Abstract: A granular bleach activator extrudate that has a size and shape that is within a relatively narrow distribution range. The bleach activator exhibits improved solubility, and reduced product separation when incorporated into a granular detergent composition. Also provided are granular detergent compositions comprising a detersive surfactant and the bleach activator extrudates. Methods for forming the extruded bleach activator particles are also provided.

Abstract: Coatings are applied to particulate detergent components or compositions to improve free-flow properties, improve dispensing and avoid dust formation. This is achieved by a two-step coating process, wherein the first coating step comprises mixing the detergent composition or component with a finely divided particulate material which is preferably aluminosilicate, and the second coating step comprises applying a coating agent. Suitable coating agents for the second step comprise from 5% to 95% by weight of cellulosic polymer; from 5% to 95%, by weight of sugar; and optionally, from 0% to 30% by weight of plasticizer.

Abstract: A tablet of compacted particulate cleaning composition which contains surfactant and detergency builder, and is suitable for fabric washing, also includes water-insoluble, water-swellable polymeric material, and disintegration-promoting particles containing at least 40% (by weight of the particles) of one or more materials selected from: compounds with a water-solubility exceeding 50 grams per 100 grams water phase 1 sodium tripolyphosphate sodium tripolyphosphate which is partially hydrated so as to contain water of hydration in an amount which is at least 0.5% by weight of the sodium tripolyphosphate in the disintegration-promoting particles.

Abstract: Laundry detergents and cleaners which, in addition to a peroxide compound, comprise a compound of the formula (R1R1)N—X—N(R1R1)  (I) or metal complexes thereof, where X and R1 have the meanings listed in the description, are claimed.

Abstract: Asymmetrical imide bleach activators for use in both solid and liquid additive, bleaching and detergent compositions are provided. The compounds have general formula (I) wherein R1 is a moiety selected from a specific group, R2 is a C1-C8 linear or branched chain saturated or unsaturated alkyl group and R3 is a C1-C4 linear or branched chain saturated or unsaturated alkyl group. Preferred compounds include the compounds when R2 and R3 are CH3. Bleach additive and bleaching compositions including the asymmetrical bleach activators and methods of cleaning fabrics are also provided.

Abstract: A detergent tablet which contains a bleach activator is disclosed. The bleach activator is in particulate form and has a particle size in a range of from about 100 microns to about 4000 microns. The bleach activator is present in a range of from about 0.1% to about 15% by weight of the detergent tablet.

Abstract: A tablet of compacted particulate detergent composition including surfactant and detergency builder, suitable for fabric washing, is sub-divided into a plurality of discrete regions with differing compositions. At least one region of the tablet contains a water-swellable polymer serving to promote disintegration of this region. The polymer is present in this region in a concentration greater than in at least one other region of the tablet so as to cause disintegration of the region at a greater speed than disintegration of another region of the tablet.

Abstract: A surfactant system capable of structuring a non-aqueous liquid composition, wherein the surfactant system comprises at least about 5% of a structuring particle. The surfactant system preferably further comprises a surfactant selected from the group consisting of anionic, nonionic, cationic, amphoteric surfactants and mixtures thereof. A well dispersed mixture of a non-aqueous liquid, for example, a nonionic surfactant, and at least about 25%, by weight of the surfactant system results in the mixture having a yield of at least about 2.0 Pa when measured at 20 sec−1 and 25° C. Moreover, the surfactant system should exhibit a peak when measured by SAXS x-ray diffraction, wherein the peak's center is between about the 1.5 to 2.5 v positions on the 2 theta axis. The structuring particles are most preferably structuring particles of sulfate and linear alkyl benzene sulfonate. Also provide is a method of making the structuring particle.

Abstract: A system for forming and releasing an aqueous peracid solution is disclosed. The system includes a container and a peracid forming composition provided within the container. The container is permeable to the passage of water and aqueous peracid solution. The peracid forming composition includes a peracid precursor and a peroxygen source. Preferably, the peracid forming composition includes a chemical heater capable of releasing heat upon hydration. When placed in water, water enters the container and interacts with the peracid forming composition provided within the container. The water combines with the peracid precursor and peroxygen source to provide an aqueous peracid composition. The presence of a chemical heater within the container provides for the generation of heat within the container which enhances the rate of peracid formation. The peracid solution leaves the container and forms an effective sanitizing amount of sanitizer.

Abstract: The present invention relates to detergent compositions, including laundry, dishwashing, and/or hard surface cleaner compositions, comprising a cyclodextrin glucanotransferase enzyme and a detergent ingredient selected from a nonionic surfactant, a protease and/or a bleaching agent. Such compositions provide excellent removal of starch-containing stains and soils and malodor control; and when formulated as laundry compositions, excellent whiteness maintenance and dingy cleaning.

Abstract: Disclosed is a method of laundering soiled fabrics comprising the steps of contacting said fabric in an aqueous laundering solution with a nonaqueous liquid detergent composition containing from about 40% to about 99% by weight of the composition of a surfactant-containing non-aqueous liquid phase and from about 1% to about 50% by weight of the composition of particulate material which is substantially insoluble in said liquid phase and which is selected from peroxygen bleaching agents, bleach activators, organic detergent builders, inorganic alkalinity sources and combinations thereof. A dye transfer inhibitor and suds suppressors are essential components in one aspect of the present invention.

Abstract: 1 The invention concerns a solid composition substantially comprising between 5 and 98 parts by weight of heterocyclic compounds (I) R1—X—L1, wherein L1 stands for groups with a cyclic carbamate, a lactoneoxy or a lactam structure, X means a carbonyl, a double carbonyl or a heterocarbonyl group, and R1 designates an organic group or a second L1 group, and/or oxime esters (II), wherein L2 stands for an oxime group (a) or (b), R2, R3 and Z4 designating organic groups or bridge members, L3 stands for the R1 group, a second L2 oxime group or a carbon ester group, carbon amide group, phenolate group, vinyloxy group, sulphoneamide group, imidazole group, amidolactam group, cyclic carbamate group, lactoneoxy group or lactam group, and m means 0 or 1. The composition further comprises between 2 and 95 parts by weight of inert porous carrier materials with an internal area of between 10 and 500 m2/g.

Abstract: A bleaching composition for laundry fabrics is provided, comprising:

Abstract: The invention relates to catalytically bleaching substrates, especially laundry fabrics, with a bleaching composition and a peroxyl source.

Abstract: A bleaching composition for laundry fabrics is provided, comprising:

Abstract: Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.

Abstract: The present invention provides a process for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150, preferably from 1.5 to 75, especially from 7.

Abstract: The invention relates to a bleaching composition. In particular the invention provides a bleaching composition which comprises: (i) a bleaching agent, and (ii) as bleach catalyst, a polyoxometalate of Keggin, Dawson or Finke structure and having the general formula (II) (A′)a′(Cox′Yy′Mm′Oo).cH2O  (II)  wherein the or each A′, which may be the same or different, is a cation; a′ has a value such that (A′)a, counters the anionic charge of (Cox′Yy′Mm′Oo); x′ has a value of 0.25 to 4; the or each Y, which may be the same or different, represents P, Si or Co; y′ is 1 or 2; o has a value of 34 to 68; the or each M, which may be the same or different, represents W, Mo, V, Nb or Ta; m′ has a value of between 9 and 18; c has a value of between 0 and 84. The bleaching compositions according to the invention have good bleaching performance and can be used without a bleach activator, e.g.

Abstract: The present invention provides a bleaching detergent composition exhibiting a wide bleaching effect for various stains including hydrophilic stains and olephilic stains, as well as an high bleaching effect and dye-transfer inhibiting effect in a wide range of temperature from a low to a high temperature of laundry water. That is, the present invention provides a bleaching detergent composition comprising (a) an alkannitrile compound having a quaternary ammonium group bondeded to a carbon atom to which the nitrile group is bonded, (b) an inorganic peroxide and (c) an alkali metal carbonate and further comprising component (d-i) an alkanoyloxybenzenesulfonic acid having an alkanoyl group of 6 to 14 carbon atoms or an alkanoyloxybenzenecarboxylic acid having an alkanoyl group of 6 to 14 carbon atoms or a salt thereof and/or (d-ii) tetraacetylethylenediamine.

Abstract: There is provided a process for enhancing the activity of a phenol oxidizing enzyme, comprising adding to the enzyme, as an enhancer for the activity of the enzyme, one or more compounds having the formula: wherein: A is an optionally substituted electron-withdrawing group, chosen from the group consisting of nitrile, carboxyl, and esters and salts thereof, amides, aldehydes, ketones, sulfoxides, sulfones, or sulphonates, and B is an optionally substituted electron-donating group, chosen from the group consisting of the oxide anion, sulfide anion, oxides, amines, imines, hydroxides, sulfides, ethers, carboxylic acids, and halogen substituents, and R1-R5 may each independently represent hydrogen, hydroxy, halogen, nitroso, formyl, carboxyl, and esters and salts thereof, carbamoyl, sulfo, and esters and salts hereof, sulfamoyl, nitro, amino, phenyl, C1-C20 alkyl, C1-C8 alkoxy, carbonyl-C1-C6-alkoxy, aryl-C1-C6-alkyl, and R2 and R5 together may form an alkylene group or an alkenylene group.

Abstract: Laundry or cleaning composition comprising: a) an effective amount of a bleach activator and/or organic percarboxylic acid; b) a catalytically effective amount of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and c) at least about 0.1% of one or more laundry or cleaning adjunct materials. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts in combination with bleach activators and/or organic perearboxylic acids.

Abstract: Detergent formulations containing cationic nitriles are shown to exhibit enhanced stain removal, enhanced starchy soil removal and enhanced enzyme stability as compared to similar formulations containing TAED.

Abstract: A process is provided for the preparation of a compound having the structure of Formula I The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of pH control substantially prevents formation of an undesirable protonated reaction intermediate.

Abstract: A bleaching or washing composition comprising a peroxy compound and a specified cobalt compound is disclosed, as well as a process for bleaching or washing a fabric or dishes by contacting them with said bleaching or washing composition.

Abstract: A method for washing dishes containing colored soil is presented involving contacting the dish surface with a dishwashing detergent containing a peroxygen compound and an activator compound of the formula R1R2R3N+CH2CN X− where R1, R2 and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, and wherein R2 and R3 may be part of a heterocycle including the N atom, and X is an anion, to form an aqueous dishwashing detergent. The method is useful for washing colored stains from crockery and cutlery, and is effective at temperatures below 80° C.

Abstract: The storage stability of bleach-activating acetonitrile derivatives in solid detergent compositions was to be improved. This was essentially achieved by the use of compounded compounds corresponding to formula R1R2R3NxCH2CN X−, in which R1, R2 and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, in addition to which the groups R2 and R3 may even be part of a heterocycle including the N atom and optionally other hetero atoms, and X is a charge-equalizing anion. “Compounds” of this type are produced by drying in vacuo, for which purpose a suspension of the acetonitrile derivative and a solid carrier material is introduced into a mixer and the resulting mixture is dried with superheated vapor. Dishwashing detergents, more particularly machine dishwashing detergents, contain about 1% by weight to 10% by weight of this bleach boosting compound.

Abstract: Detergent formulations containing cationic nitriles are shown to exhibit reduced silver tarnishing as compared to similar formulations containing TAED.

Abstract: Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source.

Abstract: A detergent bleaching composition is provided comprising a compound inclug a specified pentadentate nitrogen-containing ligand. The compound can activate hydrogen peroxide or peroxyacids and provides favourable stain removal properties, particularly in the presence or iron, manganese or copper ions. In addition, an improved stability in alkaline aqueous environment has been obtained, in particular at the peroxy compound concentrations generally present in the fabric washing liquor.

Abstract: A nonaqueous liquid detergent composition comprising a bleach precursor composition comprising: a) a bleach precursor; and b) a surfactant system; and c) an organic acid.

Abstract: A bleaching agent composition comprising (A) hydrogen peroxide or a peroxide which generates hydrogen peroxide in an aqueous solution, and (B) an addition reaction product of dicyandiamide and a glycidyl ether compound, wherein the pH of the mixed aqueous solution of compound (A) and components (B) becomes at least 7.5.

Abstract: The bleaching detergent composition in a form of granules or powders containing an organic peracid precursor which produces an organic peracid upon reaction with hydrogen peroxide in water, the organic peracid having an alkyl group with 7 to 19 carbon atoms, and a hydrogen peroxide releasing material, wherein the bleaching detergent composition comprises the following components a) to c): a) one or more surfactants; b) one or more crystalline alkali metal silicates; and c) one or more agents for capturing metal ions other than the crystalline alkali metal silicates b), wherein a total amount of the above a), b), and c) components in the bleaching detergent composition occupies from 70 to 99% by weight, and wherein the weight ratio of component b) to component a) is b/a=90/10 to 45/55, and the weight ratio of component b) to component c) is b/c=7/93 to 75/25, and wherein the weight ratio of the organic peracid precursor to nonionic surfactants used as component a) is from 10/90 to 70/30.

Abstract: Described are complexes of the transition metals manganese, iron, cobalt, ruthenium, molybdenum, titanium, vanadium and/or copper containing one or more ligands of general formula (I) ou (II)in which R is a direct bond or an optionally amin-group-substituted alkylene group with 1 to 4 C-atoms, A is a condensed or non-condensed ring system containing at least one nitrogen atom, B is hydrogen, an OH-group or the same as A, and X is a phenyl ring optionally substituted with and/or C.sub.1-4 alkyl or an optionally hydroxy-substituted C.sub.1-4 alkylene group. The complexes are suitable for use as activators or peroxy compounds in oxidative washing, cleaning and disinfectant solutions, washing and cleaning agents preferably containing 0.0025 to 0.25% by wt. of such activator complexes.

Abstract: A bleach and oxidation catalyst is provided comprising a catalytically ace iron, manganese or copper complex including a specified pentadentate nitrogen-containing ligand. The metal complex can activate hydrogen peroxide or peroxyacids and provides favourable stain removal properties. In addition, a considerably improved stability of these metal complex compounds in alkaline aqueous environment has been obtained, in particular at the peroxy compound concentrations generally present in the fabric washing liquor.

Abstract: Detergent compositions and fabric laundering and treating methods utilize certain polyamide-polyamines as fabric treatment agents that can impart fabric appearance benefits to fabric laundered or treated in washing or soaking solutions which contain such agents. Such polyamide-polyamine fabric treatment agents include adipic acid-diethylenetriamine-epichlorohydrin adducts.

Abstract: The invention relates to coated bleach activator granules of ammonium nitriles, which have been obtained by coating ammonium nitrile base granules with a water-soluble coating substance. The base granules are preferably thermally conditioned during or after the coating with the coating substance.

Abstract: Use of amines as bleaching efficiency boosters for textile detergent compositions, where the pK.sub.a of the amines is greater than the pH minus 1, preferably greater than the pH, particularly preferably at least 0.5 greater than the pH of the 1% by weight wash liquor obtained from the textile detergent composition.

Abstract: The present invention relates to laundry detergent compositions which comprise an alkoxylated polyalkyleneimine soil dispersant having the formula: ##STR1## wherein R is C.sub.2 -C.sub.6 linear alkylene, C.sub.3 -C.sub.6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:--(R.sup.1 O).sub.m (R.sup.2 O).sub.n R.sup.3wherein R.sup.1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R.sup.2 is ethylene; R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x, and y are each independently from about 4 to about 200; provided at least one --(R.sup.1 O) unit is attached to the backbone prior to attachment of an --(R.sup.2 O) unit and further provided m+n is at least 12, said dispersants are compatible with bleach. The disclosed alkoxylated polyalkyleneimines are also suitable for use as soil dispersant in bleach-containing laundry pre-soaks and bleaching agents.

Abstract: A process for decolorizing a cellulose textile bearing oxidized vat dye comprising contacting the cellulose textile with an aqueous solution of hydrogen peroxide containing an amount of a hydrogen peroxide catalyst sufficient to oxidize vat dye in the fabric until the dye is decolorized by oxidation. Then the cellulose textile is separated from the aqueous solution. The hydrogen peroxide catalyst can be a water-soluble lower alkyl quaternary amine salt such as a dihydroxypropyltrimethylammonium halide, chlorohydroxypropyltrimethylammonium halide or epoxypropyltrimethylammonium halide, or it can be a transition metal ion such as a cupric or stannous metal ion present in an amount of from 0.1 to 2 ppm. The process is suitable for decolorizing denim bearing vat dyes such as indigo, and is particularly suitable for decolorizing denim scrap.

Abstract: Use of compounds of the formula ##STR1## where the radicals R.sup.1, R.sup.2 and A are as defined in the description, as bleach activators in bleaching detergents and cleaners.

Abstract: Compositions and methods for removing soils and stains from fabrics and other surfaces employ bleaching activators and aminotrimethylenephosphonic acid (ATMP) at a pH of from greater than 0 to about 6. Compositions comprising ATMP and various sources of peroxide and various types of activators are disclosed.

Abstract: A process for making a coated bleach component which may be incorporated into a detergent composition comprising hydrogen peroxide solution. The process includes the steps of dispersing the bleach component in a continuous liquid phase to form discrete islands of dispersed phase and subsequently forming a polymeric coating at the interface between the dispersed phase and the continuous phase. The coating formed is resistant to hydrogen peroxide solution and is removable when the liquid continuous phase is diluted with aqueous wash liquor. In this way particulate material which reacts with hydrogen peroxide can be incorporated into an aqueous detergent liquid which contains dissolved hydrogen peroxide, whilst maintaining stability.

Abstract: A composition containing: (a) a peroxygen compound; and (b) an activator compound corresponding to formula I: ##STR1## wherein R is hydrogen, an aryl, alkyl, alkenyl or cycloalkyl group containing 1 to 17 carbon atoms, n is a number from 1 to 8, A, B and Y, independently of one another, represent hydrogen, an aryl, alkyl, alkenyl or cycloalkyl group containing 1 to 17 carbon atoms or a hydrophilic group selected from the group consisting of --SO.sub.3 H, --OSO.sub.3 H, --PO(OH).sub.2, --OPO(OH).sub.2, --CO.sub.2 H and anions thereof and --N.sup.+ R.sup.1 R.sup.2 R.sup.3 X.sup.-, where R.sup.1, R.sup.2 and R.sup.3, independently of one another, represent hydrogen, an aryl, alkyl, alkenyl or cycloalkyl group containing 1 to 17 carbon atoms and X.sup.- represents a charge-equalizing anion, and wherein at least one of the substituents A, B or Y in the molecule is one of the hydrophilic groups.

Abstract: A liquid composition, comprising: (A) a peroxygen bleach, or a source thereof, (B) a liquid hydrophobic bleach activator, the liquid hydrophobic bleach activator being acetyl triethyl citrate, (C) a long chain acyl sarcosinate; (D) the composition having a pH from 0 to 6; and (E) the composition being formulated either as an emulsion or as a microemulsion.

Abstract: The present invention relates to liqiuid compositions comprising a peroxygen bleach and a specific polyamine, or mixtures thereof. The present invention further encompasses a process for pretreating soiled fabrics and/or soiled colored fabrics, for reducing the color damage of said colored fabrics and/or for reducing the loss of tensile strength in said fabrics.

Abstract: The invention herein provides bleaching compositions comprising a protease enzyme which is a carbonyl hydrolase variant having an amino acid sequence not found in nature, which is derived by replacement of a plurality of amino acid residues of a precursor carbonyl hydrolase with different amino acids, wherein said plurality of amino acid residues replaced in the precursor enzyme correspond to position +76 in combination with one or more of the following residues: +99, +101, +103, +104, +107, +123, +27, +105, +109, +126, +128, +135, +156, +166, +195, +197, +204, +206, +210, +216, +217, +218, +222, +260, +265, and/or +274, where the numbered positions corresponds to naturally-occurring subtilisin from Bacillus amyloliquefaciens or to equivalent amino acid residues in other carbonyl hydrolases or subtilisins (such as Bacillus lentus subtilisin) and a bleaching agent.

Abstract: Acylated carbohydrates with at least one carboxyalkyl group etherified with the carbohydrate of the following general formulaKH(--O--CHR.sub.1 --(CH.sub.2).sub.p --(COOH or COO.sup.-)).sub.n (--O--CO--R.sub.2).sub.m,wherein KH (carbohydrate) is a monosaccharide, disaccharide, trisaccharide or polysaccharide, and whereinif KH is a monosaccharide, then n=1 to 4 and m=1 to 4 with n+m=2 to 5;if KH is a disaccharide, then n=1 to 7 and m=1 to 7 with n+m=2 to 8;if KH is a trisaccharide, then n=1 to 10 and m=1 to 10 with n+m=2 to 11; andif KH is a polysaccharide, then n=0.2 to 2.8 and m=0.2 to 2.8 with n+m=0.4 to 3 (with polysaccharide referred to the monosaccharide unit of the KH), and whereinR1 is=H or a moiety with 1-9 carbon atoms, in particular an alkyl or acyl moiety, andR2 is a moiety with 1-9 carbon atoms, in particular an alkyl or acyl moiety, and wherein p=0 to 9.

Abstract: The invention provides liquid cleaning or bleaching compositions containing compounds having the structure of Formula I ##STR1## wherein A is a saturated ring formed by five atoms in addition to the N.sub.1 atom, the five saturated ring atoms being four carbon atoms and a heteroatom, the substituent R.sub.1 bound to the N.sub.1 atom of the Formula I structure including either (a) a C.sub.1-24 alkyl or alkoxylated alkyl where the alkoxy is C.sub.2-4, (b) a C.sub.4-24 cycloalkyl, (c) a C.sub.7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C.sub.2-4, or (e) --CR.sub.2 R.sub.3 CN where R.sub.2 and R.sub.3 are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, the R.sub.2 and R.sub.3 substituents are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.

Abstract: A bleaching composition comprising a peroxygen bleaching compound and preferably a bleach activator. When nitrone scavengers are used in such composition, dye and/or fabric damage caused by radical generations of the peroxygen bleach (e.g., through thermal or transmit ion metal catalyzed degradation) can be minimized.

Abstract: This invention relates to a method of improving the stability of a bleach and lipophile composition comprising an inorganic persalt bleaching agent and a lipophile selected from the group consisting of flavorants, perfumes, coolants, antimicrobial agents, and mixtures thereof, by inclusion of an aminoalkylsilicone, having an aminoalkylsiloxane content of from about 0.1% to 2% on a repeating unit basis.