The Compound Contains Oxygen (e.g., Cresylic Acid) Patents (Class 516/181)
  • Patent number: 9200206
    Abstract: Methods are provided for making asphalt from crude oils derived from mined oil sands that have been subjected to a solvent froth treatment as part of the process for making a crude oil that is suitable for pipeline transport. A froth treatment is used that preserves a greater percentage of the asphaltene content of the crude oil derived from the mined oil sands.
    Type: Grant
    Filed: August 10, 2012
    Date of Patent: December 1, 2015
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: John H. Brownie, Mary Josephine Gale, Lyle Edwin Moran
  • Patent number: 8956529
    Abstract: Oil-water dispersions and emulsions derived from petroleum industry operations are demulsified and clarified using anionic polymers. Formation of such oil-water dispersion and emulsions is inhibited and mitigated using the anionic polymers. The anionic polymers comprise: A) 2-80% by weight of at least one C3-C8 ?,?-ethylenically unsaturated carboxylic acid monomer; B) 15-80% by weight of at least one nonionic, copolymerizable ?,?-ethylenically unsaturated monomer; C) 1-50% by weight of one or more of the following monomers: C1) at least one nonionic vinyl surfactant ester; or C2) at least one nonionic, copolymerizable ?,?-ethylenically unsaturated monomer having longer polymer chains than monomer B), or C3) at least one nonionic urethane monomer; and, optionally, D) 0-5% by weight of at least one crosslinker.
    Type: Grant
    Filed: August 4, 2010
    Date of Patent: February 17, 2015
    Assignee: Rohm and Haas Company
    Inventors: Norman Edward Byrne, Joseph Manna, Somil Chandrakant Mehta, Peter Rozowski
  • Patent number: 8940832
    Abstract: The invention relates to polymers that can be obtained by polymerizing the monomers (A), (B), and (D), and optionally (C), where (A) is a monomer of formula (I), wherein A stands for C2 to C4 alkylene, B stands for a C2 to C4 alkylene different from A, R stands for hydrogen or methyl, m stands for a number from 1 to 500, n stands for a number from 1 to 500, (B) is an ethylenically unsaturated monomer that contains at least one carboxylic acid function, (C) is optionally a further ethylenically unsaturated monomer different from (A) and (B), (D) is a monomer of formula (II), wherein D stands for C2 to C4 alkylene, E stands for a C2 to C4 alkylene group different from D, F stands for a C2 to C4 alkylene group different from E, R stands for hydrogen or methyl, o stands for a number from 1 to 500, p stands for a number from 1 to 500, q stands for a number from 1 to 500, and wherein the weight fraction of the monomers is 35 to 99% for the macromonomer (A), 0.
    Type: Grant
    Filed: February 15, 2011
    Date of Patent: January 27, 2015
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Carsten Schaefer, Oliver Mogck
  • Patent number: 8920542
    Abstract: The invention relates to the use of polymers, containing between 1 and 100 mol % of structural units of the formula (1), wherein R1 means hydrogen or C1-C6 alkyl, A means C2-C4 alkylene groups, and B means C2-C4 alkylene groups, with the stipulation that A is different from B, and x and y mean an integer from 1 to 100 independent of each other, in amounts of 0.01 to 2 wt % relative to the water phase, as gas hydrate inhibitors.
    Type: Grant
    Filed: May 19, 2010
    Date of Patent: December 30, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Dirk Leinweber, Alexander Roesch, Carsten Schaefer
  • Patent number: 8920543
    Abstract: The invention provides for the use of copolymers comprising 1 to 99 mol % of structural units of the formula (1) in which R1 is hydrogen or C1-C6-alkyl, A is C2-C4-alkylene groups and B is C2-C4-alkylene groups, with the proviso that A is different than B, and x, y are each independently an integer of 1-100, and 1 to 99 mol % of structural units of the formula (3) in which R6 is hydrogen or C1-C6-alkyl, D is C2-C4-alkylene groups and z is an integer of 1-50, in amounts of 0.01 to 2% by weight, based on the water phase, as gas hydrate inhibitors.
    Type: Grant
    Filed: April 27, 2011
    Date of Patent: December 30, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Dirk Leinweber, Alexander Roesch, Carsten Schaefer, Alexander Woerndle
  • Patent number: 8815765
    Abstract: The invention provides a catalyst composition, which includes an emulsion of an aqueous phase in an oil phase, wherein the aqueous phase comprises an aqueous solution containing a group 6 metal and a group 8, 9 or 10 metal. The metals can be provided in two separate emulsions, and these emulsions are well suited for treating hydrocarbon feedstocks.
    Type: Grant
    Filed: February 27, 2012
    Date of Patent: August 26, 2014
    Assignee: Intevep, S.A.
    Inventors: Jose Cordova, Francisco Granadillo, Roger Marzin, Bruno Solari, Luis Zacarias
  • Patent number: 8133924
    Abstract: Demulsifiers containing an anionic surfactant selected from alkylsulfosuccinates, alkylsulfonates, alkylphosphonic acids, and their salts; a nonionic surfactant selected from ethylene oxide/propylene oxide copolymers, ethoxylated fatty acids of polyethylene glycol, terpene alkoxylates, and modified alkanolamides; or a combination of an anionic and a nonionic surfactant, and methods of use thereof in breaking emulsions.
    Type: Grant
    Filed: April 2, 2009
    Date of Patent: March 13, 2012
    Assignee: Rhodia Operations
    Inventors: Ruela Talingting-Pabalan, Manilal S. Dahanayake, Gary Woodward, Herve Adam
  • Publication number: 20120029259
    Abstract: In various aspects, the invention provides for processing a hydrocarbon feed having hydrocarbon and emulsified aqueous components demulsifying into hydrocarbon and aqueous phases over an initial demulsification time, with an active agent to form a treated feed. The active agent has an active agent solubility in the hydrocarbon component and in the aqueous component, the aqueous component has an aqueous component solubility in the hydrocarbon component. The active agent solubility in the hydrocarbon component is greater than the aqueous component solubility in the hydrocarbon component. The active agent solubility in the aqueous component is greater than the active agent solubility in the hydrocarbon component. The active agent solubility in the aqueous component is greater than the active agent solubility in the hydrocarbon component.
    Type: Application
    Filed: December 17, 2009
    Publication date: February 2, 2012
    Applicant: SUNCOR ENERGY, INC.
    Inventors: Richard A. McFarlane, Michael Peter Singleton
  • Patent number: 7923418
    Abstract: This invention provides acrylate polymers having at least two different ester groups. The ester groups are selected from the following: a) an aralkyl group; b) a linear alkylether group; c) a polyethoxylated alkylaryl group; and d) a polyethoxylated alkyl group, with the proviso that at least one of said ester groups is selected from b) or d). Processes for preparing such polymers and processes for breaking emulsions with these acrylate polymers are also provided.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: April 12, 2011
    Assignee: Baker Hughes Incorporated
    Inventor: Harold L. Becker
  • Patent number: 7863339
    Abstract: A synergistic demulsifier composition for the improvement of demulsification properties and method of making said composition is disclosed along with a lubricant composition containing same. The demulsifier composition consists of effective amounts of one or more demulsifier additives and one or more dispersants. The demulsifier additives consist of a first copolymer of propylene oxide and ethylene oxide and a second copolymer of propylene oxide and ethylene oxide. The dispersant can be an untreated polyalkene succinimide type dispersant, preferably an untreated polyisobutylene succinimide type dispersant.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: January 4, 2011
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: David G. L. Holt
  • Patent number: 7816414
    Abstract: A synergistic demulsifier composition for the improvement of demulsification properties and method of making said composition is disclosed along with a lubricant composition containing same. The demulsifier composition consists of effective amounts of one or more demulsifier additives and one or more dispersants. The demulsifier additives consist of a first copolymer of propylene oxide and ethylene oxide and a second copolymer of propylene oxide and ethylene oxide. The dispersant can be an untreated polyalkene succinimide type dispersant, preferably an untreated polyisobutylene succinimide type dispersant.
    Type: Grant
    Filed: August 11, 2006
    Date of Patent: October 19, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: David G. L. Holt
  • Patent number: 7786179
    Abstract: Demulsifiers containing an anionic surfactant selected from alkylsulfosuccinates, alkylphosphonic acids, and their salts; a nonionic surfactant selected from ethylene oxide/propylene oxide copolymers, ethoxylated fatty acids of polyethylene glycol, terpene alkoxylates, and modified alkanolamides; and solvent bases comprising blends of dibasic esters. Methods for breaking emulsions using such demulsifiers and solvent bases are also disclosed.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: August 31, 2010
    Assignee: Rhodia Inc.
    Inventors: Ruela Talingting-Pabalan, Gary Woodward, Manilal S. Dahanayake, Herve Adam
  • Patent number: 7771588
    Abstract: The invention pertains to the use of a class of acetylenic surfactants to resolve or break water and oil emulsions. The surfactants are of particular advantage in resolving crude oil emulsions of the type encountered in desalter and similar apparatus designed to extract brines from the crude as they partition to the aqueous phase in the desalter. Also, the surfactants may be used to separate oil from oil sands and similar oil/solids matrices.
    Type: Grant
    Filed: May 30, 2006
    Date of Patent: August 10, 2010
    Assignee: General Electric Company
    Inventors: David Birenbaum Engel, Alan E. Goliaszewski, Cato R. McDaniel
  • Patent number: 7671099
    Abstract: A method for breaking an emulsion of oil and water comprising contacting the emulsion with a demulsifier comprising a terpene alkoxylate is disclosed.
    Type: Grant
    Filed: August 13, 2008
    Date of Patent: March 2, 2010
    Assignee: Rhodia Inc.
    Inventors: Ruela Talingting Pabalan, Gary Woodward, Manilal Dahanayake, Herve Adam
  • Patent number: 7671098
    Abstract: The invention relates to the use of alkoxylated crosslinked polyglycerols for demulsifying oil/water emulsions in amounts of from 0.0001 to 5% by weight, based on the oil content of the emulsion to be demulsified. The alkoxylated crosslinked polyglycerols of the invention is crosslinked with multifunctional electrophilic compounds having a molecular weight of from 1000 to 100 000 units and which comprise 5 to 100 glycerol units which are alkoxylated with C2-C4-alkylene oxide groups or a mixture of such alkylene oxide groups so that the crosslinked alkoxylated polyglycerols have a degree of alkoxylation of from 1 to 100 alkylene oxide units per free OH group.
    Type: Grant
    Filed: May 25, 2004
    Date of Patent: March 2, 2010
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Dirk Leinweber, Franz-Xaver Scherl, Elisabeth Wasmund, Heidi Rausch
  • Publication number: 20090197978
    Abstract: A method for breaking a crude oil emulsion includes treating the emulsion at an elevated temperature with a demulsifier. The demulsifier contains at least 70 percent by weight of ethylene oxide, 3-hydroxypropylene oxide, or a mixture and has a cloud point temperature of at least about 100° C. A method for desalting the crude oil is also provided.
    Type: Application
    Filed: January 31, 2008
    Publication date: August 6, 2009
    Inventors: Nimeshkumar Kantilal Patel, Seethalakshmi Suresh
  • Patent number: 7569615
    Abstract: Disclosed is the use of alkoxylated dendrimers for breaking oil/water emulsions. The alkoxylated dendrimers have a molecular weight of from 2400 to 100 000 g/mol and have been alkoxylated with C2-C4-alkylene oxide groups or a mixture of such alkylene oxide groups such that the alkoxylated dendrimer has a degree of alkoxylation of from 1 to 100 alkylene oxide units per free OH group. The alkoxylated dendrimers are added to the oil/water emulsions in amounts of from 0.0001 to 5% by weight, based on the oil content of the emulsion to be demulsified.
    Type: Grant
    Filed: June 19, 2004
    Date of Patent: August 4, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Dirk Leinweber, Michael Feustel, Elisabeth Wasmund, Heidi Rausch
  • Publication number: 20090048352
    Abstract: A method for breaking an emulsion of oil and water comprising contacting the emulsion with a demulsifier comprising a terpene alkoxylate is disclosed.
    Type: Application
    Filed: August 13, 2008
    Publication date: February 19, 2009
    Inventors: Ruela TALINGTING-PABALAN, Gary Woodward, Manilal Dahanayake, Herve Adan
  • Publication number: 20080039537
    Abstract: A synergistic demulsifier composition for the improvement of demulsification properties and method of making said composition is disclosed along with a lubricant composition containing same. The demulsifier composition consists of effective amounts of one or more demulsifier additives and one or more dispersants. The demulsifier additives consist of a first copolymer of propylene oxide and ethylene oxide and a second copolymer of propylene oxide and ethylene oxide. The dispersant can be an untreated polyalkene succinimide type dispersant, preferably an untreated polyisobutylene succinimide type dispersant.
    Type: Application
    Filed: August 11, 2006
    Publication date: February 14, 2008
    Inventor: David G. L. Holt
  • Patent number: 6727388
    Abstract: The present invention is a demulsifying and corrosion-inhibiting compound formed from the salt of an amphiphilic amine and an amphiphilic acid. In a preferred embodiment of the invention, the demulsifier may be a salt of an alkyl amine and an alkyl aryl sulfonic acid. Even more preferably, the demulsifier may be a salt of a methyl, di-cocoyl amine and an alkyl aryl sulfonic acid. According to another embodiment of the invention, an organic system may be demulsified by mixing the salt of an alkyl amine and an alkyl sulfonic acid with the system to be demulsified.
    Type: Grant
    Filed: February 4, 2003
    Date of Patent: April 27, 2004
    Assignee: Pilot Chemical Holdings, Inc.
    Inventor: Robert Golden
  • Publication number: 20030130534
    Abstract: The present invention is a demulsifying and corrosion-inhibiting compound formed from the salt of an amphiphilic amine and an amphiphilic acid. In a preferred embodiment of the invention, the demulsifier may be a salt of an alkyl amine and an alkyl aryl sulfonic acid. Even more preferably, the demulsifier may be a salt of a methyl, di-cocoyl amine and an alkyl aryl sulfonic acid. According to another embodiment of the invention, an organic system may be demulsified by mixing the salt of an alkyl amine and an alkyl sulfonic acid with the system to be demulsified.
    Type: Application
    Filed: February 4, 2003
    Publication date: July 10, 2003
    Applicant: Pilot Chemical Holdings, Inc.
    Inventor: Robert Golden