such as Flon 134a and the like whose molecules do not contain chlorine. The lubricant for refrigerators employing a chlorine-free Flon-type coolant in accordance with the present invention 100 parts by weight of a synthetic oil and is compounded with 0.05 to 15 parts by weight of an alicyclic epoxy compound having one or more functional groups represented by the following formula: ##STR1## (wherein R.sub.1 and R.sub.2 independently represent a hydrogen or methyl group, and may be the same or different).

Abstract: There is disclosed an improved process for making a lubricant grease wherein a basic oil is mixed with a thickening compound, a polar compound and an additive or additives to impart desired characteristics to the grease. The improvement includes selecting the basic oil from the group consisting of a polyolester, a silicone oil, a mineral oil, a vegetable oil, glycerine and propylene glycol. The improvement further includes first mixing the basic oil with a mixture of two polar agents in a vessel under constant stirring at a temperature and pressure sufficient to obtain a homogeneous mixture and then and only then reacting the homogenous mixture with the additive or additives and a thickening agent.

Abstract: A lubricant composition of suitable viscosity miscible in non-chlorinated, fluorinated hydrocarbon refrigerants includes polyhydric alcohol esters, such as TMP, mono and/or di-pentaerythritol esters, made with branched carboxylic acids.

Abstract: New oligoesters made from a tricyclic diol with 8 to 20 carbon atoms, a dicarboxylic acid with 4 to 20 carbon atoms, and an aliphatic alcohol with 1 to 30 carbon atoms are useful as lubricants, hydraulic oils and compressor oils for mobile field use in forestry and agriculture, in construction, in mining and in transport. The oligoesters have a kinematic viscosity of 50 to 50,000 mm.sup.2 /s at 40.degree. C. and are biodegradable.

Abstract: A lubricant composition for compression-type refrigerating machines containing tetrafluoroethane or the like as a refrigerant and a lubricant comprising (A) 40 to 95% by weight of a synthetic oil composed of a poly-.alpha.-olefin and/or an ethylene/.alpha.-olefin copolymer or a mixture of an alkylbenzene and a poly-.alpha.-olefin and/or an ethylene/.alpha.-olefin copolymer and (B) 5 to 60% by weight of a fluidity improver composed of both or either of an ester compound and a triglyceride. The lubricant composition is excellent in the performance such as wear resistance, electrical insulating properties, hydrolytic stability, nonhygroscopicity, etc. and also in returnability of the lubricant composition. Thus, the lubricant is especially effective when used in automobile or household air conditioner, refrigerator, etc. having high industrial usefulness.

Abstract: A lubricating oil composition for two-cycle engines, consisting essentially of, by weight: (1) 30% to 70% of a polyol ester having a kinematic viscosity of 9 to 15 cSt at 100.degree. C., 30% to 70% of a diester having a kinematic viscosity of 2 to 5 cSt at 100.degree. C., 1% to 5% of a polybutene having a molecular weight of 500 to 2,500 and/or 1% to 5% of a polymethacrylate having a molecular weight of 5,000 to 40,000, and 5% to 25% of a dispersant; or (2) 30% to 70% of a polyol ester having a kinematic viscosity of 4 to 15 cSt at 100.degree. C., 0% to 35% of a complex ester having a kinematic viscosity of 10 to 14 cSt at 100.degree. C., 10% to 70% of a diester having a kinematic viscosity of 2 to 5 cSt at 100.degree. C., and. 5% to 25% of a dispersant; or (3) a lubricating oil base, 5% to 25% of a polyamide dispersant, and 0.1% to 5% of a combination of a neutral calcium sulfonate and a neutral calcium salicylate, based on the total weight of the composition.

Abstract: An ester oil which lacks complete miscibility with fluorohydrocarbons has its miscibility with fluorohydrocarbons refrigerants improved by blending it with a second ester oil composed of molecules corresponding to the formula ROOC--CH.sub.2 CH.sub.2 -[(ROOC)CHCH.sub.2 ].sub.m --C(COOR).sub.2 --[CH.sub.2 CH(COOR)].sub.n --CH.sub.2 CH.sub.2 COOR wherein the R's represent alkyl groups of 1-30 carbons, at least 10% of which are alkyl groups of 1-4 carbons; and each of m and n represents zero or a positive integer such that the sum of m and n in a molecule is 0-30.