The Compound Contains Ether Group (e.g., Polyethylene Oxide) Patents (Class 516/191)
  • Patent number: 8940832
    Abstract: The invention relates to polymers that can be obtained by polymerizing the monomers (A), (B), and (D), and optionally (C), where (A) is a monomer of formula (I), wherein A stands for C2 to C4 alkylene, B stands for a C2 to C4 alkylene different from A, R stands for hydrogen or methyl, m stands for a number from 1 to 500, n stands for a number from 1 to 500, (B) is an ethylenically unsaturated monomer that contains at least one carboxylic acid function, (C) is optionally a further ethylenically unsaturated monomer different from (A) and (B), (D) is a monomer of formula (II), wherein D stands for C2 to C4 alkylene, E stands for a C2 to C4 alkylene group different from D, F stands for a C2 to C4 alkylene group different from E, R stands for hydrogen or methyl, o stands for a number from 1 to 500, p stands for a number from 1 to 500, q stands for a number from 1 to 500, and wherein the weight fraction of the monomers is 35 to 99% for the macromonomer (A), 0.
    Type: Grant
    Filed: February 15, 2011
    Date of Patent: January 27, 2015
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Carsten Schaefer, Oliver Mogck
  • Patent number: 8920543
    Abstract: The invention provides for the use of copolymers comprising 1 to 99 mol % of structural units of the formula (1) in which R1 is hydrogen or C1-C6-alkyl, A is C2-C4-alkylene groups and B is C2-C4-alkylene groups, with the proviso that A is different than B, and x, y are each independently an integer of 1-100, and 1 to 99 mol % of structural units of the formula (3) in which R6 is hydrogen or C1-C6-alkyl, D is C2-C4-alkylene groups and z is an integer of 1-50, in amounts of 0.01 to 2% by weight, based on the water phase, as gas hydrate inhibitors.
    Type: Grant
    Filed: April 27, 2011
    Date of Patent: December 30, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Dirk Leinweber, Alexander Roesch, Carsten Schaefer, Alexander Woerndle
  • Patent number: 8920542
    Abstract: The invention relates to the use of polymers, containing between 1 and 100 mol % of structural units of the formula (1), wherein R1 means hydrogen or C1-C6 alkyl, A means C2-C4 alkylene groups, and B means C2-C4 alkylene groups, with the stipulation that A is different from B, and x and y mean an integer from 1 to 100 independent of each other, in amounts of 0.01 to 2 wt % relative to the water phase, as gas hydrate inhibitors.
    Type: Grant
    Filed: May 19, 2010
    Date of Patent: December 30, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Dirk Leinweber, Alexander Roesch, Carsten Schaefer
  • Patent number: 8802740
    Abstract: The present invention provides environmentally friendly demulsifiers for the breakdown of petroleum oil applications. The demulsification formulations of the present invention are biodegradable and are low in toxicity. The demulsifiers include a poly(tetramethylene glycol) and an alkylene glycol copolymer linked to the poly(tetramethylene glycol) by a difunctional coupling agent.
    Type: Grant
    Filed: June 22, 2009
    Date of Patent: August 12, 2014
    Assignee: Nalco Energy Services L.P
    Inventors: Steven P. Newman, Carl Hahn, Robert D. McClain
  • Patent number: 8168062
    Abstract: A multi-component demulsifier comprising an alkoxylated C5-C7 alkyl substituted phenol-formaldehyde resin and at least one polyalkylene oxide triblock copolymer. This synergistic combination of materials is useful in breaking emulsions, of water in hydrocarbon or hydrocarbon in water.
    Type: Grant
    Filed: April 14, 2010
    Date of Patent: May 1, 2012
    Assignee: General Electric Company
    Inventors: Cato Russell McDaniel, Karl Kuklenz, Kurt Ginsel
  • Patent number: 7871964
    Abstract: A composition for mitigating or preventing the formation of an emulsion between naphthenic acid and metal cations in a hydrocarbon body, the composition including at least one alkoxylated amine and at least one acid and/or alcohol is disclosed.
    Type: Grant
    Filed: July 23, 2008
    Date of Patent: January 18, 2011
    Assignees: M-I Australia Pty. Ltd., M-I SWACO Norge AS
    Inventors: James Smith, Chandrashekhar Y. Khandekar, Rohan Wilson
  • Patent number: 7863339
    Abstract: A synergistic demulsifier composition for the improvement of demulsification properties and method of making said composition is disclosed along with a lubricant composition containing same. The demulsifier composition consists of effective amounts of one or more demulsifier additives and one or more dispersants. The demulsifier additives consist of a first copolymer of propylene oxide and ethylene oxide and a second copolymer of propylene oxide and ethylene oxide. The dispersant can be an untreated polyalkene succinimide type dispersant, preferably an untreated polyisobutylene succinimide type dispersant.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: January 4, 2011
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: David G. L. Holt
  • Patent number: 7816414
    Abstract: A synergistic demulsifier composition for the improvement of demulsification properties and method of making said composition is disclosed along with a lubricant composition containing same. The demulsifier composition consists of effective amounts of one or more demulsifier additives and one or more dispersants. The demulsifier additives consist of a first copolymer of propylene oxide and ethylene oxide and a second copolymer of propylene oxide and ethylene oxide. The dispersant can be an untreated polyalkene succinimide type dispersant, preferably an untreated polyisobutylene succinimide type dispersant.
    Type: Grant
    Filed: August 11, 2006
    Date of Patent: October 19, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: David G. L. Holt
  • Patent number: 7786179
    Abstract: Demulsifiers containing an anionic surfactant selected from alkylsulfosuccinates, alkylphosphonic acids, and their salts; a nonionic surfactant selected from ethylene oxide/propylene oxide copolymers, ethoxylated fatty acids of polyethylene glycol, terpene alkoxylates, and modified alkanolamides; and solvent bases comprising blends of dibasic esters. Methods for breaking emulsions using such demulsifiers and solvent bases are also disclosed.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: August 31, 2010
    Assignee: Rhodia Inc.
    Inventors: Ruela Talingting-Pabalan, Gary Woodward, Manilal S. Dahanayake, Herve Adam
  • Patent number: 7771588
    Abstract: The invention pertains to the use of a class of acetylenic surfactants to resolve or break water and oil emulsions. The surfactants are of particular advantage in resolving crude oil emulsions of the type encountered in desalter and similar apparatus designed to extract brines from the crude as they partition to the aqueous phase in the desalter. Also, the surfactants may be used to separate oil from oil sands and similar oil/solids matrices.
    Type: Grant
    Filed: May 30, 2006
    Date of Patent: August 10, 2010
    Assignee: General Electric Company
    Inventors: David Birenbaum Engel, Alan E. Goliaszewski, Cato R. McDaniel
  • Patent number: 7671099
    Abstract: A method for breaking an emulsion of oil and water comprising contacting the emulsion with a demulsifier comprising a terpene alkoxylate is disclosed.
    Type: Grant
    Filed: August 13, 2008
    Date of Patent: March 2, 2010
    Assignee: Rhodia Inc.
    Inventors: Ruela Talingting Pabalan, Gary Woodward, Manilal Dahanayake, Herve Adam
  • Patent number: 7612117
    Abstract: The invention pertains to the use of a class of acetylenic surfactants to resolve or break water and oil emulsions. The surfactants are of particular advantage in resolving crude oil emulsions of the type encountered in desalter and similar apparatus designed to extract brines from the crude as they partition to the aqueous phase in the desalter.
    Type: Grant
    Filed: November 17, 2005
    Date of Patent: November 3, 2009
    Assignee: General Electric Company
    Inventors: Cato R. McDaniel, Alan E. Goliaszewski, David Birenbaum Engel
  • Publication number: 20090197978
    Abstract: A method for breaking a crude oil emulsion includes treating the emulsion at an elevated temperature with a demulsifier. The demulsifier contains at least 70 percent by weight of ethylene oxide, 3-hydroxypropylene oxide, or a mixture and has a cloud point temperature of at least about 100° C. A method for desalting the crude oil is also provided.
    Type: Application
    Filed: January 31, 2008
    Publication date: August 6, 2009
    Inventors: Nimeshkumar Kantilal Patel, Seethalakshmi Suresh
  • Patent number: 7569615
    Abstract: Disclosed is the use of alkoxylated dendrimers for breaking oil/water emulsions. The alkoxylated dendrimers have a molecular weight of from 2400 to 100 000 g/mol and have been alkoxylated with C2-C4-alkylene oxide groups or a mixture of such alkylene oxide groups such that the alkoxylated dendrimer has a degree of alkoxylation of from 1 to 100 alkylene oxide units per free OH group. The alkoxylated dendrimers are added to the oil/water emulsions in amounts of from 0.0001 to 5% by weight, based on the oil content of the emulsion to be demulsified.
    Type: Grant
    Filed: June 19, 2004
    Date of Patent: August 4, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Dirk Leinweber, Michael Feustel, Elisabeth Wasmund, Heidi Rausch
  • Patent number: 7566744
    Abstract: The present invention provides environmentally friendly demulsifiers for the break down of petroleum oil applications. The demulsification formulations of the present invention are biodegradable and are low in toxicity. The demulsifiers include a poly(tetramethylene glycol) and an alkylene glycol copolymer linked to the poly(tetramethylene glycol) by a difunctional coupling agent.
    Type: Grant
    Filed: December 20, 2004
    Date of Patent: July 28, 2009
    Assignee: Nalco Company
    Inventors: Steven P. Newman, Carl Hahn, Robert D. McClain
  • Publication number: 20090149557
    Abstract: Demulsifiers containing an anionic surfactant selected from alkylsulfosuccinates, alkylphosphonic acids, and their salts; a nonionic surfactant selected from ethylene oxide/propylene oxide copolymers, ethoxylated fatty acids of polyethylene glycol, terpene alkoxylates, and modified alkanolamides; and solvent bases comprising blends of dibasic esters. Methods for breaking emulsions using such demulsifiers and solvent bases are also disclosed.
    Type: Application
    Filed: January 7, 2009
    Publication date: June 11, 2009
    Applicant: RHODIA INC.
    Inventors: Ruela Talingting-Pabalan, Gary Woodward, Manilal S. Dahanayake, Herve Adam
  • Patent number: 7491427
    Abstract: [PROBLEMS] To provide a polyimidesiloxane solution composition that is excellent in defoaming ability and that can maintain the wettability of an outer lead bonded portion on a wiring board at a high level, even when it is applied on the surface of the wiring board and then cured, to form an insulating cured film. [MEANS FOR SOLVING PROBLEMS] A polyimidesiloxane solution composition which comprises an organic solvent, polyimidesiloxane soluble in the organic solvent, a curable components such as an epoxy compound and a polyvalent isocyanate compound, and a silicone defoamer, wherein the silicone defoaming agent comprises dimethylpolysiloxane, a polysiloxane compound having a hydrophilic group in a side chain or a terminal moiety, and a micro-powder silica.
    Type: Grant
    Filed: February 21, 2005
    Date of Patent: February 17, 2009
    Assignee: UBE Industries, Ltd.
    Inventors: Koji Hayashi, Yoshiki Tanaka, Katsutoshi Hirashima, Seiichirou Takabayashi
  • Publication number: 20080039537
    Abstract: A synergistic demulsifier composition for the improvement of demulsification properties and method of making said composition is disclosed along with a lubricant composition containing same. The demulsifier composition consists of effective amounts of one or more demulsifier additives and one or more dispersants. The demulsifier additives consist of a first copolymer of propylene oxide and ethylene oxide and a second copolymer of propylene oxide and ethylene oxide. The dispersant can be an untreated polyalkene succinimide type dispersant, preferably an untreated polyisobutylene succinimide type dispersant.
    Type: Application
    Filed: August 11, 2006
    Publication date: February 14, 2008
    Inventor: David G. L. Holt
  • Patent number: 6255263
    Abstract: Hydraulic or industrial functional fluids which exhibit excellent demulse performance are prepared comprising at least one oil-soluble polyoxypropylene glycol monoalkyl ether.
    Type: Grant
    Filed: March 2, 2000
    Date of Patent: July 3, 2001
    Assignee: Ethyl Petroleum Additives, LTD
    Inventor: Helen T. Ryan
  • Patent number: 6225357
    Abstract: Polymer compositions made by reacting a polyol with an aromatic hydrocarbon containing only a single reactive functionality have been discovered to be useful demulsifiers for crude oil compositions. The aromatic hydrocarbon should have at least one aryl group and only one functionality reactive with a hydroxyl. The polyol may optionally be crosslinked prior to reaction with the aromatic hydrocarbon, and the crosslinking agent may be a diepoxide.
    Type: Grant
    Filed: March 8, 1999
    Date of Patent: May 1, 2001
    Assignee: Baker Hughes Incorporated
    Inventors: Patrick J. Breen, James Towner
  • Patent number: 6172123
    Abstract: A method for preventing or breaking oil and water mixtures comprising adding thereto a branched reaction product of A) at least one linking compound of formula I R1(X)3  (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups with two adjacent carbon atoms in the R1 group and an oxygen atom from an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; B) at least one compound of formula II and/or formula III R2(OA)nOH  (II) wherein R2 is an aliphatic group containing from 3 to 36 carbon atoms, n is a number of from 0 to 200, and each OA group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: January 9, 2001
    Assignee: Henkel Corporation
    Inventors: Andreas Lindert, Michael S. Wiggins