Abstract: A built particulate laundry detergent composition containing anionic sulphonate or sulphate surfactant and conventional ethoxylated alcohol nonionic surfactant also contains a low level of a highly ethoxylated alcohol nonionic surfactant having an average degree of ethoxylation of from 15 to 40, and a low level of a textile softening clay. The composition exhibits increased mildness to the skin without loss of detergency performance, and the softness of washed fabrics is significantly improved despite the low level of softening clay present.

Abstract: The present invention provides a liquid detergent composition being excellent in detergency and dispersion stability and a process for producing the same. The invention provides a liquid detergent composition having a degree of separation by volume of 5% or less after storage for 1 month at 25° C., comprising a liquid phase as the phase (a), a polymeric dispersant as the component (b)] and at least one selected from the group consisting of a crystalline silicate compound and an aluminosilicate compound as the component (c), wherein the component (b) has a cation exchange capacity of not less than 120 CaCO3 mg/g when the water content of the composition is 5% by weight or less and then the aluminosilicate compound only is used as the component (c) or when the water content of the composition is larger than 5% by weight.

Abstract: Rinse aid materials for coating, coating compositions, methods and articles of manufacture for use in automatic dishwashing appliances comprising a nanoparticle system or employing the same to impart surface modifying benefits for all types of dishware surfaces are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of rinse aid surface coating compositions, methods and articles of manufacture that create multi-use benefits to modified dishware surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that include at least one of the following improved surface properties: wetting and sheeting, uniform drying, anti-spotting, anti-staining, anti-filming, self cleaning, and durability benefits, relative to dishware surfaces unmodified with such nanoparticle systems.

Abstract: The present invention provides a process for preparation of a chelant composition by a non-spray-drying process, a process for improving one or more of flowability and scoopability of a laundry detergent composition, and a chelant agglomerate useful as an ad-mix in a particulate laundry detergent. In one aspect of the present invention, the process for preparation of a chelant composition by a non-spray-drying process includes the steps of admixing a transition metal chelant and an inorganic compound to form a mixture, aglomerating the mixture in an aqueous medium to form a chelant agglomerate and drying the chelant agglomerate.

Abstract: The present invention relates to a liquid enzyme cleaning composition in which the enzyme is stable at alkaline pH and in the presence of water at concentrations of at least about 50 to about 60 weight percent. In one embodiment, the composition of the invention stabilizes the enzyme with potassium borate.

Abstract: The invention provides a detergent composition comprising from 0.5 to 60% by weight of an agglomerate comprising from 35 to 68% by weight of the agglomerate of a crystalline layered silicate, from 32 to 55% by weight of the agglomerate of an anionic surfactant and comprising less than 10% by weight of the agglomerate of free moisture.

Abstract: A detergent composition containing an inexpensive detergent builder in the form of a selected crystalline calcium carbonate is provided. Specifically, the crystalline calcium carbonate has a substantially rhombohedral crystal structure with {1,0-1,1} crystallographic indices. The crystalline calcium carbonate can be calcite that has been specially modified to a rhombohedral crystal structure with {1,0-1,1} indices. The crystalline calcium carbonate of the present invention is extremely inexpensive because it can be readily formed from inexpensive naturally occurring calcite, and it performs well even when used at large median particle sizes.

Abstract: Modified starch encapsulated oil particles, and a process for making said particles and products comprising such particles are disclosed. Such particles provide a simple, efficient and effective delivery system that can be used to deliver oils to compositions.

Abstract: A detergent tablet containing a nonionic surfactant having a melting point above ambient temperature is suitable for use in an automatic dishwasher or laundry washing machine. Additionally, a process for making a detergent tablet containing such a nonionic surfactant is described.

Abstract: A multifunctional detergent material, useful in laundry and cleaning product compositions, containing functional ingredients including a condensed phosphate material and a silicate material, and optionally other inorganic materials, such as carbonate and sulfate. The condensed phosphate material forms an amorphous phase containing polyphosphates, while the silicate material is present as crystalline particulate. The composition can be used to provide multiple functions for laundry and cleaning products in a single ingredient, including the functions of a builder, a filler, and an alkaline source.

Abstract: The present invention pertains to a composite powder comprising (A) an alkali metal silicate particle having an average particle size of from 1 to 500 &mgr;m; and (B) a water-soluble salt particle having an average particle size of from 0.01 to 50 &mgr;m, of which solubility to water at 20° C. is 1 g/100 g or more, wherein the alkali metal silicate particle has a composition formula in an anhydride form represented by: xM2O.ySiO2.zMeO (I) wherein M stands for Na and/or K; Me stands for Ca and/or Mg; y/x is from 0.5 to 4.0; z/x is from 0 to 1.0; and Mg/Ca in MeO is from 0 to 10, and wherein the composite powder has a (A)/(B) weight ratio of from 1/9 to 99/1; and a detergent composition comprising the composite powder. The composite powder is a composite powder having a remarkably enhanced storage stability of the alkali metal silicate without impairing the ion exchange capacity owned by the alkali metal silicate.

Abstract: The invention relates to cogranulates comprising phyllosilicates and disintegrants, in particular cellulose, and to detergents and cleaners which comprise these cogranulates, preferably in tablet form.

Abstract: The invention relates to a granular alkali metal phyllosilicate compound which comprises a crystalline alkali metal phyllosilicate, a colorant and an additive. The invention also relates to a process for its preparation, and to detergents and cleaners which comprise such a granular alkali metal phyllosilicate compound.

Abstract: The invention relates to a crystalline alkali metal phyllosilicate of the formula aMI2O.bEO2.cX2O5.dZO3.SiO2.eH2O, in which MI is an alkali metal, E is an element of the fourth main group, X is an element of the fifth main group and Z is an element of the sixth main group of the Periodic Table of the Elements and the following also applies: 0.25≦a≦6.25 2.5·10−4≦b≦5.63 0≦c≦2.81 0≦d≦5.63 0≦e≦15.3. The invention also relates to a process for the preparation of this crystalline alkali metal phyllosilicate and also to detergents and cleaners which comprise the crystalline alkali metal phyllosilicate according to the invention.

Abstract: A particulate zero-phosphate laundry detergent powder, preferably of bulk density 600-900 g/l, contains zeolite MAP and zeolite A in a weight ratio of at least 1:1. The powder may contain at least two different granular components containing organic surfactant and zeolite builder. A first granular component, which is preferably non-spray-dried and has a bulk density of 550-900 g/l, contains zeolite MAP, while a second granular component, which is preferably spray-dried and has a bulk density of 200-450 g/l, contains zeolite A.

Abstract: This invention relates to detergent compositions having significantly improved calcium sequestration capacity as well as superior builder capacity in comparison to conventional aluminosilicate builder materials, while not redepositing on fabrics. More particularly, this invention relates to detergent compositions comprising microclusters of submicron crystallites of an aluminosilicate ion exchange material.

Abstract: A granular surfactant composition comprising sodium silicate and linear alkylbenzenesulfonates, wherein the granular surfactant composition has a mean particle diameter of ≧50 &mgr;m and an ffc value of ≧7; a process for the preparation of this granular surfactant composition, its use, and detergents and cleaners which comprise such granular surfactant composition and a process for the making of the same; and, where appropriate, the granular surfactant composition comprises other active ingredients and auxiliaries.

Abstract: The invention of this application aims to offer the detergent composition that does not destroy natural ecosystem or pollute air, as the detergent contains neither organic synthetic surfactant that pollutes environment, rivers and lakes nor petroleum volatile solvent that is the source of air pollution. The invention of this application concerns the detergent composition and manufacturing methods of said detergent. The detergent composition contains at least one or more species of sodium (III) phosphate, sodium metasilicate, sodium sulfate, sodium tripolyphosphate, sodium chloride, sodium carbonate, potassium chloride, trisodium citrate and sodium hydroxide.

Abstract: The invention relates to a finely divided crystalline layered sodium disilicate of the formula NaMSixO2x+1.yH2O, where M is sodium or hydrogen, x is a number from 1.9 to 4, and y is a number from 0 to 20, which comprises from 0 to 40% by weight of alpha-disodium disilicate from 0 to 40% by weight of beta-disodium disilicate from 40 to 100% by weight of delta-disodium disilicate from 0 to 40% by weight of amorphous components, to a process for its preparation and to its use.

Abstract: An acrylic polymer containing at least one terminal group of general formula (I), in the molecule and having a number-average molecular weight of 300 to 100,000; and a process for the preparation of the polymer, (where R1 is hydrogen or methyl; and X1 is hydrogen, alkali metal or ammonium) The invention provides acrylic polymer free from discoloration, excellent in chelating power, and biodegradable, a builder comprising the polymer, a detergent composition comprising the builder and a surfactant, a dispersant comprising a salt of the polymer, and processes for preparing them efficiently.

Abstract: The invention provides a water-soluble, water-softening builder in the form of a tablet comprising 40-98% by weight of a combination of a) one or more organic, multifunctional polycarboxylic acid(s) or alkali metal salts thereof, and b) a polymer with water-softening properties in an a:b weight ratio of from 80:20 to 50:50, where the polymer with water-softening properties is a partially neutralized polyacrylic acid having a molecular weight of 1500-8000.

Abstract: A water-containing solid detergent having a delayed, controllable and variable hardening time after addition of all the components produced by providing a) aqueous 42 to 55% lye, in a quantity of 21 to 70% by weight, b) mixing with the aqueous lye a compound selected from the group corresponding to formula (I): HOCH2CH(R1)OR2  (I) in which R1 is a hydrogen atom or a methyl group and R2, independent of R1, is a hydrogen atom, a C1-4 alkyl group, a group CH2CH(R3)0R4 or a group CH2CH(R5)OCH2—CH(R6)OR7, where R3, R5, and R6 represent hydrogen atoms or methyl groups and R4and R7 represent hydrogen atoms or C1-4 alkyl groups, and compounds corresponding to formula II: [HOCH2CH(R8)3−xNHx  (II) in which R8 is a hydrogen atom or a methyl group and x is the number 0, 1 or 2, in a total quantity of 0.

Abstract: A particulate laundry detergent composition having a bulk density of 550 to 900 g/l comprises at least two different granular multiingredient components. A first granular component (preferably non-spray-dried) has a bulk density of 550 to 1000 g/l and has a weight ratio of a first ingredient type to a second ingredient type of r; a second granular component (preferably spray-dried) has a bulk density of from 300 to 550 g/l and has a weight ratio of the first ingredient type to the second ingredient type of r′, wherein the ratio of r to r′ is within the range of from 1.25:1 to 1:1.25.

Abstract: Rinsing dyed or white fabrics in a chelator-containing rinse bath restores color and brightness. Rinse added compositions comprising chelators such as diethylenetriaminepentaacetate or ethylenediamine disuccinate are used to restore the appearance of colored and white fabrics whose drab appearance has been caused by interactions with metal ions, especially copper and nickel. Compositions comprising the chelators in combination with fabric care auxiliaries such as fabric softeners, cellulase enzymes and chlorine scavengers are provided.

Abstract: An automatic dishwashing detergent composition is described which contains an effective amount of a defined water soluble cationic or amphoteric polymer and a phosphate or nonphosphate builder. The polymers are soluble or dispersible to at least 0.01% by weight in distilled water at 25° C. A method of using the polymers to prevent fading or corrosion of dishware is also described.

Abstract: A powdery detergent composition having a high detergency and an excellent storage stability (caking resistance), and comprising (a) a chelating agent composed of a compound having an average degree of neutralization in a molecule of 20 to 70%, a molecular weight of 600 or less, the number of carboxyl groups contained in one molecule of 3 to 5, and a constant of a chelating stability with Ca2+ of 6 to 13, (b) an alkali agent composed of a compound a 0.1% by weight aqueous solution or dispersion of which has the maximum pH of 10 or more at 20° C., at least 5 ml of 0.1 N HCl aqueous solution being required to adjust 1 liter of the aqueous solution or the dispersion to pH 9, and (c) a surfactant at specific ratios, respectively.

Abstract: A particulate free-flowing laundry detergent composition comprises at least two different granular components: a granular component containing anionic surfactant, and a granular nonionic surfactant component comprising from 20 to 30 wt % of nonionic surfactant on a non-spray-dried particulate carrier material comprising sodium sesquicarbonate. The nonionic surfactant component is preferably prepared by in-situ neutralisation of sodium carbonate with a water-soluble organic acid in the presence of the nonionic surfactant, in a high- or moderate-shear mixer.

Abstract: A paste-form detergent for use in institutional laundries free from synthetic anionic surfactant of the alkyl benzenesulfonate type containing 5% to 30% by weight of an ethoxylated alcohol corresponding to formula (I): R1—(OC2H2)m—OH   (I) in which R1 is an alkyl or alkenyl group containing 12 to 14 carbon atoms and m has a value of 1 to 8, 1% to 20% by weight of an ethoxylated alcohol corresponding to formula (II): R2—(OC2H2)n—OH   (II) in which R2 is an alkyl or alkenyl group containing 12 to 22 carbon atoms and n has a value of 3 to 14, with proviso that n is greater than m by at least 1.

Abstract: A solid textile detergent formulation comprises (A) from 1 to 30% by weight of inorganic builders based on carbonates, (B) from 0 to 12% by weight of inorganic builders based on crystalline or amorphous alumosilicates and/or crystalline or amorphous silicates, (C) from 0 to 5% by weight of inorganic builders based on phosphates, (D) from 1 to 40% by weight of one or more glycine-N,N-diacetic acid derivatives I where R is an organic radical and M is hydrogen or a cation, as organic builder component, (E) from 0 to 40% by weight of anionic surfactants and (F) from 0.5 to 50% by weight of nonionic surfactants.

Abstract: The invention relates to a solid textile detergent formulation containing (A) 1-60 wt. % inorganic builders based on crystalline or amorphous aluminosilicates, crystalline or amorphous silicates, carbonates and/or phosphates, (B) 1-40 wt. % of one or several glycin-N, N-diacetic acid derivatives of formula (I), wherein R stands for an organic radical and M means hydrogen or a cation, (C) 0-6 wt. % anionic surfactants with one or several sulphate groups, one or several sulphate groups or one or two carboxylate groups and (D) 0.5-50 wt. % non ionic surfactants.

Abstract: The storage stability of bleach-activating acetonitrile derivatives in solid detergent compositions was to be improved. This was essentially achieved by the use of compounded compounds corresponding to formula R1R2R3NxCH2CN X−, in which R1, R2 and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, in addition to which the groups R2 and R3 may even be part of a heterocycle including the N atom and optionally other hetero atoms, and X is a charge-equalizing anion. “Compounds” of this type are produced by drying in vacuo, for which purpose a suspension of the acetonitrile derivative and a solid carrier material is introduced into a mixer and the resulting mixture is dried with superheated vapor. Dishwashing detergents, more particularly machine dishwashing detergents, contain about 1% by weight to 10% by weight of this bleach boosting compound.

Abstract: A high-density powdered detergent composition which has a bulk density of 0.6 to 1.2 g/ml and which comprises 0.5 to 30% by weight of (a) a glycine-N,N-diacetic acid derivative, 5 to 45% by weight of (b) a nonionic surfactant having an HLB value of 10.5 to 15.0, 0.5 to 18% by weight of (c) an anionic surfactant and 1 to 30% by weight of (d) an aluminosilicate, each percentage being based on the total weight of the composition, and the weight ratio of the component (b) to the component (c) lying between 90:1 and 60:40. This composition contains both a glycine-N,N-diacetic acid derivative which is a builder excellent in biodegradability and sequestering power and an inorganic builder such as zeolite or crystalline silicate, and exhibits high detergency.

Abstract: A granular detergent composition which includes a surfactant system containing linear alkylbenzene sulfonate, acyclic quaternary ammonium salt, alkyl sulfate and alkyl ethoxy sulfate surfactants in selected molar ratios is provided. The composition has improved performance in cold temperature (i.e., 5° C. to 30° C.) laundering operations.

Abstract: An aqueous alkaline composition for cleaning equipment used in the food industry wherein the composition contains potassium hydroxide or a mixture of potassium hydroxide and sodium hydroxide and wherein the potassium hydroxide is present in an amount of at least 20% by weight, based on the weight of hydroxide present in the composition. A process for regenerating the cleaning solution is also disclosed.

Abstract: Fabrics are laundered in detergent compositions containing a mixture of &agr;-amylase enzymes to remove malodorous materials.

Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled metal surfaces such as food fryers, baking pans, high temperature pasteurizers, and beer kettles, ceramic surfaces such as restaurant grade ceramic china plates and platters, and plastic surfaces. The cleaning composition is noncaustic and includes a peroxygen compound, a chelate, and a metasilicate and/or sesquisilicate. A preferred cleaning composition further includes a surfactant and hydrated builder.

Abstract: A granular detergent composition is provided. The detergent composition comprises at least about 1% by weight of a surfactant and at least about 1% by weight of a builder. The detergent composition also includes from about 6 to about 9% of a particulate foam control agent. In addition, the detergent composition includes from about 0.1 to about 10% of hydrated magnesium sulfate, from about 0.05 to about 0.4% of a protease enzyme, and from about 0.05 to about 0.2% of a cellulase enzyme. The detergent composition produces the low level of foam required for optimal cleaning in washing machines employing a low water wash process.

Abstract: The present invention relates to a novel alkali stable amylase obtained from Thermoalcalibacter bogoriae, an enzyme composition comprising said amylase, and the use of said enzyme and enzyme composition for a number of industrial applications.

Abstract: Foam control granules, for use in particulate laundry detergent compositions, comprise a mobile hydrophobic foam control agent, preferably silicone oil in admixture with hydrophobic silica, optionally combined with a mixture of a hydrocarbon such as petroleum jelly and an alkylphosphoric acid salt, sorbed onto a porous absorbent inorganic carrier comprising or consisting of anhydrous sodium carbonate, preferably light soda ash. When such granules are prepared by mixing and granulating in a high shear mixer/granulator, the addition of from 1 to 10 wt % water after mixing and granulation results in granules having improved flow properties.

Abstract: Process for making a free-flowing, particulate dye transfer inhibiting detergent admix for inclusion in a granular laundry detergent composition consisting essentially of the steps of: charging from 50% to 95%, by weight of the dye transfer inhibiting detergent admix, of a detergent builder into a mixer/granulator; adding to the detergent builder from 5% to 50%, by weight of the dye transfer inhibiting detergent admix, of a dye transfer inhibitor solution to thereby form a mixture; and agglomerating the mixture of the dye transfer inhibitor solution and the detergent builder so as to form the dye transfer inhibiting detergent admix.

Abstract: Acylated carbohydrates with at least one carboxyalkyl group etherified with the carbohydrate of the following general formulaKH(--O--CHR.sub.1 --(CH.sub.2).sub.p --(COOH or COO.sup.-)).sub.n (--O--CO--R.sub.2).sub.m,wherein KH (carbohydrate) is a monosaccharide, disaccharide, trisaccharide or polysaccharide, and whereinif KH is a monosaccharide, then n=1 to 4 and m=1 to 4 with n+m=2 to 5;if KH is a disaccharide, then n=1 to 7 and m=1 to 7 with n+m=2 to 8;if KH is a trisaccharide, then n=1 to 10 and m=1 to 10 with n+m=2 to 11; andif KH is a polysaccharide, then n=0.2 to 2.8 and m=0.2 to 2.8 with n+m=0.4 to 3 (with polysaccharide referred to the monosaccharide unit of the KH), and whereinR1 is=H or a moiety with 1-9 carbon atoms, in particular an alkyl or acyl moiety, andR2 is a moiety with 1-9 carbon atoms, in particular an alkyl or acyl moiety, and wherein p=0 to 9.

Abstract: Iminodisuccinic acids of the formula ##STR1## the substituents of which have the meaning given in the description, are bleaching regulators in H.sub.2 O.sub.2 bleaching of textile-forming natural plant fibers or silk, wool and their mixtures with synthetics.

Abstract: Novel magnesiosilicate compounds for use in detergent compositions and as water softeners have a calcium binding capacity of at least 10 mg CaO per gram, a magnesium binding capacity of at least 10 mg MgO per gram and a calcium binding rate of no more than 300 seconds, all at room temperature. The compounds have a stuffed silica polymorph-related structure or a layered structure with a broad X-ray powder diffraction peak at a d-spacing of between 11 and 17 .ANG.. The compounds have an anhydrous composition M.sub.a Mg.sub.b Al.sub.c Si.sub.1-(b+c) O.sub.d, where M--alkali, 0.0<a<2.0, 0.0<b<0.7, 0.0.ltoreq.c.ltoreq.0.3, 1.15<d<3.0, c<b, and partial substitution of M, Mg, Al and Si is permitted.

Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled metal surfaces such as food fryers, baking pans, high temperature pasteurizers, and beer kettles, ceramic surfaces such as restaurant grade ceramic china plates and platters, and plastic surfaces. The cleaning composition is noncaustic and includes a peroxygen compound, a chelate, and an alkali salt in both hydrated and anhydrous forms. A preferred cleaning composition further includes a surfactant.

Abstract: The present invention relates to detergent compositions comprising one or more enzymes which are immobilized by a covalent binding on an activated polymer. Such enzymes are preferably bound to the activated polymer via a spacer molecule. The enzymes are selected from a variety of enzymes including, for example, cellulases, hemicellulases, peroxidases, proteases, glucoamylases, amylases, lipases, cutinases, pectinases, reductases, oxidases, phenoloxidases, lipoxygenases, laccases, ligninases, pullulanases, xylanases, tannases, pentosanases, manlanases, .beta.-glucanases, arabinosidases, and mixtures thereof. The polymer is selected from a variety of polymers. A preferred polymer for use in the present invention is polyethylene glycol.

Abstract: Detergent compositions comprising aminodicarboxylic acid-N,N-dialkanoic acid or its salt (component A) and a synthetic surface active agent having microbial degradability (component B).In particular, in the case where an alkali salt of polyoxyalkylene alkylether acetic acid or alkyl polyglycoside is used as the surface active agent (component B), the detergent compositions exhibit excellent washing effect without forming metallic soap even in washing water with high hardness, and also show high solubility even under the condition of low water temperature, and have excellent microbial degradability. Thus, the detergent compositions are particularly suitable for washing fabrics. Further, in the case where synthetic anionic and/or nonionic surface active agent is used as the surface active agent (component B), influence of corrosion to light metals is small.

Abstract: The invention is an improved, non-phosphate, non-bleach, agglomerated laundry booster which has a) a solids portion with i) at least 5% by weight of a first builder selected from the group consisting of alkali metal carbonate, alkali metal bicarbonate, alkali metal sesquicarbonate, and mixtures thereof; and ii) a second builder of at least 25% by weight alkali metal tetraborate pentahydrate; and b) i) a first liquid which comprises an anionic, acidic surfactant, in an amount no greater than about 10% by weight; and ii) a second liquid which comprises an agglomerating agent. The first liquid is neutralized by the first builder of a)i) to form a first set of particles, the second builder forms a second set of particles, and the second liquid co-agglomerates both the first and second sets of particles. The invention also provides a method for preparing this laundry booster.

Abstract: Detergent builder/activators which can be produced from renewable resources are provided. The detergent builder/activators are obtainable by a process comprising subjecting a poly(saccharide) comprising a vicinal diol moiety to the independent steps of a) oxidative cleavage of a vicinal diol moiety with an oxidizing agent for vicinal diols to introduce carboxylic acid functionality, and b) acylation with an acylating agent.

Abstract: Pulverulent detergent compositions, particularly suitable for washing and dishwashing machines, include a surfactant and a builder therefor, such builder comprising an alkali metal silicate advantageously having a SiO.sub.2 /M.sub.2 O molar ratio ranging from about 1.6 to 3.5, at least 30% and preferably at least 50% of the silicon atoms of which being in the Q.sub.2 and Q.sub.3 configurations, or such builder comprising said alkali metal silicate sorbed onto a particulate inert support substrate. Also, detergent compositing comprising (a) an aqueous solution of an alkali metal silicate having an SiO.sub.2 /M.sub.2 O molar ratio ranging from about 1.

Abstract: A solid textile detergent formulation, comprising(A) 1-60% by weight of inorganic builders based on crystalline or amorphous aluminosilicates, crystalline or amorphous silicates, carbonates and/or phosphates,(B) 0.1-25% by weight of one or more glycine-N,N'-diacetic acid derivatives I ##STR1## where R is an organic radical and M is hydrogen or a cation, as organic cobuilders,(C) 1-40% by weight of anionic surfactants and(D) 0.5-30% by weight of nonionic surfactants.