Abstract: Three types of trisiloxane surfactants having the basic formula: MDM? are described wherein the substituents on the differing M and M? groups in conjunction with a pendant polyalkylene oxide substituents on the D group to render the surfactant resistant to hydrolysis under either basic or acidic conditions.

Abstract: Methods of treating a wellbore comprise displacing a drilling fluid comprising an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage into the wellbore. Methods of drilling a wellbore comprise: applying torque to a bit within the wellbore and concurrently applying force to urge the bit to extend through the wellbore; and circulating a drilling fluid past the bit to remove cuttings therefrom, the drilling fluid comprising an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage. Methods of preparing a drilling fluid comprise: forming an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage; and combining the organophilic clay with an oil-based fluid.

Abstract: The present invention provides methods of conducting emulsion polymerizations and dispersion resulting therefrom. The present invention additionally provides substrates coated or treated with polymeric dispersions.

Abstract: An invert emulsion drilling fluid, and a method for the use thereof in drilling wellbores, with good rheological properties at high temperatures and pressures. One embodiment of the drilling fluids are free of organophilic clays and lignites, free of calcium chloride, and comprise an alcohol in the internal phase, a quaternary ammonium emulsifier, and argillaceous solids. In one embodiment, the alcohol is a glycerol, a polyglycerol, or a mixture thereof. In one embodiment, the base oil for the emulsion is a paraffin and/or mineral oil. The drilling fluids provide good lubricity and high rates of penetration.

Abstract: To provide a precious metal colloid enabling a production in simply and in low cost, a long-term storage, and a formation of a thin film having a high conductivity, a precious metal fine-particle, a composition including the same, and a method for producing a precious metal fine-particle for forming such precious metal colloid, which is a precious metal colloid in which a protection component protects a precious metal fine-particle selected from gold, silver, platinum, and palladium, a precious metal colloid in which the maximum peak of 13C-NMR spectrum of the protection component separated from the precious metal colloid by ultracentrifugation treatment presents in 160 to 190 ppm other than peaks of a primary carbon and an aromatic carbon, or a precious metal colloid in which peaks of 13C-NMR spectrum present in 20 to 90 ppm and 160 to 190 ppm.

Abstract: Amine dispersants are disclosed. Also disclosed are organic dispersions that comprise ultrafine particles and an amine dispersant. The amine dispersant is the Michael addition product of reactants that include (a) a polyether (meth)acrylate and (b) a polyamine. Also disclosed are coating compositions that comprise such dispersions and substrates at least partially coated with such coating compositions.

Abstract: The present invention relates to new organodisilanes or carbodisilanes, a process for manufacturing the same and their use, in particular, as surface active agents, especially as spreading agents.

Abstract: Single phase microemulsions improve the removal of filter cakes formed during drilling with oil-based muds (OBMs). The single phase microemulsion removes oil and solids from the deposited filter cake. Optionally, an acid capable of solubilizing the filter cake bridging particles may also be used with the microemulsion. In one non-limiting embodiment the acid may be a polyamino carboxylic acid. Skin damage removal from internal and external filter cake deposition can be reduced. In another optional embodiment, the single phase microemulsion may contain a filtration control additive for delaying the filter cake removal, destruction or conversion.

Abstract: Methods are provided including methods of treating a well bore with drilling fluids comprising organophilic clays treated with quaternary ammonium surfactants having at least two amide linkages. In some embodiments, the methods comprise: providing a drilling fluid comprising a nonaqueous phase and an organophilic clay treated with a quaternary ammonium surfactant having at least two amide linkages; and placing at least a portion of the drilling fluid into the well bore. In other embodiments, the methods comprise combining an organophilic clay with a quaternary ammonium surfactant having at least one amide linkage to form a mixture, and combining the mixture with a fluid comprising a nonaqueous phase to form a drilling fluid. Additional methods are also provided.

Abstract: An invert emulsion fluid system and a method of performing petroleum recovery operations using an invert emulsion fluid system.

Abstract: The use of water-soluble aromatic polysulfonic acid salts for inhibiting fouling in process equipment used in the thermal treatment of heavy oils.

Abstract: Methods for the formation of colloidal suspensions. The method includes combining an aqueous substance with a second substance that is normally immiscible with the aqueous substance, to form a mixture, and before, during or after the combining removing dissolved gases from one or both of the aqueous and second substance, whereby the aqueous and second substances mix and form a colloidal suspension. The methods for the formation of colloidal suspensions include methods for the formation of emulsions as well as particulate dispersions. The methods used to form the colloidal suspensions in accordance with the present invention produce colloidal suspensions that are stable for periods from an hour to several weeks in the absence of surfactants or stabilizing agents.

Abstract: A method and a device for making a dispersion or an emulsion (41) from at least two fluids known to be unmiscible, the fluids constituting a dispersed phase (40) and a dispersing phase (44), the dispersed phase (40) being driven through a porous body (24) into the dispersing phase (44). The invention is characterized in that the porous body (24) is vibrated by a mechanical, electrical or magnetic excitation.

Abstract: Methods for the production of shaped nanoscale-to-microscale structures, wherein a nanoscale-to-microscale template is provided having an original chemical composition and an original shape, and the nanoscale-to-microscale template subjected to a chemical reaction, so as to partially or completely convert the nanoscale-to-microscale template into the shaped nanoscale-to-microscale structure having a chemical composition different than the original chemical composition and having substantially the same shape as the original shape, being a scaled version of the original shape. The shaped nanoscale-to-microscale structure formed comprises an element (such as silicon), a metallic alloy (such as a silicon alloy), or a non-oxide compound (such as silicon carbide or silicon nitride).

Abstract: Disclosed is a process for the preparation of emulsifiers E1 which are obtained by (a) reacting a polyol with propylene oxide or a mixture of ethylene oxide and propylene oxide, to give an intermediate Z1, (b) reacting the intermediate Z1 with epichlorohydrin, forming an intermediate Z2, (c) reacting the intermediate Z2 with an adduct of ethylene oxide or a mixture of ethylene oxide and propylene oxide, with a C1-C22 monoalcohol, provided that on average at least one epoxide function of the intermediate Z2 is reacted and on average at least one epoxide function originating from the intermediate Z2 is retained. Compounds E1 are suitable as emulsifiers for preparing aqueous emulsions or dispersions of epoxy resins.

Abstract: Emulsions for use in precipitating water-insoluble drug nanoparticles. The continuous phase of the emulsions include water and an external surfactant. The discontinuous phase of the emulsions include butyl lactate, a co-solvent, an internal surfactant and a water-insoluble drug that is solubilized in the discontinuous phase. The emulsions allow for the precipitation of nanoparticles of water-insoluble drugs that are otherwise difficult or impossible to precipitate using conventional emulsion techniques.

Abstract: A method for upgrading heavy oils by contacting the heavy oil with a water-soluble aromatic polysulfonic acid salt and then thermally treating the contacted heavy oil. The polysulfonic acid salt can be recovered and recycled from contacting the heavy oil. The polysulfonic acid salt is recovered and recycled. The invention also relates to the upgraded product from the enhanced thermal treatment process.

Abstract: An emulsion includes a substantially continuous liquid medium, and a plurality of droplet structures dispersed within the substantially continuous liquid medium. Each droplet structure of the plurality of droplet structures includes an outer droplet of a first liquid having an outer surface; an inner droplet of a second liquid having an inner surface contained within the outer surface of the outer droplet of the first liquid, the second liquid being immiscible in the first liquid, wherein the inner and outer droplets have a boundary surface region therebetween; an outer layer of block copolymers disposed on the outer surface of the outer droplet; and an inner layer of block copolymers disposed on the inner surface of the inner droplet. The block copolymers include a hydrophilic polymer block and a hydrophobic polymer block that act in combination to stabilize the droplet structure, and the first liquid is immiscible in the substantially continuous liquid medium.

Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water-soluble anionic copolymer prepared via a water-in-oil polymerization technique that, absent a cross-linking agent, is characterized by a Huggins' constant (k?) determined in 0.01M NaCl greater than 0.75 and a storage modulus (G?) for a 1.5 wt. % actives polymer solution at 4.6 Hz greater than 175 Pa.

Abstract: The disclosed invention relates to a process for making an emulsion. The process comprises: flowing a first liquid through a process microchannel having a wall with an apertured section; flowing a second liquid through the apertured section into the process microchannel in contact with the first liquid, the second liquid being immiscible with the first liquid, the first liquid forming a continuous phase, and the second liquid forming a discontinuous phase dispersed in the first liquid.

Abstract: The present invention relates to new organodisilanes or carbodisilanes, a process for manufacturing the same and their use, in particular, as surface active agents, especially as spreading agents.

Abstract: The present invention provides methods of conducting emulsion polymerizations and dispersion resulting therefrom. The present invention additionally provides substrates coated or treated with polymeric dispersions.

Abstract: Amine dispersants are disclosed. Also disclosed are organic dispersions that comprise ultrafine particles and an amine dispersant. The amine dispersant is the Michael addition product of reactants that include (a) a polyether (meth)acrylate and (b) a polyamine. Also disclosed are coating compositions that comprise such dispersions and substrates at least partially coated with such coating compositions.

Abstract: An anionic surfactant concentrate and method for making includes providing compound (I) R1—OH where R1 represents a branched C6-22 radical with average branching of about 2-8 per radical; providing compound (II): where R2 represents a C8-16 radical; mixing (I) and (II); ethoxylating to obtain a reaction product; reacting with a sulfating, phosphating, or sulfitation agent to obtain R1—O—[CH2—CH2O]n—A and where R1 represents a branched C6-22 radical with average branching of about 2-8, R2 represents a C8-16 radical, A represents —SO3M, —PO3M, —PO3M2, —OCCH2CH(SO3Na) COO—, or HOOCCH2CH(SO3Na)COO—, M represents a positive counterion, n represents a value from 0-100, and x and y each represents a value from 0-100, where the sum of x and y represents a value of at least 1 to 100 are provided. Anionic surfactant compositions containing the concentrate and methods for stabilizing are also provided.

Abstract: The present invention provides a novel cellular solid structure which can be used to structure an oil-water mixture into a semi-solid state. The invention is particularly useful in the manufacture of food products, drug delivery agents, coatings, barrier films and encapsulating media.

Abstract: Thermoreversible organogelator compositions comprising compounds of the formula: where X is C6 to C12 alkylene and R is C9 to C12 alkyl, and their methods of use, including forming a gel to immobilize a solvent using the compound. The method can be used to form gels that can be used for the transportation of volatile organic solvents like gasoline, cooking oil, and contaminated organic liquids to be incinerated.

Abstract: Ultradispersed ones of primary particles of nanometer-sized carbon are obtained by applying a wet-type milling method and/or a wet dispersion method to an aggregate structure of the primary particles to overcome van der Waals forces, by which forces the primary particles are held together to form the aggregate structure, whereby the ultradispersed primary particles are obtained in a colloidal dispersion on a large-scale basis at low cost without using any additive. In a method of manufacturing the ultradispersed primary particles, the wet-type milling method is carried out in a ball mill, preferably in combination with a high-energy ultrasonic-wave process carried out in a dispersing medium such as pure water, whereby a colloidal solution or slurry with a low-concentration of the primary particles ultradispersed in the dispersing medium is obtained.

Abstract: A method for enabling the use of heavy oil residuum by conversion to a useful product. The method, in one embodiment, involves the use of a heavy oil residuum which is substantially non flowable. The viscosity of the residuum is reduced by heat or a combination of heat and a diluent and subsequently mixed with water such that the mixing is high shear mixing. This results in the formation of an emulsion of predispersed residuum in an aqueous matrix. The emulsion is formed such that the aqueous matrix is in a size distribution suitable for use as a combustible fuel.

Abstract: The present invention relates to a stable emulsion of an immiscible fluid and of an aqueous phase having a determined pH value. The emulsion is optimized in that it comprises an ionic surfactant and a polyampholytic polymer whose charge depends on the pH value. The respective amounts of surfactant and of polymers are determined according to the charges. Stabilization or destabilization of the emulsion is adjusted by controlling the pH value. The invention also relates to a method of stabilizing and destabilizing an emulsion comprising a surfactant combined with an ampholytic polymer.

Abstract: Emulsified systems of a surfactant-stabilized, biodegradable water-in-solvent emulsion with bimetallic particles contained with the emulsion droplets are useful at removing PCBs from ex situ structures. The hydrophobic emulsion system draws PCBs through the solvent/surfactant membrane. Once inside the membrane, the PCBs diffuse into the bimetallic particles and undergo degradation. The PCBs continue to enter, diffuse, degrade, and biphenyl will exit the particle maintaining a concentration gradient across the membrane and maintaining a driving force of the reaction.

Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water-soluble anionic copolymer prepared via a water-in-oil polymerization technique that, absent a cross-linking agent, is characterized by a Huggins' constant (k?) determined in 0.01M NaCl greater than 0.75 and a storage modulus (G?) for a 1.5 wt. % actives polymer solution at 4.6 Hz greater than 175 Pa.

Abstract: This invention provides azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and water that are environmentally desirable for use as refrigerants, aerosol propellants, metered dose inhalers, blowing agents for polymer foam, heat transfer media, and gaseous dielectrics.

Abstract: Improved fuel compositions and fuel additive packages are disclosed which serve to increase the combustion efficiency of conventional fuels while reducing the level of CO2 emissions generated upon the combustion of the fuels. The fuels may be essentially water-free hydrocarbon fuels such as gasoline or diesel fuel, or may be in the form of hydrosols. The additive packages of the invention include sorbitan oleate, a polyoxyethylene alcohol, an alkylene glycol, and an amine.

Abstract: The present invention relates to nano-sized self-assembled structured concentrates and their use as effective suitable carriers for transferring active components into the human body. The nano-sized self-assembled concentrates are composed of an aqueous phase, an oil phase, a surfactant a co-solvent and co-surfactant. The formed nano-sized self-assembled structured concentrates may be in the form of an aqueous continuous phase, an oil continuous phase or a bicontinuous phase, and may thus be diluted to any desired extent in either oil or water maintaining their structure and the active material comprised within the nano-sized self-assembled structured concentrates.

Abstract: The present invention relates to emulsion compositions for starting a reformer of a fuel cell system. In particular, the invention includes emulsion compositions comprising hydrocarbon fuel, water and alkoxylated triazine surfactants for starting a reformer of a fuel cell system.

Abstract: Disclosed are electrostatically-sprayable topical compositions, more particularly topical emulsion compositions, and methods of treating the skin by electrostatic application of such compositions. In one aspect the composition comprises an insulating external phase comprising one or more insulating materials and a conductive internal phase comprising one or more conductive materials. The compositions preferably also contain one or more particulate materials to be deposited on the skin, e.g., pigments, inert absorbents and the like.

Abstract: A zero-valent metal emulsion is used to dehalogenate solvents, such as pooled dense non-aqueous phase liquids (DNAPLs), including trichloroethylene (TCE). The zero-valent metal emulsion contains zero-valent metal particles, a surfactant, oil and water. The preferred zero-valent metal particles are nanoscale and microscale zero-valent iron particles.

Abstract: A zero-valent metal emulsion containing zero-valent metal particles is used to remediate contaminated natural resources, such as groundwater and soil. In a preferred embodiment, the zero-valent metal emulsion removes heavy metals, such as lead (Pb), from contaminated natural resources. In another preferred embodiment, the zero-valent metal emulsion is a bimetallic emulsion containing zero-valent metal particles doped with a catalytic metal to remediate halogenated aromatic compounds, such as polychlorinated biphenyls (PCBs), from natural resources.

Abstract: This invention is a method of preparing a quaternized amidoamine surfactant comprising reacting an amidotertiaryamine of formula with methyl halide and alkylene oxide, an aqueous quaternized amidoamine surfactant composition, a gelled aqueous composition comprising the quaternized amidoamine surfactant composition and one or more salts or alcohols and use of the gelled aqueous composition for fracturing subterranean formations.

Abstract: The present invention relates to the production of dispersions and is particularly suitable for making dispersions with a viscous or solid dispersed phase in a continuous phase with a lower viscosity.

Abstract: This invention provides azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and water that are environmentally desirable for use as refrigerants, aerosol propellants, metered dose inhalers, blowing agents for polymer foam, heat transfer media, and gaseous dielectrics.

Abstract: Methods and apparatuses for comminuting and stabilizing small particles are provided. In one embodiment, an apparatus moves an organic compound dissolved in a solvent to form a suspension of particles in a first fluid stream and moves the suspension in a second fluid stream, wherein the second fluid stream is oriented and positioned with respect to the first stream to cause shearing between the streams and mixing of at least some of the particles in the first and second streams.

Abstract: A process for preparing particles of a substance comprising contacting a first formulation including a first substance with a first solvent stream and a second solvent stream, thereby causing formation of particles of the first substance, wherein both the first and second solvent streams are in a non-supercritical state, and subjecting the resultant mixture to a separation process which causes separation of the first substance from the first and second solvent streams.

Abstract: A fuel composition for fuel cells includes a polar solvent such as water, a first portion of a first fuel dissolved in the solvent at a saturated concentration, and a second portion of the first fuel suspended in the solvent to serve as a reservoir of fuel as the dissolved portion is consumed. Preferably, the first fuel is a hydride such as NaBH4. Optionally, the fuel composition also includes a second fuel such as an alcohol that also controls the solubility of the first fuel in the solvent, inhibits decomposition of the first fuel and stabilizes the suspension. Preferably, the fuel composition also includes an additive such as an alkali for stabilizing the first fuel.

Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water-soluble anionic copolymer prepared via a water-in-oil polymerization technique that, absent a cross-linking agent, is characterized by a Huggins' constant (k′) determined in 0.01M NaCl greater than 0.75 and a storage modulus (G′) for a 1.5 wt. % actives polymer solution at 4.6 Hz greater than 175 Pa.

Abstract: The present invention provides for a device and method of creating hydrodynamic cavitation in fluids. The device comprises a chamber formed by a wall where the wall has a first orifice and an opposing second orifice that are both in fluid communication with said chamber. The first orifice and the second orifice share the same center-line and the first orifice has a diameter smaller than that of the second orifice. The method comprises the steps of: introducing a first liquid stream through the first orifice of the device to create a first liquid jet; introducing a second liquid stream through the second orifice of the device to create a second liquid jet; creating a high shear intensity vortex contact layer when the first liquid jet interacts with and penetrates the second liquid jet; and creating and collapsing cavitation caverns and bubbles in the high shear intensity vortex contact layer.

Abstract: Suspensions are provided of water-soluble materials in non-aqueous carrier fluids using suspension agents that include thixotropic agents and, optionally, organophilic clays. Methods of forming such suspensions are provided. Methods are also provided for using such suspensions to prepare aqueous solutions, in particular thickened aqueous solutions, in particular for use in oilfield treatments.

Abstract: The invention relates to hydrocarbon-free aqueous creams of organosilicon compounds, their preparation and their use.

Abstract: A non-aqueous dispersion (NAD) resin from natural oils having solids content of greater than 90%, and more preferably, greater than 95%, fast cure, low VOC, and low bake temperatures, and wherein the inclusion of multifunctional isocyanates provide faster dry times and harder films.

Abstract: An invert emulsion drilling fluid includes an oleaginous continuous phase; a non-oleaginous discontinuous phase; a biodegradable surfactant including a di-fatty acid ester of triglycerol; and a weighting agent. It si preferred that the fatty acid have the formula RCO2H in which R is an alkyl or akenyl having 10 to 20 carbon atoms. The oleaginous fluid is selected from diesel oil, mineral oil, synthetic oil, ester oils, glycerides of fatty acids, aliphatic esters, aliphatic ethers, aliphatic acetals, or other such hydrocarbons and combinations of these and similar compounds. The non-oleaginous phase is selected from fresh water, sea water, brine, aqueous solutions containing water soluble organic salts, water soluble alcohols or water soluble glycols or combinations of these and similar compounds.

Abstract: A simulated insect trapping surface for removably supporting visual representations of insects. A plurality of icons symbolizing insects, for attaching to the simulated trapping surface, and an adhesive interface between each icon and the surface for temporarily holding the icons on the surface, for teaching interpretation of an insect pattern in a sticky monitoring trap. Instead of the adhesive interface, the simulated trapping surface supports visual representations of the insects by including liquid crystal, and is transparent to light for optical projection of the representations for viewing and interpretation.